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Nanotechnology at UNH:
Innovative Science In Support of Next
Generation Consumer Products
Glen P. Miller
Department of Chemistry and Materials Science Program
University of New Hampshire
Wild For Innovation
Friday, March 5, 2010
S
S
I
polymer
Active Layer
(PCBM + P3HT)
Al
Solar light
I
polymer
Active Layer
(PCBM + P3HT)
Al
Solar light
Application Road Map
Nanoelements
Thrust I
Acenes
Funct.
Fullerenes
Funct. CNTs
& Graphene
Nanocups &
Nanorings
OFETs,
OLEDs
Organic
Photovoltaics
Nanotemplates
Flexible
Electronics
Polymer
composites,
EMI Shielding
Interconnects
Structural &
Electronic Mat’s
Cyclacenes &
Uniform SWNTs
An Example:
Carbon Nanotube Memory Chip
2
ON state
OFF state
In principle… In reality…
Related Applications: SWNT Switches, Sensors, Transistor Arrays
Q: How Can We Achieve
Addressable Sites Based on 1
CNT (required to make highest
density memory chips)
A: Chemical Functionalization
Initial Result: Hydrogenation of C60
Buckminsterfullerene
Work Performed at UNH for
Collaborators at Northrup Grumman
Northrup Grumman Wanted a Faster,
Scalable Process
Innovation: Use Microwave Reactor 
Reduce Total Reaction Time to 5 minutes
Before Hydrogenation After Hydrogenation
Innovation: Apply Same Chemistry to
SWNTs  Highly Dispersed Species
30 Seconds 5 Minutes
1 Hour 2 Days
Functionalized SWNTs Stay Well
Dispersed Without Added Surfactant
H-SWNTs
H-SWNTs
H-SWNTs
H-SWNTs
SWNTs SWNTs
SWNTs SWNTs
Carbon Nanotube Memory Chip
2
ON state
OFF state
In principle… In reality…
Related Applications: SWNT Switches, Sensors, Transistor Arrays
Carbon nanotubes assembled from solution
Nanomanufacturing with Templates
S
S
I
polymer
Active Layer
(PCBM + P3HT)
Al
Solar light
I
polymer
Active Layer
(PCBM + P3HT)
Al
Solar light
Application Road Map
Nanoelements
Thrust I
Acenes
Funct.
Fullerenes
Funct. CNTs
& Graphene
Nanocups &
Nanorings
OFETs,
OLEDs
Organic
Photovoltaics
Nanotemplates
Flexible
Electronics
Polymer
composites,
EMI Shielding
Interconnects
Structural &
Electronic Mat’s
Cyclacenes &
Uniform SWNTs

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Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

  • 1. Nanotechnology at UNH: Innovative Science In Support of Next Generation Consumer Products Glen P. Miller Department of Chemistry and Materials Science Program University of New Hampshire Wild For Innovation Friday, March 5, 2010
  • 2. S S I polymer Active Layer (PCBM + P3HT) Al Solar light I polymer Active Layer (PCBM + P3HT) Al Solar light Application Road Map Nanoelements Thrust I Acenes Funct. Fullerenes Funct. CNTs & Graphene Nanocups & Nanorings OFETs, OLEDs Organic Photovoltaics Nanotemplates Flexible Electronics Polymer composites, EMI Shielding Interconnects Structural & Electronic Mat’s Cyclacenes & Uniform SWNTs
  • 3. An Example: Carbon Nanotube Memory Chip 2 ON state OFF state In principle… In reality… Related Applications: SWNT Switches, Sensors, Transistor Arrays
  • 4. Q: How Can We Achieve Addressable Sites Based on 1 CNT (required to make highest density memory chips) A: Chemical Functionalization
  • 5. Initial Result: Hydrogenation of C60 Buckminsterfullerene Work Performed at UNH for Collaborators at Northrup Grumman
  • 6. Northrup Grumman Wanted a Faster, Scalable Process Innovation: Use Microwave Reactor  Reduce Total Reaction Time to 5 minutes
  • 7. Before Hydrogenation After Hydrogenation Innovation: Apply Same Chemistry to SWNTs  Highly Dispersed Species
  • 8. 30 Seconds 5 Minutes 1 Hour 2 Days Functionalized SWNTs Stay Well Dispersed Without Added Surfactant H-SWNTs H-SWNTs H-SWNTs H-SWNTs SWNTs SWNTs SWNTs SWNTs
  • 9. Carbon Nanotube Memory Chip 2 ON state OFF state In principle… In reality… Related Applications: SWNT Switches, Sensors, Transistor Arrays
  • 10. Carbon nanotubes assembled from solution Nanomanufacturing with Templates
  • 11. S S I polymer Active Layer (PCBM + P3HT) Al Solar light I polymer Active Layer (PCBM + P3HT) Al Solar light Application Road Map Nanoelements Thrust I Acenes Funct. Fullerenes Funct. CNTs & Graphene Nanocups & Nanorings OFETs, OLEDs Organic Photovoltaics Nanotemplates Flexible Electronics Polymer composites, EMI Shielding Interconnects Structural & Electronic Mat’s Cyclacenes & Uniform SWNTs