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VCE Environmental Science: Unit 4
         Area of Study 1: Pollution
 Air pollution is the “introduction of
  chemicals, particulate matter or
  biological materials that cause harm
  or discomfort to humans or other
  living organisms, or cause damage
  to the natural or built environment,
  into the atmosphere.”
 There is great concern over
  deteriorating air quality as it can
  contribute to many health problems
  in our community, especially for the
  very young, the elderly and those
  who already have respiratory
  problems.
1. List in the chat window all the possible
sources of air pollution in your local area.
A.   Industrial sources
B.   Electricity generation
C.   Transport emissions
D.   All of the above
 Cancers and premature death
  can also be attributed to poor air
  quality.
 Air pollution not only has a real
  health cost, it also has an
  economic and environmental
  cost.
 Economic effects include the
  increased use of the health
  system and reduced activity of
  affected people, while
  environmental effects include
  damage to plants, animals and
  man-made structures, such as
  buildings and monuments.
Weather conditions can affect the amount
 of pollution in the air:

 Wind
 Temperature
 Airpressure
 Cloud cover
 Fog, dew and frost
 Precipitation (rain, snow, hail)
 1. I think air pollution is getting worse
 2. Photochemical smog occurs where
  there is lots of sunlight and high temps.
 3. The main component of smog is ozone
 4. Jogging on high smog days harms your
  health
 5. Wood-heaters add fine particles to the
  air
 6. Air quality could be improved if more
  people used public transport.
 Larger particles in the air are readily washed out in
  light rain. Fine and ultra fine particles require moderate
  to heavy rain to be washed to the ground.
 It should be noted that pollutant gases are generally
  not affected by light rain. However, nitrogen dioxide
  dissolves in water and is washed to the ground.
  Rainfall measurements will also be helpful in
  interpreting other air pollution measurements.
 For example, if there was exposed soil, windy days
  would cause much of this to be blown into the
  atmosphere and raise particulate (PM) readings.
  However, if there had been rain in the previous 48
  hours, the soil may well stay put and hence, particulate
  readings would be lower.
 Name as many as you can think of in the
 chat window.
 Carbon   monoxide and CO2
 Nitrogen oxides (esp. NO2)
 CFC’s
 Volatile Organic Compounds
 Ammonia
 Odours
 Particulate matter
 Pollen, dust-mites and other allergens
 Radioactive compounds
 Oxides of Sulphur (esp. SO2)
   It has been estimated that
    there were more dioxins
    released into the
    atmosphere from the
    fireworks in Sydney for the
    commencement of the
    year 2000 than was
    released for the entire
    year from industrial
    sources. If this is so, why
    is there such a focus on
    industry, rather than other
    sources for controlling
    dioxins?
 CO    is a colourless,
  odourless, non-
  irritating but very
  poisonous gas.
 It is a product by
  incomplete combustion
  of fuel such as natural
  gas, coal or wood.
 Vehicular exhaust is a
  major source of carbon
  monoxide.
 CO2  is a colourless,
 odourless, non-toxic
 greenhouse gas
 associated with ocean
 acidification, emitted
 from sources such as
 combustion of fossil
 fuels, cement
 production and
 respiration.
   NOx, especially nitrogen
    dioxide, are emitted from high
    temperature combustion. They
    can be seen as the brown haze
    dome above or plume downwind
    of cities.
   Nitrogen dioxide is a reddish-
    brown toxic gas with a
    characteristic sharp, biting
    odour. NO2 is one of the most
    prominent air pollutants, causing
    respiratory illnesses and
    reducing ventilation (air getting
    to the lungs), especially in young
    children, the elderly and those
    with respiratory illnesses.
   NO2 is also a precursor to summer
    smog, which is fast becoming a
    major problem in our cities. The
    NO2 in the atmosphere reacts with
    oxygen (O2) in the air when it is
    sunny and the temperatures are
    high to form ozone (O3) — the
    major component of summer
    smog.
   Summer smog causes eye, nose
    and throat irritation, damages the
    respiratory tract and increases our
    sensitivity to allergens.
   These oxides of nitrogen are
    removed from the air by rain, by
    plants and by contact with
    surfaces.
 Chloroflourocarbons
  (CFCs) are harmful to
  the ozone layer
 They are emitted from
  old aerosol cans and
  refrigeration units.
 Banned from use
  since 1989.
 VOCs include methane and
  other hydrocarbons, such as
  benzene, toluene and
  xylene.
 VOCs are significant
  greenhouse gases via their
  role in creating ozone and in
  prolonging the life of
  methane in the atmosphere.
 VOC’s are suspected
  carcinogens and may lead to
  leukemia through prolonged
  exposure.
 Ammonia is emitted from
  agricultural processes and is
  normally encountered as a gas with
  a characteristic pungent odour.
 Ammonia contributes significantly to
  the nutritional needs of terrestrial
  organisms by serving as a precursor
  to foodstuffs and fertilizers.
 Ammonia, either directly or
  indirectly, is also a building block for
  the synthesis of many
  pharmaceuticals. Although in wide
  use, ammonia is both caustic and
  hazardous
 Odours are also
  classified as air
  pollutants and can
  originate from:
 Garbage and landfills
 Sewage and treatment
  plants
 Industrial processes
  (milk and cheese
  processing for example)
 Dairies, sheep-yards,
  saleyards, zoos and
  abattoirs
   Particulates, alternatively referred
    to as particulate matter (PM) or fine
    particles, are tiny particles of solid
    or liquid suspended in a gas.
   In contrast, aerosol refers to
    particles and the gas together.
    Sources of particulate matter
    can be man made or natural.
   Some particulates occur naturally,
    originating from volcanoes, dust
    storms, forest and grassland fires,
    living vegetation, and sea spray.
   “Dirty Little Secrets” from ABC
    Catalyst is about the effects of PM
    on human health.
    http://www.abc.net.au/catalyst/stori
    es/s1630007.htm
 Indoor  particulate matter can include dust,
  smoke, pollen, animal dander, tobacco
  smoke, particles generated from combustion
  appliances such as cooking stoves, and
  particles associated with tiny organisms such
  as dust mites, moulds, bacteria, and viruses.
 Outdoors, the anthropogenic sources of
  particulate matter can be vehicle exhausts,
  industrial processes, wood heaters, fuel-
  reduction burning and power generation.
http://www.mde.state.md.us/programs/ResearchCenter/ReportsandPublicat
ions/Pages/ResearchCenter/publications/general/emde/vol1no12/particlepo
llution_photo.aspx
   Human activities, such as the
    burning of fossil fuels in
    vehicles, power plants and
    various industrial processes also
    generate significant amounts of
    aerosols.
   Averaged over the globe,
    anthropogenic aerosols—those
    made by human activities—
    currently account for about 10
    percent of the total amount of
    aerosols in our atmosphere.
   Increased levels of fine particles
    in the air are linked to health
    hazards such as heart disease,
    altered lung function and lung
    cancer.
   The increased rates of allergy and asthma in city
    environments and in those living close to highways has drawn
    attention to the role of outdoor pollution.
   Common air pollutants, such as ozone, sulfur dioxide, and
    nitrogen dioxide probably act more as irritants than as
    promoters of sensitization.
   These pollutants have been shown to be hazardous to adults
    and children with asthma. Recent studies suggest that
    prematurely born children are more sensitive to the respiratory
    effects of outdoor pollution.
   There may also be an association with diesel exhaust particles
    and the worldwide increase in respiratory allergies. Diesel
    exhaust has been shown to enhance the ability to make the
    allergy antibody, IgE, in response to exposure to allergens.
Indoor air pollution is among the
top five environmental health
risks.* Gaseous pollutants can be
released from furnishings and from
adhesives, paints, varnishes,
cleaning products and pesticides,
all of which contribute to poor
indoor air quality. Pollen, dust-mite
faeces, skin flakes, pet dander,
tobacco smoke and other
allergens can be reduced by
regular cleaning and adequate
ventilation.                   *http://www.epa.gov/iaq/pubs/airclean.html
Pollen is in the air seasonally,
with the amount varying from
one area to another,
depending on the types of wind
pollinating plants in the region
and the weather conditions.
For some people the amount of
pollen in the air has a direct
effect upon their health.
Airborne pollen on its own, or in
combination with fine particles
in the air, can influence the
incidence and severity of
asthma and hayfever in the
community.
   During and after rain (often
    thunderstorms) some grains of
    pollen burst, releasing the
    allergen containing starch
    granules. In Melbourne after
    rain, air samples have been
    shown to contain up to 50 times
    more starch granules than air
    sampled on a sunny day during
    the grass pollen season. The
    starch granules are small
    enough to be breathed in and
    can enter the bronchi (tubes to
    the lungs), where they may
    trigger allergic asthma.
 Produced by nuclear
 explosions and
 damaged nuclear
 power plants, war
 explosives and natural
 processes such as the
 radioactive decay of
 radon.
 Oxides of Sulphur, especially
  sulphur dioxide, a chemical
  compound with the formula SO2
  are common pollutants of the air.
  SO2 is produced by volcanoes and
  in various industrial processes.
 Since coal and petroleum often
  contain sulphur compounds, their
  combustion generates sulphfur
  dioxide. Further oxidation of SO2,
  usually in the presence of a
  catalyst such as NO2, forms
  H2SO4, and thus acid rain.
 Sulphur dioxide (SO2) is a
  colourless gas that is similar in
  smell to a matchstick being
  struck.
 As its name suggests it is a
  compound consisting of sulphur
  and oxygen, and has both
  natural and anthropogenic or
  man-made sources.
 It has significant health and
  environmental effects, including
  the formation of acid rain and
  smog and influences global
  warming.
   Sulphur dioxide consists of one atom
    of sulphur bonded to two atoms of
    oxygen. It is a strong, acrid smelling,
    non-flammable gas.
   It reacts in the atmosphere to form
    sulphur trioxide, and dissolves readily
    in water vapour, forming sulphuric acid.
    It can also attach to dust and soot
    particles in the atmosphere to form
    particulates.
   From these reactions, a wide range of
    effects are possible, including the
    formation of pollutants that influence
    both human health and environmental
    processes.
   Sulphur dioxide is formed through a
    number of pathways, including the burning
    of sulphur in the presence of oxygen and
    the oxidation of hydrogen sulphide,
    commonly emitted from wetlands.
   Natural sources include volcanoes, forest-
    fires, oceans and decaying plant matter.
    These outweigh anthropogenic sources,
    with volcanic activity producing about 20%
    of the global total.
    In Australia, the two main anthropogenic
    sources are power stations and metal
    manufacturing, while smaller sources
    include home-heating, chemical production
    and transportation emissions.
 Sulphur dioxide is a
 naturally occurring
 compound with a
 number of 'sinks' or
 areas that can absorb
 excess amounts thus
 reducing its abundance
 in the environment,
 such as the oceans,
 wetlands and lakes.
 This phenomenon results
  when sulphur dioxide
  dissolves in moisture in the air,
  forming sulphur acids, which
  eventually fall to the surface of
  the earth as acid rain.
 Acid rain directly attacks the
  protective coating of plants,
  acidifies lakes and soils which
  may result in the formation of
  substances that are toxic to
  plants and animals.
 This has been a major problem in
  northern USA, Canada and
  Scandinavia, where forests have
  been severely damaged, but
  fortunately regulations are improving
  emission standards, and reducing the
  incidence of acid rain.
 Coal mined in Australia is typically
  low in sulphur; therefore emissions
  are usually not a problem.
 We also have large sinks (oceans) in
  the southern hemisphere which
  assists to reduce the effects.
   In addition to damaging
    living organisms, acid rain
    can have a severe effect
    on buildings made of
    marble or limestone.
    Commonly used in statues
    and older buildings, these
    materials slowly dissolve
    under acidic conditions
    leading to structural failure.
    This has been a significant
    problem in Europe with
    many old buildings made
    of marble and limestone.
   The presence of high levels of sulphur
    dioxide has a negative effect on human
    health and society.
   Inhaled sulphur dioxide quickly
    dissolves with moisture on the lining of
    the lungs and nose, burning the mucous
    membranes. This is clear to anyone who
    accidentally inhales the smoke from a
    match being struck.
   Chronic - or long-term - exposure to high
    levels of SO2 leads to breathing
    problems and respiratory illnesses such
    as asthma, bronchitis as well as heart
    disease.
   Children tend to more vulnerable due to
    less developed lungs.
 http://www.npi.gov.au/students/sulfur-
  dioxide.html
 http://www.npi.gov.au/substances/sulfur-
  dioxide/index.html
 http://en.wikipedia.org/wiki/Sulfur_dioxide
 http://science.howstuffworks.com/natur
  e/climate-weather/atmospheric/acid-
  rain.htm

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Air Pollution and Sulphur Dioxide

  • 1. VCE Environmental Science: Unit 4 Area of Study 1: Pollution
  • 2.  Air pollution is the “introduction of chemicals, particulate matter or biological materials that cause harm or discomfort to humans or other living organisms, or cause damage to the natural or built environment, into the atmosphere.”  There is great concern over deteriorating air quality as it can contribute to many health problems in our community, especially for the very young, the elderly and those who already have respiratory problems.
  • 3. 1. List in the chat window all the possible sources of air pollution in your local area.
  • 4. A. Industrial sources B. Electricity generation C. Transport emissions D. All of the above
  • 5.  Cancers and premature death can also be attributed to poor air quality.  Air pollution not only has a real health cost, it also has an economic and environmental cost.  Economic effects include the increased use of the health system and reduced activity of affected people, while environmental effects include damage to plants, animals and man-made structures, such as buildings and monuments.
  • 6.
  • 7. Weather conditions can affect the amount of pollution in the air:  Wind  Temperature  Airpressure  Cloud cover  Fog, dew and frost  Precipitation (rain, snow, hail)
  • 8.  1. I think air pollution is getting worse  2. Photochemical smog occurs where there is lots of sunlight and high temps.  3. The main component of smog is ozone  4. Jogging on high smog days harms your health  5. Wood-heaters add fine particles to the air  6. Air quality could be improved if more people used public transport.
  • 9.  Larger particles in the air are readily washed out in light rain. Fine and ultra fine particles require moderate to heavy rain to be washed to the ground.  It should be noted that pollutant gases are generally not affected by light rain. However, nitrogen dioxide dissolves in water and is washed to the ground. Rainfall measurements will also be helpful in interpreting other air pollution measurements.  For example, if there was exposed soil, windy days would cause much of this to be blown into the atmosphere and raise particulate (PM) readings. However, if there had been rain in the previous 48 hours, the soil may well stay put and hence, particulate readings would be lower.
  • 10.
  • 11.  Name as many as you can think of in the chat window.
  • 12.  Carbon monoxide and CO2  Nitrogen oxides (esp. NO2)  CFC’s  Volatile Organic Compounds  Ammonia  Odours  Particulate matter  Pollen, dust-mites and other allergens  Radioactive compounds  Oxides of Sulphur (esp. SO2)
  • 13. It has been estimated that there were more dioxins released into the atmosphere from the fireworks in Sydney for the commencement of the year 2000 than was released for the entire year from industrial sources. If this is so, why is there such a focus on industry, rather than other sources for controlling dioxins?
  • 14.  CO is a colourless, odourless, non- irritating but very poisonous gas.  It is a product by incomplete combustion of fuel such as natural gas, coal or wood.  Vehicular exhaust is a major source of carbon monoxide.
  • 15.  CO2 is a colourless, odourless, non-toxic greenhouse gas associated with ocean acidification, emitted from sources such as combustion of fossil fuels, cement production and respiration.
  • 16. NOx, especially nitrogen dioxide, are emitted from high temperature combustion. They can be seen as the brown haze dome above or plume downwind of cities.  Nitrogen dioxide is a reddish- brown toxic gas with a characteristic sharp, biting odour. NO2 is one of the most prominent air pollutants, causing respiratory illnesses and reducing ventilation (air getting to the lungs), especially in young children, the elderly and those with respiratory illnesses.
  • 17. NO2 is also a precursor to summer smog, which is fast becoming a major problem in our cities. The NO2 in the atmosphere reacts with oxygen (O2) in the air when it is sunny and the temperatures are high to form ozone (O3) — the major component of summer smog.  Summer smog causes eye, nose and throat irritation, damages the respiratory tract and increases our sensitivity to allergens.  These oxides of nitrogen are removed from the air by rain, by plants and by contact with surfaces.
  • 18.  Chloroflourocarbons (CFCs) are harmful to the ozone layer  They are emitted from old aerosol cans and refrigeration units.  Banned from use since 1989.
  • 19.  VOCs include methane and other hydrocarbons, such as benzene, toluene and xylene.  VOCs are significant greenhouse gases via their role in creating ozone and in prolonging the life of methane in the atmosphere.  VOC’s are suspected carcinogens and may lead to leukemia through prolonged exposure.
  • 20.  Ammonia is emitted from agricultural processes and is normally encountered as a gas with a characteristic pungent odour.  Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to foodstuffs and fertilizers.  Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceuticals. Although in wide use, ammonia is both caustic and hazardous
  • 21.  Odours are also classified as air pollutants and can originate from:  Garbage and landfills  Sewage and treatment plants  Industrial processes (milk and cheese processing for example)  Dairies, sheep-yards, saleyards, zoos and abattoirs
  • 22. Particulates, alternatively referred to as particulate matter (PM) or fine particles, are tiny particles of solid or liquid suspended in a gas.  In contrast, aerosol refers to particles and the gas together. Sources of particulate matter can be man made or natural.  Some particulates occur naturally, originating from volcanoes, dust storms, forest and grassland fires, living vegetation, and sea spray.  “Dirty Little Secrets” from ABC Catalyst is about the effects of PM on human health. http://www.abc.net.au/catalyst/stori es/s1630007.htm
  • 23.  Indoor particulate matter can include dust, smoke, pollen, animal dander, tobacco smoke, particles generated from combustion appliances such as cooking stoves, and particles associated with tiny organisms such as dust mites, moulds, bacteria, and viruses.  Outdoors, the anthropogenic sources of particulate matter can be vehicle exhausts, industrial processes, wood heaters, fuel- reduction burning and power generation.
  • 25. Human activities, such as the burning of fossil fuels in vehicles, power plants and various industrial processes also generate significant amounts of aerosols.  Averaged over the globe, anthropogenic aerosols—those made by human activities— currently account for about 10 percent of the total amount of aerosols in our atmosphere.  Increased levels of fine particles in the air are linked to health hazards such as heart disease, altered lung function and lung cancer.
  • 26. The increased rates of allergy and asthma in city environments and in those living close to highways has drawn attention to the role of outdoor pollution.  Common air pollutants, such as ozone, sulfur dioxide, and nitrogen dioxide probably act more as irritants than as promoters of sensitization.  These pollutants have been shown to be hazardous to adults and children with asthma. Recent studies suggest that prematurely born children are more sensitive to the respiratory effects of outdoor pollution.  There may also be an association with diesel exhaust particles and the worldwide increase in respiratory allergies. Diesel exhaust has been shown to enhance the ability to make the allergy antibody, IgE, in response to exposure to allergens.
  • 27. Indoor air pollution is among the top five environmental health risks.* Gaseous pollutants can be released from furnishings and from adhesives, paints, varnishes, cleaning products and pesticides, all of which contribute to poor indoor air quality. Pollen, dust-mite faeces, skin flakes, pet dander, tobacco smoke and other allergens can be reduced by regular cleaning and adequate ventilation. *http://www.epa.gov/iaq/pubs/airclean.html
  • 28. Pollen is in the air seasonally, with the amount varying from one area to another, depending on the types of wind pollinating plants in the region and the weather conditions. For some people the amount of pollen in the air has a direct effect upon their health. Airborne pollen on its own, or in combination with fine particles in the air, can influence the incidence and severity of asthma and hayfever in the community.
  • 29. During and after rain (often thunderstorms) some grains of pollen burst, releasing the allergen containing starch granules. In Melbourne after rain, air samples have been shown to contain up to 50 times more starch granules than air sampled on a sunny day during the grass pollen season. The starch granules are small enough to be breathed in and can enter the bronchi (tubes to the lungs), where they may trigger allergic asthma.
  • 30.
  • 31.  Produced by nuclear explosions and damaged nuclear power plants, war explosives and natural processes such as the radioactive decay of radon.
  • 32.  Oxides of Sulphur, especially sulphur dioxide, a chemical compound with the formula SO2 are common pollutants of the air. SO2 is produced by volcanoes and in various industrial processes.  Since coal and petroleum often contain sulphur compounds, their combustion generates sulphfur dioxide. Further oxidation of SO2, usually in the presence of a catalyst such as NO2, forms H2SO4, and thus acid rain.
  • 33.  Sulphur dioxide (SO2) is a colourless gas that is similar in smell to a matchstick being struck.  As its name suggests it is a compound consisting of sulphur and oxygen, and has both natural and anthropogenic or man-made sources.  It has significant health and environmental effects, including the formation of acid rain and smog and influences global warming.
  • 34. Sulphur dioxide consists of one atom of sulphur bonded to two atoms of oxygen. It is a strong, acrid smelling, non-flammable gas.  It reacts in the atmosphere to form sulphur trioxide, and dissolves readily in water vapour, forming sulphuric acid. It can also attach to dust and soot particles in the atmosphere to form particulates.  From these reactions, a wide range of effects are possible, including the formation of pollutants that influence both human health and environmental processes.
  • 35. Sulphur dioxide is formed through a number of pathways, including the burning of sulphur in the presence of oxygen and the oxidation of hydrogen sulphide, commonly emitted from wetlands.  Natural sources include volcanoes, forest- fires, oceans and decaying plant matter. These outweigh anthropogenic sources, with volcanic activity producing about 20% of the global total.  In Australia, the two main anthropogenic sources are power stations and metal manufacturing, while smaller sources include home-heating, chemical production and transportation emissions.
  • 36.  Sulphur dioxide is a naturally occurring compound with a number of 'sinks' or areas that can absorb excess amounts thus reducing its abundance in the environment, such as the oceans, wetlands and lakes.
  • 37.  This phenomenon results when sulphur dioxide dissolves in moisture in the air, forming sulphur acids, which eventually fall to the surface of the earth as acid rain.  Acid rain directly attacks the protective coating of plants, acidifies lakes and soils which may result in the formation of substances that are toxic to plants and animals.
  • 38.  This has been a major problem in northern USA, Canada and Scandinavia, where forests have been severely damaged, but fortunately regulations are improving emission standards, and reducing the incidence of acid rain.  Coal mined in Australia is typically low in sulphur; therefore emissions are usually not a problem.  We also have large sinks (oceans) in the southern hemisphere which assists to reduce the effects.
  • 39.
  • 40. In addition to damaging living organisms, acid rain can have a severe effect on buildings made of marble or limestone. Commonly used in statues and older buildings, these materials slowly dissolve under acidic conditions leading to structural failure. This has been a significant problem in Europe with many old buildings made of marble and limestone.
  • 41. The presence of high levels of sulphur dioxide has a negative effect on human health and society.  Inhaled sulphur dioxide quickly dissolves with moisture on the lining of the lungs and nose, burning the mucous membranes. This is clear to anyone who accidentally inhales the smoke from a match being struck.  Chronic - or long-term - exposure to high levels of SO2 leads to breathing problems and respiratory illnesses such as asthma, bronchitis as well as heart disease.  Children tend to more vulnerable due to less developed lungs.
  • 42.
  • 43.
  • 44.
  • 45.
  • 46.
  • 47.
  • 48.
  • 49.  http://www.npi.gov.au/students/sulfur- dioxide.html  http://www.npi.gov.au/substances/sulfur- dioxide/index.html  http://en.wikipedia.org/wiki/Sulfur_dioxide  http://science.howstuffworks.com/natur e/climate-weather/atmospheric/acid- rain.htm