2. Vault-Ox™
Net 20 lbs.
Contains (4) 5 lb. packets
Keep material dry. Store in a cool dry place.
Do not store or expose to heat sources. For
more information see Material Safety Data
Sheet.
3. Interevent Water Quality in Manufactured BMP’s
• Strynchuk, Royal and England, 1999 Reported “the majority of organic-based
pollutants, which leach from grass clippings and leaves into water will be
released within 1 to 22 days…BOD peaked at 9 days…most of the phosphorus
was released in the first day…”
• Marino and Gannon, 1991 Tested storm drain sediments during dry weather
periods and found “Extended bacterial survival in sediments to survival in
water…FC and FS in sediments remained stable for up to 6 days (the maximum
inter-storm dry period).”
• GPI Southeast, in the Final Report – Baffle Box Effectiveness Monitoring Project,
2010 reports “net exports of fecal coliforms and anaerobic conditions…” and
suggest “probable causes for FC growth in baffle boxes are the interevent
anaerobic conditions…” and point out “…use of any water storing box can lead
to increased FC counts to water bodies”.
5. Patented dry chemical containing
Vault-Ox™ calcium and oxygen
Practically insoluble but slowly
degrades to release oxygen
Sequesters phosphate: precipitates as
CaPO4 or FePO4
Improves aerobic bioremediation
Raises pH to alkaline state:
Keeping metals out of solution
Stormwater quality structures
Underground water storage
Ponds
Ground water remediation
6. Properties of Vault-Ox™ Granules
Appearance Yellowish white granules
Composition CaO2 and additives
Calcium peroxide (%) 70% min
Available oxygen (%) 15.5% min
Metal impurities Meets Food Chemicals Codes
Particle size (90%) ~ 500-2000µ
7.5
pH (0.05% suspension)
7. Chemistry of Vault-OxTM in Water
At natural pH – very slow decomposition generating
oxygen and lime
2 CaO2 + 2 H2O 2 Ca(OH)2 + O2
Rate of oxygen generation depends upon
Product characteristics - particle size, formulation,
etc.
Environmental conditions - water quality, pH,
agitation, concentration, etc.
8. Vault-OxTM
A source of Alkalinity
Increases the formation of calcite and apatite
This increases the P-binding capacity of calcium
Reduces free H2S concentrations
Formulation buffers and regulates pH
Counters acid rain
Prevents acidification of water when sulfides are
oxidized
Maintains heavy metals in an immobilized oxidized
state
9. Chemistry of Vault-Ox™ in Acid
In buffered systems at lower pH, CaO2 dissolves faster and
produces progressively increasing amounts of H2O2
CaO2 + 2H+ Ca2+ (aq) + 2H2O2
Ca(OH)2 + 2H+ Ca2+ (aq) + 2H2O
10. SRP Removal Efficiency
Vault-oxTM vs. Aeration
140
CaO2
120 Aeration
Anoxic
100
80
P (mg/L)
60
40
20
0
0 5 10 15 20 25
Time (Days)
Treatment done after 15 days of incubation
Zhang et al, Water Science & Tech., 50, 173 (2004)
11. Effect of CaO2 on BOD, Organic C and N
100
% Removal
50 w/ CaO2
w/o CaO2
BOD Organic C Organic N
(Hanh et al, Env. Tech.), 26, 581 (2005)
15. 7.50
7.00
9.50
6.50
9.00
6.00
8.50
8.00
40263
40265
40267
40269
40271
40273
40275
40277
40279
40281
40283
40285
40287
40289
40291
40293
40295
40297
40299
40301
40303
New Water Sample
40305
40307
40309
40311
40313
40315
control
40317
40319
pH
40321
40323
Test
Control
Note: The sample water contains high
amounts of sulfur, forming H2S in the
16. Vault Ox™
can be added
to a chamber
as free
granules or
in an easily
retrofit
perforated
tubing and
mesh
system.
17. Addition of VaultOx™ with natural Z-100 have desirable
selctive ion exchange and absorption properties that be
used in the removal of:
•Ammonia from wastewater/stormwater
•Heavy Metals from industrial process,waste and
stormwaters
•Effective in the adsorption of aluminum, antimony,
arsenic, barium, cadmium, chromium, colbalt, copper, iron,
lead, magnesium, manganese, mercury and nickel
18. Control 4/21/2010 Sample with Vault Ox 4/21/2010
Coliforms: purple-blue
E. coli: pink
non-Coliform: colorless
20. Safety and Handling
Vault-oxTM Granules is classified as a 5.1 Oxidizer -
Packing group II
All individuals who handle the product for shipping
need DOT training (including those who prepare
paperwork)
Keep containers closed, dry and away from direct
sunlight and sources of heat
Decomposition agents include moisture, dirt,
organic matter, reducing agents, acids
21. Health Hazards
Most health hazards come from direct skin contact
and inhalation of dust
Wear personal protective equipment
Dustproof chemical goggles
Impervious protective gloves
Avoid breathing dust
Avoid skin contact