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MODULE- V



Air Quality Sampling
   and Monitoring
                         Prepared by
                Bibhabasu Mohanty
          Dept. of Civil Engineering
            SALITER, Ahmedabad
Contents…
Stack sampling, instrumentation and
methods of analysis of SO2, CO etc,
legislation for control of air pollution and
automobile pollution.




                                           2
Air Quality Sampling and
Monitoring...


                           3
What is air quality?

complicated by a lack of knowledge as to what is
 "clean" and what we mean by quality
main reason for air pollution control programs is
 to protect public health - define air quality based
 on its effects on people and the environment
effects of air pollution are chronic and not
 immediately obvious


                                                   4
• Measurements of air quality generally fall into three
  classes:
  – Measurements of Emissions - also called source
    sampling - when a particular emission source is
    measured, generally by on the spot tests
  – Meteorological Measurement - Measures
    meteorological factors that show how pollutants are
    transferred from source to recipient
  – Ambient Air Quality - Measures the quality of all the
    air in a particular place. Almost all the evidence of
    health effects is based on these measurements

                                                        5
• Also now have:

  – Industrial Hygiene sampling - for testing the air
    quality inside of factories and places of work

  – Residential Indoor sampling - to evaluate the
    quality of air in living spaces




                                                        6
Air Sampling Techniques

 Most air pollution monitoring equipment performs the
  act of sampling and analysis in one action = real time
  measurement

 older equipment = intermittent sampling (time lag
  between when the sample was obtained and when data
  was available)

 Almost all gaseous pollutants are monitored by real time
  analysis - Particulate pollutants are still mostly monitored
  by intermittent sampling, even though real time methods
  are available
                                                             7
Air Sampling Techniques

• When obtaining a sample for air pollution analysis
  – should be sufficient sample for analysis. Most
    pollutants ,very low levels and require a large volume
    of gas for accurate measurement
  – pollutants in very small quantities are easy to
    contaminate. Take care to purge sampling containers if
    grab samples are used
  – Collection and analysis limitations may require
    collection over extended periods means data may only
    be a 24 hr avg.
  – real time produces so much data - are often set to give
    hourly avg. to make data more understandable
                                                          8
Air Sampling Systems

require gases or particles to be drawn to the
 surface of a collecting medium or a sensor
sampling trains, which may include a vacuum
 pump, vacuum trap, a flow regulator and a
 collecting device or sensing unit
Sampling trains for gases may also utilize filters
 to present particles from entering the collection
 unit

                                                      9
Air Sampling Systems

Impingers




                       10
Air Sampling Procedures

conducted by static, grab, intermittent or
 continuous procedures
first air monitoring used static sampling - simple
 and cheap – requires days for data e.g. deposit
 gauge
Grab sampling not commonly used to monitor
 ambient air quality – uses bladders of syringes

                                                 11
Site Selection
• General Requirements for Site Selection
  – purpose of monitoring
  – number and type of instruments required
  – duration of measurements
  – best available general guide comes from AS2922
  – should be easily accessible



                                                12
Meteorological Monitoring
• changing weather conditions can produce dramatic
  changes in air quality and ambient pollution levels
• Factors such as:
  –   wind dispersion rates (velocity and direction)
  –   temperature inversions
  –   photochemical reactions, and
  –   rain


                                                       13
Choice of Monitoring Equipment
• For almost every type of air pollutant there are several
  different acceptable methods of analysis
• The type of equipment and methodology used for
  analysis may be determined by many factors such as
   –   cost
   –   the number of data points required
   –   the purpose for which the data are being used
   –   the time interval required between data points
   –   the devices power requirements
   –   the type of air pollutant, and
   –   the environment in which the monitoring equipment is being
       placed

                                                                    14
Calibration Procedures

 When a device uses airflow input need to calibrate the
  airflow system
 involves using a device or a pre-calibrated gas flow meter
  to check on the ambient airflow into the device
 All devices MUST be calibrated according to
  manufacturer‟s spec‟s in maintenance manual - times and
  results of these MUST be kept in the instrument logbook


                                                          15
Calibration Procedures

 two types of calibration procedures commonly used on
  air monitoring equipment – static methods and dynamic
  methods
 Static methods - involve a simple one point electrical or
  chemical test
 Dynamic methods - based on generating a flowing
  stream of calibration gas – which is used to calibrate the
  whole instrument = preferred method for calibration

                                                           16
Data Handling

range from the simplest manual methods to very
 sophisticated electronic devices
Manual methods - use field data sheets or log
 books, where all parameters are entered
 manually – not suitable for remote sites
 Data loggers - electronic devices that store many data
  points in an electronic memory. They can be attached
  to a device and accumulate the data for long periods of
  time if required

                                                            17
Reference Methods
 consider only those which are Australian Standards or
  where no Australian Standards exists US EPA
  Methods
 first generation devices - low cost unpowered
  devices - require long time to accumulate data e.g.
  deposit gauge
 second generation devices - powered and require
  small amounts of time to produce data e.g. high
  volume sampler
 third generation devices - produce instant
  (continuous data) e.g. nephelometer, gravimetric
  microbalance, remote UV-visible detectors and
  remote infra red sensors                            18
Source Sampling

 some sources are monitored continually with
  automated instruments (real time analysers)

 manual sampling techniques and testing are
  often required e.g. Pitot Probe


                                                19
Source Sampling

 introduce a probe into a waste gas stream flowing in
  smokestack - probe withdraws sample of waste gas,
  which is analysed in laboratory
 Gaseous pollutants collected by absorption in
  impingers, adsorption on charcoal or other media, or
  condensation in collecting traps
 Particulate matter be collected by a variety of
  techniques including wet scrubbing, filtration,
  impaction, and electrostatic precipitation

                                                         20
Stack Sampling

 emissions associated with combustion, velocity and
  temperature may be much higher than ambient
  conditions - measure to correct to standard conditions

 Velocity data determined from pressure measurements
  utilising a pitot-tube are necessary to calculate mass
  loading to the atmosphere, i.e., plant emission rates

 requires airflow through the sampling probe to be at
  the same rate as that flowing in the waste gas stream
  isokinetic
                                                          21
Air Quality Measurement




                          22
Air Quality Measurement




                          23
Air Quality Measurement




                          24
Real Time Analysis

 Several methods provide real time analysis, the
  most popular is remote UV detection for SO2




                                                    25
Particulates – Deposit Gauge

 involves simple collection of dust that settles to
  the earth by gravitation
 generally over a period of 30 days - 1 data
  point per month (See AS3580.9 for details)
 suffer from many problems (uncooperative
  pigeons and drunks who can‟t find anywhere
  else to go)
                                                  26
27
Particulates – Hi Vol Sampler

 most commonly used particle sampling method
 analysis is gravimetric - filter is weighed before
  and after the analysis on an analytical balance,
  and difference is particulates collected
 A standard high volume sampler collects
  particles in the size range from 0.1 - 100 m


                                                  28
Particulates – Hi Vol Sampler

 airflow is measured by a small flow meter
  (calibrated in m3 air/minute)
 particulate concentration measured is referred to
  as the Total Suspended Particles (TSP), =
  combination of Settleable particles and
  suspended particles
 expressed as g/m3 for a 24hour period –
  normally as part of 6 day cycle

                                                 29
Particulates – Hi Vol Sampler

 More information and the correct operating
  procedures on high volume samplers is available in
  Australian Standard AS3580.10 - 1990
 PM10 and PM2.5 high volume samplers –only collect
  particles with aerodynamic sizes of 10 m or less, or
  2.5 m or less
 recognised by PM10 head, which looks like a cross
  between a flying saucer and an overgrown wok!

                                                         30
31
Particulates – Nephelometers

 devices which use the scattering of light to measure the
  size and number of particles in a given air sample
 best used to determine the amount of particulate matter
  in different size fractions
 usually used to examine the amount of particulate
  material in the 0.1 – 2.5 m size range – that which
  presents the greatest risk to human health

                                                         32
33
Gases – Sulfur Dioxide

 many methods available for determination of SO2
 AS3580.4.1 - 1990. appropriate for SO2 0-5ppm
 permits the use of any of the following detection
  methods;
   – UV fluorescence analyser
   – flame photometric detector (with or without gas
     chromatograph)
   – electrochemical (coulimetric detector)
   – most widely used method in this country is the UV
     fluorescence analyser

                                                         34
Gases – Sulfur Dioxide

 UV Fluorescence = air sample drawn into a
  scrubber chamber (removes PAH) and then on
  into an irradiation chamber where it is exposed
  to UV light
 SO2 absorbs in 190-230nm
 The amount of fluorescent radiation is directly
  proportional to the concentration of SO2

                                                35
Measurement of sulphur dioxide (SO2) by UV fluorescence




                                                    36
Gases – Sulfur Dioxide

 SO2    +   UV              SO2*
 SO2*                   SO2 + light




                                       37
Gases – Oxides of Nitrogen
 determined using chemiluminescence
 specific for NO, but total oxides of nitrogen
  determined by passing sample over a catalyst to
  convert NO2 to NO
 suitable for ambient air containing NOx (NO
  and NO2) at levels less than 1 mL/m3


                                               38
Measurement of nitric oxides (NOx) by chemiluminescence




                                    Chemiluminescent reaction
                           NO + O3 ==> NO2+ O2 + hv (0.6 – 3 μm)
                                                              39
Gases – Oxides of Nitrogen

 reaction of NO with ozone in a dark enclosed chamber
  to produce light - detected by a pmt
 Provided the ozone is present in excess the light output is
  directly proportional to the concentration of NO

 NO + O3                    NO2* + O2
 NO2*                       NO2 + h (light)

                                                          40
Gases – Ozone

 determined either by chemiluminescence methods or
  direct reading UV detectors. AS3580.6 - .6.1 - 1990
 sample drawn into a mixing chamber mixed with a
  stream of ethane - causes a chemiluminescent
  reaction and the subsequent emitted light at about
  430nm
 direct reading UV method - stream of gas in the
  sample is drawn through a flow cell where it is
  irradiated with UV light at 254nm
                                                        41
Gases – Carbon Monoxide

 non-dispersive infra red (NDIR) devices, suitable
  for detection from 0-500ppm by volume
 sample through a flow cell in the instrument
  where it is irradiated with infrared radiation
 essentially just a modified dual beam infrared
  spectrophotometer

                                                 42
Measurement of carbon monoxide (CO) by IR photometry
            Schematic of a NDIR head




                                                 43
IR source


                      Chopper
CO     free
air in           Ambient sample in

 Reference       Sample cell
 cell
                Ambient sample out
 CO      free
 air out        IR transmitting
                windows
    0.1
                      Detector
    2
                diaphragm       &
                capacitance plate
                                     44
Gases – Non-methane H/C

 essential to discriminate between methane and other
  H/C‟s, as it is the only hydrocarbon that naturally
  occurs in large amounts in the atmosphere - remember
  those cows & termites!
 feed a continuous stream of gas sample into a GC with
  a FID
 hand held field gas chromatographs now available
  which allow sampling and analysis to be done in the
  field – eliminating sampling error

                                                     45
Gases – Fluoride

 AS2618.2-1984 which is suitable for determining
  levels of 0.1 g/m3 or greater
 automatic sampler draws ambient air through an inlet
  tube which passes it through an acid impregnated
  paper tape (initial filter tape) to collect particulate
  fluorides and then through an alkali-impregnated
  paper tape (final filter tape) to collect acidic gaseous
  fluorides
 New methods impinge the gas and use F- ISE
                                                         46
Gases – Hydrogen Sulfide

 Automatic Intermittent Sampling Gas
  Chromatographic Method as outlined in
  AS3580.8.1 - 1990
 applicable to ambient air with H2S
  concentrations in the range 0.003 - 2ppm and is
  totally specific
 GC is designed to sample air automatically at
  least ten times per hour
                                                47
LEGISLATION FOR
CONTROL OF AIR
POLLUTION


                  48
According to the Environment Protection
  Act of 1986, Environment is that which
includes the “inter-relationship which exists
among and between water, air, and land and
human beings, other living creatures, plants,
      micro-organism and property.”



                                            49
The Air (Prevention And Control Of Pollution)
  Act, 1981

This Act was passed for the “prevention, control
 and abatement of air pollution.”
This law defined an air pollutant as “any solid,
 liquid or gaseous substance present in the
 atmosphere in such concentration as may be or
 tend to be injurious to human beings or other
 living creatures or plants or property or
 environment.”
                                               50
In this Act, power to declare air pollution,
 control areas has been given to the state
 government after consulting the State Board.

By this, it may control or even prohibit burning
 of certain materials in those specific areas.

This Act requires approval prior to operating
 any industrial plant.
                                                    51
Government may suggest “control equipment”
 prior to giving its consent to any industry for its
 operation.

It may include chimney etc. In case there is any
 new technology for emission control, then the
 Board may insist on this to being installed.

Standards specific to industries have been
 specified.
                                                    52
Penalties were for a minimum of six months
 imprisonment to a maximum of seven years and
 fine up to Rs. 5,000 for every day during which
 contravention continues after conviction for the
 first such contravention.

This law makes it clear that when offenses are
 committed by a company, its director, manager,
 secretary or other officers could be held guilty
 and punished accordingly.

                                                    53
Ambient Air quality
Standards


                      54
NAAQM network is operated through NEERI
 and CPCB

Ambient Air Quality Status is described as Low
 (L), Moderate (M), High (H) and Critical (C)

2 types of NAAQS: primary and secondary
NAAQS
NAAQS
Revised NAAQS 2009
PM 2.5 and ozone have been included
Standards for NOx has been made more
 stringent
Standards for short duration exposure to deadly
 gases like ozone and CO have been set
Tighter standards for „sensitive areas‟ have been
 notified. (forest &natural vegetation)
Air Quality Index
 Is a number used by government agencies to
  characterize the quality of the air at a given location.
Limitations of the AQI
Most air contaminants do not have an associated
 AQI.
The AQI can worsen (go up) due to lack of
 dilution of air emissions by fresh air.
Stagnant air, due to anticyclone or temperature
 inversion, or lack of winds prevents dilution
LEGISLATION FOR
CONTROL OF
AUTOMOBILE POLLUTION


                       61
Multisectoral Handling
 Ministry Of Environment And Forests
   -Environment Protection Act, 1986
   -Emission Standards
   -Central Pollution Control Board
   -State Pollution Control Boards
 Ministry of Road Transport and Highways
   -Central Motor Vehicle Rules (CMVR)
   -Safety and Emission Standards
   -State Transport Departments
 Ministry of Petroleum and Natural Gas
   -Fuel Quality Specifications - Under BIS
 Ministry of Heavy Industries
   -ARAI- Prototype Approvals for new vehicles- both for safety
     and emission                                               62
Chronology of Events
Emission Norms
The Journey Began in 1984 - when the State of Maharashtra
  introduced norms for idling CO and free acceleration smoke.
1989- the above norms were extended for the entire country
1991 -Exhaust mass emission norms for gasoline for only CO &
  HC for vehicles below 3.5 ton GVW were introduced
  -Full load and free acceleration smoke regulations for diesel
  vehicles also introduced.
1992- Exhaust mass emission norms for diesel vehicles / engines
  above 3.5 ton GVW introduced

                                                                  63
1995 -Mandatory fitment of catalytic converter for gasoline
        Passenger cars in Metropolitan cities.
1996 -stringent norms for gasoline (CO, HC + NOx) and diesel
        vehicles introduced.
      -Cold start emission test for diesel vehicles below 3.5 ton
        GVW.
1998 -Cold start emission test for gasoline passenger cars
        introduced
1999- India 2000 (Equivalent to Euro-I) norms introduced for
        passenger cars in National Capital Region (Delhi)
2000 - Bharat Stage I norms for all category of vehicles
        introduced
        - Bharat Stage II (Equivalent to Euro-II) norms for
        gasoline and diesel passenger cars introduced in National
        Capital Region (Delhi)
        -Particulate limit values introduced for diesel vehicles    64
Future Emissions Norms

In April 2005
    – Bharat Stage II (Equivalent to Euro-II) norms for
      gasoline and diesel passenger cars a will be
      introduced in entire country
    – Bharat Stage II norms for 2 and 3 Wheelers will
      come into force in entire country
    – Bharat Stage III (Equivalent to Euro-III) norms
      for gasoline and Diesel vehicles will be introduced
      in 11 cities

                                                        65
Emission Norms for Petrol Passenger Cars

   Norms        CO( g/km)    (HC+ NOx)(g/km)
    1991         14.3-27.1     2.0(Only HC)

    1996        8.68-12.40      3.00-4.36

    1998        4.34-6.20       1.50-2.18

 India stage       2.75           0.97
    2000

Bharat stage-      2.2             0.5
     II
Bharat Stage-      2.3       0.35 (combined)
    III
Bharat Stage-      1.0       0.18 (combined)
     IV
                                               66
Emission Norms for Diesel Passenger Cars

YEAR       CO ( g/km)   HC+NOX (g/km) PM ( g/km)

1991       16.5         02.1          -

1996       05.7         02.2          -

2000       02.72        0.97          0.14

EURO II    01.00        0.7           0.08

EURO III   0.64         0.56          0.05

EURO IV    0.5          0.3           0.025


                                                   67
Emission Norms for 2 wheelers

    Norms          CO ( g/km)   HC+ NOx (g/km)

     1991            12-30       8-12 ( only HC)

     1996             04.5            03.6

India stage 2000      02.0            02.0

Bharat stage-II       01.6            01.5
   in 2005
Bharat Stage-III      1.0             1.0
proposed in 2008
                                                   68
Emission Norms for 3 wheelers- Petrol

      Norms          CO ( g/km)   HC+ NOx (g/km)

       1991            12-30       8-12 ( only HC)

       1996             6.75            5.4

  India stage 2000      4.0             2.0

  Bharat stage-II       2.5             2.5
      in 2005
  Bharat Stage-III      1.25            1.25
      in 2008
                                                     69
Emission Norms for 3 wheelers- Diesel
    Norms          CO         HC        NOx         PM
                (g/kwhr)   (g/kwhr)   (g/kwhr)   (g/kwhr)
     1991         304        12                     -

     1996         5.0        2.0                    -

  India stage     2.72       0.9                   0.14
     2000


    Bharat        0.85       0.01                  0.64
   stage-II
   in 2005
    Bharat        0.7        0.7                   0.05
   Stage-III
    in 2008



                                                            70
Emission Norms for Heavy Diesel Vehicles
   Norms          CO         HC        NOx         PM
               (g/kwhr)   (g/kwhr)   (g/kwhr)   (g/kwhr)
 1991Norms       14         3.5        18          -

 1996 Norms      11.2       2.4        14.4        -

 India stage     4.5        1.1        8.0        0.36
 2000 norms

   Bharat        4.0        1.1        7.0        0.15
  stage-II
   Bharat
  Stage-III      2.1        1.6        5.0        0.10

   Bharat        1.5        0.96       3.5        0.02
  Stage-IV

                                                           71
In-use Vehicle Emission Control
Pollution Under Control (PUC)
 Under Rule 115 (7) of Central Motor Vehicle Rules
  (CMVR), 1989, motor vehicles are required to carry PUC
  Certificate to be given by an agency authorized for this
  purpose by State Govt.
 Measurement of emissions from petrol vehicle is done
  by gas analyzer and in case of diesel vehicle emission
  are measured by smoke meters. There is a list of
  approved vendors and models of PUC equipment
  which is compiled and circulated by ARAI, Pune. 72
PUC
To ensure that the in-use vehicles are maintained well
and less emitting

Gasoline vehicles are tested for CO emission

Diesel vehicles are tested for Free acceleration smoke




                                                          73
Present and Proposed Emission Norms
                 for In-use -vehicles
S.No    Vehicle type                     Present          Proposed
                                         CO %      HC    CO % HC(ppm) n
                                                   (ppm)      Hexane
                                                                equivalent
1       2 Wheelers ( 2/4 stroke) & 3 4.5           -      4.5        9000
        wheelers  ( Pre year 2000)
2       2 Wheelers ( 2-stroke) &      3 4.5        -      3.5        6000
        wheelers  ( Post year 2000)

3       2 & 3      Wheelers ( 4 stroke) 4.5        -      3.5        4500
        ( Post year 2000)

4       4 wheeler vehicles   ( Post year 3.0       -      3.0        1500
        2000)                   ( Petrol/
        CNG/LPG)

5       Bharat      Stage-II compliant 3.0         -      0.5        750
        Passenger cars/CNG Buses/ LPG
        (Fitted with 3 way closed loop
        catalytic converter)
        4 GAS ANALYSER
                                                                             74
Present PUC system - Limitations
– Test procedures and norms have not changed since
  introduction
– PUC Center operators are not trained
– Equipment not maintained / calibrated
– Proper test procedure not followed
– No well defined criteria for authorizing /registering PUC
  Center
– No auditing of PUC Center
– Lack of centralized agency for co-ordination
– The number of vehicles undergoing PUC test is very small due
  to absence of control mechanism to identify vehicles escaping
  PUC
– No analysis of the data collected
– Existing system is prone to tampering                      75
Enhanced PUC system
 CMVR revised in February 2004- to be applicable from October
  2004
 PUC system revised
 Revision in idle emission norms based on the year of vehicle
  manufacture.
 Introduction of idle HC emission standards
 Introduction of idle CO and HC emission norms for CNG /
  LPG vehicles
 Will have improved test methods for gasoline and diesel vehicles
 Four gas analyzer for better accuracy
 Measurement of Engine oil temperature and engine rpm for
  repeatable and consistent smoke readings
                                                                76
Enhanced PUC system
 Improved equipment operating conditions
 Compulsory AMC for min 5 yrs.
 Annual renewal based on AMC verification
 Training of PUC center operators by equipment
  suppliers and institutionalize the complete system
 Calibration of equipment three times per year
 Communication capability with computer for data
  transfer and storage


                                                       77
Proposed Revisions in Smoke Meter
           Specifications
 Oil temperature and engine rpm measurement built into the smoke
  meter.
    oil temperature above 60 C will be used as an indication of
     engine warm-up.
    engine rpm will be measured to ensure consistency of operation
 Smoke meter to identify the initial 6 flushing cycles based on the
  rpm measurement
 Software will ensure the repeatability of the maximum rpm
  achieved for each acceleration within + 300 rpm for 4 Wheelers
  and + 500 rpm for 3 wheelers.
 The smoke meter will provide the indications to assist the user for
  operation of the accelerator pedal.                                78
4 gas analyzers v/s 2 gas analyzers
 Higher Accuracy of the Analyzer thereby reducing
  measurement errors
 Leak detection, low flow alarm and HC hang up test
  enhances accuracy of the test results
 Automatic gas calibration at least once a day for which a
  separate / inbuilt gas cylinder is required.
 Provision for RPM measurement is required
 Provision for NOx gas analysis for future requirements.

                                                          79
Proposal for Effective Inspection and
        Certification Regime
 Dovetail the present PUC system with I/C centers
 Develop loaded mode emission test methods in the long
  run
 Use technologies like Remote Sensing Device (RSD) as a
  supplement tool to identify gross polluting vehicles
 Change Pass/fail cut off points dynamically
 Involve general public in identifying the gross polluting
  vehicles by sending the SMSs through mobile phones or
  using the toll free numbers
                                                          80
Proposal for Effective Inspection and
        Certification Regime
 Introduce an efficient maintenance system to rectify the vehicles
  that have failed in the I/C centers
 Introduce certification and audit system for repair workshops
 For the quality of the services by the test centers, introduce audit
  system
 Develop a centralized software which is common to all the I&C
  centers for data transfer, storage, data analysis, uploading on a web
  site, etc
 I&C equipment manufacturers and suppliers to train I&C operators
 The validity of the I/C centers should be linked to 5 years AMC
                                                                         81
Road map for controlling vehicular pollution
   from New vehicles (all vehicle except 2/3
                  wheelers)
Norms                    Cities of Implementation   Effective date


1991 emission norms      Throughout the country     1.4.1991/92

1996 emission norms      Throughout the country     1.4.1996

Cat converter norms      45 cities                  1.10.1998
( for passenger cars)

India stage 2000 norms   Throughout the country     1.4.2000


Bharat stage-II norms    11 cities                  2000-2003
                         Throughout the country     1.4.2005

Bharat stage-III norms   11 cities                  1.4.2005
                         Throughout the country     1.4.2010

Bharat stage-IV norms    11 cities                  1.4.2010
                         Throughout the country     To be decided
                                                                     82
Road map for controlling vehicular pollution
          from New 2/3 wheelers
Norms                 Cities of implementation   Effective date

1991 emission norms   Throughout the country     1.4.1991

1996 emission norms Throughout the country       1.4.1996


India stage 2000      Throughout the country     1.4.2000
norms


Bharat stage-II       Throughout the country     1.4.2005
norms
Bharat stage-III      Throughout the country     1.4.2008/10
norms


                                                                  83
Fuel Quality Improvements
 Fuel Specifications changed progressively to meet the
  emission standards
 National Fuel Testing Laboratory established at Noida for
  testing Fuel Adulteration
 Another planned at Gurgaon - has difficulty
 Alternative fuels /Cleaner fuels like CNG/LPG encouraged
 Bio-diesel / Bio Fuels in use
 Eight States have introduced 5% ethanol in petrol
 Research on Hydrogen Fuel Cells
 Premixed oil for 2-stroke engines at fuelling station

                                                          84
Fuel Quality Improvements -
             Gasoline
 Lead phase out in 1998 in metro cities
 Lead phase out from gasoline in entire country– 1
  February 2000
 Sulphur from gasoline reduced from 0.2 % to 0.1 % in
  entire country from 1st April 2000
 4 Metro cities and NCR supplied with 0.05% max
  sulphur from 1st April 2000
 From 1st April 2005, 0.05% max sulphur fuel will be
  available in entire country
                                                         85
Fuel Quality improvements - Diesel

 Sulphur reduced from 1.0% max in April 1996 to 0.25
  % in January 2000
 In 4 metro cities, sulphur reduced to 0.05 % max
 Cetane number increased from 45 to 48




                                                        86
Fuel Quality Specifications for Gasoline
For meeting norms     Lead(g/l)           Benzene(%)        Sulphur(%)

1991 norms            0.56 (leaded)       No limit          0.25

1996norms             0.15( low leaded)   5                 0.10(unleaded)
                      0.013 (unleaded)                      0.20 ( leaded)
India stage 2000      0.013               3( 4 metros)      0.10
norms                                     5 (rest of the
                                          country)

Bharat stage-II norms 0.013               (megacities)      0.05
                                          3 ( rest of the
                                                country)
Bharat stage-III      0.005               1                 0.015
norms
Bharat Stage-IV       0.005               1                 0.005
norms

                                                                         87
Fuel Quality Specifications for Diesel
 For meeting      Sulphur   Cetane number   Density
    norms         content
 1991 norms         1.0          42            -

 1996 norms        0.50          45         820-880

 India stage       0.25          48         820-860
 2000 norms
Bharat Stage-II    0.05          48         820-860
   norms
 Bharat stage-     0.035         51         820-845
  III norms
Bharat stage-IV    0.005         51         820-845
    norms


                                                      88
Road Traffic Management
 Construction of Flyovers
 Quality of Roads
 Synchronization of Traffic lights
 Installation of Timer at Traffic Lights
 Restriction of Plying certain category of vehicles on
  certain roads
 Decongestion of Road by altering the office timings
 Shifting of Some offices out of metro cities
 Construction of Metro Rail in Delhi
 Increase in Public Transport
                                                          89
Economic Instruments
Levying Tax on Diesel
Levying Tax on Diesel Vehicles
Tax on owning more than one car
Parking Tax




                                   90
Role of Judiciary
 Various Directions and Judgments

 Environment Pollution (Prevention & Control)
  Authority (EPCA) for National Capital Region




                                                 91
Key Issues -Future Strategies
 Large fleet of In-use vehicles
 Large no. of 2-stroke vehicles
 No scrapping policy for vehicles
 15 yr old vehicles shifted to other small cities
 Poor pollution monitoring system
 Road worthiness checked manually
 Pollution equipment either faulty or not calibrated
 Lack of inter- ministerial and inter state coordination-Poor
  information exchange
 Poor maintenance of vehicles
 Lack of awareness
 Overloading, Adulteration of fuel , Traffic Congestion
                                                                 92
93

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Air quality sampling and monitoring m5

  • 1. MODULE- V Air Quality Sampling and Monitoring Prepared by Bibhabasu Mohanty Dept. of Civil Engineering SALITER, Ahmedabad
  • 2. Contents… Stack sampling, instrumentation and methods of analysis of SO2, CO etc, legislation for control of air pollution and automobile pollution. 2
  • 3. Air Quality Sampling and Monitoring... 3
  • 4. What is air quality? complicated by a lack of knowledge as to what is "clean" and what we mean by quality main reason for air pollution control programs is to protect public health - define air quality based on its effects on people and the environment effects of air pollution are chronic and not immediately obvious 4
  • 5. • Measurements of air quality generally fall into three classes: – Measurements of Emissions - also called source sampling - when a particular emission source is measured, generally by on the spot tests – Meteorological Measurement - Measures meteorological factors that show how pollutants are transferred from source to recipient – Ambient Air Quality - Measures the quality of all the air in a particular place. Almost all the evidence of health effects is based on these measurements 5
  • 6. • Also now have: – Industrial Hygiene sampling - for testing the air quality inside of factories and places of work – Residential Indoor sampling - to evaluate the quality of air in living spaces 6
  • 7. Air Sampling Techniques  Most air pollution monitoring equipment performs the act of sampling and analysis in one action = real time measurement  older equipment = intermittent sampling (time lag between when the sample was obtained and when data was available)  Almost all gaseous pollutants are monitored by real time analysis - Particulate pollutants are still mostly monitored by intermittent sampling, even though real time methods are available 7
  • 8. Air Sampling Techniques • When obtaining a sample for air pollution analysis – should be sufficient sample for analysis. Most pollutants ,very low levels and require a large volume of gas for accurate measurement – pollutants in very small quantities are easy to contaminate. Take care to purge sampling containers if grab samples are used – Collection and analysis limitations may require collection over extended periods means data may only be a 24 hr avg. – real time produces so much data - are often set to give hourly avg. to make data more understandable 8
  • 9. Air Sampling Systems require gases or particles to be drawn to the surface of a collecting medium or a sensor sampling trains, which may include a vacuum pump, vacuum trap, a flow regulator and a collecting device or sensing unit Sampling trains for gases may also utilize filters to present particles from entering the collection unit 9
  • 11. Air Sampling Procedures conducted by static, grab, intermittent or continuous procedures first air monitoring used static sampling - simple and cheap – requires days for data e.g. deposit gauge Grab sampling not commonly used to monitor ambient air quality – uses bladders of syringes 11
  • 12. Site Selection • General Requirements for Site Selection – purpose of monitoring – number and type of instruments required – duration of measurements – best available general guide comes from AS2922 – should be easily accessible 12
  • 13. Meteorological Monitoring • changing weather conditions can produce dramatic changes in air quality and ambient pollution levels • Factors such as: – wind dispersion rates (velocity and direction) – temperature inversions – photochemical reactions, and – rain 13
  • 14. Choice of Monitoring Equipment • For almost every type of air pollutant there are several different acceptable methods of analysis • The type of equipment and methodology used for analysis may be determined by many factors such as – cost – the number of data points required – the purpose for which the data are being used – the time interval required between data points – the devices power requirements – the type of air pollutant, and – the environment in which the monitoring equipment is being placed 14
  • 15. Calibration Procedures  When a device uses airflow input need to calibrate the airflow system  involves using a device or a pre-calibrated gas flow meter to check on the ambient airflow into the device  All devices MUST be calibrated according to manufacturer‟s spec‟s in maintenance manual - times and results of these MUST be kept in the instrument logbook 15
  • 16. Calibration Procedures  two types of calibration procedures commonly used on air monitoring equipment – static methods and dynamic methods  Static methods - involve a simple one point electrical or chemical test  Dynamic methods - based on generating a flowing stream of calibration gas – which is used to calibrate the whole instrument = preferred method for calibration 16
  • 17. Data Handling range from the simplest manual methods to very sophisticated electronic devices Manual methods - use field data sheets or log books, where all parameters are entered manually – not suitable for remote sites  Data loggers - electronic devices that store many data points in an electronic memory. They can be attached to a device and accumulate the data for long periods of time if required 17
  • 18. Reference Methods  consider only those which are Australian Standards or where no Australian Standards exists US EPA Methods  first generation devices - low cost unpowered devices - require long time to accumulate data e.g. deposit gauge  second generation devices - powered and require small amounts of time to produce data e.g. high volume sampler  third generation devices - produce instant (continuous data) e.g. nephelometer, gravimetric microbalance, remote UV-visible detectors and remote infra red sensors 18
  • 19. Source Sampling  some sources are monitored continually with automated instruments (real time analysers)  manual sampling techniques and testing are often required e.g. Pitot Probe 19
  • 20. Source Sampling  introduce a probe into a waste gas stream flowing in smokestack - probe withdraws sample of waste gas, which is analysed in laboratory  Gaseous pollutants collected by absorption in impingers, adsorption on charcoal or other media, or condensation in collecting traps  Particulate matter be collected by a variety of techniques including wet scrubbing, filtration, impaction, and electrostatic precipitation 20
  • 21. Stack Sampling  emissions associated with combustion, velocity and temperature may be much higher than ambient conditions - measure to correct to standard conditions  Velocity data determined from pressure measurements utilising a pitot-tube are necessary to calculate mass loading to the atmosphere, i.e., plant emission rates  requires airflow through the sampling probe to be at the same rate as that flowing in the waste gas stream isokinetic 21
  • 25. Real Time Analysis  Several methods provide real time analysis, the most popular is remote UV detection for SO2 25
  • 26. Particulates – Deposit Gauge  involves simple collection of dust that settles to the earth by gravitation  generally over a period of 30 days - 1 data point per month (See AS3580.9 for details)  suffer from many problems (uncooperative pigeons and drunks who can‟t find anywhere else to go) 26
  • 27. 27
  • 28. Particulates – Hi Vol Sampler  most commonly used particle sampling method  analysis is gravimetric - filter is weighed before and after the analysis on an analytical balance, and difference is particulates collected  A standard high volume sampler collects particles in the size range from 0.1 - 100 m 28
  • 29. Particulates – Hi Vol Sampler  airflow is measured by a small flow meter (calibrated in m3 air/minute)  particulate concentration measured is referred to as the Total Suspended Particles (TSP), = combination of Settleable particles and suspended particles  expressed as g/m3 for a 24hour period – normally as part of 6 day cycle 29
  • 30. Particulates – Hi Vol Sampler  More information and the correct operating procedures on high volume samplers is available in Australian Standard AS3580.10 - 1990  PM10 and PM2.5 high volume samplers –only collect particles with aerodynamic sizes of 10 m or less, or 2.5 m or less  recognised by PM10 head, which looks like a cross between a flying saucer and an overgrown wok! 30
  • 31. 31
  • 32. Particulates – Nephelometers  devices which use the scattering of light to measure the size and number of particles in a given air sample  best used to determine the amount of particulate matter in different size fractions  usually used to examine the amount of particulate material in the 0.1 – 2.5 m size range – that which presents the greatest risk to human health 32
  • 33. 33
  • 34. Gases – Sulfur Dioxide  many methods available for determination of SO2  AS3580.4.1 - 1990. appropriate for SO2 0-5ppm  permits the use of any of the following detection methods; – UV fluorescence analyser – flame photometric detector (with or without gas chromatograph) – electrochemical (coulimetric detector) – most widely used method in this country is the UV fluorescence analyser 34
  • 35. Gases – Sulfur Dioxide  UV Fluorescence = air sample drawn into a scrubber chamber (removes PAH) and then on into an irradiation chamber where it is exposed to UV light  SO2 absorbs in 190-230nm  The amount of fluorescent radiation is directly proportional to the concentration of SO2 35
  • 36. Measurement of sulphur dioxide (SO2) by UV fluorescence 36
  • 37. Gases – Sulfur Dioxide  SO2 + UV SO2*  SO2* SO2 + light 37
  • 38. Gases – Oxides of Nitrogen  determined using chemiluminescence  specific for NO, but total oxides of nitrogen determined by passing sample over a catalyst to convert NO2 to NO  suitable for ambient air containing NOx (NO and NO2) at levels less than 1 mL/m3 38
  • 39. Measurement of nitric oxides (NOx) by chemiluminescence Chemiluminescent reaction NO + O3 ==> NO2+ O2 + hv (0.6 – 3 μm) 39
  • 40. Gases – Oxides of Nitrogen  reaction of NO with ozone in a dark enclosed chamber to produce light - detected by a pmt  Provided the ozone is present in excess the light output is directly proportional to the concentration of NO  NO + O3 NO2* + O2  NO2* NO2 + h (light) 40
  • 41. Gases – Ozone  determined either by chemiluminescence methods or direct reading UV detectors. AS3580.6 - .6.1 - 1990  sample drawn into a mixing chamber mixed with a stream of ethane - causes a chemiluminescent reaction and the subsequent emitted light at about 430nm  direct reading UV method - stream of gas in the sample is drawn through a flow cell where it is irradiated with UV light at 254nm 41
  • 42. Gases – Carbon Monoxide  non-dispersive infra red (NDIR) devices, suitable for detection from 0-500ppm by volume  sample through a flow cell in the instrument where it is irradiated with infrared radiation  essentially just a modified dual beam infrared spectrophotometer 42
  • 43. Measurement of carbon monoxide (CO) by IR photometry Schematic of a NDIR head 43
  • 44. IR source Chopper CO free air in Ambient sample in Reference Sample cell cell Ambient sample out CO free air out IR transmitting windows 0.1 Detector 2 diaphragm & capacitance plate 44
  • 45. Gases – Non-methane H/C  essential to discriminate between methane and other H/C‟s, as it is the only hydrocarbon that naturally occurs in large amounts in the atmosphere - remember those cows & termites!  feed a continuous stream of gas sample into a GC with a FID  hand held field gas chromatographs now available which allow sampling and analysis to be done in the field – eliminating sampling error 45
  • 46. Gases – Fluoride  AS2618.2-1984 which is suitable for determining levels of 0.1 g/m3 or greater  automatic sampler draws ambient air through an inlet tube which passes it through an acid impregnated paper tape (initial filter tape) to collect particulate fluorides and then through an alkali-impregnated paper tape (final filter tape) to collect acidic gaseous fluorides  New methods impinge the gas and use F- ISE 46
  • 47. Gases – Hydrogen Sulfide  Automatic Intermittent Sampling Gas Chromatographic Method as outlined in AS3580.8.1 - 1990  applicable to ambient air with H2S concentrations in the range 0.003 - 2ppm and is totally specific  GC is designed to sample air automatically at least ten times per hour 47
  • 48. LEGISLATION FOR CONTROL OF AIR POLLUTION 48
  • 49. According to the Environment Protection Act of 1986, Environment is that which includes the “inter-relationship which exists among and between water, air, and land and human beings, other living creatures, plants, micro-organism and property.” 49
  • 50. The Air (Prevention And Control Of Pollution) Act, 1981 This Act was passed for the “prevention, control and abatement of air pollution.” This law defined an air pollutant as “any solid, liquid or gaseous substance present in the atmosphere in such concentration as may be or tend to be injurious to human beings or other living creatures or plants or property or environment.” 50
  • 51. In this Act, power to declare air pollution, control areas has been given to the state government after consulting the State Board. By this, it may control or even prohibit burning of certain materials in those specific areas. This Act requires approval prior to operating any industrial plant. 51
  • 52. Government may suggest “control equipment” prior to giving its consent to any industry for its operation. It may include chimney etc. In case there is any new technology for emission control, then the Board may insist on this to being installed. Standards specific to industries have been specified. 52
  • 53. Penalties were for a minimum of six months imprisonment to a maximum of seven years and fine up to Rs. 5,000 for every day during which contravention continues after conviction for the first such contravention. This law makes it clear that when offenses are committed by a company, its director, manager, secretary or other officers could be held guilty and punished accordingly. 53
  • 55. NAAQM network is operated through NEERI and CPCB Ambient Air Quality Status is described as Low (L), Moderate (M), High (H) and Critical (C) 2 types of NAAQS: primary and secondary
  • 56. NAAQS
  • 57. NAAQS
  • 58. Revised NAAQS 2009 PM 2.5 and ozone have been included Standards for NOx has been made more stringent Standards for short duration exposure to deadly gases like ozone and CO have been set Tighter standards for „sensitive areas‟ have been notified. (forest &natural vegetation)
  • 59. Air Quality Index  Is a number used by government agencies to characterize the quality of the air at a given location.
  • 60. Limitations of the AQI Most air contaminants do not have an associated AQI. The AQI can worsen (go up) due to lack of dilution of air emissions by fresh air. Stagnant air, due to anticyclone or temperature inversion, or lack of winds prevents dilution
  • 62. Multisectoral Handling  Ministry Of Environment And Forests -Environment Protection Act, 1986 -Emission Standards -Central Pollution Control Board -State Pollution Control Boards  Ministry of Road Transport and Highways -Central Motor Vehicle Rules (CMVR) -Safety and Emission Standards -State Transport Departments  Ministry of Petroleum and Natural Gas -Fuel Quality Specifications - Under BIS  Ministry of Heavy Industries -ARAI- Prototype Approvals for new vehicles- both for safety and emission 62
  • 63. Chronology of Events Emission Norms The Journey Began in 1984 - when the State of Maharashtra introduced norms for idling CO and free acceleration smoke. 1989- the above norms were extended for the entire country 1991 -Exhaust mass emission norms for gasoline for only CO & HC for vehicles below 3.5 ton GVW were introduced -Full load and free acceleration smoke regulations for diesel vehicles also introduced. 1992- Exhaust mass emission norms for diesel vehicles / engines above 3.5 ton GVW introduced 63
  • 64. 1995 -Mandatory fitment of catalytic converter for gasoline Passenger cars in Metropolitan cities. 1996 -stringent norms for gasoline (CO, HC + NOx) and diesel vehicles introduced. -Cold start emission test for diesel vehicles below 3.5 ton GVW. 1998 -Cold start emission test for gasoline passenger cars introduced 1999- India 2000 (Equivalent to Euro-I) norms introduced for passenger cars in National Capital Region (Delhi) 2000 - Bharat Stage I norms for all category of vehicles introduced - Bharat Stage II (Equivalent to Euro-II) norms for gasoline and diesel passenger cars introduced in National Capital Region (Delhi) -Particulate limit values introduced for diesel vehicles 64
  • 65. Future Emissions Norms In April 2005 – Bharat Stage II (Equivalent to Euro-II) norms for gasoline and diesel passenger cars a will be introduced in entire country – Bharat Stage II norms for 2 and 3 Wheelers will come into force in entire country – Bharat Stage III (Equivalent to Euro-III) norms for gasoline and Diesel vehicles will be introduced in 11 cities 65
  • 66. Emission Norms for Petrol Passenger Cars Norms CO( g/km) (HC+ NOx)(g/km) 1991 14.3-27.1 2.0(Only HC) 1996 8.68-12.40 3.00-4.36 1998 4.34-6.20 1.50-2.18 India stage 2.75 0.97 2000 Bharat stage- 2.2 0.5 II Bharat Stage- 2.3 0.35 (combined) III Bharat Stage- 1.0 0.18 (combined) IV 66
  • 67. Emission Norms for Diesel Passenger Cars YEAR CO ( g/km) HC+NOX (g/km) PM ( g/km) 1991 16.5 02.1 - 1996 05.7 02.2 - 2000 02.72 0.97 0.14 EURO II 01.00 0.7 0.08 EURO III 0.64 0.56 0.05 EURO IV 0.5 0.3 0.025 67
  • 68. Emission Norms for 2 wheelers Norms CO ( g/km) HC+ NOx (g/km) 1991 12-30 8-12 ( only HC) 1996 04.5 03.6 India stage 2000 02.0 02.0 Bharat stage-II 01.6 01.5 in 2005 Bharat Stage-III 1.0 1.0 proposed in 2008 68
  • 69. Emission Norms for 3 wheelers- Petrol Norms CO ( g/km) HC+ NOx (g/km) 1991 12-30 8-12 ( only HC) 1996 6.75 5.4 India stage 2000 4.0 2.0 Bharat stage-II 2.5 2.5 in 2005 Bharat Stage-III 1.25 1.25 in 2008 69
  • 70. Emission Norms for 3 wheelers- Diesel Norms CO HC NOx PM (g/kwhr) (g/kwhr) (g/kwhr) (g/kwhr) 1991 304 12 - 1996 5.0 2.0 - India stage 2.72 0.9 0.14 2000 Bharat 0.85 0.01 0.64 stage-II in 2005 Bharat 0.7 0.7 0.05 Stage-III in 2008 70
  • 71. Emission Norms for Heavy Diesel Vehicles Norms CO HC NOx PM (g/kwhr) (g/kwhr) (g/kwhr) (g/kwhr) 1991Norms 14 3.5 18 - 1996 Norms 11.2 2.4 14.4 - India stage 4.5 1.1 8.0 0.36 2000 norms Bharat 4.0 1.1 7.0 0.15 stage-II Bharat Stage-III 2.1 1.6 5.0 0.10 Bharat 1.5 0.96 3.5 0.02 Stage-IV 71
  • 72. In-use Vehicle Emission Control Pollution Under Control (PUC)  Under Rule 115 (7) of Central Motor Vehicle Rules (CMVR), 1989, motor vehicles are required to carry PUC Certificate to be given by an agency authorized for this purpose by State Govt.  Measurement of emissions from petrol vehicle is done by gas analyzer and in case of diesel vehicle emission are measured by smoke meters. There is a list of approved vendors and models of PUC equipment which is compiled and circulated by ARAI, Pune. 72
  • 73. PUC To ensure that the in-use vehicles are maintained well and less emitting Gasoline vehicles are tested for CO emission Diesel vehicles are tested for Free acceleration smoke 73
  • 74. Present and Proposed Emission Norms for In-use -vehicles S.No Vehicle type Present Proposed CO % HC CO % HC(ppm) n (ppm) Hexane equivalent 1 2 Wheelers ( 2/4 stroke) & 3 4.5 - 4.5 9000 wheelers ( Pre year 2000) 2 2 Wheelers ( 2-stroke) & 3 4.5 - 3.5 6000 wheelers ( Post year 2000) 3 2 & 3 Wheelers ( 4 stroke) 4.5 - 3.5 4500 ( Post year 2000) 4 4 wheeler vehicles ( Post year 3.0 - 3.0 1500 2000) ( Petrol/ CNG/LPG) 5 Bharat Stage-II compliant 3.0 - 0.5 750 Passenger cars/CNG Buses/ LPG (Fitted with 3 way closed loop catalytic converter) 4 GAS ANALYSER 74
  • 75. Present PUC system - Limitations – Test procedures and norms have not changed since introduction – PUC Center operators are not trained – Equipment not maintained / calibrated – Proper test procedure not followed – No well defined criteria for authorizing /registering PUC Center – No auditing of PUC Center – Lack of centralized agency for co-ordination – The number of vehicles undergoing PUC test is very small due to absence of control mechanism to identify vehicles escaping PUC – No analysis of the data collected – Existing system is prone to tampering 75
  • 76. Enhanced PUC system  CMVR revised in February 2004- to be applicable from October 2004  PUC system revised  Revision in idle emission norms based on the year of vehicle manufacture.  Introduction of idle HC emission standards  Introduction of idle CO and HC emission norms for CNG / LPG vehicles  Will have improved test methods for gasoline and diesel vehicles  Four gas analyzer for better accuracy  Measurement of Engine oil temperature and engine rpm for repeatable and consistent smoke readings 76
  • 77. Enhanced PUC system  Improved equipment operating conditions  Compulsory AMC for min 5 yrs.  Annual renewal based on AMC verification  Training of PUC center operators by equipment suppliers and institutionalize the complete system  Calibration of equipment three times per year  Communication capability with computer for data transfer and storage 77
  • 78. Proposed Revisions in Smoke Meter Specifications  Oil temperature and engine rpm measurement built into the smoke meter.  oil temperature above 60 C will be used as an indication of engine warm-up.  engine rpm will be measured to ensure consistency of operation  Smoke meter to identify the initial 6 flushing cycles based on the rpm measurement  Software will ensure the repeatability of the maximum rpm achieved for each acceleration within + 300 rpm for 4 Wheelers and + 500 rpm for 3 wheelers.  The smoke meter will provide the indications to assist the user for operation of the accelerator pedal. 78
  • 79. 4 gas analyzers v/s 2 gas analyzers  Higher Accuracy of the Analyzer thereby reducing measurement errors  Leak detection, low flow alarm and HC hang up test enhances accuracy of the test results  Automatic gas calibration at least once a day for which a separate / inbuilt gas cylinder is required.  Provision for RPM measurement is required  Provision for NOx gas analysis for future requirements. 79
  • 80. Proposal for Effective Inspection and Certification Regime  Dovetail the present PUC system with I/C centers  Develop loaded mode emission test methods in the long run  Use technologies like Remote Sensing Device (RSD) as a supplement tool to identify gross polluting vehicles  Change Pass/fail cut off points dynamically  Involve general public in identifying the gross polluting vehicles by sending the SMSs through mobile phones or using the toll free numbers 80
  • 81. Proposal for Effective Inspection and Certification Regime  Introduce an efficient maintenance system to rectify the vehicles that have failed in the I/C centers  Introduce certification and audit system for repair workshops  For the quality of the services by the test centers, introduce audit system  Develop a centralized software which is common to all the I&C centers for data transfer, storage, data analysis, uploading on a web site, etc  I&C equipment manufacturers and suppliers to train I&C operators  The validity of the I/C centers should be linked to 5 years AMC 81
  • 82. Road map for controlling vehicular pollution from New vehicles (all vehicle except 2/3 wheelers) Norms Cities of Implementation Effective date 1991 emission norms Throughout the country 1.4.1991/92 1996 emission norms Throughout the country 1.4.1996 Cat converter norms 45 cities 1.10.1998 ( for passenger cars) India stage 2000 norms Throughout the country 1.4.2000 Bharat stage-II norms 11 cities 2000-2003 Throughout the country 1.4.2005 Bharat stage-III norms 11 cities 1.4.2005 Throughout the country 1.4.2010 Bharat stage-IV norms 11 cities 1.4.2010 Throughout the country To be decided 82
  • 83. Road map for controlling vehicular pollution from New 2/3 wheelers Norms Cities of implementation Effective date 1991 emission norms Throughout the country 1.4.1991 1996 emission norms Throughout the country 1.4.1996 India stage 2000 Throughout the country 1.4.2000 norms Bharat stage-II Throughout the country 1.4.2005 norms Bharat stage-III Throughout the country 1.4.2008/10 norms 83
  • 84. Fuel Quality Improvements  Fuel Specifications changed progressively to meet the emission standards  National Fuel Testing Laboratory established at Noida for testing Fuel Adulteration  Another planned at Gurgaon - has difficulty  Alternative fuels /Cleaner fuels like CNG/LPG encouraged  Bio-diesel / Bio Fuels in use  Eight States have introduced 5% ethanol in petrol  Research on Hydrogen Fuel Cells  Premixed oil for 2-stroke engines at fuelling station 84
  • 85. Fuel Quality Improvements - Gasoline  Lead phase out in 1998 in metro cities  Lead phase out from gasoline in entire country– 1 February 2000  Sulphur from gasoline reduced from 0.2 % to 0.1 % in entire country from 1st April 2000  4 Metro cities and NCR supplied with 0.05% max sulphur from 1st April 2000  From 1st April 2005, 0.05% max sulphur fuel will be available in entire country 85
  • 86. Fuel Quality improvements - Diesel  Sulphur reduced from 1.0% max in April 1996 to 0.25 % in January 2000  In 4 metro cities, sulphur reduced to 0.05 % max  Cetane number increased from 45 to 48 86
  • 87. Fuel Quality Specifications for Gasoline For meeting norms Lead(g/l) Benzene(%) Sulphur(%) 1991 norms 0.56 (leaded) No limit 0.25 1996norms 0.15( low leaded) 5 0.10(unleaded) 0.013 (unleaded) 0.20 ( leaded) India stage 2000 0.013 3( 4 metros) 0.10 norms 5 (rest of the country) Bharat stage-II norms 0.013 (megacities) 0.05 3 ( rest of the country) Bharat stage-III 0.005 1 0.015 norms Bharat Stage-IV 0.005 1 0.005 norms 87
  • 88. Fuel Quality Specifications for Diesel For meeting Sulphur Cetane number Density norms content 1991 norms 1.0 42 - 1996 norms 0.50 45 820-880 India stage 0.25 48 820-860 2000 norms Bharat Stage-II 0.05 48 820-860 norms Bharat stage- 0.035 51 820-845 III norms Bharat stage-IV 0.005 51 820-845 norms 88
  • 89. Road Traffic Management  Construction of Flyovers  Quality of Roads  Synchronization of Traffic lights  Installation of Timer at Traffic Lights  Restriction of Plying certain category of vehicles on certain roads  Decongestion of Road by altering the office timings  Shifting of Some offices out of metro cities  Construction of Metro Rail in Delhi  Increase in Public Transport 89
  • 90. Economic Instruments Levying Tax on Diesel Levying Tax on Diesel Vehicles Tax on owning more than one car Parking Tax 90
  • 91. Role of Judiciary  Various Directions and Judgments  Environment Pollution (Prevention & Control) Authority (EPCA) for National Capital Region 91
  • 92. Key Issues -Future Strategies  Large fleet of In-use vehicles  Large no. of 2-stroke vehicles  No scrapping policy for vehicles  15 yr old vehicles shifted to other small cities  Poor pollution monitoring system  Road worthiness checked manually  Pollution equipment either faulty or not calibrated  Lack of inter- ministerial and inter state coordination-Poor information exchange  Poor maintenance of vehicles  Lack of awareness  Overloading, Adulteration of fuel , Traffic Congestion 92
  • 93. 93