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Formate brines
Formate brines  Important applicational niche in deep HPHT work  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
13Cr tubular from BP High Island well : 6 years exposure to 11.5 ppg formate brine packer fluid @175  o C
Conventional formate drilling fluid formulation - in field use since 1993 and good to 160 oC   Simple, effective, non-damaging reservoir drill-in fluid  Used to drill entire wells, top to bottom, in sensitive environments (e.g. Barents Sea)  Component Function Concentration Formate brine Density Lubricity Polymer protection Biocide 1 bbl Xanthan Viscosity Fluid loss control 0.75 - 1  ppb Ultralow vis PAC and modified starch Fluid loss control 3 or 4 ppb of each Sized calcium carbonate Filter cake agent 20 ppb K 2 CO 3 /KHCO 3 Buffer Acid gas corrosion control 0 – 6 ppb
Formate-based drilling fluids
1995 –  Formate brines used for first time by Mobil to drill and work over deep gas wells,  onshore ,  northern Germany  Walsrode field – onshore, high-angle slim hole wells Z1, Z5, Z6 and Z7  TVD :    4,450-5,547 metres  Reservoir:  Sandstone 0.1-125 mD BHST :    315 o F  (157 o  C)   Section length: 345-650 metres
42   d eep HPHT gas fields developed using potassium and cesium formate brines, 1995-2011  Country Fields Reservoir Description  Matrix  type Depth, TVD (metres)  Permeability  (mD) Temperature ( o C)  Germany (7) Walsrode,Sohlingen Voelkersen,I dsingen, Kalle, Weissenmoor,  Simonswolde  Sandstone 4,450-6,500 0.1-150 150-165 Hungary  (2)  Mako , Vetyem  Sandstone 5,692 - 235 Kazakhstan (1)  Kashagan Carbonate 4,595-5,088 - 100 Norway (10) Huldra ,Njord Kristin,Kvitebjoern  Tune, Valemon Victoria, Morvin,  Vega, Asgard  Sandstone 4,090-7,380 50-1,000 121-200 Pakistan (2)  Miano, Sawan Sandstone 3,400 10-5,000 175 Saudi Arabia (7)  Andar,Shedgum Uthmaniyah Hawiyah,Haradh Tinat, Midrikah Sandstone and  carbonate 3,963-4,572 0.1-40 132-154 UK  (12)  Braemar,Devenick Dunbar,Elgin Franklin,Glenelg Judy, Jura, Kessog Rhum, Shearwater West Franklin Sandstone 4,500-7,353 0.01-1,000 123-207 USA  (1)  High Island  Sandstone 4,833 -  177
Cesium formate brine : Drill-in, completion, workover and suspension fluid for HPHT gas wells  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Cesium formate brine produced by Cabot Specialty Fluids in Canada from pollucite ore ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Leasing cesium formate brine    Green and sustainable model – recognised by United Nations  Conservation  ( i.e. minimisation of cesium formate brine losses during transport, use and reclamation)  is a key and essential feature of Cabot’s Chemical Leasing business model
Key applications for cesium formate brine ,[object Object]
Cesium formate brine - Field applications ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Shell UK was the first user of cesium formate brine – Shearwater field,  September 1999  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Use of cesium formate by Total as HPHT completion and workover fluid  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Cesium formate brine has now been used by TOTAL in  34 HPHT well construction operations in 8 deep gas fields  over  the period 1999-2010
Some HPHT perforating jobs  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Cesium formate brine ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advantages of open hole screen completions in high-angle HPHT wells*  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Cesium formate brine used by BP and Statoil as combined HPHT drill-in  and  completion fluid in N. Sea ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Tune field – semi-HP/HT gas reservoir in the North Sea drilled and completed with formate brines  4 wells  : 1,100-2,950 ft (350-900 m) horizontal reservoir sections. Suspended for 6-12 months in K/Cs formate brine after completion
HPHT gas fields in northern North Sea drilled and completed with cesium formate brine  Almost every field development (oil and gas) on this map has used formate brines as well construction fluids .  Zinc bromide brine no longer used in Europe – too hazardous and damaging
HPHT gas fields in the Norwegian Sea drilled and completed with cesium formate brine  Formate brines also used as well construction fluids in  Asgard, Draugen, Morvin and Njord fields
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Cesium formate brine first used as a combined drill-in and completion fluid in the Huldra field,  2001
Huldra – drill-in, logging and completion times (days) with cesium formate brine in well    Drill, log and run lower completion in drilling fluid. Then displace to clean cesium formate brine and run upper completion. Finally displace to packer fluid  A-4  (189 m ) A-5 (263 m)  A-6 (344 m) A-8 (257 m) A-9 (230 m) A-11 (336 m)  Average  (231 m)  Drill-in  5 8 20 15 7 11 11 Logging  0 3 1 7 3 2 2.7 Lower completion  11 6 5 6 5 5 6.3 Upper completion  4 5 4 4 9 4 5 Total  20  22 30 32 24 22 25
Huldra – Fluid losses while drilling (cubic metres)    A-4  (189 m ) A-5 (263 m)  A-6 (344 m) A-8 (257 m) A-9 (230 m) A-11 (336 m)  Average  (231 m)  With cuttings  2.6 16.4 48 9.6 23.8 17.7 19.7 Other surface  1.5 3.3 10.1 2.2 12 17.1 7.7 Downhole  7.6 10.8 46.4 0 0 0 10.8 Well displacements  5.6 28.3 12.8 24.3 11 15.7 16.3 Tripping  6.5  7.2 6.3 3.6 1.6 2.8 4.7  TOTAL  23.8 66 123.6 39.7 48.4 53.3 59.1
Huldra – Production of recoverable gas and condensate reserves since 2001 (NPD data) ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Seven years of cesium formate brine use as combined drill-in and completion fluid in Kvitebjoern field, 2004 -present
A few of the highlights from Kvitebjoern Fastest HPHT well completion in the North Sea  “ The target well PI was 51,000 Sm 3 /day/bar This target would have had a skin of 7”  “ A skin of 0 would have given a PI of 100,000” “ THE WELL A-04 GAVE A PI OF 90,000 Sm 3 /day/bar  (ANOTHER FANTASTIC PI)”  Operator comments after well testing (Q3 2004  ) The Well PI was almost double the target Kvitebjoern well  Completion time  (days)  A-4 17.5 A-5 17.8 A-15 14.8 A-10 15.9 A-6 12.7 *
Economic benefits from the use of cesium formate brine in HPHT gas field developments  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Economic benefits from the use of cesium formate brine in HPHT gas field developments  ,[object Object],[object Object],[object Object],[object Object],* Quotes by Statoil relating to Kvitebjoern wells (SPE 105733)
Economic benefits from use of cesium formate brine in HPHT gas field developments  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Economic benefits from use of cesium formate brine in deep gas field developments  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Flow check  fingerprint  for a Huldra well  Duration of flow back (minutes)  Fluid Gain  (bbl)  30 0.8  15 0.56 20 0.44 30 0.56
Cesium formate drilling fluids – some important features that impact on nuclear logging    The extreme photoelectric effect of the cesium formate filtrate provides the log interpreter with valuable information regarding invasion, thus porosity and net reservoir.
Cesium formate drilling fluids – some important features that impact on nuclear logging    Filtrate is mobile :  gravity segregation over time and replacement by hydrocarbon phases  Effect of invasion and time lapse : From left to right, formation density (ROBB), medium deep resistivity (P16) and deep resistivity (P40). LWD drill pass data represented by red curves and ream pass represented by black curves.
Logged Pef and observation of filtrate movement can be used to define permeable sands  in gas reservoirs (SPE 105733)  “ Using the photoelectric factor and bulk density data, combined with resistivity measurements from both the LWD drill pass and the ream pass, produces a very reliable and consistent net reservoir definition”  Berg  et al ,  SPE 105773   Log responses from drill-pass (P16_1) and ream-pass (P16_2) provide a powerful technique for defining permeable intervals (SAND_FLAG ).
Economic benefits from the use of cesium formate brine in HPHT gas field developments  Good reservoir definition  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],“ Using photoelectric factor and bulk density data, combined with resistivity measurements from both the LWD drill pass and the ream pass, produces  a very reliable and consistent net reservoir definition .” ( SPE 105733)
Economic benefits from the use of cesium formate brine in HPHT gas field developments  Good reservoir definition  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Summary ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Unlock Your Reservoir Presentation

  • 1.  
  • 4.
  • 5. 13Cr tubular from BP High Island well : 6 years exposure to 11.5 ppg formate brine packer fluid @175 o C
  • 6. Conventional formate drilling fluid formulation - in field use since 1993 and good to 160 oC Simple, effective, non-damaging reservoir drill-in fluid Used to drill entire wells, top to bottom, in sensitive environments (e.g. Barents Sea) Component Function Concentration Formate brine Density Lubricity Polymer protection Biocide 1 bbl Xanthan Viscosity Fluid loss control 0.75 - 1 ppb Ultralow vis PAC and modified starch Fluid loss control 3 or 4 ppb of each Sized calcium carbonate Filter cake agent 20 ppb K 2 CO 3 /KHCO 3 Buffer Acid gas corrosion control 0 – 6 ppb
  • 8. 1995 – Formate brines used for first time by Mobil to drill and work over deep gas wells, onshore , northern Germany Walsrode field – onshore, high-angle slim hole wells Z1, Z5, Z6 and Z7 TVD : 4,450-5,547 metres Reservoir: Sandstone 0.1-125 mD BHST : 315 o F (157 o C) Section length: 345-650 metres
  • 9. 42 d eep HPHT gas fields developed using potassium and cesium formate brines, 1995-2011 Country Fields Reservoir Description Matrix type Depth, TVD (metres) Permeability (mD) Temperature ( o C) Germany (7) Walsrode,Sohlingen Voelkersen,I dsingen, Kalle, Weissenmoor, Simonswolde Sandstone 4,450-6,500 0.1-150 150-165 Hungary (2) Mako , Vetyem Sandstone 5,692 - 235 Kazakhstan (1) Kashagan Carbonate 4,595-5,088 - 100 Norway (10) Huldra ,Njord Kristin,Kvitebjoern Tune, Valemon Victoria, Morvin, Vega, Asgard Sandstone 4,090-7,380 50-1,000 121-200 Pakistan (2) Miano, Sawan Sandstone 3,400 10-5,000 175 Saudi Arabia (7) Andar,Shedgum Uthmaniyah Hawiyah,Haradh Tinat, Midrikah Sandstone and carbonate 3,963-4,572 0.1-40 132-154 UK (12) Braemar,Devenick Dunbar,Elgin Franklin,Glenelg Judy, Jura, Kessog Rhum, Shearwater West Franklin Sandstone 4,500-7,353 0.01-1,000 123-207 USA (1) High Island Sandstone 4,833 - 177
  • 10.
  • 11.
  • 12. Leasing cesium formate brine Green and sustainable model – recognised by United Nations Conservation ( i.e. minimisation of cesium formate brine losses during transport, use and reclamation) is a key and essential feature of Cabot’s Chemical Leasing business model
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.
  • 18.
  • 19.
  • 20.
  • 21. Tune field – semi-HP/HT gas reservoir in the North Sea drilled and completed with formate brines 4 wells : 1,100-2,950 ft (350-900 m) horizontal reservoir sections. Suspended for 6-12 months in K/Cs formate brine after completion
  • 22. HPHT gas fields in northern North Sea drilled and completed with cesium formate brine Almost every field development (oil and gas) on this map has used formate brines as well construction fluids . Zinc bromide brine no longer used in Europe – too hazardous and damaging
  • 23. HPHT gas fields in the Norwegian Sea drilled and completed with cesium formate brine Formate brines also used as well construction fluids in Asgard, Draugen, Morvin and Njord fields
  • 24.
  • 25. Huldra – drill-in, logging and completion times (days) with cesium formate brine in well Drill, log and run lower completion in drilling fluid. Then displace to clean cesium formate brine and run upper completion. Finally displace to packer fluid A-4 (189 m ) A-5 (263 m) A-6 (344 m) A-8 (257 m) A-9 (230 m) A-11 (336 m) Average (231 m) Drill-in 5 8 20 15 7 11 11 Logging 0 3 1 7 3 2 2.7 Lower completion 11 6 5 6 5 5 6.3 Upper completion 4 5 4 4 9 4 5 Total 20 22 30 32 24 22 25
  • 26. Huldra – Fluid losses while drilling (cubic metres) A-4 (189 m ) A-5 (263 m) A-6 (344 m) A-8 (257 m) A-9 (230 m) A-11 (336 m) Average (231 m) With cuttings 2.6 16.4 48 9.6 23.8 17.7 19.7 Other surface 1.5 3.3 10.1 2.2 12 17.1 7.7 Downhole 7.6 10.8 46.4 0 0 0 10.8 Well displacements 5.6 28.3 12.8 24.3 11 15.7 16.3 Tripping 6.5 7.2 6.3 3.6 1.6 2.8 4.7 TOTAL 23.8 66 123.6 39.7 48.4 53.3 59.1
  • 27.
  • 28.
  • 29.
  • 30.
  • 31. A few of the highlights from Kvitebjoern Fastest HPHT well completion in the North Sea “ The target well PI was 51,000 Sm 3 /day/bar This target would have had a skin of 7” “ A skin of 0 would have given a PI of 100,000” “ THE WELL A-04 GAVE A PI OF 90,000 Sm 3 /day/bar (ANOTHER FANTASTIC PI)” Operator comments after well testing (Q3 2004 ) The Well PI was almost double the target Kvitebjoern well Completion time (days) A-4 17.5 A-5 17.8 A-15 14.8 A-10 15.9 A-6 12.7 *
  • 32.
  • 33.
  • 34.
  • 35.
  • 36. Cesium formate drilling fluids – some important features that impact on nuclear logging The extreme photoelectric effect of the cesium formate filtrate provides the log interpreter with valuable information regarding invasion, thus porosity and net reservoir.
  • 37. Cesium formate drilling fluids – some important features that impact on nuclear logging Filtrate is mobile : gravity segregation over time and replacement by hydrocarbon phases Effect of invasion and time lapse : From left to right, formation density (ROBB), medium deep resistivity (P16) and deep resistivity (P40). LWD drill pass data represented by red curves and ream pass represented by black curves.
  • 38. Logged Pef and observation of filtrate movement can be used to define permeable sands in gas reservoirs (SPE 105733) “ Using the photoelectric factor and bulk density data, combined with resistivity measurements from both the LWD drill pass and the ream pass, produces a very reliable and consistent net reservoir definition” Berg et al , SPE 105773 Log responses from drill-pass (P16_1) and ream-pass (P16_2) provide a powerful technique for defining permeable intervals (SAND_FLAG ).
  • 39.
  • 40.
  • 41.