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CEMENT
CONTENTS

       Introduction
        Definition
          History
       Classification
          Grades
       Manufacture
      Characteristics
   Common applications
Advantages and disadvantages
        Conclusion
INTRODUCTION


  The word "cement" traces to the Romans, who
       used the term opus caementicium to
 describe masonry resembling modern concrete
that was made from crushed rock with burnt lime
         as binder. The volcanic ash and
pulverized brick additives that were added to the
burnt lime to obtain a hydraulic binder were later
                    referred to
 as cementum, cimentum, cäment, and cement.
DEFINITION
       Cements       are materials that
exhibit characteristic properties of setting
and hardening when mixed to a paste
with water. This makes them join rigid
masses into coherent structures. It is
powdery     bonding      material    having
adhesive and cohesive properties.

       Chemically it is a finely ground
mixture   of    calcium     silicates and
aluminates which set to a hard mass
when treated with water. These are called
as Hydraulic Cements (Portland Cement)
and those setting in air are Non Hydraulic
cements (Ordinary Lime).
HISTORY

  It is uncertain where it was first discovered that a
   combination of hydrated non-hydraulic lime and
   a pozzolan produces a hydraulic mixture, but
   concrete made from such mixtures was first used
   by the Ancient Macedonians and three centuries
   later on a large scale by Roman engineers. They
   used both natural pozzolans (trass or pumice) and
   artificial pozzolans (ground brick or pottery) in
   these concretes. Many excellent examples of
   structures made from these concretes are still
   standing, notably the huge dome of
   the Pantheon in Rome and the massive Baths of
   Caracalla. The vast system of Roman
   aqueducts also made extensive use of hydraulic
   cement.
    The technical knowledge of making hydraulic
   cement was later formalized by French and British
   engineers in the 18th century.
Modern hydraulic cements began to be developed
from the start of the Industrial Revolution (around
1800).
 Cement was first made by Joseph Aspdin in 1824
   in England.
CLASSIFICATION OF CEMENT

•Natural     Cement:    Obtained   by
calcinating and pulverizing natural
cement rock of argillaceous and clay
with limestone. It does not have
sufficient strength and is cheap and
quick    setting   &  have   hydraulic
properties.

•Pozzolana Cement: Volcanic ash
containing silicates of calcium, iron and
aluminum when mixed with lime and
heated produces this cement.

•Slag Cement: Mixture of blast furnace
slag (Ca and Al Silicates) and hydrated
lime.   Sometimes     accelerators  like
clay, salt, caustic soda are added to
hasten hardening process.

•Portland Cement: It consists of
compounds of lime, silica, alumina and
iron. When mixed with water it forms a
paste which binds the rock, sand and
gravel to form concrete.
GRADES OF PORTLAND
                     CEMENT

 33 grade –General Construction
  like plastering, finishing
  works etc, where strenth is not required.

 43 grade –Useful for structural
  works, precast items etc, Strength development is
  faster than 33 grade.

 53 grade–Used for multi-storey buildings, precast
  pre-stressed items, bridges, tall structures,etc.
  Develops very fast strength and speeds up
  construction.
MANUFACTURE OF PORTLAND CEMENT
            •Crushing
      •Mixing (Wet Process)
      •Mixing (Dry Process)
•Grinding (Ball Mill and Tube Mill)
  •Storage of Ground Materials
             •Burning
          –Drying Zone
        –Calcination Zone
         –Clinkering Zone
            •Grinding
            –Retarder
        –Dispersing Agent
         –Water Proofing


           •Packaging
CRUSHING

This is the first step in the manufacture of
              Portland Cement.

Jaw crushers of various sizes           are
employed for the crushing purpose.

Raw materials are crushed by crushers till
the size of the raw material reduces to ¾
of an inch.

It is than send for either Wet process or
Dry process. Wet process is universally
employed.
MIXING PROCESS
                          Wet process
Calcareous materials are crushed, powdered and stored in bins.
Argillaceous materials is mixed with water and washed. This removes
any adhering organic impurities.
Powdered Calcareous and Washed Argillaceous materials are mixed in
proper proportions to get a slurry.
Chemical composition is analyzed and corrected if necessary by addition
of the deficient materials.
This slurry is then fed into the rotary klin.


                           Dry process
Hard raw materials like cement rock or blast furnace slag are first crushed
to 50mm pieces in ball mill, then dried and stored.
Crushing is done by gyratory crushers and drying is done by rotary driers.
Separate powdered ingredients are mixed in required proportions to get
the raw mix which is then fed to rotary klins.
STORAGE OF
                GROUND MATERIALS


The ground materials containing 30 – 40% of water is stored
in separate tanks equipped with agitators.

This step is followed by process of burning.
BURNING




Slurry is burnt in rotary klin where actual chemical changes takes place.
Klin is long steel cylinder 30-40 meter in length, 2-4 meter in
diameter, lined by refractory bricks. It is inclined at gradient of 0.5-0.75
inch and can be rotated at the desired speed.
The material is introduced in the klin from the upper end as the klin
rotates material passes slowly towards the lower end.
Klin is heated by burning pulverized coal or oil and temperature is
maintained at about 1400-1500°C. At clinkering temperature actual
chemical reactions takes place.
GRINDING
          Grinding can be done in two stages

•Ball Mill


–Consists of cast iron drum containing iron and
steel balls of different sizes. The principle used in
ball mill s impact and shear produced by large
no. of tumbling and rolling balls.

•Tube Mill


–Ball mill grinding is followed by tube mill
grinding. Tube mill is conical at the discharge end
with separate inlet and outlet.
–Slower is the feeding speed finer is the product
coming out of the tube mill.
GRINDING
        Clinkers are finally grinded in ball mill and tube
mill to a fine powder. Additives added are as follows.

        Retarder:
        Gypsum or Plaster of Paris acts as retarder to
prevent quick setting. After initial setting gypsum retards
the dissolution of tricalcium aluminate by forming
tricalcium sulphoaluminate.

       Dispersing Agent:
       Sodium salts and polymers of condensed
napthlene or sulphonic acid are added to prevent the
formation of lumps and cakes in the cement.
       Water proofing agents are also added.
PACKAGING


      The ground powder is
      packed    by     automatic
      machines in a bag.

      This is then dispatched to
      the markets where it is
      sold.
CHARACTERISTICS OF
                      CEMENT



 When water is added to initiate dry mixtures of
  cement and sand, hydration of cement starts and it
  will binds sand particles as well as the surrounding
  surfaces of masonry and concrete.
 The proportion of cement and sand will decide the
  strength of mortar.
 A richer mix than 1:3 proportion is prone to
  shrinkage.
 Solid surface are provided by well proportioned
  mortar.
 A leaner mix is not able of closing the voids in sand.
COMMON APPLICATIONS
                  OF CEMENT

 Building
  (floors, beams, columns, roofing, piles, bricks,
  mortar, panels, plaster).
 Transport
  (roads, pathways, crossings, bridges, sleepers,
  viaducts, tunnels, stabilization, runways, parkin
  g).
 Water
  (pipes, culverts, kerbing, drains, canals, weirs, d
  ams, tanks, pools).
 Civil (piers, docks, retaining
  walls, silos, warehousing, poles, pylons, fencing)
  .
ADVANTAGES AND
                   DISADVANTAGES

                       Advantages:

                  Cement is very strong.
          It can create large structures quickly.
 It conforms to different shapes (arcs and circles, etc).
  It has high thermal mass (moderates temperature).

                         Disadvantages:
              Cement is subjected to cracking.
 It is very difficult to provide idoneous curing conditions.
It is not ideal for situation when settlement is expected.
CONCLUSION

 Cement is a binder, a substance that sets and hardens
  independently, and can bind other materials together.
 It was first made by Joseph Aspdin in 1824 in England.
 It is Classified as Natural Cement, Pozzolana Cement, Slag
  Cement, Portland Cement.
 Portland cement is most commonly used.
 Its manufacturing process consists of Crushing, Mixing (Wet
  Process), Mixing (Dry Process), Grinding (Ball Mill and Tube
  Mill), Storage of Ground Materials, Burning, Packaging and
  finally transporting to sell.
 It is most commonly used in building construction, civil, water
  carrying and storage, transportation and agriculture.
THANK YOU

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Cement

  • 2. CONTENTS Introduction Definition History Classification Grades Manufacture Characteristics Common applications Advantages and disadvantages Conclusion
  • 3. INTRODUCTION The word "cement" traces to the Romans, who used the term opus caementicium to describe masonry resembling modern concrete that was made from crushed rock with burnt lime as binder. The volcanic ash and pulverized brick additives that were added to the burnt lime to obtain a hydraulic binder were later referred to as cementum, cimentum, cäment, and cement.
  • 4. DEFINITION Cements are materials that exhibit characteristic properties of setting and hardening when mixed to a paste with water. This makes them join rigid masses into coherent structures. It is powdery bonding material having adhesive and cohesive properties. Chemically it is a finely ground mixture of calcium silicates and aluminates which set to a hard mass when treated with water. These are called as Hydraulic Cements (Portland Cement) and those setting in air are Non Hydraulic cements (Ordinary Lime).
  • 5. HISTORY  It is uncertain where it was first discovered that a combination of hydrated non-hydraulic lime and a pozzolan produces a hydraulic mixture, but concrete made from such mixtures was first used by the Ancient Macedonians and three centuries later on a large scale by Roman engineers. They used both natural pozzolans (trass or pumice) and artificial pozzolans (ground brick or pottery) in these concretes. Many excellent examples of structures made from these concretes are still standing, notably the huge dome of the Pantheon in Rome and the massive Baths of Caracalla. The vast system of Roman aqueducts also made extensive use of hydraulic cement.  The technical knowledge of making hydraulic cement was later formalized by French and British engineers in the 18th century. Modern hydraulic cements began to be developed from the start of the Industrial Revolution (around 1800).  Cement was first made by Joseph Aspdin in 1824 in England.
  • 6. CLASSIFICATION OF CEMENT •Natural Cement: Obtained by calcinating and pulverizing natural cement rock of argillaceous and clay with limestone. It does not have sufficient strength and is cheap and quick setting & have hydraulic properties. •Pozzolana Cement: Volcanic ash containing silicates of calcium, iron and aluminum when mixed with lime and heated produces this cement. •Slag Cement: Mixture of blast furnace slag (Ca and Al Silicates) and hydrated lime. Sometimes accelerators like clay, salt, caustic soda are added to hasten hardening process. •Portland Cement: It consists of compounds of lime, silica, alumina and iron. When mixed with water it forms a paste which binds the rock, sand and gravel to form concrete.
  • 7. GRADES OF PORTLAND CEMENT  33 grade –General Construction like plastering, finishing works etc, where strenth is not required.  43 grade –Useful for structural works, precast items etc, Strength development is faster than 33 grade.  53 grade–Used for multi-storey buildings, precast pre-stressed items, bridges, tall structures,etc. Develops very fast strength and speeds up construction.
  • 8. MANUFACTURE OF PORTLAND CEMENT •Crushing •Mixing (Wet Process) •Mixing (Dry Process) •Grinding (Ball Mill and Tube Mill) •Storage of Ground Materials •Burning –Drying Zone –Calcination Zone –Clinkering Zone •Grinding –Retarder –Dispersing Agent –Water Proofing •Packaging
  • 9. CRUSHING This is the first step in the manufacture of Portland Cement. Jaw crushers of various sizes are employed for the crushing purpose. Raw materials are crushed by crushers till the size of the raw material reduces to ¾ of an inch. It is than send for either Wet process or Dry process. Wet process is universally employed.
  • 10. MIXING PROCESS Wet process Calcareous materials are crushed, powdered and stored in bins. Argillaceous materials is mixed with water and washed. This removes any adhering organic impurities. Powdered Calcareous and Washed Argillaceous materials are mixed in proper proportions to get a slurry. Chemical composition is analyzed and corrected if necessary by addition of the deficient materials. This slurry is then fed into the rotary klin. Dry process Hard raw materials like cement rock or blast furnace slag are first crushed to 50mm pieces in ball mill, then dried and stored. Crushing is done by gyratory crushers and drying is done by rotary driers. Separate powdered ingredients are mixed in required proportions to get the raw mix which is then fed to rotary klins.
  • 11. STORAGE OF GROUND MATERIALS The ground materials containing 30 – 40% of water is stored in separate tanks equipped with agitators. This step is followed by process of burning.
  • 12. BURNING Slurry is burnt in rotary klin where actual chemical changes takes place. Klin is long steel cylinder 30-40 meter in length, 2-4 meter in diameter, lined by refractory bricks. It is inclined at gradient of 0.5-0.75 inch and can be rotated at the desired speed. The material is introduced in the klin from the upper end as the klin rotates material passes slowly towards the lower end. Klin is heated by burning pulverized coal or oil and temperature is maintained at about 1400-1500°C. At clinkering temperature actual chemical reactions takes place.
  • 13. GRINDING Grinding can be done in two stages •Ball Mill –Consists of cast iron drum containing iron and steel balls of different sizes. The principle used in ball mill s impact and shear produced by large no. of tumbling and rolling balls. •Tube Mill –Ball mill grinding is followed by tube mill grinding. Tube mill is conical at the discharge end with separate inlet and outlet. –Slower is the feeding speed finer is the product coming out of the tube mill.
  • 14. GRINDING Clinkers are finally grinded in ball mill and tube mill to a fine powder. Additives added are as follows. Retarder: Gypsum or Plaster of Paris acts as retarder to prevent quick setting. After initial setting gypsum retards the dissolution of tricalcium aluminate by forming tricalcium sulphoaluminate. Dispersing Agent: Sodium salts and polymers of condensed napthlene or sulphonic acid are added to prevent the formation of lumps and cakes in the cement. Water proofing agents are also added.
  • 15. PACKAGING The ground powder is packed by automatic machines in a bag. This is then dispatched to the markets where it is sold.
  • 16. CHARACTERISTICS OF CEMENT  When water is added to initiate dry mixtures of cement and sand, hydration of cement starts and it will binds sand particles as well as the surrounding surfaces of masonry and concrete.  The proportion of cement and sand will decide the strength of mortar.  A richer mix than 1:3 proportion is prone to shrinkage.  Solid surface are provided by well proportioned mortar.  A leaner mix is not able of closing the voids in sand.
  • 17. COMMON APPLICATIONS OF CEMENT  Building (floors, beams, columns, roofing, piles, bricks, mortar, panels, plaster).  Transport (roads, pathways, crossings, bridges, sleepers, viaducts, tunnels, stabilization, runways, parkin g).  Water (pipes, culverts, kerbing, drains, canals, weirs, d ams, tanks, pools).  Civil (piers, docks, retaining walls, silos, warehousing, poles, pylons, fencing) .
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  • 19. ADVANTAGES AND DISADVANTAGES Advantages: Cement is very strong. It can create large structures quickly. It conforms to different shapes (arcs and circles, etc). It has high thermal mass (moderates temperature). Disadvantages: Cement is subjected to cracking. It is very difficult to provide idoneous curing conditions. It is not ideal for situation when settlement is expected.
  • 20. CONCLUSION  Cement is a binder, a substance that sets and hardens independently, and can bind other materials together.  It was first made by Joseph Aspdin in 1824 in England.  It is Classified as Natural Cement, Pozzolana Cement, Slag Cement, Portland Cement.  Portland cement is most commonly used.  Its manufacturing process consists of Crushing, Mixing (Wet Process), Mixing (Dry Process), Grinding (Ball Mill and Tube Mill), Storage of Ground Materials, Burning, Packaging and finally transporting to sell.  It is most commonly used in building construction, civil, water carrying and storage, transportation and agriculture.