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The Status and Outlook for the
    Photovoltaics Industry




         David E. Carlson
         March 14, 2006
Outline of the Talk


The PV Market

The Major Players

Different Types of Solar Cells

Field Installations

Performance and Cost

Projections for the Future of Photovoltaics
$10
                  $20
                        $30
                              $40
                                    $50
                                           $60
                                                                                $70




       $0
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
                                                                   Annual MWp




1990
1991
1992
                                              ASP Constant 2005$




1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
       0
            200
                  400
                        600
                              800
                                    1000
                                           1200
                                                                                1400
                                                                                       Historical Average Selling Price and Volume
PV Shipments for Different Technologies
The Major Players
Crystalline Si    Amorphous Si      CIGS          CdTe
   Sharp            United Solar    Shell Solar   First Solar
   Kyocera          Kaneka          Showa Shell   Antec Solar
   BP Solar         Fuji Electric   Wurth Solar
   Q-Cells          Sharp           DayStar
   Mitsubishi       Mitsubisihi
   SolarWorld       Schott Solar
   Sanyo
   Schott Solar
   Isofoton
   Motech
   Suntech
Operation of a Solar Cell

Photons are absorbed in the
semiconductor resulting in the
creation of electron-hole pairs

The photo-generated electron-
hole pairs are physically
separated at the p/n junction

The photogenerated carriers
are collected by the contacts
on the front and rear of the
cell

The photocurrent can be
delivered to an external load at
an applied voltage to perform
useful work
Operation of a Solar Cell
Crystalline Silicon Solar Cells

                                             The BP Solar Saturn
                                             solar cell utilizes a
                                             laser-grooved, buried
                                             front contact
                                             The aluminum back
                                             contact is heated to
n+                                           form a back surface
     n++      P
                                             field, which reduces
                          Buried             surface recombination
                          contact
                                             Best lab efficiency =
                                             20.1%
           Back contact
Sanyo HIT Solar Cell

                                                       Screen-printed Ag
                                                       collection grids


                                                     Textured n-type CZ Si
                                                     (200 μm thick)




The HIT cell utilizes amorphous Si intrinsic layers (~ 5 nm) as super-passivation
layers. The cell is symmetric except for the a-Si p+ emitter layer (~ 10 nm) on
the front and the a-Si n+ contact layer (~ 15 nm) on the rear. The transparent
electrodes are sputter-deposited indium-tin-oxide (ITO)
Best lab efficiency = 21.6% (open-circuit voltages > 700 mV)
SunPower Back Contact Solar Cell




The SunPower cell has all its electrical contacts on the rear surface of the cell
The diffusion lengths > twice the cell thickness
Best lab efficiency = 21.6%
Amorphous Silicon Triple-Junction Cell




                                              United Solar Ovonic



United Solar has demonstrated a stable efficiency of 13% in the lab
Cadmium Telluride Solar Cells



          The CdS/CdTe
          heterojunction solar cell is
          typically formed by using a
          chemical bath technique to
          deposit the CdS and close
          space vacuum sublimation
          to deposit the CdTe
          Toxicity of Cd is perceived
          by some to be an issue
          Best lab efficiency = 16.5%
Copper-Indium-Gallium-Diselenide Cell




NREL has obtained an efficiency of 19.5% in the lab
Dye-Sensitized Solar Cells




Dye-sensitized solar cells utilize a few monolayers of ruthenium-
based dye molecules on titanium oxide particles in an electrolyte
Best lab efficiency = 11%
Spectrolab’s Triple-Junction Solar Cell




In July 2005, Spectrolab reported the highest efficiency solar cell
to date, a 39.0% triple-junction cell operating at 236 suns
Conversion Efficiencies vs. Time (NREL)
                 40
                           Multijunction Concentrators
                                                                                                                                                                                                  Spectrolab                 NREL
                           Three-junction (2-terminal, monolithic)
                 36        Two-junction (2-terminal, monolithic)                                                                                                                           Spectrolab
                           Crystalline Si Cells
                           Single crystal                                                                                                                     Japan
                 32        Multicrystalline
                                                                                                                                                              Energy                 NREL/
                                                                                                                                              NREL                                  Spectrolab
                           Thin Film Technologies                                                                                                           NREL
                 28        Cu(In,Ga)Se2
                           CdTe
                           Amorphous Si:H (stabilized)                                                                                                               UNSW
                                                                                                                                                                             UNSW
                 24                                                                                                                                         UNSW
Efficiency (%)




                           Emerging PV                                                                                     Spire
                                                                                                                                                UNSW                                       NREL
                           Dye cells                                                                                       UNSW                                                         Cu(In,Ga)Se2
                                                                                      Spire         Stanford
                           Organic cells                                                                                                                                      UNSW    14x concentration
                 20        (various technologies)                                                                                               Sharp
                                                                                                                                                              Georgia Tech        NREL
                                                         Westing- ARCO                                                      Georgia Tech
                                                                                                                                                                                                 NREL       NREL     NREL
                                                                                                     Varian
                                                             house
                                                                                                                                                                                    NREL
                 16                                           No. Carolina
                                                                                                                         University
                                                                                                                        So. Florida
                                                                                                                                                                     NREL
                                                                                                                                                                                                 NREL
                                                             State University                                                                           Euro-CIS
                                                                                                ARCO           Boeing
                                                                                Solarex
                                                                     Kodak                                                            Boeing
                 12                             Boeing                                                                                                                         United Solar
                                                                                                     AMETEK             Photon Energy
                      Matsushita                                                                                                                                        University of
                                                     Kodak           Boeing                                                                  United Solar                Lausanne
                  8                     Monosolar

                                                    Boeing           RCA                  Solarex
                                                                                                                                                                                                       Groningen Siemens
                                   University                                                                                University of                                                          Princeton*
                  4                of Maine             RCA                                                                   Lausanne                                                                                  NREL
                                     RCA            RCA                                                                                                                      Cambridge*
                        RCA                     RCA                                                                                                          UCSB*                                              University
                                            RCA                                           Kodak*                    *Not NREL-confirmed                                                     University Linz
                 0                                                                                                                                                                                      Berkeley* Linz*

                 1975                       1980                                1985                                    1990                                1995                         2000                           2005
PV Module Conversion Efficiencies

                                              Modules    Lab

Dye-sensitized solar cells                    3 – 5%     11%

Amorphous silicon (multijunction)             6 - 8%     13.2%

Cadmium Telluride (CdTe) thin film            8 - 10%    16.5%

Copper-Indium-Gallium-Selenium (CIGS)         9 - 11%    19.5%

Multicrystalline or polycrystalline silicon   12 - 15%   20.3%

Monocrystalline silicon                       14 - 16%   21.6%

High performance monocrystalline silicon      16 - 18%   24.7%

Triple-junction (GaInP/GaAs/Ge) cell (236 suns)   -      39.0%
Paths to Ultra-High Conversion Efficiencies

Multijunction solar cells

Multiple absorption path solar cells (impact ionization, multiple exciton
generation )

Multiple energy level solar cells (localized levels or intermediate bands)

Multiple spectrum solar cells (up and down conversion of photons)

Multiple temperature solar cells (utilization of hot carriers)


All these approaches have theoretical efficiency limits > 60%.

The theoretical efficiency limit is > 80% for multijunction cells
utilizing other high efficiency approaches.
Remote Telecommunication Site
Remote Application: Village Power




   Philippines Village
PV Concentrator System




A concentrator system using Fresnel lenses (Amonix)
Roof-Mounted PV Arrays
United Solar – Coca Cola Bottling Plant (LA)
BP Solar Roof-Mounted PV Array
Building-Integrated PV
Building PV Curtain Wall
Building-Integrated PV




Georgetown University
Building-Integrated PV
BIPV and Plug-Power Hybrids
DOE Targets for PV System Costs
PV Electricity Costs in Europe

                 PV electricity is
                 close to being
                 competitive in
                 Spain today
                 PV electricity is
                 also close to grid
                 parity today in
                 Japan
                 In the next few
                 decades PV
                 should become
                 cost competitive
                 in many parts of
                 the world
PV Module Price Experience Curve




At current growth rates, PV module prices should fall below $1/Wp by 2027
Forecast for PV Electricity Production
Solar Energy – the Long-Term Solution?




Source: German Advisory Council on Global Change
Projections for the Future of PV

Module efficiencies are likely to exceed 20% in the next decade

The levelized cost of PV electricity may be about 6 ¢/kWh by 2020

Disruptive technologies with theoretical limits of >60% may emerge in the next
few decades

At current growth rates, the cumulative PV production would be ~36 GWp by
2020 and 4 TWp by 2040

3 TWp of solar electricity will reduce carbon emissions by about 1 Gton per year
(7 Gtons of carbon were emitted as CO2 in 2000)

Thus, by about 2035 PV could be producing about 10% of the world’s electricity
and start to play a major role in reducing CO2 emissions

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The_Status_and_Outlook_for_the_Photovoltaics_Industry_2007 BP

  • 1. The Status and Outlook for the Photovoltaics Industry David E. Carlson March 14, 2006
  • 2. Outline of the Talk The PV Market The Major Players Different Types of Solar Cells Field Installations Performance and Cost Projections for the Future of Photovoltaics
  • 3. $10 $20 $30 $40 $50 $60 $70 $0 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 Annual MWp 1990 1991 1992 ASP Constant 2005$ 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 0 200 400 600 800 1000 1200 1400 Historical Average Selling Price and Volume
  • 4. PV Shipments for Different Technologies
  • 5. The Major Players Crystalline Si Amorphous Si CIGS CdTe Sharp United Solar Shell Solar First Solar Kyocera Kaneka Showa Shell Antec Solar BP Solar Fuji Electric Wurth Solar Q-Cells Sharp DayStar Mitsubishi Mitsubisihi SolarWorld Schott Solar Sanyo Schott Solar Isofoton Motech Suntech
  • 6. Operation of a Solar Cell Photons are absorbed in the semiconductor resulting in the creation of electron-hole pairs The photo-generated electron- hole pairs are physically separated at the p/n junction The photogenerated carriers are collected by the contacts on the front and rear of the cell The photocurrent can be delivered to an external load at an applied voltage to perform useful work
  • 7. Operation of a Solar Cell
  • 8. Crystalline Silicon Solar Cells The BP Solar Saturn solar cell utilizes a laser-grooved, buried front contact The aluminum back contact is heated to n+ form a back surface n++ P field, which reduces Buried surface recombination contact Best lab efficiency = 20.1% Back contact
  • 9. Sanyo HIT Solar Cell Screen-printed Ag collection grids Textured n-type CZ Si (200 μm thick) The HIT cell utilizes amorphous Si intrinsic layers (~ 5 nm) as super-passivation layers. The cell is symmetric except for the a-Si p+ emitter layer (~ 10 nm) on the front and the a-Si n+ contact layer (~ 15 nm) on the rear. The transparent electrodes are sputter-deposited indium-tin-oxide (ITO) Best lab efficiency = 21.6% (open-circuit voltages > 700 mV)
  • 10. SunPower Back Contact Solar Cell The SunPower cell has all its electrical contacts on the rear surface of the cell The diffusion lengths > twice the cell thickness Best lab efficiency = 21.6%
  • 11. Amorphous Silicon Triple-Junction Cell United Solar Ovonic United Solar has demonstrated a stable efficiency of 13% in the lab
  • 12. Cadmium Telluride Solar Cells The CdS/CdTe heterojunction solar cell is typically formed by using a chemical bath technique to deposit the CdS and close space vacuum sublimation to deposit the CdTe Toxicity of Cd is perceived by some to be an issue Best lab efficiency = 16.5%
  • 13. Copper-Indium-Gallium-Diselenide Cell NREL has obtained an efficiency of 19.5% in the lab
  • 14. Dye-Sensitized Solar Cells Dye-sensitized solar cells utilize a few monolayers of ruthenium- based dye molecules on titanium oxide particles in an electrolyte Best lab efficiency = 11%
  • 15. Spectrolab’s Triple-Junction Solar Cell In July 2005, Spectrolab reported the highest efficiency solar cell to date, a 39.0% triple-junction cell operating at 236 suns
  • 16. Conversion Efficiencies vs. Time (NREL) 40 Multijunction Concentrators Spectrolab NREL Three-junction (2-terminal, monolithic) 36 Two-junction (2-terminal, monolithic) Spectrolab Crystalline Si Cells Single crystal Japan 32 Multicrystalline Energy NREL/ NREL Spectrolab Thin Film Technologies NREL 28 Cu(In,Ga)Se2 CdTe Amorphous Si:H (stabilized) UNSW UNSW 24 UNSW Efficiency (%) Emerging PV Spire UNSW NREL Dye cells UNSW Cu(In,Ga)Se2 Spire Stanford Organic cells UNSW 14x concentration 20 (various technologies) Sharp Georgia Tech NREL Westing- ARCO Georgia Tech NREL NREL NREL Varian house NREL 16 No. Carolina University So. Florida NREL NREL State University Euro-CIS ARCO Boeing Solarex Kodak Boeing 12 Boeing United Solar AMETEK Photon Energy Matsushita University of Kodak Boeing United Solar Lausanne 8 Monosolar Boeing RCA Solarex Groningen Siemens University University of Princeton* 4 of Maine RCA Lausanne NREL RCA RCA Cambridge* RCA RCA UCSB* University RCA Kodak* *Not NREL-confirmed University Linz 0 Berkeley* Linz* 1975 1980 1985 1990 1995 2000 2005
  • 17. PV Module Conversion Efficiencies Modules Lab Dye-sensitized solar cells 3 – 5% 11% Amorphous silicon (multijunction) 6 - 8% 13.2% Cadmium Telluride (CdTe) thin film 8 - 10% 16.5% Copper-Indium-Gallium-Selenium (CIGS) 9 - 11% 19.5% Multicrystalline or polycrystalline silicon 12 - 15% 20.3% Monocrystalline silicon 14 - 16% 21.6% High performance monocrystalline silicon 16 - 18% 24.7% Triple-junction (GaInP/GaAs/Ge) cell (236 suns) - 39.0%
  • 18. Paths to Ultra-High Conversion Efficiencies Multijunction solar cells Multiple absorption path solar cells (impact ionization, multiple exciton generation ) Multiple energy level solar cells (localized levels or intermediate bands) Multiple spectrum solar cells (up and down conversion of photons) Multiple temperature solar cells (utilization of hot carriers) All these approaches have theoretical efficiency limits > 60%. The theoretical efficiency limit is > 80% for multijunction cells utilizing other high efficiency approaches.
  • 20. Remote Application: Village Power Philippines Village
  • 21. PV Concentrator System A concentrator system using Fresnel lenses (Amonix)
  • 23. United Solar – Coca Cola Bottling Plant (LA)
  • 30. DOE Targets for PV System Costs
  • 31. PV Electricity Costs in Europe PV electricity is close to being competitive in Spain today PV electricity is also close to grid parity today in Japan In the next few decades PV should become cost competitive in many parts of the world
  • 32. PV Module Price Experience Curve At current growth rates, PV module prices should fall below $1/Wp by 2027
  • 33. Forecast for PV Electricity Production
  • 34. Solar Energy – the Long-Term Solution? Source: German Advisory Council on Global Change
  • 35. Projections for the Future of PV Module efficiencies are likely to exceed 20% in the next decade The levelized cost of PV electricity may be about 6 ¢/kWh by 2020 Disruptive technologies with theoretical limits of >60% may emerge in the next few decades At current growth rates, the cumulative PV production would be ~36 GWp by 2020 and 4 TWp by 2040 3 TWp of solar electricity will reduce carbon emissions by about 1 Gton per year (7 Gtons of carbon were emitted as CO2 in 2000) Thus, by about 2035 PV could be producing about 10% of the world’s electricity and start to play a major role in reducing CO2 emissions