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Draw the VESPR structures for
           14.1.1
   Include bond angles, names of
              shapes
Bonding AHL
β€’ Describe sigma and pi bonds

β€’ Explain hybridization in terms of sp sp2 sp3


β€’ Explain relationship between Lewis
  structure, shape and hybridisation
Sigma Bonds
β€’ Sigma bonds are all single bonds, and result
  from axial overlap of orbitals.
Ο€ Bonds
β€’ Result from sideways overlap of parallel
  porbitals
Basics
β€’ A single bond is a SIGMA bond

β€’ A double bond is ONE SIGMA ONE PI

β€’ A triple bond is ONE SIGMA TWO PI
Hybridisation – sp3
Hybridisation – sp2
Hybridisation - sp
Homework Task
β€’ Using the following molecules create a
  student help sheet to explain the bonding, the
  shape, the hybridisation, and number of sigma
  and pi bonds.

β€’ In Carbon Dioxide, Methane and Propene.
Geometry and Hybridisation
β€’ All you have to do is count the negative
  centres, and don’t forget lone pairs
β€’ Inorganic :
     β€’ 4 negative centres is sp3, e.g. NF3 ( 3bp 1nbp in this case )
     β€’ 3 negative centres is sp2, e.g. BF3 ( 3bp in this case )
     β€’ 2 negative centres if sp
β€’ Organic :
     β€’ sp3 is Td 109.5, e.g. Alkanes
     β€’ sp2 is Trig Pl 120, e.g. Alkenes, Carbonyl groups
     β€’ sp is lin 180, e.g. Alkynes
Starter
β€’ Explain how sp2 hybridization arises 

β€’ Use electrons in boxes notation to explain
  your answer.
When electron pairs are not confined
to two adjacent bonding atoms but
   extend over 3 or more atoms
Benzene Facts 
β€’ Planar regular hexagon

β€’ All bond angles 120 degrees

β€’ Bond lengths intermediate between single and
  double bonds

β€’ Reluctant to undergo addition reactions.
Nitrate Ion
Nitrite Ion Resonance Structures ?
Carbonate Anion
Ozone
Ethanoate
Learning Check 
β€’ N01/420/H(2) part (a) ONLY

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