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Structural Bonding
of Lightweight Cars
Crash durable, safe and economical
„Without the use of bonding technology, modern lightweight
designs would hardly be feasible – especially when it comes to
bonding dissimilar and/or new materials.“
Dr. Andreas Groß, Advanced Training and Technology Transfer, Fraunhofer IFAM
Publisher: Dow Automotive Systems | Am Kronberger Hang 4 | D-65824 Schwalbach | www.dowautomotive.com
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E d i t o r i a l
BondingTechnology
Meets Lightweight
Construction
Dear Readers,
The automotive industry has in recent years successfully at-
tempted to build lighter vehicles with more fuel-efficient engines
in order to significantly reduce fleet consumption in accordance
with legal requirements. Significantly lower fuel consumption
and CO2
emissions have been the immediate pay-off of such de-
velopments.
Improved fuel consumption, environmental friendliness, driving
comfort, and safety therefore feature among the sales argu-
ments many car manufacturers now employ for their marketing
strategies.
Automotive suppliers and material manufacturers support car
makers in developing modern lightweight designs and respond
to questions concerning the potentials of current technologies
and materials to satisfy challenging future requirements.
In this context, industry experts assume that steel will remain the
primary material for vehicle structures. However, new high
strength steel grades are finding their way into vehicle structures.
Metals with low density such as aluminium and even magnesium
are increasing in demand – as are polymer materials such as fi-
bre-reinforced composites.
Fuelled by the importance of those very diverse materials, ques-
tions regarding bonding technology enter centre stage of the
discussion. This is the key interface between lightweight con-
struction and bonding technologies for new vehicle designs.
Modern lightweight designs require new bonding technologies
in addition to new materials and/or an increased material mix.
Bonding is of special importance here. It enables the use of new
materials, new material combinations and it provides structural
advantages for bonded components.
Please review the following technical summary to learn more
about the status quo of existing concepts as well as new poten-
tial development in adhesives and foams for use in modern light
weight vehicle construction.
I wish you a fascinating read and successful bonding!
Dr. Andreas Lutz
Head Developer“Metal Bonding Europe“
Dow Automotive, Horgen, Switzerland
K l e b - u n d D i c h t s t o f f e
www.lightweight-design.de
1 I n n o v at i v e L i g h t w e i g h t De s i g n s i n
Ve h i c l e De v e l o p m e n t
1 . 1 W e i g ht r e d u ctio n for m e e ti n g
f u t u r e l e g al sta n dards
Two main factors drive vehicle weight reduction. In addition to
the future maximum values for CO2
emissions as expressed in
the EU Directive 443/2009, an increasing number of countries
are planning road usage fees based on such emissions. Both fac-
tors in combination with increased fuel prices result in a strong
motivation to purchase low emission vehicles.
Fuel consumption can be lowered by a number of different
methods. Lightweight vehicle construction is a significant factor
throughout, immediately contributing to reducing fuel con-
sumption. Savings by downgauging vehicle components such
as powertrain, engine, and underbody yield further secondary
effects. Various studies show that a 100 kg weight reduction re-
sults in reduced emissions of 5.0 to 12.5 g of CO2
(ca. 3 to 7 %)
per driven kilometre.
Representing approximately 40 % of total vehicle weight, the car
body is the heaviest vehicle element. The consequent imple-
mentation of lightweight measures in the car body appears
therefore very effective. Increasing demands regarding stiffness,
acoustics, crash performance and long-term stability are gener-
ally in conflict with lightweight construction and underline the
complexity of this challenge.
1 . 2 C u rr e n t tr e n ds for r e d u ci n g v e hicl e
w e i g ht
Several methods for weight reduction are available. The three
most important approaches are:
1.	 Use of low-density materials
Aluminium, magnesium and plastics/thermoset composites are
often used in mounted parts and covers. According to a state-
ment by the Aluminum Association Inc., aluminium contributed
to an average of 7.8 % of the total weight for passenger vehicles
in the year 2009.
2.	 Targeted use of high-strength materials
High- and highest-strength steels are solutions for wall thickness-
reduced components. Tailored welded or tailored rolled-blanks
are related technologies that make use of this principle.
3.	 Integrated lightweight construction
This is a combination of various materials and functional charac-
teristics based on the use of bonding technologies and produc-
tion processes.
The most significant lightweight construction trend over recent
years is the use of high-strength steels (HSS). Even vehicle bodies
of the European compact car class now contain a HSS share of 50
to 65 %. Without exception, the safety cells of today’s cars consist
mainly of HSS. Tailored welded or tailored rolled blank technolo-
gies are consequently used for further optimisation.
Another significant trend is the use of thermoplastics and ther-
moset composites in bonded roof components, hoods, trunk
Structural adhesives
The key to making lightweight cars
Modern lightweight designs require new bonding technologies in addition to new
materials and/or an increased material mix. Bonding is of special importance here. It
enables the use of new materials, new material combinations and it provides structural
advantages for bonded components.
 K l e b - u n d D i c h t s t o f f e
covers and some body structure components. As the article will
describe in further detail, bonding technology could also solve
the challenge of joining various metallic and non-metallic ma-
terials.
1 . 3 T h e path toward a bala n c e d car
bod y
As mentioned above, reducing the body weight, while simulta-
neously increasing performance, is a complex task.The following
elements are key demands when developing innovative solu-
tions:
Increasing the static and dynamic stiffness to improve the
general vehicle quality and to optimize driving and handling
characteristics.
Reducing vibrations and noise (noise, vibration, harshness
and acoustics).
Optimising crash behaviour to comply with legal and volun-
tary safety guidelines (EG: NCAP safety testing)
Extending vehicle lifespan and long term value via higher
quality and retained driving characteristics.
Improvements in those four areas are by no means the only chal-
lenges when reducing vehicle weight. A new vehicle generation
often requires the development of greater passenger space. Con-
sequently, new vehicle models are rarely lighter than their prede-
cessors.
1 . 4 P ot e n tials a n d limits of c u rr e n t
t e ch n olo g y tr e n ds
Five years ago, mild steel contributed between 40 and 50 % of
the body shell weight. Today, new vehicles generally contain a
mild steel share not exceeding 20 to 25 %. Further materials in-
clude mostly high-strength steels and, increasingly, aluminium.
Using high- and ultra high- strength steels allowed wall thick-
nesses reduction up to 0.5 mm. It is however unlikely that such
steel grades can further increase the structural optimisation po-
tential.
1.
2.
3.
4.
Particular weight reduction measures such as tailored welded
or tailored rolled blanks have in the meantime also become a
standard in compact cars. When considering the strongly rising
aluminium share on top of that, it becomes clear that addi-
tional new technologies will be required to further reduce
weight.
2 S tat u s q u o o f s t r u c t u r a l b o n d i n g
i n t h e v e h i c l e b o d y
Structural adhesives and structural foams (see chapter 5) are
polymer solutions offering a great potential for body weight re-
ductions: Figure 1.
Such technology concepts allow for additional performance im-
provements even in already-optimised body structures. These
methods will be explained in more detail below.
2 . 1 S tr u ct u ral bo n di n g of u n coat e d
m e tal s u bstrat e s
Structural bonding signifies permanent and stable bonding
increasing the overall efficiency and effectiveness of a conven-
tionally joined structure. For current automotive metal bonding
applications more than 95 % is based on epoxy adhesives. This
is due to the combination of various advantageous character-
istics such as oil absorption capacity, durability, and outstand-
ing mechanical characteristics across a wide temperature
range.
Structural bonding in vehicle construction is used in the follow-
ing areas:
Joining non-weldable and/or heat-sensitive components and
materials.
Constructioncomponentsthatarehard,orimpossibletoaccess
with welding devices
Joining various metallic and non-metallic substrates with
regard to avoiding galvanic corrosion.
Reducing cycle times and costs by reducing spot-welds
From experience, the use of structural bonding allows the follow-
ing general performance characteristics:
Increasing static stiffness between 8 and 15 %.
Increasing dynamic stiffness by 2-3 Hz
Increasing joint durability by 100 up to 10.000 %
Special impact resistance-modified epoxy structural adhesives –
so-called crash durable adhesives (CDA) – yield additional load
path-optimisation, thus further improving a vehicle’s crash be-
haviour. Unnecessary performance potential can often directly
be used for further reducing weight by downsizing the involved
structures.
In addition to the established epoxy systems, innovative rubber-
based structural adhesives with glass transition temperatures of
over 90° C are becoming increasingly popular due to an attrac-
tive cost-benefit ratio.
●
●
●
●
●
●
●
Figure 1 New weight reduction potential with structural adhesives and structural
foams
K l e b - u n d D i c h t s t o f f e
www.lightweight-design.de
2 . 2 S tr u ct u ral bo n di n g of composit e
mat e rials
When joining composite components mainly two-component
polyurethane adhesives (2K-PU) are used. Polyurethane adhe-
sives are characterized by high strength and stiffness values at
high elongation levels. This results in very positive impact and
fatigue properties of bonded joints.
The use of bonded composite components offers the following
advantages:
Significant weight savings compared to conventional designs
Design and functional integration lead to a reduced number
of components
Lower tooling costs compared to metal pressings and thermo-
plastic welding technologies
High damage tolerance compared to aluminum and steel
materials
Very good corrosion resistance
As shown in Figure 2 composites are frequently used in hoods,
trunk lids, hang on parts and floor applications.
PU-based structural adhesives allow joining these components
in the vehicle assembly. To meet different requirements, numer-
ous adhesive systems are available. Compared with convention-
al joining techniques a number of key aspects must be consid-
ered when selecting a structural adhesive:
Consideration of assembly directions, joining and curing times
●
●
●
●
●
●
Joint geometry and material selection correlates with load
case
Possible required surface preparation
Dissimilar thermal elongation coefficients
Stress/strain limitations
Advanced structural adhesives will help to optimize strength
and elongation levels of bonded composite components and
create new applications for crash-relevant components.
3 T r e n d s w i t h s t r u c t u r a l b o n d i n g o f
n o n c o at e d m e ta l s u b s t r at e s
Over the last ten years, crash durable adhesives (CDAs) have
developed from a regionally applied adhesive technology into
a globally applied solution. They are mainly used for vehicle
structures and hem flanges for closures. Their positive contri-
butions, which have by now become known and acknowl-
edged, have improved several car characteristics, such as
higher stiffness, improved crash performance and enhanced
durability. The CDA technology furthermore enables the devel-
opment of lighter structures and bonding of new materials
such as ultra high-strength steel or composites. Future regula-
tions will not necessarily require the development of new for-
mulations, as today’s products already provide first-rate me-
chanical performance levels. The future will therefore rather be
about developing materials that further improve application
and processing.
●
●
●
●
Figure 2 Potential application areas of bonded hybrid composites
 K l e b - u n d D i c h t s t o f f e
3 . 1 N e w r e q u ir e m e n ts for str u ct u ral
adh e siv e s
Crash durable structural adhesives are globally used in the vehi-
cle body structure. The market demands robust technologies
that must meet the most diverse process requirements as out-
lined below:
Bonding galvanised steels
Today, many different steel grades are used in vehicle construc-
tion and the share of high- and ultra high-strength steels is peak-
ing. The surfaces of those steels are usually galvanised. One dis-
advantage of such coating in combination with higher strength
steels is it’s tendency toward layer delamination under strain.
Crash durable structural adhesives bond those steels very effec-
tively and significantly increase the durability of the joint, when
compared to traditional methods such as spot welding.
Bonding of galvaneal steels
Crash-resistant structural adhesives bond very well to hot-dipped
and electrolytically galvanised coatings. However galvaneal coat-
ings have a layer delamination tendency under strain even for
lower grades of steel. The development of special structural ad-
hesives is therefore necessary.
Optimal temperature resistance
Adhesives are nowadays widely used in different global climate
areas. In many cases they are stored for many months prior to ap-
plication and constant storage conditions cannot be guaranteed.
Independent of these storage conditions and modern application-
critical processes like jet-spraying, the adhesive should under all
circumstances be easily applicable. For this purpose high tem­
perature-stable crash durable adhesives have been developed.
Optimal processability: good adherence, compressibility
and gap filling
Good initial tack is necessary for oily metal substrates. This espe-
cially applies during winter when surfaces can become colder
than 15° C and the drawing oil has a greater viscosity. Good ad-
hesion must also be ensured on the opposite metal surface.
When joining the components, the adhesive must have a good
flow and squeeze behaviour in order to optimally fill gaps.
Components such as doors rarely have constant gap dimensions.
The adhesive must be able to fill the spaces resulting from those
gap variations.
The adhesive’s rheology must be perfectly tuned to the process
requirements.
3 . 2 M od e r n crash d u rabl e e po x y
adh e siv e s for str u ct u ral bo n di n g
In the meantime, new CDAs have been developed meeting all of
the above requirements and being ready for global supply.
Bonding high- and ultra high-strength steels
Compared to previous generation structural adhesives (see Ta-
ble 1), new generation adhesives show greater elongation at
break, reduced bonding strength loss after corrosion, and re-
duced loss of dynamic peel strengths at lower test temperatures
and for higher strength steel grades.
Figure 3a shows the stability of impact peel values of various
steel grades at test temperatures between +23° C and -40° C.
Compared to former generation structural adhesives, the loss in
New generation
crash durable
adhesive
Former
generation
adhesive
E-Modulus [MPa], ca. 1500 1600
Elongation at break [%], ca. 20 13
Table 1 Adhesive nominal values comparison of former and new generation crash-
resistant structural adhesives
Figure 3a Impact peel strength depending on steel grades and test temperatures
Figure 3b Impact peel strength for various test temperatures
K l e b - u n d D i c h t s t o f f e
www.lightweight-design.de
impact peel strength is very low for higher strength steel grades
and at low temperatures. The improved flexibility of the new
generation adhesives is evident in Figure 3b displaying the im-
pact peel strength of bonded steel samples of medium strength
at various temperatures below 0° C. Even at temperatures below
-40° C, the values remain remarkably high. In addition, these ad-
hesives display an excellent corrosion resistance.
Bonding galvaneal coated steels
Bonded galvaneal coatings have a tendency towards delamination
under strain. This tendency is greater for shear loads compared to
peel strains.The new generation crash durable structural adhesives
display a robust cohesive failure mode on galvaneal surfaces with-
out impacting quasi-static shear and dynamic peel strengths.
Table 2 summarises the results of the new generation adhesive
and compares this material to a former generation adhesive. Ad-
hesive characteristics and shear strengths are comparable but
dynamic impact peel strengths have significantly improved.
Temperature-resistant adhesives
The new generation adhesives display excellent temperature re-
sistance up to 60° C. They can therefore be stored and processed
for very long periods of time. The viscosity increase over time is
extremely low and enables a shelf life up to twelve months. Fig-
ure 4 illustrates the viscosity increase over time as a function of
the storage temperature.
Optimised Rheology for optimal adhesion, squeezability
and gap filling
The rheology for new generation crash durable adhesives has
been further optimized to the processing requirements.The new
generation adhesives are shear rate dependent, displaying lower
viscosity at higher shear rates and higher viscosity at lower shear
rates. This has positive effects on the initial tack to oily metal sub-
strates as well as on the adhesive’s pumping characteristics, its
squeezability and gap filling capability. The latter results in good
gap bridging and geometric stability of the adhesive bead.
3 . 3 H i g hly fl e x ibl e e po x y adh e siv e s for
h y brid bo n di n g
Many closures are bonded with low modulus rubber-based
adhesives. These adhesives however show various disadvan-
tages over epoxy adhesive systems. The static and dynamic
strengths are significantly lower than epoxy adhesives and
they are generally less corrosion resistant. The glass transition
temperature is situated within the operating temperature
range of the vehicle.
The generally higher E-modulus of epoxy resin-based structural
adhesives can result in read through effects when bonding ex-
terior panels. A low-modulus adhesive can prevent such issues.
Read through becomes an increasing issue since sheet thick-
nesses have continuously decreased over recent years.
A very flexible epoxy resin adhesive with low modulus has been
developed for this application. It possesses significantly higher
static and dynamic characteristics than rubber-based adhesives.
The dynamic characteristics even match the levels of the crash-
resistant structural adhesives.
The new adhesive technology unites sealing and reinforcing
characteristics in a single product.
Table 3 summarises the characteristics compared to current
structural adhesives.The E-modulus is significantly lower and the
Figure 4 Viscosity increase over time
New generation
crash durable
adhesive
Former
generation
adhesive
E-Modulus [MPa], ca. 400 1600
Elongation at break [%], ca. 40 13
Impact peel strength[N/mm] 48 46
Edge shear strength [MPa] 15.4 19.6
Table 3 Performance comparison between the flexible and a traditional structural
adhesive
New generation
crash durable
adhesive
Former
generation
adhesive
E-Modulus [MPa], ca. 1400 1600
Elongation at break [%], ca. 12 13
Impact peel strength*[N/mm] 32 21
Shear strength [MPa] 23 22
*Impact peel strength SCGA 270, 1 mm; shear strength SCGA 270, 1,6 mm
Table 2 Adhesive characteristics and mechanical characteristics for a galvaneal-
optimised adhesive .
 K l e b - u n d D i c h t s t o f f e
elongation at break clearly better. The values for the mechanical
characteristics are equal or slightly lower. In total, the perfor-
mance level is significantly greater compared to rubber-based
adhesives.
4 T r e n d s i n s t r u c t u r a l b o n d i n g o f
c o m p o s i t e m at e r i a l s a n d c o at e d
m e ta l s u b s t r at e s
4 . 1 D e ma n ds o n bo n di n g s y st e ms for
composit e mat e rials
The motivation factors detailed earlier for reducing vehicle
weight have also resulted in a closer consideration of composite
materials as a lightweight solution for traditional metal applica-
tions. Roofs, hoods, rear lids, and exterior claddings of future hy-
brid and electric vehicles will provide particular growth poten-
tials for the use of composite materials. These applications are
suitable for weight reduction in electric vehicles since such ve-
hicles can be up to 200 to 300 kg heavier due to construction-
and component-related requirements.
In order to insure optimum use of new innovative lightweight
materials, innovative adhesive technologies capable of creating
stable structures and withstanding high static and dynamic loads
under various driving conditions will be necessary. The integra-
tion of composite materials and plastic bonding in vehicle pro-
duction processes requires systems with very short hardening
times. Simultaneously, less temperature-dependant strength and
stiffness behaviours are necessary since the traditionally applied
PU two-component systems possess a glass transition tempera-
ture within the vehicle operating range. High performance struc-
tural bonds will be needed that are able to cope with varying
part tolerances when joining dissimilar materials and with differ-
ing joint geometries.
4 . 2 N e w g e n e ratio n of “ t e mp e rat u r e -
i n d e p e n d e n t ” P U hi g h - p e rforma n c e
adh e siv e s
New primerless adhesives have been developed as a credible
alternative to traditional bonding technologies for composite
materials.These systems allow bonding of various materials such
as SMC or carbon fibre reinforced plastics to coated metal sub-
strates (steel or aluminium). This new generation of adhesive
systems provides developers and design engineers new oppor-
tunities:
Increased stability of modulus and strength values across a
broad temperature range (-45 to +180° C)
A high level of strength and elongation, independent of the
bond thickness
Improved aging performance
Significantly lower bonding times through optimized curing
behaviour – with cycle times of less than 60 seconds.
●
●
●
●
Newly developed polyurethane adhesives provide outstanding
shear strength at high temperatures. The chart in Figure 5 di-
rectly compares a traditional PU adhesive with a newly devel-
oped PU adhesive.
The chart in Figure 6 illustrates the exceptionally high shear
strength of newly developed polyurethane adhesives with simul-
taneous high elongation.
5 Re i n f o r c e m e n t f o a m s f o r b o d y
c a v i t i e s
For several years, vehicle engineers have been able to use rein-
forcement solutions from thermoplastic and thermoset materials
during body development. The structural foams presented here
are two-component polyurethane (PU)-based reinforcement ma-
terials. They are applied directly in body cavities at the produc-
tion line in order to avoid unwanted dents and buckles in certain
areas. Immediately following application, the expanded foams
harden inside the cavity. Depending on the foam system, hard-
ening will be completed after only a few seconds. The foam den-
sities vary in structure-relevant applications, ranging from 200 to
Figure 5 Modulus over temperature for existing and new structural PU Adhesives
Figure 6 Strength and elongation properties of structural PU Adhesives
K l e b - u n d D i c h t s t o f f e
www.lightweight-design.de
600 g/l. Usually, structural foams are applied to surfaces which
are already corrosion-protected, in order to achieve the greatest
possible adhesion between foam and surrounding structure.
Figure 7 illustrates usual application locations of structural foams
at the body shell’s nodal points
PU foams provide the additional advantage of very quick pro-
cessability while allowing the targeted adjustment of the struc-
tural performance of a body platform.Traditional metal reinforce-
ments can often be replaced in a weight- and cost-optimised
manner. Such systems can also quickly and easily be adjusted to
new requirements, such as design changes. A development en-
gineer can directly fine-tune characteristics such as body stiff-
ness, crash performance, and acoustic performance via foam
density and injection volume.
We can summarise the performance characteristics as follows:
Increasing the crash and stiffness levels and/or using this in-
crease toward weight reduction
Advantageous system costs: the costs for a local reinforcement
are mainly driven by the low structural foam material costs.
Designfreedom:Nocost-intensivefoamingtoolsrequiredsince
directly applied to body cavities.
Scalability: A single lean platform allows formation of different
structuralderivatesbyvaryingfoamdensityandinjectionvolume.
Thiswillmeetthetargeteddemandsregardingconfigurationand
other performance requirements.
6 S u m m a r y
Epoxy resin and polyurethane structural adhesives have become
indispensable components of modern car construction. Origi-
nally, such materials served to increase crash performance and
long-term durability. From a current perspective however, light-
weight body construction has become a primary consideration.
This includes also the substrate mix, i.e. the combination of vari-
●
●
●
●
ous metallic and non-metallic materials where structural adhe-
sives are used for many different applications. The continuous
development of bonding systems will ensure that novel sub-
strates can be bonded with optimized safety and durability in the
future as well.
Locally effective structural foams complement the lightweight
construction potential of such adhesives and furthermore pro-
vide substantial advantages with regard to flexible design and
manufacturing of different vehicle variations. Unwanted bending
and buckling behaviour in the vehicle structure can be prevented
in a targeted manner. Load paths can thus be effectively opti-
mised.
Natural resource shortages and environmental protection were
the initially mentioned reasons for the societal and legislative
drive towards lightweight design. The current need for lighter
vehicles is very high and will without doubt increase over the
coming years. Ultimately however, all lightweight construction
measures must be guided by consumer behaviour and the evo-
lution of fuel prices.
Epoxy resin and polyurethane structural adhesives provide wide
ranging benefits of relevance to many key factors of interest to
consumers, apart from weight reduction, (e.g. safety improve-
ment and noise reduction) and will certainly continue to increase
in use and application for future vehicle designs. ●
Figure 7 Structural foam applications to the vehicle body
1 0 K l e b - u n d D i c h t s t o f f e
Application
area
Type Product
name
Product code Chemical
base
Curing Characteristics CAE Model
Body shop,
oily metal
Structural
adhesive
Betamate™ 1496 1 component epoxy E-coat oven Crash stable, vehicle structure validated
Body shop,
oily metal
Structural
adhesive
Betamate™ 1480 1 component epoxy E-coat oven Crash stable, hem flange and
vehicle structure
validated
Body shop,
oily metal
Structural
adhesive
Betamate™ 1620 1 component epoxy E-coat oven Crash stable, vehicle structure,
jet sprayable
Body shop,
oily metal
Structural
adhesive
Betamate™ 1460 1 component epoxy E-coat oven Crash stable, vehicle structure,
wash off resistant
Body shop,
oily metal
Structural
adhesive
Betamate™ 1485 1 component epoxy E-coat oven Crash stable, vehicle structure,
low temperature cure
Body shop,
oily metal
Structural
adhesive
Betamate™ 1820 1 component epoxy E-coat oven Crash stable, vehicle structure,
HSS optimized
available
Body shop,
oily metal
Structural
adhesive
Betamate™ flex 1 component epoxy E-coat oven Crash stable, hem flange,
highly flexible
Body shop,
oily metal
Structural
adhesive
Betamate™ 1025 1 component epoxy E-coat oven Semi-crash stable, hem flange,
low viscosity
validated
Body shop,
oily metal
Structural
adhesive
Betamate™ 1040 1 component epoxy E-coat oven Semi-crash stable, vehicle structure,
high viscosity
validated
Body shop,
oily metal
Structural
adhesive
Betamate™ 1060 1 component epoxy E-coat oven Semi-crash stable, vehicle structure,
wash off resistant
available
Body shop,
oily metal
Structural
adhesive
Betamate™ 5103-2 1 component epoxy E-coat oven Structural applications, cold
applicable
Body shop,
oily metal
Structural
adhesive
Betamate™ 1005 1 component epoxy E-coat oven Structural hem flange applications
Body shop,
oily metal
Structural
adhesive
Betamate™ 5096 1 component rubber E-coat oven Semi-crash stable, vehicle structure
Body shop,
oily metal
Structural
adhesive
Betamate™ 2096 2 component epoxy ambient Semi-crash stable, vehicle structure,
repair
Body shop,
oily metal
Structural
adhesive
Betamate™ 2098 2 component epoxy ambient Crash stable, vehicle structure,
repair
Body shop,
oily metal
Structural
adhesive
Betamate™ 2092 2 component epoxy ambient Semi-crash stable, vehicle structure,
repair, fast cure
Body shop,
oily metal
Structural
adhesive
Betamate™ 2080 2 component epoxy elevated
(120ºC)
Semi-crash stable, vehicle structure
Paint shop,
before wax
Structural
foam
Betafoam™ 89100/89124 2 component PU ambient Increased crash performance, 400
g/cm³
validated
Paint shop,
before wax
Structural
foam
Betafoam™ 89100/89112 2 component PU ambient Increased crash performance, 200
g/cm³
available
Trim shop Structural
adhesive
Betamate™ 2810 2 component PU ambient Semi Structural, trunk lids, fast cure
Trim shop Structural
adhesive
Betamate™ 2850 2 component PU ambient Semi Structural, roof, trunk lid,
repair
Trim shop Structural
adhesive
Betamate™ 2850 S 2 component PU ambient Semi Structural, roof, trunk lid, fast
cure
Trim shop Structural
adhesive
Betamate™ 9050 2 component PU ambient Structural, primerless on
composites and paint, repair
Trim shop Structural
adhesive
Betamate™ 9050 S 2 component PU ambient Structural, primerless on
composites and paint, fast cure
A pp e n di x
The use of structural adhesives and structural foams in flanges and cavities
can be seen as an extension of existing technologies. Available material cards
for simulation tools help to virtually validate these technologies for different
load cases and design studies. Without describing the principles of numeric
simulation using the Finite Element Method (FEM) in detail, the mathematical
description of the thermo-mechanical material behaviour represents a pivo-
tal role when representing structural components including bonding and
coupling behaviour in a certain load scenarios. A short overview about com-
mon structural adhesives and foams out of the Betamate and Betafoam port-
folio is shown in table 4.
Table 4 Material overview (selection) of BETAMATE™ structural adhesives and BETAFOAM™ structural foams.
P rod u ct O v e rvi e w
K l e b - u n d D i c h t s t o f f e 1 1
www. dowautomotive.com
Dow Automotive Systems | Am Kronberger Hang 4 | 65824 Schwalbach | Germany
Telephone: +49-6196-566-0 | Fax: +49-6196-566-444 | Toll Free: 00800 3 694 6367*
In Finland: 990 3 694 6367 | In Italy: 800 783 825
*Toll free from Austria, Belgium, Denmark, France, Germany, Hungary, Ireland, The Netherlands, Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom.
Dow Automotive Systems | 1250 Harmon Road | Auburn Hills, MI 48362 | Phone: +1-248-391-6300
Fax: +1-248-391-6417 | E-mail: dowautomotive@dow.com
NOTICE: No freedom from any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and
may change over time, the Customer is responsible for determining whether products and the information in this document are appropriate for the Customer’s use and for
ensuring that the Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Dow assumes no obligations
or liability for the information in this document. No warranties are given.
™Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow

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Structural Bonding of Lightweight Cars, Dow Automotive Antala Ltd.(uk)

  • 1. Structural Bonding of Lightweight Cars Crash durable, safe and economical
  • 2. „Without the use of bonding technology, modern lightweight designs would hardly be feasible – especially when it comes to bonding dissimilar and/or new materials.“ Dr. Andreas Groß, Advanced Training and Technology Transfer, Fraunhofer IFAM Publisher: Dow Automotive Systems | Am Kronberger Hang 4 | D-65824 Schwalbach | www.dowautomotive.com Project management: MS&L | Otto-Meßmer-Strasse 1 | D-60314 Frankfurt on the Main Project coordinator: BestCom Media | Springer Fachmedien Wiesbaden GmbH | Abraham-Lincoln-Straße 46 | D-65189 Wiesbaden Responsible for the content: Marc van den Biggelaar | Dow Automotive Systems Printing and Processing: Printing company Klimo | Eupen/Belgium | Printed on acid-free and low-chlorine bleached paper | Printed in Belgium.
  • 3. E d i t o r i a l BondingTechnology Meets Lightweight Construction Dear Readers, The automotive industry has in recent years successfully at- tempted to build lighter vehicles with more fuel-efficient engines in order to significantly reduce fleet consumption in accordance with legal requirements. Significantly lower fuel consumption and CO2 emissions have been the immediate pay-off of such de- velopments. Improved fuel consumption, environmental friendliness, driving comfort, and safety therefore feature among the sales argu- ments many car manufacturers now employ for their marketing strategies. Automotive suppliers and material manufacturers support car makers in developing modern lightweight designs and respond to questions concerning the potentials of current technologies and materials to satisfy challenging future requirements. In this context, industry experts assume that steel will remain the primary material for vehicle structures. However, new high strength steel grades are finding their way into vehicle structures. Metals with low density such as aluminium and even magnesium are increasing in demand – as are polymer materials such as fi- bre-reinforced composites. Fuelled by the importance of those very diverse materials, ques- tions regarding bonding technology enter centre stage of the discussion. This is the key interface between lightweight con- struction and bonding technologies for new vehicle designs. Modern lightweight designs require new bonding technologies in addition to new materials and/or an increased material mix. Bonding is of special importance here. It enables the use of new materials, new material combinations and it provides structural advantages for bonded components. Please review the following technical summary to learn more about the status quo of existing concepts as well as new poten- tial development in adhesives and foams for use in modern light weight vehicle construction. I wish you a fascinating read and successful bonding! Dr. Andreas Lutz Head Developer“Metal Bonding Europe“ Dow Automotive, Horgen, Switzerland K l e b - u n d D i c h t s t o f f e
  • 4. www.lightweight-design.de 1 I n n o v at i v e L i g h t w e i g h t De s i g n s i n Ve h i c l e De v e l o p m e n t 1 . 1 W e i g ht r e d u ctio n for m e e ti n g f u t u r e l e g al sta n dards Two main factors drive vehicle weight reduction. In addition to the future maximum values for CO2 emissions as expressed in the EU Directive 443/2009, an increasing number of countries are planning road usage fees based on such emissions. Both fac- tors in combination with increased fuel prices result in a strong motivation to purchase low emission vehicles. Fuel consumption can be lowered by a number of different methods. Lightweight vehicle construction is a significant factor throughout, immediately contributing to reducing fuel con- sumption. Savings by downgauging vehicle components such as powertrain, engine, and underbody yield further secondary effects. Various studies show that a 100 kg weight reduction re- sults in reduced emissions of 5.0 to 12.5 g of CO2 (ca. 3 to 7 %) per driven kilometre. Representing approximately 40 % of total vehicle weight, the car body is the heaviest vehicle element. The consequent imple- mentation of lightweight measures in the car body appears therefore very effective. Increasing demands regarding stiffness, acoustics, crash performance and long-term stability are gener- ally in conflict with lightweight construction and underline the complexity of this challenge. 1 . 2 C u rr e n t tr e n ds for r e d u ci n g v e hicl e w e i g ht Several methods for weight reduction are available. The three most important approaches are: 1. Use of low-density materials Aluminium, magnesium and plastics/thermoset composites are often used in mounted parts and covers. According to a state- ment by the Aluminum Association Inc., aluminium contributed to an average of 7.8 % of the total weight for passenger vehicles in the year 2009. 2. Targeted use of high-strength materials High- and highest-strength steels are solutions for wall thickness- reduced components. Tailored welded or tailored rolled-blanks are related technologies that make use of this principle. 3. Integrated lightweight construction This is a combination of various materials and functional charac- teristics based on the use of bonding technologies and produc- tion processes. The most significant lightweight construction trend over recent years is the use of high-strength steels (HSS). Even vehicle bodies of the European compact car class now contain a HSS share of 50 to 65 %. Without exception, the safety cells of today’s cars consist mainly of HSS. Tailored welded or tailored rolled blank technolo- gies are consequently used for further optimisation. Another significant trend is the use of thermoplastics and ther- moset composites in bonded roof components, hoods, trunk Structural adhesives The key to making lightweight cars Modern lightweight designs require new bonding technologies in addition to new materials and/or an increased material mix. Bonding is of special importance here. It enables the use of new materials, new material combinations and it provides structural advantages for bonded components. K l e b - u n d D i c h t s t o f f e
  • 5. covers and some body structure components. As the article will describe in further detail, bonding technology could also solve the challenge of joining various metallic and non-metallic ma- terials. 1 . 3 T h e path toward a bala n c e d car bod y As mentioned above, reducing the body weight, while simulta- neously increasing performance, is a complex task.The following elements are key demands when developing innovative solu- tions: Increasing the static and dynamic stiffness to improve the general vehicle quality and to optimize driving and handling characteristics. Reducing vibrations and noise (noise, vibration, harshness and acoustics). Optimising crash behaviour to comply with legal and volun- tary safety guidelines (EG: NCAP safety testing) Extending vehicle lifespan and long term value via higher quality and retained driving characteristics. Improvements in those four areas are by no means the only chal- lenges when reducing vehicle weight. A new vehicle generation often requires the development of greater passenger space. Con- sequently, new vehicle models are rarely lighter than their prede- cessors. 1 . 4 P ot e n tials a n d limits of c u rr e n t t e ch n olo g y tr e n ds Five years ago, mild steel contributed between 40 and 50 % of the body shell weight. Today, new vehicles generally contain a mild steel share not exceeding 20 to 25 %. Further materials in- clude mostly high-strength steels and, increasingly, aluminium. Using high- and ultra high- strength steels allowed wall thick- nesses reduction up to 0.5 mm. It is however unlikely that such steel grades can further increase the structural optimisation po- tential. 1. 2. 3. 4. Particular weight reduction measures such as tailored welded or tailored rolled blanks have in the meantime also become a standard in compact cars. When considering the strongly rising aluminium share on top of that, it becomes clear that addi- tional new technologies will be required to further reduce weight. 2 S tat u s q u o o f s t r u c t u r a l b o n d i n g i n t h e v e h i c l e b o d y Structural adhesives and structural foams (see chapter 5) are polymer solutions offering a great potential for body weight re- ductions: Figure 1. Such technology concepts allow for additional performance im- provements even in already-optimised body structures. These methods will be explained in more detail below. 2 . 1 S tr u ct u ral bo n di n g of u n coat e d m e tal s u bstrat e s Structural bonding signifies permanent and stable bonding increasing the overall efficiency and effectiveness of a conven- tionally joined structure. For current automotive metal bonding applications more than 95 % is based on epoxy adhesives. This is due to the combination of various advantageous character- istics such as oil absorption capacity, durability, and outstand- ing mechanical characteristics across a wide temperature range. Structural bonding in vehicle construction is used in the follow- ing areas: Joining non-weldable and/or heat-sensitive components and materials. Constructioncomponentsthatarehard,orimpossibletoaccess with welding devices Joining various metallic and non-metallic substrates with regard to avoiding galvanic corrosion. Reducing cycle times and costs by reducing spot-welds From experience, the use of structural bonding allows the follow- ing general performance characteristics: Increasing static stiffness between 8 and 15 %. Increasing dynamic stiffness by 2-3 Hz Increasing joint durability by 100 up to 10.000 % Special impact resistance-modified epoxy structural adhesives – so-called crash durable adhesives (CDA) – yield additional load path-optimisation, thus further improving a vehicle’s crash be- haviour. Unnecessary performance potential can often directly be used for further reducing weight by downsizing the involved structures. In addition to the established epoxy systems, innovative rubber- based structural adhesives with glass transition temperatures of over 90° C are becoming increasingly popular due to an attrac- tive cost-benefit ratio. ● ● ● ● ● ● ● Figure 1 New weight reduction potential with structural adhesives and structural foams K l e b - u n d D i c h t s t o f f e
  • 6. www.lightweight-design.de 2 . 2 S tr u ct u ral bo n di n g of composit e mat e rials When joining composite components mainly two-component polyurethane adhesives (2K-PU) are used. Polyurethane adhe- sives are characterized by high strength and stiffness values at high elongation levels. This results in very positive impact and fatigue properties of bonded joints. The use of bonded composite components offers the following advantages: Significant weight savings compared to conventional designs Design and functional integration lead to a reduced number of components Lower tooling costs compared to metal pressings and thermo- plastic welding technologies High damage tolerance compared to aluminum and steel materials Very good corrosion resistance As shown in Figure 2 composites are frequently used in hoods, trunk lids, hang on parts and floor applications. PU-based structural adhesives allow joining these components in the vehicle assembly. To meet different requirements, numer- ous adhesive systems are available. Compared with convention- al joining techniques a number of key aspects must be consid- ered when selecting a structural adhesive: Consideration of assembly directions, joining and curing times ● ● ● ● ● ● Joint geometry and material selection correlates with load case Possible required surface preparation Dissimilar thermal elongation coefficients Stress/strain limitations Advanced structural adhesives will help to optimize strength and elongation levels of bonded composite components and create new applications for crash-relevant components. 3 T r e n d s w i t h s t r u c t u r a l b o n d i n g o f n o n c o at e d m e ta l s u b s t r at e s Over the last ten years, crash durable adhesives (CDAs) have developed from a regionally applied adhesive technology into a globally applied solution. They are mainly used for vehicle structures and hem flanges for closures. Their positive contri- butions, which have by now become known and acknowl- edged, have improved several car characteristics, such as higher stiffness, improved crash performance and enhanced durability. The CDA technology furthermore enables the devel- opment of lighter structures and bonding of new materials such as ultra high-strength steel or composites. Future regula- tions will not necessarily require the development of new for- mulations, as today’s products already provide first-rate me- chanical performance levels. The future will therefore rather be about developing materials that further improve application and processing. ● ● ● ● Figure 2 Potential application areas of bonded hybrid composites K l e b - u n d D i c h t s t o f f e
  • 7. 3 . 1 N e w r e q u ir e m e n ts for str u ct u ral adh e siv e s Crash durable structural adhesives are globally used in the vehi- cle body structure. The market demands robust technologies that must meet the most diverse process requirements as out- lined below: Bonding galvanised steels Today, many different steel grades are used in vehicle construc- tion and the share of high- and ultra high-strength steels is peak- ing. The surfaces of those steels are usually galvanised. One dis- advantage of such coating in combination with higher strength steels is it’s tendency toward layer delamination under strain. Crash durable structural adhesives bond those steels very effec- tively and significantly increase the durability of the joint, when compared to traditional methods such as spot welding. Bonding of galvaneal steels Crash-resistant structural adhesives bond very well to hot-dipped and electrolytically galvanised coatings. However galvaneal coat- ings have a layer delamination tendency under strain even for lower grades of steel. The development of special structural ad- hesives is therefore necessary. Optimal temperature resistance Adhesives are nowadays widely used in different global climate areas. In many cases they are stored for many months prior to ap- plication and constant storage conditions cannot be guaranteed. Independent of these storage conditions and modern application- critical processes like jet-spraying, the adhesive should under all circumstances be easily applicable. For this purpose high tem­ perature-stable crash durable adhesives have been developed. Optimal processability: good adherence, compressibility and gap filling Good initial tack is necessary for oily metal substrates. This espe- cially applies during winter when surfaces can become colder than 15° C and the drawing oil has a greater viscosity. Good ad- hesion must also be ensured on the opposite metal surface. When joining the components, the adhesive must have a good flow and squeeze behaviour in order to optimally fill gaps. Components such as doors rarely have constant gap dimensions. The adhesive must be able to fill the spaces resulting from those gap variations. The adhesive’s rheology must be perfectly tuned to the process requirements. 3 . 2 M od e r n crash d u rabl e e po x y adh e siv e s for str u ct u ral bo n di n g In the meantime, new CDAs have been developed meeting all of the above requirements and being ready for global supply. Bonding high- and ultra high-strength steels Compared to previous generation structural adhesives (see Ta- ble 1), new generation adhesives show greater elongation at break, reduced bonding strength loss after corrosion, and re- duced loss of dynamic peel strengths at lower test temperatures and for higher strength steel grades. Figure 3a shows the stability of impact peel values of various steel grades at test temperatures between +23° C and -40° C. Compared to former generation structural adhesives, the loss in New generation crash durable adhesive Former generation adhesive E-Modulus [MPa], ca. 1500 1600 Elongation at break [%], ca. 20 13 Table 1 Adhesive nominal values comparison of former and new generation crash- resistant structural adhesives Figure 3a Impact peel strength depending on steel grades and test temperatures Figure 3b Impact peel strength for various test temperatures K l e b - u n d D i c h t s t o f f e
  • 8. www.lightweight-design.de impact peel strength is very low for higher strength steel grades and at low temperatures. The improved flexibility of the new generation adhesives is evident in Figure 3b displaying the im- pact peel strength of bonded steel samples of medium strength at various temperatures below 0° C. Even at temperatures below -40° C, the values remain remarkably high. In addition, these ad- hesives display an excellent corrosion resistance. Bonding galvaneal coated steels Bonded galvaneal coatings have a tendency towards delamination under strain. This tendency is greater for shear loads compared to peel strains.The new generation crash durable structural adhesives display a robust cohesive failure mode on galvaneal surfaces with- out impacting quasi-static shear and dynamic peel strengths. Table 2 summarises the results of the new generation adhesive and compares this material to a former generation adhesive. Ad- hesive characteristics and shear strengths are comparable but dynamic impact peel strengths have significantly improved. Temperature-resistant adhesives The new generation adhesives display excellent temperature re- sistance up to 60° C. They can therefore be stored and processed for very long periods of time. The viscosity increase over time is extremely low and enables a shelf life up to twelve months. Fig- ure 4 illustrates the viscosity increase over time as a function of the storage temperature. Optimised Rheology for optimal adhesion, squeezability and gap filling The rheology for new generation crash durable adhesives has been further optimized to the processing requirements.The new generation adhesives are shear rate dependent, displaying lower viscosity at higher shear rates and higher viscosity at lower shear rates. This has positive effects on the initial tack to oily metal sub- strates as well as on the adhesive’s pumping characteristics, its squeezability and gap filling capability. The latter results in good gap bridging and geometric stability of the adhesive bead. 3 . 3 H i g hly fl e x ibl e e po x y adh e siv e s for h y brid bo n di n g Many closures are bonded with low modulus rubber-based adhesives. These adhesives however show various disadvan- tages over epoxy adhesive systems. The static and dynamic strengths are significantly lower than epoxy adhesives and they are generally less corrosion resistant. The glass transition temperature is situated within the operating temperature range of the vehicle. The generally higher E-modulus of epoxy resin-based structural adhesives can result in read through effects when bonding ex- terior panels. A low-modulus adhesive can prevent such issues. Read through becomes an increasing issue since sheet thick- nesses have continuously decreased over recent years. A very flexible epoxy resin adhesive with low modulus has been developed for this application. It possesses significantly higher static and dynamic characteristics than rubber-based adhesives. The dynamic characteristics even match the levels of the crash- resistant structural adhesives. The new adhesive technology unites sealing and reinforcing characteristics in a single product. Table 3 summarises the characteristics compared to current structural adhesives.The E-modulus is significantly lower and the Figure 4 Viscosity increase over time New generation crash durable adhesive Former generation adhesive E-Modulus [MPa], ca. 400 1600 Elongation at break [%], ca. 40 13 Impact peel strength[N/mm] 48 46 Edge shear strength [MPa] 15.4 19.6 Table 3 Performance comparison between the flexible and a traditional structural adhesive New generation crash durable adhesive Former generation adhesive E-Modulus [MPa], ca. 1400 1600 Elongation at break [%], ca. 12 13 Impact peel strength*[N/mm] 32 21 Shear strength [MPa] 23 22 *Impact peel strength SCGA 270, 1 mm; shear strength SCGA 270, 1,6 mm Table 2 Adhesive characteristics and mechanical characteristics for a galvaneal- optimised adhesive . K l e b - u n d D i c h t s t o f f e
  • 9. elongation at break clearly better. The values for the mechanical characteristics are equal or slightly lower. In total, the perfor- mance level is significantly greater compared to rubber-based adhesives. 4 T r e n d s i n s t r u c t u r a l b o n d i n g o f c o m p o s i t e m at e r i a l s a n d c o at e d m e ta l s u b s t r at e s 4 . 1 D e ma n ds o n bo n di n g s y st e ms for composit e mat e rials The motivation factors detailed earlier for reducing vehicle weight have also resulted in a closer consideration of composite materials as a lightweight solution for traditional metal applica- tions. Roofs, hoods, rear lids, and exterior claddings of future hy- brid and electric vehicles will provide particular growth poten- tials for the use of composite materials. These applications are suitable for weight reduction in electric vehicles since such ve- hicles can be up to 200 to 300 kg heavier due to construction- and component-related requirements. In order to insure optimum use of new innovative lightweight materials, innovative adhesive technologies capable of creating stable structures and withstanding high static and dynamic loads under various driving conditions will be necessary. The integra- tion of composite materials and plastic bonding in vehicle pro- duction processes requires systems with very short hardening times. Simultaneously, less temperature-dependant strength and stiffness behaviours are necessary since the traditionally applied PU two-component systems possess a glass transition tempera- ture within the vehicle operating range. High performance struc- tural bonds will be needed that are able to cope with varying part tolerances when joining dissimilar materials and with differ- ing joint geometries. 4 . 2 N e w g e n e ratio n of “ t e mp e rat u r e - i n d e p e n d e n t ” P U hi g h - p e rforma n c e adh e siv e s New primerless adhesives have been developed as a credible alternative to traditional bonding technologies for composite materials.These systems allow bonding of various materials such as SMC or carbon fibre reinforced plastics to coated metal sub- strates (steel or aluminium). This new generation of adhesive systems provides developers and design engineers new oppor- tunities: Increased stability of modulus and strength values across a broad temperature range (-45 to +180° C) A high level of strength and elongation, independent of the bond thickness Improved aging performance Significantly lower bonding times through optimized curing behaviour – with cycle times of less than 60 seconds. ● ● ● ● Newly developed polyurethane adhesives provide outstanding shear strength at high temperatures. The chart in Figure 5 di- rectly compares a traditional PU adhesive with a newly devel- oped PU adhesive. The chart in Figure 6 illustrates the exceptionally high shear strength of newly developed polyurethane adhesives with simul- taneous high elongation. 5 Re i n f o r c e m e n t f o a m s f o r b o d y c a v i t i e s For several years, vehicle engineers have been able to use rein- forcement solutions from thermoplastic and thermoset materials during body development. The structural foams presented here are two-component polyurethane (PU)-based reinforcement ma- terials. They are applied directly in body cavities at the produc- tion line in order to avoid unwanted dents and buckles in certain areas. Immediately following application, the expanded foams harden inside the cavity. Depending on the foam system, hard- ening will be completed after only a few seconds. The foam den- sities vary in structure-relevant applications, ranging from 200 to Figure 5 Modulus over temperature for existing and new structural PU Adhesives Figure 6 Strength and elongation properties of structural PU Adhesives K l e b - u n d D i c h t s t o f f e
  • 10. www.lightweight-design.de 600 g/l. Usually, structural foams are applied to surfaces which are already corrosion-protected, in order to achieve the greatest possible adhesion between foam and surrounding structure. Figure 7 illustrates usual application locations of structural foams at the body shell’s nodal points PU foams provide the additional advantage of very quick pro- cessability while allowing the targeted adjustment of the struc- tural performance of a body platform.Traditional metal reinforce- ments can often be replaced in a weight- and cost-optimised manner. Such systems can also quickly and easily be adjusted to new requirements, such as design changes. A development en- gineer can directly fine-tune characteristics such as body stiff- ness, crash performance, and acoustic performance via foam density and injection volume. We can summarise the performance characteristics as follows: Increasing the crash and stiffness levels and/or using this in- crease toward weight reduction Advantageous system costs: the costs for a local reinforcement are mainly driven by the low structural foam material costs. Designfreedom:Nocost-intensivefoamingtoolsrequiredsince directly applied to body cavities. Scalability: A single lean platform allows formation of different structuralderivatesbyvaryingfoamdensityandinjectionvolume. Thiswillmeetthetargeteddemandsregardingconfigurationand other performance requirements. 6 S u m m a r y Epoxy resin and polyurethane structural adhesives have become indispensable components of modern car construction. Origi- nally, such materials served to increase crash performance and long-term durability. From a current perspective however, light- weight body construction has become a primary consideration. This includes also the substrate mix, i.e. the combination of vari- ● ● ● ● ous metallic and non-metallic materials where structural adhe- sives are used for many different applications. The continuous development of bonding systems will ensure that novel sub- strates can be bonded with optimized safety and durability in the future as well. Locally effective structural foams complement the lightweight construction potential of such adhesives and furthermore pro- vide substantial advantages with regard to flexible design and manufacturing of different vehicle variations. Unwanted bending and buckling behaviour in the vehicle structure can be prevented in a targeted manner. Load paths can thus be effectively opti- mised. Natural resource shortages and environmental protection were the initially mentioned reasons for the societal and legislative drive towards lightweight design. The current need for lighter vehicles is very high and will without doubt increase over the coming years. Ultimately however, all lightweight construction measures must be guided by consumer behaviour and the evo- lution of fuel prices. Epoxy resin and polyurethane structural adhesives provide wide ranging benefits of relevance to many key factors of interest to consumers, apart from weight reduction, (e.g. safety improve- ment and noise reduction) and will certainly continue to increase in use and application for future vehicle designs. ● Figure 7 Structural foam applications to the vehicle body 1 0 K l e b - u n d D i c h t s t o f f e
  • 11. Application area Type Product name Product code Chemical base Curing Characteristics CAE Model Body shop, oily metal Structural adhesive Betamate™ 1496 1 component epoxy E-coat oven Crash stable, vehicle structure validated Body shop, oily metal Structural adhesive Betamate™ 1480 1 component epoxy E-coat oven Crash stable, hem flange and vehicle structure validated Body shop, oily metal Structural adhesive Betamate™ 1620 1 component epoxy E-coat oven Crash stable, vehicle structure, jet sprayable Body shop, oily metal Structural adhesive Betamate™ 1460 1 component epoxy E-coat oven Crash stable, vehicle structure, wash off resistant Body shop, oily metal Structural adhesive Betamate™ 1485 1 component epoxy E-coat oven Crash stable, vehicle structure, low temperature cure Body shop, oily metal Structural adhesive Betamate™ 1820 1 component epoxy E-coat oven Crash stable, vehicle structure, HSS optimized available Body shop, oily metal Structural adhesive Betamate™ flex 1 component epoxy E-coat oven Crash stable, hem flange, highly flexible Body shop, oily metal Structural adhesive Betamate™ 1025 1 component epoxy E-coat oven Semi-crash stable, hem flange, low viscosity validated Body shop, oily metal Structural adhesive Betamate™ 1040 1 component epoxy E-coat oven Semi-crash stable, vehicle structure, high viscosity validated Body shop, oily metal Structural adhesive Betamate™ 1060 1 component epoxy E-coat oven Semi-crash stable, vehicle structure, wash off resistant available Body shop, oily metal Structural adhesive Betamate™ 5103-2 1 component epoxy E-coat oven Structural applications, cold applicable Body shop, oily metal Structural adhesive Betamate™ 1005 1 component epoxy E-coat oven Structural hem flange applications Body shop, oily metal Structural adhesive Betamate™ 5096 1 component rubber E-coat oven Semi-crash stable, vehicle structure Body shop, oily metal Structural adhesive Betamate™ 2096 2 component epoxy ambient Semi-crash stable, vehicle structure, repair Body shop, oily metal Structural adhesive Betamate™ 2098 2 component epoxy ambient Crash stable, vehicle structure, repair Body shop, oily metal Structural adhesive Betamate™ 2092 2 component epoxy ambient Semi-crash stable, vehicle structure, repair, fast cure Body shop, oily metal Structural adhesive Betamate™ 2080 2 component epoxy elevated (120ºC) Semi-crash stable, vehicle structure Paint shop, before wax Structural foam Betafoam™ 89100/89124 2 component PU ambient Increased crash performance, 400 g/cm³ validated Paint shop, before wax Structural foam Betafoam™ 89100/89112 2 component PU ambient Increased crash performance, 200 g/cm³ available Trim shop Structural adhesive Betamate™ 2810 2 component PU ambient Semi Structural, trunk lids, fast cure Trim shop Structural adhesive Betamate™ 2850 2 component PU ambient Semi Structural, roof, trunk lid, repair Trim shop Structural adhesive Betamate™ 2850 S 2 component PU ambient Semi Structural, roof, trunk lid, fast cure Trim shop Structural adhesive Betamate™ 9050 2 component PU ambient Structural, primerless on composites and paint, repair Trim shop Structural adhesive Betamate™ 9050 S 2 component PU ambient Structural, primerless on composites and paint, fast cure A pp e n di x The use of structural adhesives and structural foams in flanges and cavities can be seen as an extension of existing technologies. Available material cards for simulation tools help to virtually validate these technologies for different load cases and design studies. Without describing the principles of numeric simulation using the Finite Element Method (FEM) in detail, the mathematical description of the thermo-mechanical material behaviour represents a pivo- tal role when representing structural components including bonding and coupling behaviour in a certain load scenarios. A short overview about com- mon structural adhesives and foams out of the Betamate and Betafoam port- folio is shown in table 4. Table 4 Material overview (selection) of BETAMATE™ structural adhesives and BETAFOAM™ structural foams. P rod u ct O v e rvi e w K l e b - u n d D i c h t s t o f f e 1 1
  • 12. www. dowautomotive.com Dow Automotive Systems | Am Kronberger Hang 4 | 65824 Schwalbach | Germany Telephone: +49-6196-566-0 | Fax: +49-6196-566-444 | Toll Free: 00800 3 694 6367* In Finland: 990 3 694 6367 | In Italy: 800 783 825 *Toll free from Austria, Belgium, Denmark, France, Germany, Hungary, Ireland, The Netherlands, Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom. Dow Automotive Systems | 1250 Harmon Road | Auburn Hills, MI 48362 | Phone: +1-248-391-6300 Fax: +1-248-391-6417 | E-mail: dowautomotive@dow.com NOTICE: No freedom from any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change over time, the Customer is responsible for determining whether products and the information in this document are appropriate for the Customer’s use and for ensuring that the Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Dow assumes no obligations or liability for the information in this document. No warranties are given. ™Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow