Gas Mixing
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 RECOMMENDATIONS FOR GAS MIXING:
PLUG FLOW
5 RECOMMENDATIONS FOR GAS MIXING:
BACKMIXED INITIAL ZONE
6 BIBLIOGRAPHY
1. GBH Enterprises, Ltd.
Process Engineering Guide:
GBHE-PEG-MIX-702
Gas Mixing
Information contained in this publication or as otherwise supplied to Users is
believed to be accurate and correct at time of going to press, and is given in
good faith, but it is for the User to satisfy itself of the suitability of the information
for its own particular purpose. GBHE gives no warranty as to the fitness of this
information for any particular purpose and any implied warranty or condition
(statutory or otherwise) is excluded except to the extent that exclusion is
prevented by law. GBHE accepts no liability resulting from reliance on this
information. Freedom under Patent, Copyright and Designs cannot be assumed.
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2. Process Engineering Guide:
Gas Mixing
CONTENTS
SECTION
0
INTRODUCTION/PURPOSE
2
1
SCOPE
2
2
FIELD OF APPLICATION
2
3
DEFINITIONS
2
4
RECOMMENDATIONS FOR GAS MIXING:
PLUG FLOW
2
RECOMMENDATIONS FOR GAS MIXING:
BACKMIXED INITIAL ZONE
4
BIBLIOGRAPHY
6
5
6
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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3. FIGURES
1
RESULTS OBTAINED USING A SULZER SMV MIXER
3
2
RECIRCULATION ZONE : CONFINED JET
4
3
RECIRCULATION ZONE : BLUFF BODY
5
4
STREAMLINES OF RECIRCULATION EDDY IN SWIRLING
JET, S = 1.57
5
SCHEME OF SWIRL BURNER WITH AXIAL AND
TANGENTIAL AIR ENTRIES
6
5
6
COMPARISON OF THE RADIAL DISTRIBUTIONS OF VELOCITY
IN THE VORTEX REGION FOR JETS WITH AND WITHOUT
DIVERGENT EXTENSIONS
7
7
BACKMIXED 'PRE-REACTION' ZONE
7
DOCUMENTS REFERRED TO IN THIS PROCESS
ENGINEERING GUIDE
8
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
4. 0
INTRODUCTION/PURPOSE
This Guide is one in a series of Mixing Guides and has been produced for GBH
Enterprises.
1
SCOPE
This guide covers the mixing of gases.
If a backmixed 'pre-reaction' zone is not required, refer to Clause 4. Where a
backmixed 'pre-reaction' zone is required, refer to Clause 5.
2
FIELD OF APPLICATION
This Guide applies to Process Engineers in GBH Enterprises worldwide.
3
DEFINITIONS
No specific definitions apply to this Guide.
With the exception of terms used as proper nouns or titles, those terms with initial
capital letters which appear in this document and are not defined above are
defined in the Glossary of Engineering Terms.
4
RECOMMENDATIONS FOR GAS MIXING: PLUG FLOW
Jet flow mixers and static mixers are recommended for gas mixing. The design
procedures presented for miscible liquids in GBHE-PEG-MIX-701, should be
followed using the appropriate gas physical properties.
Empty pipes may be used in the turbulent region: for gases of the same density,
a length of about 100 pipe diameters is required for good mixing. For gases with
a density ratio > 2, up to 1000 pipe diameters may be required because of the
formation of stable layers.
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5. Static mixers can achieve good mixing in less than five pipe diameters regardless
of the density difference. Figure 1 shows the results obtained using a Sulzer
SMV mixer. Unless the densities are similar and the flow rates constant, a
minimum operating velocity, UG, is recommended. For the Sulzer SMV mixer,
this is obtained if the modified Froude number exceeds 20 [Ref 1 : Germain et
al., 1982]:
. The values of f and DH are obtained from the manufacturers' data;
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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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6. FIGURE 1
RESULTS OBTAINED USING A SULZER SMV MIXER
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
7. 5
RECOMMENDATIONS FOR GAS MIXING: BACKMIXED INITIAL ZONE
Such cases are covered in the combustion literature, e.g. in Beer, J M and
Chigier, N A, ”Combustion Aerodynamics”, Krieger, 1983 (reprint of 1972
edition).
In this reference design of jet mixers for the particular requirements of
combustion, namely rapid mixing and stable flame, are discussed, and
information provided for entrainment rate into the jet, flow patterns, recirculation
vortex position, effects of jet swirl, etc.
A recirculation zone is often used to stabilized the flame (see Figure 2). Hot
gases, entrained at the downstream end, return to pre-heat the incoming fresh
gas and supply chemically active species to it. This enables velocities much
higher than the flame propagation velocity to be used without lift-off.
Recirculation zones are provided by:
(a)
FIGURE 2
Confining the jet and starving the entrainment.
RECIRCULATION ZONE : CONFINED JET
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Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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8. (b)
FIGURE 3
Using the wake behind a bluff body (see Figure 3).
RECIRCULATION ZONE : BLUFF BODY
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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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9. (c)
FIGURE 4
Swirling the jet, with swirl number S > 0.6 (see Figure 4).
STREAMLINES OF RECIRCULATION EDDY IN SWIRLING
JET, S = 1.57
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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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10. This can be evaluated from velocity profiles either assumed, or evaluated from
computational fluid dynamics (CFD) analysis.
Swirl can be produced by using tangential inlets, helical guide vanes in the flow,
or by mechanically rotated vanes or walls (see Figure 5). The degree of swirl is
increased by higher swirl numbers and by the addition of a divergent exit duct
(see Figure 6).
FIGURE 5
SCHEME OF SWIRL BURNER WITH AXIAL AND TANGENTIAL
AIR ENTRIES
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
11. 6
BIBLIOGRAPHY
Reference
Authors, Title and Source
[1]
Germain, E & Wetter, R. Mélange Statique de gaz, Informations
Chimie No. 232. Dec 1982, p 135 (referred to in Clause 4).
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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
12. FIGURE 6
COMPARISON OF THE RADIAL DISTRIBUTIONS OF VELOCITY
IN THE VORTEX REGION FOR JETS WITH AND WITHOUT
DIVERGENT EXTENSIONS
A European plant operator reactor achieves a backmixed 'pre-reaction' zone by
jet entrainment (see Figure 7).
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
13. FIGURE 7
BACKMIXED 'PRE-REACTION' ZONE
DOCUMENTS REFERRED TO IN THIS PROCESS ENGINEERING GUIDE
This Process Engineering Guide makes reference to the following documents:
GBH ENTERPRISES ENGINEERING GUIDES
Glossary of Engineering Terms
(referred to in Clause 3)
GBHE-PEG-MIX-701
Mixing of Miscible Liquids
(referred to in Clause 4)
OTHER GBHE DOCUMENTS
“A Design Procedure for Droplet Production in Static Mixers for Newtonian and
Power Law Fluid” (referred to in Clause 4).
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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
14. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com