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Plasticizers for today and
for the future
Perstorp contributes to a better more sustainable world
by delivering innovative chemical solutions
PVC Formulation 2014, Düsselsdorf
Table of Contents
Introduction of the company
Perstorp in PVC industry
Plasticizers
– Investment
– Emoltene™ 100 (DPHP, C10)
– Pevalen™ (Polyolester plasticizer)
Summary
Perstorp in brief
World leader in several sectors of the specialty chemicals market
Pioneer in formalin chemistry, plastics and surface materials
Perstorp was formed in 1881, over 130 years of winning formulas
Since December 2005 controlled by PAI partners,
a leading European private equity company
Annual turnover of more than 10 billion SEK
in 2012
About 1,500 employees in 22 countries
Production plants in Europe, Asia and
North America
Sales offices in all major markets
Perstorp in the PVC industry
Fully integrated plasticizer producer based on the west coast of
Sweden since 1980’s
Perstorp exited the DOP business in 2012
Storage facilities in UK, Belgium, Germany and Portugal to serve
entire Europe
Focus on European market and sustainable growth
Member of ECPI, VinylPlus and founding member of PlasticiserPlus
Perstorp believes in plasticizers
Perstorp is making its largest investment in history
Based on our own technology and backwardly integrated in raw
materials
It will be on stream in Q1 2015
Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM
This investment will increase the production by 150,000 MT
EmolteneTM 100 PevalenTM
Investment for a more
sustainable future
Established C10 (DPHP) GP
plasticizer
Excellent versatility and flexibility
Expands lifespan of end products
High technical performance,
with good outdoor properties
High performance
polyol ester plasticizer
Highly efficient in providing
softness
Easy to process and use
Low volatility ensuring no VOC
and consistent properties
New capacity for
Valeraldehyde and
its derivatives
Strengthen our
production platform
Fully integrated and
secure supply chain
Ability to offer
competitive and
safe products
Innovative
plasticizer
for sensitive
applications
Flexible,
versatile
& safe
Versatile general
PVS plasticizer
Emoltene™ 100 and Pevalen™
focus on different markets
Emoltene™ 100
– Durable applications
Wire and cables
Films & sheets e.g. roofing
membranes, swimming pool liners,
automotive foils
Coated fabrics; e.g. tarpaulins
Automotive interiors
Pevalen™
– Sensitive applications
Coated fabrics; e.g. table cloths,
protective clothing
Films & sheets; e.g. office materials,
furniture foils
Flooring
Plastisols; e.g. wallpaper, toys
Moulded parts; e.g. grips
Key segments where
Emoltene™ 100 is preferable
Cables & wires
Low volatility and
high UV resistance
with C10 plasticizer
Well accepted for
PVC cables at all
major users
Automotive interior
Low volatility/migration
of C10 plasticizers
secures long life span
required
Plasticized PVC not
easy substituted for
this industry due to the
advantage PVC has vs.
other polymers
Film and sheets
Low volatility of C10
plasticizers secures
long life span required
Plasticized PVC good
UV stability and outdoor
resistance
Volatility
-25
-20
-15
-10
-5
0
DPHP DINP DOP
WeightChange,%
Emoltene™ 100 (DPHP) has low volatility
Emoltene™ 100 (DPHP) makes the product
durable
Fogging
Emoltene™ 100 (DPHP) has lower fogging
Emoltene™ 100 (DPHP) is suitable for car
interiors
0
0,5
1
1,5
2
2,5
3
3,5
4
DPHP DINP DOP
mg
Migration to plastics
ABS PC PS Acrylic
TOTM Polymeric Polymeric Polymeric
DPHP TOTM TOTM TOTM
DOTP DPHP DOTP DPHP
DEHP DINP DINP DINCH
DINCH DINCH DPHP DINP
DINP DOTP DEHP DOTP
Polymeric DEHP DINCH DEHP
DOA ATBC DOA DOA
ATBC DOA ATBC ATBC
Benzoate Benzoate Benzoate Benzoate
Source: www.filmandsheet.com, www2.teknorapex.com/PVC-Plasticizer-Migration
Emoltene™ 100 (DPHP) has low migration
Emoltene™ 100 (DPHP) contributes with high
permanency
Water absorption
0,29
0,3
0,31
0,32
0,33
0,34
0,35
0,36
DPHP DINP DOP
WeightChange,%
Emoltene™ 100 (DPHP) has low water
absorption
Emoltene™ 100 (DPHP) suitable for
outdoor applications
Pevalen™
A versatile general purpose plasticizer
that is equal to or in some cases better
than standard phthalate plasticizers.
Perstorp is increasing capacity and will meet
customer demand. Perstorp will by 2015 be
fully integrated in raw materials.
At this time, Pevalen™ will be commercially
competitive to other high volume plasticizers.
The chemistry is well established and proven.
Process for food contact approval underway.
Easy storage
Pevalen™ has low viscosity even at temperatures below 0°C
Pevalen™ does not need to be heated during storage
0
0,5
1
1,5
2
2,5
-20 0 20 40 60 80
ViscosityPas
Temperature °C
Viscosity
Emoltene 100
DOTP
DOP
DINP
Dinch
Pevalen™
DINCH
Processing – top of the class
Pevalen™ has short dry blend time
Pevalen™ gives fast processing
h:01
h:01
h:01
h:01
h:01
h:01
DINCH DINP DOP DOTP Pevalen™
Time(mm/ss)
Dry blend time
Unique product performance
79
80
81
82
83
84
85
86
87
88
0 5 10 15 20 25
Hardness(ShoreA)
Volatility (% lost)
Effciency
DINCH
DINP
DOP
DOTP
Pevalen™
Pevalen™ has a unique combination of
low volatility and high plasticizing efficiency
Migration to rubber
-022
-020
-018
-016
-014
-012
-010
DINCH DINP DOP DOTP Pevalen™
(%)
Migration to rubber, 28 days
Pevalen™ has lower or equal migration to rubber
Migration to plastics
Pevalen™ has comparable migration to plastics
Pevalen™ high compatibility to PVC is also shown here it
has a tendency to migrate more to non-plasticized PVC
-020
-018
-016
-014
-012
-010
-008
-006
-004
-002
000
PVC PC PS PMMA
Migration to plastics, 28 days
Pevalen™
DINCH
DOTP
Durability
Pevalen™ has very good resistance to chemicals
Pevalen™ has same performance as other plasticizers on oil
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Heptane Hexane Olive Oil
Weightloss%
Extraction chemicals and oil
DINCH
DINP
DOP
Pevalen™
DOTP
Durability
Pevalen™ has same or better resistance to water solution as
other plasticizers
-0.1
-0.1
0.0
0.0
0.0
0.0
0.0
1 %Soap 1% NaOH
Weightloss%
Extraction water solutions
DINCH
DINP
DOP
Pevalen™
DOTP
Summary Plasticizers
Emoltene™ 100 – well-established HMW phthalate plasticizer
Available in high volumes
Highly competitive production platform
Valued for low water absorption, low volatility and migration
Reflected in improved durability, good outdoor resistance and long life span
Pevalen™ – an innovative polyol ester plasticizer
High performance polyol ester plasticizer
Highly efficient in providing softness
Easy to process and use
Low volatility and migration ensuring no VOC
and consistent properties
Thank You for your attention!
Anders Magnusson
Application Specialist
For more information please contact:
Inna Scholz
Sales Manager
Phone: +48 22 405 1527
Mobile: +48 69 504 8386
e-mail: Inna.Scholz@perstorp.com

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Pvc formulation perstorp_eng 2014

  • 1. Plasticizers for today and for the future Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions PVC Formulation 2014, Düsselsdorf
  • 2. Table of Contents Introduction of the company Perstorp in PVC industry Plasticizers – Investment – Emoltene™ 100 (DPHP, C10) – Pevalen™ (Polyolester plasticizer) Summary
  • 3. Perstorp in brief World leader in several sectors of the specialty chemicals market Pioneer in formalin chemistry, plastics and surface materials Perstorp was formed in 1881, over 130 years of winning formulas Since December 2005 controlled by PAI partners, a leading European private equity company Annual turnover of more than 10 billion SEK in 2012 About 1,500 employees in 22 countries Production plants in Europe, Asia and North America Sales offices in all major markets
  • 4. Perstorp in the PVC industry Fully integrated plasticizer producer based on the west coast of Sweden since 1980’s Perstorp exited the DOP business in 2012 Storage facilities in UK, Belgium, Germany and Portugal to serve entire Europe Focus on European market and sustainable growth Member of ECPI, VinylPlus and founding member of PlasticiserPlus
  • 5. Perstorp believes in plasticizers Perstorp is making its largest investment in history Based on our own technology and backwardly integrated in raw materials It will be on stream in Q1 2015 Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM This investment will increase the production by 150,000 MT
  • 6. EmolteneTM 100 PevalenTM Investment for a more sustainable future Established C10 (DPHP) GP plasticizer Excellent versatility and flexibility Expands lifespan of end products High technical performance, with good outdoor properties High performance polyol ester plasticizer Highly efficient in providing softness Easy to process and use Low volatility ensuring no VOC and consistent properties New capacity for Valeraldehyde and its derivatives Strengthen our production platform Fully integrated and secure supply chain Ability to offer competitive and safe products Innovative plasticizer for sensitive applications Flexible, versatile & safe Versatile general PVS plasticizer
  • 7. Emoltene™ 100 and Pevalen™ focus on different markets Emoltene™ 100 – Durable applications Wire and cables Films & sheets e.g. roofing membranes, swimming pool liners, automotive foils Coated fabrics; e.g. tarpaulins Automotive interiors Pevalen™ – Sensitive applications Coated fabrics; e.g. table cloths, protective clothing Films & sheets; e.g. office materials, furniture foils Flooring Plastisols; e.g. wallpaper, toys Moulded parts; e.g. grips
  • 8. Key segments where Emoltene™ 100 is preferable Cables & wires Low volatility and high UV resistance with C10 plasticizer Well accepted for PVC cables at all major users Automotive interior Low volatility/migration of C10 plasticizers secures long life span required Plasticized PVC not easy substituted for this industry due to the advantage PVC has vs. other polymers Film and sheets Low volatility of C10 plasticizers secures long life span required Plasticized PVC good UV stability and outdoor resistance
  • 9. Volatility -25 -20 -15 -10 -5 0 DPHP DINP DOP WeightChange,% Emoltene™ 100 (DPHP) has low volatility Emoltene™ 100 (DPHP) makes the product durable
  • 10. Fogging Emoltene™ 100 (DPHP) has lower fogging Emoltene™ 100 (DPHP) is suitable for car interiors 0 0,5 1 1,5 2 2,5 3 3,5 4 DPHP DINP DOP mg
  • 11. Migration to plastics ABS PC PS Acrylic TOTM Polymeric Polymeric Polymeric DPHP TOTM TOTM TOTM DOTP DPHP DOTP DPHP DEHP DINP DINP DINCH DINCH DINCH DPHP DINP DINP DOTP DEHP DOTP Polymeric DEHP DINCH DEHP DOA ATBC DOA DOA ATBC DOA ATBC ATBC Benzoate Benzoate Benzoate Benzoate Source: www.filmandsheet.com, www2.teknorapex.com/PVC-Plasticizer-Migration Emoltene™ 100 (DPHP) has low migration Emoltene™ 100 (DPHP) contributes with high permanency
  • 12. Water absorption 0,29 0,3 0,31 0,32 0,33 0,34 0,35 0,36 DPHP DINP DOP WeightChange,% Emoltene™ 100 (DPHP) has low water absorption Emoltene™ 100 (DPHP) suitable for outdoor applications
  • 13. Pevalen™ A versatile general purpose plasticizer that is equal to or in some cases better than standard phthalate plasticizers. Perstorp is increasing capacity and will meet customer demand. Perstorp will by 2015 be fully integrated in raw materials. At this time, Pevalen™ will be commercially competitive to other high volume plasticizers. The chemistry is well established and proven. Process for food contact approval underway.
  • 14. Easy storage Pevalen™ has low viscosity even at temperatures below 0°C Pevalen™ does not need to be heated during storage 0 0,5 1 1,5 2 2,5 -20 0 20 40 60 80 ViscosityPas Temperature °C Viscosity Emoltene 100 DOTP DOP DINP Dinch Pevalen™ DINCH
  • 15. Processing – top of the class Pevalen™ has short dry blend time Pevalen™ gives fast processing h:01 h:01 h:01 h:01 h:01 h:01 DINCH DINP DOP DOTP Pevalen™ Time(mm/ss) Dry blend time
  • 16. Unique product performance 79 80 81 82 83 84 85 86 87 88 0 5 10 15 20 25 Hardness(ShoreA) Volatility (% lost) Effciency DINCH DINP DOP DOTP Pevalen™ Pevalen™ has a unique combination of low volatility and high plasticizing efficiency
  • 17. Migration to rubber -022 -020 -018 -016 -014 -012 -010 DINCH DINP DOP DOTP Pevalen™ (%) Migration to rubber, 28 days Pevalen™ has lower or equal migration to rubber
  • 18. Migration to plastics Pevalen™ has comparable migration to plastics Pevalen™ high compatibility to PVC is also shown here it has a tendency to migrate more to non-plasticized PVC -020 -018 -016 -014 -012 -010 -008 -006 -004 -002 000 PVC PC PS PMMA Migration to plastics, 28 days Pevalen™ DINCH DOTP
  • 19. Durability Pevalen™ has very good resistance to chemicals Pevalen™ has same performance as other plasticizers on oil -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Heptane Hexane Olive Oil Weightloss% Extraction chemicals and oil DINCH DINP DOP Pevalen™ DOTP
  • 20. Durability Pevalen™ has same or better resistance to water solution as other plasticizers -0.1 -0.1 0.0 0.0 0.0 0.0 0.0 1 %Soap 1% NaOH Weightloss% Extraction water solutions DINCH DINP DOP Pevalen™ DOTP
  • 21. Summary Plasticizers Emoltene™ 100 – well-established HMW phthalate plasticizer Available in high volumes Highly competitive production platform Valued for low water absorption, low volatility and migration Reflected in improved durability, good outdoor resistance and long life span Pevalen™ – an innovative polyol ester plasticizer High performance polyol ester plasticizer Highly efficient in providing softness Easy to process and use Low volatility and migration ensuring no VOC and consistent properties
  • 22. Thank You for your attention! Anders Magnusson Application Specialist For more information please contact: Inna Scholz Sales Manager Phone: +48 22 405 1527 Mobile: +48 69 504 8386 e-mail: Inna.Scholz@perstorp.com