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Soil and Plant nutrient
Course: B.Sc. Agriculture
Subject : Soil chemistry, Soil fertility and Nutrient management
Unit: 1
• Soil
• Soil: The word ‘soil’ is derived from a Latin
word, “Solum”, meaning ‘floor’.
• Soil is a complex system made up of mineral
matter, organic matter, and soil water and soil
air. Therefore, it contains not only the solid
and liquid phases but also the gaseous phase.
• Soil is a thin layer of earth’s crust which serves as a
natural medium for the growth of plants. Soil is the
unconsolidated mineral material on the immediate
surface of the earth that serves as a natural medium
for the growth of land plants.
• Soil is the unconsolidated mineral matter that has been
subjected to, and influenced by genetic and
environmental factors, parent material, climate,
organisms and topography all acting over a period of
time.
• Soil is a natural body, synthesized in profile form from a
variable mixture of broken and weathered minerals
and decaying organic matter which covers the earth in
a thin layer and which supplies when containing the
proper amounts of air and water, mechanical support
and in part, sustenance for plans.
• Some definitions of the soil,
According to Joffe (1949),
• “The Soil is a natural body of minerals and organic
constituents differentiate into horizons of variable depth,
which differs from the materials below in morphology,
physical make up, chemical properties and composition and
biological characteristics.”
• Soil is a dynamic natural body developed as a result of
pedogenic processes during and after weathering of rocks,
consisting of minerals and organic constituents, possessing
definite chemical, physical, mineralogical and biological
properties having variable depth over surface of the earth
and providing medium for plant growth of land plants.
• The soil is heterogeneous, polyphasic, particulate,
disperse and porous system, in which the interfacial
area per unit volume can be very large. The disperse
nature of the soil and its consequent interfacial activity
give rise to such phenomena as:
1. Absorption of water and chemical,
2. Inoic exchange,
3. Adhesion
4. Swelling and Shrinking,
5. Dispersion and Flocculation and
6. Capillary.
• Functions of soil:
1. Soil provides anchorage to root enabling plants to stand
erect.
2. It acts as a store house of water and nutrients for plant
growth.
3. It acts as an abode of flora and fauna which suitably
transform nutrients for uptake by plant roots.
4. It provides space for air and accretion which creates
healthy environment for the biological activity of soil
organisms.
Soil is natural body, differentiated into horizons of mineral and
organic constituents, usually unconsolidated, of variable
depth, which differs from the percent material below in
morphology, physical properties and constitution, chemical
properties and composition and biological characteristics.
• Soil profile: The vertical exposure of soil with
its various layers (horizons) Or
• A vertical section through the soil is called as
the soil profile.
The various distinguishable layer of soil that
occurs are called horizons.
Soil as a source of plant nutrients -
Essential and beneficial elements,
criteria of essentiality
Learning objective :
• To understand the importance of soil fertility To study the essential
nutrients in plant growth
• Crops depend on extrinsic and intrinsic factors for their growth and
environment to provide them with basic necessities for
photosynthesis. These essential plant growth factors include:
• light
• heat
• air
• water
• nutrients
• physical support
• If any one factor, or combination of factors, is in
limited supply, plant growth will be adversely
affected. The importance of each of the plant
growth factors and the proper
• combination of these factors for normal plant
growth is best described by the principle of
limiting factors.
• This principle states: "The level of crop
production can be no greater than that allowed
by the most limiting of the essential plant growth
factors." The principle of limiting factors can be
compared to that of a barrel having staves of
different lengths with each stave representing a
plant growth factor.
• Crop yield and quality depends upon the
essential growth factors and the many
interrelated soil, plant, environmental and
agronomic factors or variables. Within this
system, some of these factors cannot be
controlled; others can be controlled and are
manageable.
•
• Soil is one of the key factors affecting plant
growth as observed in the figure. The major
functions of the soil are to provide plants with
nutrients, water and oxygen.
Crop Production Factors
FAO has listed seven important soil qualities which
affect crop growth as given below.
Soil
Qualit
ies
Soil
Characteristics
SQ1 Nutrient availability Soil texture, soil organic carbon, soil pH, total
exchangeable bases
SQ2 Nutrient retention
capacity
Soil Organic carbon, Soil texture, base
saturation, cation exchange capacity of soil and
of clay fraction
SQ3 Rooting conditions Soil textures, bulk density, coarse fragments,
vertic soil properties and soil phases affecting
root penetration and soil depth and soil volume
SQ4 Oxygen
availability to
roots
Soil drainage and soil phases affecting soil
drainage
SQ5 Excess salts. Soil salinity, soil sodicity and soil phases
influencing salt conditions
SQ6 Toxicity Calcium carbonate and gypsum
SQ7 Workability
(constraining field
management)
Soil texture, effective soil depth/volume, and soil
phases constraining soil management (soil depth,
rock outcrop, stoniness, gravel/concretions and
hardpans)
Soil fertility
• "Soil fertility is the ability of the soil to supply
essential plant nutrients during growth period
of the plants, without toxic concentration of
any nutrients". i.e "the capacity of soil to
supply nutrient in available to crop".
Soil productivity
• "Soil productivity is ability of soil to produce a
particular crop or sequence of crops under a
specified mgt system" i.e the crop producing
capacity of soil".
• All the productive soils are fertile but all the
fertile soils may not be productive
• Sometimes even if the soil is fertile, they are
subjected to drought or other unsatisfactory
growth factors or management practices.
History of development of soil fertility
• Francis Bacon (1591- 1624) suggested that the principle nourishment of
plants was water and the main purpose of the soil was to keep plants
erect and to protect from heat and cold.
•
• Jan Baptiste Van Helmont (1577 - 1644) was reported that water was sole
nutrient of
• plants.
• Robert Boyle (1627 - 1691) an England scientist confirmed the findings of
Van Helmont and proved that plant synthesis salts, spirits and oil etc from
H2O.
• Anthur Young (1741 - 1820) an English agriculturist conducted pot
experiment using Barley as a test crop under sand culture condition. He
added charcoal, train oil, poultry dung, spirits of wine, oster shells and
numerous other materials and he conduced that some of the materials
were produced higher plant growth.
•
• Priestly (1800) established the essentiality of O2 for the plant
growth.
• J.B. Boussingault (1802-1882) French chemist conducted field
experiment and maintained balance sheet. He was first
scientist to conduct field experiment. He is considered as
father of field experiments.
• Justus Von Liebig (1835) suggested that
• a. Most of the carbon in plants comes from the CO2 of the
atmosphere.
• b. Hydrogen and O2 comes from H2O.
• c. Alkaline metals are needed for neutralization of acids
formed by plants as a result of their metabolic activities.
• d. Phosphorus is necessary for seed formation.
• e. Plant absorb every thing from the soil but excrete from
their roots those materials that are not essential.
• The field may contain some nutrient in excess,
some in optimum and some in least, but the
limiting factor for growth is the least available
nutrient. The law of Mn, stated by Liebig in
1862, is a simple but logical guide for
predicting crop response to fertilization. This
law states that, "the level of plant production
cannot be grater than that allowed by the
most limiting of the essential plant growth
factors". The contributions made by Liebig to
the advancement of agriculture were
monumental and he is recognized as the
father of Agricultural chemistry.
• J.B. Lawes and J. H. Gilbert (1843) established permanent
manurial experiment at Rothemsted Agricultural
experiment station at England. They conducted field
experiments for twelve years and their findings were
• a. Crop requires both P and K, but the composition of the
plant ash is no measure of the amounts of these
constituents required by the plant.
• b. No legume crop require N. without this element, no
growth will be obtained regardless of the quantities of P
and K present. The amount of ammonium contributed by
the atmosphere is insufficient for the needs of the crop.
• c. Soil fertility can be maintained for some years by
chemical fertilizers.
• d. The beneficial effect of fallow lies in the increases in
the available N compounds in the soil.
• Robert Warrington England showed that the
nitrification could be supported by carbon
disulphide and chloroform and that it would
be stopped by adding a small amount of
unsterilized soil. He demonstrated that the
reaction was two step phenomenon. First NH3
being converted to nitrites and the nitrites to
nitrites.
• Essential and Beneficial elements
• "A mineral element is considered to be essential for
plant growth and development if the element is
involved in plant metabolic functions and the plant
cannot complete its life cycle without the element".
• There are seventeen essential elements required for
plant growth viz., C, H, O, N, P, K, Ca, Mg, S, Fe, Mn,
Zn, Cu, B, Mo, Cl, Ni,
• The following is the essentiality criteria described by
Arnon and Stout (1939)
• A plant must be unable to complete its life cycle in the
absence of the mineral element.
• The function of the element must not be replaceable
by another mineral element.
• The element must be directly involved in plant
metabolism.
• Beneficial Nutrients/Elements: Beneficial
elements are the mineral elements that stimulate
the growth and exhibit beneficial effects at very
low concentration or which are essential only for
certain plant species or under specific conditions
are called as "beneficial elements".Eg.Na,Va,Co,Si
• D.J.Nicholas coined the term "functional or
metabolic nutrient"
• Any mineral element that functions in plant
metabolism, whether or not its action is specific.
(Cl, Si, Na, Va, Co, Se)
• The following table gives the essentiality of
elements established by different scientists
• Essentiality of the elements established by
Carbon Priestly (1800)
Nitrogen Theodore De saussure (1804)
Ca, Mg, K, S Carl sprengel (1839)
Phosphorus Von Liebig (1844)
Iron (Fe) E. Greiss (1844)
Manganese (Mn) J.S. Hargue (1922)
Zinc(Zn) Sommer and Lipman (1926)
Copper (Cu) Sommer, Lipman and Mc Kenny (1931)
Molybdenum (Mo) Arnon and Stout (1939)
Sodium (Na) Brownell and wood (1957)
Cobalt(Co) Ahamed and Evans (1959)
Boron(B) Warring ton (1923)
Chlorine (Cl ) Broyer (1954)
Nickel Brown et.al.(1987)
• Classification of Essential Elements
• 1) Based on the amount required by the plant
• i) Major nutrients - required in large quantities
eg. N,P,K
• ii) Secondary nutrients - required in lesser
quantities compared to Major nutrients eg.
Ca,Mg,S
• iii) Micronutrients- required in trace quantities
eg. Fe, Mn, Zn, Cu, B, Mo
• Classification based on the role of element in
plant system
• (According to TRUOG, 1954)
• Structural Elements : C, H, O
• ii). Accessory structural elements : N. P. S
iii). Regulator & Carriers : K, Ca, Mg
• iv). Catalyst & Activators : Fe, Mn, Zn, Cu, Mo,
Cl, B
• Questions to ponder
• How are the essential elements essential to crops?
• Which elements are considered to be essential for crop
growth?
• Why is some nutrient deficiencies exhibited in older
leaves, while other nutrient deficiencies show up first
on newer leaves?
• What are beneficial elements?
• What is the difference between major and
micronutrient?
Mechanism of nutrient in the plant
Learning objectives
• a. Understand ways in which nutrients in the soil reach plant roots
• b. To know how plant roots absorb nutrients and move inside plants
•
• Nutrients must reach the surface of a root for plant uptake of essential elements to occur
There are three major mechanism of movement of ions from soil to roots. They are
•
• Root interception
•
• Root interception occurs when a nutrient comes into physical contact with the root surface.
As a general rule, the occurrence of root interception increases as the root surface area and
mass increases, thus enabling the plant to explore a greater amount of soil. Root interception
may be enhanced by mycorrhizal fungi, which colonize roots and increases root exploration
into the soil. Root interception is responsible for an appreciable amount of calcium uptake,
and some amounts of magnesium, zinc and manganese. The CEC of roots for monocots is 10 -
30 meq/100 g and takes up monovalent cations more readily and that of Dicots is 40 - 100
meq/100 g and takes up divalent cations more readily. The quantity of nutrients intercepted
by roots depends on the soil concentration of nutrients and volume of soil displaced by root
system
Factors affecting root interception
• a. Anything that restricts root growth
• i. Dry soil
• ii. Compaction
• iii. Low soil pH
• iv. Poor aeration
• v. Root disease, insects, nematodes
• vi. High or low soil temperature
• b. Root growth is necessary for all three
mechanisms of nutrient supply, but absolutely
essential for root interception to occur
Mass flow:
• Mass flow occurs when nutrients are transported
to the surface of roots by the movement of water
in the soil (i.e. percolation, transpiration, or
evaporation). The rate of water flow governs the
amount of nutrients that are transported to the
root surface.
• Therefore, mass flow decreases are soil water
decreases. Most of the nitrogen, calcium,
magnesium, sulfur, copper, boron, manganese
and molybdenum move to the root by mass flow.
Quantity of nutrients transported is proportional
to:
• i. Rate of flow (volume of water transpired)
• ii. Solution concentration of nutrient
• Nutrients supplied primarily by mass flow are
considered mobile nutrients. e.g. N, S, B Factors
affecting mass flow
a. Soil water content
• i. Dry soil where there is no nutrient movement
b. Temperature
• i. Low temperature reduces transpiration and
evaporation
c. Size of root system
• i. Affects water uptake and therefore movement
• ii. Root density much less critical for nutrient supply
by mass flow than for root
interception and diffusion
Diffusion:
• Diffusion is the movement of a particular nutrient along a
concentration gradient. When there is a difference in
concentration of a particular nutrient within the soil
solution, the nutrient will move from an area of higher
concentration to an area of lower concentration.
• This phenomenon is observed when adding sugar to water.
As the sugar dissolves, it moves through parts of the water
with lower sugar concentration until it is evenly distributed,
or uniformly concentrated. Diffusion delivers appreciable
amounts of phosphorus, potassium, zinc, and iron to the
root surface. Diffusion is a relatively slow process compared
to the mass flow of nutrients with water movement toward
the root. Nutrients supplied primarily by diffusion are
considered immobile nutrients e.g. P, K
Factors affecting diffusion
• a. Fick's law is given as dC/dt = De * A * dC/dX
• dC/dt = diffusion rate (change in
concentration over time) De = effective
diffusion coefficient A = cross sectional area
for diffusion
• dC/dX = concentration gradient (change in
concentration over distance)
• Diffusion rate is directly proportional to
concentration gradient, diffusion coefficient,
and the area available for diffusion to occur
b. Effective diffusion coefficient
• Effective diffusion coefficient De = Dw * q *
(1/T) * (1/b) where
• Dw = diffusion coefficient in water q =
volumetric soil water content T = tortuosity
factor b = soil buffering capacity
a. Diffusion coefficient in water (Dw)
• i. Includes a temperature factor
• ii. Colder = slower diffusion
b. Soil water content
• i. Drier soil = slower diffusion
• ii. Less water = less area to diffuse through
c. Tortuosity
• i. Pathways through soil are not direct
• Ii. Around soil particles, through thin water films
• Iii. Affected by texture and water content
• More clay = longer diffusion pathway
• Thinner water films = longer path
d. Buffering capacity
• i. Nutrients can be removed by adsorption as they move through soil, reducing diffusion rate
• c. How far can nutrients diffuse in a growing season?
• a. Diffusion distances are very short
• i. K ~ 0.2 cm
• ii. P ~ 0.02 cm
• b. Size and density of plant root systems is very important for nutrients supplied by
diffusion
• c. Has implications for fertilizer lacement
• Ion traffic into the root
• Mineral nutrients absorbed from the root has to be
carried to the xylem. This transport follows two
pathways namely apoplastic pathway and symplastic
pathway.
• In apoplastic pathway, mineral nutrients along with
water moves from cell to cell through spaces between
cell wall by diffusion. The ions, which enter the cell
wall of the epidermis move across cell wall of cortex,
cytoplasm of endodermis, cell walls of pericycle and
finally reach the xylem.
• In symplastic pathway, mineral nutrients entering the
cytoplasm of the epidermis move across the cytoplasm
of the cortex, endodermis of pericycle through
plasmodesmata and finally reach the xylem.
• Translocation of solutes
• P.R. Stout and Dr. Hoagland have proved that
mineral nutrients absorbed by the roots are
translocated through the xylem vessel. Mineral
salts dissolved in water moves up along the xylem
vessel to be transported to all the parts of the
plant body. Translocation is aided, by
transpiration. As water is continuously lost by
transpiration on the upper surfaces of the plant,
it creates a transpirational pull, by which water
along with mineral salts is pulled up along the
xylem vessel.
• Active absorption of energy can be achieved
only by an input of energy. Following
evidences show the involvement of
metabolic energy in the absorption of
mineral salts.
• Higher rate of respiration increases the salt
accumulation inside the cell.
• Respiratory inhibitors check the process of salt
uptake.
• By decreasing oxygen content in the medium,
the salt absorption is also decreased.
Text book and web sources
- www. agriinfo.in
- ecourses.iasri.res.in
- Soil science and management by Edward J.
Plaster
- Anand Agricultural university theory notes

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B Sc Agri II Sc,Sf & Nm, U 1 Soil And Plant Nutrient

  • 1. Soil and Plant nutrient Course: B.Sc. Agriculture Subject : Soil chemistry, Soil fertility and Nutrient management Unit: 1
  • 2. • Soil • Soil: The word ‘soil’ is derived from a Latin word, “Solum”, meaning ‘floor’. • Soil is a complex system made up of mineral matter, organic matter, and soil water and soil air. Therefore, it contains not only the solid and liquid phases but also the gaseous phase.
  • 3. • Soil is a thin layer of earth’s crust which serves as a natural medium for the growth of plants. Soil is the unconsolidated mineral material on the immediate surface of the earth that serves as a natural medium for the growth of land plants. • Soil is the unconsolidated mineral matter that has been subjected to, and influenced by genetic and environmental factors, parent material, climate, organisms and topography all acting over a period of time. • Soil is a natural body, synthesized in profile form from a variable mixture of broken and weathered minerals and decaying organic matter which covers the earth in a thin layer and which supplies when containing the proper amounts of air and water, mechanical support and in part, sustenance for plans.
  • 4. • Some definitions of the soil, According to Joffe (1949), • “The Soil is a natural body of minerals and organic constituents differentiate into horizons of variable depth, which differs from the materials below in morphology, physical make up, chemical properties and composition and biological characteristics.” • Soil is a dynamic natural body developed as a result of pedogenic processes during and after weathering of rocks, consisting of minerals and organic constituents, possessing definite chemical, physical, mineralogical and biological properties having variable depth over surface of the earth and providing medium for plant growth of land plants.
  • 5. • The soil is heterogeneous, polyphasic, particulate, disperse and porous system, in which the interfacial area per unit volume can be very large. The disperse nature of the soil and its consequent interfacial activity give rise to such phenomena as: 1. Absorption of water and chemical, 2. Inoic exchange, 3. Adhesion 4. Swelling and Shrinking, 5. Dispersion and Flocculation and 6. Capillary.
  • 6. • Functions of soil: 1. Soil provides anchorage to root enabling plants to stand erect. 2. It acts as a store house of water and nutrients for plant growth. 3. It acts as an abode of flora and fauna which suitably transform nutrients for uptake by plant roots. 4. It provides space for air and accretion which creates healthy environment for the biological activity of soil organisms. Soil is natural body, differentiated into horizons of mineral and organic constituents, usually unconsolidated, of variable depth, which differs from the percent material below in morphology, physical properties and constitution, chemical properties and composition and biological characteristics.
  • 7. • Soil profile: The vertical exposure of soil with its various layers (horizons) Or • A vertical section through the soil is called as the soil profile. The various distinguishable layer of soil that occurs are called horizons.
  • 8. Soil as a source of plant nutrients - Essential and beneficial elements, criteria of essentiality
  • 9. Learning objective : • To understand the importance of soil fertility To study the essential nutrients in plant growth • Crops depend on extrinsic and intrinsic factors for their growth and environment to provide them with basic necessities for photosynthesis. These essential plant growth factors include: • light • heat • air • water • nutrients • physical support
  • 10. • If any one factor, or combination of factors, is in limited supply, plant growth will be adversely affected. The importance of each of the plant growth factors and the proper • combination of these factors for normal plant growth is best described by the principle of limiting factors. • This principle states: "The level of crop production can be no greater than that allowed by the most limiting of the essential plant growth factors." The principle of limiting factors can be compared to that of a barrel having staves of different lengths with each stave representing a plant growth factor.
  • 11. • Crop yield and quality depends upon the essential growth factors and the many interrelated soil, plant, environmental and agronomic factors or variables. Within this system, some of these factors cannot be controlled; others can be controlled and are manageable. • • Soil is one of the key factors affecting plant growth as observed in the figure. The major functions of the soil are to provide plants with nutrients, water and oxygen.
  • 12. Crop Production Factors FAO has listed seven important soil qualities which affect crop growth as given below. Soil Qualit ies Soil Characteristics SQ1 Nutrient availability Soil texture, soil organic carbon, soil pH, total exchangeable bases SQ2 Nutrient retention capacity Soil Organic carbon, Soil texture, base saturation, cation exchange capacity of soil and of clay fraction SQ3 Rooting conditions Soil textures, bulk density, coarse fragments, vertic soil properties and soil phases affecting root penetration and soil depth and soil volume
  • 13. SQ4 Oxygen availability to roots Soil drainage and soil phases affecting soil drainage SQ5 Excess salts. Soil salinity, soil sodicity and soil phases influencing salt conditions SQ6 Toxicity Calcium carbonate and gypsum SQ7 Workability (constraining field management) Soil texture, effective soil depth/volume, and soil phases constraining soil management (soil depth, rock outcrop, stoniness, gravel/concretions and hardpans)
  • 14. Soil fertility • "Soil fertility is the ability of the soil to supply essential plant nutrients during growth period of the plants, without toxic concentration of any nutrients". i.e "the capacity of soil to supply nutrient in available to crop".
  • 15. Soil productivity • "Soil productivity is ability of soil to produce a particular crop or sequence of crops under a specified mgt system" i.e the crop producing capacity of soil". • All the productive soils are fertile but all the fertile soils may not be productive • Sometimes even if the soil is fertile, they are subjected to drought or other unsatisfactory growth factors or management practices.
  • 16. History of development of soil fertility • Francis Bacon (1591- 1624) suggested that the principle nourishment of plants was water and the main purpose of the soil was to keep plants erect and to protect from heat and cold. • • Jan Baptiste Van Helmont (1577 - 1644) was reported that water was sole nutrient of • plants. • Robert Boyle (1627 - 1691) an England scientist confirmed the findings of Van Helmont and proved that plant synthesis salts, spirits and oil etc from H2O. • Anthur Young (1741 - 1820) an English agriculturist conducted pot experiment using Barley as a test crop under sand culture condition. He added charcoal, train oil, poultry dung, spirits of wine, oster shells and numerous other materials and he conduced that some of the materials were produced higher plant growth. •
  • 17. • Priestly (1800) established the essentiality of O2 for the plant growth. • J.B. Boussingault (1802-1882) French chemist conducted field experiment and maintained balance sheet. He was first scientist to conduct field experiment. He is considered as father of field experiments. • Justus Von Liebig (1835) suggested that • a. Most of the carbon in plants comes from the CO2 of the atmosphere. • b. Hydrogen and O2 comes from H2O. • c. Alkaline metals are needed for neutralization of acids formed by plants as a result of their metabolic activities. • d. Phosphorus is necessary for seed formation. • e. Plant absorb every thing from the soil but excrete from their roots those materials that are not essential.
  • 18. • The field may contain some nutrient in excess, some in optimum and some in least, but the limiting factor for growth is the least available nutrient. The law of Mn, stated by Liebig in 1862, is a simple but logical guide for predicting crop response to fertilization. This law states that, "the level of plant production cannot be grater than that allowed by the most limiting of the essential plant growth factors". The contributions made by Liebig to the advancement of agriculture were monumental and he is recognized as the father of Agricultural chemistry.
  • 19. • J.B. Lawes and J. H. Gilbert (1843) established permanent manurial experiment at Rothemsted Agricultural experiment station at England. They conducted field experiments for twelve years and their findings were • a. Crop requires both P and K, but the composition of the plant ash is no measure of the amounts of these constituents required by the plant. • b. No legume crop require N. without this element, no growth will be obtained regardless of the quantities of P and K present. The amount of ammonium contributed by the atmosphere is insufficient for the needs of the crop. • c. Soil fertility can be maintained for some years by chemical fertilizers. • d. The beneficial effect of fallow lies in the increases in the available N compounds in the soil.
  • 20. • Robert Warrington England showed that the nitrification could be supported by carbon disulphide and chloroform and that it would be stopped by adding a small amount of unsterilized soil. He demonstrated that the reaction was two step phenomenon. First NH3 being converted to nitrites and the nitrites to nitrites.
  • 21. • Essential and Beneficial elements • "A mineral element is considered to be essential for plant growth and development if the element is involved in plant metabolic functions and the plant cannot complete its life cycle without the element". • There are seventeen essential elements required for plant growth viz., C, H, O, N, P, K, Ca, Mg, S, Fe, Mn, Zn, Cu, B, Mo, Cl, Ni, • The following is the essentiality criteria described by Arnon and Stout (1939) • A plant must be unable to complete its life cycle in the absence of the mineral element. • The function of the element must not be replaceable by another mineral element. • The element must be directly involved in plant metabolism.
  • 22. • Beneficial Nutrients/Elements: Beneficial elements are the mineral elements that stimulate the growth and exhibit beneficial effects at very low concentration or which are essential only for certain plant species or under specific conditions are called as "beneficial elements".Eg.Na,Va,Co,Si • D.J.Nicholas coined the term "functional or metabolic nutrient" • Any mineral element that functions in plant metabolism, whether or not its action is specific. (Cl, Si, Na, Va, Co, Se) • The following table gives the essentiality of elements established by different scientists
  • 23. • Essentiality of the elements established by Carbon Priestly (1800) Nitrogen Theodore De saussure (1804) Ca, Mg, K, S Carl sprengel (1839) Phosphorus Von Liebig (1844) Iron (Fe) E. Greiss (1844) Manganese (Mn) J.S. Hargue (1922) Zinc(Zn) Sommer and Lipman (1926) Copper (Cu) Sommer, Lipman and Mc Kenny (1931) Molybdenum (Mo) Arnon and Stout (1939) Sodium (Na) Brownell and wood (1957) Cobalt(Co) Ahamed and Evans (1959) Boron(B) Warring ton (1923) Chlorine (Cl ) Broyer (1954) Nickel Brown et.al.(1987)
  • 24. • Classification of Essential Elements • 1) Based on the amount required by the plant • i) Major nutrients - required in large quantities eg. N,P,K • ii) Secondary nutrients - required in lesser quantities compared to Major nutrients eg. Ca,Mg,S • iii) Micronutrients- required in trace quantities eg. Fe, Mn, Zn, Cu, B, Mo
  • 25. • Classification based on the role of element in plant system • (According to TRUOG, 1954) • Structural Elements : C, H, O • ii). Accessory structural elements : N. P. S iii). Regulator & Carriers : K, Ca, Mg • iv). Catalyst & Activators : Fe, Mn, Zn, Cu, Mo, Cl, B
  • 26. • Questions to ponder • How are the essential elements essential to crops? • Which elements are considered to be essential for crop growth? • Why is some nutrient deficiencies exhibited in older leaves, while other nutrient deficiencies show up first on newer leaves? • What are beneficial elements? • What is the difference between major and micronutrient?
  • 27. Mechanism of nutrient in the plant Learning objectives • a. Understand ways in which nutrients in the soil reach plant roots • b. To know how plant roots absorb nutrients and move inside plants • • Nutrients must reach the surface of a root for plant uptake of essential elements to occur There are three major mechanism of movement of ions from soil to roots. They are • • Root interception • • Root interception occurs when a nutrient comes into physical contact with the root surface. As a general rule, the occurrence of root interception increases as the root surface area and mass increases, thus enabling the plant to explore a greater amount of soil. Root interception may be enhanced by mycorrhizal fungi, which colonize roots and increases root exploration into the soil. Root interception is responsible for an appreciable amount of calcium uptake, and some amounts of magnesium, zinc and manganese. The CEC of roots for monocots is 10 - 30 meq/100 g and takes up monovalent cations more readily and that of Dicots is 40 - 100 meq/100 g and takes up divalent cations more readily. The quantity of nutrients intercepted by roots depends on the soil concentration of nutrients and volume of soil displaced by root system
  • 28. Factors affecting root interception • a. Anything that restricts root growth • i. Dry soil • ii. Compaction • iii. Low soil pH • iv. Poor aeration • v. Root disease, insects, nematodes • vi. High or low soil temperature • b. Root growth is necessary for all three mechanisms of nutrient supply, but absolutely essential for root interception to occur
  • 29. Mass flow: • Mass flow occurs when nutrients are transported to the surface of roots by the movement of water in the soil (i.e. percolation, transpiration, or evaporation). The rate of water flow governs the amount of nutrients that are transported to the root surface. • Therefore, mass flow decreases are soil water decreases. Most of the nitrogen, calcium, magnesium, sulfur, copper, boron, manganese and molybdenum move to the root by mass flow. Quantity of nutrients transported is proportional to:
  • 30. • i. Rate of flow (volume of water transpired) • ii. Solution concentration of nutrient
  • 31. • Nutrients supplied primarily by mass flow are considered mobile nutrients. e.g. N, S, B Factors affecting mass flow a. Soil water content • i. Dry soil where there is no nutrient movement b. Temperature • i. Low temperature reduces transpiration and evaporation c. Size of root system • i. Affects water uptake and therefore movement • ii. Root density much less critical for nutrient supply by mass flow than for root interception and diffusion
  • 32. Diffusion: • Diffusion is the movement of a particular nutrient along a concentration gradient. When there is a difference in concentration of a particular nutrient within the soil solution, the nutrient will move from an area of higher concentration to an area of lower concentration. • This phenomenon is observed when adding sugar to water. As the sugar dissolves, it moves through parts of the water with lower sugar concentration until it is evenly distributed, or uniformly concentrated. Diffusion delivers appreciable amounts of phosphorus, potassium, zinc, and iron to the root surface. Diffusion is a relatively slow process compared to the mass flow of nutrients with water movement toward the root. Nutrients supplied primarily by diffusion are considered immobile nutrients e.g. P, K
  • 33. Factors affecting diffusion • a. Fick's law is given as dC/dt = De * A * dC/dX • dC/dt = diffusion rate (change in concentration over time) De = effective diffusion coefficient A = cross sectional area for diffusion • dC/dX = concentration gradient (change in concentration over distance) • Diffusion rate is directly proportional to concentration gradient, diffusion coefficient, and the area available for diffusion to occur
  • 34. b. Effective diffusion coefficient • Effective diffusion coefficient De = Dw * q * (1/T) * (1/b) where • Dw = diffusion coefficient in water q = volumetric soil water content T = tortuosity factor b = soil buffering capacity
  • 35. a. Diffusion coefficient in water (Dw) • i. Includes a temperature factor • ii. Colder = slower diffusion b. Soil water content • i. Drier soil = slower diffusion • ii. Less water = less area to diffuse through c. Tortuosity • i. Pathways through soil are not direct • Ii. Around soil particles, through thin water films • Iii. Affected by texture and water content • More clay = longer diffusion pathway • Thinner water films = longer path d. Buffering capacity • i. Nutrients can be removed by adsorption as they move through soil, reducing diffusion rate • c. How far can nutrients diffuse in a growing season? • a. Diffusion distances are very short • i. K ~ 0.2 cm • ii. P ~ 0.02 cm • b. Size and density of plant root systems is very important for nutrients supplied by diffusion • c. Has implications for fertilizer lacement
  • 36. • Ion traffic into the root • Mineral nutrients absorbed from the root has to be carried to the xylem. This transport follows two pathways namely apoplastic pathway and symplastic pathway. • In apoplastic pathway, mineral nutrients along with water moves from cell to cell through spaces between cell wall by diffusion. The ions, which enter the cell wall of the epidermis move across cell wall of cortex, cytoplasm of endodermis, cell walls of pericycle and finally reach the xylem. • In symplastic pathway, mineral nutrients entering the cytoplasm of the epidermis move across the cytoplasm of the cortex, endodermis of pericycle through plasmodesmata and finally reach the xylem.
  • 37.
  • 38. • Translocation of solutes • P.R. Stout and Dr. Hoagland have proved that mineral nutrients absorbed by the roots are translocated through the xylem vessel. Mineral salts dissolved in water moves up along the xylem vessel to be transported to all the parts of the plant body. Translocation is aided, by transpiration. As water is continuously lost by transpiration on the upper surfaces of the plant, it creates a transpirational pull, by which water along with mineral salts is pulled up along the xylem vessel.
  • 39. • Active absorption of energy can be achieved only by an input of energy. Following evidences show the involvement of metabolic energy in the absorption of mineral salts. • Higher rate of respiration increases the salt accumulation inside the cell. • Respiratory inhibitors check the process of salt uptake. • By decreasing oxygen content in the medium, the salt absorption is also decreased.
  • 40. Text book and web sources - www. agriinfo.in - ecourses.iasri.res.in - Soil science and management by Edward J. Plaster - Anand Agricultural university theory notes