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6   Matter, Forces,
UNIT
           and Energy




        How Are
      Train Schedules
        & Oil Pumps
           Connected?

524
I  n the 1800s, trains had to make frequent stops so that their moving parts could be lubricated.
   Without lubrication, the parts would have worn out due to friction. When the train stopped, a
worker had to get out and oil the parts by hand. The process was very time-consuming and made
it hard for trains to stay on schedule. Around 1870, an engineer named Elijah McCoy developed
the first automatic lubricating device, which oiled the engine while the train was running. (A
later version of his automatic lubricator is seen at lower right.) Since then, many kinds of auto-
matic lubricating devices have been developed. Today, automobiles have oil pumps that auto-
matically circulate oil to the moving parts of the engine. When you go for a ride in a car, you can
thank Elijah McCoy that you don’t have to stop every few miles to oil the engine by hand!




                                SCIENCE CONNECTION
                                    FRICTION AND LUBRICANTS A lubricant is a substance that reduces friction
                                    between surfaces that touch one another. Some of the world’s first lubricants
                                    were animal and plant products such as lard and vegetable oils. Conduct research
                                    to identify a variety of modern-day lubricants. Select one lubricant you learned
                                    about and create a poster that shows its source, how it is made or processed, its
                                    special properties, and how it is used to reduce friction.
18 Properties and
                                Changes of Matter
W
           endy Craig Duncan car-
           ried the Olympic flame
           underwater on the way to
the 2000 Summer Olympics in Syd-
ney, Australia. How many different
states of matter can you find in this
picture? What chemical and physical
changes are taking place? In this
chapter, you will learn about the four
states of matter, the physical and
chemical properties of matter, and
how those properties can change.

What do you think?
Science Journal What is the colored
band on this fish tank? Why would it
change colors? Here’s a hint: Would
you want your fish to be chilly? Write
your thoughts and ideas in your
Science Journal.




526
EXPLORE Y
                                                        our teacher has given you a collection of pennies.
                                                        It is your task to separate these pennies into

                           ACTIVITY                 groups while using words to describe each set. In this
                                                    chapter, you will learn how to identify things based
                                                    on their physical and chemical properties. With an
                          understanding of these principles of matter, you will discover how things are
                          classified or put into groups.

                          Classify coins
                           1. Observe the collection of pennies.
                           2. Choose a characteristic that will
                              allow you to separate the pennies
                              into groups.
                           3. Classify and sort each penny
                              based on the chosen feature.
                              Tally your data in a frequency
                              table.
                           4. Explain how you classified the
                              pennies. Compare your system of
                              classification with those of others
                              in the classroom.

                          Observe
                          Think about how your group classified its pennies. Describe the system your
                          group used in your Science Journal.


FOLDABLES
Reading & Study         Making an Organizational Study Fold Make the following
Skills
                        Foldable to help you organize your thoughts into clear categories
                        about properties of matter.
                                                                                        Physical      Chemical
                                                                                       Properties    Properties
1. Place a sheet of paper in front of you so the long side is at the top.
   Fold the paper in half from the left side to the right side. Unfold.
2. Fold each side in to the center fold line to divide the paper into
                                                                                          al        Chemic
   fourths. Fold the paper in half from top to bottom. Unfold.                      Physics               a
                                                                                                    Chang l
                                                                                         e
                                                                                   Chang                 es

3. Through the top thickness of paper, cut along both of the middle fold
   lines to form four tabs. Label the tabs Physical Properties, Physical
   Changes, Chemical Properties, and Chemical Changes.
4. Before you read the chapter, define each term on the front of the tabs.
   As you read the chapter, correct your definitions and write about each under the tabs.


                                                                                                              527
SECTION



                        Physical Properties
                          and Changes
                                        Using Your Senses
                                            As you look in your empty wallet and realize that your
s Identify physical properties          allowance isn’t coming anytime soon, you decide to get an after-
  of matter.                            school job. You’ve been hired at the new grocery store that will
s Describe the states of matter.        open next month. They are getting everything ready for the
s Classify matter using physical
                                        grand opening, and you will be helping make decisions about
  properties.
                                        where things will go and how they will be arranged.
Vocabulary                                  When you come into a new situation or have to make any
physical property     state of matter   kind of decision, what do you usually do first? Most people
matter                melting point
physical change       boiling point     would make some observations. Observing involves seeing,
density                                 hearing, tasting, touching, and smelling.
                                            Whether in a new job or in the laboratory, you use your
                                        senses to observe materials. Any characteristic of a material that
Observing physical properties           can be observed or measured without changing the identity of
will help you interpret the world       the material is a physical property. However, it is important to
around you.                             never taste, touch, or smell any of the materials being used in
                                        the lab without guidance, as noted in
                                        Figure 1. For safety reasons you will
                                        rely mostly on other observations.             Watch



                                                                                       Listen

Figure 1
For safety reasons, in                                                                 Do NOT
the laboratory you                                                                      touch
usually use only two
of your senses—sight
and hearing. Many                                                                      Do NOT
                                                                                        smell
chemicals can be dan-
gerous to touch,
taste, and smell.
                                                                                       Do NOT
                                                                                        taste




528
Figure 2
                                                                          The identity of the material
                                                                          does not necessarily depend on
                                                                          its color. Each of these bottles
                                                                          is made of high-density
                                                                          polyethylene (HDPE).




Physical Properties
    On the first day of your new job, the boss gives you an
inventory list and a drawing of the store layout. She explains
that every employee is going to give his or her input as to how
the merchandise should be arranged. Where will you begin?
    You decide that the first thing you’ll do is make some obser-
vations about the items on the list. One of the key senses used in
observing physical properties is sight, so you go shopping to
look at what you will be arranging.

Color and Shape Everything that you can see, touch, smell,
or taste is matter. Matter is anything that has mass and takes up
space. What things do you observe about the matter on your
inventory list? The list already is organized by similarity of prod-
ucts, so you go to an aisle and look.
    Color is the first thing you notice. The laundry detergent
bottles you are looking at come in every color. Maybe you will
organize them in the colors of the rainbow. You make a note and
look more closely. Each bottle or box has a different shape.
Some are square, some rectangular, and some are a free-form
shape. You could arrange the packages by their shape.
    When the plastic used to make the packaging is molded, it               Research Visit the
changes shape. However, the material is still plastic. This type of         Glencoe Science Web site at
change is called a physical change. It is important to realize that         science.glencoe.com
in a physical change, the physical properties of a substance                for more information about
change, but the identity of the substance does not change.                  classifying matter by its phys-
Notice Figure 2. The detergent bottles are made of high-density             ical properties. Communicate
polyethylene regardless of the differences in the physical proper-          to your class what you learn.
ties of color or shape.

                        What is matter?

                                                             SECTION 1 Physical Properties and Changes   529
Length and Mass Some properties of matter can be identi-
                                      fied by using your senses, and other properties can be measured.
                                      How much is there? How much space does it take up?
                                          One useful and measurable physical property is length.
                                      Length is measured using a ruler, meterstick, or tape measure,
                                      as shown in Figure 3. Objects can be classified by their length.
                                      For example, you could choose to organize the French bread
                                      in the bakery section of your store by the length of the loaf.
                                      But, even though the dough has been shaped in different
                                      lengths, it is still French bread.
                                          Back in the laundry aisle, you notice a child struggling to lift
                                      one of the boxes of detergent. That raises a question. How much
  Collect Data Visit the              detergent is in each box? Mass is a physical property that
  Glencoe Science Web site at         describes the amount of material in an object. Some of the
  science.glencoe.com for             boxes are heavy, but, the formula of the detergent hasn’t
  information about density.          changed from the small box to the large box. Organizing the
  Communicate to your class           boxes by mass is another option.
  what you learn.
                                      Volume and Density Mass isn’t the only physical property
                                      that describes how much of something you have. Another
                                      measurement is volume. Volume measures the amount of
                                      space an object takes up. Liquids usually are measured by
                                      volume. The juice bottles on your list could be organized
                                      by volume.
                                          Another measurable physical property related to mass and
                                      volume is density—the amount of mass a material has for a
                                      given volume. You notice this property when you try to lift two
Figure 3                              things of equal volume that have different masses. Density is
The length of any object              found by dividing the mass of an object by its volume.
can be measured with the
                                                    density ϭ massրvolume, or D ϭ mրV
appropriate tool.




530   CHAPTER 18 Properties and Changes of Matter
Figure 4
                                                                             These balls take up about the
                                                                             same space, but the bowling
                                                                             ball on the left has more mass
                                                                             than the kickball on the right.
                                                                             Therefore, the bowling ball is
                                                                             more dense.




          Bowling ball                          Kickball

Same Volume, Different Mass Figure 4 shows two balls
that are the same size but not the same mass. The bowling ball is
more dense than the kickball. The customers of your grocery
store will notice the density of their bags of groceries if the bag-
gers load all of the canned goods in one bag and put all of the
cereal and napkins in the other.
    The density of a material stays the same as long as pressure
and temperature stay the same. Water at room temperature has a
density of 1.00 g/cm3. However, when you do change the temper-
ature or pressure, the density of a material can change. Water kept             Changing Density
in the freezer at 0°C is in the form of ice. The density of that ice is
                                                                                Procedure
0.9168 g/cm3. Has the identity of water changed? No, but some-                  1. Stir three tablespoons of
thing has changed.                                                                 baking soda in 3/4 cup of
                                                                                   warm water. Set aside.
                         What two measurements are related in the               2. Pour vinegar into a clear
                         measurement of density?                                   glass until it is half full.
                                                                                3. Slowly pour the baking soda
                                                                                   and warm water mixture
States of Matter                                                                   into the glass of vinegar.
    What changes when water goes from 20°C to 0°C? It                           4. After most of the fizzing has
                                                                                   stopped, place three halves
changes from a liquid to a solid. The four states of matter are                    of raisins in the glass.
solid, liquid, gas, and plasma (PLAZ muh). The state of mat-                    5. Record your observations in
ter of a substance depends on its temperature and pressure.                        your Science Journal or on a
Three of these states of matter are things you talk about or                       computer.
experience every day, but the term plasma might be unfamil-                     Analysis
iar. The plasma state occurs at very high temperatures and is                   1. How did the bubbles affect
found in fluorescent (floo RE sunt) lightbulbs, the atmo-                          the raisins?
sphere, and in lightning strikes.                                               2. Infer what changed the
    As you look at the products to shelve in your grocery store,                   density of the raisins.
you might make choices of classification based on the state of
matter. The state of matter of a material is another physical
property. The liquid juices all will be in one place, and the solid,
frozen juice concentrates will be in another.

                                                                SECTION 1 Physical Properties and Changes   531
Moving Particles Matter is made up of moving particles.
                                       The state of matter is determined by how much energy the par-
                                       ticles have. The particles of a solid vibrate in a fixed position.
                                       They remain close together and give the solid a definite shape
                                       and volume. The particles of a liquid are moving much faster
                                       and have enough energy to slide past one another. This allows a
                                       liquid to take the shape of its container. The particles of a gas are
                                       moving so quickly that they have enough energy to move freely
                                       away from other particles. The particles of a gas take up as much
                                       space as possible and will spread out to fill any container.
                                       Figure 5 illustrates the differences in the states of water.

                                                                Which state of matter doesn’t conform to the
                                                                shape of the container?
Figure 5
Water can be in three different
                                       Changes of State You witness a change of state when you
states: solid, liquid, and gas. The
                                       put ice cubes in water and they melt. You still have water but in
molecules in a solid are tightly
packed and vibrate in place, but
                                       another form. The opposite physical change happens when you
in a liquid they can slip past each    put liquid water in ice-cube trays and pop them in your freezer.
other because they have more           The water doesn’t change identity—only the state it is in.
energy to move. In a gas, they             For your job, you will need to make some decisions based on
move freely all around the con-        the ability of materials to change state. You don’t want all those
tainer with even more energy.          frozen items thawing out and becoming slushy liquid. You also
                                       don’t want some of the liquids to get so cold that they freeze.




             Solid water                         Liquid water                        Gaseous water




532    CHAPTER 18 Properties and Changes of Matter
Melting and Boiling Points At
what temperature will water in the                            Liquid nitrogen
form of ice change into a liquid? The                       (below –195.8°C)
temperature at which a solid becomes
a liquid is its melting point. The                  Nitrogen gas
melting point of a pure substance              (above –195.8°C)
does not change with the amount of
the substance. This means that a
small sliver of ice and a block of ice
the size of a house both will melt at
0°C. Lead always melts at 327.5°C.
When a substance melts, it changes
from a solid to a liquid. This is a
physical change and the melting point
is a physical property.
     At what temperature will liquid
water change to a gas? The boiling
point is the temperature at which a substance in the liquid state            Figure 6
becomes a gas. Each pure substance has a unique boiling point at             When liquid nitrogen is poured
atmospheric pressure. The boiling point of water is 100°C at                 from a flask, you see an instant
atmospheric pressure. The boiling point of nitrogen is Ϫ195.8°C,             change to gas because nitrogen’s
so it changes to a gas when it warms after being spilled into the            boiling point is –195.8°C, which
open air, as shown in Figure 6. The boiling point, like the melting          is much lower than room
point, does not depend on the amount of the substance.                       temperature.

                         What physical change takes place at the
                         boiling point?

    However, the boiling point and melting point can help to
identify a substance. If you observe a clear liquid that boils at
56.1°C at atmospheric pressure, it is not water. Water boils at                    When geologists describe
100°C. If you know the boiling points and melting points of sub-                   rocks, they use specific
stances, you can classify substances based on those points.                        terms that have meaning to
                                                                                   all other scientists who
Metallic Properties                                                                read their descriptions. To
                                                                                   describe the appearance of
    Other physical properties allow you to classify substances as                  a rock or mineral, they use
metals. You already have seen how you can classify things as                       the following terms: metal-
solids, liquids, or gases or according to color, shape, length,                    lic, adamantine, vitreous,
mass, volume, or density. What properties do metals have?                          resinous, pearly, silky, and
                                                                                   greasy. Research these
                                                                                   terms and write a defini-
How do metals look and act? Often the first thing you                              tion and example of each in
notice about something that is a metal is its shiny appearance.                    your Science Journal.
This is due to the way light is reflected from the surface of the
metal. This shine is called luster. New handlebars on a bike have
a metallic luster. Words that describe the appearance of non-
metallic objects are pearly, milky, or dull.

                                                                   SECTION 1 Physical Properties and Changes   533
Figure 7
This artist has taken advantage
of the ductility of metal by
choosing wire as the medium
for her sculpture.

                                        Uses of Metals Metals can be used in unique ways because
                                        of some of the physical properties they have. For example, many
                                        metals can be hammered, pressed, or rolled into thin sheets.
                                        This property of metals is called malleability (mal lee uh BIH
                                        luh tee). The malleability of copper makes it an ideal choice for
                                        artwork such as the Statue of Liberty. Many metals can be drawn
                                        into wires as shown in Figure 7. This property is called ductility
                                        (duk TIH luh tee). The wires in buildings and most electrical
                                        equipment and household appliances are made from copper. Sil-
                                        ver and platinum are also ductile.
                                            You probably observe another physical property of some
                                        metals every day when you go to the refrigerator to get milk or
                                        juice for breakfast. Your refrigerator door is made of metal.
Figure 8                                Some metals respond to magnets. Most people make use of that
This junkyard magnet pulls scrap        property and put reminder notes, artwork, and photos on their
metal that can be salvaged from         refrigerators. Some metals have groups of atoms that can be
the rest of the debris. It is sorting   affected by the force of a magnet, and they are attracted to the
by a physical property.                 magnet because of that force. The magnet in Figure 8 is being
                                                                   used to select metallic objects.
                                                                       At the grocery store, your em-
                                                                   ployer might think about these prop-
                                                                   erties of metals as she looks at grocery
                                                                   carts and thinks about shelving. Mal-
                                                                   leable carts can be dented. How could
                                                                   the shelf ’s attraction of magnets be
                                                                   used to post advertisements or weekly
                                                                   specials? Perhaps the prices could be
                                                                   fixed to the shelves with magnetic
                                                                   numbers. After you observe the physi-
                                                                   cal properties of an object, you can
                                                                   make use of those properties.

534     CHAPTER 18 Properties and Changes of Matter
Using Physical
Properties
    In the previous pages,
many physical properties
were discussed. These physi-
cal properties—such as
appearance, state, shape,
length, mass, volume, ability
to attract a magnet, density,
melting point, boiling point,
malleability, and ductility—
can be used to help you iden-
tify, separate, and classify
substances.
    For example, salt can be
described as a white solid.
Each salt crystal, if you look
at it under a microscope,
could be described as having a three-dimensional cubic struc-           Figure 9
ture. You can measure the mass, volume, and density of a                Coins can be sorted by their phys-
sample of salt or find out if it would attract a magnet. These          ical properties. Sorting by size is
are examples of how physical properties can be used to iden-            used here.
tify a substance.

Sorting and Separating When you do laundry, you sort
according to physical properties. Perhaps you sort by color.
When you select a heat setting on an iron, you classify the
clothes by the type of fabric. When miners during the Gold
Rush panned for gold, they separated the dirt and rocks by den-
sity of particles. Figure 9 shows a coin sorter that separates the
coins based on their size. Iron filings can be separated from sand
by using a magnet.

                          Scientists who work with animals use
                          physical properties or characteristics
                          to determine the identity of a speci-
men. They do this by using a tool called a dichotomous (di KAH
tuh mus) key. The term dichotomous refers to two parts or divi-
sions. Part of a dichotomous key for identifying hard-shelled
crabs is shown in Figure 10. To begin the identification of your
unknown animal, you are given two choices. Your animal will
match only one of the choices. In the key in Figure 10, you are
to determine whether or not your crab lives in a borrowed shell.
Based on your answer, you are either directed to another set of
choices or given the name of the crab you are identifying.

                                                           SECTION 1 Physical Properties and Changes   535
VISUALIZING DICHOTOMOUS KEYS
Figure 10

           hether in the laboratory or

W          in the field, scientists often
           encounter substances
or organisms that they cannot imme-
                                                                Dichotomous Key

                                              1. A. Lives in a “borrowed” shell
diately identify. One approach to                (usually some type of snail shell)        Hermit Crab
tracking down the identity of such
                                                  B. Does not live in a “borrowed” shell   go to #2
“unknowns” is to use a dichotomous
key, such as the one shown. The key is        2. A. Shell completely overlaps
designed so a user can compare physi-            the walking legs                          Box Crab
cal properties or characteristics of the          B. Walking legs are exposed              Kelp Crab
unknown substance or organism—in
this case, a crab—with characteristics
of known organisms in a stepwise
manner. With each step, a choice            Can you identify the
must be made. Each choice leads to          three crabs shown here
subsequent steps that guide the user        by following this
through the key until a positive identi-    dichotomous key?
fication is made.




536     CHAPTER 18
Everyday Examples Identification by physical properties is
a subject in science that is easy to observe in the real world. Sup-
pose you volunteer to help your friend choose a family pet.
While visiting the local animal shelter, you spot a cute dog. The
dog looks like the one in Figure 11. You look at the sign on the
cage. It says that the dog is male, one to two years old, and its
breed is unknown. You and your friend wonder what breed of
dog he is. What kind of information do you and your friend
need to figure out the dog’s breed? First, you need a thorough
description of the physical properties of the dog. What does the
dog look like? Second, you need to know the descriptions of var-
ious breeds of dogs. Then you can match up the description of
the dog with the correct breed. The dog you found is a white,              Figure 11
medium-sized dog with large black spots on his back. He also               Physical descriptions are used
has black ears and a black mask around his eyes. The manager of            to determine the identities of
the shelter tells you that the dog is close to full-grown. What            unknown things. What physical
breed is the dog?                                                          properties are used to describe
                                                                           this dog?
Narrowing the Options To find out, you may need to research
the various breeds of dogs and their descriptions. Often, determin-
ing the identity of something that is unknown is easiest by using the
process of elimination.You figure out all of the breeds the dog can’t
be. Then your list of possible breeds is smaller. Upon looking at
the descriptions of various breeds,you eliminate small dog and large
dog breeds. You also eliminate breeds that do not contain white
dogs. With the remaining breeds, you might look at photos to see
which ones most resemble your dog. Scientists use similar meth-
ods to determine the identities of living and nonliving things.


Substances                                                                        Oxygen
    Matter—everything that has mass and takes up space—can
be classified by its physical properties. One way to classify mat-
ter is based on its chemical composition. Matter that has the
same composition and properties throughout is called a sub-
stance. There are two types of substances—elements and com-                                         Gold
pounds.

Elements Substances that are made up of only one type of
atom are called elements. Figure 12 shows examples of ele-
ments. Oxygen is a substance made up of only oxygen atoms. A
bar of gold is a substance made up of only gold atoms. Alu-                      Aluminum
minum foil is made up of only aluminum atoms. Elements can-                Figure 12
not be broken down into simpler substances by physical or                  Elements such as oxygen, gold,
chemical means. However, different elements can combine to                 and aluminum are made up of
form new substances—called compounds.                                      only one type of atom.

                                                              SECTION 1 Physical Properties and Changes    537
Oxygen atom

                                                                                  H
                                                                                      O

                                                                                     H
                                                                               Hydrogen atoms
                                                                                    H2O




                                      Compounds What do you call the colorless liquid that flows
                                      from the kitchen faucet? You probably call it water, but maybe
Figure 13                             you’ve seen it written as H2O. The elements hydrogen and oxy-
Compounds contain more than           gen exist separately as colorless gases. However, these two ele-
one type of atom bonded               ments can combine to form the compound water, shown in
together.Water contains a ratio       Figure 13, with properties that are different from the individual
of two hydrogen atoms bonded          gases that make it up. A compound is a substance that is made
to one oxygen atom.
                                      up of atoms of more than one element chemically bonded
                                      together. The smallest unit of water is made up of two hydrogen
                                      atoms and one oxygen atom bonded together.
                                          Compounds have a fixed ratio—or proportion of atoms
                                      throughout. For example, every drop of water contains a ratio of
                                      two hydrogen atoms to one oxygen atom. Every sample of car-
                                      bon dioxide contains a ratio of one carbon atom to two oxygen
                                      atoms.
                                          Compounds can be broken down only by chemical means
                                      into the elements that combined to make them. For example,
                                      boiling, freezing, stirring or filtering will not separate the hydro-
                                      gen atoms from the oxygen atom. However, if electricity is
                                      added to water, it can be broken down into hydrogen gas and
                                      oxygen gas.

                                      Mixtures
                                          When two or more substances come together but don’t
                                      chemically combine or bond to make a new substance, a mix-
                                      ture results. Unlike compounds, the proportions of the sub-
                                      stances in a mixture can be changed without changing the
                                      identity of the mixture. For example, if you put some sand into
                                      a bucket of water, the sand doesn’t chemically combine with the
                                      water. If you add more sand or more water, it’s still a mixture of
                                      sand and water. Physical properties can be used to separate mix-
                                      tures into simpler substances. For example, solid sand can be fil-
                                      tered from liquid water using a sieve.

538   CHAPTER 18 Properties and Changes of Matter
Homogeneous Mixtures Mixtures can be classified as
homogeneous or heterogeneous based on their physical
properties. Homogeneous means “the same throughout.”
Homogeneous mixtures contain more than one substance
evenly mixed but not chemically bonded together. You can’t
see the different parts in a homogeneous mixture no
matter how closely you look. In fact, it is difficult to
see the difference between a homogeneous mixture
and a substance because they both look uniform, or
even, throughout.
    Homogeneous mixtures can be solid, liquid or gas.
The brass in a trumpet is a solid mixture of zinc and
copper—two elements. Sugar water is a homogeneous
liquid mixture of sugar and water—both compounds.
Air is a homogeneous mixture of elements—nitrogen,
oxygen, argon, neon and helium—and two com-
pounds—carbon dioxide and water. Another name for
a homogeneous mixture is a solution.

Heterogeneous Mixtures A heterogeneous mixture is one
of two or more substances that are not mixed evenly. You can
see the different parts of a heterogeneous mixture, such as a
mixture of sand and water. A pizza is a tasty kind of heteroge-
neous mixture. Other examples of this kind of mixture include             Figure 14
salad, a bookshelf full of books, or a toolbox full of nuts and           The salad and the pizza are het-
bolts. Figure 14 shows examples of heterogeneous and homoge-              erogeneous mixtures.The fruit
neous mixtures.                                                           drink is a homogeneous mixture.



                              Section                   Assessment
   1. What property of matter is used to mea-
      sure the amount of space an object takes?     6. Concept Mapping Using a computer, draw a
   2. What are the four states of matter?              cycle concept map with the steps for changing
      Describe each and give an example.               an ice cube into steam. Use the terms melting
   3. How might a substance such as water have         point and boiling point in your answer. For more
      two different densities?                         help, refer to the Science Skill Handbook.
   4. Compare and contrast heterogeneous and        7. Solving One-Step Equations Calculate the
      homogeneous mixtures.                            volume of an object that has a length of 10 cm,
   5. Think Critically Explain why the boiling         a width of 10 cm, and a height of 10 cm. Use
      point is the same for 1 L and 3 L of water.      the formula for volume: V ϭ lwh. Express your
      Will it take the same amount of time for         answer using cubic centimeters (cm3). For more
      each volume of water to begin to boil?           help, refer to the Math Skill Handbook.



                                                             SECTION 1 Physical Properties and Changes    539
SECTION



                       Chemical Properties
                         and Changes
                                        Ability to Change
                                            It is time to celebrate. You and your coworkers have cooper-
s Recognize chemical properties.        ated in classifying all of the products and setting up the shelves
s Identify chemical changes.            in the new grocery store. The store manager agrees to a celebra-
s Classify matter according to          tion party and campfire at the nearby park. Several large pieces
  chemical properties.                  of firewood and some small pieces of kindling are needed to
s Describe the law of conservation
  of mass.                              start the campfire. After the campfire, all that remains of the
                                        wood is a small pile of ash. Where did the wood go? What prop-
Vocabulary                              erty of the wood is responsible for this change?
chemical property
chemical change                             All of the properties that you observed and used for classifi-
conservation of mass                    cation in the first section were physical properties that you
                                        could observe easily. In addition, even when those properties
                                        changed, the identity of the object remained the same. Some-
Knowing the chemical properties will    thing different seems to have happened in the bonfire example.
allow you to distinguish differences        Some properties do indicate a change of identity for the sub-
in matter.                              stances involved. A chemical property is any characteristic that
                                        gives a substance the ability to undergo a change that results in a
                                        new substance. Figure 12 shows some properties of substances
                                        that can be observed only as they undergo a chemical change.
Figure 12
These are four examples of                                     What does a chemical property give a substance
chemical properties.                                           the ability to do?




Flammability                    Reacts with oxygen          Reacts with light            Reacts with water


540    CHAPTER 18 Properties and Changes of Matter
Common Chemical Properties                                              Figure 13
                                                                        Many kinds of interactions
    You don’t have to be in a laboratory to see changes that take       with oxygen can occur.
place because of chemical properties. These are called chemical            An untreated iron gate will
changes. A chemical change is a change in the identity of a sub-        rust.    Silver dishes develop
stance due to the chemical properties of that substance. A new          tarnish.     Copper sculptures
substance or substances are formed in such a change.                    develop a green patina, which is
    The campfire you enjoyed to celebrate the opening of the gro-       a mixture of copper compounds.
cery store resulted in chemical changes. The oxygen in the air
reacted with the wood to form a new substance called ash. Wood
can burn. This chemical property is called flammability. Some
products have warnings on their labels about keeping them away
from heat and flame because of the flammability of the materials.
Sometimes after a campfire you see stones that didn’t burn
around the edge of the ashes. These stones have the chemical               Researchers have discov-
property of inflammability.                                                ered an enzyme in fruit
                                                                           that is involved in the
Common Reactions An unpainted iron gate, such as the                       browning process. They
one shown in Figure 13A, will rust in time. The rust is a result of        are doing experiments to
oxygen in the air reacting with the iron and causing corrosion.            try to grow grapevines in
                                                                           which the level of this
The corrosion produces a new substance called iron oxide.
                                                                           enzyme, polyphenol oxi-
Other chemical reactions occur when metals interact with                   dase (PPO), is reduced.
other elements. Figure 13B shows tarnish, the grayish-brown                This could result in
film that develops on silver when it reacts with sulfur in the air.        grapes that do not brown
The ability to react with oxygen or sulfur is a chemical property.         as quickly. Write a para-
Figure 13C shows another example of this chemical property.                graph in your Science
     Have you ever sliced an apple or banana and left it sitting           Journal about why this
                                                                           would be helpful to fruit
on the table? The brownish coloring that you notice is a chem-             growers, store owners,
ical change that occurs between the fruit and the oxygen in the            and customers.
air. Those who work in the produce department at the grocery
store must be careful with any fruit they slice to use as sam-
ples. Although nothing is wrong with brown apples, they don’t
look appetizing.


                                                           SECTION 2 Chemical Properties and Changes   541
Heat and Light Vitamins often are dispensed in dark-brown
                                       bottles. Do you know why? Many vitamins have the ability to
                                       change when exposed to light. This is a chemical property. They
                                       are protected in those colored bottles from undergoing a chemi-
                                       cal change with light.
                                           Some substances are sensitive to heat and will undergo
                                       a chemical change only when heated or cooled. One example
                                       is limestone. Limestone is generally thought of as un-
                                       reactive. Some limestone formations have been around for
                                       centuries without changing. However, if limestone is heated, it
                                       goes through a chemical change and produces carbon dioxide
                                       and lime, a chemical used in many industrial processes. The
                                       chemical property in this case is the ability to change when
                                       heated.
                                           Another chemical property is the ability to change with elec-
                                       trical contact. Electricity can cause a change in some substances
Figure 14                              and decompose some compounds. Water is one of those com-
When sugar and sulfuric acid           pounds that can be broken down with electricity.
combine, a chemical change
occurs and a new substance
forms. During this reaction, the
                                       Something New
mixture foams and a toxic gas is          The important difference in a chemical change is that a
released, leaving only water and       new substance is formed. Because of chemical changes, you
air-filled carbon behind. (Because     can enjoy many things in life that you would not have experi-
a toxic gas is released, students      enced without them. What about that perfect, browned marsh-
should never perform this as an        mallow you roasted at the bonfire? A chemical change
activity.)                             occurred as a result of the fire to make the taste and the
                                                                       appearance different.
                                                                           Sugar is normally a white,
                                                                       crystalline substance, but after
                                                                       you heat it over a flame, it
                                                                       turns to a dark-brown caramel.
                                                                       A new substance has been
                                                                       formed. Sugar also can under-
                                                                       go a chemical change when
                                                                       sulfuric acid is added to it. The
                                                                       new substance is obviously dif-
                                                                       ferent from the original, as
                                                                       shown in Figure 14.
                                                                           You could not enjoy a
                                                                       birthday cake if the eggs, sugar,
                                                                       flour, baking powder, and
                                                                       other ingredients didn’t change
                                                                       chemically. You would have
                                                                       what you see when you pour
                                                                       the gooey batter into the pan.

542    CHAPTER 18 Properties and Changes of Matter
Signs of Change How do you know that you have a
new substance? Is it just because it looks different? You
could put a salad in a blender and it would look differ-
ent, but a chemical change would not have occurred.
You still would have lettuce, carrots, and any other veg-
etables that were there to begin with.
    You can look for signs when evaluating whether you
have a new substance as a result of a chemical change.
Look at the piece of birthday cake in Figure 15. When a
cake bakes, gas bubbles form and grow within the
ingredients. Bubbles are a sign that a chemical change
has taken place. When you look closely at a piece of
cake, you can see the airholes left from the bubbles.                      Figure 15
    Other signs of change include the production of heat, light,           The evidence of a chemical
smoke, change in color, and sound. Which of these signs of                 change in the cake is the holes
change would you have seen or heard during the campfire?                   left by the air bubbles that were
                                                                           produced during baking.
Is it reversible? One other way to determine whether a phys-
ical change or a chemical change has occurred is to decide
whether or not you can reverse the change by simple physical
means. Physical changes usually can be reversed easily. For
example, melted butter can become solid again if it is placed in
the refrigerator. A figure made of modeling clay, like the one in
Figure 16, can be smashed to fit back into a container. However,
chemical changes can’t be reversed using physical means. For
example, the ashes in a fireplace cannot be put back together to           Figure 16
make the logs that you had to start with. Can you find the egg in          A change such as molding clay
a cake? Where is the white flour?                                          or changing shape can be
                                                                           undone easily.
                       What kind of change can be reversed easily?




                                                              SECTION 2 Chemical Properties and Changes   543
Table 1 Comparing Properties
                                          Physical Properties           color, shape, length, mass, volume,
                                                                        density, state, ability to attract
                                                                        a magnet, melting point, boiling
                                                                        point, malleability, ductility

                                          Chemical Properties           flammability; ability to react with:
                                                                        oxygen, electricity, light, water,
                                                                        heat, vinegar, bleach, etc.


                                       Classifying According to Chemical Properties Classify-
                                       ing according to physical properties is often easier than classifying
                                       according to chemical properties. Table 1 summarizes the two
                                       kinds of properties. The physical properties of a substance are
                                       easily observed, but the chemical properties can’t be observed
                                       without changing the substance. However, once you know the
                                       chemical properties, you can classify and identify matter based on
                                       those properties. For example, if you try to burn what looks like a
Observing Yeast                        piece of wood but find that it won’t burn, you can rule out the
Procedure                              possibility that it is untreated wood.
1. Observe a tablespoon of                 In a grocery store, the products sometimes are separated
   dry yeast with a hand lens.         according to their flammability or sensitivity to light or heat.
   Draw and describe what              You don’t often see the produce section in front of big windows
   you observe.
                                       where heat and light come in. The fruit and vegetables would
2. Put the yeast in 50 mL of
   warm, not hot, water.               undergo a chemical change and ripen too quickly. You also
3. Compare your observations           won’t find the lighter fluid and rubbing alcohol near the bakery
   of the dry yeast with those         or other places where heat and flame could be present.
   of the wet yeast.                       Architects and product designers have to take into account
4. Put a pinch of sugar in             the chemical properties of materials when they design buildings
   the water and observe for           and merchandise. For example, children’s sleepwear and bed-
   15 minutes.
5. Record your observations.           ding can’t be made of a flammable fabric. Also, some of the
                                       architects designing the most modern buildings are choosing
Analysis
                                       materials like titanium because it does not react with oxygen like
1. Are new substances formed
   when sugar is added to the          many other metals do.
   water and yeast? Explain.
2. Do you think this is a
   chemical change or a
                                       Conservation of Mass
   physical change? Explain.               It was so convenient to turn the firewood into the small pile
                                       of ash left after the campfire. You began with many kilograms of
                                       flammable substances but ended up with just a few kilograms of
                                       ash. Could this be a solution to the problems with landfills and
                                       garbage dumps? Why not burn all the trash? If you could make
                                       such a reduction without creating undesirable materials, this
                                       would be a great solution.

544    CHAPTER 18 Properties and Changes of Matter
Mass Is Not Destroyed Before you celebrate your discov-
ery, think this through. Did mass really disappear during the fire?
It appears that way when you compare the mass of the pile of
ashes to the mass of the firewood you started with. The law of
conservation of mass states that the mass of what you end with
is always the same as the mass of what you start with.
     This law was first investigated about 200 years ago, and many
investigations since then have proven it to be true. One experi-
ment done by French scientist Antoine Lavoisier was a small ver-
sion of a campfire. He determined that a fire does not make mass
disappear or truly get rid of anything. The question, however,
remains. Where did the mass go? The ashes aren’t heavy enough
to account for the mass of all of the pieces of firewood.
Where did the mass go? If you look at the campfire exam-
ple more closely, you see that the law of conservation of mass is
true. When flammable materials burn, they combine with oxygen.
Ash, smoke, and gases are produced. The smoke and gases escape
into the air. If you could measure the mass of the oxygen and all of
the original flammable materials that were burned and compare it
to the remaining mass of the ash, smoke, and gas, they would be
equal.


       Problem-Solving Activity

   Do light sticks conserve mass?
       ight sticks often are used on Halloween
   L   to light the way for trick-or-treaters.
   They make children visible to drivers.
   They also are used as toys, for camping,
   marking trails, emergency traffic problems,
   by the military, and they work well under-
   water. A light stick contains two chemicals
   in separate tubes. When you break the
   inner tube, the two chemicals react pro-
   ducing a greenish light. The chemicals are
   not toxic, and they will not catch fire.

   Identifying the Problem                            Solving the Problem
       In all reactions that occur in the world,          Describe how you could show that a
   mass is never lost or gained. This is the law      light stick does not gain or lose mass when
   of conservation of mass. An example of this        you allow the reaction to take place. Is this
   phenomenon is the light stick. How can you         reaction a chemical or physical change?
   prove this?                                        What is your evidence?

                                                         SECTION 2 Chemical Properties and Changes   545
Figure 17                               Before and After Mass is not destroyed or created during
This reaction demonstrates              any chemical change. The conservation of mass is demonstrated
the conservation of mass.               in Figure 17. In the first photo, you see one substance in the flask
Although a chemical change has          and a different substance contained in a test tube inside the flask.
occurred and new substances             The total mass is 16.150 g. In the second photo, the flask is turned
were made, the mass remained            upside down. This allows the two substances to mix and react.
constant.
                                        Because the flask is sealed, nothing is allowed to escape. In the
                                        third photo, the flask is placed on the balance again and the total
                                        mass is determined to be 16.150 g. If no mass is lost or gained,
                                        what happens in a reaction? Instead of disappearing or appearing,
                                        the particles in the substances rearrange into different combina-
                                        tions with different properties.



                                 Section                    Assessment
      1. What is a chemical property?
      2. List four chemical properties.                6. Comparing and Contrasting Compare
      3. What are some of the signs that a chemical       and contrast physical change and chemical
         change has occurred?                             change. For more help, refer to the Science
      4. Describe the law of conservation of mass.        Skill Handbook.
         Give an example.                              7. Solving One-Step Equations A student
      5. Think Critically You see a bright flash          heats 4.00 g of a blue compound to produce
         and then flames as your teacher performs a       2.56 g of a white compound and an unknown
         demonstration for the class. Is this an          amount of colorless gas. What is the mass of
         example of a physical change or a chemical       this gas? For more help, refer to the Math
         change? Explain.                                 Skill Handbook.



546     CHAPTER 18 Properties and Changes of Matter
Liquid Layers
                                                          Allow the glycerin to trickle down the sides of
W      hy must you shake up a bottle of Italian
       salad dressing before using it? Have you
observed how the liquids in some dressings sepa-
                                                          the container and observe.
                                                       3. Slowly pour 40 mL of water into the beaker
rate into two distinct layers? In this activity, you      and observe.
will experiment with creating layers of liquids.       4. Slowly pour 40 mL of corn oil into the beaker
What You’ll Investigate                                   and observe.
What would several liquids and solids of               5. Slowly pour 40 mL of rubbing alcohol into the
different densities look like when put into the           beaker and observe.
same container?                                        6. Carefully drop the penny, hollow plastic
                                                         sphere, and rubber ball into the beaker and
Goals                                                    observe where these items come to a stop.
s Create layers of liquids using liquids of
  different densities.
s Observe where solids of different densities                   Conclude and Apply
  will rest in the liquid layers.                      1. In your Science Journal, draw a picture of
s Infer the densities of the different materials.         the liquids and solids in your flask. Label
                                                          your diagram.
Materials
250-mL beaker               corn oil                   2. Describe what happened to the five liquids
graduated cylinder          rubbing alcohol               when you poured them into the beaker.
corn syrup                  penny                      3. Infer why the liquids behaved this way.
glycerin                    hollow plastic sphere      4. Describe what happened to the three solids
water                       rubber ball                   you placed into the beaker.
                                                       5. List the substances you used in your activity
                                                          in order from those with the highest density
                                                          to those with the lowest density.
                                                       6. If water has a density of 1 g/cm3, what can
                                                          you infer about the densities of the solids and
                                                          other liquids?




Safety Precautions                                      Draw a labeled poster of the substances
                                                        you placed in your beaker. Research the den-
                  Procedure                             sities of each substance and include these
                                                        densities on your poster. For more help,
 1. Pour 40 mL of corn syrup into your beaker.          refer to the Science Skill Handbook.
 2. Slowly pour 40 mL of glycerin into the beaker.

                                                                                        ACTIVITY       547
Fruit Salad Favorites
                   W     hen you are looking forward to enjoying a tasty, sweet fruit salad at a picnic, the
                         last thing you want to see is brown fruit in the bowl. What can you do about this
                   problem? Your teacher has given you a few different kinds of fruit. It is your task to per-
                   form a test in which you will observe a physical change and a chemical change.


                                              Recognize the Problem
                   Can a chemical change be controlled?


                                                  Form a Hypothesis
                   Based on your reading and observations, state a hypothesis about whether you can
                   control a chemical change.

                   Goals                                           Possible Materials
                   s Design an experiment that identi-             bananas
                     fies physical changes and chemical            apples
                     changes in fruit.                             pears
                   s Observe whether chemical changes              plastic or glass mixing bowls (2)
                     can be controlled.                            lemon/water solution (500 mL)
                                                                   paring knife

                                                                   Safety Precautions

                                                                   WARNING: Be careful when working
                                                                   with sharp objects. Always keep hands
                                                                   away from sharp blades. Never eat any-
                                                                   thing in the laboratory.




548   CHAPTER 18
Test Your Hypothesis
Plan                                           Do
1. As a group, agree upon the hypoth-          1. Ask your teacher to approve your
   esis and decide how you will test it.          plan and choice of constants, vari-
   Identify what results will confirm the         ables and controls before you start.
   hypothesis.                                 2. Perform the investigation as planned.
2. List each of the steps you will need        3. While doing the investigation,
   in order to test your hypothesis.              record your observations and com-
   Be specific. Describe exactly what             plete the data table you prepared in
   you will do in each step. List all of          your Science Journal.
   your materials.
3. Prepare a data table in your Science
   Journal or on a computer for your
   observations.
4. Read the entire investigation to make
   sure all steps are in logical order.
5. Identify all constants, variables,
   and controls of the investigation.



                             Analyze Your Data
1. Compare and contrast the                    4. What are your variables?
   changes you observe in the control          5. Did you encounter any
   and the test fruit.                            problems carrying out the
2. Compare your results with those of             investigation?
   other groups.                               6. Do you have any suggestions
3. What was your control in this                  for changes in a future
   investigation?                                 investigation?


                             Draw Conclusions
1. Did the results support your
  hypothesis? Explain.
                                                                Write a page for an illustrated cookbook
2. Describe what effect refrigerating the
                                                                explaining the benefits you found in this
  two salads would have on the fruit.
                                                                experiment. Include drawings and a step-by-
3. What will you do with the fruit from this                    step procedure. For more help, refer to the
  experiment? Could it be eaten?                                Science Skill Handbook.


                                                                                              ACTIVITY     549
Chapter            18          Study Guide


Section 1 Physical Properties                         Section 2 Chemical Properties
and Changes                                           and Changes
1. Any characteristic of a material that can be       1. Chemical properties give a
   observed or measured is a physical prop-              substance the ability to
   erty. What can you observe or measure about           undergo a chemical change.
   the baby in the photo?                                What chemical property is
                                                         being displayed in the photo?
                                                      2. Common chemical properties
                                                         include: ability to burn, reacts
                                                         with oxygen, reacts with heat or light, and
                                                         breaks down with electricity.
                                                      3. In a chemical change substances combine to
                                                         form a new material. Is the balloon about to
                                                         undergo a chemical or physical change?
2. The four states of matter are solid, liquid,
   gas, and plasma. The state of matter is a
   physical property that is dependent on tem-
   perature and pressure.
3. State, color, shape, length, mass, volume,
   attraction by a magnet, density, melting
   point, boiling point, luster, malleability, and
   ductility are common physical properties.
4. In a physical change the properties of a sub-      4. The mass of the products of a chemical
   stance change but the identity of the sub-            change is always the same as the mass of
   stance always stays the same.                         what you started with.
5. You can classify materials according to their      5. A chemical change results in a substance
   physical properties. What different physical          with a new identity, but matter is not
   properties could you use to classify the objects      created or destroyed.
   in the photo?

                                                                               After You Read
                                                        FOLDABLES
                                                        Reading &Study
                                                                & Study     Use the information in
                                                        Skills              your Foldable to compare
                                                                            and contrast physical and
                                                       chemical properties of matter. Write about
                                                       each on the back of the tabs.


550   CHAPTER STUDY GUIDE
Chapter               18             Study Guide


Complete the following table comparing properties of different objects.




           Properties of Matter
           Type of Matter                          Physical Properties                   Chemical Properties
           log                        brown, round, might have length, solid         flammability
           pillow                     soft, might describe color, size, solid        flammability
           bowl of cookie dough       color, gooey, chunks in it, solid              reacts with heat
           book                       might describe size, rectangle, color, solid   flammability
           glass of orange juice      might describe volume, liquid, color           reacts with bleach




Vocabulary Words                                                    Using Vocabulary
a. boiling point               f.   matter                              The sentences below include terms that have
b. chemical change             g.   melting point                   been used incorrectly. Change the incorrect terms
c. chemical property           h.   physical change                 so the sentence reads correctly.
d. conservation                i.   physical property                 1. The boiling point is the temperature at which
   of mass                     j.   states of matter                     matter in a solid state changes to a liquid.
e. density
                                                                      2. Matter is a measure of the mass of an object
                                                                         in a given volume.
                                                                      3. A chemical change is easily observed or
                            Study Tip                                    measured without changing the object.
                                                                      4. Physical changes result in a new substance
     Make a study schedule for yourself. If you have a
                                                                         and cannot be reversed by physical means.
     planner, write down exactly which hours you plan
     to spend studying and stick to it.                               5. The four states of matter are solid, volume,
                                                                         liquid, and melting point.

                                                                                             CHAPTER STUDY GUIDE   551
Chapter            18         Assessment
                                                    8. When iron reacts with oxygen, what
                                                       substance is produced?
    Choose the word or phrase that best answers        A) tarnish
the question.                                          B) rust
 1. What statement describes the physical              C) patina
    property of density?                               D) ashes
    A) the distance between two points              9. What kind of change results in a new
    B) how light is reflected from an object’s         substance being produced?
       surface                                         A) chemical          C) physical
    C) the amount of mass for a given volume           B) mass              D) change of state
    D) the amount of space an object takes up      10. What is conserved during any change?
 2. Which of the following is an example of a          A) color             C) identity
    physical change?                                   B) volume            D) mass
    A) tarnishing        C) burning
    B) rusting           D) melting
 3. Which of the choices below describes a
    boiling point?                                 11. Use the law of conservation of matter to
    A) a chemical property                             explain what happens to atoms when they
    B) a chemical change                               combine to form a new substance.
    C) a physical property                         12. Describe the four states of matter. How are
    D) a color change                                  they different?
 4. Which of the following is a sign that a        13. A globe is placed on
    chemical change has occurred?                      your desk and you are
    A) smoke             C) change in shape            asked to identify its
    B) broken pieces     D) change in state            physical properties.
 5. Which describes what volume is?                    How would you
    A) the area of a square                            describe the globe?
    B) the amount of space an object takes up      14. What information do
    C) the distance between two points                 you need to know
    D) the temperature at which boiling begins         about a material to
 6. What property is described by the ability of       find its density?
    metals to be hammered into sheets?
    A) mass              C) volume
    B) density           D) malleability
 7. Which of these is a chemical property?         15. Classifying Classify the following as a
    A) size                                            chemical or physical change: an egg breaks,
    B) density                                         a newspaper burns in the fireplace, a dish of
    C) flammability                                    ice cream is left out and melts, and a loaf of
    D) volume                                          bread is baked.


552   CHAPTER ASSESSMENT
Chapter           18            Assessment

16. Measuring in SI Find the density of the
    piece of lead that has a mass of 49.01 g and                                  Test Practice
    a volume of 4.5 mL.
                                                                 Unknown matter can be identified by
17. Concept Mapping Use the spider-mapping
                                                            taking a sample of it and comparing its
    skill to organize and define physical proper-
                                                            physical properties to those of already iden-
    ties of matter. Include the concepts of color,
                                                            tified substances.
    shape, length, density, mass, states of mat-
    ter, volume, density, melting point, and                              Physical Properties
    boiling point.
                                                                                Density
18. Making and Using Tables Complete the                      Substance                          Color
                                                                                (g/ml)
    table by supplying the missing information.
                                                               Gasoline          0.703           Clear
     States of Matter
     Type     Definition               Examples               Aluminum           2.700           Silver
     solid    Particles vibrate in a books, desk,
              fixed position.        chair, ice cubes
                                                               Methane           0.466          Colorless
     liquid   Particles do not      water, juice, tea,
              stay in one position. soft drink, etc.
              They move past                                    Water            1.000           Clear
              each other.
     gas      Particles move freely    oxygen, helium,          Study the table and answer the follow-
              with energy. They        vapor
              move all around.                              ing questions.
                                                             1. A scientist has a sample of a substance
19. Drawing Conclusions List the physical and                   with a density greater than 1 g/mL.
    chemical properties and changes that                        According to the table, which of these
    describe the process of scrambling eggs.                    substances has a density greater than
                                                                1 g/mL?
                                                                A) gasoline
20. Comic Strip Create a comic strip demon-                     B) water
    strating a chemical change in a substance.                  C) aluminum
    Include captions and drawings that demon-                   D) methane
    strate your understanding of conservation                2. A physical change occurs when the
    of matter.                                                  form or appearance of a substance
                                                                is changed. All of the following
                                                                are examples of physical changes
                  TECHNOLOGY                                    EXCEPT _____.
       Go to the Glencoe Science Web site at                    F) the vaporization of gasoline
       science.glencoe.com or use the                           G) corrosion of aluminum
       Glencoe Science CD-ROM for additional                    H) methane diluted by air
       chapter assessment.                                      J) water freezing into ice


                                                                                  CHAPTER ASSESSMENT        553

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Unit 6 Science (Glencoe Red 2002)

  • 1. 6 Matter, Forces, UNIT and Energy How Are Train Schedules & Oil Pumps Connected? 524
  • 2. I n the 1800s, trains had to make frequent stops so that their moving parts could be lubricated. Without lubrication, the parts would have worn out due to friction. When the train stopped, a worker had to get out and oil the parts by hand. The process was very time-consuming and made it hard for trains to stay on schedule. Around 1870, an engineer named Elijah McCoy developed the first automatic lubricating device, which oiled the engine while the train was running. (A later version of his automatic lubricator is seen at lower right.) Since then, many kinds of auto- matic lubricating devices have been developed. Today, automobiles have oil pumps that auto- matically circulate oil to the moving parts of the engine. When you go for a ride in a car, you can thank Elijah McCoy that you don’t have to stop every few miles to oil the engine by hand! SCIENCE CONNECTION FRICTION AND LUBRICANTS A lubricant is a substance that reduces friction between surfaces that touch one another. Some of the world’s first lubricants were animal and plant products such as lard and vegetable oils. Conduct research to identify a variety of modern-day lubricants. Select one lubricant you learned about and create a poster that shows its source, how it is made or processed, its special properties, and how it is used to reduce friction.
  • 3. 18 Properties and Changes of Matter W endy Craig Duncan car- ried the Olympic flame underwater on the way to the 2000 Summer Olympics in Syd- ney, Australia. How many different states of matter can you find in this picture? What chemical and physical changes are taking place? In this chapter, you will learn about the four states of matter, the physical and chemical properties of matter, and how those properties can change. What do you think? Science Journal What is the colored band on this fish tank? Why would it change colors? Here’s a hint: Would you want your fish to be chilly? Write your thoughts and ideas in your Science Journal. 526
  • 4. EXPLORE Y our teacher has given you a collection of pennies. It is your task to separate these pennies into ACTIVITY groups while using words to describe each set. In this chapter, you will learn how to identify things based on their physical and chemical properties. With an understanding of these principles of matter, you will discover how things are classified or put into groups. Classify coins 1. Observe the collection of pennies. 2. Choose a characteristic that will allow you to separate the pennies into groups. 3. Classify and sort each penny based on the chosen feature. Tally your data in a frequency table. 4. Explain how you classified the pennies. Compare your system of classification with those of others in the classroom. Observe Think about how your group classified its pennies. Describe the system your group used in your Science Journal. FOLDABLES Reading & Study Making an Organizational Study Fold Make the following Skills Foldable to help you organize your thoughts into clear categories about properties of matter. Physical Chemical Properties Properties 1. Place a sheet of paper in front of you so the long side is at the top. Fold the paper in half from the left side to the right side. Unfold. 2. Fold each side in to the center fold line to divide the paper into al Chemic fourths. Fold the paper in half from top to bottom. Unfold. Physics a Chang l e Chang es 3. Through the top thickness of paper, cut along both of the middle fold lines to form four tabs. Label the tabs Physical Properties, Physical Changes, Chemical Properties, and Chemical Changes. 4. Before you read the chapter, define each term on the front of the tabs. As you read the chapter, correct your definitions and write about each under the tabs. 527
  • 5. SECTION Physical Properties and Changes Using Your Senses As you look in your empty wallet and realize that your s Identify physical properties allowance isn’t coming anytime soon, you decide to get an after- of matter. school job. You’ve been hired at the new grocery store that will s Describe the states of matter. open next month. They are getting everything ready for the s Classify matter using physical grand opening, and you will be helping make decisions about properties. where things will go and how they will be arranged. Vocabulary When you come into a new situation or have to make any physical property state of matter kind of decision, what do you usually do first? Most people matter melting point physical change boiling point would make some observations. Observing involves seeing, density hearing, tasting, touching, and smelling. Whether in a new job or in the laboratory, you use your senses to observe materials. Any characteristic of a material that Observing physical properties can be observed or measured without changing the identity of will help you interpret the world the material is a physical property. However, it is important to around you. never taste, touch, or smell any of the materials being used in the lab without guidance, as noted in Figure 1. For safety reasons you will rely mostly on other observations. Watch Listen Figure 1 For safety reasons, in Do NOT the laboratory you touch usually use only two of your senses—sight and hearing. Many Do NOT smell chemicals can be dan- gerous to touch, taste, and smell. Do NOT taste 528
  • 6. Figure 2 The identity of the material does not necessarily depend on its color. Each of these bottles is made of high-density polyethylene (HDPE). Physical Properties On the first day of your new job, the boss gives you an inventory list and a drawing of the store layout. She explains that every employee is going to give his or her input as to how the merchandise should be arranged. Where will you begin? You decide that the first thing you’ll do is make some obser- vations about the items on the list. One of the key senses used in observing physical properties is sight, so you go shopping to look at what you will be arranging. Color and Shape Everything that you can see, touch, smell, or taste is matter. Matter is anything that has mass and takes up space. What things do you observe about the matter on your inventory list? The list already is organized by similarity of prod- ucts, so you go to an aisle and look. Color is the first thing you notice. The laundry detergent bottles you are looking at come in every color. Maybe you will organize them in the colors of the rainbow. You make a note and look more closely. Each bottle or box has a different shape. Some are square, some rectangular, and some are a free-form shape. You could arrange the packages by their shape. When the plastic used to make the packaging is molded, it Research Visit the changes shape. However, the material is still plastic. This type of Glencoe Science Web site at change is called a physical change. It is important to realize that science.glencoe.com in a physical change, the physical properties of a substance for more information about change, but the identity of the substance does not change. classifying matter by its phys- Notice Figure 2. The detergent bottles are made of high-density ical properties. Communicate polyethylene regardless of the differences in the physical proper- to your class what you learn. ties of color or shape. What is matter? SECTION 1 Physical Properties and Changes 529
  • 7. Length and Mass Some properties of matter can be identi- fied by using your senses, and other properties can be measured. How much is there? How much space does it take up? One useful and measurable physical property is length. Length is measured using a ruler, meterstick, or tape measure, as shown in Figure 3. Objects can be classified by their length. For example, you could choose to organize the French bread in the bakery section of your store by the length of the loaf. But, even though the dough has been shaped in different lengths, it is still French bread. Back in the laundry aisle, you notice a child struggling to lift one of the boxes of detergent. That raises a question. How much Collect Data Visit the detergent is in each box? Mass is a physical property that Glencoe Science Web site at describes the amount of material in an object. Some of the science.glencoe.com for boxes are heavy, but, the formula of the detergent hasn’t information about density. changed from the small box to the large box. Organizing the Communicate to your class boxes by mass is another option. what you learn. Volume and Density Mass isn’t the only physical property that describes how much of something you have. Another measurement is volume. Volume measures the amount of space an object takes up. Liquids usually are measured by volume. The juice bottles on your list could be organized by volume. Another measurable physical property related to mass and volume is density—the amount of mass a material has for a given volume. You notice this property when you try to lift two Figure 3 things of equal volume that have different masses. Density is The length of any object found by dividing the mass of an object by its volume. can be measured with the density ϭ massրvolume, or D ϭ mրV appropriate tool. 530 CHAPTER 18 Properties and Changes of Matter
  • 8. Figure 4 These balls take up about the same space, but the bowling ball on the left has more mass than the kickball on the right. Therefore, the bowling ball is more dense. Bowling ball Kickball Same Volume, Different Mass Figure 4 shows two balls that are the same size but not the same mass. The bowling ball is more dense than the kickball. The customers of your grocery store will notice the density of their bags of groceries if the bag- gers load all of the canned goods in one bag and put all of the cereal and napkins in the other. The density of a material stays the same as long as pressure and temperature stay the same. Water at room temperature has a density of 1.00 g/cm3. However, when you do change the temper- ature or pressure, the density of a material can change. Water kept Changing Density in the freezer at 0°C is in the form of ice. The density of that ice is Procedure 0.9168 g/cm3. Has the identity of water changed? No, but some- 1. Stir three tablespoons of thing has changed. baking soda in 3/4 cup of warm water. Set aside. What two measurements are related in the 2. Pour vinegar into a clear measurement of density? glass until it is half full. 3. Slowly pour the baking soda and warm water mixture States of Matter into the glass of vinegar. What changes when water goes from 20°C to 0°C? It 4. After most of the fizzing has stopped, place three halves changes from a liquid to a solid. The four states of matter are of raisins in the glass. solid, liquid, gas, and plasma (PLAZ muh). The state of mat- 5. Record your observations in ter of a substance depends on its temperature and pressure. your Science Journal or on a Three of these states of matter are things you talk about or computer. experience every day, but the term plasma might be unfamil- Analysis iar. The plasma state occurs at very high temperatures and is 1. How did the bubbles affect found in fluorescent (floo RE sunt) lightbulbs, the atmo- the raisins? sphere, and in lightning strikes. 2. Infer what changed the As you look at the products to shelve in your grocery store, density of the raisins. you might make choices of classification based on the state of matter. The state of matter of a material is another physical property. The liquid juices all will be in one place, and the solid, frozen juice concentrates will be in another. SECTION 1 Physical Properties and Changes 531
  • 9. Moving Particles Matter is made up of moving particles. The state of matter is determined by how much energy the par- ticles have. The particles of a solid vibrate in a fixed position. They remain close together and give the solid a definite shape and volume. The particles of a liquid are moving much faster and have enough energy to slide past one another. This allows a liquid to take the shape of its container. The particles of a gas are moving so quickly that they have enough energy to move freely away from other particles. The particles of a gas take up as much space as possible and will spread out to fill any container. Figure 5 illustrates the differences in the states of water. Which state of matter doesn’t conform to the shape of the container? Figure 5 Water can be in three different Changes of State You witness a change of state when you states: solid, liquid, and gas. The put ice cubes in water and they melt. You still have water but in molecules in a solid are tightly packed and vibrate in place, but another form. The opposite physical change happens when you in a liquid they can slip past each put liquid water in ice-cube trays and pop them in your freezer. other because they have more The water doesn’t change identity—only the state it is in. energy to move. In a gas, they For your job, you will need to make some decisions based on move freely all around the con- the ability of materials to change state. You don’t want all those tainer with even more energy. frozen items thawing out and becoming slushy liquid. You also don’t want some of the liquids to get so cold that they freeze. Solid water Liquid water Gaseous water 532 CHAPTER 18 Properties and Changes of Matter
  • 10. Melting and Boiling Points At what temperature will water in the Liquid nitrogen form of ice change into a liquid? The (below –195.8°C) temperature at which a solid becomes a liquid is its melting point. The Nitrogen gas melting point of a pure substance (above –195.8°C) does not change with the amount of the substance. This means that a small sliver of ice and a block of ice the size of a house both will melt at 0°C. Lead always melts at 327.5°C. When a substance melts, it changes from a solid to a liquid. This is a physical change and the melting point is a physical property. At what temperature will liquid water change to a gas? The boiling point is the temperature at which a substance in the liquid state Figure 6 becomes a gas. Each pure substance has a unique boiling point at When liquid nitrogen is poured atmospheric pressure. The boiling point of water is 100°C at from a flask, you see an instant atmospheric pressure. The boiling point of nitrogen is Ϫ195.8°C, change to gas because nitrogen’s so it changes to a gas when it warms after being spilled into the boiling point is –195.8°C, which open air, as shown in Figure 6. The boiling point, like the melting is much lower than room point, does not depend on the amount of the substance. temperature. What physical change takes place at the boiling point? However, the boiling point and melting point can help to identify a substance. If you observe a clear liquid that boils at 56.1°C at atmospheric pressure, it is not water. Water boils at When geologists describe 100°C. If you know the boiling points and melting points of sub- rocks, they use specific stances, you can classify substances based on those points. terms that have meaning to all other scientists who Metallic Properties read their descriptions. To describe the appearance of Other physical properties allow you to classify substances as a rock or mineral, they use metals. You already have seen how you can classify things as the following terms: metal- solids, liquids, or gases or according to color, shape, length, lic, adamantine, vitreous, mass, volume, or density. What properties do metals have? resinous, pearly, silky, and greasy. Research these terms and write a defini- How do metals look and act? Often the first thing you tion and example of each in notice about something that is a metal is its shiny appearance. your Science Journal. This is due to the way light is reflected from the surface of the metal. This shine is called luster. New handlebars on a bike have a metallic luster. Words that describe the appearance of non- metallic objects are pearly, milky, or dull. SECTION 1 Physical Properties and Changes 533
  • 11. Figure 7 This artist has taken advantage of the ductility of metal by choosing wire as the medium for her sculpture. Uses of Metals Metals can be used in unique ways because of some of the physical properties they have. For example, many metals can be hammered, pressed, or rolled into thin sheets. This property of metals is called malleability (mal lee uh BIH luh tee). The malleability of copper makes it an ideal choice for artwork such as the Statue of Liberty. Many metals can be drawn into wires as shown in Figure 7. This property is called ductility (duk TIH luh tee). The wires in buildings and most electrical equipment and household appliances are made from copper. Sil- ver and platinum are also ductile. You probably observe another physical property of some metals every day when you go to the refrigerator to get milk or juice for breakfast. Your refrigerator door is made of metal. Figure 8 Some metals respond to magnets. Most people make use of that This junkyard magnet pulls scrap property and put reminder notes, artwork, and photos on their metal that can be salvaged from refrigerators. Some metals have groups of atoms that can be the rest of the debris. It is sorting affected by the force of a magnet, and they are attracted to the by a physical property. magnet because of that force. The magnet in Figure 8 is being used to select metallic objects. At the grocery store, your em- ployer might think about these prop- erties of metals as she looks at grocery carts and thinks about shelving. Mal- leable carts can be dented. How could the shelf ’s attraction of magnets be used to post advertisements or weekly specials? Perhaps the prices could be fixed to the shelves with magnetic numbers. After you observe the physi- cal properties of an object, you can make use of those properties. 534 CHAPTER 18 Properties and Changes of Matter
  • 12. Using Physical Properties In the previous pages, many physical properties were discussed. These physi- cal properties—such as appearance, state, shape, length, mass, volume, ability to attract a magnet, density, melting point, boiling point, malleability, and ductility— can be used to help you iden- tify, separate, and classify substances. For example, salt can be described as a white solid. Each salt crystal, if you look at it under a microscope, could be described as having a three-dimensional cubic struc- Figure 9 ture. You can measure the mass, volume, and density of a Coins can be sorted by their phys- sample of salt or find out if it would attract a magnet. These ical properties. Sorting by size is are examples of how physical properties can be used to iden- used here. tify a substance. Sorting and Separating When you do laundry, you sort according to physical properties. Perhaps you sort by color. When you select a heat setting on an iron, you classify the clothes by the type of fabric. When miners during the Gold Rush panned for gold, they separated the dirt and rocks by den- sity of particles. Figure 9 shows a coin sorter that separates the coins based on their size. Iron filings can be separated from sand by using a magnet. Scientists who work with animals use physical properties or characteristics to determine the identity of a speci- men. They do this by using a tool called a dichotomous (di KAH tuh mus) key. The term dichotomous refers to two parts or divi- sions. Part of a dichotomous key for identifying hard-shelled crabs is shown in Figure 10. To begin the identification of your unknown animal, you are given two choices. Your animal will match only one of the choices. In the key in Figure 10, you are to determine whether or not your crab lives in a borrowed shell. Based on your answer, you are either directed to another set of choices or given the name of the crab you are identifying. SECTION 1 Physical Properties and Changes 535
  • 13. VISUALIZING DICHOTOMOUS KEYS Figure 10 hether in the laboratory or W in the field, scientists often encounter substances or organisms that they cannot imme- Dichotomous Key 1. A. Lives in a “borrowed” shell diately identify. One approach to (usually some type of snail shell) Hermit Crab tracking down the identity of such B. Does not live in a “borrowed” shell go to #2 “unknowns” is to use a dichotomous key, such as the one shown. The key is 2. A. Shell completely overlaps designed so a user can compare physi- the walking legs Box Crab cal properties or characteristics of the B. Walking legs are exposed Kelp Crab unknown substance or organism—in this case, a crab—with characteristics of known organisms in a stepwise manner. With each step, a choice Can you identify the must be made. Each choice leads to three crabs shown here subsequent steps that guide the user by following this through the key until a positive identi- dichotomous key? fication is made. 536 CHAPTER 18
  • 14. Everyday Examples Identification by physical properties is a subject in science that is easy to observe in the real world. Sup- pose you volunteer to help your friend choose a family pet. While visiting the local animal shelter, you spot a cute dog. The dog looks like the one in Figure 11. You look at the sign on the cage. It says that the dog is male, one to two years old, and its breed is unknown. You and your friend wonder what breed of dog he is. What kind of information do you and your friend need to figure out the dog’s breed? First, you need a thorough description of the physical properties of the dog. What does the dog look like? Second, you need to know the descriptions of var- ious breeds of dogs. Then you can match up the description of the dog with the correct breed. The dog you found is a white, Figure 11 medium-sized dog with large black spots on his back. He also Physical descriptions are used has black ears and a black mask around his eyes. The manager of to determine the identities of the shelter tells you that the dog is close to full-grown. What unknown things. What physical breed is the dog? properties are used to describe this dog? Narrowing the Options To find out, you may need to research the various breeds of dogs and their descriptions. Often, determin- ing the identity of something that is unknown is easiest by using the process of elimination.You figure out all of the breeds the dog can’t be. Then your list of possible breeds is smaller. Upon looking at the descriptions of various breeds,you eliminate small dog and large dog breeds. You also eliminate breeds that do not contain white dogs. With the remaining breeds, you might look at photos to see which ones most resemble your dog. Scientists use similar meth- ods to determine the identities of living and nonliving things. Substances Oxygen Matter—everything that has mass and takes up space—can be classified by its physical properties. One way to classify mat- ter is based on its chemical composition. Matter that has the same composition and properties throughout is called a sub- stance. There are two types of substances—elements and com- Gold pounds. Elements Substances that are made up of only one type of atom are called elements. Figure 12 shows examples of ele- ments. Oxygen is a substance made up of only oxygen atoms. A bar of gold is a substance made up of only gold atoms. Alu- Aluminum minum foil is made up of only aluminum atoms. Elements can- Figure 12 not be broken down into simpler substances by physical or Elements such as oxygen, gold, chemical means. However, different elements can combine to and aluminum are made up of form new substances—called compounds. only one type of atom. SECTION 1 Physical Properties and Changes 537
  • 15. Oxygen atom H O H Hydrogen atoms H2O Compounds What do you call the colorless liquid that flows from the kitchen faucet? You probably call it water, but maybe Figure 13 you’ve seen it written as H2O. The elements hydrogen and oxy- Compounds contain more than gen exist separately as colorless gases. However, these two ele- one type of atom bonded ments can combine to form the compound water, shown in together.Water contains a ratio Figure 13, with properties that are different from the individual of two hydrogen atoms bonded gases that make it up. A compound is a substance that is made to one oxygen atom. up of atoms of more than one element chemically bonded together. The smallest unit of water is made up of two hydrogen atoms and one oxygen atom bonded together. Compounds have a fixed ratio—or proportion of atoms throughout. For example, every drop of water contains a ratio of two hydrogen atoms to one oxygen atom. Every sample of car- bon dioxide contains a ratio of one carbon atom to two oxygen atoms. Compounds can be broken down only by chemical means into the elements that combined to make them. For example, boiling, freezing, stirring or filtering will not separate the hydro- gen atoms from the oxygen atom. However, if electricity is added to water, it can be broken down into hydrogen gas and oxygen gas. Mixtures When two or more substances come together but don’t chemically combine or bond to make a new substance, a mix- ture results. Unlike compounds, the proportions of the sub- stances in a mixture can be changed without changing the identity of the mixture. For example, if you put some sand into a bucket of water, the sand doesn’t chemically combine with the water. If you add more sand or more water, it’s still a mixture of sand and water. Physical properties can be used to separate mix- tures into simpler substances. For example, solid sand can be fil- tered from liquid water using a sieve. 538 CHAPTER 18 Properties and Changes of Matter
  • 16. Homogeneous Mixtures Mixtures can be classified as homogeneous or heterogeneous based on their physical properties. Homogeneous means “the same throughout.” Homogeneous mixtures contain more than one substance evenly mixed but not chemically bonded together. You can’t see the different parts in a homogeneous mixture no matter how closely you look. In fact, it is difficult to see the difference between a homogeneous mixture and a substance because they both look uniform, or even, throughout. Homogeneous mixtures can be solid, liquid or gas. The brass in a trumpet is a solid mixture of zinc and copper—two elements. Sugar water is a homogeneous liquid mixture of sugar and water—both compounds. Air is a homogeneous mixture of elements—nitrogen, oxygen, argon, neon and helium—and two com- pounds—carbon dioxide and water. Another name for a homogeneous mixture is a solution. Heterogeneous Mixtures A heterogeneous mixture is one of two or more substances that are not mixed evenly. You can see the different parts of a heterogeneous mixture, such as a mixture of sand and water. A pizza is a tasty kind of heteroge- neous mixture. Other examples of this kind of mixture include Figure 14 salad, a bookshelf full of books, or a toolbox full of nuts and The salad and the pizza are het- bolts. Figure 14 shows examples of heterogeneous and homoge- erogeneous mixtures.The fruit neous mixtures. drink is a homogeneous mixture. Section Assessment 1. What property of matter is used to mea- sure the amount of space an object takes? 6. Concept Mapping Using a computer, draw a 2. What are the four states of matter? cycle concept map with the steps for changing Describe each and give an example. an ice cube into steam. Use the terms melting 3. How might a substance such as water have point and boiling point in your answer. For more two different densities? help, refer to the Science Skill Handbook. 4. Compare and contrast heterogeneous and 7. Solving One-Step Equations Calculate the homogeneous mixtures. volume of an object that has a length of 10 cm, 5. Think Critically Explain why the boiling a width of 10 cm, and a height of 10 cm. Use point is the same for 1 L and 3 L of water. the formula for volume: V ϭ lwh. Express your Will it take the same amount of time for answer using cubic centimeters (cm3). For more each volume of water to begin to boil? help, refer to the Math Skill Handbook. SECTION 1 Physical Properties and Changes 539
  • 17. SECTION Chemical Properties and Changes Ability to Change It is time to celebrate. You and your coworkers have cooper- s Recognize chemical properties. ated in classifying all of the products and setting up the shelves s Identify chemical changes. in the new grocery store. The store manager agrees to a celebra- s Classify matter according to tion party and campfire at the nearby park. Several large pieces chemical properties. of firewood and some small pieces of kindling are needed to s Describe the law of conservation of mass. start the campfire. After the campfire, all that remains of the wood is a small pile of ash. Where did the wood go? What prop- Vocabulary erty of the wood is responsible for this change? chemical property chemical change All of the properties that you observed and used for classifi- conservation of mass cation in the first section were physical properties that you could observe easily. In addition, even when those properties changed, the identity of the object remained the same. Some- Knowing the chemical properties will thing different seems to have happened in the bonfire example. allow you to distinguish differences Some properties do indicate a change of identity for the sub- in matter. stances involved. A chemical property is any characteristic that gives a substance the ability to undergo a change that results in a new substance. Figure 12 shows some properties of substances that can be observed only as they undergo a chemical change. Figure 12 These are four examples of What does a chemical property give a substance chemical properties. the ability to do? Flammability Reacts with oxygen Reacts with light Reacts with water 540 CHAPTER 18 Properties and Changes of Matter
  • 18. Common Chemical Properties Figure 13 Many kinds of interactions You don’t have to be in a laboratory to see changes that take with oxygen can occur. place because of chemical properties. These are called chemical An untreated iron gate will changes. A chemical change is a change in the identity of a sub- rust. Silver dishes develop stance due to the chemical properties of that substance. A new tarnish. Copper sculptures substance or substances are formed in such a change. develop a green patina, which is The campfire you enjoyed to celebrate the opening of the gro- a mixture of copper compounds. cery store resulted in chemical changes. The oxygen in the air reacted with the wood to form a new substance called ash. Wood can burn. This chemical property is called flammability. Some products have warnings on their labels about keeping them away from heat and flame because of the flammability of the materials. Sometimes after a campfire you see stones that didn’t burn around the edge of the ashes. These stones have the chemical Researchers have discov- property of inflammability. ered an enzyme in fruit that is involved in the Common Reactions An unpainted iron gate, such as the browning process. They one shown in Figure 13A, will rust in time. The rust is a result of are doing experiments to oxygen in the air reacting with the iron and causing corrosion. try to grow grapevines in which the level of this The corrosion produces a new substance called iron oxide. enzyme, polyphenol oxi- Other chemical reactions occur when metals interact with dase (PPO), is reduced. other elements. Figure 13B shows tarnish, the grayish-brown This could result in film that develops on silver when it reacts with sulfur in the air. grapes that do not brown The ability to react with oxygen or sulfur is a chemical property. as quickly. Write a para- Figure 13C shows another example of this chemical property. graph in your Science Have you ever sliced an apple or banana and left it sitting Journal about why this would be helpful to fruit on the table? The brownish coloring that you notice is a chem- growers, store owners, ical change that occurs between the fruit and the oxygen in the and customers. air. Those who work in the produce department at the grocery store must be careful with any fruit they slice to use as sam- ples. Although nothing is wrong with brown apples, they don’t look appetizing. SECTION 2 Chemical Properties and Changes 541
  • 19. Heat and Light Vitamins often are dispensed in dark-brown bottles. Do you know why? Many vitamins have the ability to change when exposed to light. This is a chemical property. They are protected in those colored bottles from undergoing a chemi- cal change with light. Some substances are sensitive to heat and will undergo a chemical change only when heated or cooled. One example is limestone. Limestone is generally thought of as un- reactive. Some limestone formations have been around for centuries without changing. However, if limestone is heated, it goes through a chemical change and produces carbon dioxide and lime, a chemical used in many industrial processes. The chemical property in this case is the ability to change when heated. Another chemical property is the ability to change with elec- trical contact. Electricity can cause a change in some substances Figure 14 and decompose some compounds. Water is one of those com- When sugar and sulfuric acid pounds that can be broken down with electricity. combine, a chemical change occurs and a new substance forms. During this reaction, the Something New mixture foams and a toxic gas is The important difference in a chemical change is that a released, leaving only water and new substance is formed. Because of chemical changes, you air-filled carbon behind. (Because can enjoy many things in life that you would not have experi- a toxic gas is released, students enced without them. What about that perfect, browned marsh- should never perform this as an mallow you roasted at the bonfire? A chemical change activity.) occurred as a result of the fire to make the taste and the appearance different. Sugar is normally a white, crystalline substance, but after you heat it over a flame, it turns to a dark-brown caramel. A new substance has been formed. Sugar also can under- go a chemical change when sulfuric acid is added to it. The new substance is obviously dif- ferent from the original, as shown in Figure 14. You could not enjoy a birthday cake if the eggs, sugar, flour, baking powder, and other ingredients didn’t change chemically. You would have what you see when you pour the gooey batter into the pan. 542 CHAPTER 18 Properties and Changes of Matter
  • 20. Signs of Change How do you know that you have a new substance? Is it just because it looks different? You could put a salad in a blender and it would look differ- ent, but a chemical change would not have occurred. You still would have lettuce, carrots, and any other veg- etables that were there to begin with. You can look for signs when evaluating whether you have a new substance as a result of a chemical change. Look at the piece of birthday cake in Figure 15. When a cake bakes, gas bubbles form and grow within the ingredients. Bubbles are a sign that a chemical change has taken place. When you look closely at a piece of cake, you can see the airholes left from the bubbles. Figure 15 Other signs of change include the production of heat, light, The evidence of a chemical smoke, change in color, and sound. Which of these signs of change in the cake is the holes change would you have seen or heard during the campfire? left by the air bubbles that were produced during baking. Is it reversible? One other way to determine whether a phys- ical change or a chemical change has occurred is to decide whether or not you can reverse the change by simple physical means. Physical changes usually can be reversed easily. For example, melted butter can become solid again if it is placed in the refrigerator. A figure made of modeling clay, like the one in Figure 16, can be smashed to fit back into a container. However, chemical changes can’t be reversed using physical means. For example, the ashes in a fireplace cannot be put back together to Figure 16 make the logs that you had to start with. Can you find the egg in A change such as molding clay a cake? Where is the white flour? or changing shape can be undone easily. What kind of change can be reversed easily? SECTION 2 Chemical Properties and Changes 543
  • 21. Table 1 Comparing Properties Physical Properties color, shape, length, mass, volume, density, state, ability to attract a magnet, melting point, boiling point, malleability, ductility Chemical Properties flammability; ability to react with: oxygen, electricity, light, water, heat, vinegar, bleach, etc. Classifying According to Chemical Properties Classify- ing according to physical properties is often easier than classifying according to chemical properties. Table 1 summarizes the two kinds of properties. The physical properties of a substance are easily observed, but the chemical properties can’t be observed without changing the substance. However, once you know the chemical properties, you can classify and identify matter based on those properties. For example, if you try to burn what looks like a Observing Yeast piece of wood but find that it won’t burn, you can rule out the Procedure possibility that it is untreated wood. 1. Observe a tablespoon of In a grocery store, the products sometimes are separated dry yeast with a hand lens. according to their flammability or sensitivity to light or heat. Draw and describe what You don’t often see the produce section in front of big windows you observe. where heat and light come in. The fruit and vegetables would 2. Put the yeast in 50 mL of warm, not hot, water. undergo a chemical change and ripen too quickly. You also 3. Compare your observations won’t find the lighter fluid and rubbing alcohol near the bakery of the dry yeast with those or other places where heat and flame could be present. of the wet yeast. Architects and product designers have to take into account 4. Put a pinch of sugar in the chemical properties of materials when they design buildings the water and observe for and merchandise. For example, children’s sleepwear and bed- 15 minutes. 5. Record your observations. ding can’t be made of a flammable fabric. Also, some of the architects designing the most modern buildings are choosing Analysis materials like titanium because it does not react with oxygen like 1. Are new substances formed when sugar is added to the many other metals do. water and yeast? Explain. 2. Do you think this is a chemical change or a Conservation of Mass physical change? Explain. It was so convenient to turn the firewood into the small pile of ash left after the campfire. You began with many kilograms of flammable substances but ended up with just a few kilograms of ash. Could this be a solution to the problems with landfills and garbage dumps? Why not burn all the trash? If you could make such a reduction without creating undesirable materials, this would be a great solution. 544 CHAPTER 18 Properties and Changes of Matter
  • 22. Mass Is Not Destroyed Before you celebrate your discov- ery, think this through. Did mass really disappear during the fire? It appears that way when you compare the mass of the pile of ashes to the mass of the firewood you started with. The law of conservation of mass states that the mass of what you end with is always the same as the mass of what you start with. This law was first investigated about 200 years ago, and many investigations since then have proven it to be true. One experi- ment done by French scientist Antoine Lavoisier was a small ver- sion of a campfire. He determined that a fire does not make mass disappear or truly get rid of anything. The question, however, remains. Where did the mass go? The ashes aren’t heavy enough to account for the mass of all of the pieces of firewood. Where did the mass go? If you look at the campfire exam- ple more closely, you see that the law of conservation of mass is true. When flammable materials burn, they combine with oxygen. Ash, smoke, and gases are produced. The smoke and gases escape into the air. If you could measure the mass of the oxygen and all of the original flammable materials that were burned and compare it to the remaining mass of the ash, smoke, and gas, they would be equal. Problem-Solving Activity Do light sticks conserve mass? ight sticks often are used on Halloween L to light the way for trick-or-treaters. They make children visible to drivers. They also are used as toys, for camping, marking trails, emergency traffic problems, by the military, and they work well under- water. A light stick contains two chemicals in separate tubes. When you break the inner tube, the two chemicals react pro- ducing a greenish light. The chemicals are not toxic, and they will not catch fire. Identifying the Problem Solving the Problem In all reactions that occur in the world, Describe how you could show that a mass is never lost or gained. This is the law light stick does not gain or lose mass when of conservation of mass. An example of this you allow the reaction to take place. Is this phenomenon is the light stick. How can you reaction a chemical or physical change? prove this? What is your evidence? SECTION 2 Chemical Properties and Changes 545
  • 23. Figure 17 Before and After Mass is not destroyed or created during This reaction demonstrates any chemical change. The conservation of mass is demonstrated the conservation of mass. in Figure 17. In the first photo, you see one substance in the flask Although a chemical change has and a different substance contained in a test tube inside the flask. occurred and new substances The total mass is 16.150 g. In the second photo, the flask is turned were made, the mass remained upside down. This allows the two substances to mix and react. constant. Because the flask is sealed, nothing is allowed to escape. In the third photo, the flask is placed on the balance again and the total mass is determined to be 16.150 g. If no mass is lost or gained, what happens in a reaction? Instead of disappearing or appearing, the particles in the substances rearrange into different combina- tions with different properties. Section Assessment 1. What is a chemical property? 2. List four chemical properties. 6. Comparing and Contrasting Compare 3. What are some of the signs that a chemical and contrast physical change and chemical change has occurred? change. For more help, refer to the Science 4. Describe the law of conservation of mass. Skill Handbook. Give an example. 7. Solving One-Step Equations A student 5. Think Critically You see a bright flash heats 4.00 g of a blue compound to produce and then flames as your teacher performs a 2.56 g of a white compound and an unknown demonstration for the class. Is this an amount of colorless gas. What is the mass of example of a physical change or a chemical this gas? For more help, refer to the Math change? Explain. Skill Handbook. 546 CHAPTER 18 Properties and Changes of Matter
  • 24. Liquid Layers Allow the glycerin to trickle down the sides of W hy must you shake up a bottle of Italian salad dressing before using it? Have you observed how the liquids in some dressings sepa- the container and observe. 3. Slowly pour 40 mL of water into the beaker rate into two distinct layers? In this activity, you and observe. will experiment with creating layers of liquids. 4. Slowly pour 40 mL of corn oil into the beaker What You’ll Investigate and observe. What would several liquids and solids of 5. Slowly pour 40 mL of rubbing alcohol into the different densities look like when put into the beaker and observe. same container? 6. Carefully drop the penny, hollow plastic sphere, and rubber ball into the beaker and Goals observe where these items come to a stop. s Create layers of liquids using liquids of different densities. s Observe where solids of different densities Conclude and Apply will rest in the liquid layers. 1. In your Science Journal, draw a picture of s Infer the densities of the different materials. the liquids and solids in your flask. Label your diagram. Materials 250-mL beaker corn oil 2. Describe what happened to the five liquids graduated cylinder rubbing alcohol when you poured them into the beaker. corn syrup penny 3. Infer why the liquids behaved this way. glycerin hollow plastic sphere 4. Describe what happened to the three solids water rubber ball you placed into the beaker. 5. List the substances you used in your activity in order from those with the highest density to those with the lowest density. 6. If water has a density of 1 g/cm3, what can you infer about the densities of the solids and other liquids? Safety Precautions Draw a labeled poster of the substances you placed in your beaker. Research the den- Procedure sities of each substance and include these densities on your poster. For more help, 1. Pour 40 mL of corn syrup into your beaker. refer to the Science Skill Handbook. 2. Slowly pour 40 mL of glycerin into the beaker. ACTIVITY 547
  • 25. Fruit Salad Favorites W hen you are looking forward to enjoying a tasty, sweet fruit salad at a picnic, the last thing you want to see is brown fruit in the bowl. What can you do about this problem? Your teacher has given you a few different kinds of fruit. It is your task to per- form a test in which you will observe a physical change and a chemical change. Recognize the Problem Can a chemical change be controlled? Form a Hypothesis Based on your reading and observations, state a hypothesis about whether you can control a chemical change. Goals Possible Materials s Design an experiment that identi- bananas fies physical changes and chemical apples changes in fruit. pears s Observe whether chemical changes plastic or glass mixing bowls (2) can be controlled. lemon/water solution (500 mL) paring knife Safety Precautions WARNING: Be careful when working with sharp objects. Always keep hands away from sharp blades. Never eat any- thing in the laboratory. 548 CHAPTER 18
  • 26. Test Your Hypothesis Plan Do 1. As a group, agree upon the hypoth- 1. Ask your teacher to approve your esis and decide how you will test it. plan and choice of constants, vari- Identify what results will confirm the ables and controls before you start. hypothesis. 2. Perform the investigation as planned. 2. List each of the steps you will need 3. While doing the investigation, in order to test your hypothesis. record your observations and com- Be specific. Describe exactly what plete the data table you prepared in you will do in each step. List all of your Science Journal. your materials. 3. Prepare a data table in your Science Journal or on a computer for your observations. 4. Read the entire investigation to make sure all steps are in logical order. 5. Identify all constants, variables, and controls of the investigation. Analyze Your Data 1. Compare and contrast the 4. What are your variables? changes you observe in the control 5. Did you encounter any and the test fruit. problems carrying out the 2. Compare your results with those of investigation? other groups. 6. Do you have any suggestions 3. What was your control in this for changes in a future investigation? investigation? Draw Conclusions 1. Did the results support your hypothesis? Explain. Write a page for an illustrated cookbook 2. Describe what effect refrigerating the explaining the benefits you found in this two salads would have on the fruit. experiment. Include drawings and a step-by- 3. What will you do with the fruit from this step procedure. For more help, refer to the experiment? Could it be eaten? Science Skill Handbook. ACTIVITY 549
  • 27. Chapter 18 Study Guide Section 1 Physical Properties Section 2 Chemical Properties and Changes and Changes 1. Any characteristic of a material that can be 1. Chemical properties give a observed or measured is a physical prop- substance the ability to erty. What can you observe or measure about undergo a chemical change. the baby in the photo? What chemical property is being displayed in the photo? 2. Common chemical properties include: ability to burn, reacts with oxygen, reacts with heat or light, and breaks down with electricity. 3. In a chemical change substances combine to form a new material. Is the balloon about to undergo a chemical or physical change? 2. The four states of matter are solid, liquid, gas, and plasma. The state of matter is a physical property that is dependent on tem- perature and pressure. 3. State, color, shape, length, mass, volume, attraction by a magnet, density, melting point, boiling point, luster, malleability, and ductility are common physical properties. 4. In a physical change the properties of a sub- 4. The mass of the products of a chemical stance change but the identity of the sub- change is always the same as the mass of stance always stays the same. what you started with. 5. You can classify materials according to their 5. A chemical change results in a substance physical properties. What different physical with a new identity, but matter is not properties could you use to classify the objects created or destroyed. in the photo? After You Read FOLDABLES Reading &Study & Study Use the information in Skills your Foldable to compare and contrast physical and chemical properties of matter. Write about each on the back of the tabs. 550 CHAPTER STUDY GUIDE
  • 28. Chapter 18 Study Guide Complete the following table comparing properties of different objects. Properties of Matter Type of Matter Physical Properties Chemical Properties log brown, round, might have length, solid flammability pillow soft, might describe color, size, solid flammability bowl of cookie dough color, gooey, chunks in it, solid reacts with heat book might describe size, rectangle, color, solid flammability glass of orange juice might describe volume, liquid, color reacts with bleach Vocabulary Words Using Vocabulary a. boiling point f. matter The sentences below include terms that have b. chemical change g. melting point been used incorrectly. Change the incorrect terms c. chemical property h. physical change so the sentence reads correctly. d. conservation i. physical property 1. The boiling point is the temperature at which of mass j. states of matter matter in a solid state changes to a liquid. e. density 2. Matter is a measure of the mass of an object in a given volume. 3. A chemical change is easily observed or Study Tip measured without changing the object. 4. Physical changes result in a new substance Make a study schedule for yourself. If you have a and cannot be reversed by physical means. planner, write down exactly which hours you plan to spend studying and stick to it. 5. The four states of matter are solid, volume, liquid, and melting point. CHAPTER STUDY GUIDE 551
  • 29. Chapter 18 Assessment 8. When iron reacts with oxygen, what substance is produced? Choose the word or phrase that best answers A) tarnish the question. B) rust 1. What statement describes the physical C) patina property of density? D) ashes A) the distance between two points 9. What kind of change results in a new B) how light is reflected from an object’s substance being produced? surface A) chemical C) physical C) the amount of mass for a given volume B) mass D) change of state D) the amount of space an object takes up 10. What is conserved during any change? 2. Which of the following is an example of a A) color C) identity physical change? B) volume D) mass A) tarnishing C) burning B) rusting D) melting 3. Which of the choices below describes a boiling point? 11. Use the law of conservation of matter to A) a chemical property explain what happens to atoms when they B) a chemical change combine to form a new substance. C) a physical property 12. Describe the four states of matter. How are D) a color change they different? 4. Which of the following is a sign that a 13. A globe is placed on chemical change has occurred? your desk and you are A) smoke C) change in shape asked to identify its B) broken pieces D) change in state physical properties. 5. Which describes what volume is? How would you A) the area of a square describe the globe? B) the amount of space an object takes up 14. What information do C) the distance between two points you need to know D) the temperature at which boiling begins about a material to 6. What property is described by the ability of find its density? metals to be hammered into sheets? A) mass C) volume B) density D) malleability 7. Which of these is a chemical property? 15. Classifying Classify the following as a A) size chemical or physical change: an egg breaks, B) density a newspaper burns in the fireplace, a dish of C) flammability ice cream is left out and melts, and a loaf of D) volume bread is baked. 552 CHAPTER ASSESSMENT
  • 30. Chapter 18 Assessment 16. Measuring in SI Find the density of the piece of lead that has a mass of 49.01 g and Test Practice a volume of 4.5 mL. Unknown matter can be identified by 17. Concept Mapping Use the spider-mapping taking a sample of it and comparing its skill to organize and define physical proper- physical properties to those of already iden- ties of matter. Include the concepts of color, tified substances. shape, length, density, mass, states of mat- ter, volume, density, melting point, and Physical Properties boiling point. Density 18. Making and Using Tables Complete the Substance Color (g/ml) table by supplying the missing information. Gasoline 0.703 Clear States of Matter Type Definition Examples Aluminum 2.700 Silver solid Particles vibrate in a books, desk, fixed position. chair, ice cubes Methane 0.466 Colorless liquid Particles do not water, juice, tea, stay in one position. soft drink, etc. They move past Water 1.000 Clear each other. gas Particles move freely oxygen, helium, Study the table and answer the follow- with energy. They vapor move all around. ing questions. 1. A scientist has a sample of a substance 19. Drawing Conclusions List the physical and with a density greater than 1 g/mL. chemical properties and changes that According to the table, which of these describe the process of scrambling eggs. substances has a density greater than 1 g/mL? A) gasoline 20. Comic Strip Create a comic strip demon- B) water strating a chemical change in a substance. C) aluminum Include captions and drawings that demon- D) methane strate your understanding of conservation 2. A physical change occurs when the of matter. form or appearance of a substance is changed. All of the following are examples of physical changes TECHNOLOGY EXCEPT _____. Go to the Glencoe Science Web site at F) the vaporization of gasoline science.glencoe.com or use the G) corrosion of aluminum Glencoe Science CD-ROM for additional H) methane diluted by air chapter assessment. J) water freezing into ice CHAPTER ASSESSMENT 553