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Chapter 3
     Elements and Compounds
This
reclining
Buddha in
the Grand
Palace in
Bangkok, T
hailand, is
made of
gold.      Introduction to General, Organic, and Biochemistry 10e
                           John Wiley & Sons, Inc
                 Morris Hein, Scott Pattison, and Susan Arena
Chapter Outline

3.1 Elements                              3.6 Elements in Their Natural
3.2 Distribution of Elements                  States
3.3 Names of Elements                     3.7 Elements That Exist as
3.4 Symbols of the Elements                   Diatomic Molecules

3.5 Introduction to the Periodic 3.8 Compounds
Table                            3.9 Chemical Formulas




                     Copyright 2012 John Wiley & Sons, Inc
Elements

An element is …



An atom is …




                  Copyright 2012 John Wiley & Sons, Inc
Elements

An element is a fundamental substance that cannot be
  broken down by chemical means to simpler
  substances.
There are 118 known elements.
All but 4 of the first 92 elements
  occur in nature.
All elements beyond 92 except for
  plutonium (94) are man made.


                  Copyright 2012 John Wiley & Sons, Inc
Elements

An atom is the smallest particle of an element that can
 exist.




                   Copyright 2012 John Wiley & Sons, Inc
Distribution of Elements




      Copyright 2012 John Wiley & Sons, Inc
Your Turn!

The most abundant element in the earth’s crust, oceans,
  and atmosphere is
   A. Water
   B. Hydrogen
   C. Iron
   D. Oxygen




                   Copyright 2012 John Wiley & Sons, Inc
Distribution of Elements




      Copyright 2012 John Wiley & Sons, Inc
Names of the Elements

The names of the elements are derived from a variety of
  sources:
• Iodine comes from Greek iodes, which means
  violetlike.
• Bismuth comes from the German weisse masse,
  which means white mass.
• Germanium was named for Germany, where it was
  discovered.


                   Copyright 2012 John Wiley & Sons, Inc
Symbols of the Elements

Rules for symbols of elements
1. Symbols have either one, two or three letters.
2. If one letter is used, it is capitalized.
3. If two or three letters are used, only the first is
   capitalized.
   N nitrogen            I iodine            Ni nickel
  C carbon              O oxygen                            Co cobalt



                    Copyright 2012 John Wiley & Sons, Inc
Symbols of Common Elements




        Copyright 2012 John Wiley & Sons, Inc
Symbols of Elements
Derived from Early Names




      Copyright 2012 John Wiley & Sons, Inc
Introduction to the Periodic Table

Elements are arranged in order of increasing atomic
  number.
Elements within a group have similar properties.
The representative elements are groups IA-VIIA and
  the noble gases.




                  Copyright 2012 John Wiley & Sons, Inc
Periodic Table
Your Turn!

The element potassium is in the first group on the
   Periodic Table (group IA). Potassium is
a. an alkali metal
b. an alkaline earth metal
c. a transition element
d. a halogen




                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

The elements on the periodic table are placed in order of
  increasing
a. Density
b. Atomic number
c. Boiling point
d. Atomic mass




                   Copyright 2012 John Wiley & Sons, Inc
Metals, Nonmetals and Metalloids




          Copyright 2012 John Wiley & Sons, Inc
Classifying Elements: Metals

Some properties of metals:
• Lustrous
• Malleable
• Conduct heat and electricity
• Ductile
• High density
• High melting point




                   Copyright 2012 John Wiley & Sons, Inc
Classifying Elements: Nonmetals

Some properties of nonmetals:
• Dull (if solid)
• Brittle (if solid)
• Poor conductors of heat and electricity
• Non-Ductile
                                                           Iodine crystals
• Low density
• Low melting point



                   Copyright 2012 John Wiley & Sons, Inc
Classifying Elements: Metalloids

Metalloids have properties that
  are intermediate between those
  of metals and those of
  nonmetals.
Some are used to make the
  semiconductors we need for
  computer chips.




                  Copyright 2012 John Wiley & Sons, Inc
Your Turn!

A solid sample of an unknown element is dull and
  brittle and does not conduct heat or electricity. How
  should the element be classified?
a. Metal
b. Nonmetal
c. Metalloid
d. Transition element



                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

The majority of the elements are
a. Metals
b. Gases
c. Nonmetals
d. Metalloids




                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which is not a metalloid?
a. Boron (B)
b. Silicon (Si)
c. Germanium (Ge)
d. Aluminum (Al)




                   Copyright 2012 John Wiley & Sons, Inc
Elements in Their Natural States

Most elements are found as compounds in
 nature because they are very reactive.

The noble metals (gold, silver and platinum)
  are nonreactive and are found as elements in
  nature.

The noble gases are the least reactive elements
  and are found in uncombined form.



                   Copyright 2012 John Wiley & Sons, Inc
Physical States of the Elements

• Most are solids at room temperature.
• Some are gases (the noble gases, nitrogen, oxygen,
  fluorine and chlorine).
• Two are liquids (mercury and bromine).




                   Copyright 2012 John Wiley & Sons, Inc
Elements




Copyright 2012 John Wiley & Sons, Inc
Elements That Exist as
            Diatomic Molecules
• Diatomic molecules each contain
  exactly two atoms.
• There are 7 diatomic elements.




                  Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which of the following is not a diatomic element?
a. Fluorine
b. Oxygen
c. Nitrogen
d. Carbon




                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which of the following metals is not a solid at room
   temperature?
a. Iron
b. Aluminum
c. Chromium
d. Calcium
e. Mercury



                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which of the following nonmetals is not reactive?
a. Helium
b. Fluorine
c. Oxygen
d. Carbon




                   Copyright 2012 John Wiley & Sons, Inc
Compounds

Compounds are composed of two or more elements
  combined in a definite proportion by mass.
• Elements are always combined in whole number
  ratios. Al2O3           KNO3        CaCl2
• Can be decomposed chemically into simpler
  substances.
• Each compound has unique properties that are
  different from the elements that make it up.


                 Copyright 2012 John Wiley & Sons, Inc
Compounds




Copyright 2012 John Wiley & Sons, Inc
Molecules

• A molecule is the smallest uncharged individual unit
  of a compound.
• Usually composed of two or more nonmetals.
• Can be solids, liquids or gases.
• Do not conduct electricity.




     H2O                           H2O2                    PCl5
                   Copyright 2012 John Wiley & Sons, Inc
Water

• Water molecules can be decomposed into oxygen
  molecules and hydrogen molecules.
• The properties of water are very different from the
  properties of oxygen gas and hydrogen gas.




                   Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which of the following is not likely to be a molecule?
a. CaCl2
b. NH3
c. CO2
d. SF6




                   Copyright 2012 John Wiley & Sons, Inc
Ionic Compounds

• Contain ions (charged particles).
• Compounds are held together by
  the attractive forces between the
  cations (positive ions) and the
  anions (negative ions).
• Formulas are the simplest whole
  number ratio of each element. NaCl
• Solids at room temperature.
• Conduct electricity when
  molten.
                  Copyright 2012 John Wiley & Sons, Inc
Sodium Chloride

The properties of sodium chloride are very different
from the properties of sodium metal and chlorine gas.
     2NaCl(s)                               2Na(s)          +   Cl2(g)




 Figure 3.8 When sodium chloride (a) is decomposed,
 it forms sodium metal (b) and chlorine gas (c).
                    Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Which of the following is true?
a. Metals form anions with negative charges.
b. Metals form anions with positive charges.
c. Metals form cations with positive charges.
d. Metals form cations with negative charges.




                   Copyright 2012 John Wiley & Sons, Inc
Chemical Formulas

Specifies the number of atoms of each element in the
   compound.




                   Copyright 2012 John Wiley & Sons, Inc
Chemical Formulas

When the formula contains more than one of a group of
  atoms that occurs as a unit, parentheses are placed
  around the group and a subscript is placed to the
  right of the group.




                  Copyright 2012 John Wiley & Sons, Inc
Your Turn!

The formula for table sugar is C12H22O11. How many
   oxygen atoms are found in a molecule of sugar?
a. 1
b. 12
c. 22
d. 11




                  Copyright 2012 John Wiley & Sons, Inc
Your Turn!

Aluminum sulfate is a compound that is often found in
   baking powder. How many sulfur atoms are found in
   Al2(SO4)3?
a. 4                     2 Al
b. 12
                         3*1=3S
c. 3
d. 7
                         3 * 4 = 12 O


                  Copyright 2012 John Wiley & Sons, Inc
Your Turn!

How many hydrogen atoms are found in Al(C2H3O2)3?
a. 1
b. 9                  1 Al
c. 6                  3*2=6C
d. 7
                               3*3=9H
                               3*2=6O


                 Copyright 2012 John Wiley & Sons, Inc
Your Turn!

The formula for ethyl alcohol is CH3CH2OH. How
   many H atoms are found in a molecule of ethyl
   alcohol?
a. 6                      1+1=2C
b. 3
                          3+2+1=6H
c. 5
d. 1                      1O


                  Copyright 2012 John Wiley & Sons, Inc
Questions

Review Questions (pg 58)
  – Do odd
  – Practice later even
Paired Questions
  – Do 1, 5, 9, 13, 17, 21, 25, 29, 33, 37, 41
  – Practice later every other even (2, 6, etc)




                    Copyright 2012 John Wiley & Sons, Inc   1-45

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Elements and Compounds Explained

  • 1. Chapter 3 Elements and Compounds This reclining Buddha in the Grand Palace in Bangkok, T hailand, is made of gold. Introduction to General, Organic, and Biochemistry 10e John Wiley & Sons, Inc Morris Hein, Scott Pattison, and Susan Arena
  • 2. Chapter Outline 3.1 Elements 3.6 Elements in Their Natural 3.2 Distribution of Elements States 3.3 Names of Elements 3.7 Elements That Exist as 3.4 Symbols of the Elements Diatomic Molecules 3.5 Introduction to the Periodic 3.8 Compounds Table 3.9 Chemical Formulas Copyright 2012 John Wiley & Sons, Inc
  • 3. Elements An element is … An atom is … Copyright 2012 John Wiley & Sons, Inc
  • 4. Elements An element is a fundamental substance that cannot be broken down by chemical means to simpler substances. There are 118 known elements. All but 4 of the first 92 elements occur in nature. All elements beyond 92 except for plutonium (94) are man made. Copyright 2012 John Wiley & Sons, Inc
  • 5. Elements An atom is the smallest particle of an element that can exist. Copyright 2012 John Wiley & Sons, Inc
  • 6. Distribution of Elements Copyright 2012 John Wiley & Sons, Inc
  • 7. Your Turn! The most abundant element in the earth’s crust, oceans, and atmosphere is A. Water B. Hydrogen C. Iron D. Oxygen Copyright 2012 John Wiley & Sons, Inc
  • 8. Distribution of Elements Copyright 2012 John Wiley & Sons, Inc
  • 9. Names of the Elements The names of the elements are derived from a variety of sources: • Iodine comes from Greek iodes, which means violetlike. • Bismuth comes from the German weisse masse, which means white mass. • Germanium was named for Germany, where it was discovered. Copyright 2012 John Wiley & Sons, Inc
  • 10. Symbols of the Elements Rules for symbols of elements 1. Symbols have either one, two or three letters. 2. If one letter is used, it is capitalized. 3. If two or three letters are used, only the first is capitalized. N nitrogen I iodine Ni nickel C carbon O oxygen Co cobalt Copyright 2012 John Wiley & Sons, Inc
  • 11. Symbols of Common Elements Copyright 2012 John Wiley & Sons, Inc
  • 12. Symbols of Elements Derived from Early Names Copyright 2012 John Wiley & Sons, Inc
  • 13. Introduction to the Periodic Table Elements are arranged in order of increasing atomic number. Elements within a group have similar properties. The representative elements are groups IA-VIIA and the noble gases. Copyright 2012 John Wiley & Sons, Inc
  • 15. Your Turn! The element potassium is in the first group on the Periodic Table (group IA). Potassium is a. an alkali metal b. an alkaline earth metal c. a transition element d. a halogen Copyright 2012 John Wiley & Sons, Inc
  • 16. Your Turn! The elements on the periodic table are placed in order of increasing a. Density b. Atomic number c. Boiling point d. Atomic mass Copyright 2012 John Wiley & Sons, Inc
  • 17. Metals, Nonmetals and Metalloids Copyright 2012 John Wiley & Sons, Inc
  • 18. Classifying Elements: Metals Some properties of metals: • Lustrous • Malleable • Conduct heat and electricity • Ductile • High density • High melting point Copyright 2012 John Wiley & Sons, Inc
  • 19. Classifying Elements: Nonmetals Some properties of nonmetals: • Dull (if solid) • Brittle (if solid) • Poor conductors of heat and electricity • Non-Ductile Iodine crystals • Low density • Low melting point Copyright 2012 John Wiley & Sons, Inc
  • 20. Classifying Elements: Metalloids Metalloids have properties that are intermediate between those of metals and those of nonmetals. Some are used to make the semiconductors we need for computer chips. Copyright 2012 John Wiley & Sons, Inc
  • 21. Your Turn! A solid sample of an unknown element is dull and brittle and does not conduct heat or electricity. How should the element be classified? a. Metal b. Nonmetal c. Metalloid d. Transition element Copyright 2012 John Wiley & Sons, Inc
  • 22. Your Turn! The majority of the elements are a. Metals b. Gases c. Nonmetals d. Metalloids Copyright 2012 John Wiley & Sons, Inc
  • 23. Your Turn! Which is not a metalloid? a. Boron (B) b. Silicon (Si) c. Germanium (Ge) d. Aluminum (Al) Copyright 2012 John Wiley & Sons, Inc
  • 24. Elements in Their Natural States Most elements are found as compounds in nature because they are very reactive. The noble metals (gold, silver and platinum) are nonreactive and are found as elements in nature. The noble gases are the least reactive elements and are found in uncombined form. Copyright 2012 John Wiley & Sons, Inc
  • 25. Physical States of the Elements • Most are solids at room temperature. • Some are gases (the noble gases, nitrogen, oxygen, fluorine and chlorine). • Two are liquids (mercury and bromine). Copyright 2012 John Wiley & Sons, Inc
  • 26. Elements Copyright 2012 John Wiley & Sons, Inc
  • 27. Elements That Exist as Diatomic Molecules • Diatomic molecules each contain exactly two atoms. • There are 7 diatomic elements. Copyright 2012 John Wiley & Sons, Inc
  • 28. Your Turn! Which of the following is not a diatomic element? a. Fluorine b. Oxygen c. Nitrogen d. Carbon Copyright 2012 John Wiley & Sons, Inc
  • 29. Your Turn! Which of the following metals is not a solid at room temperature? a. Iron b. Aluminum c. Chromium d. Calcium e. Mercury Copyright 2012 John Wiley & Sons, Inc
  • 30. Your Turn! Which of the following nonmetals is not reactive? a. Helium b. Fluorine c. Oxygen d. Carbon Copyright 2012 John Wiley & Sons, Inc
  • 31. Compounds Compounds are composed of two or more elements combined in a definite proportion by mass. • Elements are always combined in whole number ratios. Al2O3 KNO3 CaCl2 • Can be decomposed chemically into simpler substances. • Each compound has unique properties that are different from the elements that make it up. Copyright 2012 John Wiley & Sons, Inc
  • 32. Compounds Copyright 2012 John Wiley & Sons, Inc
  • 33. Molecules • A molecule is the smallest uncharged individual unit of a compound. • Usually composed of two or more nonmetals. • Can be solids, liquids or gases. • Do not conduct electricity. H2O H2O2 PCl5 Copyright 2012 John Wiley & Sons, Inc
  • 34. Water • Water molecules can be decomposed into oxygen molecules and hydrogen molecules. • The properties of water are very different from the properties of oxygen gas and hydrogen gas. Copyright 2012 John Wiley & Sons, Inc
  • 35. Your Turn! Which of the following is not likely to be a molecule? a. CaCl2 b. NH3 c. CO2 d. SF6 Copyright 2012 John Wiley & Sons, Inc
  • 36. Ionic Compounds • Contain ions (charged particles). • Compounds are held together by the attractive forces between the cations (positive ions) and the anions (negative ions). • Formulas are the simplest whole number ratio of each element. NaCl • Solids at room temperature. • Conduct electricity when molten. Copyright 2012 John Wiley & Sons, Inc
  • 37. Sodium Chloride The properties of sodium chloride are very different from the properties of sodium metal and chlorine gas. 2NaCl(s) 2Na(s) + Cl2(g) Figure 3.8 When sodium chloride (a) is decomposed, it forms sodium metal (b) and chlorine gas (c). Copyright 2012 John Wiley & Sons, Inc
  • 38. Your Turn! Which of the following is true? a. Metals form anions with negative charges. b. Metals form anions with positive charges. c. Metals form cations with positive charges. d. Metals form cations with negative charges. Copyright 2012 John Wiley & Sons, Inc
  • 39. Chemical Formulas Specifies the number of atoms of each element in the compound. Copyright 2012 John Wiley & Sons, Inc
  • 40. Chemical Formulas When the formula contains more than one of a group of atoms that occurs as a unit, parentheses are placed around the group and a subscript is placed to the right of the group. Copyright 2012 John Wiley & Sons, Inc
  • 41. Your Turn! The formula for table sugar is C12H22O11. How many oxygen atoms are found in a molecule of sugar? a. 1 b. 12 c. 22 d. 11 Copyright 2012 John Wiley & Sons, Inc
  • 42. Your Turn! Aluminum sulfate is a compound that is often found in baking powder. How many sulfur atoms are found in Al2(SO4)3? a. 4 2 Al b. 12 3*1=3S c. 3 d. 7 3 * 4 = 12 O Copyright 2012 John Wiley & Sons, Inc
  • 43. Your Turn! How many hydrogen atoms are found in Al(C2H3O2)3? a. 1 b. 9 1 Al c. 6 3*2=6C d. 7 3*3=9H 3*2=6O Copyright 2012 John Wiley & Sons, Inc
  • 44. Your Turn! The formula for ethyl alcohol is CH3CH2OH. How many H atoms are found in a molecule of ethyl alcohol? a. 6 1+1=2C b. 3 3+2+1=6H c. 5 d. 1 1O Copyright 2012 John Wiley & Sons, Inc
  • 45. Questions Review Questions (pg 58) – Do odd – Practice later even Paired Questions – Do 1, 5, 9, 13, 17, 21, 25, 29, 33, 37, 41 – Practice later every other even (2, 6, etc) Copyright 2012 John Wiley & Sons, Inc 1-45

Notes de l'éditeur

  1. Figure 3.1 The surface of a penny is made up of tiny identical copper atoms packed tightly together.
  2. Table 3.3 Symbols of the most common elements
  3. Table 3.4 Symbols of the elements derived from early names
  4. Table 3.5 The Periodic Table
  5. Figure 3.7 A representation of the decomposition of water into oxygen and hydrogen molecules.
  6. Figure 3.9 b Explanation of the formula of H2SO4
  7. Figure 3.9 c Explanation of the formula of Ca(NO3)2