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FIRE PREVENTION
Understanding Its Causes
THE FIRE TRIANGLE
For a fire to start three conditions must be
met at the same time:
FUEL

OXIDIZER

IGNITION
2
THE FIRE TRIANGLE



Fuels are materials that burn
The higher the temperature, the easier and
quicker they burn
Common fuels include:
-- Solvents such as acetone, alcohols, and
toluene
-- Gases such as acetylene and propane
-- Solids such as wood and paper
3
THE FIRE TRIANGLE




Oxidizers: Oxygen or other substances
capable of releasing oxygen to a fire
Common oxidizers include:




acids, especially nitric and perchloric acids
chlorine dioxide
Others such as potassium permanganate
and potassium chlorate
4
THE FIRE TRIANGLE


An ignition source can be:







A Spark
Static electricity
Arcs from electrical equipment, faulty or
otherwise
A lit cigarette
A hot light bulb
5
THE FIRE TRIANGLE


Fire prevention consists of making sure

that the three legs of the fire triangle
never meet
FUEL

OXIDIZER

IGNITION
6
FIRE PROPAGATION


Recent studies indicate that the spread
or propagation of a fire is also
dependent on a fourth factor - the
chemical chain reactions that can occur
as a result of heat produced by the fire.

7
FLAMABLE CONDITIONS




A fire will not always start when the
legs of the fire triangle meet, unless all
three elements are present in the
required amounts
For example, vapors from a flammable
liquid must be mixed with a certain
amount of air in order to ignite and
propagate a flame
8
FLAMMABLE RANGE


Lower Flammable Limit: The lowest
concentration at which a fuel/air mixture
will burn. Below this there is too little fuel
(the mixture is too lean)



Upper Flammable Limit: The highest
concentration at which a fuel/air mixture
will burn. Above this there is not enough
oxygen (the mixture is too rich)
9
FLASH POINT


The lowest temperature at which
sufficient vapors form above the liquid
to produce an ignitable mixture with air

10
FLAMMABILITY RANGE


The Department of Transportation
classifies liquids for transportation
regulation purposes




Flammables: All liquids with a flash point
below 100 degrees Fahrenheit
Combustibles: All liquids with a flash
point above 100 degrees Fahrenheit
11
FLAMMABLE GASES &
SOLIDS








Gas cylinders such as acetylene welding
gas need to be properly stored and used
Solids such as paper, wood, and cloth
need to be treated as potential fuels
Rags or paper soaked with flammable
liquids need to properly handled and
disposed
Metals that burn (pyrophorics) are
especially dangerous
12
STORAGE & HANDLING


Since it is impossible to eliminate
oxygen from the fire triangle, fire
prevention depends on trying to:



Eliminate sources of ignition
Restrict the amount of flammable and
combustible liquids

13
STORAGE & HANDLING









Eliminate sources of ignition
Choose the least hazardous materials
possible
Reduce the amounts stored to a
minimum
Use safe storage procedures and
containers
Ensure containers are properly labeled
14
CONTAINER LABELING
Flammable liquids should have a label
such as this:
DANGER
FLAMMABLE
KEEP AWAY FROM HEAT, SPARKS &
OPEN FLAMES
KEEP CLOSED WHEN NOT IN USE
15
NFPA LABELING SYSTEM

16
MATERIAL SAFETY DATA
SHEETS (MSDS)







Information regarding fire prevention
and fire extinguishing
Safe storage and handling procedures
Spill clean-up procedures
Proper labeling
Use to compare products for hazards
such as flash point and flammability
range
17
STORAGE AMOUNTS
Local and state fire codes limit the
amounts of flammable and combustible
liquids that can be stored in various
locations

CHECK WITH YOUR LOCAL FIRE
DEPARTMENT
18
STORAGE AREAS




Best location to store large amounts of
flammable and combustible liquids is a
separate outside building
If this is not possible, then a suitable
flammable storage cabinet or inside
storage room should be built

19
FLAMMABLE STOREAGE
CABINETS








Built to meet OSHA and NFPA
standards
Labeled in large letters:
FLAMMABLE-- KEEP FIRE AWAY
Maximum of 120 gallons of Class I, II,
and III A liquids (60 gallons of Classes I
and II)
Maximum of three cabinets may be
20
located in a given fire area
STORAGE CONTAINERS




Quantities of flammable liquids
exceeding one pint should be stored in
approved portable safety cans
In instructional laboratories the largest
container size for flammable liquids is
one gallon (or a two gallon safety can)

21
STORAGE DRUMS




55 gallon drums should only be stored
in a separate storage area away from
heat and sunlight.
The maximum size of drum that should
be stored indoors is 5 gallons

22
INSIDE STORAGE ROOMS










Requirements found in NFPA 30
(Flammable & Combustible Liquids Code)
Fire resistance rating of 2 hours for walls,
floor, and ceiling
Class B fire doors
Automatic fire protection systems
Mechanical ventilation depending on the
amount stored
Class I-Division 2 electrical wiring and
fixtures
23
DISPENSING




When dispensing from drums, use
approved transfer pumps or drum
faucets
When pouring flammable liquids from a
drum to a metal container, ground the
drum and bond the metal container to
the drum to prevent the build-up of any
static charge
24
SPILLS AND LEAKS








Spills must be quickly and safely cleaned up
to prevent flammable vapors from igniting
A sufficient quantity of absorbent material should
be kept on hand
Treat spill clean-up materials as flammable and
dispose of separately from the regular trash
Large spills of flammable liquids (more than one
quart) need special cleanup procedures
25
FIRE FIGHTING
Four Basic Types of Fires
 Class A -- Common Solids
 Class B -- Flammable Liquids
 Class C -- Electrical Equipment
 Class D -- Burning Metals

26
FIRE EXTINGUISHERS








Class A Types -- Water based for areas
containing ordinary combustibles
Class ABC Multipurpose Dry Chemical -Displaces oxygen and smothers the flame
Class ABC Halon 1211 -- Inhibits chain
reactions of a fire
Class BC -- Carbon Dioxide displaces air
and cuts off the oxygen supply
27
Automatic Sprinkler Systems




Water -- Sprays a mist when activated
by the heat of a fire
Halon -- Sprays a halogenated
chemical onto the fire. Halons
decompose to toxic gases when
heated. Use must be carefully planned.

28
OSHA REQUIRED
PROCEDURES FOR FIGHTING
FIRES


OSHA regulations allow for three
situations:







Total evacuation in case of fire alarm
Partial evacuation with some employees
allowed
to use fire extinguishers
All employees allowed to use fire
extinguishers

OSHA specifies training requirements if
any employees are allowed to use fire
extinguishers
29
USING FIRE
EXTINGUISHERS








If you think you can handle the fire, sound the
fire alarm to set the emergency plan in
operation
Grab the closet fire extinguisher that
conforms to the type of fire
Activate the fire extinguisher and follow the
directions for use
If at any time you feel overwhelmed, or the
extinguisher charge runs out, leave the area
and wait for the professional fire fighters
30
INTEGRITY OF EQUIPMENT






Fire fighting equipment must be well
maintained and checked periodically for
pressure and integrity
Fire extinguishers must be placed
prominently according to OSHA regulations
Fire suppression equipment, such as
sprinkler systems, must also meet the
appropriate OSHA and NFPA standards
31
REMEMBER !
Fire Prevention Is
Everyone’s
Responsibility

32

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Fire Prevention Training by Oklahoma State Regents for Higher Education

  • 2. THE FIRE TRIANGLE For a fire to start three conditions must be met at the same time: FUEL OXIDIZER IGNITION 2
  • 3. THE FIRE TRIANGLE   Fuels are materials that burn The higher the temperature, the easier and quicker they burn Common fuels include: -- Solvents such as acetone, alcohols, and toluene -- Gases such as acetylene and propane -- Solids such as wood and paper 3
  • 4. THE FIRE TRIANGLE   Oxidizers: Oxygen or other substances capable of releasing oxygen to a fire Common oxidizers include:    acids, especially nitric and perchloric acids chlorine dioxide Others such as potassium permanganate and potassium chlorate 4
  • 5. THE FIRE TRIANGLE  An ignition source can be:      A Spark Static electricity Arcs from electrical equipment, faulty or otherwise A lit cigarette A hot light bulb 5
  • 6. THE FIRE TRIANGLE  Fire prevention consists of making sure that the three legs of the fire triangle never meet FUEL OXIDIZER IGNITION 6
  • 7. FIRE PROPAGATION  Recent studies indicate that the spread or propagation of a fire is also dependent on a fourth factor - the chemical chain reactions that can occur as a result of heat produced by the fire. 7
  • 8. FLAMABLE CONDITIONS   A fire will not always start when the legs of the fire triangle meet, unless all three elements are present in the required amounts For example, vapors from a flammable liquid must be mixed with a certain amount of air in order to ignite and propagate a flame 8
  • 9. FLAMMABLE RANGE  Lower Flammable Limit: The lowest concentration at which a fuel/air mixture will burn. Below this there is too little fuel (the mixture is too lean)  Upper Flammable Limit: The highest concentration at which a fuel/air mixture will burn. Above this there is not enough oxygen (the mixture is too rich) 9
  • 10. FLASH POINT  The lowest temperature at which sufficient vapors form above the liquid to produce an ignitable mixture with air 10
  • 11. FLAMMABILITY RANGE  The Department of Transportation classifies liquids for transportation regulation purposes   Flammables: All liquids with a flash point below 100 degrees Fahrenheit Combustibles: All liquids with a flash point above 100 degrees Fahrenheit 11
  • 12. FLAMMABLE GASES & SOLIDS     Gas cylinders such as acetylene welding gas need to be properly stored and used Solids such as paper, wood, and cloth need to be treated as potential fuels Rags or paper soaked with flammable liquids need to properly handled and disposed Metals that burn (pyrophorics) are especially dangerous 12
  • 13. STORAGE & HANDLING  Since it is impossible to eliminate oxygen from the fire triangle, fire prevention depends on trying to:   Eliminate sources of ignition Restrict the amount of flammable and combustible liquids 13
  • 14. STORAGE & HANDLING      Eliminate sources of ignition Choose the least hazardous materials possible Reduce the amounts stored to a minimum Use safe storage procedures and containers Ensure containers are properly labeled 14
  • 15. CONTAINER LABELING Flammable liquids should have a label such as this: DANGER FLAMMABLE KEEP AWAY FROM HEAT, SPARKS & OPEN FLAMES KEEP CLOSED WHEN NOT IN USE 15
  • 17. MATERIAL SAFETY DATA SHEETS (MSDS)      Information regarding fire prevention and fire extinguishing Safe storage and handling procedures Spill clean-up procedures Proper labeling Use to compare products for hazards such as flash point and flammability range 17
  • 18. STORAGE AMOUNTS Local and state fire codes limit the amounts of flammable and combustible liquids that can be stored in various locations CHECK WITH YOUR LOCAL FIRE DEPARTMENT 18
  • 19. STORAGE AREAS   Best location to store large amounts of flammable and combustible liquids is a separate outside building If this is not possible, then a suitable flammable storage cabinet or inside storage room should be built 19
  • 20. FLAMMABLE STOREAGE CABINETS     Built to meet OSHA and NFPA standards Labeled in large letters: FLAMMABLE-- KEEP FIRE AWAY Maximum of 120 gallons of Class I, II, and III A liquids (60 gallons of Classes I and II) Maximum of three cabinets may be 20 located in a given fire area
  • 21. STORAGE CONTAINERS   Quantities of flammable liquids exceeding one pint should be stored in approved portable safety cans In instructional laboratories the largest container size for flammable liquids is one gallon (or a two gallon safety can) 21
  • 22. STORAGE DRUMS   55 gallon drums should only be stored in a separate storage area away from heat and sunlight. The maximum size of drum that should be stored indoors is 5 gallons 22
  • 23. INSIDE STORAGE ROOMS       Requirements found in NFPA 30 (Flammable & Combustible Liquids Code) Fire resistance rating of 2 hours for walls, floor, and ceiling Class B fire doors Automatic fire protection systems Mechanical ventilation depending on the amount stored Class I-Division 2 electrical wiring and fixtures 23
  • 24. DISPENSING   When dispensing from drums, use approved transfer pumps or drum faucets When pouring flammable liquids from a drum to a metal container, ground the drum and bond the metal container to the drum to prevent the build-up of any static charge 24
  • 25. SPILLS AND LEAKS     Spills must be quickly and safely cleaned up to prevent flammable vapors from igniting A sufficient quantity of absorbent material should be kept on hand Treat spill clean-up materials as flammable and dispose of separately from the regular trash Large spills of flammable liquids (more than one quart) need special cleanup procedures 25
  • 26. FIRE FIGHTING Four Basic Types of Fires  Class A -- Common Solids  Class B -- Flammable Liquids  Class C -- Electrical Equipment  Class D -- Burning Metals 26
  • 27. FIRE EXTINGUISHERS     Class A Types -- Water based for areas containing ordinary combustibles Class ABC Multipurpose Dry Chemical -Displaces oxygen and smothers the flame Class ABC Halon 1211 -- Inhibits chain reactions of a fire Class BC -- Carbon Dioxide displaces air and cuts off the oxygen supply 27
  • 28. Automatic Sprinkler Systems   Water -- Sprays a mist when activated by the heat of a fire Halon -- Sprays a halogenated chemical onto the fire. Halons decompose to toxic gases when heated. Use must be carefully planned. 28
  • 29. OSHA REQUIRED PROCEDURES FOR FIGHTING FIRES  OSHA regulations allow for three situations:     Total evacuation in case of fire alarm Partial evacuation with some employees allowed to use fire extinguishers All employees allowed to use fire extinguishers OSHA specifies training requirements if any employees are allowed to use fire extinguishers 29
  • 30. USING FIRE EXTINGUISHERS     If you think you can handle the fire, sound the fire alarm to set the emergency plan in operation Grab the closet fire extinguisher that conforms to the type of fire Activate the fire extinguisher and follow the directions for use If at any time you feel overwhelmed, or the extinguisher charge runs out, leave the area and wait for the professional fire fighters 30
  • 31. INTEGRITY OF EQUIPMENT    Fire fighting equipment must be well maintained and checked periodically for pressure and integrity Fire extinguishers must be placed prominently according to OSHA regulations Fire suppression equipment, such as sprinkler systems, must also meet the appropriate OSHA and NFPA standards 31
  • 32. REMEMBER ! Fire Prevention Is Everyone’s Responsibility 32