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Spintronics

A new class of device based on the quantum of electron spin, rather than
on charge, may yield the next generation of microelectronics


Sankar Das Sarma



T    he last half of the 20th century, it
     has been argued with considerable
justification, could be called the micro-
                                                      carrying out processing and data stor-
                                                      age on the same chip), investigators
                                                      have been eager to exploit another
                                                                                                   the flow of charge. In fact, the spin-
                                                                                                   tronics dream is a seamless integration
                                                                                                   of electronic, optoelectronic and mag-
electronics era. During that 50-year pe-              property of the electron—a characteris-      netoelectronic multifunctionality on a
riod, the world witnessed a revolution                tic known as spin. Spin is a purely          single device that can perform much
based on a digital logic of electrons.                quantum phenomenon roughly akin to           more than is possible with today’s mi-
From the earliest transistor to the re-               the spinning of a child’s top or the di-     croelectronic devices.
markably powerful microprocessor in                   rectional behavior of a compass needle.
your desktop computer, most electron-                 The top could spin in the clockwise or       The Logic Of Spin
ic devices have employed circuits that                counterclockwise direction; electrons        Spin relaxation (how spins are created
express data as binary digits, or bits—               have spin of a sort in which their com-      and disappear) and spin transport
ones and zeroes represented by the ex-                pass needles can point either “up” or        (how spins move in metals and semi-
istence or absence of electric charge.                “down” in relation to a magnetic field.      conductors) are fundamentally impor-
Furthermore, the communication be-                    Spin therefore lends itself elegantly to a   tant not only as basic physics questions
tween microelectronic devices occurs                  new kind of binary logic of ones and         but also because of their demonstrated
by the binary flow of electric charges.               zeros. The movement of spin, like the        value as phenomena in electronic tech-
The technologies that emerged from                    flow of charge, can also carry informa-      nology. One device already in use is the
this simple logic have created a multi-               tion among devices. One advantage of         giant magnetoresistive, or GMR, sand-
trillion dollar per year global industry              spin over charge is that spin can be eas-    wich structure, which consists of alter-
whose products are ubiquitous. In-                    ily manipulated by externally applied        nating ferromagnetic (that is, perma-
deed, the relentless growth of micro-                 magnetic fields, a property already in       nently magnetized) and nonmagnetic
electronics is often popularly summa-                 use in magnetic storage technology.          metal layers. Depending on the relative
rized in Moore’s Law, which holds that                Another more subtle (but potentially         orientation of the magnetizations in the
microprocessors will double in power                  significant) property of spin is its long    magnetic layers, the electrical resistance
every 18 months as electronic devices                 coherence, or relaxation, time—once          through the layers changes from small
shrink and more logic is packed into                  created it tends to stay that way for a      (parallel magnetizations) to large (an-
every chip.                                           long time, unlike charge states, which       tiparallel magnetizations). Investigators
   Yet even Moore’s Law will run out                  are easily destroyed by scattering or        discovered that they could use this
of momentum one day as the size of                    collision with defects, impurities or        change in resistance (called magnetore-
individual bits approaches the dimen-                 other charges.                               sistance, and “giant” because of the
sion of atoms—this has been called the                   These characteristics open the possi-     large magnitude of the effect in this
end of the silicon road map. For this                 bility of developing devices that could      case) to construct exquisitely sensitive
reason and also to enhance the multi-                 be much smaller, consume less electric-      detectors of changing magnetic fields,
functionality of devices (for example,                ity and be more powerful for certain         such as those marking the data on a
                                                      types of computations than is possible       computer hard-disk platter. These disk
Sankar Das Sarma is Distinguished University          with electron-charge-based systems.          drive read/write heads have been
Professor at the University of Maryland, College      Those of us in the spintronics (short for    wildly successful, permitting the stor-
Park, where he has been on the physics faculty
                                                      spin electronics) community hope that        age of tens of gigabytes of data on note-
since 1980. He received his Ph.D. from Brown
                                                      by understanding the behavior of elec-       book computer hard drives, and have
University in 1979. He is a widely published and
highly cited theoretical condensed matter physicist   tron spin in materials we can learn          created a billion-dollar per year indus-
with broad research interests in electronic proper-   something fundamentally new about            try. Groups have also been working to
ties of materials and nonequilibrium statistical      solid state physics that will lead to a      develop nonvolatile memory elements
mechanics. Internet: dassarma@physics.umd.edu;        new generation of electronic devices         from these materials, possibly a route
http://www.physics.umd.edu/rgroups/spin/              based on the flow of spin in addition to     to instant-on computers.

516   American Scientist, Volume 89
Figure 1. Physicists and engineers are creating an entirely new generation of microelectronic devices that operate on a quantum mechanical
property of electrons called “spin” rather than on the electron’s electrical charge. These investigators are racing to use spin effects to create
transistors and other circuit elements, including quantum computers, in a field known as spintronics. Shown here is an artist’s depiction of a
proposal by Bruce Kane, now at the University of Maryland, for a quantum computer based on the nuclear spin of phosphorus atoms. The
quantum properties of superposition and entanglement may someday permit quantum computers to perform certain types of computations
much more quickly using less power than is possible with conventional charge-based devices. For an explanation of how a quantum com-
puter might work, see Figure 7.


    Researchers and developers of spin-          function as spin polarizers and spin              applications, many basic questions per-
tronic devices currently take two differ-        valves. This is crucial because, unlike           taining to combining semiconductors
ent approaches. In the first, they seek to       semiconductor transistors, existing met-          with other materials to produce viable
perfect the existing GMR-based technol-          al-based devices do not amplify signals           spintronic technology remain unan-
ogy either by developing new materials           (although they are successful switches or         swered. For example, it is far from well
with larger populations of oriented spins        valves). If spintronic devices could be           understood whether or how placing a
(called spin polarization) or by making          made from semiconductors, however,                semiconductor in contact with another
improvements in existing devices to pro-         then in principle they would provide              material would impede spin transport
vide better spin filtering. The second ef-       amplification and serve, in general, as           across the interface. In the past, our
fort, which is more radical, focuses on          multi-functional devices. Perhaps even            strategy for understanding spin trans-
finding novel ways both to generate and          more importantly, semiconductor-based             port in hybrid semiconductor struc-
to utilize spin-polarized currents—that          devices could much more easily be inte-           tures was to borrow knowledge ob-
is, to actively control spin dynamics. The       grated with traditional semiconductor             tained from studies of more traditional
intent is to thoroughly investigate spin         technology.                                       magnetic materials. More recently,
transport in semiconductors and search              Although semiconductors offer clear            however, investigators have begun di-
for ways in which semiconductors can             advantages for use in novel spintronic            rect investigation of spin transport

                                                                                                            2001    November–December        517
(similar, in effect, to the source and
                                                                                                   drain, respectively, in a field effect tran-
                                                                                                   sistor). The emitter emits electrons with
                                                                                                   their spins oriented along the direction
                                                                                                   of the electrode’s magnetization, while
                                                                                                   the collector (with the same electrode
                                                                                                   magnetization) acts as a spin filter and
                                                                                                   accepts electrons with the same spin
                                                                                                   only. In the absence of any changes to
                                                                                                   the spins during transport, every emit-
                                                                                                   ted electron enters the collector. In this
random spin                                      spin alignment                                    device, the gate electrode produces a
                                                                                                   field that forces the electron spins to
                                                                                                   precess, just like the precession of a
                                                                                                   spinning top under the force of gravity.
                                                                                                   The electron current is modulated by
                                                                                                   the degree of precession in electron
                                                                                                   spin introduced by the gate field: An
                                                                                                   electron passes through the collector if
                                                                                                   its spin is parallel, and does not if it is
                                                                                                   antiparallel, to the magnetization. The
                                                                                                   Datta-Das effect should be most visible
                                                                                                   for narrow band-gap semiconductors
                                                                                                   such as InGaAs, which have relatively
                                                                                                   large spin-orbit interactions (that is, a
unmagnetized                                     magnetized                                        magnetic field introduced by the gate
                                                                                                   current has a relatively large effect on
Figure 2. Spins can arrange themselves in a variety of ways that are important for spintronic
devices. They can be completely random, with their spins pointing in every possible direc-         electron spin). Despite several years of
tion and located throughout a material in no particular order (upper left). Or these randomly      effort, however, the effect has yet to be
located spins can all point in the same direction, called spin alignment (upper right). In solid   convincingly demonstrated experi-
state materials, the spins might be located in an orderly fashion on a crystal lattice (lower      mentally.
left) forming a nonmagnetic material. Or the spins may be on a lattice and be aligned as in a         Another interesting concept is the
magnetic material (lower right).                                                                   all-metal spin transistor developed by
                                                                                                   Mark Johnson at the Naval Research
across interfaces in all-semiconductor           spin devices may be well suited to                Laboratory. Its trilayer structure con-
devices. In such a scenario a combina-           such tasks, since spin is an intrinsically        sists of a nonmagnetic metallic layer
tion of optical manipulation (for exam-          quantum property.                                 sandwiched between two ferromag-
ple, shining circularly polarized light                                                            nets. The all-metal transistor has the
on a material to create net spin polar-          Spintronic Devices                                same design philosophy as do giant
ization) and material inhomogeneities            The first scheme for a spintronic device          magnetoresistive devices: The current
(by suitable doping as in a recently dis-        based on the metal-oxide-semiconduc-              flowing through the structure is modi-
covered class of gallium-manganese-              tor technology familiar to microelec-             fied by the relative orientation of the
arsenide ferromagnetic materials) can            tronics designers was the field effect            magnetic layers, which in turn can be
be employed to tailor spin transport             spin transistor proposed in 1989 by               controlled by an applied magnetic
properties.                                      Supriyo Datta and Biswajit Das of Pur-            field. In this scheme, a battery is con-
   In addition to the near-term studies          due University. In a conventional field           nected to the control circuit (emitter-
of various spin transistors and spin             effect transistor, electric charge is intro-      base), while the direction of the current
transport properties of semiconduc-              duced via a source electrode and col-             in the working circuit (base-collector)
tors, a long-term and ambitious sub-             lected at a drain electrode. A third elec-        is effectively switched by changing the
field of spintronics is the application of       trode, the gate, generates an electric            magnetization of the collector. The cur-
electron and nuclear spins to quantum            field that changes the size of the chan-          rent is drained from the base in order
information processing and quantum               nel through which the source-drain                to allow for the working current to
computation. The late Richard Feyn-              current can flow, akin to stepping on a           flow under the “reverse” base-collec-
man and others have pointed out that             garden hose. This results in a very               tor bias (antiparallel magnetizations).
quantum mechanics may provide great              small electric field being able to control        Neither current nor voltage is ampli-
advantages over classical physics in             large currents.                                   fied, but the device acts as a switch or
computation. However, the real boom                 In the Datta-Das device, a structure           spin valve to sense changes in an exter-
started after Peter Shor of Bell Labs de-        made from indium-aluminum-ar-                     nal magnetic field. A potentially signif-
vised a quantum algorithm that would             senide and indium-gallium-arsenide                icant feature of the Johnson transistor
factor very large numbers into primes,           provides a channel for two-dimension-             is that, being all metallic, it can in prin-
an immensely difficult task for conven-          al electron transport between two fer-            ciple be made extremely small using
tional computers and the basis for               romagnetic electrodes. One electrode              nanolithographic techniques (perhaps
modern encryption. It turns out that             acts as an emitter, the other a collector         as small as tens of nanometers). An im-

518   American Scientist, Volume 89
portant disadvantage of Johnson’s
transistor is that, being all-metallic, it
will be difficult to integrate this spin                                      gate V
transistor device into existing semicon-
ductor microelectronic circuitry.                 ferromagnetic emitter                                           ferromagnetic collector
   As noted previously, a critical disad-
vantage of metal-based spintronic de-                                                      InAlAs
vices is that they do not amplify sig-
nals. There is no obvious metallic                                                         InGaAs
analog of the traditional semiconductor
transistor in which draining one elec-
tron from the base allows tens of elec-
trons to pass from the emitter into the
collector (by reducing the electrostatic
barrier generated by electrons trapped
in the base). Motivated by the possibili-      ferromagnetic                                                                    ferromagnetic
ty of having both spin polarization and            emitter                                                                         collector
amplification, my group has recently
studied a prototype device, the spin-
polarized p-n junction. (In the p, or pos-                                                  InAlAs
itive, region the electrons are the mi-
nority carriers, holes the majority; in the
n, or negative, region the roles are re-
versed.) In our scheme we illuminate
the surface of the p-type region of a gal-
lium arsenide p-n junction with circu-                                                     InGaAs
larly polarized light to optically orient
the minority electrons. By performing
a realistic device-modeling calculation
we have discovered that the spin can
be effectively transferred from the p
side into the n side, via what we call
spin pumping through the minority              ferromagnetic                                                                    ferromagnetic
channel. In effect, the spin gets ampli-           emitter                                                                         collector
fied going from the p to the n region
through the depletion layer.                                                                InAlAs
   One possible application of our pro-
posed spin-polarized p-n junction is
something we call the spin-polarized
solar cell. As in ordinary solar cells,
light illuminates the depletion layer of
a semiconductor (such as gallium ar-                                                       InGaAs
senide), generating electron-hole pairs.
The huge built-in electric field in the
layer (typically 104 volts per centime-
ter) swiftly sweeps electrons into the n      Figure 3. Datta-Das spin transistor was the first spintronic device to be proposed for fabrica-
region and holes into the p region. If a      tion in a metal-oxide-semiconductor geometry familiar in conventional microelectronics. An
wire connects the edges of the junction,      electrode made of a ferromagnetic material (purple) emits spin-aligned electrons (red
                                              spheres), which pass through a narrow channel (blue) controlled by the gate electrode (gold)
a current flows. If the light is circularly
                                              and are collected by another ferromagnetic electrode (top). With the gate voltage off, the
polarized (from filtered solar photons,       aligned spins pass through the channel and are collected at the other side (middle). With the
for instance), the generated electrons are    gate voltage on, the field produces magnetic interaction that causes the spins to precess, like
spin polarized. (Holes in III-V semicon-      spinning tops in a gravity field. If the spins are not aligned with the direction of magnetiza-
ductors—for example, gallium arsenide,        tion of the collector, no current can pass. In this way, the emitter-collector current is modulat-
indium arsenide and others—which are          ed by the gate electrode. As yet, no convincingly successful application of this proposal has
most useful for opto-spin-electronic          been demonstrated.
purposes, lose their spin very quickly,
so that their polarization can be ne-                                  ˇ
                                                 Most recently, Igor Zutic , Jaroslav
                                                                           ´                    junction around the electrodes. If the
glected.) As the spin-polarized elec-         Fabian and I have proposed a new kind             depletion layer is wider than the elec-
trons created in the depletion layer          of magnetic field effect transistor. Elec-        trodes, no (or very small) electric cur-
pump the spin into the n region, the re-      trodes of an external circuit are placed          rent flows. As the width decreases,
sulting current is spin polarized.            perpendicular to the p-n junction. The            more and more electrons come into
Hence, photons of light are converted         current is determined by the amount of            contact with the electrodes and the cur-
into oriented spins.                          available electrons in the region of the          rent rapidly increases. Traditionally,

                                                                                                          2001    November–December         519
is spin-polarized. Today, the range of
                                                                                                   materials we can study has significant-
                                                                                                   ly increased, including novel ferro-
                                                                                                   magnetic semiconductors, high-tem-
                    base                                                                           perature superconductors and carbon
                                                                                                   nanotubes. But several questions—
                                                                                                   such as the role of the interface sepa-
                                                                                                   rating different materials and how to
                                                                                                   create and measure spin polarization—
        collector            emitter
                                                                                                   still remain open and are of fundamen-
                                                                                                   tal importance to novel spintronic ap-
                                                                                                   plications.
                                                                                                      As devices decrease in size, the scat-
Figure 4. In the spin transistor invented by Mark Johnson, two ferromagnetic electrodes—           tering from interfaces plays a domi-
the emitter and collector—sandwich a nonmagnetic layer—the base. When the ferromagnets             nant role. In these hybrid structures the
are aligned, current flows from emitter to collector (left). But when the ferromagnets have        presence of magnetically active inter-
different directions of magnetization, the current flows out of the base to emitter and collec-    faces can lead to spin-dependent trans-
tor (right). Although it can act as a spin valve, this structure shares the disadvantage of all-   mission (spin filtering) and strongly in-
metal spintronic devices in that it cannot be an amplifier.                                        fluence operation of spintronic devices
                                                                                                   by modifying the degree of spin polar-
field effect transistors operate with an         device could find use in magnetic sen-            ization. One way to test these ideas is
applied electric field (voltage) along the       sor technology such as magnetic read              by directly injecting spins from a fer-
junction, as the width of the depletion          heads or magnetic memory cells.                   romagnet, where the spins start out in
layer is sensitive to the voltage. We pro-       Go with the Flow                                  alignment, into a nonmagnetic semi-
pose to use instead a magnetic field. If         If spintronic devices are ever to be              conductor. Understanding this kind of
the n or p region (or both) is doped             practical, we need to understand how              spin injection is also required for hy-
with magnetic impurities, an external            spins move through materials and how              brid semiconductor devices, such as
magnetic field produces a physical ef-           to create large quantities of aligned             the Datta-Das spin transistor discussed
fect equivalent to applying an external          spins. Thirty years ago, pioneering ex-           in the previous section. But this situa-
voltage and could effectively tailor the         periments on spin transport were per-             tion is very complicated, and a com-
width of the junction. (At the same              formed by Paul Tedrow and Robert                  plete picture of transport across the fer-
time, this affects spin-up and spin-             Meservy of MIT on ferromagnet/su-                 romagnetic-semiconductor interface is
down electrons differently: A spin-po-           perconductor sandwiches to demon-                 not yet available. In its absence, re-
larized current results as well). Such a         strate that current across the interface          searches have been studying a simpler
                                                                                                   case of normal metal - semiconductor
                                                                                                   contacts.
                                                circularly polarized light                            Unfortunately, experiments on spin
                                                                                                   injection into a semiconductor indicate
                                                                                                   that the obtained spin polarization is
                                                                                                   substantially smaller than in the ferro-
                                                                                                   magnetic spin injector, spelling trouble
                                                                                                   for spintronic devices. In this case,
                    holes                                                                          where spins diffuse across the inter-
                                                                                                   face, there is a large mismatch in con-
                                                                                                   ductivities, and this presents a basic
                    p                                                        n                     obstacle to achieving higher semicon-
                                                                                                   ductor spin polarization with injection.
                                                                                                   An interesting solution has been pro-
                                                                        IIIV                       posed to circumvent this limitation. By
                                                                   semiconductor                   inserting tunnel contacts—a special
                                                                                                   kind of express lane for carriers—in-
                                                                                                   vestigators found that they could elim-
                                                                                                   inate the conductivity mismatch. More-
                                                                                                   over, to reduce significant material
                                                                                                   differences between ferromagnets and
Figure 5. Spintronic solar cells have been proposed by the author and his colleagues.              semiconductors, one can use a magnet-
Sunlight passes through a filter to produce circularly polarized light, which is absorbed in       ic semiconductor as the injector. While
the region between p-type and n-type semiconductors. This creates spin polarized electron          it was shown that this approach could
hole pairs in this so-called “depletion” layer, but if a semiconductor of the III-V variety is
                                                                                                   lead to a high degree of spin polariza-
used (gallium arsenide, for example), the polarization is only retained by the electrons. The
inherent electric field at the layer boundaries sweeps the holes to the p side and the electrons
                                                                                                   tion in a nonmagnetic semiconductor,
to the n side. Just as with a conventional solar cell, a wire connected from the p electrode to    it only worked at low temperature. For
the n electrode will now have a current flowing in it, but in this case the current is spin        successful spintronic applications, fu-
polarized.                                                                                         ture efforts will have to concentrate on

520   American Scientist, Volume 89
fabricating ferromagnetic semiconduc-
tors in which ferromagnetism will per-
sist at higher temperatures.
   The issues involving spin injection
in semiconductors, as well as efforts to
fabricate hybrid structures, point to-
ward a need to develop methods to
study fundamental aspects of spin-po-
larized transport in semiconductors.           magnetic           p                                                   n            magnetic
We recently suggested studying hybrid            field                                                                               field
semiconductor-superconductor struc-                                                      depletion
tures for understanding spin transmis-                                                     layer
sion properties, where the presence of
the superconducting region can serve
as a tool to investigate interfacial trans-
parency and spin-polarization. In ad-
dition to charge transport, which can
be used to infer the degree of spin-po-
larization, one could also consider pure
                        ˇ ´
spin transport. Igor Zutic and I have
                                              Figure 6. In the magnetic field effect transistor proposed by the author and his colleagues, an
been able to calculate this in a hybrid       external current flows vertically through the structure shown. Normally, semiconductors are
semiconductor structure with our              “doped” with impurity atoms to create the p-type and n-type materials, but if these impuri-
model of the interface. We choose a           ties are magnetic atoms, then a magnetic field applied in the direction shown can alter the
geometry where semi-infinite semicon-         thickness of the middle depletion layer. As the size of this channel is increased and
ductor and superconductor regions are         decreased, the current flowing in the external circuit is increased and decreased, respectively.
separated by an interface at which par-       Thus a small magnetic field can extert a large effect on an electric current. This is analogous
ticles can experience potential and           to a conventional field effect transistor where an electric field controls the thickness of the
spin-flip scattering. In this approach        depletion layer and hence the current.
we need to identify the appropriate
scattering processes and their corre-         arated.) These properties give a quan-           coherent much longer than even their
sponding magnitudes. We find that al-         tum computer the ability to, in effect,          already long coherence times in the
though spin conductance shows high            operate in parallel—making many                  bulk. However, to trap a single electron
sensitivity to spin polarization, there       computations simultaneously.                     in a gated quantum dot is a difficult
remains an experimental challenge to             Quantum computation requires that             task experimentally. In addition, to ap-
directly measure the spin current,            the quantum states remain coherent, or           ply a local magnetic field on one quan-
rather than the usual charge current.         undisturbed by interactions with the             tum dot without affecting other neigh-
                                              outside world, for a long time, and the          boring dots and trapped spins may also
Computing with Spins                          states need to be controlled precisely.          be impossible in practice.
One of the most ambitious spintronic          Because of the requirement of very long             We recently showed that in princi-
devices is the spin-based quantum             coherence time for a quantum comput-             ple it is possible (albeit with great diffi-
computer in solid-state structures. The       er, both nuclear spin and electron spin          culties) to overcome both of these
use of electron (or nuclear) spin for         have been proposed as qubits, since              problems. Regarding the difficulty of
these purposes is a manifestly obvious        spins inherently have long coherence             trapping single electrons in an array of
idea. The particles that physicists call      times because they are immune to the             quantum dots, Xuedong Hu and I car-
“fermions” have two states of spin and        long-range electrostatic Coulomb inter-          ried out a multi-electron calculation
so can assume either “up” or “down”           actions between charges. I will review           and showed that, subject to certain
states, making them natural and intrin-       only a few of the representative                 conditions, an odd number of electrons
sic binary units called quantum bits, or      schemes proposed during the past sev-            trapped in a quantum dot could effec-
qubits. A qubit, as opposed to a classi-      eral years and discuss some recent               tively work as a qubit. The problem of
cal binary computing bit, however, is         work with my colleagues on electron              the local magnetic field may be solved
not restricted to representing just 0 or 1.   spin based quantum computation.                  by the method of quantum error cor-
Because of the quantum property of su-           One such scheme uses the spin of a            rection. The lack of a purely local mag-
perposition, it may represent arbitrary       single electron trapped in an isolated           netic field that acts on just a single
combinations of both values—that is,          structure called a quantum dot as its            qubit is essentially a problem of an in-
an infinite number of possibilities be-       qubit. Local magnetic fields are used to         homogeneous magnetic field that the
tween 0 and 1. To perform a computa-          manipulate single spins, while inter-dot         other qubits feel. Such a field may
tion, some initial state is imposed on        interaction is used to couple neighbor-          come from magnetic impurities or un-
the spins, and this state is allowed to       ing qubits and introduce two-qubit en-           wanted currents away from the struc-
evolve in time through a process of en-       tanglement. A single trapped electron            ture. We have done a detailed analysis
tanglement. (Quantum entanglement             in a quantum dot implies an extremely            and found that there is an error pro-
means that the spins of particles polar-      low carrier density, which means very            portional to the field inhomogeneity.
ized together remain correlated, even         low coupling with the outside world.             Using realistic estimates for such an in-
though they may become spatially sep-         Thus the electron spins should remain            homogeneous magnetic field on

                                                                                                         2001    November–December        521
nanometer scale quantum dots showed        external gate voltages. In addition, the   the silicon computer scheme. Another
that the error introduced by the field     final measurement is also supplied by      potential advantage of a quantum
can actually be corrected (with great      the donor electrons by converting spin     computer based on silicon is the
difficulty).                               information into charge information. A     prospect of using the vast resources
   One of the most influential schemes     significant advantage of silicon is that   available from the semiconductor chip
is the nuclear spin based quantum          its most abundant isotope is spinless,     industry.
computer proposed by Bruce Kane,           thus providing a “quiet” environment          In addition to all the operational
now at the University of Maryland.         for donor nuclear spin qubits. In gen-     problems discussed above, there is still
Here silicon donor nuclei serve as         eral, nuclear spins have very long co-     the very hard question of how to reli-
qubits, while donor electrons together     herence times because they do not          ably measure single electron spins (the
with external gates provide single-        strongly couple with their environment     readout in quantum computers). Not
qubit (using an external magnetic field)   and are thus good candidates for           only must one be able to measure single
and two-qubit operations (using elec-      qubits. However, this isolation from       spin states, but one has to be able to do
tron-nuclear and electron-electron spin    the environment also brings with it the    it reasonably fast (nanoseconds to mi-
interactions). The donor electrons are     baggage that individual nuclear spins      croseconds) so that the spin state does
essentially shuttles between different     are difficult to control. This is why      not decay before readout. Existing spin-
nuclear qubits and are controlled by       donor electrons play a crucial role in     measurement techniques can at best
                                                                                      measure 500 to 1,000 electron spins, and
                                                                                      extensive experimental exploration is
                                                                                      needed to solve this problem.

                                                                                      Future prospects
                                                                                      Much remains to be understood about
                                                                                      the behavior of electron spins in mate-
                                                                                      rials for technological applications, but
                                                                 radio frequency      much has been accomplished. A num-
                                                                                      ber of novel spin-based microelectronic
                                                                                      devices have been proposed, and the
                                                                                      giant magnetoresistive sandwich struc-
                                                                                      ture is a proven commercial success,
                                                                                      being a part of every computer coming
                                                                                      off the production line. In addition,
                                                                                      spintronic-based nonvolatile memory
                                                                                      elements may very well become avail-
                                                                                      able in the near future. But before we
                                                                                      can move forward into broad applica-
                                                                                      tion of spin-based multifunctional and
                                                                                      novel technologies, we face the funda-
                                                                                      Figure 7. Quantum computing may be possi-
                                                                                      ble one day with spintronic devices. In an
                                                                                      implementation proposed by Bruce Kane,
                                                                                      phosphorus atoms doped into a silicon sub-
                                                                                      strate act as the quantum computing ele-
                                                                                      ments. The diagram shows one part of a
                                                                                      larger array of phosphorus atoms in a hypo-
                                                                                      thetical quantum computer. Each phospho-
                                                                                      rus nucleus embedded in the substrate has
                                                                                      its own nuclear spin and each donates an
                                                                                      electron, which in turn have their own spin.
                                                                                      The state of the nuclear spins can be read
                                                                                      and written by the outer electrodes, called
         read                                    read                                 “A gates,” and the nuclear spins can be
          out                                     out                                 allowed to interact via the electrons, which
                                                                                      are controlled with the center, or “J gates.”
                                                                                      In a typical series of steps, the nuclear spins
                                                                                      would be set with a pulse of a radio fre-
                                                                 radio frequency
                                                                                      quency magnetic field (top panel). Next, the
                                                                                      electrons (red spheres) would be activated
                                                                                      with the J gates to move between the phos-
                                                                                      phorus atoms (black circles with arrows),
                                                                                      creating a quantum mechanical “entangled”
                                                                                      state (middle panel). Finally, the gates are
                                                                                      used again to read out the final quantum
                                                                                      state of the array of phosphorus atoms via
                                                                                      the spin state of the electrons (bottom panel).


522   American Scientist, Volume 89
mental challenges of creating and mea-         Bibliography                                            Kane, B. E. 1998. Silicon based quantum com-
suring spin, understanding better the                                                                     putation. Nature 393:133.
                                               Bennett, C. H., and D. P. DiVincenzo. 2000.
transport of spin at interfaces, particu-         Quantum information and computation.                 Loss, D., and D. DiVincenzo. 1998. Quantum
                                                  Nature (404):267.                                       computation with quantum dots. Physical
larly at ferromagnetic/semiconductor                                                                      Review A 57:120.
interfaces, and clarifying the types of        Das Sarma, S., et al. 2000. Theoretical perspec-
                                                  tives on spintronics and spin-polarized              Ohno, H. 1998. Making nonmagnetic semicon-
errors in spin-based computational                transport. IEEE Transactions on Magnetics               ductors ferromagnetic. Science 281:951.
systems. Tackling these will require              36:2821.                                             Prinz, G. A. 1999. Device physics—Magneto-
that we develop new experimental               Das Sarma, S., et al. 2001. Spin electronics and           electronics. Science 282:1660
tools and broaden considerably our                spin computation. Solid State Communica-             Wolf, S. A., and D. Treger. 2000. Spintronics: A
theoretical understanding of quantum              tions 119:207.                                          new paradigm for electronics for the new
                                               Datta, S., and B. Das. 1990. Electronic analog of          millennium. IEEE Transactions on Magnetics
spin, learning in the process how to ac-                                                                  36:2748.
tively control and manipulate spins in            the electrooptic modulator. Applied Physics
                                                  Letters 56:665.                                      ˇ ´,
                                                                                                       Zutic I., J. Fabian and S. Das Sarma. 2001. Pro-
ultrasmall structures. If we can do this,                                                                 posal for a spin polarized solar battery. Ap-
                                               Fabian, J., and S. Das Sarma. 1999. Spin relax-
the payoff will be an entirely new                ation of conduction electrons. Journal of Vac-          plied Physics Letters 17:156.
world of spin technology with new ca-             uum Science and Technology B17:1780.                 ˇ ´,
                                                                                                       Zutic I., J. Fabian and S. Das Sarma. 2001. Spin
pabilities and opportunities. In partic-                                                                  injection through the depletion layer: A the-
                                               Fabian, J., and S. Das Sarma. 1999. Phonon in-
ular, the tantalizing possibility of build-                                                               ory of spin polarized p-n junctions and so-
                                                  duced spin relaxation of conduction elec-
                                                                                                          lar cells. Physical Review B 64:121201.
ing a spintronics quantum computer                trons. Physical Review Letters 83:1211.
                                                                                                        ˇ ´,
                                                                                                       Zutic I., and S. Das Sarma. 1999. Spin polar-
will keep researchers busy for quite           Gregg, J., et al. 1997. The art of spintronics. Jour-
                                                                                                          ized transport and Andreev reflection in
some time.                                        nal of Magnetics and Magnetic Materials 175:1.
                                                                                                          semiconductor/superconductor hybrid
                                               Hu, X., and S. Das Sarma. 2000. Hilbert space              structures. Physical Review B 60:R16322.T
                                                  structure of a solid-state quantum comput-
Acknowledgment                                    er. Physical Review A 61:062301.
The author acknowledges spintronics re-        Hu, X., R. De Sousa and S. Das Sarma. 2001. In-
search support from the U.S. Office of            terplay between Zeeman coupling and
Naval Research, the Defense Advance Re-           swap action in spin based quantum com-                       Links to Internet resources for
search Projects Agency, the National Se-          puter models: Error correction in inhomo-                  “Spintronics” are available on the
curity Agency and the Advanced Research           geneous magnetic fields. Physical Review Let-                 American Scientist Web site:
                                                  ters 86:918.
and Development Activity. He wishes to                                                                    http://www.americanscientist.org/art
                                               Hu, X., and S. Das Sarma. 2001. Spin-based
thank Jaroslav Fabian, Xuedong Hu and             quantum computation in multielectron                        icles/01articles/dassarma.html
     ˇ ´
Igor Zutic for extensive research collabora-      quantum dots. Physical Review A 64:042312.
tions leading to the ideas, theories and re-   Johnson, M. 1994. The all-metal spin transistor.
sults presented in this article.                  IEEE Spectrum 31:47.




                                                                                                                 2001    November–December         523

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Spintronics

  • 1. Spintronics A new class of device based on the quantum of electron spin, rather than on charge, may yield the next generation of microelectronics Sankar Das Sarma T he last half of the 20th century, it has been argued with considerable justification, could be called the micro- carrying out processing and data stor- age on the same chip), investigators have been eager to exploit another the flow of charge. In fact, the spin- tronics dream is a seamless integration of electronic, optoelectronic and mag- electronics era. During that 50-year pe- property of the electron—a characteris- netoelectronic multifunctionality on a riod, the world witnessed a revolution tic known as spin. Spin is a purely single device that can perform much based on a digital logic of electrons. quantum phenomenon roughly akin to more than is possible with today’s mi- From the earliest transistor to the re- the spinning of a child’s top or the di- croelectronic devices. markably powerful microprocessor in rectional behavior of a compass needle. your desktop computer, most electron- The top could spin in the clockwise or The Logic Of Spin ic devices have employed circuits that counterclockwise direction; electrons Spin relaxation (how spins are created express data as binary digits, or bits— have spin of a sort in which their com- and disappear) and spin transport ones and zeroes represented by the ex- pass needles can point either “up” or (how spins move in metals and semi- istence or absence of electric charge. “down” in relation to a magnetic field. conductors) are fundamentally impor- Furthermore, the communication be- Spin therefore lends itself elegantly to a tant not only as basic physics questions tween microelectronic devices occurs new kind of binary logic of ones and but also because of their demonstrated by the binary flow of electric charges. zeros. The movement of spin, like the value as phenomena in electronic tech- The technologies that emerged from flow of charge, can also carry informa- nology. One device already in use is the this simple logic have created a multi- tion among devices. One advantage of giant magnetoresistive, or GMR, sand- trillion dollar per year global industry spin over charge is that spin can be eas- wich structure, which consists of alter- whose products are ubiquitous. In- ily manipulated by externally applied nating ferromagnetic (that is, perma- deed, the relentless growth of micro- magnetic fields, a property already in nently magnetized) and nonmagnetic electronics is often popularly summa- use in magnetic storage technology. metal layers. Depending on the relative rized in Moore’s Law, which holds that Another more subtle (but potentially orientation of the magnetizations in the microprocessors will double in power significant) property of spin is its long magnetic layers, the electrical resistance every 18 months as electronic devices coherence, or relaxation, time—once through the layers changes from small shrink and more logic is packed into created it tends to stay that way for a (parallel magnetizations) to large (an- every chip. long time, unlike charge states, which tiparallel magnetizations). Investigators Yet even Moore’s Law will run out are easily destroyed by scattering or discovered that they could use this of momentum one day as the size of collision with defects, impurities or change in resistance (called magnetore- individual bits approaches the dimen- other charges. sistance, and “giant” because of the sion of atoms—this has been called the These characteristics open the possi- large magnitude of the effect in this end of the silicon road map. For this bility of developing devices that could case) to construct exquisitely sensitive reason and also to enhance the multi- be much smaller, consume less electric- detectors of changing magnetic fields, functionality of devices (for example, ity and be more powerful for certain such as those marking the data on a types of computations than is possible computer hard-disk platter. These disk Sankar Das Sarma is Distinguished University with electron-charge-based systems. drive read/write heads have been Professor at the University of Maryland, College Those of us in the spintronics (short for wildly successful, permitting the stor- Park, where he has been on the physics faculty spin electronics) community hope that age of tens of gigabytes of data on note- since 1980. He received his Ph.D. from Brown by understanding the behavior of elec- book computer hard drives, and have University in 1979. He is a widely published and highly cited theoretical condensed matter physicist tron spin in materials we can learn created a billion-dollar per year indus- with broad research interests in electronic proper- something fundamentally new about try. Groups have also been working to ties of materials and nonequilibrium statistical solid state physics that will lead to a develop nonvolatile memory elements mechanics. Internet: dassarma@physics.umd.edu; new generation of electronic devices from these materials, possibly a route http://www.physics.umd.edu/rgroups/spin/ based on the flow of spin in addition to to instant-on computers. 516 American Scientist, Volume 89
  • 2. Figure 1. Physicists and engineers are creating an entirely new generation of microelectronic devices that operate on a quantum mechanical property of electrons called “spin” rather than on the electron’s electrical charge. These investigators are racing to use spin effects to create transistors and other circuit elements, including quantum computers, in a field known as spintronics. Shown here is an artist’s depiction of a proposal by Bruce Kane, now at the University of Maryland, for a quantum computer based on the nuclear spin of phosphorus atoms. The quantum properties of superposition and entanglement may someday permit quantum computers to perform certain types of computations much more quickly using less power than is possible with conventional charge-based devices. For an explanation of how a quantum com- puter might work, see Figure 7. Researchers and developers of spin- function as spin polarizers and spin applications, many basic questions per- tronic devices currently take two differ- valves. This is crucial because, unlike taining to combining semiconductors ent approaches. In the first, they seek to semiconductor transistors, existing met- with other materials to produce viable perfect the existing GMR-based technol- al-based devices do not amplify signals spintronic technology remain unan- ogy either by developing new materials (although they are successful switches or swered. For example, it is far from well with larger populations of oriented spins valves). If spintronic devices could be understood whether or how placing a (called spin polarization) or by making made from semiconductors, however, semiconductor in contact with another improvements in existing devices to pro- then in principle they would provide material would impede spin transport vide better spin filtering. The second ef- amplification and serve, in general, as across the interface. In the past, our fort, which is more radical, focuses on multi-functional devices. Perhaps even strategy for understanding spin trans- finding novel ways both to generate and more importantly, semiconductor-based port in hybrid semiconductor struc- to utilize spin-polarized currents—that devices could much more easily be inte- tures was to borrow knowledge ob- is, to actively control spin dynamics. The grated with traditional semiconductor tained from studies of more traditional intent is to thoroughly investigate spin technology. magnetic materials. More recently, transport in semiconductors and search Although semiconductors offer clear however, investigators have begun di- for ways in which semiconductors can advantages for use in novel spintronic rect investigation of spin transport 2001 November–December 517
  • 3. (similar, in effect, to the source and drain, respectively, in a field effect tran- sistor). The emitter emits electrons with their spins oriented along the direction of the electrode’s magnetization, while the collector (with the same electrode magnetization) acts as a spin filter and accepts electrons with the same spin only. In the absence of any changes to the spins during transport, every emit- ted electron enters the collector. In this random spin spin alignment device, the gate electrode produces a field that forces the electron spins to precess, just like the precession of a spinning top under the force of gravity. The electron current is modulated by the degree of precession in electron spin introduced by the gate field: An electron passes through the collector if its spin is parallel, and does not if it is antiparallel, to the magnetization. The Datta-Das effect should be most visible for narrow band-gap semiconductors such as InGaAs, which have relatively large spin-orbit interactions (that is, a unmagnetized magnetized magnetic field introduced by the gate current has a relatively large effect on Figure 2. Spins can arrange themselves in a variety of ways that are important for spintronic devices. They can be completely random, with their spins pointing in every possible direc- electron spin). Despite several years of tion and located throughout a material in no particular order (upper left). Or these randomly effort, however, the effect has yet to be located spins can all point in the same direction, called spin alignment (upper right). In solid convincingly demonstrated experi- state materials, the spins might be located in an orderly fashion on a crystal lattice (lower mentally. left) forming a nonmagnetic material. Or the spins may be on a lattice and be aligned as in a Another interesting concept is the magnetic material (lower right). all-metal spin transistor developed by Mark Johnson at the Naval Research across interfaces in all-semiconductor spin devices may be well suited to Laboratory. Its trilayer structure con- devices. In such a scenario a combina- such tasks, since spin is an intrinsically sists of a nonmagnetic metallic layer tion of optical manipulation (for exam- quantum property. sandwiched between two ferromag- ple, shining circularly polarized light nets. The all-metal transistor has the on a material to create net spin polar- Spintronic Devices same design philosophy as do giant ization) and material inhomogeneities The first scheme for a spintronic device magnetoresistive devices: The current (by suitable doping as in a recently dis- based on the metal-oxide-semiconduc- flowing through the structure is modi- covered class of gallium-manganese- tor technology familiar to microelec- fied by the relative orientation of the arsenide ferromagnetic materials) can tronics designers was the field effect magnetic layers, which in turn can be be employed to tailor spin transport spin transistor proposed in 1989 by controlled by an applied magnetic properties. Supriyo Datta and Biswajit Das of Pur- field. In this scheme, a battery is con- In addition to the near-term studies due University. In a conventional field nected to the control circuit (emitter- of various spin transistors and spin effect transistor, electric charge is intro- base), while the direction of the current transport properties of semiconduc- duced via a source electrode and col- in the working circuit (base-collector) tors, a long-term and ambitious sub- lected at a drain electrode. A third elec- is effectively switched by changing the field of spintronics is the application of trode, the gate, generates an electric magnetization of the collector. The cur- electron and nuclear spins to quantum field that changes the size of the chan- rent is drained from the base in order information processing and quantum nel through which the source-drain to allow for the working current to computation. The late Richard Feyn- current can flow, akin to stepping on a flow under the “reverse” base-collec- man and others have pointed out that garden hose. This results in a very tor bias (antiparallel magnetizations). quantum mechanics may provide great small electric field being able to control Neither current nor voltage is ampli- advantages over classical physics in large currents. fied, but the device acts as a switch or computation. However, the real boom In the Datta-Das device, a structure spin valve to sense changes in an exter- started after Peter Shor of Bell Labs de- made from indium-aluminum-ar- nal magnetic field. A potentially signif- vised a quantum algorithm that would senide and indium-gallium-arsenide icant feature of the Johnson transistor factor very large numbers into primes, provides a channel for two-dimension- is that, being all metallic, it can in prin- an immensely difficult task for conven- al electron transport between two fer- ciple be made extremely small using tional computers and the basis for romagnetic electrodes. One electrode nanolithographic techniques (perhaps modern encryption. It turns out that acts as an emitter, the other a collector as small as tens of nanometers). An im- 518 American Scientist, Volume 89
  • 4. portant disadvantage of Johnson’s transistor is that, being all-metallic, it will be difficult to integrate this spin gate V transistor device into existing semicon- ductor microelectronic circuitry. ferromagnetic emitter ferromagnetic collector As noted previously, a critical disad- vantage of metal-based spintronic de- InAlAs vices is that they do not amplify sig- nals. There is no obvious metallic InGaAs analog of the traditional semiconductor transistor in which draining one elec- tron from the base allows tens of elec- trons to pass from the emitter into the collector (by reducing the electrostatic barrier generated by electrons trapped in the base). Motivated by the possibili- ferromagnetic ferromagnetic ty of having both spin polarization and emitter collector amplification, my group has recently studied a prototype device, the spin- polarized p-n junction. (In the p, or pos- InAlAs itive, region the electrons are the mi- nority carriers, holes the majority; in the n, or negative, region the roles are re- versed.) In our scheme we illuminate the surface of the p-type region of a gal- lium arsenide p-n junction with circu- InGaAs larly polarized light to optically orient the minority electrons. By performing a realistic device-modeling calculation we have discovered that the spin can be effectively transferred from the p side into the n side, via what we call spin pumping through the minority ferromagnetic ferromagnetic channel. In effect, the spin gets ampli- emitter collector fied going from the p to the n region through the depletion layer. InAlAs One possible application of our pro- posed spin-polarized p-n junction is something we call the spin-polarized solar cell. As in ordinary solar cells, light illuminates the depletion layer of a semiconductor (such as gallium ar- InGaAs senide), generating electron-hole pairs. The huge built-in electric field in the layer (typically 104 volts per centime- ter) swiftly sweeps electrons into the n Figure 3. Datta-Das spin transistor was the first spintronic device to be proposed for fabrica- region and holes into the p region. If a tion in a metal-oxide-semiconductor geometry familiar in conventional microelectronics. An wire connects the edges of the junction, electrode made of a ferromagnetic material (purple) emits spin-aligned electrons (red spheres), which pass through a narrow channel (blue) controlled by the gate electrode (gold) a current flows. If the light is circularly and are collected by another ferromagnetic electrode (top). With the gate voltage off, the polarized (from filtered solar photons, aligned spins pass through the channel and are collected at the other side (middle). With the for instance), the generated electrons are gate voltage on, the field produces magnetic interaction that causes the spins to precess, like spin polarized. (Holes in III-V semicon- spinning tops in a gravity field. If the spins are not aligned with the direction of magnetiza- ductors—for example, gallium arsenide, tion of the collector, no current can pass. In this way, the emitter-collector current is modulat- indium arsenide and others—which are ed by the gate electrode. As yet, no convincingly successful application of this proposal has most useful for opto-spin-electronic been demonstrated. purposes, lose their spin very quickly, so that their polarization can be ne- ˇ Most recently, Igor Zutic , Jaroslav ´ junction around the electrodes. If the glected.) As the spin-polarized elec- Fabian and I have proposed a new kind depletion layer is wider than the elec- trons created in the depletion layer of magnetic field effect transistor. Elec- trodes, no (or very small) electric cur- pump the spin into the n region, the re- trodes of an external circuit are placed rent flows. As the width decreases, sulting current is spin polarized. perpendicular to the p-n junction. The more and more electrons come into Hence, photons of light are converted current is determined by the amount of contact with the electrodes and the cur- into oriented spins. available electrons in the region of the rent rapidly increases. Traditionally, 2001 November–December 519
  • 5. is spin-polarized. Today, the range of materials we can study has significant- ly increased, including novel ferro- magnetic semiconductors, high-tem- base perature superconductors and carbon nanotubes. But several questions— such as the role of the interface sepa- rating different materials and how to create and measure spin polarization— collector emitter still remain open and are of fundamen- tal importance to novel spintronic ap- plications. As devices decrease in size, the scat- Figure 4. In the spin transistor invented by Mark Johnson, two ferromagnetic electrodes— tering from interfaces plays a domi- the emitter and collector—sandwich a nonmagnetic layer—the base. When the ferromagnets nant role. In these hybrid structures the are aligned, current flows from emitter to collector (left). But when the ferromagnets have presence of magnetically active inter- different directions of magnetization, the current flows out of the base to emitter and collec- faces can lead to spin-dependent trans- tor (right). Although it can act as a spin valve, this structure shares the disadvantage of all- mission (spin filtering) and strongly in- metal spintronic devices in that it cannot be an amplifier. fluence operation of spintronic devices by modifying the degree of spin polar- field effect transistors operate with an device could find use in magnetic sen- ization. One way to test these ideas is applied electric field (voltage) along the sor technology such as magnetic read by directly injecting spins from a fer- junction, as the width of the depletion heads or magnetic memory cells. romagnet, where the spins start out in layer is sensitive to the voltage. We pro- Go with the Flow alignment, into a nonmagnetic semi- pose to use instead a magnetic field. If If spintronic devices are ever to be conductor. Understanding this kind of the n or p region (or both) is doped practical, we need to understand how spin injection is also required for hy- with magnetic impurities, an external spins move through materials and how brid semiconductor devices, such as magnetic field produces a physical ef- to create large quantities of aligned the Datta-Das spin transistor discussed fect equivalent to applying an external spins. Thirty years ago, pioneering ex- in the previous section. But this situa- voltage and could effectively tailor the periments on spin transport were per- tion is very complicated, and a com- width of the junction. (At the same formed by Paul Tedrow and Robert plete picture of transport across the fer- time, this affects spin-up and spin- Meservy of MIT on ferromagnet/su- romagnetic-semiconductor interface is down electrons differently: A spin-po- perconductor sandwiches to demon- not yet available. In its absence, re- larized current results as well). Such a strate that current across the interface searches have been studying a simpler case of normal metal - semiconductor contacts. circularly polarized light Unfortunately, experiments on spin injection into a semiconductor indicate that the obtained spin polarization is substantially smaller than in the ferro- magnetic spin injector, spelling trouble for spintronic devices. In this case, holes where spins diffuse across the inter- face, there is a large mismatch in con- ductivities, and this presents a basic p n obstacle to achieving higher semicon- ductor spin polarization with injection. An interesting solution has been pro- IIIV posed to circumvent this limitation. By semiconductor inserting tunnel contacts—a special kind of express lane for carriers—in- vestigators found that they could elim- inate the conductivity mismatch. More- over, to reduce significant material differences between ferromagnets and Figure 5. Spintronic solar cells have been proposed by the author and his colleagues. semiconductors, one can use a magnet- Sunlight passes through a filter to produce circularly polarized light, which is absorbed in ic semiconductor as the injector. While the region between p-type and n-type semiconductors. This creates spin polarized electron it was shown that this approach could hole pairs in this so-called “depletion” layer, but if a semiconductor of the III-V variety is lead to a high degree of spin polariza- used (gallium arsenide, for example), the polarization is only retained by the electrons. The inherent electric field at the layer boundaries sweeps the holes to the p side and the electrons tion in a nonmagnetic semiconductor, to the n side. Just as with a conventional solar cell, a wire connected from the p electrode to it only worked at low temperature. For the n electrode will now have a current flowing in it, but in this case the current is spin successful spintronic applications, fu- polarized. ture efforts will have to concentrate on 520 American Scientist, Volume 89
  • 6. fabricating ferromagnetic semiconduc- tors in which ferromagnetism will per- sist at higher temperatures. The issues involving spin injection in semiconductors, as well as efforts to fabricate hybrid structures, point to- ward a need to develop methods to study fundamental aspects of spin-po- larized transport in semiconductors. magnetic p n magnetic We recently suggested studying hybrid field field semiconductor-superconductor struc- depletion tures for understanding spin transmis- layer sion properties, where the presence of the superconducting region can serve as a tool to investigate interfacial trans- parency and spin-polarization. In ad- dition to charge transport, which can be used to infer the degree of spin-po- larization, one could also consider pure ˇ ´ spin transport. Igor Zutic and I have Figure 6. In the magnetic field effect transistor proposed by the author and his colleagues, an been able to calculate this in a hybrid external current flows vertically through the structure shown. Normally, semiconductors are semiconductor structure with our “doped” with impurity atoms to create the p-type and n-type materials, but if these impuri- model of the interface. We choose a ties are magnetic atoms, then a magnetic field applied in the direction shown can alter the geometry where semi-infinite semicon- thickness of the middle depletion layer. As the size of this channel is increased and ductor and superconductor regions are decreased, the current flowing in the external circuit is increased and decreased, respectively. separated by an interface at which par- Thus a small magnetic field can extert a large effect on an electric current. This is analogous ticles can experience potential and to a conventional field effect transistor where an electric field controls the thickness of the spin-flip scattering. In this approach depletion layer and hence the current. we need to identify the appropriate scattering processes and their corre- arated.) These properties give a quan- coherent much longer than even their sponding magnitudes. We find that al- tum computer the ability to, in effect, already long coherence times in the though spin conductance shows high operate in parallel—making many bulk. However, to trap a single electron sensitivity to spin polarization, there computations simultaneously. in a gated quantum dot is a difficult remains an experimental challenge to Quantum computation requires that task experimentally. In addition, to ap- directly measure the spin current, the quantum states remain coherent, or ply a local magnetic field on one quan- rather than the usual charge current. undisturbed by interactions with the tum dot without affecting other neigh- outside world, for a long time, and the boring dots and trapped spins may also Computing with Spins states need to be controlled precisely. be impossible in practice. One of the most ambitious spintronic Because of the requirement of very long We recently showed that in princi- devices is the spin-based quantum coherence time for a quantum comput- ple it is possible (albeit with great diffi- computer in solid-state structures. The er, both nuclear spin and electron spin culties) to overcome both of these use of electron (or nuclear) spin for have been proposed as qubits, since problems. Regarding the difficulty of these purposes is a manifestly obvious spins inherently have long coherence trapping single electrons in an array of idea. The particles that physicists call times because they are immune to the quantum dots, Xuedong Hu and I car- “fermions” have two states of spin and long-range electrostatic Coulomb inter- ried out a multi-electron calculation so can assume either “up” or “down” actions between charges. I will review and showed that, subject to certain states, making them natural and intrin- only a few of the representative conditions, an odd number of electrons sic binary units called quantum bits, or schemes proposed during the past sev- trapped in a quantum dot could effec- qubits. A qubit, as opposed to a classi- eral years and discuss some recent tively work as a qubit. The problem of cal binary computing bit, however, is work with my colleagues on electron the local magnetic field may be solved not restricted to representing just 0 or 1. spin based quantum computation. by the method of quantum error cor- Because of the quantum property of su- One such scheme uses the spin of a rection. The lack of a purely local mag- perposition, it may represent arbitrary single electron trapped in an isolated netic field that acts on just a single combinations of both values—that is, structure called a quantum dot as its qubit is essentially a problem of an in- an infinite number of possibilities be- qubit. Local magnetic fields are used to homogeneous magnetic field that the tween 0 and 1. To perform a computa- manipulate single spins, while inter-dot other qubits feel. Such a field may tion, some initial state is imposed on interaction is used to couple neighbor- come from magnetic impurities or un- the spins, and this state is allowed to ing qubits and introduce two-qubit en- wanted currents away from the struc- evolve in time through a process of en- tanglement. A single trapped electron ture. We have done a detailed analysis tanglement. (Quantum entanglement in a quantum dot implies an extremely and found that there is an error pro- means that the spins of particles polar- low carrier density, which means very portional to the field inhomogeneity. ized together remain correlated, even low coupling with the outside world. Using realistic estimates for such an in- though they may become spatially sep- Thus the electron spins should remain homogeneous magnetic field on 2001 November–December 521
  • 7. nanometer scale quantum dots showed external gate voltages. In addition, the the silicon computer scheme. Another that the error introduced by the field final measurement is also supplied by potential advantage of a quantum can actually be corrected (with great the donor electrons by converting spin computer based on silicon is the difficulty). information into charge information. A prospect of using the vast resources One of the most influential schemes significant advantage of silicon is that available from the semiconductor chip is the nuclear spin based quantum its most abundant isotope is spinless, industry. computer proposed by Bruce Kane, thus providing a “quiet” environment In addition to all the operational now at the University of Maryland. for donor nuclear spin qubits. In gen- problems discussed above, there is still Here silicon donor nuclei serve as eral, nuclear spins have very long co- the very hard question of how to reli- qubits, while donor electrons together herence times because they do not ably measure single electron spins (the with external gates provide single- strongly couple with their environment readout in quantum computers). Not qubit (using an external magnetic field) and are thus good candidates for only must one be able to measure single and two-qubit operations (using elec- qubits. However, this isolation from spin states, but one has to be able to do tron-nuclear and electron-electron spin the environment also brings with it the it reasonably fast (nanoseconds to mi- interactions). The donor electrons are baggage that individual nuclear spins croseconds) so that the spin state does essentially shuttles between different are difficult to control. This is why not decay before readout. Existing spin- nuclear qubits and are controlled by donor electrons play a crucial role in measurement techniques can at best measure 500 to 1,000 electron spins, and extensive experimental exploration is needed to solve this problem. Future prospects Much remains to be understood about the behavior of electron spins in mate- rials for technological applications, but radio frequency much has been accomplished. A num- ber of novel spin-based microelectronic devices have been proposed, and the giant magnetoresistive sandwich struc- ture is a proven commercial success, being a part of every computer coming off the production line. In addition, spintronic-based nonvolatile memory elements may very well become avail- able in the near future. But before we can move forward into broad applica- tion of spin-based multifunctional and novel technologies, we face the funda- Figure 7. Quantum computing may be possi- ble one day with spintronic devices. In an implementation proposed by Bruce Kane, phosphorus atoms doped into a silicon sub- strate act as the quantum computing ele- ments. The diagram shows one part of a larger array of phosphorus atoms in a hypo- thetical quantum computer. Each phospho- rus nucleus embedded in the substrate has its own nuclear spin and each donates an electron, which in turn have their own spin. The state of the nuclear spins can be read and written by the outer electrodes, called read read “A gates,” and the nuclear spins can be out out allowed to interact via the electrons, which are controlled with the center, or “J gates.” In a typical series of steps, the nuclear spins would be set with a pulse of a radio fre- radio frequency quency magnetic field (top panel). Next, the electrons (red spheres) would be activated with the J gates to move between the phos- phorus atoms (black circles with arrows), creating a quantum mechanical “entangled” state (middle panel). Finally, the gates are used again to read out the final quantum state of the array of phosphorus atoms via the spin state of the electrons (bottom panel). 522 American Scientist, Volume 89
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