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CHEMISTRY

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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
International General Certificate of Secondary Education

0620/22

Paper 2

October/November 2010
1 hour 15 minutes

Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name in the spaces at the top of this page.
Write in dark blue or black pen.
You may need to use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
A copy of the Periodic Table is printed on page 16.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
question.

For Examiner’s Use
1
2
3
4
5
6
7
Total

This document consists of 15 printed pages and 1 blank page.
IB10 11_0620_22/4RP
© UCLES 2010

[Turn over
2
1

For
Examiner’s
Use

Choose from the following list of oxides to answer the questions below.
You can use each oxide once, more than once or not at all.
carbon dioxide
carbon monoxide
magnesium oxide
nitrogen dioxide
sulfur dioxide
water
(a) Which one of these oxides is a basic oxide?
..................................................................................................................................... [1]

(b) Which two oxides cause acid rain?
......................................................... and .........................................................

[2]

(c) Which two oxides are formed when a hydrocarbon undergoes complete combustion?
......................................................... and .........................................................

[2]

(d) Which one of these oxides turns white copper(II) sulfate blue?
..................................................................................................................................... [1]

(e) Which oxide is formed when calcium carbonate undergoes thermal decomposition?
..................................................................................................................................... [1]
[Total: 7]

© UCLES 2010

0620/22/O/N/10
3
2

For
Examiner’s
Use

The diagram shows the structure of some compounds containing iodine.
A

B

Cl

Cl

Cl

I–

Na+

I–

I–

Na+

I–

I–

Na+

I–

O

Na+

Na+

I

D

C

Na+

H

I

O

I

O

I
O

O

(a) (i) What do you understand by the term compound ?
....................................................................................................................................
.............................................................................................................................. [1]
(ii) Which one of these compounds, A, B, C or D, has a high melting point?
Explain your answer.
compound ..................................................................................................................
explanation .......................................................................................................... [2]
(iii) Which one of these compounds is similar in structure to hydrogen chloride?
.............................................................................................................................. [1]

(b) Compound B is sodium iodide.
(i) Which statement about the electrical conductivity of sodium iodide is correct?
Tick one box.
It conducts electricity when molten.
It conducts electricity when solid.
It does not conduct electricity when molten.
It does not conduct electricity in aqueous solution.
[1]
(ii) Describe a test for iodide ions.
test .............................................................................................................................
result .................................................................................................................... [2]

(c) Compound D is iodine(V) oxide. It is an acidic oxide.
Suggest why iodine(V) oxide is an acidic oxide.
..................................................................................................................................... [1]
[Total: 8]

© UCLES 2010

0620/22/O/N/10

[Turn over
4
3

For
Examiner’s
Use

Some properties of the Group I elements are given in the table.
melting point
/ °C

boiling point
/ °C

density
in g / cm3

lithium

181

1342

0.53

sodium

98

883

0.97

potassium

63

rubidium

39

686

1.53

caesium

29

669

1.88

element

0.86

(a) (i) Predict the boiling point of potassium.
.............................................................................................................................. [1]
(ii) Which Group I elements are liquids at 50 °C?
.............................................................................................................................. [2]
(iii) How, in general, does the density of the Group I elements change down the group?
.............................................................................................................................. [1]
(b) Complete the following sentences about the Group I elements using words from the list
below.
crystallising

decreases

melting

hard

similarity

increases
soft

The Group I elements are relatively ............................. metals which show a trend in
............................. point and reaction with water.
The reactivity with water ............................. down the group.

[3]

(c) The equation for the reaction of sodium with water is given below.
2Na + 2H2O → 2NaOH + H2
Write a word equation for this reaction.

[2]

© UCLES 2010

0620/22/O/N/10
5
For
Examiner’s
Use

(d) Chlorine reacts with sodium to form sodium chloride.
(i) Complete the equation for this reaction.
...............Na + Cl 2 → ...............NaCl
[2]
(ii) Chlorine is a diatomic gas.
What do you understand by the term diatomic ?
.............................................................................................................................. [1]
(iii) Describe the arrangement and motion of the molecules in chlorine gas.
arrangement ..............................................................................................................
motion .................................................................................................................. [2]
(iv) Draw a diagram to show the arrangement of the electrons in a molecule of
chlorine.
Show only the outer electrons.

[2]
[Total: 16]

© UCLES 2010

0620/22/O/N/10

[Turn over
6
4

For
Examiner’s
Use

The formulae of four organic compounds are shown below.
A

B

H

H

H
C

H

C

H

H

C
H

C
H

C

H
H

H

C

C

H

O

O

D
H

H

H

H

H

C

C

H

H

O

H

(a) (i) State the name of the type of bonding between the atoms in these four
compounds.
.............................................................................................................................. [1]
(ii) Which one of these compounds, A, B, C or D, is a saturated hydrocarbon?
.............................................................................................................................. [1]
(iii) Which one of these compounds is acidic?
.............................................................................................................................. [1]
(iv) State the name of compound D.
.............................................................................................................................. [1]
(v) Compound A contains a C=C double bond.
Describe a test for a C=C double bond.
test .............................................................................................................................
result .................................................................................................................... [2]

(b) Compound C is a member of the alkane homologous series.
(i) State two features of an homologous series.
1. ................................................................................................................................
2. ............................................................................................................................[2]
(ii) State the formula and name of another alkane in the same homologous series as
compound C.

formula

name .................................................................................................................... [2]

© UCLES 2010

0620/22/O/N/10
7
For
Examiner’s
Use

(c) The alkanes present in petroleum can be separated by fractional distillation.
The diagram below shows a fractional distillation column.

(i) On the diagram, label where the temperature in the column is the lowest.
Mark this with the letter X.

[1]

(ii) On the diagram, label where the bitumen fraction is collected.
Mark this with the letter Y.

[1]
[Total: 12]

© UCLES 2010

0620/22/O/N/10

[Turn over
8
5

A student used the apparatus shown below to investigate the speed of reaction when large
lumps of zinc reacted with excess sulfuric acid.
zinc + sulfuric acid → zinc sulfate + hydrogen

gas syringe
sulfuric acid

zinc
(a) As the reaction proceeds, describe what happens to
(i) the mass of the zinc lumps.
.............................................................................................................................. [1]
(ii) the concentration of zinc sulfate in the solution in the flask.
.............................................................................................................................. [1]

© UCLES 2010

0620/22/O/N/10

For
Examiner’s
Use
9
For
Examiner’s
Use

(b) The student’s results are shown below.
time / minutes

0

10

20

30

40

50

60

volume of hydrogen / cm3

0

24

39

48

53

55

55

(i) Plot a graph of volume of hydrogen against time. Use the axes below.
60

50

40

volume of
hydrogen 30
/ cm3

20

10

0
0

10

20

30

40

50

60

time / minutes
[3]
(ii) Use your graph to calculate the volume of hydrogen given off after 25 minutes.
volume of hydrogen ............................................................................................. [1]
(iii) Explain why no more hydrogen was given off after 50 minutes.
.............................................................................................................................. [1]
(iv) Describe a test for hydrogen.
test .............................................................................................................................
result .................................................................................................................... [2]

© UCLES 2010

0620/22/O/N/10

[Turn over
10
For
Examiner’s
Use

(c) What happens to the speed of the reaction when
(i) smaller pieces of zinc are used?
.............................................................................................................................. [1]
(ii) some water is added to the sulfuric acid?
.............................................................................................................................. [1]

(d) The reaction between zinc and sulfuric acid is catalysed by copper(II) sulfate solution.
What do you understand by the term catalyst ?
..................................................................................................................................... [1]
[Total: 12]

© UCLES 2010

0620/22/O/N/10
11
6

For
Examiner’s
Use

Iron is a transition element.
(a) State three properties of transition elements which are not shown by the Group I
elements.
1. .......................................................................................................................................
2. .......................................................................................................................................
3. ................................................................................................................................. [3]

(b) The symbols for two isotopes of iron are shown below.
54
26 Fe

57
26 Fe

(i) How do these two isotopes differ in their atomic structure?
.............................................................................................................................. [1]
(ii) State the number of nucleons present in one atom of the isotope

57
26 Fe

.

.............................................................................................................................. [1]
54

(iii) How many electrons are there in one atom of the isotope 26 Fe ?
.............................................................................................................................. [1]

(c) Pure iron rusts very easily.
(i) State the two conditions that are needed for rusting to take place.
1. ................................................................................................................................
2. .......................................................................................................................... [2]
(ii) Describe and explain one method of preventing rusting.
method .......................................................................................................................
explain why this method works ..................................................................................
.............................................................................................................................. [2]

© UCLES 2010

0620/22/O/N/10

[Turn over
12
For
Examiner’s
Use

(d) In the blast furnace, iron(III) oxide reacts with carbon monoxide.
Fe2O3 + 3CO → 2Fe + 3CO2
Which substance gets reduced in this reaction?
Explain your answer.
substance .........................................................................................................................
explanation .......................................................................................................................
..................................................................................................................................... [2]

(e) (i) Carbon monoxide is a pollutant gas produced in motor car engines.
Explain why carbon monoxide is formed.
.............................................................................................................................. [1]
(ii) State one harmful effect of carbon monoxide.
.............................................................................................................................. [1]
[Total: 14]

© UCLES 2010

0620/22/O/N/10
13
7

Boric acid is an acid. Urea is a base. Both compounds are crystalline.
A student placed some crystals of boric acid and urea in a large beaker of water. The pH
value of the water at the start of the experiment was pH 7.

For
Examiner’s
Use

water
A

B

boric acid

urea

(a) After 15 minutes the pH at point A in the beaker was pH 6.2.
(i) Suggest why the pH at point A had decreased.
.............................................................................................................................. [1]
(ii) What was the most likely pH at point B in the beaker after 15 minutes?
Put a ring around the correct answer.
pH 1

pH 6

pH 7

pH 8

[1]

(iii) The particles of boric acid and urea diffuse throughout the solution.
What do you understand by the term diffusion ?
....................................................................................................................................
.............................................................................................................................. [1]

(iv) After 24 hours the pH throughout the whole solution was pH 7.
Use your knowledge of acids and alkalis to explain why the pH returned to pH 7.
....................................................................................................................................
.............................................................................................................................. [1]

(b) The structure of urea is shown below.
H 2N

C

NH2

O
(i) Write the simplest formula for urea.

[1]

© UCLES 2010

0620/22/O/N/10

[Turn over
14
For
Examiner’s
Use

(ii) Calculate the relative molecular mass of urea.
Use your Periodic Table to help you.

[1]

(c) Urea is used as a fertiliser.
(i) Which element present in urea is an essential part of most fertilisers?
.............................................................................................................................. [1]
(ii) Explain why farmers put fertilisers on their fields.
....................................................................................................................................
.............................................................................................................................. [2]

(d) Describe how you can obtain pure, dry crystals of urea from an aqueous solution of
urea.
...........................................................................................................................................
...........................................................................................................................................
..................................................................................................................................... [2]
[Total: 11]

© UCLES 2010

0620/22/O/N/10
15
BLANK PAGE

© UCLES 2010

0620/22/O/N/10
© UCLES 2010

24

40

Sodium

Calcium

88

0620/22/O/N/10

89

Key

b

X

a

72

b = proton (atomic) number

X = atomic symbol

a = relative atomic mass

*58-71 Lanthanoid series
90-103 Actinoid series

88

Ac

Actinium

Ra

Radium

Fr

Francium

87

*

Hafnium

Lanthanum

57

Hf

La

40

Zirconium

Zr

91

Titanium

178

Yttrium

22

48

Ti

139

39

Y

89

Scandium

21

227

Caesium

56

Barium

Cs

45

Sc

226

55

137

Ba

133

Strontium

Rubidium

38

Rb

37

Sr

85

20

Potassium

19

Ca

39

Magnesium

Na

12

Mg

23

Beryllium

4

Lithium

K

11

3

9

Be

7

II

Li

I

93

Ta

181

Niobium

Nb

90

58

73

52

96

Mo

W

184

141

Pa

Thorium

55

Tc
186

Re

144

Nd

92

60

Uranium

U

238

Neodymium

75

Rhenium

43

Technetium

25

Manganese

Mn
29

30

65

8

9

VII

2

0

Ru

101

Iron

190

Pm

Osmium

Os

93

Np
Neptunium

61

Promethium

76

44

Ruthenium

26

56

Fe

Sm

150

Iridium

94

Pu
Plutonium

62

Eu

152

Platinum

95

Am
Americium

63

Europium

78

195

Pt

192

46

Palladium

Pd

106

Nickel

Ni

Ir

Samarium

77

45

Rhodium

Rh

103

Cobalt

Co

Gd

157

Gold

Au

197

Silver

96

64

Curium

Cm

Gadolinium

79

47

Ag

108

Copper

Cu

201

Bk

Terbium

Tb

159

Mercury

Hg

97

Berkelium

65

80

48

Cadmium

Cd

112

Zinc

Zn

11

70

Dy

162

Thallium

Tl

204

Indium

98

Cf
Californium

66

Es

Holmium

Ho

165

Lead

Pb

207

Tin

99

Einsteinium

67

82

50

119

Sn

In

32

Germanium

Ge

73

Silicon

115

Gallium

Ga

Dysprosium

81

49

31

13

Aluminium

Si

Al
14

28

Carbon

27

Boron

12

C

14

75

Sb

122

Arsenic

As

Bi

209

Fermium

Fm

Erbium

Er

167

Bismuth

100

68

83

51

Antimony

33

15

Phosphorus

P

31

Nitrogen

N

Se

79

Sulfur

S

32

Oxygen

Po

169

Md

Thulium

Tm

101

Mendelevium

69

84

Polonium

52

Tellurium

Te

128

Selenium

34

16

16

O

Yb

173

Astatine

At

Iodine

I

127

Bromine

Br

80

Chlorine

No
102

Nobelium

70

Ytterbium

85

53

35

17

Cl

35.5

Fluorine

F

19

Lr

Lutetium

Lu

175

Radon

Rn

Xenon

Xe

131

Krypton

Kr

84

Argon

Ar

40

Neon

103

Lawrencium

71

86

54

36

18

10

Ne

20

Helium

Hydrogen

B

4

28

64

7

VI

He

27

59

6

V

H

59

5

IV

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

91

Protactinium

Th

232

Praseodymium

Cerium

59

Pr

Ce

74

Tungsten

42

Molybdenum

24

Chromium

Cr

140

Tantalum

41

23

Vanadium

V

51

1

III
1

Group

DATA SHEET
The Periodic Table of the Elements

16

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included the
publisher will be pleased to make amends at the earliest possible opportunity.

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

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0620 14

  • 1. w w om .c s er *5310008024* CHEMISTRY ap eP m e tr .X w UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education 0620/22 Paper 2 October/November 2010 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name in the spaces at the top of this page. Write in dark blue or black pen. You may need to use a pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fluid. DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part question. For Examiner’s Use 1 2 3 4 5 6 7 Total This document consists of 15 printed pages and 1 blank page. IB10 11_0620_22/4RP © UCLES 2010 [Turn over
  • 2. 2 1 For Examiner’s Use Choose from the following list of oxides to answer the questions below. You can use each oxide once, more than once or not at all. carbon dioxide carbon monoxide magnesium oxide nitrogen dioxide sulfur dioxide water (a) Which one of these oxides is a basic oxide? ..................................................................................................................................... [1] (b) Which two oxides cause acid rain? ......................................................... and ......................................................... [2] (c) Which two oxides are formed when a hydrocarbon undergoes complete combustion? ......................................................... and ......................................................... [2] (d) Which one of these oxides turns white copper(II) sulfate blue? ..................................................................................................................................... [1] (e) Which oxide is formed when calcium carbonate undergoes thermal decomposition? ..................................................................................................................................... [1] [Total: 7] © UCLES 2010 0620/22/O/N/10
  • 3. 3 2 For Examiner’s Use The diagram shows the structure of some compounds containing iodine. A B Cl Cl Cl I– Na+ I– I– Na+ I– I– Na+ I– O Na+ Na+ I D C Na+ H I O I O I O O (a) (i) What do you understand by the term compound ? .................................................................................................................................... .............................................................................................................................. [1] (ii) Which one of these compounds, A, B, C or D, has a high melting point? Explain your answer. compound .................................................................................................................. explanation .......................................................................................................... [2] (iii) Which one of these compounds is similar in structure to hydrogen chloride? .............................................................................................................................. [1] (b) Compound B is sodium iodide. (i) Which statement about the electrical conductivity of sodium iodide is correct? Tick one box. It conducts electricity when molten. It conducts electricity when solid. It does not conduct electricity when molten. It does not conduct electricity in aqueous solution. [1] (ii) Describe a test for iodide ions. test ............................................................................................................................. result .................................................................................................................... [2] (c) Compound D is iodine(V) oxide. It is an acidic oxide. Suggest why iodine(V) oxide is an acidic oxide. ..................................................................................................................................... [1] [Total: 8] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 4. 4 3 For Examiner’s Use Some properties of the Group I elements are given in the table. melting point / °C boiling point / °C density in g / cm3 lithium 181 1342 0.53 sodium 98 883 0.97 potassium 63 rubidium 39 686 1.53 caesium 29 669 1.88 element 0.86 (a) (i) Predict the boiling point of potassium. .............................................................................................................................. [1] (ii) Which Group I elements are liquids at 50 °C? .............................................................................................................................. [2] (iii) How, in general, does the density of the Group I elements change down the group? .............................................................................................................................. [1] (b) Complete the following sentences about the Group I elements using words from the list below. crystallising decreases melting hard similarity increases soft The Group I elements are relatively ............................. metals which show a trend in ............................. point and reaction with water. The reactivity with water ............................. down the group. [3] (c) The equation for the reaction of sodium with water is given below. 2Na + 2H2O → 2NaOH + H2 Write a word equation for this reaction. [2] © UCLES 2010 0620/22/O/N/10
  • 5. 5 For Examiner’s Use (d) Chlorine reacts with sodium to form sodium chloride. (i) Complete the equation for this reaction. ...............Na + Cl 2 → ...............NaCl [2] (ii) Chlorine is a diatomic gas. What do you understand by the term diatomic ? .............................................................................................................................. [1] (iii) Describe the arrangement and motion of the molecules in chlorine gas. arrangement .............................................................................................................. motion .................................................................................................................. [2] (iv) Draw a diagram to show the arrangement of the electrons in a molecule of chlorine. Show only the outer electrons. [2] [Total: 16] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 6. 6 4 For Examiner’s Use The formulae of four organic compounds are shown below. A B H H H C H C H H C H C H C H H H C C H O O D H H H H H C C H H O H (a) (i) State the name of the type of bonding between the atoms in these four compounds. .............................................................................................................................. [1] (ii) Which one of these compounds, A, B, C or D, is a saturated hydrocarbon? .............................................................................................................................. [1] (iii) Which one of these compounds is acidic? .............................................................................................................................. [1] (iv) State the name of compound D. .............................................................................................................................. [1] (v) Compound A contains a C=C double bond. Describe a test for a C=C double bond. test ............................................................................................................................. result .................................................................................................................... [2] (b) Compound C is a member of the alkane homologous series. (i) State two features of an homologous series. 1. ................................................................................................................................ 2. ............................................................................................................................[2] (ii) State the formula and name of another alkane in the same homologous series as compound C. formula name .................................................................................................................... [2] © UCLES 2010 0620/22/O/N/10
  • 7. 7 For Examiner’s Use (c) The alkanes present in petroleum can be separated by fractional distillation. The diagram below shows a fractional distillation column. (i) On the diagram, label where the temperature in the column is the lowest. Mark this with the letter X. [1] (ii) On the diagram, label where the bitumen fraction is collected. Mark this with the letter Y. [1] [Total: 12] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 8. 8 5 A student used the apparatus shown below to investigate the speed of reaction when large lumps of zinc reacted with excess sulfuric acid. zinc + sulfuric acid → zinc sulfate + hydrogen gas syringe sulfuric acid zinc (a) As the reaction proceeds, describe what happens to (i) the mass of the zinc lumps. .............................................................................................................................. [1] (ii) the concentration of zinc sulfate in the solution in the flask. .............................................................................................................................. [1] © UCLES 2010 0620/22/O/N/10 For Examiner’s Use
  • 9. 9 For Examiner’s Use (b) The student’s results are shown below. time / minutes 0 10 20 30 40 50 60 volume of hydrogen / cm3 0 24 39 48 53 55 55 (i) Plot a graph of volume of hydrogen against time. Use the axes below. 60 50 40 volume of hydrogen 30 / cm3 20 10 0 0 10 20 30 40 50 60 time / minutes [3] (ii) Use your graph to calculate the volume of hydrogen given off after 25 minutes. volume of hydrogen ............................................................................................. [1] (iii) Explain why no more hydrogen was given off after 50 minutes. .............................................................................................................................. [1] (iv) Describe a test for hydrogen. test ............................................................................................................................. result .................................................................................................................... [2] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 10. 10 For Examiner’s Use (c) What happens to the speed of the reaction when (i) smaller pieces of zinc are used? .............................................................................................................................. [1] (ii) some water is added to the sulfuric acid? .............................................................................................................................. [1] (d) The reaction between zinc and sulfuric acid is catalysed by copper(II) sulfate solution. What do you understand by the term catalyst ? ..................................................................................................................................... [1] [Total: 12] © UCLES 2010 0620/22/O/N/10
  • 11. 11 6 For Examiner’s Use Iron is a transition element. (a) State three properties of transition elements which are not shown by the Group I elements. 1. ....................................................................................................................................... 2. ....................................................................................................................................... 3. ................................................................................................................................. [3] (b) The symbols for two isotopes of iron are shown below. 54 26 Fe 57 26 Fe (i) How do these two isotopes differ in their atomic structure? .............................................................................................................................. [1] (ii) State the number of nucleons present in one atom of the isotope 57 26 Fe . .............................................................................................................................. [1] 54 (iii) How many electrons are there in one atom of the isotope 26 Fe ? .............................................................................................................................. [1] (c) Pure iron rusts very easily. (i) State the two conditions that are needed for rusting to take place. 1. ................................................................................................................................ 2. .......................................................................................................................... [2] (ii) Describe and explain one method of preventing rusting. method ....................................................................................................................... explain why this method works .................................................................................. .............................................................................................................................. [2] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 12. 12 For Examiner’s Use (d) In the blast furnace, iron(III) oxide reacts with carbon monoxide. Fe2O3 + 3CO → 2Fe + 3CO2 Which substance gets reduced in this reaction? Explain your answer. substance ......................................................................................................................... explanation ....................................................................................................................... ..................................................................................................................................... [2] (e) (i) Carbon monoxide is a pollutant gas produced in motor car engines. Explain why carbon monoxide is formed. .............................................................................................................................. [1] (ii) State one harmful effect of carbon monoxide. .............................................................................................................................. [1] [Total: 14] © UCLES 2010 0620/22/O/N/10
  • 13. 13 7 Boric acid is an acid. Urea is a base. Both compounds are crystalline. A student placed some crystals of boric acid and urea in a large beaker of water. The pH value of the water at the start of the experiment was pH 7. For Examiner’s Use water A B boric acid urea (a) After 15 minutes the pH at point A in the beaker was pH 6.2. (i) Suggest why the pH at point A had decreased. .............................................................................................................................. [1] (ii) What was the most likely pH at point B in the beaker after 15 minutes? Put a ring around the correct answer. pH 1 pH 6 pH 7 pH 8 [1] (iii) The particles of boric acid and urea diffuse throughout the solution. What do you understand by the term diffusion ? .................................................................................................................................... .............................................................................................................................. [1] (iv) After 24 hours the pH throughout the whole solution was pH 7. Use your knowledge of acids and alkalis to explain why the pH returned to pH 7. .................................................................................................................................... .............................................................................................................................. [1] (b) The structure of urea is shown below. H 2N C NH2 O (i) Write the simplest formula for urea. [1] © UCLES 2010 0620/22/O/N/10 [Turn over
  • 14. 14 For Examiner’s Use (ii) Calculate the relative molecular mass of urea. Use your Periodic Table to help you. [1] (c) Urea is used as a fertiliser. (i) Which element present in urea is an essential part of most fertilisers? .............................................................................................................................. [1] (ii) Explain why farmers put fertilisers on their fields. .................................................................................................................................... .............................................................................................................................. [2] (d) Describe how you can obtain pure, dry crystals of urea from an aqueous solution of urea. ........................................................................................................................................... ........................................................................................................................................... ..................................................................................................................................... [2] [Total: 11] © UCLES 2010 0620/22/O/N/10
  • 15. 15 BLANK PAGE © UCLES 2010 0620/22/O/N/10
  • 16. © UCLES 2010 24 40 Sodium Calcium 88 0620/22/O/N/10 89 Key b X a 72 b = proton (atomic) number X = atomic symbol a = relative atomic mass *58-71 Lanthanoid series 90-103 Actinoid series 88 Ac Actinium Ra Radium Fr Francium 87 * Hafnium Lanthanum 57 Hf La 40 Zirconium Zr 91 Titanium 178 Yttrium 22 48 Ti 139 39 Y 89 Scandium 21 227 Caesium 56 Barium Cs 45 Sc 226 55 137 Ba 133 Strontium Rubidium 38 Rb 37 Sr 85 20 Potassium 19 Ca 39 Magnesium Na 12 Mg 23 Beryllium 4 Lithium K 11 3 9 Be 7 II Li I 93 Ta 181 Niobium Nb 90 58 73 52 96 Mo W 184 141 Pa Thorium 55 Tc 186 Re 144 Nd 92 60 Uranium U 238 Neodymium 75 Rhenium 43 Technetium 25 Manganese Mn 29 30 65 8 9 VII 2 0 Ru 101 Iron 190 Pm Osmium Os 93 Np Neptunium 61 Promethium 76 44 Ruthenium 26 56 Fe Sm 150 Iridium 94 Pu Plutonium 62 Eu 152 Platinum 95 Am Americium 63 Europium 78 195 Pt 192 46 Palladium Pd 106 Nickel Ni Ir Samarium 77 45 Rhodium Rh 103 Cobalt Co Gd 157 Gold Au 197 Silver 96 64 Curium Cm Gadolinium 79 47 Ag 108 Copper Cu 201 Bk Terbium Tb 159 Mercury Hg 97 Berkelium 65 80 48 Cadmium Cd 112 Zinc Zn 11 70 Dy 162 Thallium Tl 204 Indium 98 Cf Californium 66 Es Holmium Ho 165 Lead Pb 207 Tin 99 Einsteinium 67 82 50 119 Sn In 32 Germanium Ge 73 Silicon 115 Gallium Ga Dysprosium 81 49 31 13 Aluminium Si Al 14 28 Carbon 27 Boron 12 C 14 75 Sb 122 Arsenic As Bi 209 Fermium Fm Erbium Er 167 Bismuth 100 68 83 51 Antimony 33 15 Phosphorus P 31 Nitrogen N Se 79 Sulfur S 32 Oxygen Po 169 Md Thulium Tm 101 Mendelevium 69 84 Polonium 52 Tellurium Te 128 Selenium 34 16 16 O Yb 173 Astatine At Iodine I 127 Bromine Br 80 Chlorine No 102 Nobelium 70 Ytterbium 85 53 35 17 Cl 35.5 Fluorine F 19 Lr Lutetium Lu 175 Radon Rn Xenon Xe 131 Krypton Kr 84 Argon Ar 40 Neon 103 Lawrencium 71 86 54 36 18 10 Ne 20 Helium Hydrogen B 4 28 64 7 VI He 27 59 6 V H 59 5 IV The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.). 91 Protactinium Th 232 Praseodymium Cerium 59 Pr Ce 74 Tungsten 42 Molybdenum 24 Chromium Cr 140 Tantalum 41 23 Vanadium V 51 1 III 1 Group DATA SHEET The Periodic Table of the Elements 16 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.