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Explosives, Theory
of Breakage and
Blasting Operations



  Author: Partha Das Sharma, B.Tech(Hons.) in Mining Engineering,
  E.mail: sharmapd1@gmail.com, Website: http://miningandblasting.wordpress.com/
Introduction

General types of Explosives

     • Commercial explosives

     • Military explosives




                               2
Explosive Ingredients and their Function
         Ingredient            Chemical formula                        Function
Ethylene glycol dinitrate      C2H4(NO3)2         Explosive base – lowers freezing point
Nitrocellulose (guncotton)     C6H7(NO3)2O2       Explosive base – gelatinizing agent
Nitroglycerin                  C3H5(NO3)3         Explosive base
Nitrostarch                                       Explosive base
Trinitrotoluene (TNT)          C7H5N3O6           Explosive base
Metallic powder                Al                 Fuel sensitizer : used in high density slurries
Black powder                   NaNO3 + C+ S       Explosive base
Pentaerythritol tetranitrate   C3H8N4O12          Explosive base
(PETN)
Lead azide                     Pb(N3)2            Explosive used in blasting caps
Mercury fulminate              Hg(ONC)2           Explosive used in blasting caps
Ammonium nitrate               NH4NO3             Explosive base : oxygen carrier
Liquid oxygen                  O2                 Oxygen carrier
Sodium nitrate                 NaNO3              Oxygen carrier – lowers freezing point
Potassium nitrate              KNO3               Oxygen carrier
Ground coal - Charcoal         C                  Combustible, or fuel
Paraffin                       CnH2n+2            Combustible, or fuel
Sulfur                         S                  Combustible, or fuel
Fuel oil                       (CH3)2(CH2)        Combustible, or fuel
Wood pulp                      (C6H16O3)n         Combustible, absorbent
Lampblack                      C                  Combustible
Kieselguhr                     SiO2               Absorbent – prevents caking
Chalk -Calcium carbonate       CaCO3              Antacid
Zinc oxide                     ZnO                Antacid
                                                                                                    3
Sodium chloride                NaCI               Flame depressant (permissible explosives)
Chemical explosives


• is a compound or mixture which is capable of
  undergoing extremely rapid decomposition.

• An explosion can be broken down into four
  phases
  •   Release of gas
  •   Intense heat
  •   Extreme pressure, and
  •   The explosion

                                                 4
Chemical explosives


When the explosive is detonated,

•   gas is released,
•   temperature of the gas increases,
•   pressure also increases (Charles’ law).
•   move and break the rock.
                                              5
How to compare explosives


• Strength
• Detonating velocity
• Fume class            •   Detonation pressure
• Water resistance      •   Energy
• Density               •   Sensitivity
• Physical
  characteristics       •   Sensitiveness
• Storage               •   Flammability
• Freezing

                                             6
How to compare explosives




• Strength : % of active material

• Velocity of Detonating (VOD): is the velocity at
  which the detonation wave moves through the
  explosive (ft/s or m/s)

• Fume class : the amount of toxic fumes which
  determine its safety to be used in particular
  situation such as underground operations.
                                                 7
How to compare explosives




• Detonation pressure : is the pressure behind
  the detonation front.
• Energy
• Sensitivity : the minimum energy/pressure
  needed for detonation.
• Sensitiveness: measure of explosion wave
  spreading from one stick to another.
• Flammability : easiness to ignite by flame or
  heat
                                              8
How to compare explosives




• Water resistance : is the ability to resist
  contamination or a reduction in strength when
  exposed to water. Sometimes determined by the
  length of time it can be submerged in water and
  still perform as designed.

• Density : is the explosive wt per given volume.
  Aid in blast design.
                                                    9
How to compare explosives




• Physical     characteristics:   commercial
  explosives can take three basic forms:
  granular, gelatin, slurry and emulsion. The
  choice of form depends on the usage
  required.


                                           10
How to compare explosives



• Storage: how explosive can be stored without
  affecting its safety, reliability, and performance.
  Early nitroglycerin (NG) dynamites were
  extremely poor for storing due to separation of NG
  from the other components and creates an
  extremely hazardous condition.
• Freezing : important for safety and performance
  especially in cold climate. Anitfreezing additives
  may be used.
                                                   11
Drills and Drilling



• The drilling system consists of the drill: the drill
  steel, or rod; and the bit. The bit penetrates the
  rock by the force it imposes on the rock. Bits are
  designed for percussion, rotary drilling, or both.
• Hand held drills
• External –percussion drills
• Down-the-hole drills
• Rotary drills
                                                     12
Theory of Breakage


Purpose of blasting
• One solid piece → smaller pieces (fragmentation)
  → to be moved or excavated (movement).
• Underground blasting, for example, requires
  greater fragmentation than surface blasting
  because of the size of the equipment that can be
  used and the difficulty of access.
• Get the desired results with a minimum cost
                                                13
Theory of Breakage


Involves two basic processes:
   • Radial cracking
   • Flexural rupture
• Rock is stronger in compression than in tension.
  Therefore, the easiest way to break rock is to
  subject it to a tensile stress greater than its ultimate
  strength in tension.
• Rocks are heterogeneous (contain different types
  of rocks). They differ in their density.
                                                        14
Theory of Breakage




Free face




                       Compression
            Borehole     waves
                                     Radial cracking
                                                       15
Theory of Breakage



• The distance from the borehole to the free face is
  the burden.
• The denser the rock the faster the waves
• Proper fragmentation when enough to travel to the
  face and back overcoming the tensile strength of
  the rock.
• Along the face the outermost edge is stretched in
  tension which causes cracks.
                                                  16
Flexural Rupture




• The second process in breaking rock by bending
  the rock to the point where the outside edge, the
  side in tension, breaks.
• Caused by the rapid expansion of gases in
  borehole.
• Analogous to the bending and breaking of a beam.
• Movement or displacement are required in
  addition to cracking.
                                                 17
Flexural Rupture




• After detonation the redial cracks expands
  and the gas starts to the movement by
  putting a CS against the borehole wall
  causing its bending.
• The deeper the hole, the greater the burden
  and borehole spacing.

                                                18
Blast Design


• Is the safe and economic way to do blasting

• Factors affecting blasting design
• Geological factors (out of blaster’s control)
• Controllable factors
   •   Borehole dia.
   •   Burden
   •   Spacing
   •   Stemming
   •   Design of the delay firing system.
                                                  19
Burden & spacing


 Burden is the distance from the blast hole to the nearest perpendicular free face.

                                Spacing




                                            Burden




                                                                                      20
Free face
Burden & spacing determination



Andersen Formula                   B= (dL)0.5
• B : burden, ft          d : borehole dia, in
• L : borehole Length, ft

• Langefors’ Formula                   V= (db/33) [Ps/cf(E/V)]0.5

•   V : burden, m             db : dia of drill bit, mm
•   P : degree of packing = 1-1.6 kg/dm3
•   s : wt strength of explosives (1.3 for gelatin)
•   c : rock constant, generally 0.45
•   f : 1 degree of fraction, for straight hole = 1
•   E/V = ratio of spacing to burden
                                                                    21
Spacing determination


Spacing is the distance between blast holes fired in
  the same row
• It is necessary to complete burden calculations
  before determining the spacing.

   S= (BL)0.5

• B : burden, ft
• L : borehole Length, ft
                                                       22
Controlled Blasting



To control overbreak and to aid the stability of
  the remaining rock formation.
• There are following methods:
  •   Line drilling (unloaded),
  •   Cushion blasting
  •   Smooth-wall blasting
  •   Presplitting
                                              23
Controlled Blasting – Line drilling



• Provides a plane of weakness to which the rock can break.
• Helps to reflect shock waves,
• Reduces the shattering effect of the rock outside the
  perimeter.
• Do not exceed 3 in in dia and are spaced one to four
  diameters apart (due to cost).
• Are not loaded
• Requires more drilling more than the other controlled
  blasting methods.
• Is not very effective in non-homogeneous formations.
                                                          24
Controlled Blasting – Line drilling




Free                           Unloaded
face                           line drill
                               holes




                                            25
Cushion Blasting


• Requires a single row of holes ( 2 to 3.5 in) in dia.
• Permits a reduction in the No. of holes required by line-drilling
• Unlike line-drilling holes, the cushion holes are loaded with
  light charges.
• Holes are fully stemmed between charges, allowing no air gap,
  and are fired after the production shot has been excavated.
• The stemming acts as a cushion to protect the finished wall from
  the shock waves. The larger the borehole, the greater the
  cushion.
• Not suitable for underground - tough stemming requirements.
• Drawbacks: (1) requires removal of excavated material before
  firing (costly due to production delay – no excavation for entire
  area at once). (2) Sometimes the production shot can break back
  to the cushion holes, creating redrilling problems and causing
  loading changes.                                                  26
Smooth-wall Blasting


• Similar to cushion blasting




                                27
Pre-splitting



• Creates a plane of shear in solid rows along
  the desired excavation before the production
  blast.
• All holes are loaded like cushion blasting
• Reduces overbreak
• Reduces the vibration
                                             28

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Explosives, Theory Of Breakage And Blasting Operations

  • 1. Explosives, Theory of Breakage and Blasting Operations Author: Partha Das Sharma, B.Tech(Hons.) in Mining Engineering, E.mail: sharmapd1@gmail.com, Website: http://miningandblasting.wordpress.com/
  • 2. Introduction General types of Explosives • Commercial explosives • Military explosives 2
  • 3. Explosive Ingredients and their Function Ingredient Chemical formula Function Ethylene glycol dinitrate C2H4(NO3)2 Explosive base – lowers freezing point Nitrocellulose (guncotton) C6H7(NO3)2O2 Explosive base – gelatinizing agent Nitroglycerin C3H5(NO3)3 Explosive base Nitrostarch Explosive base Trinitrotoluene (TNT) C7H5N3O6 Explosive base Metallic powder Al Fuel sensitizer : used in high density slurries Black powder NaNO3 + C+ S Explosive base Pentaerythritol tetranitrate C3H8N4O12 Explosive base (PETN) Lead azide Pb(N3)2 Explosive used in blasting caps Mercury fulminate Hg(ONC)2 Explosive used in blasting caps Ammonium nitrate NH4NO3 Explosive base : oxygen carrier Liquid oxygen O2 Oxygen carrier Sodium nitrate NaNO3 Oxygen carrier – lowers freezing point Potassium nitrate KNO3 Oxygen carrier Ground coal - Charcoal C Combustible, or fuel Paraffin CnH2n+2 Combustible, or fuel Sulfur S Combustible, or fuel Fuel oil (CH3)2(CH2) Combustible, or fuel Wood pulp (C6H16O3)n Combustible, absorbent Lampblack C Combustible Kieselguhr SiO2 Absorbent – prevents caking Chalk -Calcium carbonate CaCO3 Antacid Zinc oxide ZnO Antacid 3 Sodium chloride NaCI Flame depressant (permissible explosives)
  • 4. Chemical explosives • is a compound or mixture which is capable of undergoing extremely rapid decomposition. • An explosion can be broken down into four phases • Release of gas • Intense heat • Extreme pressure, and • The explosion 4
  • 5. Chemical explosives When the explosive is detonated, • gas is released, • temperature of the gas increases, • pressure also increases (Charles’ law). • move and break the rock. 5
  • 6. How to compare explosives • Strength • Detonating velocity • Fume class • Detonation pressure • Water resistance • Energy • Density • Sensitivity • Physical characteristics • Sensitiveness • Storage • Flammability • Freezing 6
  • 7. How to compare explosives • Strength : % of active material • Velocity of Detonating (VOD): is the velocity at which the detonation wave moves through the explosive (ft/s or m/s) • Fume class : the amount of toxic fumes which determine its safety to be used in particular situation such as underground operations. 7
  • 8. How to compare explosives • Detonation pressure : is the pressure behind the detonation front. • Energy • Sensitivity : the minimum energy/pressure needed for detonation. • Sensitiveness: measure of explosion wave spreading from one stick to another. • Flammability : easiness to ignite by flame or heat 8
  • 9. How to compare explosives • Water resistance : is the ability to resist contamination or a reduction in strength when exposed to water. Sometimes determined by the length of time it can be submerged in water and still perform as designed. • Density : is the explosive wt per given volume. Aid in blast design. 9
  • 10. How to compare explosives • Physical characteristics: commercial explosives can take three basic forms: granular, gelatin, slurry and emulsion. The choice of form depends on the usage required. 10
  • 11. How to compare explosives • Storage: how explosive can be stored without affecting its safety, reliability, and performance. Early nitroglycerin (NG) dynamites were extremely poor for storing due to separation of NG from the other components and creates an extremely hazardous condition. • Freezing : important for safety and performance especially in cold climate. Anitfreezing additives may be used. 11
  • 12. Drills and Drilling • The drilling system consists of the drill: the drill steel, or rod; and the bit. The bit penetrates the rock by the force it imposes on the rock. Bits are designed for percussion, rotary drilling, or both. • Hand held drills • External –percussion drills • Down-the-hole drills • Rotary drills 12
  • 13. Theory of Breakage Purpose of blasting • One solid piece → smaller pieces (fragmentation) → to be moved or excavated (movement). • Underground blasting, for example, requires greater fragmentation than surface blasting because of the size of the equipment that can be used and the difficulty of access. • Get the desired results with a minimum cost 13
  • 14. Theory of Breakage Involves two basic processes: • Radial cracking • Flexural rupture • Rock is stronger in compression than in tension. Therefore, the easiest way to break rock is to subject it to a tensile stress greater than its ultimate strength in tension. • Rocks are heterogeneous (contain different types of rocks). They differ in their density. 14
  • 15. Theory of Breakage Free face Compression Borehole waves Radial cracking 15
  • 16. Theory of Breakage • The distance from the borehole to the free face is the burden. • The denser the rock the faster the waves • Proper fragmentation when enough to travel to the face and back overcoming the tensile strength of the rock. • Along the face the outermost edge is stretched in tension which causes cracks. 16
  • 17. Flexural Rupture • The second process in breaking rock by bending the rock to the point where the outside edge, the side in tension, breaks. • Caused by the rapid expansion of gases in borehole. • Analogous to the bending and breaking of a beam. • Movement or displacement are required in addition to cracking. 17
  • 18. Flexural Rupture • After detonation the redial cracks expands and the gas starts to the movement by putting a CS against the borehole wall causing its bending. • The deeper the hole, the greater the burden and borehole spacing. 18
  • 19. Blast Design • Is the safe and economic way to do blasting • Factors affecting blasting design • Geological factors (out of blaster’s control) • Controllable factors • Borehole dia. • Burden • Spacing • Stemming • Design of the delay firing system. 19
  • 20. Burden & spacing Burden is the distance from the blast hole to the nearest perpendicular free face. Spacing Burden 20 Free face
  • 21. Burden & spacing determination Andersen Formula B= (dL)0.5 • B : burden, ft d : borehole dia, in • L : borehole Length, ft • Langefors’ Formula V= (db/33) [Ps/cf(E/V)]0.5 • V : burden, m db : dia of drill bit, mm • P : degree of packing = 1-1.6 kg/dm3 • s : wt strength of explosives (1.3 for gelatin) • c : rock constant, generally 0.45 • f : 1 degree of fraction, for straight hole = 1 • E/V = ratio of spacing to burden 21
  • 22. Spacing determination Spacing is the distance between blast holes fired in the same row • It is necessary to complete burden calculations before determining the spacing. S= (BL)0.5 • B : burden, ft • L : borehole Length, ft 22
  • 23. Controlled Blasting To control overbreak and to aid the stability of the remaining rock formation. • There are following methods: • Line drilling (unloaded), • Cushion blasting • Smooth-wall blasting • Presplitting 23
  • 24. Controlled Blasting – Line drilling • Provides a plane of weakness to which the rock can break. • Helps to reflect shock waves, • Reduces the shattering effect of the rock outside the perimeter. • Do not exceed 3 in in dia and are spaced one to four diameters apart (due to cost). • Are not loaded • Requires more drilling more than the other controlled blasting methods. • Is not very effective in non-homogeneous formations. 24
  • 25. Controlled Blasting – Line drilling Free Unloaded face line drill holes 25
  • 26. Cushion Blasting • Requires a single row of holes ( 2 to 3.5 in) in dia. • Permits a reduction in the No. of holes required by line-drilling • Unlike line-drilling holes, the cushion holes are loaded with light charges. • Holes are fully stemmed between charges, allowing no air gap, and are fired after the production shot has been excavated. • The stemming acts as a cushion to protect the finished wall from the shock waves. The larger the borehole, the greater the cushion. • Not suitable for underground - tough stemming requirements. • Drawbacks: (1) requires removal of excavated material before firing (costly due to production delay – no excavation for entire area at once). (2) Sometimes the production shot can break back to the cushion holes, creating redrilling problems and causing loading changes. 26
  • 27. Smooth-wall Blasting • Similar to cushion blasting 27
  • 28. Pre-splitting • Creates a plane of shear in solid rows along the desired excavation before the production blast. • All holes are loaded like cushion blasting • Reduces overbreak • Reduces the vibration 28