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Nuclear Chemistry




          Bravo – 15,000 kilotons
CA Standards
Students know the three most common forms
of radioactive decay (alpha, beta, and gamma)
and know how the nucleus changes in each type
of decay.
Students know alpha, beta, and gamma
radiation produce different amounts and kinds
of damage in matter and have different
penetrations.
Students know some naturally occurring
isotopes of elements are radioactive, as are
isotopes formed in nuclear reactions.
Nuclear Symbols

Mass number             Element
 (p+ + no)               symbol

                  235
                    U
                   92
 Atomic number
 (number of p+)
Types of Radioactive Decay
alpha production (a, He): helium nucleus
          238
           92   U  He 
                       4
                       2
                                 234
                                  90  Th
beta production (b, e):
          234
           90   Th    234
                        91   Pa  e
                                  0
                                 1

 gamma ray production (g):

            U  He 
          238
           92
                       4
                       2          Th  2 g
                                234
                                 90
                                           0
                                           0
Nuclear
     Stability

Decay will occur in
such a way as to
return a nucleus to
the band (line) of
stability.
Alpha
  Radiation
Alpha decay is
limited to VERY
large, nuclei
such as those in
heavy metals.
Beta
  Radiation

Beta decay
converts a
neutron into a
proton.
Alpha Particle     Beta Particle           Gamma Ray
                         Emission          Emission               Emission
              4
       Symbol 2       He 2 or 2 a 2
                               4          0
                                         1   e        0
                                                   or 1   b
                                                                      0
                                                                      0   g
          Mass            Heavy                   Light            No Mass

How it changes        Decreases the     Converts a           No change to the
   the nucleus         mass number        neutron into a           nucleus
                       by 4               proton
                      Decreases the     Increases
                       atomic number      atomic number
                       by 2               by 1


   Penetration             Low                Medium                High

     Protection           Skin           Paper, clothing            Lead
  provided by…

        Danger             Low                Medium                High
CA Standards
Students know protons and neutrons in the
nucleus are held together by nuclear forces
that overcome the electromagnetic repulsion
between the protons.

Students know the energy release per gram of
material is much larger in nuclear fusion or
fission reactions than in chemical reactions.
The change in mass (calculated by E = mc2) is
small but significant in nuclear reactions.
Fission




Fission - Splitting a
heavy nucleus into two
nuclei with smaller mass
numbers.
Deuterium – Tritium Fusion Reaction




Fusion - Combining two light nuclei to
form a heavier, more stable nucleus.
Energy and Mass
Nuclear changes occur with small but measurable
losses of mass. The lost mass is called the mass
defect, and is converted to energy according to
Einstein’s equation:
                   DE = Dmc2
              Dm = mass defect
              DE = change in energy
               c = speed of light


Because c2 is so large, even small amounts of
mass are converted to enormous amount of
energy.
A Fission Reactor

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Nuclear chemistry

  • 1. Nuclear Chemistry Bravo – 15,000 kilotons
  • 2. CA Standards Students know the three most common forms of radioactive decay (alpha, beta, and gamma) and know how the nucleus changes in each type of decay. Students know alpha, beta, and gamma radiation produce different amounts and kinds of damage in matter and have different penetrations. Students know some naturally occurring isotopes of elements are radioactive, as are isotopes formed in nuclear reactions.
  • 3. Nuclear Symbols Mass number Element (p+ + no) symbol 235 U 92 Atomic number (number of p+)
  • 4. Types of Radioactive Decay alpha production (a, He): helium nucleus 238 92 U  He  4 2 234 90 Th beta production (b, e): 234 90 Th  234 91 Pa  e 0 1  gamma ray production (g): U  He  238 92 4 2 Th  2 g 234 90 0 0
  • 5. Nuclear Stability Decay will occur in such a way as to return a nucleus to the band (line) of stability.
  • 6. Alpha Radiation Alpha decay is limited to VERY large, nuclei such as those in heavy metals.
  • 7. Beta Radiation Beta decay converts a neutron into a proton.
  • 8. Alpha Particle Beta Particle Gamma Ray Emission Emission Emission 4 Symbol 2 He 2 or 2 a 2 4 0 1 e 0 or 1 b 0 0 g Mass Heavy Light No Mass How it changes  Decreases the  Converts a No change to the the nucleus mass number neutron into a nucleus by 4 proton  Decreases the  Increases atomic number atomic number by 2 by 1 Penetration Low Medium High Protection Skin Paper, clothing Lead provided by… Danger Low Medium High
  • 9. CA Standards Students know protons and neutrons in the nucleus are held together by nuclear forces that overcome the electromagnetic repulsion between the protons. Students know the energy release per gram of material is much larger in nuclear fusion or fission reactions than in chemical reactions. The change in mass (calculated by E = mc2) is small but significant in nuclear reactions.
  • 10. Fission Fission - Splitting a heavy nucleus into two nuclei with smaller mass numbers.
  • 11. Deuterium – Tritium Fusion Reaction Fusion - Combining two light nuclei to form a heavier, more stable nucleus.
  • 12. Energy and Mass Nuclear changes occur with small but measurable losses of mass. The lost mass is called the mass defect, and is converted to energy according to Einstein’s equation: DE = Dmc2 Dm = mass defect DE = change in energy c = speed of light Because c2 is so large, even small amounts of mass are converted to enormous amount of energy.
  • 13.