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Advanced Chemistry Types of Chemical Reactions and Solution Stoichiometry
The Common Solvent ,[object Object]
Water as a Solvent ,[object Object],[object Object],[object Object]
Water as a Solvent ,[object Object],[object Object]
Polar Water Molecules Interact with the Positive and Negative Ions of a Salt Assisting in the Dissolving Process
Solubility ,[object Object],[object Object],[object Object]
Solubility ,[object Object],[object Object],[object Object]
An Ethanol Molecule Contains a Polar O-H Bond Similar to Those in the Water Molecule
The Polar Water Molecule Interacts Strongly with the Polar-O-H bond in Ethanol
Strong and Weak Electrolytes ,[object Object]
Strong and Weak Electrolytes ,[object Object],[object Object],[object Object]
Strong and Weak Electrolytes ,[object Object],[object Object],[object Object],[object Object]
Electrical Conductivity of Aqueous Solutions
Svante Arrhenius ,[object Object],[object Object],[object Object]
Strong Electrolytes ,[object Object],[object Object],[object Object],[object Object]
NaCl Dissolves
Acids ,[object Object],[object Object],[object Object]
HCl is Completely Ionized
Acids An  Acid  is a substance that produces H +  ions when it is dissolved in water.
Acids In conductivity studies, virtually every molecule ionizes. Therefore, strong electrolytes are strong acids.
Strong Acids ,[object Object],[object Object],[object Object]
Strong Bases ,[object Object],[object Object]
Strong Bases
An Aqueous Solution of Sodium Hydroxide
Weak Electrolytes ,[object Object],[object Object],[object Object]
Weak Acids ,[object Object]
Weak Acids ,[object Object],[object Object],[object Object]
Acetic Acid (HC 2 H 3 O 2 )
Weak Bases ,[object Object],[object Object]
The Reaction of NH 3  in Water
Nonelectrolytes ,[object Object]
The Composition of Solutions ,[object Object]
Solutions ,[object Object],[object Object],[object Object]
Concentration ,[object Object],[object Object]
Example ,[object Object],.192 M NaOH
Example ,[object Object],1.60M HCl
Example ,[object Object],Co 2+  = 0.50 M Co 2+ NO 3 -  = 1.0 M NO 3 -
Example ,[object Object],3.5 x 10 -3  mol Cl -
Dilution ,[object Object],[object Object],[object Object],[object Object]
Example ,[object Object],9.4 ml solution
Steps Involved in the Preparation of a Standard Aqueous Solution
Types of Chemical Reactions
Types of Solution Reactions ,[object Object],[object Object],[object Object],[object Object]
Precipitation Reactions ,[object Object],[object Object]
Precipitation Reaction Example A more accurate representation is:
Reactant Solutions
Solution Post-Reaction
Precipitation Reaction Example ,[object Object],[object Object],[object Object],[object Object],[object Object]
Precipitation Reaction Example Two of these combinations are the reactants and can be ruled out: ,[object Object],[object Object],[object Object],[object Object]
Solubility ,[object Object],[object Object],[object Object]
Simple Rules for the Solubility of Salts in Water
Precipitation Reaction Example Two of these combinations are the reactants and can be ruled out: ,[object Object],[object Object],[object Object],[object Object]
Precipitation Reactions ,[object Object]
Solutions ,[object Object]
Formula Equation ,[object Object],[object Object]
Complete Ionic Equation ,[object Object],[object Object]
Net Ionic Equation ,[object Object],[object Object]
Example Problem ,[object Object]
of Precipitation Reactions ,[object Object]
Solution Stoichiometry ,[object Object],[object Object],[object Object]
Determining the Mass of Product Formed
Example Problem ,[object Object],Determine the amount of Ag +  ions in solution.  Determine the amount of Cl -  needed to react with Ag +
Steps to Solution Stoichiometry ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Reactions ,[object Object]
Acids ,[object Object],[object Object]
Brønsted-Lowry Acids ,[object Object],[object Object],[object Object]
Acid-Base Reactions ,[object Object],[object Object],[object Object],[object Object],[object Object]
Acid-Base Reactions ,[object Object],In this case, the salt is soluble and remains as ions. But water, a nonelectrolyte, will form since H +  and OH -  have a strong attraction for each other and do not ionize.
Acid-Base Reactions When a weak acid and a strong base react, the weak acid usually doesn’t ionize.  However, the hydroxide ion is such a strong base that for the purposes of stoichiometric calculations it can be assumed to react completely with any weak acid.
Performing Calculations for Acid-Base Reactions ,[object Object],[object Object],[object Object]
Performing Calculations for Acid-Base Reactions ,[object Object],[object Object],[object Object]
Acid-Base Reaction ,[object Object],[object Object]
Step by Step Example ,[object Object],What ions are present?  What are the possible reactions?
Example ,[object Object],NaCl is soluble.  Na +  and Cl -  are spectators. Write a balanced net ionic equation.
Example ,[object Object],What are the moles of reactant present in solution?
Example ,[object Object],How many moles of H +  are needed? The mole ratio is 1:1
Example ,[object Object],What volume of HCl is required?
Example ,[object Object],H +  is limiting 7.00x10 -3 mol H 2 O .123 M OH -  excess
Acid-Base Titrations ,[object Object],[object Object]
Acid-Base Titrations ,[object Object],[object Object]
Acid-Base Titrations ,[object Object],[object Object]
Indicators ,[object Object]
Example ,[object Object]
Example ,[object Object],[object Object],[object Object],[object Object],.1546 M
Reactions ,[object Object]
Oxidation and Reduction ,[object Object],[object Object],[object Object]
Oxidation States ,[object Object],[object Object]
Oxidation States ,[object Object],[object Object],[object Object]
Oxidation State Example ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oxidation States ,[object Object],[object Object],[object Object]
 
Examples ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Non- Integer Example ,[object Object],[object Object],[object Object],[object Object]
Redox Reactions ,[object Object]
Redox Reactions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Redox Reactions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Example ,[object Object],[object Object],[object Object]
Example ,[object Object],[object Object],[object Object],Sulfur is oxidized and oxygen is reduced. Oxygen gas is the oxidizing agent and lead sulfide is the reducing agent.
Example ,[object Object],[object Object],[object Object],Lead is reduced and carbon is oxidized.  PbO is the oxidizing agent, and CO is the reducing agent.
Oxidation-Reduction Equations ,[object Object]
Balancing Redox Reactions ,[object Object],[object Object],[object Object],[object Object]
Oxidation States Balancing Method ,[object Object]
Balancing Redox Steps ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Example +1   -1   0   +5  -2    +4  -1   +4  -2  +1  -2 Note that hydrogen, chlorine, and oxygen do not change oxidation states and are not involved in electron exchange. 0 +5  -2    +4  -1   +4  -2
Example 0 +5  -2    +4  -1   +4  -2  Tin lost 4 electrons and each Nitrogen gained 1 electron.  Therefore each nitrogen must have a coefficient of 4.  Balance the rest as usual
END ,[object Object]
Figure 4.11a-b  Measuring Pipets and Volumetric Pipets Measure Liquid Volume
Figure 4.12a-c  A Measuring Pipet is Used to Add Acetic Solution to a Volumetric Flask
Figure 4.15 a&b  The Reaction of K 2 CrO 4  and Ba(NO 3 ) 2
Figure 4.17  Molecular-Level Representations Illustrating the Reaction of KCl ( aq ) with AgNO 3  ( aq ) to Form AgCl ( s )
Determining the Mass of Product Formed
Performing Calculations for Acid-Base Reactions
Neutralization Reactions I
Neutralization Reactions II
Neutralization Titration
Figure 4.19  The Reaction of Solid Sodium and Gaseous Chlorine to Form Solid Sodium Chloride
Figure 4.20  A Summary of Oxidation-Reduction Process
The Half-Reaction Method  (Acidic Solution)
The Half-Reaction Method  (Basic Solution)
Figure 4.4a-c  Electrical Conductivity of Aqueous Solutions
An Aqueous Solution of Co(NO 3 ) 2 .
Figure 4.10  Steps Involved in the Preparation of a Standard Aqueous Solution
Yellow Aqueous Potassium
Figure 4.14a-b  Reactant Solutions
Figure 4.16  Addition of Silver Nitrate to Aqueous Solution of Potassium Chloride
Figure 4.17  Reaction of KCI(aq) with AgNO 3 (aq) to form AgCI(s).
Lead Sulfate
KOH and Fe(NO 3 ) 3  Mix to Create Solid Fe(OH) 3 .
Figure 4.18a-c The Titration of an Acid with a Base
Figure 4.19  The Reaction of Solid Sodium and Gaseous Chlorine to Form Solid Sodium Chloride
Oxidation of Copper Metal by Nitric Acid
Magnetite
Aluminum and Iodine Mix to Form Aluminum Iodide
Chocolate
When Potassium Dichromate Reacts with Ethanol, the Solution Contains Cr 3+ .
Table 4.2  Rules for Assigning Oxidation States
The End

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