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Wood replaces plastic
New business from Finnish forest 10.5.2014
Prof. Ali Harlin, Esa Torniainen, Jouni Lattu
VTT Technical Research Centre of Finland
207/05/2014 2
Bioeconomy – extended value
Modified from the source: Metsäteollisuus ry
2
Harvesting and logistics
Bioenergia- lämpö ja sähkö
teollisuudelle ja kotitalouksille
Biopolttoaineet liikenteeseen
Biokemikaalit
Biomateriaalit
Lääkkeet ja
kosmetiikka
Value
Volyme
Sellu, paperi ja kartonki viestintään, pakkaamiseen ja
pehmopapereihin sekä puutuotteet mm. rakentamiseen
Coatings
ladhesives…
Competitive
Existing
products
Uuden osaamisen
kerryttäminen
Investoinnit uuteen
teknologiaan ja
liiketoimintoihin
Globaali verkostoituminen
T&K ja innovaatiot
Bioenergy, Heat and
Electricity
Biofuels
Biochemicals
Biomaterials
Medical
Cosmetics
Wood products, cellulose,
paper and board
,Pellets
gasification…
Biopolymers, composites…
New materials,
products and
service
Bioenergy
Bio fuels
307/05/2014 3
Eco-efficient materials
Drivers
Goals
Reduce
Renew
Recycle
Light
Hi-performance
Replace oil
Low resouces
Raw-material efficiency
Click to edit Master title style
Click to edit Master text styles
Second level
Third level
Fourth level
Fifth level
407/05/2014 4
Basic research
Applied research
Development
UNIVERSITIES
INDUSTRY
VTT
VTT’s status as performer of R&D work
507/05/2014 5
Global packaging industry
Global packaging industry turnover 2013 nearly 600 Mrd EUR,
mainly in converted materials.
Primary packaging market is fragmented according to
materials, converting and packaging technologies.
Transport packaging dominated by corrugated board.
Industrial packaging is mainly corrugated, plastic films and
different containers.
Corrugated board 105 milj. tons, Plastics 80 milj. tons,
Cardboard 46 milj. tons, Bioplastics 1 milj. tons.
607/05/2014 6
100% bio-based packages
Recycled pulp and biopolymers
Compatibility in value chain
Effective production methods in packaging applications.
Flexible processing with conventional methods
707/05/2014 7
Typical Environmental Statements
Biodegradability
Compostability
Degradation in ocean
Biobased
Low carbon foot print
807/05/2014 8
Sustainable development is coming
Braskem sugar based polyethylene since 2009.
Johnson&Johnson, Danone, Tetrapak.
Coca-Cola launched 2009
PlantBottle with 30% bio
- targeting 100 % for PET .
Natureworks PLA has been
on markets for years, new
application coming (Danone).
907/05/2014 9
Hybrid cardboards – improved strength
From MD/CD to multiaxial strength
1007/05/2014 10
New fibre materials
Changed view-point:
Transparency
Moldabilty
Printability
1107/05/2014 11
Example: Fibre based blister
Concept:
Designed blisters
Simplified production
Apply moldable web
Apply bio barrier tech
Replace plastic and aluminum
1207/05/2014 12
Moldable web
New
Fibre based
Sustainable
Easy waste mgt
Communication
Material and design by VTT
1307/05/2014 13
Moldable web examples
Tray packaging demo, Drupa 2012
4 inventions:
Foam forming
Dispersions
Thermoforming
Translucency
Next on
Wood based deep drawn packages
1407/05/2014 14
Modified hemicellulose (side stream)
Products out of modified hemicellulose
Oxygen and grease barrier
Flexible and transparent film
Moldable film
Hydrogels (hygienic)
Active films
Hemicellulose hydrogel
(Aca/VTT)
Heat-activated cellulose film
(FC/VTT)
Flexible hemicellulose film
(FC/VTT)
Hemicellulose barrier
dispersion (KCL/VTT)
Mouldable hemicellulose film
(VTT)
1507/05/2014 15
What is nanocellulose?
Microscope Macro
Totally New
Properties
Esau, Anatomy of seed plants,
1977, Wiley, NY
Pääkkö et al,
Biomacromolecules,
8(2007)1934 1,7% solids
Young´s modulus 140 GPa
(T. Nishino et al. J.Polym.Sci.,Part B,1995)
Tensile strength 3 GPa
(D.Page, F. El-Hosseiny, J.Pulp Paper Sci. 1983)
Coefficient of thermal expansion 0,1 ppm/ºK
(H.Yano, Seminar lecture, Otaniemi 2009)
Aalto: Seppälä
VTT
1607/05/2014 16
Use of nanocellulose based on patents
Applications (NFC)
Composites (38%)
Disposables (18%)
Paper and board (16%)
Food products (13%)
Paper converting ( 8%)
Cosmetics (3%)
Filters (4%)
13 %
3%
18 %
4 %
16 %
8 %
38 %
NFC applications
Data collected by Dr. Juha Merta, Aalto University School of Science and Technology.
1707/05/2014 17
SEM x50 SE images from uncalendered
paper surfaces.
Peruspaperi
NFC-pinnoitettu paperi
Nanocellulose as paper coating
Thin film
Applied as foam
Surface can be modified efficiently
Reduce air permeability
No binders
Towards monomaterials
1807/05/2014 18
Nanocellulose films
Properties
Wood based
Biodegradable
Like HDPE film
Not discharging
Printable
Sustainable intelligent applications
1907/05/2014 19
Rigid foams made of bio-materials
Replacing oil
Light weight
Insulation, both thermal and mechanical
Applications from packaging to building
construction
Nanofibrillated cellulose
Pääkkö et al,
Biomacromolecules, 8(2007)1934
Nanocellulose foam
Light materials – Cellulose foam
2007/05/2014 20
VTT FiCus Concept – Simple, Flexible, Cost Competitive
Mixing
pulp,
surfactant
and air
Molding,
water
removal,
layering
Drying
Technology readiness level:
Demonstrators ready
2107/05/2014 21
Bio-barriers in food packages
Dry food
Replacing fluorochemicals in fast-food
packages.
Grease barrier for cookies and pizza
Oxygen barrier in frozen goods
High barrier solutions
2207/05/2014 22
Bioplastic synergy
• Plastic performance
• Production and logistics known
• Performing products
• Waste management: recycle or energy
Benefit
• Sustainable products for brands and retailers
• Added value for chemical and material industry
Our vision
Fibre materials are renewable
• Easy to recycle
• Low environment burden
• Synergy with (bio)plastics
TECHNOLOGY FOR BUSINESS

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Wood replaces plastics

  • 1. Wood replaces plastic New business from Finnish forest 10.5.2014 Prof. Ali Harlin, Esa Torniainen, Jouni Lattu VTT Technical Research Centre of Finland
  • 2. 207/05/2014 2 Bioeconomy – extended value Modified from the source: Metsäteollisuus ry 2 Harvesting and logistics Bioenergia- lämpö ja sähkö teollisuudelle ja kotitalouksille Biopolttoaineet liikenteeseen Biokemikaalit Biomateriaalit Lääkkeet ja kosmetiikka Value Volyme Sellu, paperi ja kartonki viestintään, pakkaamiseen ja pehmopapereihin sekä puutuotteet mm. rakentamiseen Coatings ladhesives… Competitive Existing products Uuden osaamisen kerryttäminen Investoinnit uuteen teknologiaan ja liiketoimintoihin Globaali verkostoituminen T&K ja innovaatiot Bioenergy, Heat and Electricity Biofuels Biochemicals Biomaterials Medical Cosmetics Wood products, cellulose, paper and board ,Pellets gasification… Biopolymers, composites… New materials, products and service Bioenergy Bio fuels
  • 4. Click to edit Master title style Click to edit Master text styles Second level Third level Fourth level Fifth level 407/05/2014 4 Basic research Applied research Development UNIVERSITIES INDUSTRY VTT VTT’s status as performer of R&D work
  • 5. 507/05/2014 5 Global packaging industry Global packaging industry turnover 2013 nearly 600 Mrd EUR, mainly in converted materials. Primary packaging market is fragmented according to materials, converting and packaging technologies. Transport packaging dominated by corrugated board. Industrial packaging is mainly corrugated, plastic films and different containers. Corrugated board 105 milj. tons, Plastics 80 milj. tons, Cardboard 46 milj. tons, Bioplastics 1 milj. tons.
  • 6. 607/05/2014 6 100% bio-based packages Recycled pulp and biopolymers Compatibility in value chain Effective production methods in packaging applications. Flexible processing with conventional methods
  • 7. 707/05/2014 7 Typical Environmental Statements Biodegradability Compostability Degradation in ocean Biobased Low carbon foot print
  • 8. 807/05/2014 8 Sustainable development is coming Braskem sugar based polyethylene since 2009. Johnson&Johnson, Danone, Tetrapak. Coca-Cola launched 2009 PlantBottle with 30% bio - targeting 100 % for PET . Natureworks PLA has been on markets for years, new application coming (Danone).
  • 9. 907/05/2014 9 Hybrid cardboards – improved strength From MD/CD to multiaxial strength
  • 10. 1007/05/2014 10 New fibre materials Changed view-point: Transparency Moldabilty Printability
  • 11. 1107/05/2014 11 Example: Fibre based blister Concept: Designed blisters Simplified production Apply moldable web Apply bio barrier tech Replace plastic and aluminum
  • 12. 1207/05/2014 12 Moldable web New Fibre based Sustainable Easy waste mgt Communication Material and design by VTT
  • 13. 1307/05/2014 13 Moldable web examples Tray packaging demo, Drupa 2012 4 inventions: Foam forming Dispersions Thermoforming Translucency Next on Wood based deep drawn packages
  • 14. 1407/05/2014 14 Modified hemicellulose (side stream) Products out of modified hemicellulose Oxygen and grease barrier Flexible and transparent film Moldable film Hydrogels (hygienic) Active films Hemicellulose hydrogel (Aca/VTT) Heat-activated cellulose film (FC/VTT) Flexible hemicellulose film (FC/VTT) Hemicellulose barrier dispersion (KCL/VTT) Mouldable hemicellulose film (VTT)
  • 15. 1507/05/2014 15 What is nanocellulose? Microscope Macro Totally New Properties Esau, Anatomy of seed plants, 1977, Wiley, NY Pääkkö et al, Biomacromolecules, 8(2007)1934 1,7% solids Young´s modulus 140 GPa (T. Nishino et al. J.Polym.Sci.,Part B,1995) Tensile strength 3 GPa (D.Page, F. El-Hosseiny, J.Pulp Paper Sci. 1983) Coefficient of thermal expansion 0,1 ppm/ºK (H.Yano, Seminar lecture, Otaniemi 2009) Aalto: Seppälä VTT
  • 16. 1607/05/2014 16 Use of nanocellulose based on patents Applications (NFC) Composites (38%) Disposables (18%) Paper and board (16%) Food products (13%) Paper converting ( 8%) Cosmetics (3%) Filters (4%) 13 % 3% 18 % 4 % 16 % 8 % 38 % NFC applications Data collected by Dr. Juha Merta, Aalto University School of Science and Technology.
  • 17. 1707/05/2014 17 SEM x50 SE images from uncalendered paper surfaces. Peruspaperi NFC-pinnoitettu paperi Nanocellulose as paper coating Thin film Applied as foam Surface can be modified efficiently Reduce air permeability No binders Towards monomaterials
  • 18. 1807/05/2014 18 Nanocellulose films Properties Wood based Biodegradable Like HDPE film Not discharging Printable Sustainable intelligent applications
  • 19. 1907/05/2014 19 Rigid foams made of bio-materials Replacing oil Light weight Insulation, both thermal and mechanical Applications from packaging to building construction Nanofibrillated cellulose Pääkkö et al, Biomacromolecules, 8(2007)1934 Nanocellulose foam Light materials – Cellulose foam
  • 20. 2007/05/2014 20 VTT FiCus Concept – Simple, Flexible, Cost Competitive Mixing pulp, surfactant and air Molding, water removal, layering Drying Technology readiness level: Demonstrators ready
  • 21. 2107/05/2014 21 Bio-barriers in food packages Dry food Replacing fluorochemicals in fast-food packages. Grease barrier for cookies and pizza Oxygen barrier in frozen goods High barrier solutions
  • 22. 2207/05/2014 22 Bioplastic synergy • Plastic performance • Production and logistics known • Performing products • Waste management: recycle or energy Benefit • Sustainable products for brands and retailers • Added value for chemical and material industry Our vision Fibre materials are renewable • Easy to recycle • Low environment burden • Synergy with (bio)plastics