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Integrity  Service  Excellence
Distribution A: Approved for public release; distribution is unlimited
MECHANICS OF
MULTIFUNCTIONAL
MATERIALS &
MICROSYSTEMS
7 March 2013
B. L. (“Les”) Lee, ScD
AFOSR/RTD
Air Force Research Laboratory
2
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
2013 AFOSR SPRING REVIEW
3002B PORTFOLIO OVERVIEW
Distribution A: Approved for public release; distribution is unlimited
3
INSPIRED BY BIOLOGY…
Creating a Synthetic Autonomic System
11
AUTONOMIC RESPONSE
Autonomy:Autonomy:
The ability to function in an
independent and automatic
fashion
Distribution A: Approved for public release; distribution is unlimited
4
INSPIRED BY BIOLOGY…
Creating a Synthetic Autonomic System
11
AUTONOMIC RESPONSE
Autonomy:Autonomy:
The ability to function in an
independent and automatic
fashion
11
FUNCTIONS OF INTEREST
Active Regulation
Reactive Materials
Mesoporous Networks
Adaptive Fluids/Solids
Self-Regulating
Function
Self-Generating
Function
Distribution A: Approved for public release; distribution is unlimited
5
Mechanization
Flexible Skins
Moving Beyond Swept Wing
Large Scale Area Changes
Showing It Can Be Done!
Enablers
Wind Tunnel Tests
NASA 16 Ft Transonic Dynamics Tunnel
Concepts
A First In Aviation History
MORPHING AIRCRAFT
Source: AFRL/RB
Adaptive Structures
Distribution A: Approved for public release; distribution is unlimited
6
• Structural materials are
made to NOT deform,
• Those that deform by
mechanization, add
weight and complexity
• Reconfiguring is easy
on land, but not air,
under sea, or in space
• Structural materials
made to deform on
demand with minimized
weight and complexity
is a key technology. 0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100 1000
ElasticModulus(GPa)
Max. Elastic Strain (%)
Bond stretching
Steel
Al alloy
PZN-PTPZT
T-D
CFRP
G10 SMA
Epoxy
Nylon 6,6
PMMA
PVDF
FSMA
Elastomers
Domain
reorientation
Bond & chain
straightening
Muscle
Ferrogels
Free volume
flow
Vitraloy
PAN
Polyaniline
LCE
IPMC
Ionic
Gel
Structural meta
Polymer – repta
Active material
Intercalants – fr
Elastomers – ch
Foams
Chain
unfolding
Common materials cannot achieve simultaneous high stiffness and
large deformation
G. McKnight (HRL, Inc.)
ADAPTIVE STRUCTURES:
TECHNICAL CHALLENGES
Distribution A: Approved for public release; distribution is unlimited
7
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
2013 AFOSR SPRING REVIEW
3002B PORTFOLIO OVERVIEW
Distribution A: Approved for public release; distribution is unlimited
8
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
2013 AFOSR SPRING REVIEW
3002B PORTFOLIO OVERVIEW
Distribution A: Approved for public release; distribution is unlimited
9
PROGRAM INTERACTION
AFOSR
Structural Mechanics
Structural Materials
Organic Chemistry
Biosciences
Microelectronics
OTHERS
AFRL/RV
Space Vehicles
AFRL/RB
Air Vehicles
AFRL/RW
Munitions
AFRL/RZ
Propulsion
EXTRAMURAL
UNIVERSITIES
INDUSTRY
MECHANICS OF
MULTIFUNCTIONAL
MATERIALS &
MICROSYSTEMS
AFRL/RX
Materials
Army
Navy
DARPA
NSF
ESF
NASA
AFRL/RY
Sensors
Distribution A: Approved for public release; distribution is unlimited
10
PROGRAM INTERACTION
AFOSR
Structural Mechanics
Structural Materials
Organic Chemistry
Biosciences
Microelectronics
OTHERS
AFRL/RB
Reconfigurable
AFRL/RW
UAV Sensors
AFRL/RX
Thermal Mgt
AFRL/RX
Vascular
AFOSR MURI ‘05
Self-Healing
AFOSR MURI ‘06
Energy Harvesting
EXTRAMURAL
UNIVERSITIES
INDUSTRY
MECHANICS OF
MULTIFUNCTIONAL
MATERIALS &
MICROSYSTEMS
AFRL/RX
Lightening
Army
Navy
DARPA
GameChanger ‘07
Antenna Integration
NSF
ESF
NASA
AFRL/RX
Composites
11
PROGRAM INTERACTION
AFOSR
Structural Mechanics
Structural Materials
Organic Chemistry
Biosciences
Microelectronics
OTHERS
AFRL/RB
Reconfigurable
AFRL/RW
UAV Sensors
AFRL/RX
Thermal Mgt
AFRL/RX
Active Polymer
EXTRAMURAL
UNIVERSITIES
INDUSTRY
MECHANICS OF
MULTIFUNCTIONAL
MATERIALS &
MICROSYSTEMS
AFRL/RX
Irradiation
Army
Navy
DARPA
Discovery CT ‘09
Reconfigurable
AFOSR MURI ’09
Sensory Network
Director’s Call ’09
Energy from Environ
NSF
ESF
NASA
AFRL/RX
Structrl Battery
AFOSR/RW CoE ’12
High-Rate Physics
AFOSR BRI ‘12
Biomolecules
Distribution A: Approved for public release; distribution is unlimited
12
• Self-healable or in-situ remendable structural materials
(1st-ever program; world lead)
• Microvascular composites for continuous self-healing
and self-cooling systems (1st-ever program; world lead)
• Structural integration of energy harvest/storage
capabilities (1st-ever program on harvest capabilities; DoD lead)
• Neurological system-inspired sensing/diagnosis/
actuation network (pot’l world lead)
• Biomolecules for sensing and actuation (pot’l world lead)
• Mechanized material systems and micro-devices for
reconfigurable structures (DoD lead)
• Experimental nano-mechanics (DoD lead)
Scientific Challenges &
Program Achievement
Distribution A: Approved for public release; distribution is unlimited
13
Transformational Opportunities
• Self-healable or in-situ remendable structural materials
– Quantum improvement in survivability of aerospace structures
• Microvascular composites for continuous self-healing
and self-cooling systems – Quantum improvement in
survivability of aerospace structures & thermal management
• Structural integration of energy harvest/storage
capabilities – Self-sustaining UAV and hybrid-powered aircraft
• Neurological system-inspired sensing/diagnosis/
actuation network – Autonomic state awareness in aerospace
• Mechanized material systems and micro-devices for
reconfigurable structures – Morphing wing aircraft &
Neutralization of penetration threats
Distribution A: Approved for public release; distribution is unlimited
14
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO TRENDS
Distribution A: Approved for public release; distribution is unlimited
15
donleo@vt.edu
Traditional Transducer Materials
Transduction
Mechanism
Material
Device/
System
Material
Transformation
Dipole
Rotation
Ion
Migration
Shape
Memory
Alloy
Piezoelectric
Ceramics and
Polymers
Ionomeric
Polymer
Materials
Increasinglengthscale
ENGINEERED DEVICES:
BEYOND CURRENT VISION
Distribution A: Approved for public release; distribution is unlimited
16
donleo@vt.edu
Traditional Transducer Materials
Transduction
Mechanism
Material
Device/
System
Material
Transformation
Dipole
Rotation
Ion
Migration
Shape
Memory
Alloy
Piezoelectric
Ceramics and
Polymers
Ionomeric
Polymer
Materials
Increasinglengthscale
donleo@vt.edu
The question we are studying …
How can we use
biomolecules to
make completely
new types of
materials for
engineered
devices? Transduction
Mechanism
Material
Device/
System
Channels,
Pumps,
Transporters
Durable,
Robust,
Easy to
Manufacture
Sensors,
Energy
Capture and
Conversion,
Color Changes
Increasinglengthscale
ENGINEERED DEVICES:
BEYOND CURRENT VISION
Distribution A: Approved for public release; distribution is unlimited
17
Structure of the mechanically-activated
channel MscL (top left), the voltage-
gated channel alamethicin (top right),
and the light-activated channel
bacteriorhodopsin (bottom).
Gating response of the
voltage-gated channel
alamethicin to an applied
potential.
Over 3.5 billion years of evolution,
nature has produced a highly
diversified set of biomolecular
transducers that exhibit a wide range
of transduction properties.
In the past two decades humans have
been able controllably modify these
transduction properties and
incorporate them into durable
material systems.
A biomolecular unit cell utilizes the stimuli-responsive
properties of biomolecules as a means of creating new
transducer materials.
How can we utilize the stimuli-responsive properties of
biomolecules to create a new class of transducer system?
Co-PM’s: B. L. Lee, Hugh Delong
BRI’12 - BIOMOLECULES FOR
SENSING (VT/U TN/U MD/UIUC: Leo)
Distribution A: Approved for public release; distribution is unlimited
18
Design by Nature:
BONE REMODELING
Resorption vs Ossification; 4~20% renewal per year;
Subjecting a bone to stress will make it stronger
Fig. 6-4a Anatomy and Physiology: From Science to Life © 2006 John Wiley & Sons
US-Europe Workshop on
Structural Regeneration
(27-28 June 2012, Venice)
Co-organized by AFOSR, ARO,
U Illinois & Max Planck Inst.
Distribution A: Approved for public release; distribution is unlimited
19
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
Transition from: Active Materials for
Adaptive Structures
Distribution A: Approved for public release; distribution is unlimited
20
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
Transition from: Active Materials for
Adaptive Structures
Distribution A: Approved for public release; distribution is unlimited
21
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
48
• To design better actuators/morphing
devices using shape memory alloy
honeycomb which combines benefits of
cellular structures and monolithic SMA’s
Objectives:
• After non-uniformity due to structural
level instabilities at moderate strains, the
deformation pattern becomes uniform
again upon further straining .
• This morphing behavior reverses under
unloading.
CELLULAR SHAPE MEMORY
STRUCTURES (U Mich: Triantafylli)
47
 Forest-drawn carbon nanotube sheets
have higher specific strength than steel.
 Charge injection of carbon nanotube
sheets produces giant width-direction
actuation (>3.3 X) from 80 to 1900 K.
 Sheets CONTRACT in nanotube
direction by up to 2% during actuation.
 Generated stress is 32 times the stress
generation capability of natural muscle.
Motor
Nanotube Forest
Mandrel
Meterlongcarbonnanotubesheet
Forest
Sheet (right) being spun
from nanotube forest (left)
Side view of above sheet
spinning from forest
300 K, 0 kV
300 K, 5 kV
1500 K, 5 kV
NANOTUBE ARTIFICIAL MUSCLE
(U Texas Dallas: Baughman)
57
Commonly Used Shape Memory
Polymers (SMP)
 One-way shape memory (SM) effects  Not
being able to recover the temporary shape
 No design tools available
Two-way Shape Memory Polymers
 Two-way SM effects using switching
between two stable states  No two-way SM
due to intrinsic material property change
Two-way SMPs Applications
 Require combinatorialmethods for
material synthesis, modeling, and design.
Two-Way SMP by the Concept of
Opposing Microstructural-Scale
Spring
 Two opposing spring can generate motions
if one or both of them can change properties
as temperature changes  Opposing spring
can be realized through material/structure
design at micro-scale.
MAIN ACHIEVEMENTS:
 Demonstrate two-way shape memory effects assisted by
external force.
 Fabricate reversible free-standingtwo-way shape
memory polymer composites.
HOW IT WORKS:
 Stretched induced crystallization (SIC) can relax the
stress  Opposing microstructural-scalespring creates
reversible free-standingtwo-way SMP  Shape memory
effect is fully reversible.
Current Impact
 First free-standing two-way SMP based on
intrinsic materialproperty change  Large
reversible actuation strain
Planned Impact
 Two-way SMPs for multifunctional
structural  Design tools that enhance robust
design  Novel applicationsbased on two-
way SMP
Research Goals
 Complete understanding of material
behaviors  Design tools for novel
applications of these materials  Explore
other polymer-based shape memory
materials  Explore applications with AFRL
STATUSQUO
END-OF-PHASEGOALQUANTITATIVEIMPACT
NEWINSIGHTS
Proposed applications:a) Rotational actuation
in shear to enable autonomous rotation for
mirror motion, wing joints. b) Reversible
blistering of two-way SMPs for variable
boundary layer aircraftcontrol surfaces.
Ki Ks(T)Ki Ks(T)
The spring on
the left has a
constant
stiffness Ki and
the stiffness of
right spring Ks
depends on the
temperature.
SMP
in shearStator
Rotor
Reversible Torsion
Via SMP Shear
to mirror(a)
(b)
SMP
in shearStator
Rotor
Reversible Torsion
Via SMP Shear
to mirror
SMP
in shearStator
Rotor
Reversible Torsion
Via SMP Shear
to mirror(a)
(b)
Two-way shape
memory effect
assisted by an
external force
2W-SMP 2W-SMP is
stretched at
high T, then
cooled to low T
2W-SMP is
laid on top
of the
polymer
A polymer
layer is photo-
synthesized
on top.
0mn 1min 2min 3min 4min 5min 6min 7min
Heating Cooling
REVERSIBLE SHAPE MEMORY
(Syracuse U / U CO: Mather)
59
• Developed model to describe BZ gels
with chemo-responsive X-links
– Modified Oregonator model
– f – dependent complex formation
– Time-dependent elastic contribution
• Studied response to steady and periodic
compression in 1D model
• Mechanical impact increases X-link density
– Self-reinforcing material
– Stiffens in response to impact
V.V. Yashin, O. Kuksenok, A.C. Balazs,
J. Phys. Chem. B 2010, 114(19), 6316.
+
Oxidation
Reduction
PP
0.511 0.926
c/c
0
DESIGNING SELF-REINFORCING
MATERIALS (U Pitt: Balazs)
x / L0
45 kPa
c/c
0
Transition from: Active Materials for
Adaptive Structures
Distribution A: Approved for public release; distribution is unlimited
22
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
27
1st Bird-like Morphing UAV (TU Delft-led team):
 Design of a morphing wing with feathers inspired by birds.
 A servo sweeps the first feather back and forth with a
pushrod. The other feathers are connected with a parallel
mechanism to the first feather and follow.
 The 50cm long wing is built of super-thin light-weight
carbon fiber composites with the plane weight of 100 gram.
 Successfully flew in an impressive wind force 5-6.
BIRD-LIKE MORPHING WING
Courtesy of D. Lentink (Stanford U)
Transition to: Multifunctional
Design of Morphing Air Vehicles
Distribution A: Approved for public release; distribution is unlimited
23
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
27
1st Bird-like Morphing UAV (TU Delft-led team):
 Design of a morphing wing with feathers inspired by birds.
 A servo sweeps the first feather back and forth with a
pushrod. The other feathers are connected with a parallel
mechanism to the first feather and follow.
 The 50cm long wing is built of super-thin light-weight
carbon fiber composites with the plane weight of 100 gram.
 Successfully flew in an impressive wind force 5-6.
BIRD-LIKE MORPHING WING
Courtesy of D. Lentink (Stanford U)
Transition to: Multifunctional
Design of Morphing Air Vehicles
New Focus:
Morphing air vehicles capable
of altering the geometry,
surface area and mechanical
properties of wing structures
Mimicking “muscular-skeletal”
system of bird wings
Deploying mechanized active
materials and computational
metamaterials for structural
reconfiguration.
Objective:
To achieve multifunctional design of morphing air
vehicle as an autonomic system (in collaboration with
the expertise in biomimetics, dynamics and control)
Distribution A: Approved for public release; distribution is unlimited
24
PROGRAM COLLABORATION
THE 2ND “MULTIFUNCTIONAL
MATERIALS FOR DEFENSE”
WORKSHOP
Theme: Sensing, Actuation & Energy Transduction
In conjunction with:
The 2012 Annual Grantees’/Contractors’ Meeting for
AFOSR Program on “Mechanics of Multifunctional
Materials & Microsystems"
30 July-1 August 2012
Hilton Arlington Hotel, Arlington, VA
Workshop Co-Chairs:
Gregory Reich (AFRL/RBSA)
William Nothwang (ARL/SEDD)
James Thomas (NRL)
Organizing Committee:
B.-L. (“Les”) Lee (AFOSR), Co-Chair
David Stepp (ARO), Co-Chair
Ignacio Perez de Leon (ONR), Co-Chair
William Baron (AFRL/RBSA)
Jeff Baur (AFRL/RXBC)
Mark Derriso (AFRL/RBSI)
Gregory Reich (AFRL/RBSA)
William Nothwang (ARL/SEDD)
Daniel O’Brien (ARL/WMRD)
James Thomas (NRL)
Agent for 8 Projects; Concluded
Proposed for
AFOSR-NSF
Collaboration:
“Muscular-Skeletal
System Inspired
Reconfigurable
Materials Design”;
“Structural
Regeneration &
Remodeling”
Pot’l MURI or BRI
BioSensing and BioActuation
Proposed Research Opportunities/Challenges
1. Hierarchical Organization of Biological Systems
Uncover the unifying aspects underlying hierarchical bio-structures and bio-systems and use
them for sensing and actuation; apply to new multi-scale and multi-functional sensor/actuator
concepts.
2. Sensor Informatics Guided by Life
Create new knowledge that will be exploited in novel bio-inspired data mining and dynamic
control, including capabilities to monitor, assess, and control living and engineered systems in
sensor-rich environments.
3. Multifunctional Materials and Devices for Distributed
Actuation and Sensing
Understand biological systems and mechanisms that lead to their ability to exhibit fault-tolerant
actuation with a wide dynamic range, the production of practical means for producing artificial
structures that exhibit similar behaviors, and their incorporation into useful engineered systems.
4. Forward Engineering & Design of Biological/Biomedical
Components & Systems
Synthesize hybrid synthetic-living systems through systems-level integration of biological and
engineered components that sense, actuate, compute, regenerate and efficiently allocate
resources in order to achieve desired responses and functions.
Design of Engineering
Materials Systems
(DEMS)
Martin L. Dunn, Mary Toney, Clark Cooper,
Grace Hsuan, Christina Bloebaum
Program Directors
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25
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
Distribution A: Approved for public release; distribution is unlimited
26
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Tsu-Wei Chou (U Del)
Yuntian Zhu (NCSU)
Ioannis Chasiotis (UIUC)
Liping Liu (Rutgers U)^
David Kisailus (UC Riverside)*
Pablo Zavattieri (Purdue U)
Don Leo (VA Tech)#
S. Andrew Sarles (U TN)
Sergei Sukharev (U MD)
Narayan Aluru (UIUC)
^ YIP; * HBCU/MI; # BRI
Distribution A: Approved for public release; distribution is unlimited
27
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Tsu-Wei Chou (U Del)
Yuntian Zhu (NCSU)
Ioannis Chasiotis (UIUC)
Liping Liu (Rutgers U)^
David Kisailus (UC Riverside)*
Pablo Zavattieri (Purdue U)
Don Leo (VA Tech)#
S. Andrew Sarles (U TN)
Sergei Sukharev (U MD)
Narayan Aluru (UIUC)
^ YIP; * HBCU/MI; # BRI
Subject:
Thin Flexible CNT Composites
>> Compliant Nano-spring Interfaces
Designing Structures for Functional Materials
Damage-tolerant Biological Composites
>> Biomolecular Materials for Sensing & Actuation
>> New
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28
Radular Teeth of Chiton (elongated mollusk):
 Ribbon-like structure covered with small dentacles for
tearing food into pieces
 Composed of an nanocrystalline iron phosphate core with
a magnetite veneer edge
 The deposited mineral phase is ultra hard and abrasion
resistant and 4-fold modulus difference at core-veneer
interface effectively deflects crack propagation
DAMAGE TOLERANT BIOLOGICAL
COMPOSITES (UCR: Kisailus)
Chiton
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29
DAMAGE TOLERANT BIOLOGICAL
COMPOSITES (Purdue U: Zavattieri)
(a) Micromechanical model of
rod like structure of radular
tooth, including a potential
RVE. (b) Hierarchical model to
connect nano- to microscale.
(c) Hierarchical model to
connect the microscale to
macroscopic fracture tests.
Relevance: Bio-inspired design of
gears or abrasion-resistant materials
(c)
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30
Synthesis and Fabrication of
Multi-Cellular Arrays:
 Autonomic, multifunctional behavior can only
be achieved by incorporating large numbers
of stimuli-responsive “cells” into the material.
 The program will establish in-depth
understanding of the methods required for
synthesizing and fabricating multicellular
material systems with characteristic length
scales less than 100 microns and functional
densities that approach those of natural
systems.
GOALSACCOMPLISHMENTSNEXTSTEPS
Fabricated a four-cell material
system with a characteristic
length scale on the order of
100s of microns.
Measured voltage-gated
channel activity across
multiple interfaces in this
four-cell material.
Begin the development of injection and printing methodologies for multi-cell arrays.
BRI’12 - BIOMOLECULES FOR
SENSING (VT/U TN/U MD/UIUC: Leo)
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31
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Patrick Mather (Syracuse U)
H. Jerry Qi (U CO)
Martin Dunn (U CO)
Shiv Joshi (NextGen)
Sharon Swartz (Brown U)
Nakhiah Goulbourne (VA Tech)
Minoru Taya (U WA)
Frank Ko (U Brit Columbia)
Nicolaus Correll (U CO)
Ray Baughman (U Texas Dallas)
A. John Hart (U Mich)^
Aaron Dollar (Yale U)^
Xin Zhang (Boston U)
C. T. Sun (Purdue U)
Olivier Mondain-Monval (CNRS)
Thomas Siegmund (Purdue U)
Anna Balazs (U Pitt)
Nicole Zacharia (Texas A&M)
Richard Vaia (AFRL/RXBN)
Greg Reich (AFRL/RBSA)
^ YIP
Distribution A: Approved for public release; distribution is unlimited
32
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Patrick Mather (Syracuse U)
H. Jerry Qi (U CO)
Martin Dunn (U CO)
Shiv Joshi (NextGen)
Sharon Swartz (Brown U)
Nakhiah Goulbourne (VA Tech)
Minoru Taya (U WA)
Frank Ko (U Brit Columbia)
Nicolaus Correll (U CO)
Ray Baughman (U Texas Dallas)
A. John Hart (U Mich)^
Aaron Dollar (Yale U)^
Xin Zhang (Boston U)
C. T. Sun (Purdue U)
Olivier Mondain-Monval (CNRS)
Thomas Siegmund (Purdue U)
Anna Balazs (U Pitt)
Nicole Zacharia (Texas A&M)
Richard Vaia (AFRL/RXBN)
Greg Reich (AFRL/RBSA)
^ YIP
Subject:
<< Reversible Shape Memory Polymer Composites
<< Ultra-Maneuverable Bat Technologies
<< Bio-inspired Reconfigurable Structures
Self-Assembly and Self-Repair of Structures
Artificial Muscles for Large Stroke & High Force
Morphing CNT Microstructures
Active Cells for Multifunctional Structures
Metamaterial Enhanced MEMS
Acoustic Metamaterials w Local Resonance
Ultrasonic Tunable Ultra-Damping Metamaterials
Macroscale Meta-Materials
Active Materials w Sensory & Adaptive Capabilities
Mechano-Responsive Polymer Systems
>> Mechanically-Adaptive Materials
Thermally-Activated Reconfigurable Systems
>> New; << Concluded
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33
 effE
ω0: local resonance frequency
Effective stress-strain relations
Effective Young’s modulus• A model is formulated for acoustic metamaterials
with locally resonant microstructures.
• Under sinusoidal loading the stress-strain
relation depends on the frequency.
• Near the local resonance frequency ω0 of the side
masses, the effective modulus is extremely large.
• The effective Young’s modulus becomes
negative in a certain frequency range.
• Wave amplitude decays when its frequency falls
inside this band gap, especially if the frequency is
near the frequency ω* .
• At the lower bound frequency of the band gap ω*,
the effective modulus approaches zero.
Negative
Modulus
METAMATERIALS WITH NEGATIVE
MODULUS (Purdue U: Sun)
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34
Experimental Setup
• Piezoelectric actuator patches were used for generating
in-plane and out-of-plane waves
• Piezoelectric sensor patch was used for wave reception.
Actuator
Sensor
Direction of Wave Propagation
Result
• Significant attenuation of wave amplitude after passing
through the metamaterial.
• Band gap regions of experimental results agree with that
of the theoretical prediction (shaded regions).
Input of In-plane PulseOutput of In-plane Pulse
Output of Out-of-plane
Pulse
Input of Out-of-plane
Pulse
Goals
• Develop acoustic metamaterials for mitigating
dynamic/impulsive loads
• Utilize the unusual wave propagation behavior of
acoustic metamaterials in signal transmission,
vibration isolation, and wave mode switching.
METAMATERIALS WITH NEGATIVE
MODULUS (Purdue U: Sun)
Acoustic
Metamaterial
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35
CURRENTSTATENEWINSIGHTS
QUANTITATIVEIMPACTEND-OF-PHASEGOAL
MAIN ACHIEVEMENTS (Cont’d): Current Impact
Inertial Measurement (IM)
• Acceleration and angular velocities recorded for
straight and obstructed flights
• Dorsal mount miniature wireless IM Unit (IMU)
Mechanical Characterization of Bat Membrane
• Strain experiments
• Constitutive modeling
-Fiber bundle dist.
-Fiber bundle comp.
-Base matrix corrugation
• Result satisfy material
anisotropy property
MAIN ACHIEVEMENTS:
Skeletal Assembly
• Bones assembled in CAD
• CAD model guides
mechanical design
Robotic Wing
• 4 DOF
• High flapping frequency
Data Smoothing, Motion Trajectory
• Motion capture data
improved
• Motion trajectory defined
for humerus and radius
• High-fidelity models for
components and integrated
structure representative of a
bat-wing
• Quantitative evaluation of
flight performance, energy
consumption / efficiency
• Estimates of weight, volume
and geometry of a robotic
bat-wing
• Guidelines to develop an
autonomous, hovering, highly
maneuverable, bat-like MAV
• Reconfigurable hovering ultra-maneuerable
bat technologies (RHUMBAT) offers
potential benefits in operational robustness.
• Most research has focused on recreating
three degrees of freedom (DOF’s) assoc
with this motion: flap, lag, and feather
• Small vehicle size and low inertia make
fine-scale control required for envisioned
missions difficult.
• New unique approach considers actuators
that are distributed across the structure.
• Provides detailed analysis for selection of
actuation DOF using motion capture and
revealing complex morphologies of
joints.
• Wing membrane characterization shows
thickness inhomogeneities to be
considered in materials selection.
• In depth understanding of
bat skeletal structure and
skeletal dynamics during
flight
• Materials analysis for
structural & aerodynamic
surfaces
• Translation of bat dynamics
to robotic system
Biological Experiments
• Examined wing fiber
under polarized light
• Guides constitutive
model development
IMU
Right wing assembly
Preliminary design
Wing fibers
Improved suturing and biaxial setup
Simulated Stress-Strain CurveBiaxial loading
Strain analysis
BAT-INSPIRED MORPHING WING
(NextGen/Brown U/VPI: Joshi)
36
• Reconfiguration planning for smart
structures with embedded sensing,
computation and actuation
• Take into account physical
constraints including gravity, wind
and vibration
• Enabling materials with the ability
to self-reconfigure and self-repair
Objectives:
Achievements:
Reconfiguration planning
• Initial focus: robotic assembly under
gravity constraints
• Discrete/Continuous search
framework combining graph-based
search, FEA and full-physics
simulation
Platform development
• Begun development of light-weight
in-air self-assembly test-bed
• Begun development of manipulation
test-bed
• Begun development of variable
stiffness material
Perspectives:
• Novel structural components that
can change their shape, function and
appearance
• Reconfigurable materials to change
function taking into account and in
response to physical constraints
Flying/self-mobility External
actuation
In-material sensing, computation
and actuation
Approach:
• Combination of finite element
analysis and real-time physics
simulation with discrete search to
find suitable reconfiguration paths.
• Embedding of intelligence for
sensing and control of
internal/external actuators
Light-weight in-air module; robotic assembly;
variable stiffness material with embedded
sensing/actuation
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Assembly graph of a T-structure (left),
full-physics simulation (right)
Smart Structures
SELF-ASSEMBLY & SELF-REPAIR
(U CO: Correll)
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37
43
Capability/Payoff
Objective
Programs Involved
Approach
To establish new “morphing” aerospace structures
capable of altering their shape, functionality and
mechanical properties for real-time optimization
in response to the changes in environments or
operating conditions
• Develop new concepts for structural reconfiguration, energy
transduction mechanisms and system integration allowing the
combination of UAV and space-deployable systems.
• Indentify new adaptive materials, mechanized material systems and
micro-devices for sensing, communication or actuation.
• Model the influences of morphology, dimensionality and topography
on the multifunctional performance and manufacturability.
• Reduce weight/size and increase the system efficiency by
incorporating multi-functionality into load-bearing structures
• Allow mission-specific and real-time optimization of multi-
functional performance of military systems
• Potential systems to be impacted are: unmanned aerial
vehicles (UAV), sensor platforms, dash/loiter theatre
dominance platforms, space deployable systems, etc.
DCT’09: SUPER-CONFIGURABLE
MULTIFUNCTIONAL STRUCTURES
Mechanics of Multifunctional
Materials & Microsystems;
Structural Mechanics;
Polymer Composites;
High Temperature Materials
Workshops:
(a) AFRL-wide Brainstorming
Discussion (Arlington, VA, 26
February 2007)
(b) 6th AFOSR Workshop on
“Multifunctional Aerospace
Materials & Structures:
Manufacturing Issues” (Seattle,
WA, 18-19 September 2007)
(c) AFOSR/NSF/ESF Workshop
on "Adaptive Structures and
Materials” (St. Maximin, France,
4-7 November 2007)
(d) AFOSR/ARO/DARPA
Workshop on "Bio-inspired
Networks” (Boston, MA, 29-30
November 2007)
(e) AFRL-wide Round Table
Discussion on DCT Topic (Eglin
AFB, FL, 28 January 2008)
27
1st Bird-like Morphing UAV (TU Delft-led team):
 Design of a morphing wing with feathers inspired by birds.
 A servo sweeps the first feather back and forth with a
pushrod. The other feathers are connected with a parallel
mechanism to the first feather and follow.
 The 50cm long wing is built of super-thin light-weight
carbon fiber composites with the plane weight of 100 gram.
 Successfully flew in an impressive wind force 5-6.
BIRD-LIKE MORPHING WING
Courtesy of D. Lentink (Stanford U)
Transition to: Multifunctional
Design of Morphing Air Vehicles
New Focus:
Morphing air vehicles capable
of altering the geometry,
surface area and mechanical
properties of wing structures
Mimicking “muscular-skeletal”
system of bird wings
Deploying mechanized active
materials and computational
metamaterials for structural
reconfiguration.
Objective:
To achieve multifunctional design of morphing air
vehicle as an autonomic system (in collaboration with
the expertise in biomimetics, dynamics and control)
Distribution A: Approved for public release; distribution is unlimited
38
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Sven Bilén (Penn St U)
Michael Strano (MIT)
Max Shtein (U Mich) #
Henry Sodano (U FL)
Dan Inman (VA Tech)
Greg Carman (UCLA)
Wonbong Choi (FL Int’l U)
Ioannis Chasiotis (UIUC)
Hugh Bruck (U MD)
Gleb Yushin (GA Tech)^
Carmel Majidi (Carnegie-Mellon)^
Michael Durstock (AFRL/RXBN)
Benji Maruyama (AFRL/RXBN)
John Coggin (Prime Photonics)+
Shashank Priya (VA Tech)+
^ YIP; # PECASE; + STTR
Distribution A: Approved for public release; distribution is unlimited
39
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Sven Bilén (Penn St U)
Michael Strano (MIT)
Max Shtein (U Mich) #
Henry Sodano (U FL)
Dan Inman (VA Tech)
Greg Carman (UCLA)
Wonbong Choi (FL Int’l U)
Ioannis Chasiotis (UIUC)
Hugh Bruck (U MD)
Gleb Yushin (GA Tech)^
Carmel Majidi (Carnegie-Mellon)^
Michael Durstock (AFRL/RXBN)
Benji Maruyama (AFRL/RXBN)
John Coggin (Prime Photonics)+
Shashank Priya (VA Tech)+
^ YIP; # PECASE; + STTR
Subject:
<< Energy Harvesting via Electrodynamic Tethers
Environmental Hydrocarbon Harvesting via CNT
Energy Harvesting Textile Composites
Active Structural Fibers for Multif’l Composites
Vibration Suppression and Energy Harvesting
Nanoscale Based Thermal Energy Harvesting
Flexible Battery of Graphene-CNT Hybrid
Integrity of Energy Harvest/Storage Materials
Integrated Solar Cells for MAV Wings
>> << Electrodes for Multifunctional Li-ion Battery
>> Energy Harvesting for Soft-Matter Machines
Nanomaterials for Structural Batteries
Hybrid Energy Harvesting Systems
>> New; << Concluded
Distribution A: Approved for public release; distribution is unlimited
40
Film of nanosprings fabricated by glancing
angle deposition (GLAD).
Solid cap layer
Cu nanosprings
Metal or ceramic substrate
Fragmentation of a 2-µm thick ZnO/Si solar cell
bonded on (±45°)4 laminate loaded according to
the arrows. The vertically parallel strips are
ZnO/Si film fragments.
Challenges for Integration of Solar Cells & Batteries into Load-Bearing Composite Structures:
 Materials degradation of thin film solar cells and batteries during curing of the composite materials.
 Thermal mismatch between thin films and the underlying structure generate high strains. As a result, the
integrated structure could suffer wavy blister type delamination and fragmentation failure.
 Prior efforts to integrate thin film solar cells with CFRPs pointed out 0.3% and 1% critical strains for
performance reduction and fragmentation failure respectively.
 Micron- or nano-scale springs of metallic or ceramic thin films benefit from size effects to provide
compliant, yet strong and tough, multifunctional interface (A new grant initiated) .
 High capacity battery electrodes are prone to cracking under stress upon lithiation.
STRUCTURAL INTEGRITY OF
ENERGY DEVICES (UIUC: Chasiotis)
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41
Traditional Electrodes &
Cell Architecture
• Low electrical conductivity
• Low thermal conductivity
• Heavy/bulky metal foils
• No mechanical strength
Uncoated portion of CNT
fabric serves as a current
collector
Strong and flexible Mg- or Si- coated
CNT fabric as an anode; Cannot be
replaced with uncoated CNT due to
mechanical degradation induced by Li
15-50 µm
Anode
15-50 µm
Cathode
Active coating
Multifunctional Nanocomposite Fabric
for Electrodes & Current Collector
• Ultra-high electrical conductivity
• High thermal conductivity
• No metal foil current collectors needed
• High mechanical strength
• Enhanced safety (with solid electrolyte)
solid electrolyte
LiV2O5 coated CNT
fabric as a cathode
Cu current collector; Graphite anode with
PVDF binder; LiMOx cathode (M: Co, Mn, Ni)
YIP’09 - LOAD BEARING BATTERIES
(GA Tech: Yushin)
Distribution A: Approved for public release; distribution is unlimited
42
20 40 60 80 100
0
50
100
150
200
250
300
350
400
450
500
550
600
Regular Graphite-PVDF Anode on Cu foil
LiExtractionCapacity(mAh/g)
Cycle Index
Multifunctional Si-on-CNT Fabric Anode (54% Si)
(limited Li insertion to avoid Li insertion into CNT)
Regular Graphite Anode
Si-coated CNT Fabric Anode
1 mm
40 mm
25
50
75
100
125
150 StructuralsteelA36
CastironASTM40
Ti99.5%
Alalloy713
Alalloy514
Brass
Cu99.5%
CastironASTM20
SpecificStrength/kNmkg
-1
Alalloy443
Si-CNT
fabric
YIP’09 - LOAD BEARING BATTERIES
(GA Tech: Yushin)
Distribution A: Approved for public release; distribution is unlimited
43
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Alma Hodzic (U Sheffield)
Tom Darlington (Nanocomposix)+
Tony Starr (SensorMetrix)+
Tom Hahn (UCLA)+
Nancy Sottos (UIUC)
Scott White (UIUC)
Jeffrey Moore (UIUC)
Jimmy Xu (Brown U)
Ajit Roy (AFRL/RXBT)
Abraham Stroock (Cornell U)
Noel Holbrook (Harvard U)
Patrick Kwon (Mich St U)
George Lesieutre (Penn St U)
Mary Frecker(Penn St U)
James Adair(Penn St U)
Assimina Pelegri (Rutgers U)
Aaron Esser-Kahn (UC Irvine)^
Jim Thomas (NRL)
Jeff Baur (AFRL/RXBC)
Ajit Roy (AFRL/RXBT)
^ YIP; + STTR
Distribution A: Approved for public release; distribution is unlimited
44
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Alma Hodzic (U Sheffield)
Tom Darlington (Nanocomposix)+
Tony Starr (SensorMetrix)+
Tom Hahn (UCLA)+
Nancy Sottos (UIUC)
Scott White (UIUC)
Jeffrey Moore (UIUC)
Jimmy Xu (Brown U)
Ajit Roy (AFRL/RXBT)
Abraham Stroock (Cornell U)
Noel Holbrook (Harvard U)
Patrick Kwon (Mich St U)
George Lesieutre (Penn St U)
Mary Frecker(Penn St U)
James Adair(Penn St U)
Assimina Pelegri (Rutgers U)
Aaron Esser-Kahn (UC Irvine)^
Jim Thomas (NRL)
Jeff Baur (AFRL/RXBC)
Ajit Roy (AFRL/RXBT)
^ YIP; + STTR
Subject:
<< Inkjet-Assisted Creation of Self-Healing Layers
<< Remendable Composites w Resistive Heating
<< Interfacial Self-Healing in Composites
Regeneration & Remodeling of Composites
<< Thermal Signature Reduction & EMI Shielding
<< Carbon Fiber Morphology for Thermal Materials
Plant-mimetic Heat Pipes
New Generation of Perspirable Skin
Variable Thermal Conductivity Structures
Graphene Composites for Lightning Protection
Microvascular Systems for Mass/Energy Transport
>> Multifunctional Poro-Vascular Composites
>> Composites under High Energy Irradiation
>> New; << Concluded
Distribution A: Approved for public release; distribution is unlimited
45
10 um
h =
thealed
tvirgin
=
Ph
Pv
= 100%
 Full recovery of interfacial adhesion is observed for glass fibers with the capsules
of EPA solvent + EPON 862 resin outperforming DCPD/Grubbs system.
Functionalized
glass fiber
EPA solvent + EPON 862
resin healing chemistry
200 nm
TEM image of
nanocapsules
Single fiber microbond test
INTERFACIAL SELF-HEALING IN
COMPOSITES (UIUC: Sottos)
Distribution A: Approved for public release; distribution is unlimited
46
 Successfully processed the 1st self-healing prepreg in continuous production mode
SEM image of E-glass fiber tow (200 count)
with 3.3 μm diameter PU/UF microcapsules
Fiber tow Sized fiber Dried fiber
0◦ : 1ply
90◦ : 10 plies
[0/905 ]s
0◦ : 1ply
 Cross-ply laminates of self-healing composite with well dispersed microcapsules
were fabricated from prepreg.
E-glass fiber/epoxy resin
Matrix: EPON862/EPIKURE3274
Microcapsules
Core: 97:3 EPA(solvent)/EPON862
Shell: Polyurethane/polyUF shell
INTERFACIAL SELF-HEALING IN
COMPOSITES (UIUC: Sottos)
Proposed:
STTR (incl. Phase III) program
covering multidisciplinary
research on “self-healing
composites” and involving the
academia, AFRL and industry
Distribution A: Approved for public release; distribution is unlimited
47
STRUCTURAL REMODELING
(UIUC: White/Moore) - Update
Regeneration in Nature:
Tree skink
lizard
Linckia
starfish
Human
bone
Approach: Dynamic Polymers + Inert Scaffolds
Accomplishments:
• Synthesis of dynamic polymers which undergo stimuli-
responsive (de)polymerization via reversible covalent
bonds (i.e. liquid to solid and vice versa).
• Systematic study of structure-property relationships for
dynamic polymers based on ionic bonds that are
generally stronger and widely used in biological
systems such as sacrificial bonds and proteins.
• A new class of material called ionic molecular glass
which form a rigid network of ionic bonds below Tg .
• Developed novel bi-stage chemistry for regeneration
allowing independent temporal control of sol-gel and
gel-polymer transitions
Sol Gel Polymer
Distribution A: Approved for public release; distribution is unlimited
48
Phase Changing Polymer -
Poly(N-isopropylacrylamide) (PNIPAM)
 When heated in water above Lower Critical
Solution Temperature (LCST) of ~32oC, it
undergoes a reversible phase transition
from a swollen hydrated state to a shrunken
dehydrated state, losing ~90% of volume.
 Melting point depends on molecular weight:
96oC for molecular weight of 20,000.
 Signature of polymer phase-change is still
seen at ~32oC with high heating rate for
CNT reinforced composites with PNIPAM
matrices.
CNT-PNIPAM composite
LCST
Proposed: Synthetic skin for self-regulated
cooling (‘sweating’) leading to thermal
signature reduction
SELF-COOLING COMPOSITES
(Brown U: Xu)
Porous Al2O3 Membrane
Distribution A: Approved for public release; distribution is unlimited
49
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Erik Thostenson (U Del)^
Gregory Huff (Texas A&M)
Zoubeida Ounaies (Penn St U)
Michael Bevan (Johns Hopkins U)
Alexander Bogdanovich (NCSU)
Philip Bradford (NCSU)
fu-Kuo Chang (Stanford U)
Akira Todoroki (Tokyo Tech)
fu-Kuo Chang (Stanford U)*
Xian Wang (Stanford U)*
Boris Murmann (Stanford U)*
Robert McLeod (U CO)*
Greg Carman (UCLA)*
Yong Chen (UCLA)*
Somnath Ghosh (Ohio St U)*
Rahmat Shoureshi (NYIT)*
Frank Ko (U Brit Columbia)*
Ben Dickinson (AFRL/RWGN)
Yakup Bayram (PaneraTech)+
John Volakis (Ohio St U)+
^ YIP; * MURI; + STTR
Distribution A: Approved for public release; distribution is unlimited
50
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
Erik Thostenson (U Del)^
Gregory Huff (Texas A&M)
Zoubeida Ounaies (Penn St U)
Michael Bevan (Johns Hopkins U)
Alexander Bogdanovich (NCSU)
Philip Bradford (NCSU)
fu-Kuo Chang (Stanford U)
Akira Todoroki (Tokyo Tech)
fu-Kuo Chang (Stanford U)*
Xian Wang (Stanford U)*
Boris Murmann (Stanford U)*
Robert McLeod (U CO)*
Greg Carman (UCLA)*
Yong Chen (UCLA)*
Somnath Ghosh (Ohio St U)*
Rahmat Shoureshi (NYIT)*
Frank Ko (U Brit Columbia)*
Ben Dickinson (AFRL/RWGN)
Yakup Bayram (PaneraTech)+
John Volakis (Ohio St U)+
^ YIP; * MURI; + STTR
Subject:
<< Nanocomposites for Sensing & Actuation
EM Tunable Fluids & Reconfigurable Antennas
Shear Pressed CNT Sheets for Strain Sensing
>> Self-Diagnostic Adhesive for Bonded Joints
Damage Detection w Time Domain Reflectometry
Bio-inspired Intelligent Sensing Materials
Embedded Sensors & Actuators for MAV
>> Load-Bearing Antennas of Conductive Textiles
>> New; << Concluded
Distribution A: Approved for public release; distribution is unlimited
51
Co-mingled Nanofibrous Films
• Entanglement of the electrospun jets in the
instability region can result in a uniformly
co-mingled film of fibers where nanotubes
are confined within individual filaments.
• Secondary-processing of co-mingled
micro/nanofiber assemblies in a dense film
results in a self-reinforced hierarchical
composite with active polymer matrix.
Breakthrough in Composites Processing
 Rapid consolidation of thermoplastics
 Greater control over morphology of nano-
reinforcement at high concentration
YIP’09 - NANOCOMPOSITES FOR
SENSING (U Del: Thostenson)
Distribution A: Approved for public release; distribution is unlimited
52
Erik T. Thostenson
0
1
2
3
4
5
6
0 0.05 0.1 0.15 0.2 0.25
EffectiveImpedanceChange
Strain (%)
-1
0
1
2
3
4
5
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0 200 400 600 800 1000 1200 1400
EffectiveImpedanceChange
Strain(%)
Time (s)
Neat CNT (0.001) - PVDF
Copper sheet
Composite
Specimen
d
w
TensileForce
TensileForce
Solder Joint(For
connectionto TDR
module)
Accomplishments:
• The electromechanical response of piezoelectric nanocomposites is established at high
frequencies utilizing a time-domain reflectometry approach.
• The integration of small quantities of carbon nanotubes impart apparent dielectrorestrictive
response and capability for non-contact strain sensing.
• High-frequency effective impedance changes are directly related to changes in dielectric
properties associated with strain
• Alteration of the percolating network can result in significant changes to the resistance-
strain behavior in films and foams of nanocomposites.
YIP’09 - NANOCOMPOSITES FOR
SENSING (U Del: Thostenson)
Distribution A: Approved for public release; distribution is unlimited
53
Stretchable Matrix
Autonomous System
Multi-Scale Design,
Synthesis & Fabrication
Sensors
(temperature,
pressure,
strain, etc)
Local neurons
(processor, memory,
communication
devices)
BUILT-IN SENSING NETWORK
(Stanford/UC/DU/UCLA: Chang et al)
MURI ‘09
Synaptic Circuits
Synapse:
Cognition and decision-making are
determined by a relative level of
cumulative signal strength with respect
to the synapse threshold values
Biological sensory systems
rely on large numbers of
sensors distributed over
large areas and are
specialized to detect and
process a large number of
stimuli. These systems are
also capable to self-organize
and are damage tolerant.
PM: B. L. Lee; Co-PM: Hugh Delong
Distribution A: Approved for public release; distribution is unlimited
54
 The 2nd generation device emulating a biological synapse, which integrates spatiotemporal logic,
memory and learning functions, has been developed by integrating CNT’s and C60-doped polymer
layer in a field-effect transistor. This novel “synapstor” offers drastically reduced power
consumption compared to Si CMOS transistors.
 A voltage pulse applied on the gate of a synaptic transistor triggers electronic charge/discharge in
the C60 molecules in the polymer to generate post-synaptic current (PSC).
 The amplitudes of the post-synaptic current can be configured to analog states quantitatively
(ranging from 10^-12 to 10^-7 A) and reversibly by modifying the charge inside the C60 molecules
with a series of gate pulses.
 Based on the extrapolations of the experimental data, the analog values could be distinguished and
preserved for years, indicating the long-term nonvolatile analog memory of the synapstor.
C60
Carbon Nanotube
++
+
─ ─
Gate Electrode
Insulator
Electrons
Holes
MURI ‘09
EMULATING BIOLOGICAL
SYNAPSE (UCLA: Chen) - Update
Distribution A: Approved for public release; distribution is unlimited
55
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
John Kieffer (U Mich)
Ioannis Chasiotis (UIUC)
Jerry Qi (U CO)
Kurt Maute (U CO)
Martin Dunn (U CO)
G. Ravichandran (Caltech)*
Jose Andrade (Caltech)*
Kaushik Bhattacharya (Caltech)*
Chiara Daraio (Caltech)*
Michael Ortiz (Caltech)*
Chris Lynch (UCLA)*
Greg Carman (UCLA)*
Naresh Thadhani (GA Tech)
Sarah Stewart (Harvard U)
John Borg (Marquette U)
* CoE
Distribution A: Approved for public release; distribution is unlimited
56
NAME: B. L. (“Les”) Lee
BRIEF DESCRIPTION OF PORTFOLIO:
Basic science for integration of emerging materials and micro-devices
into future Air Force systems requiring multi-functional design
LIST OF SUB-AREAS:
 Design of Autonomic/Self-Sustaining Systems;
 Design of Reconfigurable Systems;
Fundamentals of Mechanics of Materials;
Life Prediction (Materials & Micro-devices);
Sensing, Detection & Self-Diagnosis;
Self-Healing, Remediation & Structural Regeneration;
Self-Cooling & Thermal/Irradiation Management;
Energy Transduction & System Integration;
Actuation, Morphing & Threat Neutralization;
Engineered Bio/Nano/Info-materials
PORTFOLIO OVERVIEW
PI’s & Co-PI’s:
John Kieffer (U Mich)
Ioannis Chasiotis (UIUC)
Jerry Qi (U CO)
Kurt Maute (U CO)
Martin Dunn (U CO)
G. Ravichandran (Caltech)*
Jose Andrade (Caltech)*
Kaushik Bhattacharya (Caltech)*
Chiara Daraio (Caltech)*
Michael Ortiz (Caltech)*
Chris Lynch (UCLA)*
Greg Carman (UCLA)*
Naresh Thadhani (GA Tech)
Sarah Stewart (Harvard U)
John Borg (Marquette U)
* CoE
Subject:
<< Multi-scale Simulation of Interfacial Phenomena
<< Deformation & Fracture of Silicon for MEMS
>> 3D Printed Composites for Topology Transform
High-rate Physics of Heterogeneous Materials
Dynamic High-Pressure Behavior of Geomaterials
>> New; << Concluded
Distribution A: Approved for public release; distribution is unlimited
57
• Fundamental understanding of the
physics of heterogeneous materials
at high-strain-rates (105-107/s) and
high-pressures (1-100 GPa)
• Development of microstructures and
functional nanomaterials for
mitigating shock and damage
• Use of innovative methods for
educating and training the next
generation of scientists and
practitioners
Objectives: Achievements:
Perspectives:
• New generation of analysis, design,
simulation and experimental tools
for heterogeneous material
structures and systems of interest to
the Air Force
• Design of robust munitions systems
with novel protective systems for
structures, electronics and guidance
systems
Experimental
shock physics
Shock
mitigation
 Ferroelectric and ferromagnetic based
energy harvesting materials for shock
mitigation
 Pressure induced depolarization in 95/5
and 52/48 PZT based compositions
characterized under hydrostatic and
dynamic loading (split Hopkinson bar)
Shock energy corresponding to area to left of
the curve can be harvested for ferroelectrics
(Similar cycle for ferromagnetics)• Validated Granular Element Method
(GEM) for computing interparticle
forces in a model particulate material
Experiment GEM Simulation
• Concept of metaconcrete with
effective “negative” mass which can
potentially trap or disperse waves
generated by shock loading
• Shock physics of “model” particulate
composite (glass spheres embedded
in PMMA).
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
-0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1
ParticleVelocity[km/s]
Time [ ms ]
AFOSR/RW CoE’12 - SHOCK PHYSICS
(Caltech/UCLA: Ravichandran)
Distribution A: Approved for public release; distribution is unlimited
58
Objective:
To develop a comprehensive 3D multi-physics, multi-scale
computational analysis and simulation capability for multi-
functional composite structures.
Approaches:
1. Ubiquitous Multi-Physics Modeling incl. Transients:
Coupled transient electromagnetic (EM) and dynamic
mechanical (ME) fields
2. Temporal Multi-Scaling for Disparate Frequencies:
Electromagnetics (ultrasonic frequency) and mechanical
vibration (moderate frequency) in a unified modeling
framework
3. Spatial Multi-Scaling for Composite Media: Need to
account for microstructure-structure interaction and design,
e.g. conductors/reinforcements in antenna, conductor-
substrate in sensors, and nodes (piezoelectric sensor) and
wires (connection of nodes) in sensor network.
4. Piezoelectric Materials: Undergoing finite deformation
COUPLING EM-STRUCTURAL
DYMAMICS (JHU: Ghosh)
MURI ‘09
Time (sec)
.10 .15 .20 .25
Displacement(m)
-.02
-.01
0.00
.01
.02
ElectricField(V/m)
-4e-6
-2e-6
0
2e-6
4e-6
Displacement
Electric Field
Time (sec)
0.0 0.1 0.2 0.3 0.4
ElectricField(V/m)
-2e-6
-2e-6
-1e-6
-5e-7
0
5e-7
1e-6
1e-6
2e-6
Displacement(m)
-0.02
-0.01
0.00
0.01
0.02
Electric Field
Displacement
Distribution A: Approved for public release; distribution is unlimited
59
SUMMARY
• The program is fully focused on the multi-functional design of
advanced aerospace materials and structures.
• A major progress has been made in pursuing a new vision for
autonomic, self-sustaining and reconfigurable systems and
providing basic research support for mechanics of emerging
materials and micro-devices as its foundation.
• Multi-disciplinary research bases are successfully formed for
“self-healing,” “structurally integrated energy harvest/storage
capabilities,” “load-bearing antennas” and “morphing materials.”
• Thee initiatives are in progress for “neurological system inspired
sensory network” (MURI ’09), “high-rate deformation” (CoE’12)
and “biomolecular autonomic material systems” (BRI’12).
• New initiatives are planned for “muscular-skeletal system inspired
actuation network” and “structural regeneration and remodeling”
in collaboration with AFOSR/AFRL-TD/NSF colleagues.
Distribution A: Approved for public release; distribution is unlimited

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Les Lee - Mechanics of Multifunctional Materials and Microsystems - Spring Review 2013

  • 1. 1 Integrity  Service  Excellence Distribution A: Approved for public release; distribution is unlimited MECHANICS OF MULTIFUNCTIONAL MATERIALS & MICROSYSTEMS 7 March 2013 B. L. (“Les”) Lee, ScD AFOSR/RTD Air Force Research Laboratory
  • 2. 2 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials 2013 AFOSR SPRING REVIEW 3002B PORTFOLIO OVERVIEW Distribution A: Approved for public release; distribution is unlimited
  • 3. 3 INSPIRED BY BIOLOGY… Creating a Synthetic Autonomic System 11 AUTONOMIC RESPONSE Autonomy:Autonomy: The ability to function in an independent and automatic fashion Distribution A: Approved for public release; distribution is unlimited
  • 4. 4 INSPIRED BY BIOLOGY… Creating a Synthetic Autonomic System 11 AUTONOMIC RESPONSE Autonomy:Autonomy: The ability to function in an independent and automatic fashion 11 FUNCTIONS OF INTEREST Active Regulation Reactive Materials Mesoporous Networks Adaptive Fluids/Solids Self-Regulating Function Self-Generating Function Distribution A: Approved for public release; distribution is unlimited
  • 5. 5 Mechanization Flexible Skins Moving Beyond Swept Wing Large Scale Area Changes Showing It Can Be Done! Enablers Wind Tunnel Tests NASA 16 Ft Transonic Dynamics Tunnel Concepts A First In Aviation History MORPHING AIRCRAFT Source: AFRL/RB Adaptive Structures Distribution A: Approved for public release; distribution is unlimited
  • 6. 6 • Structural materials are made to NOT deform, • Those that deform by mechanization, add weight and complexity • Reconfiguring is easy on land, but not air, under sea, or in space • Structural materials made to deform on demand with minimized weight and complexity is a key technology. 0.0001 0.001 0.01 0.1 1 10 100 0.1 1 10 100 1000 ElasticModulus(GPa) Max. Elastic Strain (%) Bond stretching Steel Al alloy PZN-PTPZT T-D CFRP G10 SMA Epoxy Nylon 6,6 PMMA PVDF FSMA Elastomers Domain reorientation Bond & chain straightening Muscle Ferrogels Free volume flow Vitraloy PAN Polyaniline LCE IPMC Ionic Gel Structural meta Polymer – repta Active material Intercalants – fr Elastomers – ch Foams Chain unfolding Common materials cannot achieve simultaneous high stiffness and large deformation G. McKnight (HRL, Inc.) ADAPTIVE STRUCTURES: TECHNICAL CHALLENGES Distribution A: Approved for public release; distribution is unlimited
  • 7. 7 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials 2013 AFOSR SPRING REVIEW 3002B PORTFOLIO OVERVIEW Distribution A: Approved for public release; distribution is unlimited
  • 8. 8 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials 2013 AFOSR SPRING REVIEW 3002B PORTFOLIO OVERVIEW Distribution A: Approved for public release; distribution is unlimited
  • 9. 9 PROGRAM INTERACTION AFOSR Structural Mechanics Structural Materials Organic Chemistry Biosciences Microelectronics OTHERS AFRL/RV Space Vehicles AFRL/RB Air Vehicles AFRL/RW Munitions AFRL/RZ Propulsion EXTRAMURAL UNIVERSITIES INDUSTRY MECHANICS OF MULTIFUNCTIONAL MATERIALS & MICROSYSTEMS AFRL/RX Materials Army Navy DARPA NSF ESF NASA AFRL/RY Sensors Distribution A: Approved for public release; distribution is unlimited
  • 10. 10 PROGRAM INTERACTION AFOSR Structural Mechanics Structural Materials Organic Chemistry Biosciences Microelectronics OTHERS AFRL/RB Reconfigurable AFRL/RW UAV Sensors AFRL/RX Thermal Mgt AFRL/RX Vascular AFOSR MURI ‘05 Self-Healing AFOSR MURI ‘06 Energy Harvesting EXTRAMURAL UNIVERSITIES INDUSTRY MECHANICS OF MULTIFUNCTIONAL MATERIALS & MICROSYSTEMS AFRL/RX Lightening Army Navy DARPA GameChanger ‘07 Antenna Integration NSF ESF NASA AFRL/RX Composites
  • 11. 11 PROGRAM INTERACTION AFOSR Structural Mechanics Structural Materials Organic Chemistry Biosciences Microelectronics OTHERS AFRL/RB Reconfigurable AFRL/RW UAV Sensors AFRL/RX Thermal Mgt AFRL/RX Active Polymer EXTRAMURAL UNIVERSITIES INDUSTRY MECHANICS OF MULTIFUNCTIONAL MATERIALS & MICROSYSTEMS AFRL/RX Irradiation Army Navy DARPA Discovery CT ‘09 Reconfigurable AFOSR MURI ’09 Sensory Network Director’s Call ’09 Energy from Environ NSF ESF NASA AFRL/RX Structrl Battery AFOSR/RW CoE ’12 High-Rate Physics AFOSR BRI ‘12 Biomolecules Distribution A: Approved for public release; distribution is unlimited
  • 12. 12 • Self-healable or in-situ remendable structural materials (1st-ever program; world lead) • Microvascular composites for continuous self-healing and self-cooling systems (1st-ever program; world lead) • Structural integration of energy harvest/storage capabilities (1st-ever program on harvest capabilities; DoD lead) • Neurological system-inspired sensing/diagnosis/ actuation network (pot’l world lead) • Biomolecules for sensing and actuation (pot’l world lead) • Mechanized material systems and micro-devices for reconfigurable structures (DoD lead) • Experimental nano-mechanics (DoD lead) Scientific Challenges & Program Achievement Distribution A: Approved for public release; distribution is unlimited
  • 13. 13 Transformational Opportunities • Self-healable or in-situ remendable structural materials – Quantum improvement in survivability of aerospace structures • Microvascular composites for continuous self-healing and self-cooling systems – Quantum improvement in survivability of aerospace structures & thermal management • Structural integration of energy harvest/storage capabilities – Self-sustaining UAV and hybrid-powered aircraft • Neurological system-inspired sensing/diagnosis/ actuation network – Autonomic state awareness in aerospace • Mechanized material systems and micro-devices for reconfigurable structures – Morphing wing aircraft & Neutralization of penetration threats Distribution A: Approved for public release; distribution is unlimited
  • 14. 14 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO TRENDS Distribution A: Approved for public release; distribution is unlimited
  • 15. 15 donleo@vt.edu Traditional Transducer Materials Transduction Mechanism Material Device/ System Material Transformation Dipole Rotation Ion Migration Shape Memory Alloy Piezoelectric Ceramics and Polymers Ionomeric Polymer Materials Increasinglengthscale ENGINEERED DEVICES: BEYOND CURRENT VISION Distribution A: Approved for public release; distribution is unlimited
  • 16. 16 donleo@vt.edu Traditional Transducer Materials Transduction Mechanism Material Device/ System Material Transformation Dipole Rotation Ion Migration Shape Memory Alloy Piezoelectric Ceramics and Polymers Ionomeric Polymer Materials Increasinglengthscale donleo@vt.edu The question we are studying … How can we use biomolecules to make completely new types of materials for engineered devices? Transduction Mechanism Material Device/ System Channels, Pumps, Transporters Durable, Robust, Easy to Manufacture Sensors, Energy Capture and Conversion, Color Changes Increasinglengthscale ENGINEERED DEVICES: BEYOND CURRENT VISION Distribution A: Approved for public release; distribution is unlimited
  • 17. 17 Structure of the mechanically-activated channel MscL (top left), the voltage- gated channel alamethicin (top right), and the light-activated channel bacteriorhodopsin (bottom). Gating response of the voltage-gated channel alamethicin to an applied potential. Over 3.5 billion years of evolution, nature has produced a highly diversified set of biomolecular transducers that exhibit a wide range of transduction properties. In the past two decades humans have been able controllably modify these transduction properties and incorporate them into durable material systems. A biomolecular unit cell utilizes the stimuli-responsive properties of biomolecules as a means of creating new transducer materials. How can we utilize the stimuli-responsive properties of biomolecules to create a new class of transducer system? Co-PM’s: B. L. Lee, Hugh Delong BRI’12 - BIOMOLECULES FOR SENSING (VT/U TN/U MD/UIUC: Leo) Distribution A: Approved for public release; distribution is unlimited
  • 18. 18 Design by Nature: BONE REMODELING Resorption vs Ossification; 4~20% renewal per year; Subjecting a bone to stress will make it stronger Fig. 6-4a Anatomy and Physiology: From Science to Life © 2006 John Wiley & Sons US-Europe Workshop on Structural Regeneration (27-28 June 2012, Venice) Co-organized by AFOSR, ARO, U Illinois & Max Planck Inst. Distribution A: Approved for public release; distribution is unlimited
  • 19. 19 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) Transition from: Active Materials for Adaptive Structures Distribution A: Approved for public release; distribution is unlimited
  • 20. 20 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) Transition from: Active Materials for Adaptive Structures Distribution A: Approved for public release; distribution is unlimited
  • 21. 21 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) 48 • To design better actuators/morphing devices using shape memory alloy honeycomb which combines benefits of cellular structures and monolithic SMA’s Objectives: • After non-uniformity due to structural level instabilities at moderate strains, the deformation pattern becomes uniform again upon further straining . • This morphing behavior reverses under unloading. CELLULAR SHAPE MEMORY STRUCTURES (U Mich: Triantafylli) 47  Forest-drawn carbon nanotube sheets have higher specific strength than steel.  Charge injection of carbon nanotube sheets produces giant width-direction actuation (>3.3 X) from 80 to 1900 K.  Sheets CONTRACT in nanotube direction by up to 2% during actuation.  Generated stress is 32 times the stress generation capability of natural muscle. Motor Nanotube Forest Mandrel Meterlongcarbonnanotubesheet Forest Sheet (right) being spun from nanotube forest (left) Side view of above sheet spinning from forest 300 K, 0 kV 300 K, 5 kV 1500 K, 5 kV NANOTUBE ARTIFICIAL MUSCLE (U Texas Dallas: Baughman) 57 Commonly Used Shape Memory Polymers (SMP)  One-way shape memory (SM) effects  Not being able to recover the temporary shape  No design tools available Two-way Shape Memory Polymers  Two-way SM effects using switching between two stable states  No two-way SM due to intrinsic material property change Two-way SMPs Applications  Require combinatorialmethods for material synthesis, modeling, and design. Two-Way SMP by the Concept of Opposing Microstructural-Scale Spring  Two opposing spring can generate motions if one or both of them can change properties as temperature changes  Opposing spring can be realized through material/structure design at micro-scale. MAIN ACHIEVEMENTS:  Demonstrate two-way shape memory effects assisted by external force.  Fabricate reversible free-standingtwo-way shape memory polymer composites. HOW IT WORKS:  Stretched induced crystallization (SIC) can relax the stress  Opposing microstructural-scalespring creates reversible free-standingtwo-way SMP  Shape memory effect is fully reversible. Current Impact  First free-standing two-way SMP based on intrinsic materialproperty change  Large reversible actuation strain Planned Impact  Two-way SMPs for multifunctional structural  Design tools that enhance robust design  Novel applicationsbased on two- way SMP Research Goals  Complete understanding of material behaviors  Design tools for novel applications of these materials  Explore other polymer-based shape memory materials  Explore applications with AFRL STATUSQUO END-OF-PHASEGOALQUANTITATIVEIMPACT NEWINSIGHTS Proposed applications:a) Rotational actuation in shear to enable autonomous rotation for mirror motion, wing joints. b) Reversible blistering of two-way SMPs for variable boundary layer aircraftcontrol surfaces. Ki Ks(T)Ki Ks(T) The spring on the left has a constant stiffness Ki and the stiffness of right spring Ks depends on the temperature. SMP in shearStator Rotor Reversible Torsion Via SMP Shear to mirror(a) (b) SMP in shearStator Rotor Reversible Torsion Via SMP Shear to mirror SMP in shearStator Rotor Reversible Torsion Via SMP Shear to mirror(a) (b) Two-way shape memory effect assisted by an external force 2W-SMP 2W-SMP is stretched at high T, then cooled to low T 2W-SMP is laid on top of the polymer A polymer layer is photo- synthesized on top. 0mn 1min 2min 3min 4min 5min 6min 7min Heating Cooling REVERSIBLE SHAPE MEMORY (Syracuse U / U CO: Mather) 59 • Developed model to describe BZ gels with chemo-responsive X-links – Modified Oregonator model – f – dependent complex formation – Time-dependent elastic contribution • Studied response to steady and periodic compression in 1D model • Mechanical impact increases X-link density – Self-reinforcing material – Stiffens in response to impact V.V. Yashin, O. Kuksenok, A.C. Balazs, J. Phys. Chem. B 2010, 114(19), 6316. + Oxidation Reduction PP 0.511 0.926 c/c 0 DESIGNING SELF-REINFORCING MATERIALS (U Pitt: Balazs) x / L0 45 kPa c/c 0 Transition from: Active Materials for Adaptive Structures Distribution A: Approved for public release; distribution is unlimited
  • 22. 22 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) 27 1st Bird-like Morphing UAV (TU Delft-led team):  Design of a morphing wing with feathers inspired by birds.  A servo sweeps the first feather back and forth with a pushrod. The other feathers are connected with a parallel mechanism to the first feather and follow.  The 50cm long wing is built of super-thin light-weight carbon fiber composites with the plane weight of 100 gram.  Successfully flew in an impressive wind force 5-6. BIRD-LIKE MORPHING WING Courtesy of D. Lentink (Stanford U) Transition to: Multifunctional Design of Morphing Air Vehicles Distribution A: Approved for public release; distribution is unlimited
  • 23. 23 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) 27 1st Bird-like Morphing UAV (TU Delft-led team):  Design of a morphing wing with feathers inspired by birds.  A servo sweeps the first feather back and forth with a pushrod. The other feathers are connected with a parallel mechanism to the first feather and follow.  The 50cm long wing is built of super-thin light-weight carbon fiber composites with the plane weight of 100 gram.  Successfully flew in an impressive wind force 5-6. BIRD-LIKE MORPHING WING Courtesy of D. Lentink (Stanford U) Transition to: Multifunctional Design of Morphing Air Vehicles New Focus: Morphing air vehicles capable of altering the geometry, surface area and mechanical properties of wing structures Mimicking “muscular-skeletal” system of bird wings Deploying mechanized active materials and computational metamaterials for structural reconfiguration. Objective: To achieve multifunctional design of morphing air vehicle as an autonomic system (in collaboration with the expertise in biomimetics, dynamics and control) Distribution A: Approved for public release; distribution is unlimited
  • 24. 24 PROGRAM COLLABORATION THE 2ND “MULTIFUNCTIONAL MATERIALS FOR DEFENSE” WORKSHOP Theme: Sensing, Actuation & Energy Transduction In conjunction with: The 2012 Annual Grantees’/Contractors’ Meeting for AFOSR Program on “Mechanics of Multifunctional Materials & Microsystems" 30 July-1 August 2012 Hilton Arlington Hotel, Arlington, VA Workshop Co-Chairs: Gregory Reich (AFRL/RBSA) William Nothwang (ARL/SEDD) James Thomas (NRL) Organizing Committee: B.-L. (“Les”) Lee (AFOSR), Co-Chair David Stepp (ARO), Co-Chair Ignacio Perez de Leon (ONR), Co-Chair William Baron (AFRL/RBSA) Jeff Baur (AFRL/RXBC) Mark Derriso (AFRL/RBSI) Gregory Reich (AFRL/RBSA) William Nothwang (ARL/SEDD) Daniel O’Brien (ARL/WMRD) James Thomas (NRL) Agent for 8 Projects; Concluded Proposed for AFOSR-NSF Collaboration: “Muscular-Skeletal System Inspired Reconfigurable Materials Design”; “Structural Regeneration & Remodeling” Pot’l MURI or BRI BioSensing and BioActuation Proposed Research Opportunities/Challenges 1. Hierarchical Organization of Biological Systems Uncover the unifying aspects underlying hierarchical bio-structures and bio-systems and use them for sensing and actuation; apply to new multi-scale and multi-functional sensor/actuator concepts. 2. Sensor Informatics Guided by Life Create new knowledge that will be exploited in novel bio-inspired data mining and dynamic control, including capabilities to monitor, assess, and control living and engineered systems in sensor-rich environments. 3. Multifunctional Materials and Devices for Distributed Actuation and Sensing Understand biological systems and mechanisms that lead to their ability to exhibit fault-tolerant actuation with a wide dynamic range, the production of practical means for producing artificial structures that exhibit similar behaviors, and their incorporation into useful engineered systems. 4. Forward Engineering & Design of Biological/Biomedical Components & Systems Synthesize hybrid synthetic-living systems through systems-level integration of biological and engineered components that sense, actuate, compute, regenerate and efficiently allocate resources in order to achieve desired responses and functions. Design of Engineering Materials Systems (DEMS) Martin L. Dunn, Mary Toney, Clark Cooper, Grace Hsuan, Christina Bloebaum Program Directors Distribution A: Approved for public release; distribution is unlimited
  • 25. 25 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW Distribution A: Approved for public release; distribution is unlimited
  • 26. 26 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Tsu-Wei Chou (U Del) Yuntian Zhu (NCSU) Ioannis Chasiotis (UIUC) Liping Liu (Rutgers U)^ David Kisailus (UC Riverside)* Pablo Zavattieri (Purdue U) Don Leo (VA Tech)# S. Andrew Sarles (U TN) Sergei Sukharev (U MD) Narayan Aluru (UIUC) ^ YIP; * HBCU/MI; # BRI Distribution A: Approved for public release; distribution is unlimited
  • 27. 27 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Tsu-Wei Chou (U Del) Yuntian Zhu (NCSU) Ioannis Chasiotis (UIUC) Liping Liu (Rutgers U)^ David Kisailus (UC Riverside)* Pablo Zavattieri (Purdue U) Don Leo (VA Tech)# S. Andrew Sarles (U TN) Sergei Sukharev (U MD) Narayan Aluru (UIUC) ^ YIP; * HBCU/MI; # BRI Subject: Thin Flexible CNT Composites >> Compliant Nano-spring Interfaces Designing Structures for Functional Materials Damage-tolerant Biological Composites >> Biomolecular Materials for Sensing & Actuation >> New Distribution A: Approved for public release; distribution is unlimited
  • 28. 28 Radular Teeth of Chiton (elongated mollusk):  Ribbon-like structure covered with small dentacles for tearing food into pieces  Composed of an nanocrystalline iron phosphate core with a magnetite veneer edge  The deposited mineral phase is ultra hard and abrasion resistant and 4-fold modulus difference at core-veneer interface effectively deflects crack propagation DAMAGE TOLERANT BIOLOGICAL COMPOSITES (UCR: Kisailus) Chiton Distribution A: Approved for public release; distribution is unlimited
  • 29. 29 DAMAGE TOLERANT BIOLOGICAL COMPOSITES (Purdue U: Zavattieri) (a) Micromechanical model of rod like structure of radular tooth, including a potential RVE. (b) Hierarchical model to connect nano- to microscale. (c) Hierarchical model to connect the microscale to macroscopic fracture tests. Relevance: Bio-inspired design of gears or abrasion-resistant materials (c) Distribution A: Approved for public release; distribution is unlimited
  • 30. 30 Synthesis and Fabrication of Multi-Cellular Arrays:  Autonomic, multifunctional behavior can only be achieved by incorporating large numbers of stimuli-responsive “cells” into the material.  The program will establish in-depth understanding of the methods required for synthesizing and fabricating multicellular material systems with characteristic length scales less than 100 microns and functional densities that approach those of natural systems. GOALSACCOMPLISHMENTSNEXTSTEPS Fabricated a four-cell material system with a characteristic length scale on the order of 100s of microns. Measured voltage-gated channel activity across multiple interfaces in this four-cell material. Begin the development of injection and printing methodologies for multi-cell arrays. BRI’12 - BIOMOLECULES FOR SENSING (VT/U TN/U MD/UIUC: Leo) Distribution A: Approved for public release; distribution is unlimited
  • 31. 31 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Patrick Mather (Syracuse U) H. Jerry Qi (U CO) Martin Dunn (U CO) Shiv Joshi (NextGen) Sharon Swartz (Brown U) Nakhiah Goulbourne (VA Tech) Minoru Taya (U WA) Frank Ko (U Brit Columbia) Nicolaus Correll (U CO) Ray Baughman (U Texas Dallas) A. John Hart (U Mich)^ Aaron Dollar (Yale U)^ Xin Zhang (Boston U) C. T. Sun (Purdue U) Olivier Mondain-Monval (CNRS) Thomas Siegmund (Purdue U) Anna Balazs (U Pitt) Nicole Zacharia (Texas A&M) Richard Vaia (AFRL/RXBN) Greg Reich (AFRL/RBSA) ^ YIP Distribution A: Approved for public release; distribution is unlimited
  • 32. 32 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Patrick Mather (Syracuse U) H. Jerry Qi (U CO) Martin Dunn (U CO) Shiv Joshi (NextGen) Sharon Swartz (Brown U) Nakhiah Goulbourne (VA Tech) Minoru Taya (U WA) Frank Ko (U Brit Columbia) Nicolaus Correll (U CO) Ray Baughman (U Texas Dallas) A. John Hart (U Mich)^ Aaron Dollar (Yale U)^ Xin Zhang (Boston U) C. T. Sun (Purdue U) Olivier Mondain-Monval (CNRS) Thomas Siegmund (Purdue U) Anna Balazs (U Pitt) Nicole Zacharia (Texas A&M) Richard Vaia (AFRL/RXBN) Greg Reich (AFRL/RBSA) ^ YIP Subject: << Reversible Shape Memory Polymer Composites << Ultra-Maneuverable Bat Technologies << Bio-inspired Reconfigurable Structures Self-Assembly and Self-Repair of Structures Artificial Muscles for Large Stroke & High Force Morphing CNT Microstructures Active Cells for Multifunctional Structures Metamaterial Enhanced MEMS Acoustic Metamaterials w Local Resonance Ultrasonic Tunable Ultra-Damping Metamaterials Macroscale Meta-Materials Active Materials w Sensory & Adaptive Capabilities Mechano-Responsive Polymer Systems >> Mechanically-Adaptive Materials Thermally-Activated Reconfigurable Systems >> New; << Concluded Distribution A: Approved for public release; distribution is unlimited
  • 33. 33  effE ω0: local resonance frequency Effective stress-strain relations Effective Young’s modulus• A model is formulated for acoustic metamaterials with locally resonant microstructures. • Under sinusoidal loading the stress-strain relation depends on the frequency. • Near the local resonance frequency ω0 of the side masses, the effective modulus is extremely large. • The effective Young’s modulus becomes negative in a certain frequency range. • Wave amplitude decays when its frequency falls inside this band gap, especially if the frequency is near the frequency ω* . • At the lower bound frequency of the band gap ω*, the effective modulus approaches zero. Negative Modulus METAMATERIALS WITH NEGATIVE MODULUS (Purdue U: Sun) Distribution A: Approved for public release; distribution is unlimited
  • 34. 34 Experimental Setup • Piezoelectric actuator patches were used for generating in-plane and out-of-plane waves • Piezoelectric sensor patch was used for wave reception. Actuator Sensor Direction of Wave Propagation Result • Significant attenuation of wave amplitude after passing through the metamaterial. • Band gap regions of experimental results agree with that of the theoretical prediction (shaded regions). Input of In-plane PulseOutput of In-plane Pulse Output of Out-of-plane Pulse Input of Out-of-plane Pulse Goals • Develop acoustic metamaterials for mitigating dynamic/impulsive loads • Utilize the unusual wave propagation behavior of acoustic metamaterials in signal transmission, vibration isolation, and wave mode switching. METAMATERIALS WITH NEGATIVE MODULUS (Purdue U: Sun) Acoustic Metamaterial Distribution A: Approved for public release; distribution is unlimited
  • 35. 35 CURRENTSTATENEWINSIGHTS QUANTITATIVEIMPACTEND-OF-PHASEGOAL MAIN ACHIEVEMENTS (Cont’d): Current Impact Inertial Measurement (IM) • Acceleration and angular velocities recorded for straight and obstructed flights • Dorsal mount miniature wireless IM Unit (IMU) Mechanical Characterization of Bat Membrane • Strain experiments • Constitutive modeling -Fiber bundle dist. -Fiber bundle comp. -Base matrix corrugation • Result satisfy material anisotropy property MAIN ACHIEVEMENTS: Skeletal Assembly • Bones assembled in CAD • CAD model guides mechanical design Robotic Wing • 4 DOF • High flapping frequency Data Smoothing, Motion Trajectory • Motion capture data improved • Motion trajectory defined for humerus and radius • High-fidelity models for components and integrated structure representative of a bat-wing • Quantitative evaluation of flight performance, energy consumption / efficiency • Estimates of weight, volume and geometry of a robotic bat-wing • Guidelines to develop an autonomous, hovering, highly maneuverable, bat-like MAV • Reconfigurable hovering ultra-maneuerable bat technologies (RHUMBAT) offers potential benefits in operational robustness. • Most research has focused on recreating three degrees of freedom (DOF’s) assoc with this motion: flap, lag, and feather • Small vehicle size and low inertia make fine-scale control required for envisioned missions difficult. • New unique approach considers actuators that are distributed across the structure. • Provides detailed analysis for selection of actuation DOF using motion capture and revealing complex morphologies of joints. • Wing membrane characterization shows thickness inhomogeneities to be considered in materials selection. • In depth understanding of bat skeletal structure and skeletal dynamics during flight • Materials analysis for structural & aerodynamic surfaces • Translation of bat dynamics to robotic system Biological Experiments • Examined wing fiber under polarized light • Guides constitutive model development IMU Right wing assembly Preliminary design Wing fibers Improved suturing and biaxial setup Simulated Stress-Strain CurveBiaxial loading Strain analysis BAT-INSPIRED MORPHING WING (NextGen/Brown U/VPI: Joshi)
  • 36. 36 • Reconfiguration planning for smart structures with embedded sensing, computation and actuation • Take into account physical constraints including gravity, wind and vibration • Enabling materials with the ability to self-reconfigure and self-repair Objectives: Achievements: Reconfiguration planning • Initial focus: robotic assembly under gravity constraints • Discrete/Continuous search framework combining graph-based search, FEA and full-physics simulation Platform development • Begun development of light-weight in-air self-assembly test-bed • Begun development of manipulation test-bed • Begun development of variable stiffness material Perspectives: • Novel structural components that can change their shape, function and appearance • Reconfigurable materials to change function taking into account and in response to physical constraints Flying/self-mobility External actuation In-material sensing, computation and actuation Approach: • Combination of finite element analysis and real-time physics simulation with discrete search to find suitable reconfiguration paths. • Embedding of intelligence for sensing and control of internal/external actuators Light-weight in-air module; robotic assembly; variable stiffness material with embedded sensing/actuation 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 1 2 3 457 6 8 Assembly graph of a T-structure (left), full-physics simulation (right) Smart Structures SELF-ASSEMBLY & SELF-REPAIR (U CO: Correll) Distribution A: Approved for public release; distribution is unlimited
  • 37. 37 43 Capability/Payoff Objective Programs Involved Approach To establish new “morphing” aerospace structures capable of altering their shape, functionality and mechanical properties for real-time optimization in response to the changes in environments or operating conditions • Develop new concepts for structural reconfiguration, energy transduction mechanisms and system integration allowing the combination of UAV and space-deployable systems. • Indentify new adaptive materials, mechanized material systems and micro-devices for sensing, communication or actuation. • Model the influences of morphology, dimensionality and topography on the multifunctional performance and manufacturability. • Reduce weight/size and increase the system efficiency by incorporating multi-functionality into load-bearing structures • Allow mission-specific and real-time optimization of multi- functional performance of military systems • Potential systems to be impacted are: unmanned aerial vehicles (UAV), sensor platforms, dash/loiter theatre dominance platforms, space deployable systems, etc. DCT’09: SUPER-CONFIGURABLE MULTIFUNCTIONAL STRUCTURES Mechanics of Multifunctional Materials & Microsystems; Structural Mechanics; Polymer Composites; High Temperature Materials Workshops: (a) AFRL-wide Brainstorming Discussion (Arlington, VA, 26 February 2007) (b) 6th AFOSR Workshop on “Multifunctional Aerospace Materials & Structures: Manufacturing Issues” (Seattle, WA, 18-19 September 2007) (c) AFOSR/NSF/ESF Workshop on "Adaptive Structures and Materials” (St. Maximin, France, 4-7 November 2007) (d) AFOSR/ARO/DARPA Workshop on "Bio-inspired Networks” (Boston, MA, 29-30 November 2007) (e) AFRL-wide Round Table Discussion on DCT Topic (Eglin AFB, FL, 28 January 2008) 27 1st Bird-like Morphing UAV (TU Delft-led team):  Design of a morphing wing with feathers inspired by birds.  A servo sweeps the first feather back and forth with a pushrod. The other feathers are connected with a parallel mechanism to the first feather and follow.  The 50cm long wing is built of super-thin light-weight carbon fiber composites with the plane weight of 100 gram.  Successfully flew in an impressive wind force 5-6. BIRD-LIKE MORPHING WING Courtesy of D. Lentink (Stanford U) Transition to: Multifunctional Design of Morphing Air Vehicles New Focus: Morphing air vehicles capable of altering the geometry, surface area and mechanical properties of wing structures Mimicking “muscular-skeletal” system of bird wings Deploying mechanized active materials and computational metamaterials for structural reconfiguration. Objective: To achieve multifunctional design of morphing air vehicle as an autonomic system (in collaboration with the expertise in biomimetics, dynamics and control) Distribution A: Approved for public release; distribution is unlimited
  • 38. 38 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Sven Bilén (Penn St U) Michael Strano (MIT) Max Shtein (U Mich) # Henry Sodano (U FL) Dan Inman (VA Tech) Greg Carman (UCLA) Wonbong Choi (FL Int’l U) Ioannis Chasiotis (UIUC) Hugh Bruck (U MD) Gleb Yushin (GA Tech)^ Carmel Majidi (Carnegie-Mellon)^ Michael Durstock (AFRL/RXBN) Benji Maruyama (AFRL/RXBN) John Coggin (Prime Photonics)+ Shashank Priya (VA Tech)+ ^ YIP; # PECASE; + STTR Distribution A: Approved for public release; distribution is unlimited
  • 39. 39 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Sven Bilén (Penn St U) Michael Strano (MIT) Max Shtein (U Mich) # Henry Sodano (U FL) Dan Inman (VA Tech) Greg Carman (UCLA) Wonbong Choi (FL Int’l U) Ioannis Chasiotis (UIUC) Hugh Bruck (U MD) Gleb Yushin (GA Tech)^ Carmel Majidi (Carnegie-Mellon)^ Michael Durstock (AFRL/RXBN) Benji Maruyama (AFRL/RXBN) John Coggin (Prime Photonics)+ Shashank Priya (VA Tech)+ ^ YIP; # PECASE; + STTR Subject: << Energy Harvesting via Electrodynamic Tethers Environmental Hydrocarbon Harvesting via CNT Energy Harvesting Textile Composites Active Structural Fibers for Multif’l Composites Vibration Suppression and Energy Harvesting Nanoscale Based Thermal Energy Harvesting Flexible Battery of Graphene-CNT Hybrid Integrity of Energy Harvest/Storage Materials Integrated Solar Cells for MAV Wings >> << Electrodes for Multifunctional Li-ion Battery >> Energy Harvesting for Soft-Matter Machines Nanomaterials for Structural Batteries Hybrid Energy Harvesting Systems >> New; << Concluded Distribution A: Approved for public release; distribution is unlimited
  • 40. 40 Film of nanosprings fabricated by glancing angle deposition (GLAD). Solid cap layer Cu nanosprings Metal or ceramic substrate Fragmentation of a 2-µm thick ZnO/Si solar cell bonded on (±45°)4 laminate loaded according to the arrows. The vertically parallel strips are ZnO/Si film fragments. Challenges for Integration of Solar Cells & Batteries into Load-Bearing Composite Structures:  Materials degradation of thin film solar cells and batteries during curing of the composite materials.  Thermal mismatch between thin films and the underlying structure generate high strains. As a result, the integrated structure could suffer wavy blister type delamination and fragmentation failure.  Prior efforts to integrate thin film solar cells with CFRPs pointed out 0.3% and 1% critical strains for performance reduction and fragmentation failure respectively.  Micron- or nano-scale springs of metallic or ceramic thin films benefit from size effects to provide compliant, yet strong and tough, multifunctional interface (A new grant initiated) .  High capacity battery electrodes are prone to cracking under stress upon lithiation. STRUCTURAL INTEGRITY OF ENERGY DEVICES (UIUC: Chasiotis) Distribution A: Approved for public release; distribution is unlimited
  • 41. 41 Traditional Electrodes & Cell Architecture • Low electrical conductivity • Low thermal conductivity • Heavy/bulky metal foils • No mechanical strength Uncoated portion of CNT fabric serves as a current collector Strong and flexible Mg- or Si- coated CNT fabric as an anode; Cannot be replaced with uncoated CNT due to mechanical degradation induced by Li 15-50 µm Anode 15-50 µm Cathode Active coating Multifunctional Nanocomposite Fabric for Electrodes & Current Collector • Ultra-high electrical conductivity • High thermal conductivity • No metal foil current collectors needed • High mechanical strength • Enhanced safety (with solid electrolyte) solid electrolyte LiV2O5 coated CNT fabric as a cathode Cu current collector; Graphite anode with PVDF binder; LiMOx cathode (M: Co, Mn, Ni) YIP’09 - LOAD BEARING BATTERIES (GA Tech: Yushin) Distribution A: Approved for public release; distribution is unlimited
  • 42. 42 20 40 60 80 100 0 50 100 150 200 250 300 350 400 450 500 550 600 Regular Graphite-PVDF Anode on Cu foil LiExtractionCapacity(mAh/g) Cycle Index Multifunctional Si-on-CNT Fabric Anode (54% Si) (limited Li insertion to avoid Li insertion into CNT) Regular Graphite Anode Si-coated CNT Fabric Anode 1 mm 40 mm 25 50 75 100 125 150 StructuralsteelA36 CastironASTM40 Ti99.5% Alalloy713 Alalloy514 Brass Cu99.5% CastironASTM20 SpecificStrength/kNmkg -1 Alalloy443 Si-CNT fabric YIP’09 - LOAD BEARING BATTERIES (GA Tech: Yushin) Distribution A: Approved for public release; distribution is unlimited
  • 43. 43 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Alma Hodzic (U Sheffield) Tom Darlington (Nanocomposix)+ Tony Starr (SensorMetrix)+ Tom Hahn (UCLA)+ Nancy Sottos (UIUC) Scott White (UIUC) Jeffrey Moore (UIUC) Jimmy Xu (Brown U) Ajit Roy (AFRL/RXBT) Abraham Stroock (Cornell U) Noel Holbrook (Harvard U) Patrick Kwon (Mich St U) George Lesieutre (Penn St U) Mary Frecker(Penn St U) James Adair(Penn St U) Assimina Pelegri (Rutgers U) Aaron Esser-Kahn (UC Irvine)^ Jim Thomas (NRL) Jeff Baur (AFRL/RXBC) Ajit Roy (AFRL/RXBT) ^ YIP; + STTR Distribution A: Approved for public release; distribution is unlimited
  • 44. 44 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Alma Hodzic (U Sheffield) Tom Darlington (Nanocomposix)+ Tony Starr (SensorMetrix)+ Tom Hahn (UCLA)+ Nancy Sottos (UIUC) Scott White (UIUC) Jeffrey Moore (UIUC) Jimmy Xu (Brown U) Ajit Roy (AFRL/RXBT) Abraham Stroock (Cornell U) Noel Holbrook (Harvard U) Patrick Kwon (Mich St U) George Lesieutre (Penn St U) Mary Frecker(Penn St U) James Adair(Penn St U) Assimina Pelegri (Rutgers U) Aaron Esser-Kahn (UC Irvine)^ Jim Thomas (NRL) Jeff Baur (AFRL/RXBC) Ajit Roy (AFRL/RXBT) ^ YIP; + STTR Subject: << Inkjet-Assisted Creation of Self-Healing Layers << Remendable Composites w Resistive Heating << Interfacial Self-Healing in Composites Regeneration & Remodeling of Composites << Thermal Signature Reduction & EMI Shielding << Carbon Fiber Morphology for Thermal Materials Plant-mimetic Heat Pipes New Generation of Perspirable Skin Variable Thermal Conductivity Structures Graphene Composites for Lightning Protection Microvascular Systems for Mass/Energy Transport >> Multifunctional Poro-Vascular Composites >> Composites under High Energy Irradiation >> New; << Concluded Distribution A: Approved for public release; distribution is unlimited
  • 45. 45 10 um h = thealed tvirgin = Ph Pv = 100%  Full recovery of interfacial adhesion is observed for glass fibers with the capsules of EPA solvent + EPON 862 resin outperforming DCPD/Grubbs system. Functionalized glass fiber EPA solvent + EPON 862 resin healing chemistry 200 nm TEM image of nanocapsules Single fiber microbond test INTERFACIAL SELF-HEALING IN COMPOSITES (UIUC: Sottos) Distribution A: Approved for public release; distribution is unlimited
  • 46. 46  Successfully processed the 1st self-healing prepreg in continuous production mode SEM image of E-glass fiber tow (200 count) with 3.3 μm diameter PU/UF microcapsules Fiber tow Sized fiber Dried fiber 0◦ : 1ply 90◦ : 10 plies [0/905 ]s 0◦ : 1ply  Cross-ply laminates of self-healing composite with well dispersed microcapsules were fabricated from prepreg. E-glass fiber/epoxy resin Matrix: EPON862/EPIKURE3274 Microcapsules Core: 97:3 EPA(solvent)/EPON862 Shell: Polyurethane/polyUF shell INTERFACIAL SELF-HEALING IN COMPOSITES (UIUC: Sottos) Proposed: STTR (incl. Phase III) program covering multidisciplinary research on “self-healing composites” and involving the academia, AFRL and industry Distribution A: Approved for public release; distribution is unlimited
  • 47. 47 STRUCTURAL REMODELING (UIUC: White/Moore) - Update Regeneration in Nature: Tree skink lizard Linckia starfish Human bone Approach: Dynamic Polymers + Inert Scaffolds Accomplishments: • Synthesis of dynamic polymers which undergo stimuli- responsive (de)polymerization via reversible covalent bonds (i.e. liquid to solid and vice versa). • Systematic study of structure-property relationships for dynamic polymers based on ionic bonds that are generally stronger and widely used in biological systems such as sacrificial bonds and proteins. • A new class of material called ionic molecular glass which form a rigid network of ionic bonds below Tg . • Developed novel bi-stage chemistry for regeneration allowing independent temporal control of sol-gel and gel-polymer transitions Sol Gel Polymer Distribution A: Approved for public release; distribution is unlimited
  • 48. 48 Phase Changing Polymer - Poly(N-isopropylacrylamide) (PNIPAM)  When heated in water above Lower Critical Solution Temperature (LCST) of ~32oC, it undergoes a reversible phase transition from a swollen hydrated state to a shrunken dehydrated state, losing ~90% of volume.  Melting point depends on molecular weight: 96oC for molecular weight of 20,000.  Signature of polymer phase-change is still seen at ~32oC with high heating rate for CNT reinforced composites with PNIPAM matrices. CNT-PNIPAM composite LCST Proposed: Synthetic skin for self-regulated cooling (‘sweating’) leading to thermal signature reduction SELF-COOLING COMPOSITES (Brown U: Xu) Porous Al2O3 Membrane Distribution A: Approved for public release; distribution is unlimited
  • 49. 49 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Erik Thostenson (U Del)^ Gregory Huff (Texas A&M) Zoubeida Ounaies (Penn St U) Michael Bevan (Johns Hopkins U) Alexander Bogdanovich (NCSU) Philip Bradford (NCSU) fu-Kuo Chang (Stanford U) Akira Todoroki (Tokyo Tech) fu-Kuo Chang (Stanford U)* Xian Wang (Stanford U)* Boris Murmann (Stanford U)* Robert McLeod (U CO)* Greg Carman (UCLA)* Yong Chen (UCLA)* Somnath Ghosh (Ohio St U)* Rahmat Shoureshi (NYIT)* Frank Ko (U Brit Columbia)* Ben Dickinson (AFRL/RWGN) Yakup Bayram (PaneraTech)+ John Volakis (Ohio St U)+ ^ YIP; * MURI; + STTR Distribution A: Approved for public release; distribution is unlimited
  • 50. 50 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: Erik Thostenson (U Del)^ Gregory Huff (Texas A&M) Zoubeida Ounaies (Penn St U) Michael Bevan (Johns Hopkins U) Alexander Bogdanovich (NCSU) Philip Bradford (NCSU) fu-Kuo Chang (Stanford U) Akira Todoroki (Tokyo Tech) fu-Kuo Chang (Stanford U)* Xian Wang (Stanford U)* Boris Murmann (Stanford U)* Robert McLeod (U CO)* Greg Carman (UCLA)* Yong Chen (UCLA)* Somnath Ghosh (Ohio St U)* Rahmat Shoureshi (NYIT)* Frank Ko (U Brit Columbia)* Ben Dickinson (AFRL/RWGN) Yakup Bayram (PaneraTech)+ John Volakis (Ohio St U)+ ^ YIP; * MURI; + STTR Subject: << Nanocomposites for Sensing & Actuation EM Tunable Fluids & Reconfigurable Antennas Shear Pressed CNT Sheets for Strain Sensing >> Self-Diagnostic Adhesive for Bonded Joints Damage Detection w Time Domain Reflectometry Bio-inspired Intelligent Sensing Materials Embedded Sensors & Actuators for MAV >> Load-Bearing Antennas of Conductive Textiles >> New; << Concluded Distribution A: Approved for public release; distribution is unlimited
  • 51. 51 Co-mingled Nanofibrous Films • Entanglement of the electrospun jets in the instability region can result in a uniformly co-mingled film of fibers where nanotubes are confined within individual filaments. • Secondary-processing of co-mingled micro/nanofiber assemblies in a dense film results in a self-reinforced hierarchical composite with active polymer matrix. Breakthrough in Composites Processing  Rapid consolidation of thermoplastics  Greater control over morphology of nano- reinforcement at high concentration YIP’09 - NANOCOMPOSITES FOR SENSING (U Del: Thostenson) Distribution A: Approved for public release; distribution is unlimited
  • 52. 52 Erik T. Thostenson 0 1 2 3 4 5 6 0 0.05 0.1 0.15 0.2 0.25 EffectiveImpedanceChange Strain (%) -1 0 1 2 3 4 5 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0 200 400 600 800 1000 1200 1400 EffectiveImpedanceChange Strain(%) Time (s) Neat CNT (0.001) - PVDF Copper sheet Composite Specimen d w TensileForce TensileForce Solder Joint(For connectionto TDR module) Accomplishments: • The electromechanical response of piezoelectric nanocomposites is established at high frequencies utilizing a time-domain reflectometry approach. • The integration of small quantities of carbon nanotubes impart apparent dielectrorestrictive response and capability for non-contact strain sensing. • High-frequency effective impedance changes are directly related to changes in dielectric properties associated with strain • Alteration of the percolating network can result in significant changes to the resistance- strain behavior in films and foams of nanocomposites. YIP’09 - NANOCOMPOSITES FOR SENSING (U Del: Thostenson) Distribution A: Approved for public release; distribution is unlimited
  • 53. 53 Stretchable Matrix Autonomous System Multi-Scale Design, Synthesis & Fabrication Sensors (temperature, pressure, strain, etc) Local neurons (processor, memory, communication devices) BUILT-IN SENSING NETWORK (Stanford/UC/DU/UCLA: Chang et al) MURI ‘09 Synaptic Circuits Synapse: Cognition and decision-making are determined by a relative level of cumulative signal strength with respect to the synapse threshold values Biological sensory systems rely on large numbers of sensors distributed over large areas and are specialized to detect and process a large number of stimuli. These systems are also capable to self-organize and are damage tolerant. PM: B. L. Lee; Co-PM: Hugh Delong Distribution A: Approved for public release; distribution is unlimited
  • 54. 54  The 2nd generation device emulating a biological synapse, which integrates spatiotemporal logic, memory and learning functions, has been developed by integrating CNT’s and C60-doped polymer layer in a field-effect transistor. This novel “synapstor” offers drastically reduced power consumption compared to Si CMOS transistors.  A voltage pulse applied on the gate of a synaptic transistor triggers electronic charge/discharge in the C60 molecules in the polymer to generate post-synaptic current (PSC).  The amplitudes of the post-synaptic current can be configured to analog states quantitatively (ranging from 10^-12 to 10^-7 A) and reversibly by modifying the charge inside the C60 molecules with a series of gate pulses.  Based on the extrapolations of the experimental data, the analog values could be distinguished and preserved for years, indicating the long-term nonvolatile analog memory of the synapstor. C60 Carbon Nanotube ++ + ─ ─ Gate Electrode Insulator Electrons Holes MURI ‘09 EMULATING BIOLOGICAL SYNAPSE (UCLA: Chen) - Update Distribution A: Approved for public release; distribution is unlimited
  • 55. 55 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: John Kieffer (U Mich) Ioannis Chasiotis (UIUC) Jerry Qi (U CO) Kurt Maute (U CO) Martin Dunn (U CO) G. Ravichandran (Caltech)* Jose Andrade (Caltech)* Kaushik Bhattacharya (Caltech)* Chiara Daraio (Caltech)* Michael Ortiz (Caltech)* Chris Lynch (UCLA)* Greg Carman (UCLA)* Naresh Thadhani (GA Tech) Sarah Stewart (Harvard U) John Borg (Marquette U) * CoE Distribution A: Approved for public release; distribution is unlimited
  • 56. 56 NAME: B. L. (“Les”) Lee BRIEF DESCRIPTION OF PORTFOLIO: Basic science for integration of emerging materials and micro-devices into future Air Force systems requiring multi-functional design LIST OF SUB-AREAS:  Design of Autonomic/Self-Sustaining Systems;  Design of Reconfigurable Systems; Fundamentals of Mechanics of Materials; Life Prediction (Materials & Micro-devices); Sensing, Detection & Self-Diagnosis; Self-Healing, Remediation & Structural Regeneration; Self-Cooling & Thermal/Irradiation Management; Energy Transduction & System Integration; Actuation, Morphing & Threat Neutralization; Engineered Bio/Nano/Info-materials PORTFOLIO OVERVIEW PI’s & Co-PI’s: John Kieffer (U Mich) Ioannis Chasiotis (UIUC) Jerry Qi (U CO) Kurt Maute (U CO) Martin Dunn (U CO) G. Ravichandran (Caltech)* Jose Andrade (Caltech)* Kaushik Bhattacharya (Caltech)* Chiara Daraio (Caltech)* Michael Ortiz (Caltech)* Chris Lynch (UCLA)* Greg Carman (UCLA)* Naresh Thadhani (GA Tech) Sarah Stewart (Harvard U) John Borg (Marquette U) * CoE Subject: << Multi-scale Simulation of Interfacial Phenomena << Deformation & Fracture of Silicon for MEMS >> 3D Printed Composites for Topology Transform High-rate Physics of Heterogeneous Materials Dynamic High-Pressure Behavior of Geomaterials >> New; << Concluded Distribution A: Approved for public release; distribution is unlimited
  • 57. 57 • Fundamental understanding of the physics of heterogeneous materials at high-strain-rates (105-107/s) and high-pressures (1-100 GPa) • Development of microstructures and functional nanomaterials for mitigating shock and damage • Use of innovative methods for educating and training the next generation of scientists and practitioners Objectives: Achievements: Perspectives: • New generation of analysis, design, simulation and experimental tools for heterogeneous material structures and systems of interest to the Air Force • Design of robust munitions systems with novel protective systems for structures, electronics and guidance systems Experimental shock physics Shock mitigation  Ferroelectric and ferromagnetic based energy harvesting materials for shock mitigation  Pressure induced depolarization in 95/5 and 52/48 PZT based compositions characterized under hydrostatic and dynamic loading (split Hopkinson bar) Shock energy corresponding to area to left of the curve can be harvested for ferroelectrics (Similar cycle for ferromagnetics)• Validated Granular Element Method (GEM) for computing interparticle forces in a model particulate material Experiment GEM Simulation • Concept of metaconcrete with effective “negative” mass which can potentially trap or disperse waves generated by shock loading • Shock physics of “model” particulate composite (glass spheres embedded in PMMA). 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 -0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 ParticleVelocity[km/s] Time [ ms ] AFOSR/RW CoE’12 - SHOCK PHYSICS (Caltech/UCLA: Ravichandran) Distribution A: Approved for public release; distribution is unlimited
  • 58. 58 Objective: To develop a comprehensive 3D multi-physics, multi-scale computational analysis and simulation capability for multi- functional composite structures. Approaches: 1. Ubiquitous Multi-Physics Modeling incl. Transients: Coupled transient electromagnetic (EM) and dynamic mechanical (ME) fields 2. Temporal Multi-Scaling for Disparate Frequencies: Electromagnetics (ultrasonic frequency) and mechanical vibration (moderate frequency) in a unified modeling framework 3. Spatial Multi-Scaling for Composite Media: Need to account for microstructure-structure interaction and design, e.g. conductors/reinforcements in antenna, conductor- substrate in sensors, and nodes (piezoelectric sensor) and wires (connection of nodes) in sensor network. 4. Piezoelectric Materials: Undergoing finite deformation COUPLING EM-STRUCTURAL DYMAMICS (JHU: Ghosh) MURI ‘09 Time (sec) .10 .15 .20 .25 Displacement(m) -.02 -.01 0.00 .01 .02 ElectricField(V/m) -4e-6 -2e-6 0 2e-6 4e-6 Displacement Electric Field Time (sec) 0.0 0.1 0.2 0.3 0.4 ElectricField(V/m) -2e-6 -2e-6 -1e-6 -5e-7 0 5e-7 1e-6 1e-6 2e-6 Displacement(m) -0.02 -0.01 0.00 0.01 0.02 Electric Field Displacement Distribution A: Approved for public release; distribution is unlimited
  • 59. 59 SUMMARY • The program is fully focused on the multi-functional design of advanced aerospace materials and structures. • A major progress has been made in pursuing a new vision for autonomic, self-sustaining and reconfigurable systems and providing basic research support for mechanics of emerging materials and micro-devices as its foundation. • Multi-disciplinary research bases are successfully formed for “self-healing,” “structurally integrated energy harvest/storage capabilities,” “load-bearing antennas” and “morphing materials.” • Thee initiatives are in progress for “neurological system inspired sensory network” (MURI ’09), “high-rate deformation” (CoE’12) and “biomolecular autonomic material systems” (BRI’12). • New initiatives are planned for “muscular-skeletal system inspired actuation network” and “structural regeneration and remodeling” in collaboration with AFOSR/AFRL-TD/NSF colleagues. Distribution A: Approved for public release; distribution is unlimited