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Copyright	
  ©	
  2015	
  M	
  E	
  R	
  Deed	
  and	
  M	
  Preene	
  
Mike Deed, Geoquip Water Solutions Ltd, UK, and !
Martin Preene, Preene Groundwater Consulting Ltd, UK!
Groundwater	
  wells	
  are	
  common	
  to	
  many	
  civil	
  engineering	
  schemes	
  and	
  
are	
  used	
  for	
  a	
  wide	
  range	
  of	
  purposes	
  such	
  as	
  construcBon	
  dewatering,	
  
open	
   loop	
   geothermal	
   systems	
   or	
   alternaBve	
   water	
   supplies	
   for	
  
buildings	
   and	
   faciliBes.	
   Whatever	
   the	
   applicaBon,	
   well	
   performance	
  
must	
  be	
  opBmised	
  and	
  high	
  levels	
  of	
  operaBonal	
  efficiency	
  and	
  service	
  
availability	
   achieved.	
   However,	
   the	
   benefits	
   of	
   proacBve	
   planned	
  
maintenance	
  of	
  groundwater	
  wells	
  on	
  civil	
  engineering	
  projects	
  are	
  not	
  
widely	
  recognised.	
  
Typically,	
   wells	
   have	
   a	
   near	
   surface	
   secBon	
   of	
   well	
   liner,	
   from	
   which	
  
groundwater	
  is	
  excluded.	
  The	
  deeper	
  part	
  of	
  the	
  well	
  is	
  the	
  permeable	
  
well	
  screen,	
  through	
  which	
  water	
  enters	
  the	
  well.	
  Water	
  enters	
  the	
  well	
  
exclusively	
   through	
   the	
   well	
   screen,	
   and	
   it	
   is	
   here	
   that	
   clogging	
  
processes	
  occur.	
  
Pumping	
  lowers	
  the	
  water	
  level	
  in	
  the	
  well	
  by	
  an	
  amount	
  known	
  as	
  the	
  
‘drawdown’.	
  This	
  comprises	
  the	
  drawdown	
  in	
  the	
  aquifer	
  and	
  the	
  ‘well	
  
loss’,	
  a	
  head	
  difference	
  between	
  the	
  inside	
  and	
  outside	
  of	
  the	
  well	
  that	
  
represents	
  the	
  resistance	
  to	
  flow	
  of	
  water	
  into	
  the	
  well.	
  An	
  inefficient	
  
(clogged)	
  well	
  will	
  have	
  a	
  greater	
  well	
  loss	
  than	
  an	
  unclogged	
  well,	
  and	
  
therefore	
  a	
  greater	
  drawdown	
  for	
  a	
  given	
  pumped	
  flow	
  rate.	
  Clogging	
  
can	
  become	
  so	
  severe	
  that	
  the	
  yield	
  of	
  the	
  well	
  is	
  reduced,	
  so	
  that	
  less	
  
water	
  is	
  available	
  to	
  users,	
  or	
  so	
  that	
  dewatering	
  is	
  less	
  effecBve.	
  
CLOGGING	
  AND	
  ENCRUSTATION	
  PROCESSES	
  	
  
A	
  groundwater	
  well	
  is	
  a	
  complex	
  hydrodynamic	
  environment.	
  As	
  water	
  
passes	
   through	
   the	
   well	
   and	
   the	
   downstream	
   pumping	
   system,	
   it	
  
undergoes	
  pressure	
  changes,	
  temperatures	
  changes,	
  is	
  exposed	
  to	
  the	
  
atmosphere	
   and	
   comes	
   into	
   contact	
   with	
   arBficial	
   surfaces	
   in	
   well	
  
screens	
   and	
   pumps.	
   This	
   can	
   create	
   ideal	
   condiBons	
   for	
   clogging	
   to	
  
occur.	
  	
  
Three	
   main	
   clogging	
   processes	
   occur	
   in	
   and	
   around	
   wells:	
   physical	
  
clogging,	
   where	
   parBculate	
   maWer	
   is	
   re-­‐arranged;	
   bacterial	
   clogging,	
  
where	
   bacterial	
   colonies	
   grow	
   in	
   the	
   well,	
   feeding	
   from	
   dissolved	
  
material	
  in	
  the	
  well;	
  and	
  chemical	
  clogging,	
  where	
  mineral	
  compounds	
  
derived	
  from	
  dissolved	
  material	
  in	
  the	
  water	
  are	
  deposited.	
  The	
  focus	
  of	
  
this	
  paper	
  is	
  on	
  chemical	
  and	
  bacterial	
  problems.	
  	
  	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
Iron-­‐related	
  deposits	
  on	
  well	
  pumping	
  equipment	
  
	
  
Bacterial	
  clogging:	
  Iron	
  bacteria	
  are	
  one	
  of	
  the	
  most	
  common	
  clogging	
  
processes	
   in	
   wells.	
   Their	
   life	
   cycle	
   oxidises	
   the	
   soluble	
   ferrous	
   iron	
  
(Fe2+)	
   in	
   the	
   groundwater	
   to	
   an	
   insoluble	
   ferric	
   form	
   (Fe3+).	
   The	
  
potenBally	
  turbulent,	
  oxygenated	
  environment	
  in	
  a	
  well	
  and	
  pumping	
  
system	
   creates	
   an	
   ideal	
   environment	
   for	
   this	
   to	
   occur.	
   The	
   bacteria	
  
produce	
   a	
   biofilm,	
   typically	
   a	
   slimy	
   or	
   gelaBnous	
   red-­‐brown	
   deposit	
  
(commonly	
  known	
  as	
  biofouling)	
  that	
  can	
  be	
  difficult	
  to	
  remove.	
  	
  
Chemical	
   clogging:	
   Occurs	
   by	
   chemical	
   precipitaBon	
   induced	
   by	
   the	
  
natural	
  pressure	
  release	
  on	
  the	
  water	
  as	
  it	
  moves	
  from	
  the	
  formaBon	
  
into	
  the	
  well	
  bore	
  and	
  to	
  the	
  pump,	
  combined	
  with	
  the	
  oxygen	
  available	
  
in	
   the	
   well.	
   The	
   most	
   commonly	
   reported	
   chemical	
   encrustaBons	
   are	
  
iron	
   oxyhydroxides,	
   sulphides	
   and	
   calcium	
   carbonates.	
   Carbonate	
  
clogging	
  occurs	
  when	
  the	
  natural	
  carbon	
  dioxide	
  dissolved	
  in	
  soluBon	
  is	
  
released,	
  resulBng	
  in	
  an	
  increase	
  in	
  water	
  pH.	
  As	
  the	
  pH	
  increases	
  in	
  
waters	
   with	
   high	
   levels	
   of	
   calcium	
   carbonates,	
   rapid	
   precipitaBon	
   of	
  
white	
  or	
  pale	
  grey	
  calcareous	
  deposits	
  occur	
  in	
  the	
  well	
  and	
  pump. 	

Managing the Clogging of Groundwater Wells!
STRATEGIES	
  TO	
  MANAGE	
  CLOGGING	
  AND	
  ENCRUSTATION	
  	
  
Chemical	
   treatments	
   are	
   widely	
   used	
   to	
   rehabilitate	
   wells;	
   many	
  
products	
  and	
  commercial	
  treatments,	
  are	
  available	
  (see	
  table	
  below,	
  
which	
   is	
   based	
   on	
   US	
   Army	
   Corps	
   of	
   Engineers	
   2000).	
   Research	
   has	
  
shown	
  that	
  chemical	
  rehabilitaBon	
  can	
  provide	
  40	
  to	
  60%	
  of	
  the	
  total	
  
gain	
   during	
   a	
   combined	
   chemical	
   and	
   hydro-­‐	
   or	
   mechanical	
  
rehabilitaBon	
   (Houben	
   2001).	
   	
   The	
   challenge	
   for	
   the	
   well	
   owner	
   or	
  
operator	
  is	
  that	
  each	
  site	
  will	
  have	
  unique	
  aspects,	
  requiring	
  care	
  in	
  
the	
   choice	
   of	
   rehabilitaBon	
   methods	
   and	
   chemical	
   agents	
   if	
   well	
  
performance	
  is	
  to	
  be	
  returned	
  to	
  close	
  to	
  its	
  original	
  levels.	
  
However,	
   rehabilitaBon	
   alone	
   is	
   not	
   the	
   opBmal	
   soluBon.	
   The	
   most	
  
effecBve	
   programmes	
   to	
   manage	
   well	
   performance	
   typically	
  
incorporate	
  a	
  monitoring	
  and	
  measurement	
  plan	
  alongside	
  a	
  regular	
  
chemical	
   treatment.	
   The	
   elements	
   of	
   a	
   well	
   rehabiltaBon	
   can	
   be	
  
illustrated	
   by	
   reference	
   to	
   the	
   BoreSaver	
   well	
   management	
  
programme	
  intended	
  to	
  return	
  performance	
  to	
  as	
  close	
  to	
  the	
  original	
  
drilled	
  capacity	
  as	
  possible	
  and	
  to	
  help	
  maintain	
  a	
  conBnual,	
  problem-­‐
free	
  water	
  supply.	
  The	
  elements	
  of	
  such	
  a	
  programme	
  are:	
  
Pre-­‐rehabilitaAon	
   survey:	
   CollaBon	
   of	
   operaBonal	
   data	
   (pumping	
  
rates,	
   water	
   levels	
   and	
   water	
   quality),	
   visual	
   inspecBon	
   of	
   pumps	
  
following	
  removal,	
  and	
  a	
  downhole	
  camera	
  survey.	
  
Assessment	
   of	
   borehole	
   condiAon	
   and	
   required	
   rehabilitaAon:	
  
Review	
   and	
   analysis	
   of	
   key	
   well	
   performance	
   parameters	
   and	
  
benchmarking	
  against	
  historical	
  data	
  for	
  each	
  well	
  and	
  wellfield.	
  	
  
RehabilitaAon	
  treatment:	
  A	
  combinaBon	
  of	
  mechanical	
  and	
  chemical	
  
methods	
   is	
   usually	
   the	
   most	
   effecBve	
   approach.	
   Mechanical	
  
treatments	
   can	
   include:	
   scrubbing;	
   surging;	
   water	
   or	
   air	
   jedng;	
  
vibraBon.	
   The	
   chemical	
   treatment	
   component	
   requires	
   suitable	
  
treatment	
  products	
  and	
  specialist	
  rehabilitaBon	
  equipment	
  to	
  deliver	
  
the	
  products	
  to	
  the	
  relevant	
  secBon	
  of	
  the	
  well	
  screen.	
  
Post-­‐treatment	
   survey:	
   Downhole	
   camera	
   survey	
   and	
   monitoring	
   of	
  
iniBal	
  post-­‐treatment	
  pumping.	
  
ConAnuing	
   monitoring	
   and	
   maintenance:	
   To	
   provide	
   the	
   data	
   to	
  
allow	
  future	
  rehabilitaBon	
  treatments	
  to	
  be	
  planned	
  and	
  scheduled.	
  
	
  
	
  
	
  
	
  
	
  
	
  
SelecBon	
   of	
   the	
   appropriate	
   chemical	
   treatments	
   is	
   important	
   to	
  
ensure	
  that	
  they	
  are	
  effecBve	
  against	
  the	
  type	
  of	
  clogging	
  idenBfied,	
  
have	
   the	
   necessary	
   regulatory	
   approvals	
   and	
   the	
   post-­‐treatment	
  
residues	
  are	
  harmless	
  and	
  can	
  be	
  safely	
  disposed	
  of.	
  	
  
REFERENCES	
  
Houben,	
   G.J.	
   2001.	
   Well	
   ageing	
   and	
   its	
   implicaBons	
   for	
   well	
   and	
   piezometer	
   performance.	
  
Impact	
   of	
   Human	
   Ac;vity	
   on	
   Groundwater	
   Dynamics.	
   IAHS	
   Publ.	
   269,	
   297–300.	
   IAHS,	
  
Wallingford.	
  
US	
  Army	
  Corps	
  of	
  Engineers.	
  2000.	
  Opera;on	
  and	
  Maintenance	
  of	
  Extrac;on	
  and	
  Injec;on	
  
Wells	
  at	
  HTRW	
  Sites.	
  Department	
  of	
  the	
  Army,	
  Washington	
  DC.	
  
Contact:	
   	
  Mike	
  Deed:	
  mike@geoquipservices.co.uk	
  	
  
	
  MarBn	
  Preene:	
  mp@preene.com	
  
	
  
Chemical) Advantages) Disadvantages)
Hydrochloric*Acid*
(also*known*as*
Muriatic*Acid)*(HCI)*
Effective*against*a*range*of*mineral*
deposits*and*highly*effective*at*removing*
scale.*Widely*used*in*groundwater*well*
rehabilitation.*
Corrosive*to*most*metals,*particularly*stainless*steel*
because*of*chloride*content.*Not*effective*against*iron*
biofouling.*Produces*toxic*fumes,*requires*careful*handling,*
purity*levels*needed*be*defined*before*handling,*lowers*pH*
levels.*
Sulfamic*Acid*
(H2NSO3H)*
Strong*acid*which*reacts*very*quickly*
against*carbonate*scales.*Powder*form*
should*be*dissolved*in*water*before*
adding.*Safer*to*handle*than*muriatic*acid.*
Not*effective*against*iron*or*manganese*deposits.*More*
effective*as*a*combination*chemical*treatment*against*
biofouling*or*metal*oxides.**
Phosphoric*Acid*
(H3PO4)*
Less*corrosive*than*hydrochloric*acid*but*
slower*acting.*Effective*against*iron*and*
manganese*deposits.*
Requires*careful*handling.**Leaves*phosphates*behind*
which*can*provide*nutrients*for*microbial*growth.*
Sodium*
hypochlorite*
(NaOCI)*
Liquid*product.*Good*disinfectant*
capabilities.*Effective*at*oxidising*and*
killing*bacteria.*
Not*effective*against*mineral*deposits.*Short*shelf*life.*Can*
increase*the*redox*potential*of*the*aquifer.*
Acetic*Acid*(CH3*
COOOH)*
Effective*biocide*and*biofilm*dispersing*
acid.*Relatively*safe*to*handle.**
Glacial*acetic*is*very*corrosive*to*the*skin*and*produces*a*
pungent*vapor*that*can*cause*mild*to*severe*lung*damage.*
Oxalic*Acid*(COOH)2* Strong,*reducing*acid*and*is*excellent*
against*iron*and*manganese*oxide.*
Biodegradable.*As*a*combination*chemical*
works*with*even*greater*power.*
Salts*of*the*acid*are*poisonous*but*during*a*treatment*
converts*to*inert*elements,*with*any*residues*easily*
removed*from*water*body.*
!
!
Well	
  rehabilita;on	
  
rig	
  used	
  in	
  
BoreSaver	
  
maintenance	
  
programmes	
  	
  

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Managing the clogging of groundwater wells

  • 1. Copyright  ©  2015  M  E  R  Deed  and  M  Preene   Mike Deed, Geoquip Water Solutions Ltd, UK, and ! Martin Preene, Preene Groundwater Consulting Ltd, UK! Groundwater  wells  are  common  to  many  civil  engineering  schemes  and   are  used  for  a  wide  range  of  purposes  such  as  construcBon  dewatering,   open   loop   geothermal   systems   or   alternaBve   water   supplies   for   buildings   and   faciliBes.   Whatever   the   applicaBon,   well   performance   must  be  opBmised  and  high  levels  of  operaBonal  efficiency  and  service   availability   achieved.   However,   the   benefits   of   proacBve   planned   maintenance  of  groundwater  wells  on  civil  engineering  projects  are  not   widely  recognised.   Typically,   wells   have   a   near   surface   secBon   of   well   liner,   from   which   groundwater  is  excluded.  The  deeper  part  of  the  well  is  the  permeable   well  screen,  through  which  water  enters  the  well.  Water  enters  the  well   exclusively   through   the   well   screen,   and   it   is   here   that   clogging   processes  occur.   Pumping  lowers  the  water  level  in  the  well  by  an  amount  known  as  the   ‘drawdown’.  This  comprises  the  drawdown  in  the  aquifer  and  the  ‘well   loss’,  a  head  difference  between  the  inside  and  outside  of  the  well  that   represents  the  resistance  to  flow  of  water  into  the  well.  An  inefficient   (clogged)  well  will  have  a  greater  well  loss  than  an  unclogged  well,  and   therefore  a  greater  drawdown  for  a  given  pumped  flow  rate.  Clogging   can  become  so  severe  that  the  yield  of  the  well  is  reduced,  so  that  less   water  is  available  to  users,  or  so  that  dewatering  is  less  effecBve.   CLOGGING  AND  ENCRUSTATION  PROCESSES     A  groundwater  well  is  a  complex  hydrodynamic  environment.  As  water   passes   through   the   well   and   the   downstream   pumping   system,   it   undergoes  pressure  changes,  temperatures  changes,  is  exposed  to  the   atmosphere   and   comes   into   contact   with   arBficial   surfaces   in   well   screens   and   pumps.   This   can   create   ideal   condiBons   for   clogging   to   occur.     Three   main   clogging   processes   occur   in   and   around   wells:   physical   clogging,   where   parBculate   maWer   is   re-­‐arranged;   bacterial   clogging,   where   bacterial   colonies   grow   in   the   well,   feeding   from   dissolved   material  in  the  well;  and  chemical  clogging,  where  mineral  compounds   derived  from  dissolved  material  in  the  water  are  deposited.  The  focus  of   this  paper  is  on  chemical  and  bacterial  problems.                           Iron-­‐related  deposits  on  well  pumping  equipment     Bacterial  clogging:  Iron  bacteria  are  one  of  the  most  common  clogging   processes   in   wells.   Their   life   cycle   oxidises   the   soluble   ferrous   iron   (Fe2+)   in   the   groundwater   to   an   insoluble   ferric   form   (Fe3+).   The   potenBally  turbulent,  oxygenated  environment  in  a  well  and  pumping   system   creates   an   ideal   environment   for   this   to   occur.   The   bacteria   produce   a   biofilm,   typically   a   slimy   or   gelaBnous   red-­‐brown   deposit   (commonly  known  as  biofouling)  that  can  be  difficult  to  remove.     Chemical   clogging:   Occurs   by   chemical   precipitaBon   induced   by   the   natural  pressure  release  on  the  water  as  it  moves  from  the  formaBon   into  the  well  bore  and  to  the  pump,  combined  with  the  oxygen  available   in   the   well.   The   most   commonly   reported   chemical   encrustaBons   are   iron   oxyhydroxides,   sulphides   and   calcium   carbonates.   Carbonate   clogging  occurs  when  the  natural  carbon  dioxide  dissolved  in  soluBon  is   released,  resulBng  in  an  increase  in  water  pH.  As  the  pH  increases  in   waters   with   high   levels   of   calcium   carbonates,   rapid   precipitaBon   of   white  or  pale  grey  calcareous  deposits  occur  in  the  well  and  pump. Managing the Clogging of Groundwater Wells! STRATEGIES  TO  MANAGE  CLOGGING  AND  ENCRUSTATION     Chemical   treatments   are   widely   used   to   rehabilitate   wells;   many   products  and  commercial  treatments,  are  available  (see  table  below,   which   is   based   on   US   Army   Corps   of   Engineers   2000).   Research   has   shown  that  chemical  rehabilitaBon  can  provide  40  to  60%  of  the  total   gain   during   a   combined   chemical   and   hydro-­‐   or   mechanical   rehabilitaBon   (Houben   2001).     The   challenge   for   the   well   owner   or   operator  is  that  each  site  will  have  unique  aspects,  requiring  care  in   the   choice   of   rehabilitaBon   methods   and   chemical   agents   if   well   performance  is  to  be  returned  to  close  to  its  original  levels.   However,   rehabilitaBon   alone   is   not   the   opBmal   soluBon.   The   most   effecBve   programmes   to   manage   well   performance   typically   incorporate  a  monitoring  and  measurement  plan  alongside  a  regular   chemical   treatment.   The   elements   of   a   well   rehabiltaBon   can   be   illustrated   by   reference   to   the   BoreSaver   well   management   programme  intended  to  return  performance  to  as  close  to  the  original   drilled  capacity  as  possible  and  to  help  maintain  a  conBnual,  problem-­‐ free  water  supply.  The  elements  of  such  a  programme  are:   Pre-­‐rehabilitaAon   survey:   CollaBon   of   operaBonal   data   (pumping   rates,   water   levels   and   water   quality),   visual   inspecBon   of   pumps   following  removal,  and  a  downhole  camera  survey.   Assessment   of   borehole   condiAon   and   required   rehabilitaAon:   Review   and   analysis   of   key   well   performance   parameters   and   benchmarking  against  historical  data  for  each  well  and  wellfield.     RehabilitaAon  treatment:  A  combinaBon  of  mechanical  and  chemical   methods   is   usually   the   most   effecBve   approach.   Mechanical   treatments   can   include:   scrubbing;   surging;   water   or   air   jedng;   vibraBon.   The   chemical   treatment   component   requires   suitable   treatment  products  and  specialist  rehabilitaBon  equipment  to  deliver   the  products  to  the  relevant  secBon  of  the  well  screen.   Post-­‐treatment   survey:   Downhole   camera   survey   and   monitoring   of   iniBal  post-­‐treatment  pumping.   ConAnuing   monitoring   and   maintenance:   To   provide   the   data   to   allow  future  rehabilitaBon  treatments  to  be  planned  and  scheduled.               SelecBon   of   the   appropriate   chemical   treatments   is   important   to   ensure  that  they  are  effecBve  against  the  type  of  clogging  idenBfied,   have   the   necessary   regulatory   approvals   and   the   post-­‐treatment   residues  are  harmless  and  can  be  safely  disposed  of.     REFERENCES   Houben,   G.J.   2001.   Well   ageing   and   its   implicaBons   for   well   and   piezometer   performance.   Impact   of   Human   Ac;vity   on   Groundwater   Dynamics.   IAHS   Publ.   269,   297–300.   IAHS,   Wallingford.   US  Army  Corps  of  Engineers.  2000.  Opera;on  and  Maintenance  of  Extrac;on  and  Injec;on   Wells  at  HTRW  Sites.  Department  of  the  Army,  Washington  DC.   Contact:    Mike  Deed:  mike@geoquipservices.co.uk      MarBn  Preene:  mp@preene.com     Chemical) Advantages) Disadvantages) Hydrochloric*Acid* (also*known*as* Muriatic*Acid)*(HCI)* Effective*against*a*range*of*mineral* deposits*and*highly*effective*at*removing* scale.*Widely*used*in*groundwater*well* rehabilitation.* Corrosive*to*most*metals,*particularly*stainless*steel* because*of*chloride*content.*Not*effective*against*iron* biofouling.*Produces*toxic*fumes,*requires*careful*handling,* purity*levels*needed*be*defined*before*handling,*lowers*pH* levels.* Sulfamic*Acid* (H2NSO3H)* Strong*acid*which*reacts*very*quickly* against*carbonate*scales.*Powder*form* should*be*dissolved*in*water*before* adding.*Safer*to*handle*than*muriatic*acid.* Not*effective*against*iron*or*manganese*deposits.*More* effective*as*a*combination*chemical*treatment*against* biofouling*or*metal*oxides.** Phosphoric*Acid* (H3PO4)* Less*corrosive*than*hydrochloric*acid*but* slower*acting.*Effective*against*iron*and* manganese*deposits.* Requires*careful*handling.**Leaves*phosphates*behind* which*can*provide*nutrients*for*microbial*growth.* Sodium* hypochlorite* (NaOCI)* Liquid*product.*Good*disinfectant* capabilities.*Effective*at*oxidising*and* killing*bacteria.* Not*effective*against*mineral*deposits.*Short*shelf*life.*Can* increase*the*redox*potential*of*the*aquifer.* Acetic*Acid*(CH3* COOOH)* Effective*biocide*and*biofilm*dispersing* acid.*Relatively*safe*to*handle.** Glacial*acetic*is*very*corrosive*to*the*skin*and*produces*a* pungent*vapor*that*can*cause*mild*to*severe*lung*damage.* Oxalic*Acid*(COOH)2* Strong,*reducing*acid*and*is*excellent* against*iron*and*manganese*oxide.* Biodegradable.*As*a*combination*chemical* works*with*even*greater*power.* Salts*of*the*acid*are*poisonous*but*during*a*treatment* converts*to*inert*elements,*with*any*residues*easily* removed*from*water*body.* ! ! Well  rehabilita;on   rig  used  in   BoreSaver   maintenance   programmes