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Other useful substances from
          crude oil
Key words
Hydrocarbons
Cracked
Molecules
Vapours
Catalyst
Thermal decomposition
Alkanes
Alkenes
Double bond
Cracking
Alkenes

                              C2H4



                              C3H6




 What’s the    What’s the
 formula for   general
 these?        formula for   CnH2n
               alkenes?
Test for an unsaturated hydrocarbon (an alkene)


            Shake
Cracking

Hydrocarbons with shorter carbon chains are more
useful, so sometimes we cut longer chains into shorter
ones using the process of cracking.
A long alkane is heated, vaporised and passed over a
ceramic catalyst to produce a shorter alkane and an
alkene.
               C8H18 →      C4H10 + C4H8
               C10H22 →      C7H16 + C3H6


Note
Any combination of alkene and alkane can be made, including
straight and branched chains, so long as the numbers of atoms
balance.
Hydrocarbons are compounds made of only hydrogen and
carbon atoms.

Hydrocarbons – for example methane (CH4) – burn very well producing
only carbon dioxide (CO2) and water (H2O):

                       CH4 + 2O2 → CO2 +2 H2O

Alkanes
These are the simplest hydrocarbons. They are ‘saturated’ which means
they only contain single bonds. They are pretty unreactive but burn well
making them good fuels.

Alkenes
These are hydrocarbons containing a C=C double bond. The double bond
makes them quite reactive and they are used as a starting material to
make many other organic compounds.
The equation below shows the cracking of a hydrocarbon compound
   into two different compounds, A and B.




State two differences between the structures of compounds A and B.
 Compound A has fewer C atoms
 or Compound B has fewer H atoms              Compound A is reactive
      Compound A has C = C/double bond        or can be used to make
 or Compound A is unsaturated                 many substances
Why is compound A useful in industry?         or can be used in
                                              polymerisation/making
                                              plastics/named plastic
                                              or can be used as a fuel
In 1939 Roy Plunkett opened the valve on a new cylinder of tetrafluoroethene
gas. No gas came out!




   He cut the cylinder open and found that the gas had changed into a white
   solid. This solid was an addition polymer

Give the name of the addition polymer that formed inside the cylinder.

   poly(tetrafluoroethene) or polytetrafluoroethene

The structure of this polymer can be represented by the diagram below.

                      Draw the structure of the monomer, tetrafluoroethene, from
                      which it is formed
The diagram shows an apparatus that can be used to carry out cracking
reactions in a laboratory.




Why is aluminium oxide or broken porcelain used?

                                  catalyst or speeds up the reaction
Paraffin contains decane. The cracking of decane can be represented by the
equation below. A decane molecule is split into two smaller molecules.

Complete the equation by adding the formula of the other product.

           C10H22 (l) →.................... (l) + C2H4 (g)
               decaneS

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Other useful substances from crude oil

  • 1. Other useful substances from crude oil
  • 3. Alkenes C2H4 C3H6 What’s the What’s the formula for general these? formula for CnH2n alkenes?
  • 4. Test for an unsaturated hydrocarbon (an alkene) Shake
  • 5. Cracking Hydrocarbons with shorter carbon chains are more useful, so sometimes we cut longer chains into shorter ones using the process of cracking. A long alkane is heated, vaporised and passed over a ceramic catalyst to produce a shorter alkane and an alkene. C8H18 → C4H10 + C4H8 C10H22 → C7H16 + C3H6 Note Any combination of alkene and alkane can be made, including straight and branched chains, so long as the numbers of atoms balance.
  • 6. Hydrocarbons are compounds made of only hydrogen and carbon atoms. Hydrocarbons – for example methane (CH4) – burn very well producing only carbon dioxide (CO2) and water (H2O): CH4 + 2O2 → CO2 +2 H2O Alkanes These are the simplest hydrocarbons. They are ‘saturated’ which means they only contain single bonds. They are pretty unreactive but burn well making them good fuels. Alkenes These are hydrocarbons containing a C=C double bond. The double bond makes them quite reactive and they are used as a starting material to make many other organic compounds.
  • 7. The equation below shows the cracking of a hydrocarbon compound into two different compounds, A and B. State two differences between the structures of compounds A and B. Compound A has fewer C atoms or Compound B has fewer H atoms Compound A is reactive Compound A has C = C/double bond or can be used to make or Compound A is unsaturated many substances Why is compound A useful in industry? or can be used in polymerisation/making plastics/named plastic or can be used as a fuel
  • 8. In 1939 Roy Plunkett opened the valve on a new cylinder of tetrafluoroethene gas. No gas came out! He cut the cylinder open and found that the gas had changed into a white solid. This solid was an addition polymer Give the name of the addition polymer that formed inside the cylinder. poly(tetrafluoroethene) or polytetrafluoroethene The structure of this polymer can be represented by the diagram below. Draw the structure of the monomer, tetrafluoroethene, from which it is formed
  • 9. The diagram shows an apparatus that can be used to carry out cracking reactions in a laboratory. Why is aluminium oxide or broken porcelain used? catalyst or speeds up the reaction
  • 10. Paraffin contains decane. The cracking of decane can be represented by the equation below. A decane molecule is split into two smaller molecules. Complete the equation by adding the formula of the other product. C10H22 (l) →.................... (l) + C2H4 (g) decaneS