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Chapter 8 Hatch

           Fiber Properties and Identification




09/12/12                 TMS 211
Fiber Responses

How do fibers respond to changes in?:
Mechanical forces
Water
Dry and wet heat
Ultraviolet radiation
Chemical solutions
Biological organisms
09/12/12           TMS 211
Mechanical Properties

How do they respond to changes in applied
 forces
How do fibers recover?
Depends on fine structure




09/12/12           TMS 211
Stress-Strain

Gradually apply a force or stress along the
 fiber axis
The fiber elongates
The amount of this
elongation or strain
can be plotted as
 a stress/strain curve
09/12/12            TMS 211
09/12/12   TMS 211
Stress-strain

The elongation
Δl = lf - lo


The strain


ε= Δl / lo = (lf – lo)/ lo

09/12/12                  TMS 211
Stress and Strain

Stress is generally reported as:
 grams per denier g/den
or newtons per tex N/tex
Strain is reported as percent on the x-axis




09/12/12            TMS 211
Characteristic stress-strain
curves




09/12/12      TMS 211
Characteristics

How well does fiber resist elongation?
How far will it elongates before breaking?
Will the fiber recover if I release the
 stress?
How strong is the fiber?
How tough is the fiber?
Std. Cond. 70°F (21°C) and 65% R.H.
09/12/12             TMS 211
Model Stress-strain curve




09/12/12      TMS 211
Analysis of curve

Straight line segment at first (AB)
Flattening out (BC)
Rise steeply to break (CD)
AB is the initial modulus or Young’s
 modulus – 45 degrees is an average
Cotton is steep (high) and wool has a low
 initial modulus
09/12/12            TMS 211
Analysis

Do you want the fiber to give with a small
    stress (women’s nylon sheer hosiery)?
     – Less crystalline
Resist deformation? (polyester)
     – Crystallites resist movement when stressed




09/12/12                  TMS 211
Yield point

Curve begins to flatten as the polymers
 “Yield” to the stress
Ropes and safety belts
Want this to be well beyond load applied
Polyester > 8 % -good seatbelt material
Wool – very low 3%


09/12/12           TMS 211
Hardening point

Polymers continue to compact in the far
    region.




09/12/12           TMS 211
Tenacity

After hardening, internal structure begins
 to fail and approaches rupture.
Breaking tenacity – draw a line straight
 across to Y-axis
Wool and Acetate very low.
Flax and olefin very high (good ski rope)


09/12/12            TMS 211
Elongation at break

Drop a vertical line from Rupture point to
 x-axis.
Wool and nylon very high
Cotton and flax very low.




09/12/12            TMS 211
Work of Rupture (Toughness)

Can the fiber withstand sudden bursts of
 energy?
The total area under the stress-strain curve
Nylon and polyester are tough
Acetate is weak



09/12/12            TMS 211
Elastic Recovery

Section A-B acts like a
spring (Hooke’s Law)
If stress is removed, complete recovery.
If stressed beyond yield point and before
 hardening, partial recovery.
Viscose rayon very poor
Nylon, very good.
09/12/12            TMS 211
Resilience (Work of Recovery)

 Ratio of energy returned to that absorbed.
 Areas X/(X+Y)
 Crimped better
 than flat fibers
 Polyester very high
 Cotton and rayon lowest
 Polyester fabrics are wrinkle –free
 Rayon and cotton wrinkle badly.
09/12/12                TMS 211
Resilience




09/12/12     TMS 211
Flexural Rigidity (Stiffness)

Spectra (olefin) is off the chart
Spandex is easily bent




09/12/12             TMS 211
Abrasion Resistance

Difficult to rub individual fibers
Yarn and fabric structure complicate




09/12/12            TMS 211
Flexibility

Related to crystallinity
Triacetate low; carbon nil
Polyester high (note break in scale)




09/12/12            TMS 211

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3 fibe properties and identification0 (1)

  • 1. Chapter 8 Hatch Fiber Properties and Identification 09/12/12 TMS 211
  • 2. Fiber Responses How do fibers respond to changes in?: Mechanical forces Water Dry and wet heat Ultraviolet radiation Chemical solutions Biological organisms 09/12/12 TMS 211
  • 3. Mechanical Properties How do they respond to changes in applied forces How do fibers recover? Depends on fine structure 09/12/12 TMS 211
  • 4. Stress-Strain Gradually apply a force or stress along the fiber axis The fiber elongates The amount of this elongation or strain can be plotted as  a stress/strain curve 09/12/12 TMS 211
  • 5. 09/12/12 TMS 211
  • 6. Stress-strain The elongation Δl = lf - lo The strain ε= Δl / lo = (lf – lo)/ lo 09/12/12 TMS 211
  • 7. Stress and Strain Stress is generally reported as:  grams per denier g/den or newtons per tex N/tex Strain is reported as percent on the x-axis 09/12/12 TMS 211
  • 9. Characteristics How well does fiber resist elongation? How far will it elongates before breaking? Will the fiber recover if I release the stress? How strong is the fiber? How tough is the fiber? Std. Cond. 70°F (21°C) and 65% R.H. 09/12/12 TMS 211
  • 11. Analysis of curve Straight line segment at first (AB) Flattening out (BC) Rise steeply to break (CD) AB is the initial modulus or Young’s modulus – 45 degrees is an average Cotton is steep (high) and wool has a low initial modulus 09/12/12 TMS 211
  • 12. Analysis Do you want the fiber to give with a small stress (women’s nylon sheer hosiery)? – Less crystalline Resist deformation? (polyester) – Crystallites resist movement when stressed 09/12/12 TMS 211
  • 13. Yield point Curve begins to flatten as the polymers “Yield” to the stress Ropes and safety belts Want this to be well beyond load applied Polyester > 8 % -good seatbelt material Wool – very low 3% 09/12/12 TMS 211
  • 14. Hardening point Polymers continue to compact in the far region. 09/12/12 TMS 211
  • 15. Tenacity After hardening, internal structure begins to fail and approaches rupture. Breaking tenacity – draw a line straight across to Y-axis Wool and Acetate very low. Flax and olefin very high (good ski rope) 09/12/12 TMS 211
  • 16. Elongation at break Drop a vertical line from Rupture point to x-axis. Wool and nylon very high Cotton and flax very low. 09/12/12 TMS 211
  • 17. Work of Rupture (Toughness) Can the fiber withstand sudden bursts of energy? The total area under the stress-strain curve Nylon and polyester are tough Acetate is weak 09/12/12 TMS 211
  • 18. Elastic Recovery Section A-B acts like a spring (Hooke’s Law) If stress is removed, complete recovery. If stressed beyond yield point and before hardening, partial recovery. Viscose rayon very poor Nylon, very good. 09/12/12 TMS 211
  • 19. Resilience (Work of Recovery)  Ratio of energy returned to that absorbed.  Areas X/(X+Y)  Crimped better  than flat fibers  Polyester very high  Cotton and rayon lowest  Polyester fabrics are wrinkle –free  Rayon and cotton wrinkle badly. 09/12/12 TMS 211
  • 21. Flexural Rigidity (Stiffness) Spectra (olefin) is off the chart Spandex is easily bent 09/12/12 TMS 211
  • 22. Abrasion Resistance Difficult to rub individual fibers Yarn and fabric structure complicate 09/12/12 TMS 211
  • 23. Flexibility Related to crystallinity Triacetate low; carbon nil Polyester high (note break in scale) 09/12/12 TMS 211