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Rate of reaction definition
Rate of reaction is the change in
concentration of any one reactant
or product in unit time
Monitoring the rate of production of
oxygen from hydrogen peroxide, using
manganese dioxide as catalyst

2

H2O2

MnO2

2

H2O

+

O2

Monitor the rate by measuring the volume of
oxygen evolved over time
Procedure

Record the volume of gas in the syringe every
10 s until there is no increase in the volume of gas
Procedure
How to start the Reaction and
stopwatch at the same time
Pull the thread
to tilt test tube,
and spill its
contents.
At the same
time start the
stopwatch
Graph Volume Oxygen

V
O
L
U
M
E
G
A
S
cm3

v Time

160
140
120
100
80
60
40
20

10

20

30

40

TIME sec

50

60

70

80

90
V
O
L
U
M
E
G
A
S
cm3

160
140
120
100
80
60
40
20

10

20

30

40

TIME sec

50

60

70

80

90
120cm3

V
O
L
U
M
E
G
A
S
cm3

160
140
120
100

What volume
of gas was
collected
after 30 s ?

80
60
40
20

10

20

30

40

TIME sec

50

60

70

80

90
When maximum
volume of oxygen
V
O
L
U
M
E
G
A
S
cm3

160

obtained

140
120

After what
time was
the reaction
finished ?

100
80
60
40
20

10

20

30

40

TIME sec

50

60

70

80

90
When half maximum
volume of oxygen
V
O
L
U
M
E
G
A
S
cm3

obtained

160
140
120

When was
the reaction
half finished
?

100
80
60
40
20

10

20

30

40

TIME sec

50

60

70

80

90
V
O
L
U
M
E
G
A
S
cm3

160

Y2=150

140
120

What was the
Rate= Y2-Y1
instanteous
X2-X
rate at 30 s ? 1

100

Y1=95

80

Rate= 1.375 cm3/sec
55
150-95
40
50-10

60
40
20

10

X1=10

20

30

40

50

X2=50

60

TIME

70

80

90
V
O
L
U
M
E
G
A
S
cm3

160
140
120
100

How would the
graph change if
the solution as
more
concentrated ?

80
60
40
20

10

20

30

40

50

60

70

TIME sec

80

90
V
O
L
U
M
E
G
A
S
cm3

160
140
120
100

How would the
graph change if
the temperature
was higher ?

80
60
40
20

30

TIME

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6.1 reaction rates