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Dipartimento di Ingegneria chimica,
      Chimica industriale e Scienza dei materiali




               Prof. Sandra Vitolo




Bologna, September 20th 2011
Evaluation of Environmental Impact of Leather
Process Using LCA Methodology


                                  Outline
                                          Basic concepts
                                          Environmental labelling
                                          LCA analysis steps
                                          Case study



                 Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Basic concepts
    According to ISO 14040, the Life Cycle Assessment is a
quantitative approach to evaluate the environmental burdens
associated with a product/process over its entire life cycle by:

 Compiling an inventory of relevant inputs
 and outputs of a product system
 Evaluating the potential environmental
 impacts associated with those inputs and
 outputs
 Interpreting the results of the inventory
 analysis and impact assessment phases in
 relation to the objectives of the study




                             Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Basic concepts
The basic concept is that the impact an item has on the environment does
not depend exclusively on the manufacturing process, but begins with the
design and ends with the final disposal.




        Raw material         Manufacture                  Use                    Waste
         acquisition                                                           management


 • LCA calculates energy and resource use, emissions, environment and health
   impacts
 • LCA covers the entire life cycle, from ”cradle‐to‐grave”

                            Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Basic concepts
LCAs started in the early 1970s, initially to investigate the energy
requirements for different processes; emissions and raw materials
were added later
LCAs are considered to be the most comprehensive approach to
assessing environmental impact
Initially, numerous variants of LCA “methods” were
developed/investigated, but today there is consensus that there is
only one basic method with a large number of variants
The Society of Environmental Toxicology and Chemistry (SETAC),
an international platform for toxicologists, published a Code of
Practice, a widely accepted series of guidelines and definitions.
Nowadays, IS0 14040:2006 and 14044:2006 are considered to be
the LCA standard.

                       Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA applications
            Product/process design, development, improvement
                                     Public policy
                                      Marketing
                                    Eco‐labelling


LCAs have been used increasingly by industry to help reduce the overall environmental
burdens across the whole life cycle of goods and services
LCA is also used to improve the competitiveness of the company’s products and in
communication with governmental bodies
LCA is used in decision making as a tool to improve product design, for example the
choice of materials, the selection of technologies, specific design criteria and when
considering recycling
LCA allows benchmarking of product system options and can therefore also be used in
decision making of purchasing and technology investments, innovation systems, etc



                              Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA applications
LCA is one of the tools to apply life cycle thinking in the implementation of the EU’s thematic
strategy on the sustainable use of natural resources and the thematic strategy on prevention
and recycling of waste

In its Communication on Integrated Product Policy (COM (2003)302), the European
Commission concluded that Life Cycle Assessments provide the best framework for
   assessing the potential environmental impacts of products currently available.

                         Integrated Product Policy (IPP)
    seeks to minimise the environmental degradation that a product causes in
    some way, by looking at all phases of a products' life‐cycle (manufacturing,
            use, disposal) and taking action where it is most effective

                                                                                    ques
                            Ecode                                       able techni
                                 si n g                    Bes   t avail
    Integrated Pro                         Life Cycle                         curement
                  du   ct Policy (IPP)                       Green public pro
                                           Thinking
      Integrated waste management                         Environmental labelling


                                  Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Environmental labelling
        The International Standards Organisation (ISO) have
       developed standards for three types of environmental
            product claims, termed ISO Type I, II and III.

• Type I (ISO 14024): claims are based on criteria set by a third party and are
  multiissue, being based on the product’s life cycle impacts. The awarding
  body may be either a governmental organisation or a private non‐
  commercial entity.




        Ecolabel            Nordic White Swan                  German Blue Angel

                           Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Environmental labelling
• Type II (ISO 14021): claims are based on self‐declarations by manufacturers or
  retailers. There are numerous examples of such claims e.g. ‘made from x%
  recycled material’




        Mobius loop

• Type III (ISO 14025): claims consist of quantified product information based on
  life cycle impacts. These impacts are presented in a form that facilitates
  comparison between products e.g. a set of parameters.

                                                Environmental
                                                Product
                                                Declaration

                             Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Environmental labelling                                       Life Cycle Assessment
                                                                 (LCA)
                                                                 The tool for assessing the
                                                              potential environmental impacts
   Product Category Rules
   (PCR)
 The Product Category Rules (PCRs)
     are vital for the concept of
   environmental declarations and
        climate declarations.
The PCRs enable transparency for the
     EPD‐development and also
  comparability between differents
    EPDs based on the same PCR.




                             Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Environmental labelling
            EPD Programme Development




               Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Environmental labelling
            EPD Programme Development


                                    Finished bovine leather
                                    UN CPC product class 2912
                                    “Other leather, of bovine or equine
                                    animals, without hair on”

                                    The PCR document is a living
                                    document. If relevant changes in the
                                    LCA methodology or in the
                                    technology for the product category
                                    occur, the document will be revised
                                    and any changes will be published on
                                    the international website
                                    www.environdec.com


               Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
    LCA Steps: defined in ISO 14040 series


                                            I. Goal & Scope Definition
                                                 ‘the reason why LCA is performed’
•
                                            II. Inventory Analysis (LCI)
                                                 ‘quantification of environmental loads’
                                            III. Impact Assessment (LCIA)
                                                 ‘assess the relevance of flows’
                                            IV. Interpretation
                                                 ‘interpretation and results analysis’




                         Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Inventory: draw flow chart of product system, build the system
model




                      Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Inventory: draw flow chart of product system, build the
system model
  Collect data of resource use and emissions of all processes
  Data sources: LCA databases, reports, scientific papers, on‐site
  investigation, expert knowledge, qualified guesses
  Calculate resource use and emissions of studied product.
  Present results in charts and tables.
  Iterative procedure!




                      Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Impact analysis
Classification: each chemical listed in the Inventory is assigned to one or more
   impact categories

                               Human Health
                                Ozone Layer
                              Global Warming
                              Non renewable
                                Resources
           Chemicals
                              Eutrophication
                                 Ecotoxicity
                                Acidification
                                    Waste


                          Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Impact analysis
Characterisation: a connection between the environmental loads and known
  exposure pathways to humans and ecology is made, in order to assess the
  effects of each chemicals on the corresponding impact categories.
This is made through an equivalence factor that expresses its effects in relation
   with a reference parameter.




                          Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Impact analysis
       Relations between emissions and impact categories




                     Evaluation of Environmental Impact of Leather Process Using LCA Methodology
LCA analysis steps
Impact analysis
                         Environmental Profiles




     The final result of the characterisation step is a list of potential
     environmental impacts. This list of effect scores, one for each
      category, is called the environmental profile of the product.
                          Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Case study
Leather Industry: Environmental impact of unhairing process

                       Traditional unhairing




                       Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Case study
Leather Industry: Environmental impact of unhairing process

                        Oxidative unhairing




                       Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Case study
Leather Industry: Environmental impact of unhairing process
Normalized Results




                       Evaluation of Environmental Impact of Leather Process Using LCA Methodology
Case study
Leather Industry: Environmental impact of unhairing process
                         1000

                         100
                                                                Oxidative unhairing
                                                                Traditional unhairing
                          10

                           1
    Normalized Results




                          0,1

                         0,01

                         1E-3

                         1E-4

                         1E-5




                                Evaluation of Environmental Impact of Leather Process Using LCA Methodology

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Evaluation of Environmental Impact of Leather Process Using LCA Methodology

  • 1. Dipartimento di Ingegneria chimica, Chimica industriale e Scienza dei materiali Prof. Sandra Vitolo Bologna, September 20th 2011
  • 2. Evaluation of Environmental Impact of Leather Process Using LCA Methodology Outline Basic concepts Environmental labelling LCA analysis steps Case study Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 3. Basic concepts According to ISO 14040, the Life Cycle Assessment is a quantitative approach to evaluate the environmental burdens associated with a product/process over its entire life cycle by: Compiling an inventory of relevant inputs and outputs of a product system Evaluating the potential environmental impacts associated with those inputs and outputs Interpreting the results of the inventory analysis and impact assessment phases in relation to the objectives of the study Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 4. Basic concepts The basic concept is that the impact an item has on the environment does not depend exclusively on the manufacturing process, but begins with the design and ends with the final disposal. Raw material Manufacture Use Waste acquisition management • LCA calculates energy and resource use, emissions, environment and health impacts • LCA covers the entire life cycle, from ”cradle‐to‐grave” Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 5. Basic concepts LCAs started in the early 1970s, initially to investigate the energy requirements for different processes; emissions and raw materials were added later LCAs are considered to be the most comprehensive approach to assessing environmental impact Initially, numerous variants of LCA “methods” were developed/investigated, but today there is consensus that there is only one basic method with a large number of variants The Society of Environmental Toxicology and Chemistry (SETAC), an international platform for toxicologists, published a Code of Practice, a widely accepted series of guidelines and definitions. Nowadays, IS0 14040:2006 and 14044:2006 are considered to be the LCA standard. Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 6. LCA applications Product/process design, development, improvement Public policy Marketing Eco‐labelling LCAs have been used increasingly by industry to help reduce the overall environmental burdens across the whole life cycle of goods and services LCA is also used to improve the competitiveness of the company’s products and in communication with governmental bodies LCA is used in decision making as a tool to improve product design, for example the choice of materials, the selection of technologies, specific design criteria and when considering recycling LCA allows benchmarking of product system options and can therefore also be used in decision making of purchasing and technology investments, innovation systems, etc Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 7. LCA applications LCA is one of the tools to apply life cycle thinking in the implementation of the EU’s thematic strategy on the sustainable use of natural resources and the thematic strategy on prevention and recycling of waste In its Communication on Integrated Product Policy (COM (2003)302), the European Commission concluded that Life Cycle Assessments provide the best framework for assessing the potential environmental impacts of products currently available. Integrated Product Policy (IPP) seeks to minimise the environmental degradation that a product causes in some way, by looking at all phases of a products' life‐cycle (manufacturing, use, disposal) and taking action where it is most effective ques Ecode able techni si n g Bes t avail Integrated Pro Life Cycle curement du ct Policy (IPP) Green public pro Thinking Integrated waste management Environmental labelling Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 8. Environmental labelling The International Standards Organisation (ISO) have developed standards for three types of environmental product claims, termed ISO Type I, II and III. • Type I (ISO 14024): claims are based on criteria set by a third party and are multiissue, being based on the product’s life cycle impacts. The awarding body may be either a governmental organisation or a private non‐ commercial entity. Ecolabel Nordic White Swan German Blue Angel Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 9. Environmental labelling • Type II (ISO 14021): claims are based on self‐declarations by manufacturers or retailers. There are numerous examples of such claims e.g. ‘made from x% recycled material’ Mobius loop • Type III (ISO 14025): claims consist of quantified product information based on life cycle impacts. These impacts are presented in a form that facilitates comparison between products e.g. a set of parameters. Environmental Product Declaration Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 10. Environmental labelling Life Cycle Assessment (LCA) The tool for assessing the potential environmental impacts Product Category Rules (PCR) The Product Category Rules (PCRs) are vital for the concept of environmental declarations and climate declarations. The PCRs enable transparency for the EPD‐development and also comparability between differents EPDs based on the same PCR. Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 11. Environmental labelling EPD Programme Development Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 12. Environmental labelling EPD Programme Development Finished bovine leather UN CPC product class 2912 “Other leather, of bovine or equine animals, without hair on” The PCR document is a living document. If relevant changes in the LCA methodology or in the technology for the product category occur, the document will be revised and any changes will be published on the international website www.environdec.com Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 13. LCA analysis steps LCA Steps: defined in ISO 14040 series I. Goal & Scope Definition ‘the reason why LCA is performed’ • II. Inventory Analysis (LCI) ‘quantification of environmental loads’ III. Impact Assessment (LCIA) ‘assess the relevance of flows’ IV. Interpretation ‘interpretation and results analysis’ Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 14. LCA analysis steps Inventory: draw flow chart of product system, build the system model Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 15. LCA analysis steps Inventory: draw flow chart of product system, build the system model Collect data of resource use and emissions of all processes Data sources: LCA databases, reports, scientific papers, on‐site investigation, expert knowledge, qualified guesses Calculate resource use and emissions of studied product. Present results in charts and tables. Iterative procedure! Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 16. LCA analysis steps Impact analysis Classification: each chemical listed in the Inventory is assigned to one or more impact categories Human Health Ozone Layer Global Warming Non renewable Resources Chemicals Eutrophication Ecotoxicity Acidification Waste Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 17. LCA analysis steps Impact analysis Characterisation: a connection between the environmental loads and known exposure pathways to humans and ecology is made, in order to assess the effects of each chemicals on the corresponding impact categories. This is made through an equivalence factor that expresses its effects in relation with a reference parameter. Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 18. LCA analysis steps Impact analysis Relations between emissions and impact categories Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 19. LCA analysis steps Impact analysis Environmental Profiles The final result of the characterisation step is a list of potential environmental impacts. This list of effect scores, one for each category, is called the environmental profile of the product. Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 20. Case study Leather Industry: Environmental impact of unhairing process Traditional unhairing Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 21. Case study Leather Industry: Environmental impact of unhairing process Oxidative unhairing Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 22. Case study Leather Industry: Environmental impact of unhairing process Normalized Results Evaluation of Environmental Impact of Leather Process Using LCA Methodology
  • 23. Case study Leather Industry: Environmental impact of unhairing process 1000 100 Oxidative unhairing Traditional unhairing 10 1 Normalized Results 0,1 0,01 1E-3 1E-4 1E-5 Evaluation of Environmental Impact of Leather Process Using LCA Methodology