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Geochemistry 319
Table of Contents
1. Introduction and Periodic Table
2. Abundance of elements ( Crust Universe and Whole Earth)
3. Recalculation of Mineral Formulae
4. Radiometric dating of rocks
5. Interpretation of chemical analyses. Use of Niggli Values
Mid-Term Exam
6. Interpretation of chemical analyses. Use of CIPW Norm Calculations
7. Interpretation of chemical analyses. CIPW Norm Calculations (Mafic Rocks)
8. Continuation of CIPW Norm Calculations (Ultramafic Rocks)
9. Classification and Naming of the Igneous Rocks
10. Use of ACF Diagrams to Interpret Metamorphic Rocks
The Final
Periodic Table
• The periodic table is divided into four blocks (s, p, d, f) based on
which sublevel is in the process of being filled. Alkali metals, alkaline
earth metals, halogens, and noble gases are the common names of
groups 1, 2, 17, and 18.
• Electro positive and electronegative elements
• The electron configuration of an element describes how electrons are
distributed in its atomic orbitals. Electron configurations of atoms
follow a standard notation in which all electron-containing atomic
subshells (with the number of electrons they hold written in
superscript) are placed in a sequence.
• 1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s<5f<6d<7p
• I: 1s22s22p63s23p64s23d104p65s24d105p5
• or
• I: [Kr]5s24d105p5
subshell number of orbitals
total number of
possible electrons
in each orbital
s 1 2
p 3 (px, py, pz) 6
d
5 (dx
2
-y
2
, dz
2
, dxy, dxz,
dyz)
10
f
7 (fz
3
, fxz
2
, fxyz, fx(x
2
-
3y
2
), fyz
2
, fz(x
2
-y
2
),
fy(3x
2
-y
2
)
14
Geochemical classification
•Recalculation of Mineral formula
Q 2. Follwing is the chemical analysis of a feldspar mineral. You are
required to
Calculate the chemical formula on the basis of 24 Oxygens.
Calculate the mole percent of Ab , An and Or.
Predict the type and name of feldspar by plotting on the triangular
(ternary) diagram.
Radiometric Dating of Rocks
Isotopes
• Isotopes are variants of a particular chemical element which differ in neutron
number, and consequently in nucleon number. All isotopes of a given element
have the same number of protons but different numbers of neutrons in each
atom.
• The abundances of parent and daughter isotopes in a sample can be measured
and used to determine their age. This method is known as radiometric dating.
The amount of time that it takes for half of the parent isotope to decay into
daughter isotopes is called the half-life of an isotope
• Radiometric dating, often called radioactive dating, is a technique used to
determine the age of materials such as rocks. It is based on a comparison
between the observed abundance of a naturally occurring radioactive isotope
and its decay products, using known decay rates.
• Carbon, uranium, and potassium are just a few examples of elements used in
radioactive dating. Each element is made up of atoms, and within each atom is a
central particle called a nucleus. Within the nucleus, we find neutrons and
protons; but for now, let's just focus on the neutrons
The ratio of parent to daughter after one half-life will be 1:1. After two half-lives,
half of the remaining half will decay, leaving one-quarter of the original
radioactive parent atoms. Those transformed atoms bring the tally
of daughter atoms to three-quarters of the crop of parent plus daughter atoms.
Radiocarbon dating is also simply called carbon-14 dating. Carbon-14 is a
radioactive isotope of carbon, with a half-life of 5,730 years (which is very short
compared with the above isotopes), and decays into nitrogen.
When an organism dies, it ceases to take in new carbon-14, and the existing isotope decays
with a characteristic half-life (5730 years). The proportion of carbon-14 left when the
remains of the organism are examined provides an indication of the time elapsed since its
death.
The rate of decay is conveniently expressed in terms of an isotope's half-life, or the time it
takes for one-half of a particular radioactive isotope in a sample to decay.
Most radioactive isotopes have rapid rates of decay (that is, short half-lives) and lose their
radioactivity within a few days or years.
Age calculations
• https://youtu.be/T7ivdB2qQyo
• https://youtu.be/sc7xvgJ7Sn8
• https://youtu.be/K8IaH3adKz8
• https://youtu.be/j4jSywmXrcU
https://youtu.be/rQVzNynZ9vM
Radiocarbon dating (also referred to as carbon dating or carbon-14
dating) is a method for determining the age of an object containing
organic material by using the properties of radiocarbon,
a radioactive isotope of carbon. ... The development
of radiocarbon dating has had a profound impact on archaeology.
https://youtu.be/5aX2YcOjyKE
Cathedral Peak granodiorite
y = 0.0014x + 0.7063
R2
= 0.9109
0.706
0.7062
0.7064
0.7066
0.7068
0.707
0.7072
0.7074
0.7076
0.7078
0.708
0.000 0.200 0.400 0.600 0.800 1.000 1.200 1.400
87Rb/86Sr
87Sr/86Sr
• . Using the decay equation and the calculated slope from the
isochron plot:
• Slope = λt; or t = Slope/ (1.42 x 10-11)
•
• For the Cathedral Peak Batholith, the calculated slope is: 0.001336;
• the calculated Sri (intercept) is: .7063
•
• t = (.00136)/(1.42 x 10-11) = 9.58 x 107 ≈ 96 Ma (million years)
Geochemistry
Niggli Values
Munawer Khan
CIPW Norm Calculations
Classification of Rocks
ACF Diagrams
• A=0.156+0.0326-(0.0678+0.0114)= 0.1094=24%
• C=.0.0784-(3.33*0.0008)=0.0757=17%
• F=0.0851+0.1811=0.2662=59%
• A+C+F=0.4513
END
THANK YOU
GOOD LUCK

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Geochem all Labs. Lab for geochemistry a branch

  • 1. Geochemistry 319 Table of Contents 1. Introduction and Periodic Table 2. Abundance of elements ( Crust Universe and Whole Earth) 3. Recalculation of Mineral Formulae 4. Radiometric dating of rocks 5. Interpretation of chemical analyses. Use of Niggli Values Mid-Term Exam 6. Interpretation of chemical analyses. Use of CIPW Norm Calculations 7. Interpretation of chemical analyses. CIPW Norm Calculations (Mafic Rocks) 8. Continuation of CIPW Norm Calculations (Ultramafic Rocks) 9. Classification and Naming of the Igneous Rocks 10. Use of ACF Diagrams to Interpret Metamorphic Rocks The Final
  • 2.
  • 3. Periodic Table • The periodic table is divided into four blocks (s, p, d, f) based on which sublevel is in the process of being filled. Alkali metals, alkaline earth metals, halogens, and noble gases are the common names of groups 1, 2, 17, and 18. • Electro positive and electronegative elements
  • 4.
  • 5. • The electron configuration of an element describes how electrons are distributed in its atomic orbitals. Electron configurations of atoms follow a standard notation in which all electron-containing atomic subshells (with the number of electrons they hold written in superscript) are placed in a sequence. • 1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s<5f<6d<7p • I: 1s22s22p63s23p64s23d104p65s24d105p5 • or • I: [Kr]5s24d105p5
  • 6. subshell number of orbitals total number of possible electrons in each orbital s 1 2 p 3 (px, py, pz) 6 d 5 (dx 2 -y 2 , dz 2 , dxy, dxz, dyz) 10 f 7 (fz 3 , fxz 2 , fxyz, fx(x 2 - 3y 2 ), fyz 2 , fz(x 2 -y 2 ), fy(3x 2 -y 2 ) 14
  • 7.
  • 8.
  • 9.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.
  • 18.
  • 19.
  • 20.
  • 21.
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28. Q 2. Follwing is the chemical analysis of a feldspar mineral. You are required to Calculate the chemical formula on the basis of 24 Oxygens. Calculate the mole percent of Ab , An and Or. Predict the type and name of feldspar by plotting on the triangular (ternary) diagram.
  • 29.
  • 31. Isotopes • Isotopes are variants of a particular chemical element which differ in neutron number, and consequently in nucleon number. All isotopes of a given element have the same number of protons but different numbers of neutrons in each atom. • The abundances of parent and daughter isotopes in a sample can be measured and used to determine their age. This method is known as radiometric dating. The amount of time that it takes for half of the parent isotope to decay into daughter isotopes is called the half-life of an isotope • Radiometric dating, often called radioactive dating, is a technique used to determine the age of materials such as rocks. It is based on a comparison between the observed abundance of a naturally occurring radioactive isotope and its decay products, using known decay rates. • Carbon, uranium, and potassium are just a few examples of elements used in radioactive dating. Each element is made up of atoms, and within each atom is a central particle called a nucleus. Within the nucleus, we find neutrons and protons; but for now, let's just focus on the neutrons
  • 32.
  • 33. The ratio of parent to daughter after one half-life will be 1:1. After two half-lives, half of the remaining half will decay, leaving one-quarter of the original radioactive parent atoms. Those transformed atoms bring the tally of daughter atoms to three-quarters of the crop of parent plus daughter atoms.
  • 34.
  • 35.
  • 36. Radiocarbon dating is also simply called carbon-14 dating. Carbon-14 is a radioactive isotope of carbon, with a half-life of 5,730 years (which is very short compared with the above isotopes), and decays into nitrogen. When an organism dies, it ceases to take in new carbon-14, and the existing isotope decays with a characteristic half-life (5730 years). The proportion of carbon-14 left when the remains of the organism are examined provides an indication of the time elapsed since its death. The rate of decay is conveniently expressed in terms of an isotope's half-life, or the time it takes for one-half of a particular radioactive isotope in a sample to decay. Most radioactive isotopes have rapid rates of decay (that is, short half-lives) and lose their radioactivity within a few days or years.
  • 37.
  • 38.
  • 39. Age calculations • https://youtu.be/T7ivdB2qQyo • https://youtu.be/sc7xvgJ7Sn8 • https://youtu.be/K8IaH3adKz8 • https://youtu.be/j4jSywmXrcU
  • 40. https://youtu.be/rQVzNynZ9vM Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon, a radioactive isotope of carbon. ... The development of radiocarbon dating has had a profound impact on archaeology. https://youtu.be/5aX2YcOjyKE
  • 41.
  • 42.
  • 43.
  • 44.
  • 45. Cathedral Peak granodiorite y = 0.0014x + 0.7063 R2 = 0.9109 0.706 0.7062 0.7064 0.7066 0.7068 0.707 0.7072 0.7074 0.7076 0.7078 0.708 0.000 0.200 0.400 0.600 0.800 1.000 1.200 1.400 87Rb/86Sr 87Sr/86Sr
  • 46. • . Using the decay equation and the calculated slope from the isochron plot: • Slope = λt; or t = Slope/ (1.42 x 10-11) • • For the Cathedral Peak Batholith, the calculated slope is: 0.001336; • the calculated Sri (intercept) is: .7063 • • t = (.00136)/(1.42 x 10-11) = 9.58 x 107 ≈ 96 Ma (million years)
  • 48.
  • 49.
  • 50.
  • 51.
  • 52.
  • 54.
  • 55.
  • 56.
  • 57.
  • 58.
  • 59.
  • 60.
  • 61.
  • 62.
  • 63.
  • 64.
  • 65.
  • 66.
  • 67.
  • 69.
  • 70.
  • 71.
  • 72.
  • 73.
  • 74.
  • 75.
  • 76.
  • 77.
  • 78.
  • 79.
  • 80.
  • 81.
  • 83.
  • 84.
  • 85.
  • 86.
  • 87.
  • 88.
  • 89. • A=0.156+0.0326-(0.0678+0.0114)= 0.1094=24% • C=.0.0784-(3.33*0.0008)=0.0757=17% • F=0.0851+0.1811=0.2662=59% • A+C+F=0.4513
  • 90.
  • 91.
  • 92.
  • 93.
  • 94.
  • 95.