SlideShare une entreprise Scribd logo
1  sur  7
Télécharger pour lire hors ligne
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



                           THE POLONNARUWA METEORITE:
              OXYGEN ISOTOPE, CRYSTALLINE AND BIOLOGICAL COMPOSITION

        Jamie Wallis2, Nori Miyake1, Richard B. Hoover1, Andrew Oldroyd3, Daryl H. Wallis1, Anil
     Samaranayake4, K. Wickramarathne4, M.K. Wallis1, Carl H. Gibson1,5 and N. C. Wickramasinghe1†
                   1
                       Buckingham Centre for Astrobiology, University of Buckingham, Buckingham, UK
                                   2
                                     School of Mathematics, Cardiff University, Cardiff, UK
                            3
                              School of Earth and Ocean Sciences, Cardiff University. Cardiff, UK
                                       4
                                         Medical Research Institute, Colombo, Sri Lanka
                            5
                              University of California San Diego, La Jolla, CA, 92093-0411, USA


Abstract: Results of X-Ray Diffraction (XRD) analysis, Triple Oxygen Isotope analysis and Scanning Electron Microscopic (SEM)
studies are presented for stone fragments recovered from the North Central Province of Sri Lanka following a witnessed fireball event
on 29 December 2012. The existence of numerous nitrogen depleted highly carbonaceous fossilized biological structures fused into the
rock matrix is inconsistent with recent terrestrial contamination. Oxygen isotope results compare well with those of CI and CI-like
chondrites but are inconsistent with the fulgurite hypothesis.

Keywords: Polonnaruwa Meteorites, Carbonaceous Meteorites, Fulgurites, Diatoms, Comets, Panspermia


1.       Introduction†                                               numbers of slender cylinders of lengths 5 - 10μm, and a
                                                                     few micrometers in diameter were seen to be distributed
A bright yellow fireball that turned green as it travelled           extensively throughout the sample (Wickramasinghe et
across the sky was observed by several eyewitnesses in               al., 2013a). A separate sample was then sent to the United
the North Central Province of Polonnaruwa, Sri Lanka at              States, where it was investigated by one of us (RBH)
18:30 PM on December 29, 2012. The green fireball was                using the Hitachi Field Emission Scanning Electron
observed to disintegrate into sparkling fragments that fell          Microscope. This independent study on a different sample
to the ground near the villages of Aralaganwila and                  confirmed the presence of a range of diatom frustules,
Dimbulagala and in a rice field (N 7 o 52’ 59.5” N; 81o 09’          some of which were embedded in the rock matrix.
15.7” E) near Dalukkane. The inferred NE to SW                           As a working hypothesis, we take the originating
trajectory was determined from eyewitness observations               bolide to be of mass <100kg with a final explosive break-
and a distribution of stones recovered from a strewn field           up occurring at about ~10km altitude, consistent with
of >10 km. Police records indicate reports of low level              sightings of the fireball over tens of km and the dispersal
burn injuries from immediate contact with the fallen                 of stones.
stones and subsequent reports of a strong aroma. One                     Initial examination of one stone indicated that it was
woman was reported to have lost consciousness and was                uniquely inhomogeneous and poorly compacted with
transported to the hospital after inhaling fumes from one            density less than 1g cm-3 i.e. less than all known
of the stones. Witnesses reported that the newly fallen              carbonaceous meteorites. The stone was predominantly
stones had a strong odour of tar or asphalt. Local police            black, though dark grey and grey regions could be
officials responded immediately by collecting samples                visually detected together with evidence of a partial
and submitting them to the Medical Research Institute of             fusion crust. CHN analysis indicates an average carbon
the Ministry of Health in Colombo, Sri Lanka.                        content of the order of 1-4% and combined with GC-MS
Preliminary optical microscopic studies of deep interior             spectra showing an abundance of high molecular weight
samples extracted from the stones revealed the presence              organic compounds suggest tentative classification as a
of a wide range of 10-40 µm-sized objects with a                     “carbonaceous chondrite ungrouped”.
morphology characteristic of siliceous microalgae known
as diatoms (Wickramasinghe et al., 2013a).                           2.        Samples
    A sample of the recovered stones was then sent to us at
Cardiff University, where we conducted studies of freshly            During the days and weeks that followed the initial
cleaved interior surfaces using the Environmental                    collection of material in Polonnaruwa by local police
Scanning Electron Microscope at the University’s School              officials, large quantities of stone artifacts were recovered
of Earth and Ocean Sciences. These studies resulted in a             from the rice fields in the vicinity of Aralaganwila and
number of images showing diatom frustules, some of                   submitted for analysis. These included substantial
which were clearly embedded in the rock matrix, thereby              quantities of stones recovered by the Department of
excluding the possibility of post-arrival contamination.             Geology, University of Peradeniya as well as 628 separate
Other structures of various shapes including large                   fragments that were collected about a month later and
                                                                     subsequently submitted to us. The task of identifying
†
  Author correspondence Professor N. C. Wickramasinghe               broken fragments of meteorite from a mass of other
Buckingham Centre for Astrobiology, mail: ncwick@gmail.com           stones was not easy. Of the 628 pieces examined, only
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



three were clearly identified as possible meteorites after
comparison with the original stones collected on the 29th                    300
December 2012. Of the samples rejected for further study,
most were either, indigenous terrestrial stones, masonry                     250

composites or by-products of industrial processes. In                                                                 P159/001-04
                                                                             200
addition to the above, a number of further samples were




                                                              Counts/s
collected by us during a site visit on the 29th January                      150
2013. These fragments were visibly different to the
rejected material: they showed evidence of a partial,                        100
moderately thick fusion crust (0.25-0.5mm) with fractured
                                                                              50
surfaces exhibiting a highly porous composite structure
characteristic of a carbonaceous chondrite, with fine                          0
grained olivine aggregates connected with mineral                                  0   10   20       30         40       50    60   70
intergrowths. These samples were stored in sealed glass                                          2 θ Degrees→
vials for later analysis.                                                    300
   For the purpose of this study, one of the original
samples submitted by the Medical Research Institute in                       250
Colombo was selected for analysis. This fragment was                                                                  P159/001-03
                                                                             200
portioned for interior section Scanning Electron


                                                              Counts/s
Microscopy        (SEM),    oxygen     isotope    analysis,                  150
compositional analysis by X-Ray Diffraction (XRD) and
elemental analysis by Inductively Coupled Plasma Optical                     100
Emission Spectroscopy (ICP-OES).
                                                                              50
   In addition to the portioned fragment, a sample of sand
fulgurite was also analysed for comparative purposes                           0
together with a soil sample recovered from the fall site                           0   10   20       30         40       50    60   70
                                                                                                 2 θ Degrees→
and a further sample of calcium-rich terrestrial rock
selected for control purposes. Preliminary oxygen and                      2000
carbon isotope analysis of the calcium rich control sample
produced values of δ13C = -9.716 ± 0.02 and δ18O = -                       1600
6.488 ± 0.04 which accord well with the values for soil
carbonates determined by T.E. Cerling and J. Quade,                                                                  S159/001-05
                                                                Counts/s




                                                                           1200
1993.
                                                                             800
      Sample ID            Origin             Description
                                                                             400
     D159/001-01    Dambulla, Sri Lanka      Soil Carbonate
                                                                               0
     F159/001-02       Sahara Desert           Fulgurite                           0   10   20        30        40       50    60   70
     P159/001-03   Aralaganwila, Sri Lanka   Witnessed Fall                                      2 θ Degrees→
     P159/001-04   Aralaganwila, Sri Lanka   Witnessed Fall                1000
     S159/001-05   Aralaganwila, Sri Lanka    Soil Sample
                                                                             800

Table 1 Details of samples analysed                                                                                  D159/001-01
                                                                  Counts/s




                                                                             600


                                                                             400
3.         X-Ray Diffraction Analysis
                                                                             200
    X-Ray Diffraction was carried out using a Philips
PW1710 Automated Powder Diffractometer using Cu Kα                             0
radiation at 35kV and 40mA, between 2 and 70 o2θ at a                              0   10   20        30        40       50    60   70
scan speed of 0.04o 2θ/s. From the scans, phases were                                            2 θ Degrees→
identified using PC-Identity software and from the peak
areas, semi-quantitative analysis was performed and           Figure 1. Shows X-Ray Diffraction patterns (counts/s against 2θ
percentage of each phase calculated. Each of the four         degrees) for samples P159/001-04, P159/001-03, S159/001-05 (soil)
samples provided for analysis were powdered, mixed with       and D159/001-01 (control). The broad humps displayed in samples
a small amount of acetone and pipetted out onto glass         P159/001-04 and P159/001-03 are due to bulk composition of
slides. Sample preparation and analysis was conducted at      amorphous silica of (between 85-95%). The three crystaline phases
the School of Earth Sciences at Cardiff University.           detected are quartz (between 3-10%) together with anorthite (1-3%)
                                                              and cristobaloite (approximately 2% in each sample).
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



   X-Ray Diffraction patterns for the selected samples            Data are reported relative to SMOW. Error bars are
P159/001-04, P159/001-03, S159/001-05 and D159/001-           about ± 0.1 ‰ for 17O and 18O and about ± 0.01 ‰ or
01 (control) are represented in Figure 1. The broad hump      better for Δ17O. The reference gas was analysed relative
displayed in P159/001-03 and P159/001-04 at ~18-36O 2θ        to SMOW calibrated O2 by E. Barkan (Hebrew University
corresponds to a bulk composition of amorphous silica.        of Jerusalem). All values are permil unless otherwise
    P159/001-03, P159/001-04 and S159/001-05 all              stated.
display strong features at 20.8 2θ reported to be that of         Results are presented in δ-notation such that:
crystalline quartz. A strong feature at ~21.8 2θ in           δxOVSMOW /1000 = [(xO/16O)sample / (xO/16O)VSMOW] - 1. We
P159/001-04       was     reported     as    (NaK)AlSi3O8     use a slope of 0.5251 for the terrestrial fractionation line
(anorthoclase) with further features in the 42-46 2θ range    and linearized form of the δ-notation so that Δ17O = δ17O
attributed to the presence of the silica polymorph            – 0.5251 δ18O. Error has been established through
cristobalite. P159/001-03 also reported the presence of       observation of the standard deviation in 290 single
NaAlSi3O8 (albite). Further weak but distinct peaks were      analyses of terrestrial rocks and minerals, carried out in
noted at ~33.32 and 35.72 2θ in P159/001-04 with              30 sessions at this stable isotope laboratory using the
corresponding peaks at ~33.32, ~54.30 and ~35.72 2θ in        same equipment and is reported as +/- 0.06‰ (A. Gehler
P159/001-03 which is most likely due to the presence of       et al, 2011).
Fe2O3 (hematite). Additional features at ~28.83 2θ in both
P159/001-03 and P159/001-04 may be due to the presence
of coesite. A weak feature at ~60.5 2θ suggests possible                           12
                                                                                                                                                 11.59
inclusions of stishovite but corresponding features at
                                                                                                                                                            11.58
30.18 and 45.76 2θ could not be determined with                                    11                                                      10.94
certainty and further work will be required to confirm        δ O (‰ rel. SMOW)                                                                         10.91
this.                                                                              10
    S159/001-05 (soil) reported the expected presence of                                                     9.23
approximately 75% quartz, 17% KAlSi3O8 (microcline),                                    9             8.79
                                                                                                                               P159/001-03
4% (NaK)AlSi3O8, 3% Al2Si2O5(OH)4 (kaolinite) and 1%                                                                           Polonnaruwa
                                                              17




opal. Results reported for the control sample D159/001-01                                               8.6
                                                                                        8
were consisted with the available literature on soil
carbonates comprising of 81% calcite, 13% quartz, 4%
ankerite and 2% anorthite.                                                              7
                                                                                            15         16      17        18         19     20      21      22    23
                                                                                                                          18
4.       Triple Oxygen Isotope Analysis                                                                                  δ O (‰ rel. SMOW)

Triple oxygen isotope analyses were conducted in the          Figure 2. Oxygen isotope compositions of sample P159/001-04
stable isotope laboratory at the University of Göttingen,     and of CI chondrites: Alais (8.6), Ivuna (9.23) and Orgueil
Germany. Approximately 2mg of crushed sample was              (8.79) together with CI-like chondrites (Meta-C) B-7904
placed inside a Ni sample holder, evacuated overnight and     (10.91), Y-82162 (11.59), Y-86720 (11.58) and Y-86789
heated to 70°C for 12h. An infrared (IR) laser (50W CO2       (10.94). Data from Clayton and Mayeda, 1998.
laser, λ = 10.6µm) was used to fluorinate the samples in
purified F2 gas under pressures of approximately 20 mbar.
Sample O2 was purified through the removal of excess F2                                     0.5
by reaction with NaCl at 110°C to form NaF. Cl2 gas was
collected at a cold trap at -196°C. Sample oxygen was                                                                                        CI +0.417 ± 0.05
                                                                    Δ O (‰ rel. SMOW)




then collected at a 5Å molecular sieve at -196°C,                                       0.25                MFL +0.301 ± 0.013
expanded into a stainless steel capillary, transported with
He carrier gas and re-trapped before release at 92°C                                         0
                                                                                                                                    Terrestial Fractionation Line
through a 5Å molecular sieve GC-column of a Thermo
Scientific GasBench II. The GC column was utilised to                                                                                       MC -0.055 ± 0.005
                                                                                                        EFL -0.239 ± 0.007
separate interfering NF3, from O2, as required for analysis                             -0.25
                                                                  17




of 17O (Pack et al, 2008). The resulting purified sample O2
                                                                                                                                         POL -0.335      0.011
was then expanded to the dual inlet system of a Thermo
                                                                                         -0.5
MAT 253 gas mass spectrometer. Results are presented in                                           0            5               10           15           20         25
δ- and Δ17O-notation.                                                                                               18
                                                                                                                    δ O (‰ rel. SMOW)


              δ17O        8.978         ± 0.050
                                                              Figure 3. Oxygen isotope Δ17O (‰ rel. SMOW) values of
              δ18O        17.816        ± 0.100               sample P159/001-04 (POL). Data for MFL: martian
              Δ17O        -0.335        ± 0.011               fractionation from Franchi et al. 1999. EFL: eucrite fractionation
                                                              from Greenwood et al., 2005. CI: fractionation line for CI1
                                                              chondrites and MC: fractionation of Meta-C chondrites (B-9704
Table 2. Results of Oxygen Isotope Analysis                   and Y-86789) from Clayton at al., 1998.
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



   Results of analysis are displayed in Table 2, showing                                 2000
Δ17O = - 0.335. Figure 2 shows a plot of δ 17O/ δ18O                                                C
values compared to those of known CI chondrites as                                       1600
reported by Clayton and Mayeda, 1998. It is noted that                                                                                            Spectrum S1




                                                                    Relative Intensity
δ18O values are relatively high but are within the range of                              1200
the CI1 carbonaceous meteorites (Alais, Ivuna and
Orgueil) and the CI-like and CM-like MCC                                                  800           O
(Metamorphosed Carbonaceous Chondrite) members on                                                                          Si
the new Meta-C group. Meteorites of the Meta-C group                                      400
                                                                                                                      Al
have been thermally metamorphosed on their parent body                                                           Mg                               K   Ca
and have low water content and IR spectra indicating                                        0
dehydration of their matrix phyllosilicates, very similar to                                    0                1              keV
                                                                                                                                2             3            4      5

our samples. Although the Meta-C meteorites somewhat
                                                                                         2400
resemble CI and CM carbonaceous chondrites, they are                                                    O
relatively depleted in Iron and Sulfur as compared to the                                2000
                                                                                                                           Si                     Spectrum S2




                                                                 Relative Intensity
CI and CM stones. The Meta-C meteorites show
                                                                                         1600
comparatively young Cosmic Ray Exposure (CRE) ages
suggesting a near Earth asteroid as their common parent                                  1200                         Al
body. They have been recovered from Antarctica
(Belgica-7904, Yamato 82162, Yamato 86720, and                                            800
Yamato 86789) and the desert of Oman (Dhofar 225 and                                      400
Dhofar 735 (Ikeda, 1992; (Ivanova et. al. 2002; Tameoka,                                            C                                             K
                                                                                                                 Mg                                    Ca
1990). The Meta-C meteorites show common Oxygen                                             0
                                                                                                0                1              keV
                                                                                                                                2             3            4      5
isotopic compositions that are entirely distinct from the
Oxygen isotopic composition of CI1 and the CM1 and
                                                                                         2000
CM2 carbonaceous chondrites.                                                                            O
                                                                                                                           Si
                                                                                         1600
                                                                 Relative Intensity




5.       Scanning Electron Microscopy                                                                                                             Spectrum S3
                                                                                         1200                         Al
    Scanning Electron Microscopy (SEM) was conducted
using the FEI (Phillips) XL30 FEG ESEM
                                                                                          800
(Environmental Scanning Electron Microscope) FEG                                                    C
(Field Emission Gun) at the School of Earth Sciences at                                   400
Cardiff University. The unit incorporates a secondary                                                            Mg                               K Ca
electron detector (SE), a back scatter electron detector                                    0
(BSE) and a gaseous secondary electron detector (GSE).                                          0                1              keV
                                                                                                                                2             3            4      5
It also has an Oxford Instruments INCA ENERGY (EDX)
x-ray analysis system.                                          Figure 5 Energy Dispersive X-ray analysis (EDX) results for
                                                                the three points S1, S2 and S3 as displayed in Figure 4




                                                                                         Spec               S1         S2             S3           Max         Min

                                                                                      C                     59.81      29.26           0.00           59.81     0.00
                                      S2                                              N                      0.00       5.11           0.00            5.11     0.00
                                                                                      O                      31.3      44.98          60.53           60.53     31.3
             S3                                                                       Mg                     0.34       0.42           0.00            0.42     0.34
                       S1                                                             Al                     2.11       6.68          12.15           12.15     2.11
                                                                                      Si                     3.55       9.98          20.91           20.91     3.55
                                                                                      P                      0.00       0.23           0.00            0.23     0.23
                                                                                      S                      0.00       0.00           0.33            0.33     0.33
                                                                                      K                      1.38       1.47           2.14            2.14     1.38
                                                                                      Ca                     1.04       0.42           0.53            1.04     0.42
                                                                                      Ti                     0.00       0.00           0.57            0.57     0.57
                                                                                      Fe                     0.47       1.45           2.84            2.84     0.47

Figure 4 Shows a highly carbonaceous partially degraded
biological structure. Note the apparent fracture from the
surrounding mineral matrix along the leading edge. Points S1,   Table 3 Elemental abundances as detected by energy X-ray
S2 and S3 correspond to elemental abundances determined by      analysis for points S1, S2 and S3 as displayed in Figure 4
EDX as detailed in Table 2 and Figure 5
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



                                                                                           140
                                                                                                            C
                                                                                           120
                                                                                                                                                           Spectrum S1




                                                                         Relative Intensity
                                                                                           100
                                                                                                                                          Au
                                                                                                   80
                           (b)
                                                                                                   60
                                                                                                                 O                    P
                                                                                                   40                                             Pd

                                      (c)                                                          20

                                                                                                    0
                                                                                                        0               1                 2
                                                                                                                                          keV          3         4           5

                      S1                                                                           50
                                                     Fig. 6(a)                                                                         Au
                                                                                                   40
                                                                                                                                                           Spectrum S2




                                                                              Relative Intensity
                                                                                                   30
                                                                                                                                      P

                                                                                                   20                            Si
                                                                                                                        Mg                        Pd
                                                                                                                O
                                                                                                   10       C               Al

                                                                                                    0
                                                                                                        0               1                 2            3         4           5
                                                                                                                                       keV
                                                                                              250
                                                                                                            C
                                                                                              200
                                                                                                                                                           Spectrum S3
                                                                      Relative Intensity




                                                    Fig. 6(b)                                 150                                         Au


                                                                                              100
                                               S2                                                               O
                                                                                                   50                                             Pd
                                                                                                                                  Al

                                                                                                    0
                                                                                                        0               1                 2            3          4          5
                                                                                                                                          keV

                                                                     Figure 7. Energy X-ray analysis (EDX) results for the three
                                                                     points S1, S2 and S3 as displayed in Figure 6. Gold and
                      S3                                             Paladium readings are a result of sample coating.



                                                                                           Spec                  S1          S2            S3     Mean          SD       Max.
                                                    Fig. 6(c)
                                                                                                   C            67.94        0.00         65.73    44.56       38.60     67.94
Figure 6 (a-c) show images of a large (100 µm diameter) and                                        N             0.00        0.00          0.00     0.00        0.00     0.00
very complex, thick-walled, carbon-rich (kerogenous)                                               O            26.21       39.82         24.80    30.28        8.29     39.82
microfossil that we have tentatively identified as a                                               Na            0.00        0.00          0.00     0.00        0.00     0.00
hystrichosphere. Hystrichospheres are thought to be associated                                     Mg            0.00       13.02          0.00     4.34        7.52     13.02
with the resting stages of a group of largely extinct marine                                       Al            0.00       10.35          0.00     3.45        5.98     10.35
dinoflagellate algae. The EDX data reveals a lack of detectable                                    Si            0.00       36.81          2.17    12.99       20.66     36.81
nitrogen and an anomalous C/O ratio (similar to bitumen)                                           P             0.00        0.00          0.00     0.00        0.00     0.00
clearly establishing that this obviously biological form could not                                 S             0.00        0.00          0.00     0.00        0.00     0.00
possibly represent a modern biological contaminant. The
                                                                                                   K             5.85        0.00          7.29     4.38        3.86     7.29
extremely well-preserved and very thin (2 µm diameter x 100
                                                                                                   Ca            0.00        0.00          0.00     0.00        0.00     0.00
µm long) flagella are interpreted as indicating a low-gravity,
low-pressure environment and rapid freeze-drying. In the                                           Fe            0.00        0.00          0.00     0.00        0.00     0.00
vicinity of this form are highly carbonaceous embedded
filaments of cyanobacteria (“blue-green algae”). Low nitrogen
shows they are ancient fossils. Points S1, S2 and S3 relate to       Table 4. Elemental abundances as detected by energy X-ray
target corordinates of energy X-ray readings detailed in Figure 7    analysis for points S1, S2 and S3 as displayed in Figure 6. (Au
and Table 4. The sample was coated with a gold/palladium             and Pd subtracted).
surface to facilitate high resolution image capture.
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



Image recording is via a SONY video graphics printer or            Furthermore, none of the Polonnaruwa meteorites
digital by processing image frames in a 16 bit framestore      studied are in the form of hollow tubes, which is a well-
computer for output to hard drive.                             known common characteristic of fulgurites. Additionally,
   Sample preparation involved the use of a flame              due to the method in which they form, fulgurites typically
sterilised wide-bore hypodermic needle to fracture the         have to be dug out of the soil. In contrast, the
fragments before mounting on aluminium stubs. Further          Polonnaruwa stones were found lying on the surface of
SEM studies were conducted at the NASA Marshall                undisturbed sandy soil in a rice field. The eyewitnesses
Space Flight Centre using uncoated freshly fractured           reported that there was no lightning activity in this region
surfaces that were examined using a Hitachi S-3700N            on the night of Dec. 29, 2012. To have produced such a
Field Emission Scanning Electron Microscope with               large number of stones as have been found in a small field
images gathered using both the Back-Scatter Electron           would have required cloud to ground lightning strikes
and the Secondary Electron detectors.                          many orders of magnitude greater than ever before
   Preliminary inspection of a few of the SEM images           reported. In addition, the temperature at which sand must
revealed the presence of a number of highly carbonaceous       be heated by lightning to melt and form a fulgurite (1770
biological structures. Some of these were deeply               C) would certainly have vaporized and burned all carbon-
integrated in the surrounding mineral matrix indicating        rich        biological      (cyanobacterial        filaments,
they could not have been recent biological contaminants.       hystrichospheres, etc.) and melted and thus destroyed the
EDX data indicates they are severely depleted in nitrogen      delicately marked silica frustules of the diatoms.
(N < 0.5%). Hoover (2007) explored the use of Nitrogen             Subsequent suggestions that an “unusually porous”
levels and biogenic element ratios for distinguishing          fulgurite may have floated in on water ignores the fact
between modern and fossil microorganisms as a                  that many of these low-density (<1 g cm-3) stones were
mechanism       for    recognizing     recent    biological    recovered between Dec. 29, 2012 and Jan. 29, 2013 and
contaminants in terrestrial rocks and meteorites.              found to exhibit similar mineralogy, morphology,
Detectable (2-18%) levels of Nitrogen were encountered         physical and microbiological properties. None of these
in the hair and tissues from mummies from Peru (2 Kyr)         original stones studied at Cardiff University or at the
and Egypt (5 Kyr) and the hair/tissues of Pleistocene          NASA Marshall Space Flight Center were observed to be
Wooly Mammoths (40-32 Kyr). Comparative studies on             hollow tubes and none were found to be composed of the
fossilized insects in Miocene (8.4 Myr) Amber,                 mineral lechatelierite. The “floating on water” hypothesis
Cretaceous Ammonites (100 Myr), Cambrian trilobites of         is also inconsistent with FTIR data obtained using
Wheeler Shale of Utah (505 Myr) and filamentous                diamond ATR instrumentation that show a conspicuous
cyanobacteria from Karelia (2.7 Gyr) showed nitrogen           absence of a characteristic water peak (Wickramasinghe
levels below the limit of detection with the FESEM EDS         et al, 2013c). This observation alone appears to rule out
detector (N < 0.5%). This provides clear and convincing        the likelihood of aqueous-based contaminants being
evidence that these obviously ancient remains of extinct       responsible for the presence of observed diatom frustules
marine algae found embedded in the Polonnaruwa                 in either a non-terrestrial fragment or a formerly sterile
meteorite are indigenous to the stones and not the result of   terrestrial fulgurite.
post-arrival microbial contaminants.                               Finally, the results of triple-oxygen isotope analysis
                                                               presented here give a Δ17O value of - 0.335. This result,
6.   Discussion                                                together with previous studies on the oxygen isotope
                                                               composition of fulgurites (Robert and Javoy, 1992) that
Results of initial studies on the Polonnaruwa stones were      find no marked isotope exchange with atmospheric
reported in a series of short bulletins in the Journal of      molecular oxygen during the formation process provides a
Cosmology during the early part of 2013                        strong case against the fulgurite conjecture.
(Wickramasinghe et al, 2013a, 2013b, 2013c, 2013d). A              We are aware that a large number of unrelated stones
number of critical observations followed relating to the       have been submitted for analysis, and we have no direct
possible terrestrial origin of the stones as well as           information or knowledge regarding the nature, source,
terrestrial contaminants being the most likely explanation     origin or provenance of the stones our critics have
for the observations. Critics also pointed to the unusual      examined. Based upon the physical, chemical, isotopic,
bulk composition of the stone (i.e. amorphous SiO2), the       mineralogical and microbiological studies that we have
presence of some crystalline phases of SiO2 (quartz), the      performed, we are certain that the Polonnaruwa stones
low density (<1g cm-3) and the potential unreliability of      submitted to us for examination by the Medical Research
eye witness reports. The hypothesis that the stones            Institute in Sri Lanka and the stones that we recovered
comprise of terrestrial fulgurite, the glassy product of       from the rice field (7 o 52’ 59.5” N; 81 o 9’ 15.7” E) on
tubes formed when quartzose sand, silica, or soil is heated    Jan. 29, 2013 were not fulgurites, scoria, lava, pumice or
by lightning strikes was suggested. However, the fulgurite     the product of industrial processes.
hypothesis is readily disproved by the fact that the               The presence of a number of carbonaceous biological
mineral lechatelierite (which comprises fulgurites) has an     structures exhibiting severe nitrogen depletion is highly
average density of 2.57 g cm-3, whereas the density of the     indicative of ancient fossilised biological remains. Some
Polonnaruwa meteorites is <1 g cm-3.                           of these were deeply integrated in the surrounding mineral
                                                               matrix suggesting they could not have been recent
Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013



terrestrial contaminants. The presence of these structures       Ikeda Y. An overview of the research consortium, “Antarctic
may have further implications since diatoms are known to             carbonaceous chondrites with CI affinities, Yamato-86720,
be unable to break the strong triple bond of the inorganic           Yamato-82162, and Belgica-7904.” Proc. NIPR Symp.
di-nitrogen (N2) molecule and convert it into the organic            Antarct. Meteorites, 5, 49–73, (1992).
                                                                 Ivanova M. A., Taylor L. A.., Clayton R. N., Mayeda T. K.,
nitrogen. Nitrogen in molecules such as NO2 or NH3 can               Nazarov M. A., Brandstaetter F., and Kurat G., Dhofar 225
be readily used for the construction of amino acids,                 vs. the CM clan: Metamorphosed or new type of
proteins, DNA, RNA and other life-critical biomolecules.             carbonaceous chondrite? (abstract). In Lunar and Planetary
The function of nitrogen-fixation is carried out by the              Science XXXIII, Abstract #1437. Lunar and Planetary
nitrogenous enzyme that is housed in structures known as             Institute, Houston, (2002).
heterocysts of several species of several genera (Nostoc         Pack, A., 2008, Fractionation of refractory lithophile elements in
Tolypothrix, etc.) of heterocystous cyanobacteria.                   bulk chondrites and chondrite components. Lunar and
Consequently, cyanobacteria are considered a crucial                 Planetary Science Conference, Houston.
component of a cometary ecosystem.                               Robert, F., and Javoy, M., 1992, Oxygen Isotope Compositions
                                                                     of Fulgarites, Meteoritics 27 (1992): 281.
   We conclude that the oxygen isotope data show                 Tameoka, K. 1990. Mineralogy and Petrology of Belgica-7904:
P159/001-03 and P/159001-04 are unequivocally                        A New Kind of Carbonaceous Chondrite from Antarctica.
meteorites, almost certainly fragments originating from              Proc. NIPR Symp. Antarct. Meteorites. 3, 40-54, 1990.
the fireball-causing bolide. The most likely origin of this      Wickramasinghe, N.C., Wallis, J., Wallis, D.H., Samaranayake,
low density meteorite with delicate structures, some                 A., 2013a. Fossil diatoms in a new carbonaceous meteorite,
highly carbonaceous, is a comet (Wickramasinghe et al.,              Journal of Cosmology, 21, 37.
2013b). The presence of fossilized biological structures         Wickramasinghe, N.C., Wallis, J., Wallis, D.H., Wallis M.K., Al-
provides compelling evidence in support of the theory of             Mufti, S., Wickramasinghe, J.T., Samaranayake, A. and
cometary panspermia first proposed over thirty years ago             Wickramarathne, K., 2013b. On the cometary origin of the
                                                                     Polonnaruwa meteorite, Journal of Cosmology, 21, 38.
(Hoyle and Wickramainghe, 1981, 1982, 2000).                     Wickramasinghe, N.C., Wallis, J., Miyake, N., Wallis D.H.,
                                                                     Samaranayake, A., Wickramarathne, K., Hoover, R., and
Acknowledgement                                                      Wallis M.K., 2013c. Authenticity of the life-bearing
                                                                     Polonnaruwa meteorite, Journal of Cosmology, 21, 39.
We are grateful to Professor Andreas Pack of the                 Wickramasinghe, N.C., Samaranayake, A., Wickramarathne, K.,
University of Göttingen, Germany for his assistance with             Wallis, D.H., Wallis M.K., Miyake, N., Coulson, S.J.,
the Triple Oxygen Isotope analysis.                                  Hoover, R., Gibson, C.H., and Wallis, J.H., 2013d, Living
                                                                     Diatoms in the Polonnaruwa meteorite – Possible link to red
                                                                     and yellow rain, Journal of Cosmology, 21, 40.
REFERENCES

Cerling, T. E., and Quade, J., 1993, Stable Carbon and Oxygen
   Isotopes in Soil Carbonates, In P.K. Swart, K.C. Lohmann,
   J.A.McKenzie, and S.M.Savin, eds., Climate Change in
   Continental Isotope Records, pp217-231.
Clayton, R. N., and Mayeda, T. K., 1999, Oxygen Isotope
   Studies of carbonaceous chondrites, Geochimica et
   Cosmochimica Acta, Vol 63, No 13/14 pp2089-2104.
Franchi, I.A., Wright, I.P., Sexton, A.S., and Pillinger, C.T.
   1999, The oxygen isotope composition of Earth and Mars,
   Meteoritics & Planetary Science 34, pp657-661.
Gehler, A., Tütken, T., and Pack, A., 2011, Triple oxygen
   isotope analysis of bioapatite as tracer for diagenetic
   alteration of bones and teeth, Palaeogeography,
   Palaeoclimatology, Palaeoecology, Vol 310, 1-2 pp 84-91.
Greenwood R.C., Franchi I.A., Jambon A. and Buchanan P.C.
   (2005) Widespread magma oceans on asteroidal bodies in
   the early solar system. Nature 435, 916-918.
Hoover, R. B., 2007, Ratios of Biogenic Elements for
   Distinguishing Recent from Fossil Microorganisms.
   Instruments, Methods, and Missions for Astrobiology X,
   Proc. SPIE 66940D.
Hoyle, F. and Wickramasinghe, C., “Proofs that Life is
   Cosmic”, Memoirs of the Institute of Fundamental Studies,
   Sri Lanka, No. 1, Dec 1982.
Hoyle, F. and Wickramasinghe, N.C., 1981. “Comets - a vehicle
   for panspermia”, in Comets and the Origin of Life, ed. C.
   Ponnamperuma, D. Reidel Publishing Co. Dordrecht.
Hoyle, F. and Wickramasinghe, N.C., 2000. “Astronomical
   Origins of Life – Steps towards panspermia” (Kluwer
   Academic Publishers, Dordrecht).

Contenu connexe

Tendances

Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...
Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...
Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...Oleg Maksimov
 
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...inventionjournals
 
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...IJARIIT
 
Synthesis and Characterisation of Copper Oxide nanoparticles
Synthesis and Characterisation of Copper Oxide nanoparticlesSynthesis and Characterisation of Copper Oxide nanoparticles
Synthesis and Characterisation of Copper Oxide nanoparticlesIOSR Journals
 
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...IRJET Journal
 
Biopolymer based nanomaterials as potential biosorbents for toxic metal ions
Biopolymer based nanomaterials as potential biosorbents for toxic metal ionsBiopolymer based nanomaterials as potential biosorbents for toxic metal ions
Biopolymer based nanomaterials as potential biosorbents for toxic metal ionsAlexander Decker
 
IRJET - Photoluminescence Study of Rare Earth Doped ZnO Nanoparticles
IRJET - Photoluminescence Study of Rare Earth Doped ZnO NanoparticlesIRJET - Photoluminescence Study of Rare Earth Doped ZnO Nanoparticles
IRJET - Photoluminescence Study of Rare Earth Doped ZnO NanoparticlesIRJET Journal
 
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...EROMOR
 
Effect of glycine as an impurity on the properties of Epsomite single crystals
Effect of glycine as an impurity on the properties of Epsomite single crystalsEffect of glycine as an impurity on the properties of Epsomite single crystals
Effect of glycine as an impurity on the properties of Epsomite single crystalsIOSR Journals
 
IRJET - Comparative Study on the Structural and Optical Characterization of Z...
IRJET - Comparative Study on the Structural and Optical Characterization of Z...IRJET - Comparative Study on the Structural and Optical Characterization of Z...
IRJET - Comparative Study on the Structural and Optical Characterization of Z...IRJET Journal
 
Study of Optical Property of Gel Grown Mercuric Iodate Crystals
Study of Optical Property of Gel Grown Mercuric Iodate CrystalsStudy of Optical Property of Gel Grown Mercuric Iodate Crystals
Study of Optical Property of Gel Grown Mercuric Iodate CrystalsIOSR Journals
 
Sonia Katdare Research Presentation 2008
Sonia Katdare Research Presentation 2008Sonia Katdare Research Presentation 2008
Sonia Katdare Research Presentation 2008soniakatdare
 
Growth and Analysis of Urea Thiourea Sodium Sulphate Crystal
Growth and Analysis of Urea Thiourea Sodium Sulphate CrystalGrowth and Analysis of Urea Thiourea Sodium Sulphate Crystal
Growth and Analysis of Urea Thiourea Sodium Sulphate CrystalIOSR Journals
 

Tendances (17)

Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...
Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...
Investigation of As-doped ZnO films synthesized via thermal annealing of ZnSe...
 
T4409103113
T4409103113T4409103113
T4409103113
 
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...
Infrared Spectral and EPR Studies of Mn2+ Ions Doped K2O - CdO - B2O3 - SiO2 ...
 
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...
Preparation, Structure, and Characterization of Nd2mo2o9 fast Oxide Ion Condu...
 
Synthesis and Characterisation of Copper Oxide nanoparticles
Synthesis and Characterisation of Copper Oxide nanoparticlesSynthesis and Characterisation of Copper Oxide nanoparticles
Synthesis and Characterisation of Copper Oxide nanoparticles
 
Application of Drilling Mud Waste as Raw Material In Building Brick Making
Application of Drilling Mud Waste as Raw Material In Building Brick MakingApplication of Drilling Mud Waste as Raw Material In Building Brick Making
Application of Drilling Mud Waste as Raw Material In Building Brick Making
 
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...
IRJET- Thermal Property and Structural Characteristics of Ni0.9Cu0.1Fe2O4 Fer...
 
Biopolymer based nanomaterials as potential biosorbents for toxic metal ions
Biopolymer based nanomaterials as potential biosorbents for toxic metal ionsBiopolymer based nanomaterials as potential biosorbents for toxic metal ions
Biopolymer based nanomaterials as potential biosorbents for toxic metal ions
 
IRJET - Photoluminescence Study of Rare Earth Doped ZnO Nanoparticles
IRJET - Photoluminescence Study of Rare Earth Doped ZnO NanoparticlesIRJET - Photoluminescence Study of Rare Earth Doped ZnO Nanoparticles
IRJET - Photoluminescence Study of Rare Earth Doped ZnO Nanoparticles
 
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...
Study of columnar growth polycrystalline (sn, cr) co doped in2 o3 films depos...
 
Effect of glycine as an impurity on the properties of Epsomite single crystals
Effect of glycine as an impurity on the properties of Epsomite single crystalsEffect of glycine as an impurity on the properties of Epsomite single crystals
Effect of glycine as an impurity on the properties of Epsomite single crystals
 
IRJET - Comparative Study on the Structural and Optical Characterization of Z...
IRJET - Comparative Study on the Structural and Optical Characterization of Z...IRJET - Comparative Study on the Structural and Optical Characterization of Z...
IRJET - Comparative Study on the Structural and Optical Characterization of Z...
 
Y04505127134
Y04505127134Y04505127134
Y04505127134
 
Study of Optical Property of Gel Grown Mercuric Iodate Crystals
Study of Optical Property of Gel Grown Mercuric Iodate CrystalsStudy of Optical Property of Gel Grown Mercuric Iodate Crystals
Study of Optical Property of Gel Grown Mercuric Iodate Crystals
 
Sonia Katdare Research Presentation 2008
Sonia Katdare Research Presentation 2008Sonia Katdare Research Presentation 2008
Sonia Katdare Research Presentation 2008
 
CdS Nanoparticles
CdS Nanoparticles CdS Nanoparticles
CdS Nanoparticles
 
Growth and Analysis of Urea Thiourea Sodium Sulphate Crystal
Growth and Analysis of Urea Thiourea Sodium Sulphate CrystalGrowth and Analysis of Urea Thiourea Sodium Sulphate Crystal
Growth and Analysis of Urea Thiourea Sodium Sulphate Crystal
 

En vedette

La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...
La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...
La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...bueno buono good
 
Informe del Relator Especial sobre los derechos de los pueblos indígenas, Ja...
Informe del Relator Especial sobre los derechos de los  pueblos indígenas, Ja...Informe del Relator Especial sobre los derechos de los  pueblos indígenas, Ja...
Informe del Relator Especial sobre los derechos de los pueblos indígenas, Ja...bueno buono good
 
хосткей
хосткейхосткей
хосткейifranz74
 

En vedette (10)

NkpPS
NkpPSNkpPS
NkpPS
 
Alghe oil
Alghe oilAlghe oil
Alghe oil
 
La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...
La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...
La conanp informa sobre el hallazgo de un ballenato siamés en la laguna ojo d...
 
Informe del Relator Especial sobre los derechos de los pueblos indígenas, Ja...
Informe del Relator Especial sobre los derechos de los  pueblos indígenas, Ja...Informe del Relator Especial sobre los derechos de los  pueblos indígenas, Ja...
Informe del Relator Especial sobre los derechos de los pueblos indígenas, Ja...
 
Inceneration and health
Inceneration and healthInceneration and health
Inceneration and health
 
Water resourcers group
Water resourcers groupWater resourcers group
Water resourcers group
 
LIBERTÀ STAMPA 2014
LIBERTÀ STAMPA 2014LIBERTÀ STAMPA 2014
LIBERTÀ STAMPA 2014
 
Privacy facebook 2015
Privacy facebook 2015Privacy facebook 2015
Privacy facebook 2015
 
Galline libere guida
Galline libere guidaGalline libere guida
Galline libere guida
 
хосткей
хосткейхосткей
хосткей
 

Similaire à Journal reports discovery of biological structures in Sri Lankan meteorite

K0364062067
K0364062067K0364062067
K0364062067theijes
 
Comparative studies on flotation of kasolite using cationic and anionic surfa...
Comparative studies on flotation of kasolite using cationic and anionic surfa...Comparative studies on flotation of kasolite using cationic and anionic surfa...
Comparative studies on flotation of kasolite using cationic and anionic surfa...eSAT Publishing House
 
Investigations on the Properties of Copper Sulphide Nanoparticles
Investigations on the Properties of Copper Sulphide NanoparticlesInvestigations on the Properties of Copper Sulphide Nanoparticles
Investigations on the Properties of Copper Sulphide NanoparticlesIRJET Journal
 
Cockle Creek Sediments Assessment Project
Cockle Creek Sediments Assessment ProjectCockle Creek Sediments Assessment Project
Cockle Creek Sediments Assessment ProjectCar0lyn
 
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smid
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_SmidAuckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smid
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smidelainesmid
 
The physio chemical and mineralogical properties of mbaduku clay and its suit...
The physio chemical and mineralogical properties of mbaduku clay and its suit...The physio chemical and mineralogical properties of mbaduku clay and its suit...
The physio chemical and mineralogical properties of mbaduku clay and its suit...eSAT Publishing House
 
INORG CHEM Cu-S Ist paper Prashant
INORG CHEM Cu-S Ist paper PrashantINORG CHEM Cu-S Ist paper Prashant
INORG CHEM Cu-S Ist paper PrashantPrashant Sharma
 
Nanochemistry presentation final
Nanochemistry presentation finalNanochemistry presentation final
Nanochemistry presentation finalJaveriaJaved26
 
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...madlovescience
 
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...tshankar20134
 
Characterization of Archaeological Ceramic Materials Collected from Recently ...
Characterization of Archaeological Ceramic Materials Collected from Recently ...Characterization of Archaeological Ceramic Materials Collected from Recently ...
Characterization of Archaeological Ceramic Materials Collected from Recently ...IRJET Journal
 
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...IJERA Editor
 
Characterization of cobalt oxide and calcium aluminum
Characterization of cobalt oxide and calcium aluminumCharacterization of cobalt oxide and calcium aluminum
Characterization of cobalt oxide and calcium aluminumShujaul Mulk Khan
 
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...Alexandra Vasile
 

Similaire à Journal reports discovery of biological structures in Sri Lankan meteorite (20)

K0364062067
K0364062067K0364062067
K0364062067
 
6
66
6
 
Comparative studies on flotation of kasolite using cationic and anionic surfa...
Comparative studies on flotation of kasolite using cationic and anionic surfa...Comparative studies on flotation of kasolite using cationic and anionic surfa...
Comparative studies on flotation of kasolite using cationic and anionic surfa...
 
Investigations on the Properties of Copper Sulphide Nanoparticles
Investigations on the Properties of Copper Sulphide NanoparticlesInvestigations on the Properties of Copper Sulphide Nanoparticles
Investigations on the Properties of Copper Sulphide Nanoparticles
 
CARBON-CUPROUS OXIDE COMPOSITE NANOPARTICLES ON GLASS TUBES FOR SOLAR HEAT CO...
CARBON-CUPROUS OXIDE COMPOSITE NANOPARTICLES ON GLASS TUBES FOR SOLAR HEAT CO...CARBON-CUPROUS OXIDE COMPOSITE NANOPARTICLES ON GLASS TUBES FOR SOLAR HEAT CO...
CARBON-CUPROUS OXIDE COMPOSITE NANOPARTICLES ON GLASS TUBES FOR SOLAR HEAT CO...
 
Cockle Creek Sediments Assessment Project
Cockle Creek Sediments Assessment ProjectCockle Creek Sediments Assessment Project
Cockle Creek Sediments Assessment Project
 
Synthesis of polyaniline
Synthesis of polyanilineSynthesis of polyaniline
Synthesis of polyaniline
 
Volcanic Tuff
Volcanic TuffVolcanic Tuff
Volcanic Tuff
 
Absolute Dating.pptx
Absolute Dating.pptxAbsolute Dating.pptx
Absolute Dating.pptx
 
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smid
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_SmidAuckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smid
Auckland Volcanic Field Olivine Research Poster for AGU Fall 2013_Smid
 
The physio chemical and mineralogical properties of mbaduku clay and its suit...
The physio chemical and mineralogical properties of mbaduku clay and its suit...The physio chemical and mineralogical properties of mbaduku clay and its suit...
The physio chemical and mineralogical properties of mbaduku clay and its suit...
 
INORG CHEM Cu-S Ist paper Prashant
INORG CHEM Cu-S Ist paper PrashantINORG CHEM Cu-S Ist paper Prashant
INORG CHEM Cu-S Ist paper Prashant
 
Nanochemistry presentation final
Nanochemistry presentation finalNanochemistry presentation final
Nanochemistry presentation final
 
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
 
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...Synthesis, characterization and electrocatalytic activity of silver nanorods ...
Synthesis, characterization and electrocatalytic activity of silver nanorods ...
 
Characterization of Archaeological Ceramic Materials Collected from Recently ...
Characterization of Archaeological Ceramic Materials Collected from Recently ...Characterization of Archaeological Ceramic Materials Collected from Recently ...
Characterization of Archaeological Ceramic Materials Collected from Recently ...
 
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...
Spectroscopic studies on Mn2+ ions doped Cadmium Aluminum Fluoro Lead Borate ...
 
Characterization of cobalt oxide and calcium aluminum
Characterization of cobalt oxide and calcium aluminumCharacterization of cobalt oxide and calcium aluminum
Characterization of cobalt oxide and calcium aluminum
 
416403a
416403a416403a
416403a
 
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...
74.three digestion methods to determine concentrations of cu, zn, cd, ni, pb,...
 

Plus de bueno buono good

Complete patents nikola_tesla
Complete patents nikola_teslaComplete patents nikola_tesla
Complete patents nikola_teslabueno buono good
 
Global energy transmittion tesla tower 2014
Global energy transmittion tesla tower 2014Global energy transmittion tesla tower 2014
Global energy transmittion tesla tower 2014bueno buono good
 
Wikileaks secret-tpp-treaty-ip-chapter
Wikileaks secret-tpp-treaty-ip-chapterWikileaks secret-tpp-treaty-ip-chapter
Wikileaks secret-tpp-treaty-ip-chapterbueno buono good
 
Farmaci coinvolti traffici_illegali_14.08.2014
Farmaci coinvolti traffici_illegali_14.08.2014Farmaci coinvolti traffici_illegali_14.08.2014
Farmaci coinvolti traffici_illegali_14.08.2014bueno buono good
 
Country reports on_terrorism_2013-7
Country reports on_terrorism_2013-7Country reports on_terrorism_2013-7
Country reports on_terrorism_2013-7bueno buono good
 
Bohemian grove-members-list 2010
Bohemian grove-members-list 2010Bohemian grove-members-list 2010
Bohemian grove-members-list 2010bueno buono good
 
Bohemian grove-and-other-retreats1
Bohemian grove-and-other-retreats1Bohemian grove-and-other-retreats1
Bohemian grove-and-other-retreats1bueno buono good
 
Cremation of care traduzione italiano
Cremation of care traduzione italianoCremation of care traduzione italiano
Cremation of care traduzione italianobueno buono good
 
Bohemian grove special spy magazine (november-1989)
Bohemian grove special   spy magazine (november-1989)Bohemian grove special   spy magazine (november-1989)
Bohemian grove special spy magazine (november-1989)bueno buono good
 
Synopsis reverby 'normal exposure'
Synopsis reverby 'normal exposure'Synopsis reverby 'normal exposure'
Synopsis reverby 'normal exposure'bueno buono good
 

Plus de bueno buono good (20)

Tesla confid
Tesla confidTesla confid
Tesla confid
 
Complete patents nikola_tesla
Complete patents nikola_teslaComplete patents nikola_tesla
Complete patents nikola_tesla
 
Global energy transmittion tesla tower 2014
Global energy transmittion tesla tower 2014Global energy transmittion tesla tower 2014
Global energy transmittion tesla tower 2014
 
Wikileaks secret-tpp-treaty-ip-chapter
Wikileaks secret-tpp-treaty-ip-chapterWikileaks secret-tpp-treaty-ip-chapter
Wikileaks secret-tpp-treaty-ip-chapter
 
Ttip draft
Ttip draftTtip draft
Ttip draft
 
2013 cpi brochure_en
2013 cpi brochure_en2013 cpi brochure_en
2013 cpi brochure_en
 
Farmaci coinvolti traffici_illegali_14.08.2014
Farmaci coinvolti traffici_illegali_14.08.2014Farmaci coinvolti traffici_illegali_14.08.2014
Farmaci coinvolti traffici_illegali_14.08.2014
 
Country reports on_terrorism_2013-7
Country reports on_terrorism_2013-7Country reports on_terrorism_2013-7
Country reports on_terrorism_2013-7
 
Doc 10502 290_en
Doc 10502 290_enDoc 10502 290_en
Doc 10502 290_en
 
Sipri yearbook 2013
Sipri yearbook 2013Sipri yearbook 2013
Sipri yearbook 2013
 
Bohemian grove-members-list 2010
Bohemian grove-members-list 2010Bohemian grove-members-list 2010
Bohemian grove-members-list 2010
 
Bohemian grove-and-other-retreats1
Bohemian grove-and-other-retreats1Bohemian grove-and-other-retreats1
Bohemian grove-and-other-retreats1
 
Cremation of care traduzione italiano
Cremation of care traduzione italianoCremation of care traduzione italiano
Cremation of care traduzione italiano
 
Bohemian grove special spy magazine (november-1989)
Bohemian grove special   spy magazine (november-1989)Bohemian grove special   spy magazine (november-1989)
Bohemian grove special spy magazine (november-1989)
 
Minsud 2014
Minsud 2014Minsud 2014
Minsud 2014
 
Piano nyc cigni 2014
Piano nyc cigni 2014Piano nyc cigni 2014
Piano nyc cigni 2014
 
Emp
EmpEmp
Emp
 
Porto trieste
Porto triestePorto trieste
Porto trieste
 
Ultimatum all'italia
Ultimatum all'italiaUltimatum all'italia
Ultimatum all'italia
 
Synopsis reverby 'normal exposure'
Synopsis reverby 'normal exposure'Synopsis reverby 'normal exposure'
Synopsis reverby 'normal exposure'
 

Journal reports discovery of biological structures in Sri Lankan meteorite

  • 1. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 THE POLONNARUWA METEORITE: OXYGEN ISOTOPE, CRYSTALLINE AND BIOLOGICAL COMPOSITION Jamie Wallis2, Nori Miyake1, Richard B. Hoover1, Andrew Oldroyd3, Daryl H. Wallis1, Anil Samaranayake4, K. Wickramarathne4, M.K. Wallis1, Carl H. Gibson1,5 and N. C. Wickramasinghe1† 1 Buckingham Centre for Astrobiology, University of Buckingham, Buckingham, UK 2 School of Mathematics, Cardiff University, Cardiff, UK 3 School of Earth and Ocean Sciences, Cardiff University. Cardiff, UK 4 Medical Research Institute, Colombo, Sri Lanka 5 University of California San Diego, La Jolla, CA, 92093-0411, USA Abstract: Results of X-Ray Diffraction (XRD) analysis, Triple Oxygen Isotope analysis and Scanning Electron Microscopic (SEM) studies are presented for stone fragments recovered from the North Central Province of Sri Lanka following a witnessed fireball event on 29 December 2012. The existence of numerous nitrogen depleted highly carbonaceous fossilized biological structures fused into the rock matrix is inconsistent with recent terrestrial contamination. Oxygen isotope results compare well with those of CI and CI-like chondrites but are inconsistent with the fulgurite hypothesis. Keywords: Polonnaruwa Meteorites, Carbonaceous Meteorites, Fulgurites, Diatoms, Comets, Panspermia 1. Introduction† numbers of slender cylinders of lengths 5 - 10μm, and a few micrometers in diameter were seen to be distributed A bright yellow fireball that turned green as it travelled extensively throughout the sample (Wickramasinghe et across the sky was observed by several eyewitnesses in al., 2013a). A separate sample was then sent to the United the North Central Province of Polonnaruwa, Sri Lanka at States, where it was investigated by one of us (RBH) 18:30 PM on December 29, 2012. The green fireball was using the Hitachi Field Emission Scanning Electron observed to disintegrate into sparkling fragments that fell Microscope. This independent study on a different sample to the ground near the villages of Aralaganwila and confirmed the presence of a range of diatom frustules, Dimbulagala and in a rice field (N 7 o 52’ 59.5” N; 81o 09’ some of which were embedded in the rock matrix. 15.7” E) near Dalukkane. The inferred NE to SW As a working hypothesis, we take the originating trajectory was determined from eyewitness observations bolide to be of mass <100kg with a final explosive break- and a distribution of stones recovered from a strewn field up occurring at about ~10km altitude, consistent with of >10 km. Police records indicate reports of low level sightings of the fireball over tens of km and the dispersal burn injuries from immediate contact with the fallen of stones. stones and subsequent reports of a strong aroma. One Initial examination of one stone indicated that it was woman was reported to have lost consciousness and was uniquely inhomogeneous and poorly compacted with transported to the hospital after inhaling fumes from one density less than 1g cm-3 i.e. less than all known of the stones. Witnesses reported that the newly fallen carbonaceous meteorites. The stone was predominantly stones had a strong odour of tar or asphalt. Local police black, though dark grey and grey regions could be officials responded immediately by collecting samples visually detected together with evidence of a partial and submitting them to the Medical Research Institute of fusion crust. CHN analysis indicates an average carbon the Ministry of Health in Colombo, Sri Lanka. content of the order of 1-4% and combined with GC-MS Preliminary optical microscopic studies of deep interior spectra showing an abundance of high molecular weight samples extracted from the stones revealed the presence organic compounds suggest tentative classification as a of a wide range of 10-40 µm-sized objects with a “carbonaceous chondrite ungrouped”. morphology characteristic of siliceous microalgae known as diatoms (Wickramasinghe et al., 2013a). 2. Samples A sample of the recovered stones was then sent to us at Cardiff University, where we conducted studies of freshly During the days and weeks that followed the initial cleaved interior surfaces using the Environmental collection of material in Polonnaruwa by local police Scanning Electron Microscope at the University’s School officials, large quantities of stone artifacts were recovered of Earth and Ocean Sciences. These studies resulted in a from the rice fields in the vicinity of Aralaganwila and number of images showing diatom frustules, some of submitted for analysis. These included substantial which were clearly embedded in the rock matrix, thereby quantities of stones recovered by the Department of excluding the possibility of post-arrival contamination. Geology, University of Peradeniya as well as 628 separate Other structures of various shapes including large fragments that were collected about a month later and subsequently submitted to us. The task of identifying † Author correspondence Professor N. C. Wickramasinghe broken fragments of meteorite from a mass of other Buckingham Centre for Astrobiology, mail: ncwick@gmail.com stones was not easy. Of the 628 pieces examined, only
  • 2. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 three were clearly identified as possible meteorites after comparison with the original stones collected on the 29th 300 December 2012. Of the samples rejected for further study, most were either, indigenous terrestrial stones, masonry 250 composites or by-products of industrial processes. In P159/001-04 200 addition to the above, a number of further samples were Counts/s collected by us during a site visit on the 29th January 150 2013. These fragments were visibly different to the rejected material: they showed evidence of a partial, 100 moderately thick fusion crust (0.25-0.5mm) with fractured 50 surfaces exhibiting a highly porous composite structure characteristic of a carbonaceous chondrite, with fine 0 grained olivine aggregates connected with mineral 0 10 20 30 40 50 60 70 intergrowths. These samples were stored in sealed glass 2 θ Degrees→ vials for later analysis. 300 For the purpose of this study, one of the original samples submitted by the Medical Research Institute in 250 Colombo was selected for analysis. This fragment was P159/001-03 200 portioned for interior section Scanning Electron Counts/s Microscopy (SEM), oxygen isotope analysis, 150 compositional analysis by X-Ray Diffraction (XRD) and elemental analysis by Inductively Coupled Plasma Optical 100 Emission Spectroscopy (ICP-OES). 50 In addition to the portioned fragment, a sample of sand fulgurite was also analysed for comparative purposes 0 together with a soil sample recovered from the fall site 0 10 20 30 40 50 60 70 2 θ Degrees→ and a further sample of calcium-rich terrestrial rock selected for control purposes. Preliminary oxygen and 2000 carbon isotope analysis of the calcium rich control sample produced values of δ13C = -9.716 ± 0.02 and δ18O = - 1600 6.488 ± 0.04 which accord well with the values for soil carbonates determined by T.E. Cerling and J. Quade, S159/001-05 Counts/s 1200 1993. 800 Sample ID Origin Description 400 D159/001-01 Dambulla, Sri Lanka Soil Carbonate 0 F159/001-02 Sahara Desert Fulgurite 0 10 20 30 40 50 60 70 P159/001-03 Aralaganwila, Sri Lanka Witnessed Fall 2 θ Degrees→ P159/001-04 Aralaganwila, Sri Lanka Witnessed Fall 1000 S159/001-05 Aralaganwila, Sri Lanka Soil Sample 800 Table 1 Details of samples analysed D159/001-01 Counts/s 600 400 3. X-Ray Diffraction Analysis 200 X-Ray Diffraction was carried out using a Philips PW1710 Automated Powder Diffractometer using Cu Kα 0 radiation at 35kV and 40mA, between 2 and 70 o2θ at a 0 10 20 30 40 50 60 70 scan speed of 0.04o 2θ/s. From the scans, phases were 2 θ Degrees→ identified using PC-Identity software and from the peak areas, semi-quantitative analysis was performed and Figure 1. Shows X-Ray Diffraction patterns (counts/s against 2θ percentage of each phase calculated. Each of the four degrees) for samples P159/001-04, P159/001-03, S159/001-05 (soil) samples provided for analysis were powdered, mixed with and D159/001-01 (control). The broad humps displayed in samples a small amount of acetone and pipetted out onto glass P159/001-04 and P159/001-03 are due to bulk composition of slides. Sample preparation and analysis was conducted at amorphous silica of (between 85-95%). The three crystaline phases the School of Earth Sciences at Cardiff University. detected are quartz (between 3-10%) together with anorthite (1-3%) and cristobaloite (approximately 2% in each sample).
  • 3. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 X-Ray Diffraction patterns for the selected samples Data are reported relative to SMOW. Error bars are P159/001-04, P159/001-03, S159/001-05 and D159/001- about ± 0.1 ‰ for 17O and 18O and about ± 0.01 ‰ or 01 (control) are represented in Figure 1. The broad hump better for Δ17O. The reference gas was analysed relative displayed in P159/001-03 and P159/001-04 at ~18-36O 2θ to SMOW calibrated O2 by E. Barkan (Hebrew University corresponds to a bulk composition of amorphous silica. of Jerusalem). All values are permil unless otherwise P159/001-03, P159/001-04 and S159/001-05 all stated. display strong features at 20.8 2θ reported to be that of Results are presented in δ-notation such that: crystalline quartz. A strong feature at ~21.8 2θ in δxOVSMOW /1000 = [(xO/16O)sample / (xO/16O)VSMOW] - 1. We P159/001-04 was reported as (NaK)AlSi3O8 use a slope of 0.5251 for the terrestrial fractionation line (anorthoclase) with further features in the 42-46 2θ range and linearized form of the δ-notation so that Δ17O = δ17O attributed to the presence of the silica polymorph – 0.5251 δ18O. Error has been established through cristobalite. P159/001-03 also reported the presence of observation of the standard deviation in 290 single NaAlSi3O8 (albite). Further weak but distinct peaks were analyses of terrestrial rocks and minerals, carried out in noted at ~33.32 and 35.72 2θ in P159/001-04 with 30 sessions at this stable isotope laboratory using the corresponding peaks at ~33.32, ~54.30 and ~35.72 2θ in same equipment and is reported as +/- 0.06‰ (A. Gehler P159/001-03 which is most likely due to the presence of et al, 2011). Fe2O3 (hematite). Additional features at ~28.83 2θ in both P159/001-03 and P159/001-04 may be due to the presence of coesite. A weak feature at ~60.5 2θ suggests possible 12 11.59 inclusions of stishovite but corresponding features at 11.58 30.18 and 45.76 2θ could not be determined with 11 10.94 certainty and further work will be required to confirm δ O (‰ rel. SMOW) 10.91 this. 10 S159/001-05 (soil) reported the expected presence of 9.23 approximately 75% quartz, 17% KAlSi3O8 (microcline), 9 8.79 P159/001-03 4% (NaK)AlSi3O8, 3% Al2Si2O5(OH)4 (kaolinite) and 1% Polonnaruwa 17 opal. Results reported for the control sample D159/001-01 8.6 8 were consisted with the available literature on soil carbonates comprising of 81% calcite, 13% quartz, 4% ankerite and 2% anorthite. 7 15 16 17 18 19 20 21 22 23 18 4. Triple Oxygen Isotope Analysis δ O (‰ rel. SMOW) Triple oxygen isotope analyses were conducted in the Figure 2. Oxygen isotope compositions of sample P159/001-04 stable isotope laboratory at the University of Göttingen, and of CI chondrites: Alais (8.6), Ivuna (9.23) and Orgueil Germany. Approximately 2mg of crushed sample was (8.79) together with CI-like chondrites (Meta-C) B-7904 placed inside a Ni sample holder, evacuated overnight and (10.91), Y-82162 (11.59), Y-86720 (11.58) and Y-86789 heated to 70°C for 12h. An infrared (IR) laser (50W CO2 (10.94). Data from Clayton and Mayeda, 1998. laser, λ = 10.6µm) was used to fluorinate the samples in purified F2 gas under pressures of approximately 20 mbar. Sample O2 was purified through the removal of excess F2 0.5 by reaction with NaCl at 110°C to form NaF. Cl2 gas was collected at a cold trap at -196°C. Sample oxygen was CI +0.417 ± 0.05 Δ O (‰ rel. SMOW) then collected at a 5Å molecular sieve at -196°C, 0.25 MFL +0.301 ± 0.013 expanded into a stainless steel capillary, transported with He carrier gas and re-trapped before release at 92°C 0 Terrestial Fractionation Line through a 5Å molecular sieve GC-column of a Thermo Scientific GasBench II. The GC column was utilised to MC -0.055 ± 0.005 EFL -0.239 ± 0.007 separate interfering NF3, from O2, as required for analysis -0.25 17 of 17O (Pack et al, 2008). The resulting purified sample O2 POL -0.335 0.011 was then expanded to the dual inlet system of a Thermo -0.5 MAT 253 gas mass spectrometer. Results are presented in 0 5 10 15 20 25 δ- and Δ17O-notation. 18 δ O (‰ rel. SMOW) δ17O 8.978 ± 0.050 Figure 3. Oxygen isotope Δ17O (‰ rel. SMOW) values of δ18O 17.816 ± 0.100 sample P159/001-04 (POL). Data for MFL: martian Δ17O -0.335 ± 0.011 fractionation from Franchi et al. 1999. EFL: eucrite fractionation from Greenwood et al., 2005. CI: fractionation line for CI1 chondrites and MC: fractionation of Meta-C chondrites (B-9704 Table 2. Results of Oxygen Isotope Analysis and Y-86789) from Clayton at al., 1998.
  • 4. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 Results of analysis are displayed in Table 2, showing 2000 Δ17O = - 0.335. Figure 2 shows a plot of δ 17O/ δ18O C values compared to those of known CI chondrites as 1600 reported by Clayton and Mayeda, 1998. It is noted that Spectrum S1 Relative Intensity δ18O values are relatively high but are within the range of 1200 the CI1 carbonaceous meteorites (Alais, Ivuna and Orgueil) and the CI-like and CM-like MCC 800 O (Metamorphosed Carbonaceous Chondrite) members on Si the new Meta-C group. Meteorites of the Meta-C group 400 Al have been thermally metamorphosed on their parent body Mg K Ca and have low water content and IR spectra indicating 0 dehydration of their matrix phyllosilicates, very similar to 0 1 keV 2 3 4 5 our samples. Although the Meta-C meteorites somewhat 2400 resemble CI and CM carbonaceous chondrites, they are O relatively depleted in Iron and Sulfur as compared to the 2000 Si Spectrum S2 Relative Intensity CI and CM stones. The Meta-C meteorites show 1600 comparatively young Cosmic Ray Exposure (CRE) ages suggesting a near Earth asteroid as their common parent 1200 Al body. They have been recovered from Antarctica (Belgica-7904, Yamato 82162, Yamato 86720, and 800 Yamato 86789) and the desert of Oman (Dhofar 225 and 400 Dhofar 735 (Ikeda, 1992; (Ivanova et. al. 2002; Tameoka, C K Mg Ca 1990). The Meta-C meteorites show common Oxygen 0 0 1 keV 2 3 4 5 isotopic compositions that are entirely distinct from the Oxygen isotopic composition of CI1 and the CM1 and 2000 CM2 carbonaceous chondrites. O Si 1600 Relative Intensity 5. Scanning Electron Microscopy Spectrum S3 1200 Al Scanning Electron Microscopy (SEM) was conducted using the FEI (Phillips) XL30 FEG ESEM 800 (Environmental Scanning Electron Microscope) FEG C (Field Emission Gun) at the School of Earth Sciences at 400 Cardiff University. The unit incorporates a secondary Mg K Ca electron detector (SE), a back scatter electron detector 0 (BSE) and a gaseous secondary electron detector (GSE). 0 1 keV 2 3 4 5 It also has an Oxford Instruments INCA ENERGY (EDX) x-ray analysis system. Figure 5 Energy Dispersive X-ray analysis (EDX) results for the three points S1, S2 and S3 as displayed in Figure 4 Spec S1 S2 S3 Max Min C 59.81 29.26 0.00 59.81 0.00 S2 N 0.00 5.11 0.00 5.11 0.00 O 31.3 44.98 60.53 60.53 31.3 S3 Mg 0.34 0.42 0.00 0.42 0.34 S1 Al 2.11 6.68 12.15 12.15 2.11 Si 3.55 9.98 20.91 20.91 3.55 P 0.00 0.23 0.00 0.23 0.23 S 0.00 0.00 0.33 0.33 0.33 K 1.38 1.47 2.14 2.14 1.38 Ca 1.04 0.42 0.53 1.04 0.42 Ti 0.00 0.00 0.57 0.57 0.57 Fe 0.47 1.45 2.84 2.84 0.47 Figure 4 Shows a highly carbonaceous partially degraded biological structure. Note the apparent fracture from the surrounding mineral matrix along the leading edge. Points S1, Table 3 Elemental abundances as detected by energy X-ray S2 and S3 correspond to elemental abundances determined by analysis for points S1, S2 and S3 as displayed in Figure 4 EDX as detailed in Table 2 and Figure 5
  • 5. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 140 C 120 Spectrum S1 Relative Intensity 100 Au 80 (b) 60 O P 40 Pd (c) 20 0 0 1 2 keV 3 4 5 S1 50 Fig. 6(a) Au 40 Spectrum S2 Relative Intensity 30 P 20 Si Mg Pd O 10 C Al 0 0 1 2 3 4 5 keV 250 C 200 Spectrum S3 Relative Intensity Fig. 6(b) 150 Au 100 S2 O 50 Pd Al 0 0 1 2 3 4 5 keV Figure 7. Energy X-ray analysis (EDX) results for the three points S1, S2 and S3 as displayed in Figure 6. Gold and S3 Paladium readings are a result of sample coating. Spec S1 S2 S3 Mean SD Max. Fig. 6(c) C 67.94 0.00 65.73 44.56 38.60 67.94 Figure 6 (a-c) show images of a large (100 µm diameter) and N 0.00 0.00 0.00 0.00 0.00 0.00 very complex, thick-walled, carbon-rich (kerogenous) O 26.21 39.82 24.80 30.28 8.29 39.82 microfossil that we have tentatively identified as a Na 0.00 0.00 0.00 0.00 0.00 0.00 hystrichosphere. Hystrichospheres are thought to be associated Mg 0.00 13.02 0.00 4.34 7.52 13.02 with the resting stages of a group of largely extinct marine Al 0.00 10.35 0.00 3.45 5.98 10.35 dinoflagellate algae. The EDX data reveals a lack of detectable Si 0.00 36.81 2.17 12.99 20.66 36.81 nitrogen and an anomalous C/O ratio (similar to bitumen) P 0.00 0.00 0.00 0.00 0.00 0.00 clearly establishing that this obviously biological form could not S 0.00 0.00 0.00 0.00 0.00 0.00 possibly represent a modern biological contaminant. The K 5.85 0.00 7.29 4.38 3.86 7.29 extremely well-preserved and very thin (2 µm diameter x 100 Ca 0.00 0.00 0.00 0.00 0.00 0.00 µm long) flagella are interpreted as indicating a low-gravity, low-pressure environment and rapid freeze-drying. In the Fe 0.00 0.00 0.00 0.00 0.00 0.00 vicinity of this form are highly carbonaceous embedded filaments of cyanobacteria (“blue-green algae”). Low nitrogen shows they are ancient fossils. Points S1, S2 and S3 relate to Table 4. Elemental abundances as detected by energy X-ray target corordinates of energy X-ray readings detailed in Figure 7 analysis for points S1, S2 and S3 as displayed in Figure 6. (Au and Table 4. The sample was coated with a gold/palladium and Pd subtracted). surface to facilitate high resolution image capture.
  • 6. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 Image recording is via a SONY video graphics printer or Furthermore, none of the Polonnaruwa meteorites digital by processing image frames in a 16 bit framestore studied are in the form of hollow tubes, which is a well- computer for output to hard drive. known common characteristic of fulgurites. Additionally, Sample preparation involved the use of a flame due to the method in which they form, fulgurites typically sterilised wide-bore hypodermic needle to fracture the have to be dug out of the soil. In contrast, the fragments before mounting on aluminium stubs. Further Polonnaruwa stones were found lying on the surface of SEM studies were conducted at the NASA Marshall undisturbed sandy soil in a rice field. The eyewitnesses Space Flight Centre using uncoated freshly fractured reported that there was no lightning activity in this region surfaces that were examined using a Hitachi S-3700N on the night of Dec. 29, 2012. To have produced such a Field Emission Scanning Electron Microscope with large number of stones as have been found in a small field images gathered using both the Back-Scatter Electron would have required cloud to ground lightning strikes and the Secondary Electron detectors. many orders of magnitude greater than ever before Preliminary inspection of a few of the SEM images reported. In addition, the temperature at which sand must revealed the presence of a number of highly carbonaceous be heated by lightning to melt and form a fulgurite (1770 biological structures. Some of these were deeply C) would certainly have vaporized and burned all carbon- integrated in the surrounding mineral matrix indicating rich biological (cyanobacterial filaments, they could not have been recent biological contaminants. hystrichospheres, etc.) and melted and thus destroyed the EDX data indicates they are severely depleted in nitrogen delicately marked silica frustules of the diatoms. (N < 0.5%). Hoover (2007) explored the use of Nitrogen Subsequent suggestions that an “unusually porous” levels and biogenic element ratios for distinguishing fulgurite may have floated in on water ignores the fact between modern and fossil microorganisms as a that many of these low-density (<1 g cm-3) stones were mechanism for recognizing recent biological recovered between Dec. 29, 2012 and Jan. 29, 2013 and contaminants in terrestrial rocks and meteorites. found to exhibit similar mineralogy, morphology, Detectable (2-18%) levels of Nitrogen were encountered physical and microbiological properties. None of these in the hair and tissues from mummies from Peru (2 Kyr) original stones studied at Cardiff University or at the and Egypt (5 Kyr) and the hair/tissues of Pleistocene NASA Marshall Space Flight Center were observed to be Wooly Mammoths (40-32 Kyr). Comparative studies on hollow tubes and none were found to be composed of the fossilized insects in Miocene (8.4 Myr) Amber, mineral lechatelierite. The “floating on water” hypothesis Cretaceous Ammonites (100 Myr), Cambrian trilobites of is also inconsistent with FTIR data obtained using Wheeler Shale of Utah (505 Myr) and filamentous diamond ATR instrumentation that show a conspicuous cyanobacteria from Karelia (2.7 Gyr) showed nitrogen absence of a characteristic water peak (Wickramasinghe levels below the limit of detection with the FESEM EDS et al, 2013c). This observation alone appears to rule out detector (N < 0.5%). This provides clear and convincing the likelihood of aqueous-based contaminants being evidence that these obviously ancient remains of extinct responsible for the presence of observed diatom frustules marine algae found embedded in the Polonnaruwa in either a non-terrestrial fragment or a formerly sterile meteorite are indigenous to the stones and not the result of terrestrial fulgurite. post-arrival microbial contaminants. Finally, the results of triple-oxygen isotope analysis presented here give a Δ17O value of - 0.335. This result, 6. Discussion together with previous studies on the oxygen isotope composition of fulgurites (Robert and Javoy, 1992) that Results of initial studies on the Polonnaruwa stones were find no marked isotope exchange with atmospheric reported in a series of short bulletins in the Journal of molecular oxygen during the formation process provides a Cosmology during the early part of 2013 strong case against the fulgurite conjecture. (Wickramasinghe et al, 2013a, 2013b, 2013c, 2013d). A We are aware that a large number of unrelated stones number of critical observations followed relating to the have been submitted for analysis, and we have no direct possible terrestrial origin of the stones as well as information or knowledge regarding the nature, source, terrestrial contaminants being the most likely explanation origin or provenance of the stones our critics have for the observations. Critics also pointed to the unusual examined. Based upon the physical, chemical, isotopic, bulk composition of the stone (i.e. amorphous SiO2), the mineralogical and microbiological studies that we have presence of some crystalline phases of SiO2 (quartz), the performed, we are certain that the Polonnaruwa stones low density (<1g cm-3) and the potential unreliability of submitted to us for examination by the Medical Research eye witness reports. The hypothesis that the stones Institute in Sri Lanka and the stones that we recovered comprise of terrestrial fulgurite, the glassy product of from the rice field (7 o 52’ 59.5” N; 81 o 9’ 15.7” E) on tubes formed when quartzose sand, silica, or soil is heated Jan. 29, 2013 were not fulgurites, scoria, lava, pumice or by lightning strikes was suggested. However, the fulgurite the product of industrial processes. hypothesis is readily disproved by the fact that the The presence of a number of carbonaceous biological mineral lechatelierite (which comprises fulgurites) has an structures exhibiting severe nitrogen depletion is highly average density of 2.57 g cm-3, whereas the density of the indicative of ancient fossilised biological remains. Some Polonnaruwa meteorites is <1 g cm-3. of these were deeply integrated in the surrounding mineral matrix suggesting they could not have been recent
  • 7. Journal of Cosmology, Vol. 22, No. 2 published, 5 March 2013 terrestrial contaminants. The presence of these structures Ikeda Y. An overview of the research consortium, “Antarctic may have further implications since diatoms are known to carbonaceous chondrites with CI affinities, Yamato-86720, be unable to break the strong triple bond of the inorganic Yamato-82162, and Belgica-7904.” Proc. NIPR Symp. di-nitrogen (N2) molecule and convert it into the organic Antarct. Meteorites, 5, 49–73, (1992). Ivanova M. A., Taylor L. A.., Clayton R. N., Mayeda T. K., nitrogen. Nitrogen in molecules such as NO2 or NH3 can Nazarov M. A., Brandstaetter F., and Kurat G., Dhofar 225 be readily used for the construction of amino acids, vs. the CM clan: Metamorphosed or new type of proteins, DNA, RNA and other life-critical biomolecules. carbonaceous chondrite? (abstract). In Lunar and Planetary The function of nitrogen-fixation is carried out by the Science XXXIII, Abstract #1437. Lunar and Planetary nitrogenous enzyme that is housed in structures known as Institute, Houston, (2002). heterocysts of several species of several genera (Nostoc Pack, A., 2008, Fractionation of refractory lithophile elements in Tolypothrix, etc.) of heterocystous cyanobacteria. bulk chondrites and chondrite components. Lunar and Consequently, cyanobacteria are considered a crucial Planetary Science Conference, Houston. component of a cometary ecosystem. Robert, F., and Javoy, M., 1992, Oxygen Isotope Compositions of Fulgarites, Meteoritics 27 (1992): 281. We conclude that the oxygen isotope data show Tameoka, K. 1990. Mineralogy and Petrology of Belgica-7904: P159/001-03 and P/159001-04 are unequivocally A New Kind of Carbonaceous Chondrite from Antarctica. meteorites, almost certainly fragments originating from Proc. NIPR Symp. Antarct. Meteorites. 3, 40-54, 1990. the fireball-causing bolide. The most likely origin of this Wickramasinghe, N.C., Wallis, J., Wallis, D.H., Samaranayake, low density meteorite with delicate structures, some A., 2013a. Fossil diatoms in a new carbonaceous meteorite, highly carbonaceous, is a comet (Wickramasinghe et al., Journal of Cosmology, 21, 37. 2013b). The presence of fossilized biological structures Wickramasinghe, N.C., Wallis, J., Wallis, D.H., Wallis M.K., Al- provides compelling evidence in support of the theory of Mufti, S., Wickramasinghe, J.T., Samaranayake, A. and cometary panspermia first proposed over thirty years ago Wickramarathne, K., 2013b. On the cometary origin of the Polonnaruwa meteorite, Journal of Cosmology, 21, 38. (Hoyle and Wickramainghe, 1981, 1982, 2000). Wickramasinghe, N.C., Wallis, J., Miyake, N., Wallis D.H., Samaranayake, A., Wickramarathne, K., Hoover, R., and Acknowledgement Wallis M.K., 2013c. Authenticity of the life-bearing Polonnaruwa meteorite, Journal of Cosmology, 21, 39. We are grateful to Professor Andreas Pack of the Wickramasinghe, N.C., Samaranayake, A., Wickramarathne, K., University of Göttingen, Germany for his assistance with Wallis, D.H., Wallis M.K., Miyake, N., Coulson, S.J., the Triple Oxygen Isotope analysis. Hoover, R., Gibson, C.H., and Wallis, J.H., 2013d, Living Diatoms in the Polonnaruwa meteorite – Possible link to red and yellow rain, Journal of Cosmology, 21, 40. REFERENCES Cerling, T. E., and Quade, J., 1993, Stable Carbon and Oxygen Isotopes in Soil Carbonates, In P.K. Swart, K.C. Lohmann, J.A.McKenzie, and S.M.Savin, eds., Climate Change in Continental Isotope Records, pp217-231. Clayton, R. N., and Mayeda, T. K., 1999, Oxygen Isotope Studies of carbonaceous chondrites, Geochimica et Cosmochimica Acta, Vol 63, No 13/14 pp2089-2104. Franchi, I.A., Wright, I.P., Sexton, A.S., and Pillinger, C.T. 1999, The oxygen isotope composition of Earth and Mars, Meteoritics & Planetary Science 34, pp657-661. Gehler, A., Tütken, T., and Pack, A., 2011, Triple oxygen isotope analysis of bioapatite as tracer for diagenetic alteration of bones and teeth, Palaeogeography, Palaeoclimatology, Palaeoecology, Vol 310, 1-2 pp 84-91. Greenwood R.C., Franchi I.A., Jambon A. and Buchanan P.C. (2005) Widespread magma oceans on asteroidal bodies in the early solar system. Nature 435, 916-918. Hoover, R. B., 2007, Ratios of Biogenic Elements for Distinguishing Recent from Fossil Microorganisms. Instruments, Methods, and Missions for Astrobiology X, Proc. SPIE 66940D. Hoyle, F. and Wickramasinghe, C., “Proofs that Life is Cosmic”, Memoirs of the Institute of Fundamental Studies, Sri Lanka, No. 1, Dec 1982. Hoyle, F. and Wickramasinghe, N.C., 1981. “Comets - a vehicle for panspermia”, in Comets and the Origin of Life, ed. C. Ponnamperuma, D. Reidel Publishing Co. Dordrecht. Hoyle, F. and Wickramasinghe, N.C., 2000. “Astronomical Origins of Life – Steps towards panspermia” (Kluwer Academic Publishers, Dordrecht).