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CHARACTERIZING THE VARIABILITY IN RESPIRABLE
      DUST EXPOSURE AND EXAMINING 2010 PROPOSED
        CHANGES TO THE UNDERGROUND COAL MINE
                    DUST STANDARD




Al Imran Khan
Graduate Student (MS)
Thesis Supervisor: Dr. Thomas Novak
Department of Mining Engineering
University of Kentucky
Contents
•   Dust and Respirable Dust
•   Coal Workers’ Pneumoconiosis
•   Sampling Dust Exposure
•   Methodology
•   Results
•   Discussions
•   Recommendations
Dust
“Dust: Small, dry, solid particles projected into the air
 by natural forces, such as wind, volcanic eruption, and
 by mechanical or man-made processes such as
 crushing, grinding, milling, drilling, demolition, shovelin
 g, conveying, screening, bagging and sweeping. Dust
 particles are usually in the size range from about 1 to
 100 micron in diameter, and they settle slowly under
 the influence of gravity.”

                     (IUPAC, 1990)
Dust Particle Type and Particle Deposition

• Inhalable fraction (less than 100 micron AED)
• Thoracic fraction (less than 25 micron AED)
• Respirable fraction (less than 10 micron AED)




Breysse [2006]
Respirable Fraction of Dust

              Aerodynamic    Respirable
              Diameter, μm    Fraction
                      2.0       1.0
                      2.5      0.75
                      3.5      0.50
                      5.0      0.25
                     10.0        0

Los Alamos Group [1962]
Motivation            Respirable Coal Dust Study

• Respirable dust is the reason
  for development of chronic
  disease such as Coal Workers’
  Pneumoconiosis (CWP)
• Respirable dust particles are
  insoluble in water and can not
  be absorbed into the blood
  stream                              Normal lung (left) and a lung from a
• Respirable dust particles are       miner diagnosed with CWP (right).
  invisible to the human eye


                            Best Practices for Dust Control, NIOSH [2010]
Prevalence of CWP in Recent Years




Best Practices for Dust Control, NIOSH [2010]
Sampling Dust Exposure
                          Sampling Device




(a) Existing Gravimetric Sampler   (b) Proposed Personal Dust Monitor
Sampling Dust Exposure
                      COMPARISION
                                    Personal Dust Monitor
 Gravimetric Sampler
                                           (PDM)
Care must be taken to ensure the
                                          Ergonomic Design
   upright position of cyclone
            assembly
        No Mass Sensor
                                             Mass Sensor

                                        Real Time Measurement,
Measurement obtained after the
                                   Continuous Monitoring throughout
       end of the shift
                                                the shift

                                        Low measurement bias
    High measurement bias
Sampling Dust Exposure




                      Internal View of PDM
Volkwein [2006]
Sampling Dust Exposure




                       PDM Display

Volkwein [2006]
Sampling Dust Exposure
                       PDM Output
  Primary Measurements
• MC0: Primary current mass concentration for
  the last 30 minute
• CUM0: Primary cumulative mass
  concentration since the beginning of the
  working shift.
• PROJ: Projected End-of-Shift (EOS)
  concentration.

Volkwein [2006]
Sampling Dust Exposure




    Reading Exposure from PDM
Existing Standard VS Proposed Standard

       PARAMETER                  EXISTING STANDARD          PROPOSED STANDARD

                                                             1.0 mg/m3 (24-month
     Threshold Limit                   2.0 mg/m3              period following the
                                                           effective date of final rule)
                                 Average of five sample    Measuring Exposure Every
    Sampling Method
                               measurements (Bi-monthly)            Shift
   Production rate as a
  percentage of average                   50%                         100%
production of last 30 shifts

     Sampling Device              Gravimetric Sampler        Personal Dust Monitor

                                                               Converted to 8-hr
      Sampling Time              Standard 8-hr Sampling
                                                               equivalent sample
Respirable Dust Exposure Study
                   METHODOLOGY

• The data was collected from three mines one after
  another
• The data was standardized to a mean of 1.00 mg/m^3
  in order to assess variability
• Fitting the data to a suitable distribution
• Determining confidence bounds and exceedance
  fractions
• Determining the mean exposure if the data is not
  expected to exceed the permissible limit
Variability in Dust Exposure
•Relative standard deviation (RSD) is a useful tool to
statistically inspect sets of data and is commonly used
for scientific studies.
•RSD allows the variability of different sample groups to
be compared more meaningfully.
•The RSD is the ratio of standard deviation to mean.

     Criteria         Mine A   Mine B   Mine C    Total
   Sample Size         197      206      197      600
      Mean             1.00     1.00     1.00     1.00
   RSD (Relative
                       0.45     0.32     0.60     0.47
Standard Deviation)
Plotting Exposure Data
Fitting Data to Distribution
• Lognormal: The occupational exposure in
  some environments follows a lognormal
  distribution.
  If y is the lognormally distributed exposure
  measurement of an employee, then x = ln(y) is
  distributed normally
  The collected mine exposure data did not fit
  the lognormal
  Lyles and Kupper [1996]
Fitting Data to Distribution
• Johnson Transformation fit the data very well.
• Johnson Transformation



Z is a standard normal random variable, γ and δ
are shape parameters, σ is a scale parameter and
θ is a location parameter. Without loss of
generality, it is assumed that δ>0 and θ > 0.
Inverse Transform
• In order to present the results in actual
  exposure, it is essential to convert the
  transformed dust exposure to original value
  using inverse transform.
• The inverse transform to the original value:
Fitting the Exposure Data

Lognormal                Johnson Transformation
                                    Probability Plot of Transformed Dust Exposure (Combined Data)
                                   99.99
                                                                                         Mean      1.416665E-11
                                                                                         StDev            1.001
                                                                                         N                  600
                                     99                                                  AD               0.312
                                                                                         P-Value          0.550
                                     95

                                     80




                         Percent
                                     50

                                     20

                                      5

                                      1



                                    0.01
                                           -4   -3   -2    -1    0     1     2   3   4
                                                     Transformed Dust Exposure
Confidence Upper Bound Calculation
• The 95% confidence bound defines that 95%
  of population will be less than it
• Analysis was conducted with the transformed
  data to determine upper confidence bounds
  for a single (1) measurement, the average of
  five (5) measurements, and the average of ten
  (10) measurements
• The confidence bound was calculated using
  equation: mean + z*(σ/√n)
Confidence Upper Bound Calculation
Sample   Mine A   Mine B   Mine C   Total
  Size

  1      1.82     1.54      2.13    1.85

  5      1.29     1.21      1.31    1.29

 10      1.18     1.14      1.17    1.17
Reliability of the Results
• Mine A
  10 out of 197 measurements exceed 1.82 mg/m^3, which
  is 5.1%
• Mine B
  8 out of 206 measurements exceed 1.54 mg/m^3, which is
  3.9%
• Mine C
  12 out of 197 measurements exceed 2.13 mg/m^3, which
  is 6.1%
• Combined Data
  28 out of 600 measurements exceed 1.85 mg/m^3, which
  is 4.6%
Exceedance Fraction
• The exceedance fraction is the percentage of
  dust exposure measurements that will be
  above an occupational exposure limit for an
  exposure group in a particular sampling
  environment. The proposed standard
  demands that the dust concentration should
  not exceed 1.13 mg/m3 for any shift.
Exceedance Fraction Calculation
    The algorithm to find the exceedance fraction:
•   Determining the transformed value (Z) of
    permissible limit, i.e. 1.13 mg/m^3
•   From normal probability table, the probability of
    exceeding Z was obtained
•   For different sample sizes, Z was divided by the
    respective sample size. Then probability of
    exceeding this new value was found
•   The number obtained from the normal
    probability table indicates the exceedance
    fraction for the respective sample size
Exceedance Fraction
Sample
         Mine A   Mine B   Mine C   Total
  Size
  1       34       31       32       34

  5       18       14       15       17

 10       10        6        7       9
Reliability of the Results
• Mine A
  70 out of 197 measurements exceed 1.13 mg/m^3, which
  is 35.5%. It was 34% according to the model
• Mine B
  65 out of 206 measurements exceed 1.13 mg/m^3, which
  is 31.5%. It was 31% according to the model
• Mine C
  58 out of 197 measurements exceed 1.13 mg/m^3, which
  is 29.4%. It was 32% according to the model
• Combined Data
  193 out of 600 measurements exceed 1.13 mg/m^3, which
  is 32%. It was 34% according to the model
Standard Mean Exposure
• If the dust exposure is expected to be within a
  permissible limit with a probability of
  95%, then a desired mean exposure must be
  determined. Therefore, a recommended mean
  exposure value can be calculated where the
  individual shift exposure does not exceed 1.13
  mg/m3.
Standard Mean Exposure
  The algorithm to find standard mean
  exposure:
• In this case the X = 1.13 mg/m3 was fixed for Z
  = 1.645 for the parameters obtained from
  Johnson transformation
• Excel Solver was used to change the
  parameters of Johnson transformation
• Then the inverse transformed value of zero is
  the standard mean exposure
Standard Mean Exposure
                         Standard Mean
          95% confidence     Exposure
Mine
         bound (mg/m^3)     (mg/m^3)

Mine A        1.13           0.625
Mine B        1.13           0.725
Mine C        1.13           0.53
 Total        1.13            0.6
Discussions
• The exposure data was not normally
  distributed
• It did not fit the lognormal distribution
• Johnson transformation was the best fit
  among the selected distributions
• The behavior of dust was similar when it
  comes to exceeding permissible limit across
  different mines
Discussions
• An RSD of 0.078 was used to calculate ECV
  1.13 mg/m^3 in the proposed rule of MSHA
• The RSD found in this study is 0.47
Revised Rule ECV
   Sample Size                1                 1             5              10
Applicable Standard   Proposed Rule ECV   Revised Rule   Revised Rule   Revised Rule
     (mg/m^3)              mg/m^3         ECV mg/m^3     ECV mg/m^3     ECV mg/m^3
         2                  2.26              3.7            2.58           2.36
        1.9                 2.15              3.51           2.44           2.23
        1.8                 2.03              3.32           2.31           2.11
        1.7                 1.92              3.15           2.19            2
        1.6                 1.81              2.96           2.06           1.88
        1.5                 1.70              2.77           1.93           1.76
        1.4                 1.58              2.58           1.8            1.64
        1.3                 1.47              2.41           1.68           1.53
        1.2                 1.36              2.21           1.54           1.4
        1.1                 1.24              2.04           1.42           1.29
         1                  1.13              1.85           1.29           1.17
        0.9                 1.02              1.66           1.15           1.05
        0.8                 0.90              1.47           1.03           0.94
        0.7                 0.79              1.3            0.91           0.83
        0.6                 0.68              1.11           0.78           0.71
        0.5                 0.56              0.93           0.64           0.59
        0.4                 0.45              0.74           0.51           0.46
        0.3                 0.34              0.56           0.39           0.35
        0.2                 0.23              0.38           0.26           0.24
Recommendations
• RSD is an important tool to compare dust across
  different sample group of dust exposure. However,
  the confidence bounds and exceedance fractions
  need to be calculated
• The Johnson transformation is a good fit to the
  dust exposure data
• An ECV of 1.85 mg/m^3 can still satisfy the mean
  exposure of 1.00 mg/m^3
• RSD of 0.47 would be more appropriate to
  determine exposure limits
Characterizing Variability in Underground Coal Mine Dust Exposure

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Characterizing Variability in Underground Coal Mine Dust Exposure

  • 1. CHARACTERIZING THE VARIABILITY IN RESPIRABLE DUST EXPOSURE AND EXAMINING 2010 PROPOSED CHANGES TO THE UNDERGROUND COAL MINE DUST STANDARD Al Imran Khan Graduate Student (MS) Thesis Supervisor: Dr. Thomas Novak Department of Mining Engineering University of Kentucky
  • 2. Contents • Dust and Respirable Dust • Coal Workers’ Pneumoconiosis • Sampling Dust Exposure • Methodology • Results • Discussions • Recommendations
  • 3. Dust “Dust: Small, dry, solid particles projected into the air by natural forces, such as wind, volcanic eruption, and by mechanical or man-made processes such as crushing, grinding, milling, drilling, demolition, shovelin g, conveying, screening, bagging and sweeping. Dust particles are usually in the size range from about 1 to 100 micron in diameter, and they settle slowly under the influence of gravity.” (IUPAC, 1990)
  • 4. Dust Particle Type and Particle Deposition • Inhalable fraction (less than 100 micron AED) • Thoracic fraction (less than 25 micron AED) • Respirable fraction (less than 10 micron AED) Breysse [2006]
  • 5. Respirable Fraction of Dust Aerodynamic Respirable Diameter, μm Fraction 2.0 1.0 2.5 0.75 3.5 0.50 5.0 0.25 10.0 0 Los Alamos Group [1962]
  • 6. Motivation Respirable Coal Dust Study • Respirable dust is the reason for development of chronic disease such as Coal Workers’ Pneumoconiosis (CWP) • Respirable dust particles are insoluble in water and can not be absorbed into the blood stream Normal lung (left) and a lung from a • Respirable dust particles are miner diagnosed with CWP (right). invisible to the human eye Best Practices for Dust Control, NIOSH [2010]
  • 7. Prevalence of CWP in Recent Years Best Practices for Dust Control, NIOSH [2010]
  • 8. Sampling Dust Exposure Sampling Device (a) Existing Gravimetric Sampler (b) Proposed Personal Dust Monitor
  • 9. Sampling Dust Exposure COMPARISION Personal Dust Monitor Gravimetric Sampler (PDM) Care must be taken to ensure the Ergonomic Design upright position of cyclone assembly No Mass Sensor Mass Sensor Real Time Measurement, Measurement obtained after the Continuous Monitoring throughout end of the shift the shift Low measurement bias High measurement bias
  • 10. Sampling Dust Exposure Internal View of PDM Volkwein [2006]
  • 11. Sampling Dust Exposure PDM Display Volkwein [2006]
  • 12. Sampling Dust Exposure PDM Output Primary Measurements • MC0: Primary current mass concentration for the last 30 minute • CUM0: Primary cumulative mass concentration since the beginning of the working shift. • PROJ: Projected End-of-Shift (EOS) concentration. Volkwein [2006]
  • 13. Sampling Dust Exposure Reading Exposure from PDM
  • 14. Existing Standard VS Proposed Standard PARAMETER EXISTING STANDARD PROPOSED STANDARD 1.0 mg/m3 (24-month Threshold Limit 2.0 mg/m3 period following the effective date of final rule) Average of five sample Measuring Exposure Every Sampling Method measurements (Bi-monthly) Shift Production rate as a percentage of average 50% 100% production of last 30 shifts Sampling Device Gravimetric Sampler Personal Dust Monitor Converted to 8-hr Sampling Time Standard 8-hr Sampling equivalent sample
  • 15. Respirable Dust Exposure Study METHODOLOGY • The data was collected from three mines one after another • The data was standardized to a mean of 1.00 mg/m^3 in order to assess variability • Fitting the data to a suitable distribution • Determining confidence bounds and exceedance fractions • Determining the mean exposure if the data is not expected to exceed the permissible limit
  • 16. Variability in Dust Exposure •Relative standard deviation (RSD) is a useful tool to statistically inspect sets of data and is commonly used for scientific studies. •RSD allows the variability of different sample groups to be compared more meaningfully. •The RSD is the ratio of standard deviation to mean. Criteria Mine A Mine B Mine C Total Sample Size 197 206 197 600 Mean 1.00 1.00 1.00 1.00 RSD (Relative 0.45 0.32 0.60 0.47 Standard Deviation)
  • 18. Fitting Data to Distribution • Lognormal: The occupational exposure in some environments follows a lognormal distribution. If y is the lognormally distributed exposure measurement of an employee, then x = ln(y) is distributed normally The collected mine exposure data did not fit the lognormal Lyles and Kupper [1996]
  • 19. Fitting Data to Distribution • Johnson Transformation fit the data very well. • Johnson Transformation Z is a standard normal random variable, γ and δ are shape parameters, σ is a scale parameter and θ is a location parameter. Without loss of generality, it is assumed that δ>0 and θ > 0.
  • 20. Inverse Transform • In order to present the results in actual exposure, it is essential to convert the transformed dust exposure to original value using inverse transform. • The inverse transform to the original value:
  • 21. Fitting the Exposure Data Lognormal Johnson Transformation Probability Plot of Transformed Dust Exposure (Combined Data) 99.99 Mean 1.416665E-11 StDev 1.001 N 600 99 AD 0.312 P-Value 0.550 95 80 Percent 50 20 5 1 0.01 -4 -3 -2 -1 0 1 2 3 4 Transformed Dust Exposure
  • 22. Confidence Upper Bound Calculation • The 95% confidence bound defines that 95% of population will be less than it • Analysis was conducted with the transformed data to determine upper confidence bounds for a single (1) measurement, the average of five (5) measurements, and the average of ten (10) measurements • The confidence bound was calculated using equation: mean + z*(σ/√n)
  • 23. Confidence Upper Bound Calculation Sample Mine A Mine B Mine C Total Size 1 1.82 1.54 2.13 1.85 5 1.29 1.21 1.31 1.29 10 1.18 1.14 1.17 1.17
  • 24. Reliability of the Results • Mine A 10 out of 197 measurements exceed 1.82 mg/m^3, which is 5.1% • Mine B 8 out of 206 measurements exceed 1.54 mg/m^3, which is 3.9% • Mine C 12 out of 197 measurements exceed 2.13 mg/m^3, which is 6.1% • Combined Data 28 out of 600 measurements exceed 1.85 mg/m^3, which is 4.6%
  • 25.
  • 26. Exceedance Fraction • The exceedance fraction is the percentage of dust exposure measurements that will be above an occupational exposure limit for an exposure group in a particular sampling environment. The proposed standard demands that the dust concentration should not exceed 1.13 mg/m3 for any shift.
  • 27. Exceedance Fraction Calculation The algorithm to find the exceedance fraction: • Determining the transformed value (Z) of permissible limit, i.e. 1.13 mg/m^3 • From normal probability table, the probability of exceeding Z was obtained • For different sample sizes, Z was divided by the respective sample size. Then probability of exceeding this new value was found • The number obtained from the normal probability table indicates the exceedance fraction for the respective sample size
  • 28. Exceedance Fraction Sample Mine A Mine B Mine C Total Size 1 34 31 32 34 5 18 14 15 17 10 10 6 7 9
  • 29. Reliability of the Results • Mine A 70 out of 197 measurements exceed 1.13 mg/m^3, which is 35.5%. It was 34% according to the model • Mine B 65 out of 206 measurements exceed 1.13 mg/m^3, which is 31.5%. It was 31% according to the model • Mine C 58 out of 197 measurements exceed 1.13 mg/m^3, which is 29.4%. It was 32% according to the model • Combined Data 193 out of 600 measurements exceed 1.13 mg/m^3, which is 32%. It was 34% according to the model
  • 30.
  • 31. Standard Mean Exposure • If the dust exposure is expected to be within a permissible limit with a probability of 95%, then a desired mean exposure must be determined. Therefore, a recommended mean exposure value can be calculated where the individual shift exposure does not exceed 1.13 mg/m3.
  • 32. Standard Mean Exposure The algorithm to find standard mean exposure: • In this case the X = 1.13 mg/m3 was fixed for Z = 1.645 for the parameters obtained from Johnson transformation • Excel Solver was used to change the parameters of Johnson transformation • Then the inverse transformed value of zero is the standard mean exposure
  • 33. Standard Mean Exposure Standard Mean 95% confidence Exposure Mine bound (mg/m^3) (mg/m^3) Mine A 1.13 0.625 Mine B 1.13 0.725 Mine C 1.13 0.53 Total 1.13 0.6
  • 34. Discussions • The exposure data was not normally distributed • It did not fit the lognormal distribution • Johnson transformation was the best fit among the selected distributions • The behavior of dust was similar when it comes to exceeding permissible limit across different mines
  • 35. Discussions • An RSD of 0.078 was used to calculate ECV 1.13 mg/m^3 in the proposed rule of MSHA • The RSD found in this study is 0.47
  • 36. Revised Rule ECV Sample Size 1 1 5 10 Applicable Standard Proposed Rule ECV Revised Rule Revised Rule Revised Rule (mg/m^3) mg/m^3 ECV mg/m^3 ECV mg/m^3 ECV mg/m^3 2 2.26 3.7 2.58 2.36 1.9 2.15 3.51 2.44 2.23 1.8 2.03 3.32 2.31 2.11 1.7 1.92 3.15 2.19 2 1.6 1.81 2.96 2.06 1.88 1.5 1.70 2.77 1.93 1.76 1.4 1.58 2.58 1.8 1.64 1.3 1.47 2.41 1.68 1.53 1.2 1.36 2.21 1.54 1.4 1.1 1.24 2.04 1.42 1.29 1 1.13 1.85 1.29 1.17 0.9 1.02 1.66 1.15 1.05 0.8 0.90 1.47 1.03 0.94 0.7 0.79 1.3 0.91 0.83 0.6 0.68 1.11 0.78 0.71 0.5 0.56 0.93 0.64 0.59 0.4 0.45 0.74 0.51 0.46 0.3 0.34 0.56 0.39 0.35 0.2 0.23 0.38 0.26 0.24
  • 37. Recommendations • RSD is an important tool to compare dust across different sample group of dust exposure. However, the confidence bounds and exceedance fractions need to be calculated • The Johnson transformation is a good fit to the dust exposure data • An ECV of 1.85 mg/m^3 can still satisfy the mean exposure of 1.00 mg/m^3 • RSD of 0.47 would be more appropriate to determine exposure limits

Notes de l'éditeur

  1. Statistical Distribution:Lognormal: This is a type of a parametric distribution where the log of data follows a normal distribution.
  2. Equation