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Proprietary and Confidential            ©2009 EcoSense
•   EcoSense International Inc. formed in 2000
•   EcoVaultTM , The Next Generation Baffle Boxes
•   EcoSenseTM, Inlet Insert Filtration and Debris Collection
•   Oxy-ProTM, Environmental Redox Chemistry (Nitrate Reduction)
•   Smart GrowTM, Environmentally Sound Fertilization and Weed Control
•   Vault-OxTM, Static Stormwater Remediation Chemistry
Vault-Ox™




                                                Net 20 lbs.
                                                Contains (4) 5 lb. packets
Keep material dry. Store in a cool dry place.
Do not store or expose to heat sources. For
more information see Material Safety Data
Sheet.
Interevent Water Quality in Manufactured BMP’s


•   Strynchuk, Royal and England, 1999 Reported “the majority of organic-based
    pollutants, which leach from grass clippings and leaves into water will be
    released within 1 to 22 days…BOD peaked at 9 days…most of the phosphorus
    was released in the first day…”
•   Marino and Gannon, 1991 Tested storm drain sediments during dry weather
    periods and found “Extended bacterial survival in sediments to survival in
    water…FC and FS in sediments remained stable for up to 6 days (the maximum
    inter-storm dry period).”
•   GPI Southeast, in the Final Report – Baffle Box Effectiveness Monitoring Project,
    2010 reports “net exports of fecal coliforms and anaerobic conditions…” and
    suggest “probable causes for FC growth in baffle boxes are the interevent
    anaerobic conditions…” and point out “…use of any water storing box can lead
    to increased FC counts to water bodies”.
Introducing Static Stormwater
Remediation Chemistry                     SSRC
                                    Vault-Ox™
  Improves Dissolved Oxygen
  Sequester Phosphates
  Elevates pH
  Absorbs Nitrogen
  Promotes Oxidation of Organics
  Enhances Aerobic Activity
  Lowers COD/BOD
  Affordable and lasting
 Patented dry chemical containing
Vault-Ox™     calcium and oxygen
             Practically insoluble but slowly
              degrades to release oxygen

             Sequesters phosphate: precipitates as
              CaPO4 or FePO4

             Improves aerobic bioremediation
             Raises pH to alkaline state:
                Keeping metals out of solution
             Stormwater quality structures
             Underground water storage
             Ponds
             Ground water remediation
Properties of Vault-Ox™ Granules
  Appearance              Yellowish white granules
  Composition             CaO2 and additives
  Calcium peroxide (%)    70% min
  Available oxygen (%)    15.5% min
  Metal impurities        Meets Food Chemicals Codes
  Particle size (90%)     ~ 500-2000µ
                           7.5
  pH (0.05% suspension)
Chemistry of Vault-OxTM in Water
 At natural pH – very slow decomposition generating
  oxygen and lime
  2 CaO2 + 2 H2O         2 Ca(OH)2 + O2

 Rate of oxygen generation depends upon
    Product characteristics - particle size, formulation,
     etc.
    Environmental conditions - water quality, pH,
     agitation, concentration, etc.
Vault-OxTM
             A source of Alkalinity

 Increases the formation of calcite and apatite
    This increases the P-binding capacity of calcium
 Reduces free H2S concentrations
 Formulation buffers and regulates pH
 Counters acid rain
 Prevents acidification of water when sulfides are
  oxidized
 Maintains heavy metals in an immobilized oxidized
  state
Chemistry of Vault-Ox™ in Acid

 In buffered systems at lower pH, CaO2 dissolves faster and
  produces progressively increasing amounts of H2O2

  CaO2 + 2H+        Ca2+ (aq) + 2H2O2

  Ca(OH)2 + 2H+        Ca2+ (aq) + 2H2O
SRP Removal Efficiency
                                      Vault-oxTM vs. Aeration
           140

                     CaO2
           120       Aeration
                     Anoxic
           100


           80
P (mg/L)




           60


           40


           20


            0
                 0                5           10                 15      20      25

                                                   Time (Days)
                                Treatment done after 15 days of incubation


                            Zhang et al, Water Science & Tech., 50, 173 (2004)
Effect of CaO2 on BOD, Organic C and N
      100
% Removal




        50                                                  w/ CaO2
                                                            w/o CaO2




             BOD              Organic C             Organic N
              (Hanh et al, Env. Tech.), 26, 581 (2005)
Retention Pond – Before Treatment
Retention Pond – 6 Weeks Later
2lb/acre.ft CaO2 + Enzymes
8
                                                                                    10




                               0
                                                                    6
                                                                                9




                                   1
                                                                5

                                                  4




                                       2
                                           3
                                                                        7
                   3/26/2010
                   3/28/2010
                   3/30/2010
                    4/1/2010
                    4/3/2010
                    4/5/2010
                    4/7/2010
                    4/9/2010
                   4/11/2010
                   4/13/2010
                   4/15/2010
                   4/17/2010
                   4/19/2010
                   4/21/2010
                   4/23/2010
                   4/25/2010
                   4/27/2010
                   4/29/2010
                    5/1/2010
                    5/3/2010
                    5/5/2010




New Water Sample
                    5/7/2010
                    5/9/2010
                   5/11/2010
                   5/13/2010
                   5/15/2010
                   5/17/2010
                   5/19/2010
                   5/21/2010
                   5/23/2010
                   5/25/2010
                                                         Test
                                               Control
7.50



                                                              7.00
                                                                                                           9.50




                                                       6.50
                                                                                                    9.00




                                                6.00
                                                                                             8.50



                                                                                      8.00
                                        40263
                                        40265
                                        40267
                                        40269
                                        40271
                                        40273
                                        40275
                                        40277
                                        40279
                                        40281
                                        40283
                                        40285
                                        40287
                                        40289
                                        40291
                                        40293
                                        40295
                                        40297
                                        40299
                                        40301
                                        40303




         New Water Sample
                                        40305
                                        40307
                                        40309
                                        40311
                                        40313
                                        40315
control


                                        40317
                                        40319
                                                                                                                  pH




                                        40321
                                        40323
                                                                               Test
                                                                     Control




Note: The sample water contains high
amounts of sulfur, forming H2S in the
Vault Ox™
can be added
to a chamber
as free
granules or
in an easily
retrofit
perforated
tubing and
mesh
system.
Addition of VaultOx™ with natural Z-100 have desirable
selctive ion exchange and absorption properties that be
used in the removal of:
•Ammonia from wastewater/stormwater
•Heavy Metals from industrial process,waste and
stormwaters
•Effective in the adsorption of aluminum, antimony,
arsenic, barium, cadmium, chromium, colbalt, copper, iron,
lead, magnesium, manganese, mercury and nickel
Control 4/21/2010   Sample with Vault Ox 4/21/2010




Coliforms: purple-blue
E. coli: pink
non-Coliform: colorless
Control 4/25/2010   Sample with VaultOx, Four day treatment
Safety and Handling
  Vault-oxTM Granules is classified as a 5.1 Oxidizer -
   Packing group II
    All individuals who handle the product for shipping
     need DOT training (including those who prepare
     paperwork)
  Keep containers closed, dry and away from direct
   sunlight and sources of heat
  Decomposition agents include moisture, dirt,
   organic matter, reducing agents, acids
Health Hazards
 Most health hazards come from direct skin contact
 and inhalation of dust

 Wear personal protective equipment
   Dustproof chemical goggles
   Impervious protective gloves
   Avoid breathing dust
   Avoid skin contact
www.EcoSenseInt.com




     Info@ecosenseint.com

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EcoSense International, Inc. VaultOx

  • 1. Proprietary and Confidential ©2009 EcoSense • EcoSense International Inc. formed in 2000 • EcoVaultTM , The Next Generation Baffle Boxes • EcoSenseTM, Inlet Insert Filtration and Debris Collection • Oxy-ProTM, Environmental Redox Chemistry (Nitrate Reduction) • Smart GrowTM, Environmentally Sound Fertilization and Weed Control • Vault-OxTM, Static Stormwater Remediation Chemistry
  • 2. Vault-Ox™ Net 20 lbs. Contains (4) 5 lb. packets Keep material dry. Store in a cool dry place. Do not store or expose to heat sources. For more information see Material Safety Data Sheet.
  • 3. Interevent Water Quality in Manufactured BMP’s • Strynchuk, Royal and England, 1999 Reported “the majority of organic-based pollutants, which leach from grass clippings and leaves into water will be released within 1 to 22 days…BOD peaked at 9 days…most of the phosphorus was released in the first day…” • Marino and Gannon, 1991 Tested storm drain sediments during dry weather periods and found “Extended bacterial survival in sediments to survival in water…FC and FS in sediments remained stable for up to 6 days (the maximum inter-storm dry period).” • GPI Southeast, in the Final Report – Baffle Box Effectiveness Monitoring Project, 2010 reports “net exports of fecal coliforms and anaerobic conditions…” and suggest “probable causes for FC growth in baffle boxes are the interevent anaerobic conditions…” and point out “…use of any water storing box can lead to increased FC counts to water bodies”.
  • 4. Introducing Static Stormwater Remediation Chemistry SSRC Vault-Ox™  Improves Dissolved Oxygen  Sequester Phosphates  Elevates pH  Absorbs Nitrogen  Promotes Oxidation of Organics  Enhances Aerobic Activity  Lowers COD/BOD  Affordable and lasting
  • 5.  Patented dry chemical containing Vault-Ox™ calcium and oxygen  Practically insoluble but slowly degrades to release oxygen  Sequesters phosphate: precipitates as CaPO4 or FePO4  Improves aerobic bioremediation  Raises pH to alkaline state:  Keeping metals out of solution  Stormwater quality structures  Underground water storage  Ponds  Ground water remediation
  • 6. Properties of Vault-Ox™ Granules  Appearance Yellowish white granules  Composition CaO2 and additives  Calcium peroxide (%) 70% min  Available oxygen (%) 15.5% min  Metal impurities Meets Food Chemicals Codes  Particle size (90%) ~ 500-2000µ 7.5  pH (0.05% suspension)
  • 7. Chemistry of Vault-OxTM in Water  At natural pH – very slow decomposition generating oxygen and lime 2 CaO2 + 2 H2O 2 Ca(OH)2 + O2  Rate of oxygen generation depends upon  Product characteristics - particle size, formulation, etc.  Environmental conditions - water quality, pH, agitation, concentration, etc.
  • 8. Vault-OxTM A source of Alkalinity  Increases the formation of calcite and apatite  This increases the P-binding capacity of calcium  Reduces free H2S concentrations  Formulation buffers and regulates pH  Counters acid rain  Prevents acidification of water when sulfides are oxidized  Maintains heavy metals in an immobilized oxidized state
  • 9. Chemistry of Vault-Ox™ in Acid  In buffered systems at lower pH, CaO2 dissolves faster and produces progressively increasing amounts of H2O2 CaO2 + 2H+ Ca2+ (aq) + 2H2O2 Ca(OH)2 + 2H+ Ca2+ (aq) + 2H2O
  • 10. SRP Removal Efficiency Vault-oxTM vs. Aeration 140 CaO2 120 Aeration Anoxic 100 80 P (mg/L) 60 40 20 0 0 5 10 15 20 25 Time (Days) Treatment done after 15 days of incubation Zhang et al, Water Science & Tech., 50, 173 (2004)
  • 11. Effect of CaO2 on BOD, Organic C and N 100 % Removal 50 w/ CaO2 w/o CaO2 BOD Organic C Organic N (Hanh et al, Env. Tech.), 26, 581 (2005)
  • 12. Retention Pond – Before Treatment
  • 13. Retention Pond – 6 Weeks Later 2lb/acre.ft CaO2 + Enzymes
  • 14. 8 10 0 6 9 1 5 4 2 3 7 3/26/2010 3/28/2010 3/30/2010 4/1/2010 4/3/2010 4/5/2010 4/7/2010 4/9/2010 4/11/2010 4/13/2010 4/15/2010 4/17/2010 4/19/2010 4/21/2010 4/23/2010 4/25/2010 4/27/2010 4/29/2010 5/1/2010 5/3/2010 5/5/2010 New Water Sample 5/7/2010 5/9/2010 5/11/2010 5/13/2010 5/15/2010 5/17/2010 5/19/2010 5/21/2010 5/23/2010 5/25/2010 Test Control
  • 15. 7.50 7.00 9.50 6.50 9.00 6.00 8.50 8.00 40263 40265 40267 40269 40271 40273 40275 40277 40279 40281 40283 40285 40287 40289 40291 40293 40295 40297 40299 40301 40303 New Water Sample 40305 40307 40309 40311 40313 40315 control 40317 40319 pH 40321 40323 Test Control Note: The sample water contains high amounts of sulfur, forming H2S in the
  • 16. Vault Ox™ can be added to a chamber as free granules or in an easily retrofit perforated tubing and mesh system.
  • 17. Addition of VaultOx™ with natural Z-100 have desirable selctive ion exchange and absorption properties that be used in the removal of: •Ammonia from wastewater/stormwater •Heavy Metals from industrial process,waste and stormwaters •Effective in the adsorption of aluminum, antimony, arsenic, barium, cadmium, chromium, colbalt, copper, iron, lead, magnesium, manganese, mercury and nickel
  • 18. Control 4/21/2010 Sample with Vault Ox 4/21/2010 Coliforms: purple-blue E. coli: pink non-Coliform: colorless
  • 19. Control 4/25/2010 Sample with VaultOx, Four day treatment
  • 20. Safety and Handling  Vault-oxTM Granules is classified as a 5.1 Oxidizer - Packing group II  All individuals who handle the product for shipping need DOT training (including those who prepare paperwork)  Keep containers closed, dry and away from direct sunlight and sources of heat  Decomposition agents include moisture, dirt, organic matter, reducing agents, acids
  • 21. Health Hazards  Most health hazards come from direct skin contact and inhalation of dust  Wear personal protective equipment  Dustproof chemical goggles  Impervious protective gloves  Avoid breathing dust  Avoid skin contact
  • 22. www.EcoSenseInt.com Info@ecosenseint.com