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Fullerenes: discovery, properties and applications
How did we get to know about fullerenes? ,[object Object]
A Japanese physical organic chemist E. G. Osawa had perceived that carbon in the single layer closed cages structure would be aromatic and therefore stable, in early 1970.
Gal’pern (Russian scientist) had completed the first of many Hückel calculations showing that it would be a closed shell molecule with a large HOMO-LUMO gap in 1973.
Fullerenes were discovered experimentally for the first time by a group of scientists at Rice University, Houston, Texas, in September of 1985.,[object Object]
Each carbon atom on the cage surface is bonded to three carbon neighbors therefore is sp2 hybridized.
The most famous fullerene is C60, known also by “ buckyball ".
Other relatively common clusters are C70, C72, C74, C76, C80, C82 and C84 (plenty of others, higher or lower than C60, exist too but less abundant in the experimentally produced mixture fullerene soot). ,[object Object]
Schematic cross-sectional drawing of the supersonic laser-vaporization nozzle  used in the discovery of fullerenes How are fullerenes made? ,[object Object],[object Object]
Buckyballs are relatively cheap; carbon is everywhere!
Even though each carbon atom is only bonded with three other carbons (they are most comfortable with four bonds) in a fullerene molecule, dangling a single carbon atom next to the structure is not strong enough to break the structure of the fullerene molecule.,[object Object]
Fullerenes contain carbon atoms arranged as a combination of 12 pentagonal rings and n hexagonal rings. The chemical formula is C20+2n.
Fullerene cages are about 7-15 Å in diameter, and are one carbon atom thick.,[object Object]

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Fullerenes