SlideShare une entreprise Scribd logo
1  sur  27
Télécharger pour lire hors ligne
;4
       j ,
           00              (19)        'f.
                           (12)~~{-'Jt~~~M]*
                                                 ~ ml ~a ~J!~ A..NJ
                                                                                (ll)~MIMHt: TW20ll22096Al
  ....., ~?rFc~~a'                       ~       II          l=f                (43)~MIa:             'f" ~
                                                                                               iJ 100 (2011)                   .if- 07 A   01   a


(21)'f"tt~~t          : 099132618                                               (22) 'f"tt E3 :       rf -f. ~ @I 99 (2010)   ~   09 A 27 E3
(51)Int. Cl. :                               CllD7/36              ~OO~O~                llOlL21/306          ~OO~O~

(30)11: 7t;fJ : 200911 0/24                           ~ @I                  61/254,669
(71) 'f "tt A. :     *ffi    ~ (~ @I) LEE, WAI MUN                           (US)
                     ~@J
(72)~aAA.       :    *ffi~           LEE, WAI MUN (US)
(74 )1.1(.1£ A. :    ~*- ,"t )Rij~

'f"ttJfBt:~             : $.it,       'f"ttj}:;f~$[!IlJ~tt:           20 J~      Iii(.tt: 0            # 27 Ji

(54)~~~

5t5~ f- ttB£M              mfA fJl)5~AbJ~1iit-
COMPOSITION AND METHOD FOR CLEANING SEMICONDUCTOR SUBSTRATES
(57H~*

     *~aAl~m~~~~~*~~~~~~.~&~~~fAk~~&1i*o#~~~'*~aAl
~-~£~f- ttB£~t ~~~4g~ ~fA1t.~i~~tM.7t1&.5t5~~~. 4bJfA fJl~4bJ&1iit-                                                       0   -~£5t5~f- ttB
£M ~1i it- ' Jt ~ %Wf t~ !ff £M ~ HP~ ' &;fo                                +..::.
                                                tt£ Jt,1;*@t ' ..::. If Jt,1;*@t ' If Jt,1;*@t ' ~;Ui£ If
@t, mt£,1;*@t, 2-mt£L.-,1;*@t, ~fL,1;)lUt~:1fi~Jt@t5tt.%~jt,)J'-ifAtt£..::.~@tlLpHft.&~~~-t­
)~f~~"t%Jfrl ~ A.~                6   .f-i:~   10 '   &~ ~5';H1.1if'1PJT ~fA)Z-/~*$J          ,   "t~tt£..::.~@t ~%~ ~ 1-,~ L.-tt-1,1-
..::.~@t   ' §.If £..::.~@t ' '~§.If £..::.~@t ' ..::.jl§.1f £..::.~@t ' ,~li c.,£§.1f £..::.~@t ' 1-,~£-3­
mt~tt-1,1-..::.~@t                '   1-'~£-4-mtTtt-1,1-..::.~@tfAtt£..::.~@t                     0




                                                             Rl
                                  OH                                                 O.H.

     0
                                      I
                                      "(1
                                                                                      I 0
                                                                                     -I>
                      I
                    110
                                                                                      I
                                                                                     01-1
                                                                   R2
;4
       j ,
           00              (19)        'f.
                           (12)~~{-'Jt~~~M]*
                                                 ~ ml ~a ~J!~ A..NJ
                                                                                (ll)~MIMHt: TW20ll22096Al
  ....., ~?rFc~~a'                       ~       II          l=f                (43)~MIa:              'f" ~
                                                                                               iJ 100 (2011)                      .if- 07 A   01   a


(21)'f"tt~~t          : 099132618                                               (22) 'f"tt E3 :        rf -f. ~ @I 99 (2010)     ~   09 A 27 E3
(51)Int. Cl. :                               CllD7/36              ~OO~O~                 llOlL21/306          ~OO~O~

(30)11: 7t;fJ : 200911 0/24                           ~ @I                  61/254,669
(71) 'f "tt A. :     *ffi    ~ (~ @I) LEE, WAI MUN                           (US)
                     ~@J
(72)~aAA.       :    *ffi~           LEE, WAI MUN (US)
(74 )1.1(.1£ A. :    ~*- ,"t )Rij~

'f"ttJfBt:~             : $.it,       'f"ttj}:;f~$[!IlJ~tt:           20 J~     Iii(.tt: 0              # 27 Ji

(54)~~~

5t5~ f- ttB£M              mfA fJl)5~AbJ~1iit-
COMPOSITION AND METHOD FOR CLEANING SEMICONDUCTOR SUBSTRATES
(57H~*

     *~aAl~m~~~~~*~~~~~~.~&~~~fAk~~&1i*o#~~~'*~aAl
~-~£~f- ttB£~t ~~~4g~ ~fA1t.~i~~tM.7t1&.5t5~~~. 4bJfA fJl~4bJ&1iit-                                                          0   -~£5t5~f- ttB
£M ~1i it- ' Jt ~ %Wf t~ !ff £M ~ HP~ , &;fo                                +..::. tt£ Jt,1;*@t ' ..::. If Jt,1;*@t '   If   Jt,1;*@t '   ~;Ui£ If
@t, mt£,1;*@t, 2-mt£L.-,1;*@t,                          ~fL,1;)lUt~:1fi~Jt@t5tt.%~jt,)J'-ifAtt£..::.~@tlLpHft.&~~~-t­

)~f~~"t%Jfrl ~ A.~                6   .f-i:~   10 '   &~ ~5';H1.1if'1PJT ~fA)Z-/~*$J           ,   "t~tt£..::.~@t ~%~ ~ 1-,~ L.-tt-1,1-
..::.~@t   ' §.If £..::.~@t ' '~§.If £..::.~@t ' ..::.jl§.1f £..::.~@t ' ,~li c.,£§.1f £..::.~@t ' 1-,~£-3­
mt~tt-1,1-..::.~@t                '   1-'~£-4-mtTtt-1,1-..::.~@tfAtt£..::.~@t                      0




                                                             Rl
                                  OH                                              O.H.

     0
                                      I
                                      "(1
                                                                                   I 0
                                                                                  -I>
                      I
                    110
                                                                                   I
                                                                                  01-1
                                                                   R2
201122096


    if§   ~    $      g~ ~

              *        $    g~ ~        ±     ~ 2 0 0 9 if 1 0 Jj 24                B $   g~ Z ~ ~ ~ B'lf 111     "fJ. ffj
    $     g~ ~        61/2546695J}t !¥;               ff       )t   tl   0




     [~EY3pJT~Z11VltT#j!~                                  ]

              *~EY3~~m~§~~~~m~oo~~~~~~*~

o   ~ ~g ~            00 i3t    ~       * it ~ 91 fll ~o/.) !¥; *Jl J!fG ~o/.) Ez.. 11 1t.          ' ;tt: -§, -2; - -a-

    ~m£=.M~~~z*m~,~~~~~~~~*~~

    91 fll    ~o/.)   s"J   ~ ra~       0




     [ )t;    JW      11 fiILT ]

              ~ ~           "fJ. ffj 6, 1 4 3 , 7 0 5 5J}t , 6, 3 1 0 , 0 1 9 5J}t , 6, 4 4 0 , 8 5 6 5J}t ,
    6,514,3525J}t' 6,514,9215J}t , 6,534,4585JJE ' 6,541,4345m '

    6,716,8035JJE' 7,250,3915JJE '                                       7,312,1865JJE Ez.. 7,541,3225m j:-m



    -a-~ij~~~               0




              ~ ~           "fJ. ffj 6, 3 9 5 , 6 9 3 5JJE Ez.. 6, 5 4 1 , 4 345m f-m 7G - m 1£ * ?¥

    ~~~~~~~~~*~m~~*?¥~~~~ooz~~~

    !¥J~J!fG~Ez..1f$'~1f$-§,-a-~m~~mfl~mEz..~                                                                    ••

    r~~~Z~*?¥~~~~ooW-~-a-~£1£~2m£%~

    ~ :P z            m ~~ , *'~ O. 1 m £ % ~ ~ :P z -a- ij~                               it   ~ ~o/.) JJz. *'~ 2m £ %

    ~~:Pz~.M!¥;~~~~~o~m~~~~~~~~~

    ~ *'~ 4-6Z pH                   0       t5t   f~:till ~ m ~              *Jl   ~ ~o/.) ~ ~ *'~ 4.5-5.5!¥; pH       0




                                                                              -5-
201122096




     ( Jj ~p lOp P m ij~                    M J-j    1 % f$ ~ ~~)                      0




            ij~   M ' flf JjU                ~ 1 - f~         Z iJ'C - 1 , 1 -          =   ijm   M ( -          jlR   ffi   ~ HEDPA

    )   '~~~.~W~~~.ft~®m~~~m~B~~o

    B 3iS   7t J           f§~   'M    HEDPA          f*      .L-~ ~         ;. /J     fj~ 3 0   {51   ~-j   B m; {51 71<        *    f~   m
    ~   , rij         fF   m~ •              f!t! tJ:!] FtU    ~U        0       m i@    1 50 {51 ~-j         B m; {51 71<        B~ ~U     3iS


    JE 1& ;       HEDPA~                     it. ¥A 1'1       ~     fF       0




     [ ~ EjJ      pg       ~     ]

            *~~~~m~m~~~~~MLm~~&n$o*




            mgM~-OO~~.~~~~m~m~,~~g~*

    *'5 ffiJ PO T          z     iJ'C ~      =  ijm ~~


                                                                OH Rl                 OH
                                                            I
                                                     o=p-.....-P_O
                                                                                      I
                                                            I                         I
                                                           HO                    R2   OH

    ~ tp R 1 ~ R 2 {*                  ttl   [q[ gtz ~ [q[ :Mz               m I§       EB T 3lU pJT          *g ~ L         ~$   *g : i
     ( H)         ,    i        ~    ft to/] (      0 H)            ,       l (       C 1)      , ~:fF 1 ~             r,C;   8 00   mR 1*


                                                                                  -6-
201122096

    TZ~~~H~R~~~~H~~o~~m~~~~~=

    Mtt~~~·.~.;Z-~~m~                                                                 • • TB • •                   tt~~

    ~m   tJ   ~JWJ ~1J p H:* n~         6:¥ *Cj 10      • ~ ~           till       fft 0 m ;         %   R B       ~   :¥ 5 m
    ;    %    Z   ~    00 m tl:;1!fu • R 'U             ~   ;.   ~ 7]<         0




              m~~zm~~mR~~~=.Mtim=Mtt~ft~

    Z    ~ 1}     tt   ~     *Cj 1 : 1:¥ *Cj 10: 1               0




              ~{*ziJE~=n~M{*~l-f~Z~-l,l-=n~M' 5:2Ef3~

o   =n~M' f~5:2Ef3~=n~M' =lt5:2Ef3~=n~M' f<1f.1a~

    5:2 Ef3   ~   =     n~   M.        1-f~ ~ -3-n~ ~                 i7t   -1,1-=             n~    M.     1-f~ ~ -4-

    n~Ti7t-1,1-=n~~~· JJ<.fEt~ZrMfttm                                                 0




              ~m~~~~m=Mzm~~,.~z,~m=Mm

    ~+=m~~~M'=Ef3~~M'Ef3~~M'~§~Ef3M

    .    n~~~M' 2-n~~Z~M'                                            .iiJW~~~~~~M                              0   ~*fI.~

    tmmm~-2r~f~~M                               0




              ~m~~-2r~~.~Mzm~~'~Mm~~M·~

o   M'~~M'Ef3M'~EM'~M'~Ef3M'm~OOM'

    M~M·~*M·~=M·~mM·EffiTM·TM·=

    #i, Z     MJJ<. fEt      ~     z rM ft tm       0




              ~~mmM~~,~~m~~mm~-2r.~.tt~ft

    ~'~~~.~~·~.~~JJ<.~

    ~~~~-2r~-~ft~~~~~~ft~o
                                                                                   ••     TB • •               o~~m



              ~   • • TB • •                    tt~~~~~ft~~~~Tmm~~

    .tt~~~~Z:¥~-~:~~~B                                                               ••        ~~~~m~~

    .    ~ ~      1t   [g    iJE   ~   j1i: (   T M A H)             • ~ ~           1t   [g   iiC   ~   j1i: E    7]<   ft tm

                                                                     -7-
201122096

     ( TM A H 1i 71< -2t 1o/J)                         , f,     ~         1t =f          [9 EJ3       £ti: ( B T M A H)                , f,        ~


    1t     [9   T    ~ti:       ( TBAH)                , •       ~         f, ~ 1t ~m                  '   ~    f, ~ 1t       -= (         2- 1~

    Z ~)             EJ3 ~ti:       (THEMAH)                             , -        Z ~~~~ , 2- (2-1~ Z ~~~)

    Z~~,             2-      (2-~~Z~~) Z~~,                                               N,N,N--                 (2-f<]Z~)                      i
     ,     ~    P3   ~~ ~~         ,    3-~~ ~         -1-P3         ~~        ,    2-~~ ~             -1-P3      ~~    ,    2- (N-EJ3           ij~


    ~)          Z~~'              2- (2-~~Zij~~) Z~''=: (f<]EJ3~) ij~~Z

    ~'~1Bt~Z¥~-2t~o/)                                  0




                ~ {*        Z pHi'B         rm {* 1)£ *-             n~        6¥ k0 10            0




                ~oomttM*~m~*~m~mzm~1o/J$o~~Z

    ~      Im m '1'1        ~rr   19 115    ~F     • -T'lt '                   ~.           -T'lt '              ~.      -T'lt ' Ez. I 9X,

    mtt'M~m.9X,~*mtt                                                           • • '~*MZM~*.M9X,

    ~71<~~'lt.~1Ez.~.{~~                                             0




                ~¥®.m$,.ooz,~~m~1o/J~~m.tta~

    ¥1: 10,                     a~¥l                   50,           a~¥l:                         100,          a~¥l:                      150,

    a      ~    ¥ 1 : 2 50 ' Ez. a                     ~      ¥ 1 : 500 9X, *                          ~    $ Z {3: {P]         tt     -WU r     1--)

    D I 71< #Ii      f~     0     H ED PAW             ~      Im m 'It              ~rr    *J3. -2t    ~    £    ~     tJ%   r§J ~~    *     0   ~

    Im m '[t         ~rr    /f    im fF     m     ~        7t tfj(       ~rr       ' 'M HEDPA1--) m                     W!    150{5} t1 Ef

    ~      {51 71< !¥J      ¥. N it m             B~   *     ~ :ijt ~              H ED PAZ                 J~   Wi   ~o/] ~~ fg~     lIt   ~g   0




                -g~m*~m~zm~1o/J!¥J~$,~1g~~m-~

    ft '        ~ ~ ;ft ~ ~                 !¥J   ~    Im 19         ~ ~            ill    ~   e Ez.        {~   -k if       ~ ~o/)    Jf Ez. -

    9X,~g~~~~Im~zrnM,~~gWi1o/J'~Im~gWi1o/J

     'Ez.~~~,~~;ft~§*AA~~*AA~~W!~$£

    ~       ;   M~ ~ ~            ft    ~   00 W ~            fJ!J. ;.         Z    ~ ~ ~              * *5 f~ PO r             Z      ~7t ~         =
    ~tlf   • !¥J m          ~&    tft   fI] :


                                                                                    - 8-
201122096

                                                                            Rl
                                                                  yH                  yH
                                                              O=r'---"'~r=O
                                                               HO                     OH
                                                                            Rz

    Jt 9=J    R      1   EZ.    R 2 1*      if§     ~ ~ ~ ~          illz   ~ §       ill T JU pJT      *Ji glG z    M *Ji     :    ~

     ( H)                ,     ii.    ¥i. 1t      ~o/)   ( 0 H)       ,     l ( C 1)          , ~ ~ 1 ¥ $CJ 8 @J ~                 !*




o
     'EZ.~.~~*o~mglG~~~~~~~mm,gw~EZ.

    /~¥i.~~z~~W~~TW£ff~~om~~nmz~




    :ti   ~   ffif       Fa~    1* 1£ *9            1 0 fj;   W *9   3 0 5t      it Z Fa'      0   :$: 3t pJT ~ z         *Ji glG   ~o/)

    ~~*~R~~~~M~m~m~~~~~~~*z~®

    ~*.~®~m~~~'~EZ.m~~m~.~B~zJt~


o

              :$:~~~~-~~~zm~m~,~m~~mm¥=

    ij~ ~     Wm                =      ~~   '1:1    1t -EI    ~o/) ~ ~ ~         tt   *9   1       1¥    *9   10 :    1   T   i§    1J~

    71<. ~ ~         -EI       ~o/)    0




              ifG£=ij~~Z£:$:*5mtzDT




                                                                                 -9-
201122096

                                                                      Rl
                                                                OIl            OB
                                                             I
                                                         O=p'--+--p=O
                                                                               I
                                                             I
                                                           I10
                                                                               I
                                                                               OIl


    ~    $   R     I   Et..   R 2 1*   if§   ~ :@G ~ ~           :Mz ~ § EE ~ JU pJT        *Ji m ~    M *Ji     :   ~

    ( H)               , ~ ~          1t to/.) (         0 H)    ,jA ( C 1)             , ~ fj 1 ~   *Cj 8 1iI   ~   1*

    -T   ~   i3t       ~ :@G     :5    ~     Et.. ;tfG   ~ g~ :@G     :5   ~ g~     0




             ;tfG ~           =- g~ ~ ~ Jf -WU ~D ~ JU                     :




                                                                           - 10 -
201122096

     ~m                     RI   R2             tf:im
     l-~z.m-l,l-=JmM        OH   CH3
                                                         yH   OH OH




     52Efl~=JmM             H    H
                                                  =r+t=° OH eH 3 0lI

                                                         OH H      OH



                                                  o=t+t=o
     (MDP)




                                                        HO    H    OH

     ~52Efl~=JmM (HMDP)     OH   H
                                                         O~OH
o                                                 O=!              !=O
                                                         1
                                                        HO    H
                                                                   1
                                                                   OR

     =l52Efl~=JmM(ChMDP)   Cl   Cl
                                                         OIl Cl    Oll



                                                  o=t+t=o
                                                        HO    CI   OH

     ~tiB~52EJ3~-JmM        OH
                                                         Oll Oll OIl
     (HCMDP)

                                  0               O-P
                                                    -I
                                                      I
                                                        HO
                                                                   1
                                                                   1'=0
                                                                   1
                                                                   on
o




                                       - 11 -
201122096

     1-~~-3-H3t~m-l,1--~M   OH   -CH2CH2NH2



                                                O=!+!=O
     (APD)
                                                  OH OH OH




                                                 H! HC iH
                                                        2
                                                            I H2
                                                   H 2N
                                                            I
     1-~£-4-MCTm-l,1--~M    OH   -CH2
                                 CH2 CH2NH2       OH OH OH



                                                =t+t=°
                                                 HO H

                                                   CH
                                                        Z1
                                                                2
                                                                    OH



                                                    H 2C
                                                        I
                                                        I
                                                        NH      2




                                       - 12 -
201122096

    p H:* 1i~ 6               ¥ *,q   10 '     ffiJ   ~ Jf9 ~              '[1: it 1%     ~o/.] ~    ii.    ~     it     jlfl ,    Ii. ¥, it
    ~&~T~Z.~I%~mm~z~                                                                       ••        ~m           •• ~I%~:
    ~     ¥, i t . ' ~ ~ it [9                        in       ~.              ( T M A H)            , ~ ¥,            it   [9   in   ~ ~1i:

    1i 7.K 1%         ~o/.]    ( T M A H 1i           7.K 1%       ~o/.])        , ~ ¥,       it T         [9 Ej3 ~1i:       (    BTMAH

     )     ,    T BAH '               ~. ~ ~             it        ~o/.]    ,   WG       ~ ~   it    ~        ( 2 - 1<4 Z          ~)      Ej3

    •      ( THE M A H)                    , 1~ ~           Hti:   ~tfj    /fIt. '        1~ ~       Hti:   11J   !t to/.]    ~D N , N -   =
    z~~~,~~~mffi'~~~~~z{B~~~M'Z=


o   Hti:,      -Z~~H~'                     N,N-=ZH~~Z~'                                         2-       (2-1~ZH~~)                        Z

    ~~,        2-      (2-H~Z~~) Z~~,                                            N,N,N-.=                (2-1<4Z~) ~,


    oW rg      ~~ H~           ' 3-Hti:    ~   -1-rg M ' ,                       2-H~ ~        -1-rg M ' 2- ( N-Ej3                        H~

    ~)         Z~~,              2-    (2-H~~ZHtt~) Z~~,                                             -       (1~Ej3~)                   Htt~

    Z~,               WG1m:~Z1EBI%~o/.]                     0




               • '11: *i 1iI          ~U   Z   I)(    £ PI         ~       l&   ~ ~       *,q 25m £ %                0




               ~{~ZpH{*1t£*1i~6~*q 10                                                0




o   • 1ifi     ~J

    ':I.' 1iffi -Wu   1

               T~~~mm~~.1iffi~~~~I%~Z~E~o




                                                                                 - 13 -
201122096


    *Jirrx                1t~lm
                                                ~1j:     ~1j:     ~tf1f   ~tf1f    m£ m£
     lm                                         m£        ~       ~1j:    i}::£     %        tt~
             I-f<1Z3Jt=g~M                      206           6   0.69    142.1    14.21        3.79
             +=m~$:ii~M                         326.5         1   0.115   37.55    3.75
      1      25% TMAH71<~tf~                                                  ~JWj~1J~pH 6

             71<                                                          *U~£
             *~..§.
             r~c,.m                                                       1000
             I-f<1Zm=gmM                        206           6   0.69    142.1    14.21        9.96
             ~l§~Ef3~                           128           1   0.115   14.72    1.47
      2      25% TMAH71<~tf~                                                  ~JWj~1J:¥pH 6

             71<                                                          *U~;.
             *~..§.
             rvc,.m                                                       1000
             I-f<1Zm=gmM                        206           6   0.69    142.1    14.21     13.73
             1f!!~                               90           1   0.115   10.35    1.04
             65% ~ ~ 1t.=. (2- f~ Z ~ ) Ef3 ~
      3                                                                       ~~1J~pH 9
             (THEMAH)
             71<                                                          *U~;.
             *~..§.
             'jc.,~                                                      1000
             1-~ZiJt=gmM                        206           6   0.69    142.1    14.21     12.74
             g~~ii~~                             97           1   0.115   11.16    1.12
      4      45%JJt~~~1tlo/)m~                                                ~JWj~1J:¥pH   9
             71<                                                          *U~;.
             *~..§.
             !'/C'13!.                                                    1000
             I-f~Z3Jt=gm~                       206           6   0.69    142.1    14.21     16.26
             f~£Z~~                              76           1   0.115    8.74    0.87
             N,N-=Zf~~g~/- Z~¥g~
      5                                                                       ~)WJ~1J~pH 7
             (1:1m;.tt)
             71<                                                          *U~£
             ~..§.
             f,/C,1I!                                                    1000
      6      I-f<1Zm=gmM                        206           6   0.69    142.1    14.21     14.08
             li3iJ1lJ~                          87.8          1   0.115    10.1    1.01
             Z=g~                                                             ~JWj~1J:¥pH   10
             71<                                                          *U~;.

                                                      - 14-
201122096

         *~E3..
         '~C,.m                                               1000
          1-f<1Z33t=fl~~            206           6   0.69    142.1      14.21   85.24
         2-n*~Z~~~                 14.5           1   0.115   1.688      0.17
     7   25% TMAH7](~~1&                                             ~JW1i1J¥pH 7
         7](                                                  *U~£
         *~E3..
         IVC'.m                                               1000
         1-f<1Z~3t=n~~              206           3    0.3    61.8       6.18       2.92
         f~2 Ef3~=n~~~              192           3    0.3    33.6       3.36
         +=i5C~~Ui~                326.5          1    0.1    32.65      3.27
     8
         N,N-=Zn*Zr!¥                                                IDWli1J¥pH 7
         7](                                                  *U~£
o        ~E3..
         I>C'.m                                               1000
         1-f~~-3-n3rpgm-1,1-=n~~   235            6    1.2     282       28.2    18.55
         f~~Z~                      76            1    0.2     15.2      1.52
     9   -=-(f~ Ef3 ~)fl*~Zm                                      ~JW1i1J¥pH 9
         7](                                                  *U~£
         *~E3..
         fVC"l3!                                              1000
         2Ef3~=n~~                  176           6   0.69    121.4     12.10       8.64
         2-n*~Z~~                  125            1   0.115   14.4       1.40
    10   28%i~1ttt~~1&                                           ~i1J¥pH 7
         7](                                                  *U~£
         *~E3..                                               1000
o        /VD".m


         1-f~Zm=n~~                206            6   0.69    142.1     14.21       6.44
         f$~~~                     192            1   0.115   22.08      2.21
         65%i~1t - (2-f~Z~)
    11                                                            ~i1J¥pH 9
         Ej3~(THEMAH)

         7](                                                  *U~£
         *~E3..
         "Jc",lt!.                                            1000
         f~2Ef3~=n~~               192            6   0.69    67.2       6.72       2.06
         + =~3t~~Ui~~              326.5          1    0.1    32.65      3.27
    12   25% TMAH7](~~1&                                         ~JW1i1J¥pH 10
         7](                                                  *U~£
         *~E3..
         I'JC,1I!                                             1000
    13   1-f~Z~3t=n~~~             206            6   0.69    142.1     14.21    16.26
         f~~Z~~                     76            1   0.115   8.74       0.87
                                         - 15 -
201122096

          1O%i~1t~7j(7§~j(                                        ~WJ~fj~pH 7
          7j(                                                  'U~.m
          *IZI-E!.
          f'JC'£                                                1000
          1-1~Z:3n=H~~              206        10      1.15    236.9    23.69 21.24
          H3(~iii~~                  97            1   0.115   11.16     1.12
     14   10%i~1t~7j(7§~                                          ~WJ~fj~pH 7
          7j(                                                  'U~.m
          *IZI-E!.
           "c.,.m                                               1000
          I-f~Z~=H~~                206            3   0.345   71.07     7.11         8.13
          f~~Z~                      76            1   0.115    8.74     0.87
     15   10%i~1t~7j(m~                                           ~~fj~pH        7
          7j(                                                  'U~.m
          ~-E!.
          f'JC'..m..                                            1000
          I-f~Zm=ij~~               206            3   0.345   71.07     7.11         7.04
          lUiJJH~                   87.8           1   0.115    10.1     1.01
     16   10%i~1t~7j(7§~j(                                        ~}jiJ~fj:¥pH   10
          7j(                                                  'U~.m.
          *IZI-E!.
          rvc.,.m                                               1000
          I-f<1Zin=ij~~             206            1   0.115   23.69     2.37      14.21
          2-ij3(~ZiiiM              14.5           1   0.115    1.67     0.17
     17 25% TMAH7j(7§~                                             ~~fj:¥pH       7
          7j(                                                  'U~.m.
          ~-E!.
          I'JC'.JI!.                                            1000
          I-f<1Z;tn=ij~~            206            4    0.4     82.4     8.24          3.9
          f~~Ej3~=ij~~              112            4    0.4     44.8     4.48
          +=~~~iii~                 326.5          1    0.1    32.65     3.27
     18   65%i~1t     - (2-f~Z~)
                                                                   ~}jiJ~fj~pH    9
          Ej3 j1(THEMAH)
          7j(                                                  'U~~
          *IZI-E!.
          f'JC,lI!                                              1000
          1-1~Z~=H~M                206            8   0.92    189.5    18.95      12.88
          ~.~Ej3~~                  128            1   0.115   14.72     1.47
     19   25% TMAH7j(7§~                                           ~WJ~fj~pH      7
          7j(                                                  'U~.m
          ~.§..
          f'JC'.JI!                                             1000
                                          - 16 -
201122096

                I-f<1ZJlt=ij~~~                             206         8      0.92   189.5    18.95    18.31

               ~~~                                          90          1     0.115   10.35    1.04
               65%i~it =: (24~Z~)
        20                                                                                ~JWJ~1f¥pH 9
                Ef3~(THEMAH)

               71<                                                                    'U~;
               *~.§.
               rvc,13!                                                                1000
               f~:s:2 Ef3 ~=ij~~                            192         1      0.1     11.2    1.12      0.34

               +=~lt~~Ui~                                  326.5        1      0.1    32.65    3.27
               65%i~it.=.(2-f<1Z~)
        21                                                                               ~JWJ~p~pH 10
               Ef3~(THEMAH)

               71<                                                                    'U~£
o              *~.§.
               f'J(j"l3:!.                                                            1000




                ~.~~~~~*B~zm~m~~$~~=.M~

    m=MttmffiZ~~~'~.~~~~OO~Z.M.~g

    Wlto/.]R~                ••     -TJ~Wlto/.)8"1m~t1             0




o



    •    ~ ~U 2

               ,DJ 5 {51      *Jl   ~   to/.] 9 m ~ 1 00 {51 D I 71< ( 1 : 2071<      m f¥    ) flft   m fX

    =    ij~   MR            O. 1 2 2 % f~ ~ Z ~~      0   ~   ill 1t- *1£   :t~ 6 : 1 ~ ~    tt 8"1   ~lt ~

                                                               - 17 -
201122096

    =.~~m=~tt~~~oM~~m~~~~~.mffi~

    8~ *~     *     0




    •    :fjf!! -WU 3

              .L-~ 1 {51           *J3.   ~    to/.] 5 ~~      ~ 1 0 0 {51 D I      7.K (       1 :    100      7.K   m f¥    ) TIft   m
    fl~:lV,~                   0          ~~~~~~jili~~0.141%                                          1-f~Z~5G=ij~~Ez.

    o. 0 0 9 % f~       ~             Z ~~       0       ;It   ill    ~   *t t:;f 6:    1 ~ 1}        tt   ~ ~ ~         =    ij~ ~    f1

    m=~tt~~~oM~~m~~~~~.mffi~®~*o




    •    :M!! {§U 4
              .L-~ 1 {51           *J3.   ~   to/.] 1 5 ~~       fj~ 1 0 0 {51 D I 7.K      (   1 :    1 0 0 7.K      mt¥     ) TIft   m
    fl   ~:lV,~            0          lIt   m~ ~~:)( jili ~ ~ 0.0711%                                 1-f<]     Z     ~5G =   ij~ ~ Ez.

    o. 0 0 9 % f~       ~             Z     ~~   0       ;It   ill    ~   *t t:;f 3 :   1 ~ 1}        tt   B~ ~ ~        =    ij~ ~~   f1

    m=~tt~~~oM~~m~~~~~.mffi~~~*o




    •    :fjf!! {§U 5

              tJ   5 {51           *J3.   ~    to/.] 14m             ~ 1 00 {51 D I     7.K (    1 : 20         7.K   mt¥     ) TIft   m
    fl   ~ :lV,~           0          lIt     ~~ ~ ~ fJlj. jili ~ ~ 1.185%                            1-f~      Z     ~ =     ij~ ~ Ez.

    o. 0 5 6 % ij~      ~ E~ ~~                      0   ;It   ill    ~   *t t:;f 1 0   :   1 ~ 1}         tt   B~ ~5G ~ =       ij~ ~

    ~m=~tt~~~o.~~m~~~~~.mffi~®~*




                                                                                 - 18 -
201122096


                  J7JGfB                  jiJjQ~~/j££~                  fjtff!jiJj     Wt(051)       %
         I-f~ZJJt=g~~~
                                         DEQUEST 2010                 Thennphos           580      13.0%
         CAS#2809-21-4
        r~~z:.~ (70%)                      Glycolic Acid                Dupont            60        1.3%
      r~~g3(~m~fM (50%)                                                 SanFu             600      13.4%
         - z:.~~H3( (85%)                     TEA85                       Dow             470      10.5%
                      7j(                                                                2760      61.7%
                                                                                         4470     100.0%



o

                  J7JGfB                  jiJj£~/j££~                   fjtff!f,Jj     Wt(051)       %
        1-~z:.~=~~
                                         DEQUEST 2010                 Thennphos           530      11.2%
         CAS#2809-21-4
    ~~n~7j(Zg3(~ =: (~Ef3~g~
                                         DEQUEST 2000                 Thennphos           90       1.9%
       ~~)   CAS#6419-19-8
     N,N-=z:.r~~g3( 85%
                                                                       Arkema             310      6.6%
        CAS#3710-84-7
o               -z:.~~g3(                      MEA                       Dow              310      6.6%
                      7j(                                                                3480      73.7%
                                                                                         4720      100%




         ::$:   -x.    r:p Jt II • 1ifli -wU B"J *J3. J7JG   ~o/]   /F ffl   ~ ~     ( r e que s t) J3. ii

    ~f=EfE1Jm~B"JJE~~/F¥A1:r~                                0



                                                             - 19 -
201122096

               ~m~=~~ft~&~*~~~(~~ffifiB~ffi*

    ~f;.f:1)         PJfFffl~m~~tl                0




               ft~-~            ••     ~oo~,~m~~~~PJm~~m~m

    ~ 40/1     Z m~ tl:         ~~ 8~ ~    ITll   ~5   t1   ~tl ffij   if   1J~   JJ!   1;) ~   m~   =   g~ ~   Z
    *fi gIG to/.J    0




               .~~'~~~ITllmttmw.~~m~u.~~.~

    ~~~~m.~m~m~~Zm~~ho~~m~~z~

    ITllmttm~~mo~~~~ffl~ffifi~~Z~ITllmttm~

    tl5   ~    iii T 111: '     ~   iii T 1[1: ' ;}F iii T 1[1: '                 m 1[1:   ' !YZ   ~ ~   m~ ,
    ~~m.z*~tt                          ••             ,*mZ~~*~M,!YZ~~m~

    Z     7.1<. ~~   1[1: • •   0




               B~m®A                ••    ~OOB.~~mM~~.'~.&.

    ~OO~~~~'~.~.~~*B~~~~m~m®~~

    ~§~ffi~~Z~.W*.~~~m~o~~~~.~ffi

    ~.~,m®~E.fl~~~                                              ••          m~~~ft~o*W~

    ~~.&.~oo~~~~m~OOtt'~*B~Z~~~~

    &ffl~~~T~Z$mW~~~ffi~~oW~$m~ffig

    Z pJT     ~      • ~ ~!IX ' W ffj , W ffj $ ~~ ~ ~ ~ gB ~ ?G #~ iff A                                       *
    ~~1;tt.~               0




                                                                - 20 -
201122096                                                                               862638



                                 ~t BA         l- *1 ~! BA .-
                         (;zfs:$~*:Ji~rt '   11Im ' ~o/J{£~~ , *§~B7:1'~*~)

    * tJl   1t$~     : 099132618                                   C- [/ /)   "1-1b   (2006.01)

    *tJl1t8 : 099~09)127EJ                            *IPC~. : rt:>fL L ~b            (2006.01)


    - , it B,ij ~.: (4':>c./ ~ :>c. )
            m~*~~~tt        m8~*J3.frlG~O/]W 151*
            Composition and method for cleaning semiconductor substrates


o
             *~~~~m~§~~~ft~~OO~~~~~&~~

    ~~mfrlG~&h$o~k~Z'*~~~~-m~*~~

    ~ttzm~~~OO~~~~~~*~m~~~~~mm~

    &l5$o-mm~*~~~ttzl5$,~~~~~~~tt

    W~*'&W+=~~~~M'=~~~M'~~~M'

    ~e~~M' H3Z~~~~' 2-H3Z~Z~wM' ~i1iJWM~~~

o




                                                       - 1-
201122096



             The compositions and methods herein relate to the method for the removal of residues
    and contaminants from metal or dielectric surfaces. Particularly, a composition and method of
    cleaning residues after chemical mechanical polishing of a copper or aluminum surface of the
    semiconductor substrates. A method of cleaning semiconductor substrates comprising contacting
    the substrates with a solution of water, and sufficient amount of alkyl diphosphonic acid
    comprising alkyl diphosphonic acid selected from the group of 1 hydroxyethane 1,1
    diphosphonic acid, methylene diphosphonic acid, hydroxymethylene diphosphonic acid,
    dichloromethylene diphosphonic acid, hydroxycyclohexylmethylene diphosphonic acid, 1-
    hydroxy-3-aminopropane 1,1 diphosphonic acid, l-hydroxy-4-aminobutane 1,1 diphosphonic
    acid mixed with dodecylbenzenesulfonic acid, xylenesulfonic acid, toluenesulfonic acid,
    phosphonoformic acid, sulfamic acid, 2-amino ethane sulfonic acid, or fluoroboric acid or an
    organic carboxylic acid and pH is adjusted to from greater than 6 to about 10 with a metal ion
    free base, and a surfactant.




                                                       -2-
201122096




                                                                       OH Rl             OH
                                                                I
                                                         O=p-+--p=O
                                                                                         I
                                                                I
                                                              110
                                                                                         I
                                                                                         OIl

                  ~    rp    R       Ez..     R 2 1*         t§    [Q] :@G    /f   [Q]   1ft   ~      EJ ill T 7U ptf *43. nJG Z             tt~
o                 *43. :     W. (
                                 1


                                              H)         ,        W.   $i, 1t lo/.j ( 0 H)                     'j (     C 1)      'Jt       ~

                  1~       *c;   8@ ~               Jw: T Z ;tJt              ~ :@G      7!i   ~    Ez.. 1ft    ~   Htz :@G 7!i    ~   Htz




            e.   71<   0




o           2 . ~D     $ ~N      J!J. fU i'B             ~        rg       1 Jj   Z *43. nJG       ~o/.j   ,    ~   rp 1ft   ~     =   Hl    ~

    tl rg   =    ~~ I[j:    1t it           ~o/.j   Z    ~    If tt 1* 1:£            *c;      1 : 1 ¥ ~ 1 0:                1 0

            3 . ~D $ ~N          J!J. fU i'B             ~ ~ 1 Jj                 Z *43. nJG lo/.j ,            ~   rp   ~   1ft !k    =     ij~

    ~~1*~I-f~Z1ft-l,I-=ij~~~,                                                      ~Et'~=g~~~,                           f~~Et'~=

    ij~~~'       =j~Et'~=ij~~~' f~$a~~Et'~=gl~~'                                                                                       1-1<1

    ~   -3-Htz    ~    1ft   -1,1-=                     Hl   ~~        ,    1-1<1 ~         -4-Htz T 1ft            -1,1-= ij~ ~:@G




    ,Et'~~~~, ~e~Et'~~, Htz~£i~~' 2-Htz~Z~~~' ~
                                                                                   - 21 -
201122096

    tiJ1IJ~~&~~1~~~                          0




               5.      tm $        ~~   W frj ii'B    ~ ~ 4 Jj      Z ffi PIG       ~~        '   Jt   tp      ~ ~ f~ ~ ~~

    ~~~~~~ffim~z~m:~M·~M·~.M·~M

     '~EM'~M'~~M'm~ooM'oo~M'~*M'

    ~=M·~mM·liffl~M·TM·-.ZM&~~zm

    -@I   ~~    0




               6.   PO         $ ~~     W frj ii'B    ~ ~ 1 Jj      Z ffi PIG       ~~       '    Jt   tp      ~ ~      fir   ~    1*
    ~~~~~ffimPIGz~m:._~~·._~~·~                                                                                               ••
    ~~m.~&1Bl~ZYR-@lt~                                       0




               7 . PO $ ~~              W flJ ii'B    ~ ~ 6 Jj      z   *J3. fflG   t~       ' ;1t     tp      ~ ~      1Ir   ~ ~

    .~~.~~~~~T~ffimPIGz.tt~-@I~tpz~~­

    ~:~~~~.~·~~~m~~·                                                                     ••            ~~~~~(

    T M A H)                   • ••        it    ~ ~ ~ ~          li 7.K -@I   ~~        (    TMAH            li 7.K -@I      t~   )
    . •        ~       it =T?       ~ ~ ~'fr.     (   B T M A H)        • •         ~    it       ~   T     j'fr.   ( T BAH )

    . Jlt          ~       •       • it     t~   .    :@(; • ¥i, it -=. ( 2- 1<] Z                        ~         )   ~ ~          (
    THEMAH)                         . -Z~'H~' 2- (2-1<]ZH~~) Z~' 2- (2-

    H~Z¥i,~) Z~"                                 N,N,N--=.         (2-1<]Z~)                      ~.           :W~~'H~'

    3-H~~-I-~~"                             2-H~~-I-rg~,·                 2- (N-~H~~) Z~' 2-

     (2-H~ZH~~) Z~'                                      -       (1<]~~)            H~~Z~'                          &1Bl~Z

    YR -@I     t~      0




               8 . PO          $   ~~   W frj ii'B    ~ ~ 1 Jj     Z ffi PIG    t~       ' Jt         ~ ~ pH:*: 15~ 6 ~

    *110       0




               9.   PO $           ~~   W frj ii8     ~ ~ 1 Jj      Z ffi PIG       t~       ' Jt tp           ~ ~      ITfi 15    '1:1
    m~M~.~tt·~.~tt·#.~tt·mtl:@(;~~mM


                                                                     - 22-
201122096




           1 0 . ~D     $ gN          :w frj i'B III m1 Jj Z *J3. fJt to/]                    ,   ~   rp   ~   *J3. fJt to/] 1*
    1£   mt¥ tt m1 :                  5 0 0 j;J ~ • -=r 71< mt¥                    0




           1 1. -      mm ~                   *    ~   II   ~     ift Z 15 1:t '        ~ ~       f15 T :>7U   &,~       :
           a.   m 1~         -       ~        ift '    ~ ~         ift   ~ ~ 8~        1f< 00     ~   -a -a ~       ~   m JJz.
                1~     - k fi'       m ift *4 JJz.          - ~      :g, fl ill.   n~   1£   ~    1f< 00 J: Z       ~£l ~u '


o



                                                             OH Rl            0
                                                              I               IH
                                                   O=P"-......-p=o
                                                        HO
                                                              I               I
                                                                              OH
o
                jt:    rp    R   1   JJz. R 2 1* if§! f§j ~ /f f§j ~ ~ § ill                      T :>7U pff *J3. ffX: Z lW
                *J3. :       ~        (       H)       , ~ ~       it    ~m   ( 0 H)          , ~      ( C 1)        , ~ ~

                1 ~ *t:J 8 00                 mR 1* -=r Z       ~Jt ~ ~       15 £ JJz. ;tJt      ~ ij3( ~     15   ~ ij3(




                      iii.   *f       Ir       ~   .,;. z - J$G :g, fl             ~ ~       • -=r 11H •       ~    tt it fI
                             ~o/]     .L-J g}iiJ   ~p p     H:* n~ 6 ~ *t:J 1 0 ;



                      v.     71<          0




                                                                         - 23-
201122096

             1 2 . ~D   $ ~% W- flj '8 ~ ~                 1 1 Jj    Z 15 1* '       jt   rp    ~Jt ~        =     ij~ ~3t

    t1   ~   =   ~   '1:1 it if 4m z           ~ 1:}   tt 1* 1tf. $c.J   1 :   1:¥ ¥3 1 0:           1   0




             1 3 . ~D   $ g% W- flj '8 ~ ~                 1 1 Jj    Z 15 1* '       jt   rp    ~    ;tjG    ~     =    ij~

    ~1*m1-f~Z~Jt-1,1-=ij~M' 52EfI~=ij~M' ~]52EfI~=

    ij~M'        =l52EfI~=ij~M'                            f~f.ia~52EfI~=ij~~3t'                                  1-f~

    ~ -3-ij~      rg tt     -1,1-= ij~           M'        1-~1 ~ -4-ij~        T tt      -1,1-= ij~               M~
    1El~zi~if4m                  0




             1 4 . ~D   $ ~% W- flj '8 ~ ~                 1 1 Jj    Z 15 1* '       jt   rp    ~ ~          =M '1:1
    ~if~~~~~~~mm~z~m                                                           +=tt~~~M'=

    EfI~uIM'                EfI~ul~'               ~a~EfI~3t,                  H~~~~3t,                  2-ij~~Z

    filM'        I'i.UJWM&~~~M                         0




             1 5 . ~D   $   ~%       W- flj '8    ~ ~ 1 4 Jj         Z 15 1* '       jt   rp    ~ ~          tl    ».   ~3t

    ~~~~~~mm~z~m:~M'~~·~.M·EfIM

    '~EM'rgM'~EfIM'm~ooM'oo~M'~*M'

    rg=M,~mM'liffl~M·TM'=I'i.ZM&~~Z~

    tr 4m    0




             1 6 . ~D $ ~%           W- flj f8    ~ ~ 1 1 Jj         Z 15 1* '       jt   rp    ~ ~          1mr   ~    1*
    ~~~~~mm~z~m:                                           •• ~~, •• ~~,~ ••
    ~1nf.~&1El~zi~tr4m                                 0




             1 7 . ~D   $   ~%       W- flj '8    ~ ~ 1 6 Jj         Z 15 1* '       jt   rp    ~ ~          1fr   ~    •
    •    ~~.~~~~~~~mm~z.tt~if~rpz:¥&­

    ~:~~~~.~'~~~lli~~·fi~~~;tjG~~(

    T M A H)         • ••              it    ~ ~Jt ~ ~i(    Ii 7}(   if 4m (        TMAH        Ii 7}(       if 4m )
    , • • it            T   ~    EfI   ~i(    ( B T M A H)          , ••       it   ~   T      ji(   ( T BAH )


                                                                - 24-
201122096

    , Ht          ~       i    ~        it      ~o/.)   ,   ~   i   ~   it -        (   2 - f~   Z £          )       EfJ ~         (

    THEMAH)                         ,    -       Z       ~¥H3(   , 2-     (2-f~      Z    ij3(~)        z      ~¥   '    2- (2-

    H~Z~~) Z~¥, N,N,N--                                                   (2-f~Z~)                 i'         ~~MH3('

    3-H~ ~ -1-~ ~¥                           '    2-ij3( ~ -1-~ ~¥          '    2- ( N-EfJ H~ £ )                  Z   ~¥       '   2-

     (2-Hg(ZHg(£)                                Z~¥''=' (f<lEfJ£)                        Hg(£Z;tJt,                Ez.1J5l~Z

    i~iJ~o/.)         0




             18.          tzo   $ ~N $. fU iB ~ mIl Jj Z }j                           its. '    ~ ~      1'f   pH    *   ~ 6 .¥


o   *s 10     0




             19 .         tzo   $ ~~ $. fU iB ~ m I l Jj                        Z 15 its. '        ~   r:p   ~ ~        1m   $       t1
    m~M~.~tt,~.~tt,#.~tt,mtt~~~~M

    '~~~Mz*~tt.m'*Mz~m*MM'~~~~

    ~~   z   7.1< 1~        t1 • m               0




             20.          tzo   $       ~N   $. fU iB ~          m I l Jj       z   15 its. '   ~      r:p 1£       *   ~    II      ~

    ~~~~OO~m~~~~m~~~~~~~1m~~~o




o




                                                                           - 25-
201122096

    1Z9 .. .t~ ~~*   III :
         (-)   *~.t~~~*1Il4: 1ft.
         (~)*~*IIl~~*~~~~~~:1ft.




o




o




                             -3-
201122096

    :E.. ..   *- $
              i(.:
                     ~   :t ~t •   i(.   * ' "*   4~ ;F   Jl ~ •   ;F   it   ~ ~   It ftJ   ~t   •


                                           OH Rl          OH
                                            I
                                     O=P----ll---P-=O
                                                          I
                                            I
                                          lIO
                                                          I
                                                          OIl
                                                  Rz




                                                       - 4-

Contenu connexe

Tendances

แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)
แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)
แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)kanidta vatanyoo
 
Aicraft (investigation of accidents and incidents) rules, 2012
Aicraft (investigation of accidents and incidents) rules, 2012Aicraft (investigation of accidents and incidents) rules, 2012
Aicraft (investigation of accidents and incidents) rules, 2012S P Singh
 
Csir net December 2012 mathematical science with with answer key
Csir net  December 2012 mathematical science with  with answer keyCsir net  December 2012 mathematical science with  with answer key
Csir net December 2012 mathematical science with with answer keyMD Kutubuddin Sardar
 
Blanche Rebecca Bingham Story
Blanche Rebecca Bingham StoryBlanche Rebecca Bingham Story
Blanche Rebecca Bingham StoryLarry Cragun
 
La tahzan or GHAM NA KARAIN by dr.ayez alqarni shared by meritehreer786@gmai...
La tahzan or GHAM NA KARAIN  by dr.ayez alqarni shared by meritehreer786@gmai...La tahzan or GHAM NA KARAIN  by dr.ayez alqarni shared by meritehreer786@gmai...
La tahzan or GHAM NA KARAIN by dr.ayez alqarni shared by meritehreer786@gmai...MyWritings
 
Washington state emission testing
Washington state emission testingWashington state emission testing
Washington state emission testingfueltec
 
Chana benni catalog changan auto parts chana star www.cinaautoparts.com
Chana benni catalog changan auto parts chana star www.cinaautoparts.comChana benni catalog changan auto parts chana star www.cinaautoparts.com
Chana benni catalog changan auto parts chana star www.cinaautoparts.comCina Autoparts
 
คู่มืองานอาสาสมัคร
คู่มืองานอาสาสมัครคู่มืองานอาสาสมัคร
คู่มืองานอาสาสมัครSathitpong Krajangrat
 
Rajasthan rte & private schools.guide lines
Rajasthan rte & private schools.guide linesRajasthan rte & private schools.guide lines
Rajasthan rte & private schools.guide linesJANGID_ML
 
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmis
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmisEpistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmis
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmiseretrianews
 

Tendances (18)

Semi tor
Semi torSemi tor
Semi tor
 
แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)
แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)
แนวปฏิบัติในการแจกคอมพิวเตอร์พกพา (แท็บเล็ต)
 
แท็บเล็ต
แท็บเล็ตแท็บเล็ต
แท็บเล็ต
 
Aicraft (investigation of accidents and incidents) rules, 2012
Aicraft (investigation of accidents and incidents) rules, 2012Aicraft (investigation of accidents and incidents) rules, 2012
Aicraft (investigation of accidents and incidents) rules, 2012
 
Csir net December 2012 mathematical science with with answer key
Csir net  December 2012 mathematical science with  with answer keyCsir net  December 2012 mathematical science with  with answer key
Csir net December 2012 mathematical science with with answer key
 
Blanche Rebecca Bingham Story
Blanche Rebecca Bingham StoryBlanche Rebecca Bingham Story
Blanche Rebecca Bingham Story
 
La tahzan or GHAM NA KARAIN by dr.ayez alqarni shared by meritehreer786@gmai...
La tahzan or GHAM NA KARAIN  by dr.ayez alqarni shared by meritehreer786@gmai...La tahzan or GHAM NA KARAIN  by dr.ayez alqarni shared by meritehreer786@gmai...
La tahzan or GHAM NA KARAIN by dr.ayez alqarni shared by meritehreer786@gmai...
 
Degaussser
DegaussserDegaussser
Degaussser
 
Sur f xwave
Sur f xwaveSur f xwave
Sur f xwave
 
Unidad 2..
Unidad 2..Unidad 2..
Unidad 2..
 
一个证券分析师的醒悟
一个证券分析师的醒悟一个证券分析师的醒悟
一个证券分析师的醒悟
 
Washington state emission testing
Washington state emission testingWashington state emission testing
Washington state emission testing
 
Chana benni catalog changan auto parts chana star www.cinaautoparts.com
Chana benni catalog changan auto parts chana star www.cinaautoparts.comChana benni catalog changan auto parts chana star www.cinaautoparts.com
Chana benni catalog changan auto parts chana star www.cinaautoparts.com
 
Cg Layout[1]
Cg Layout[1]Cg Layout[1]
Cg Layout[1]
 
คู่มืองานอาสาสมัคร
คู่มืองานอาสาสมัครคู่มืองานอาสาสมัคร
คู่มืองานอาสาสมัคร
 
Rajasthan rte & private schools.guide lines
Rajasthan rte & private schools.guide linesRajasthan rte & private schools.guide lines
Rajasthan rte & private schools.guide lines
 
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmis
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmisEpistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmis
Epistoli dimarxou eretrias gia ta dimosieumata tis euboikis gnwmis
 
Mech0110_5-6
Mech0110_5-6Mech0110_5-6
Mech0110_5-6
 

Similaire à Tw201122096 A

Cn101397301 a2
Cn101397301 a2Cn101397301 a2
Cn101397301 a2djsmith414
 
Gbt 5126 2001 (2)
Gbt 5126 2001 (2)Gbt 5126 2001 (2)
Gbt 5126 2001 (2)gagetman
 
King of the Campus
King of the CampusKing of the Campus
King of the Campustua92031
 
Chemistry Problem Set
Chemistry Problem SetChemistry Problem Set
Chemistry Problem Setjjlendaya
 
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...Bryon Kunz
 
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengali
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengaliবাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengali
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan BengaliTruth Within
 
Prc Analysis Searchable0001
Prc Analysis Searchable0001Prc Analysis Searchable0001
Prc Analysis Searchable0001guesta9fa9e6
 
YBM sach 2.pdf
YBM sach 2.pdfYBM sach 2.pdf
YBM sach 2.pdfMtconVtcon
 
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...Mohotasimur Anik
 
Notification msme
Notification msmeNotification msme
Notification msmemianagpur
 
綠建材
綠建材綠建材
綠建材pureway
 

Similaire à Tw201122096 A (20)

Cn101397301 a2
Cn101397301 a2Cn101397301 a2
Cn101397301 a2
 
Gbt 5126 2001 (2)
Gbt 5126 2001 (2)Gbt 5126 2001 (2)
Gbt 5126 2001 (2)
 
King of the Campus
King of the CampusKing of the Campus
King of the Campus
 
Patent V9
Patent V9Patent V9
Patent V9
 
Chemistry Problem Set
Chemistry Problem SetChemistry Problem Set
Chemistry Problem Set
 
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...
Residential Kitchen Remodel - Preliminary and Final Sketches per Client Inter...
 
Scan_Doc0004
Scan_Doc0004Scan_Doc0004
Scan_Doc0004
 
Degaussser
DegaussserDegaussser
Degaussser
 
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengali
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengaliবাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengali
বাঙ্গালী Dadaji Probach - Prothom Uchchas 1 Sankalokji parvachan Bengali
 
Prc Analysis Searchable0001
Prc Analysis Searchable0001Prc Analysis Searchable0001
Prc Analysis Searchable0001
 
YBM sach 2.pdf
YBM sach 2.pdfYBM sach 2.pdf
YBM sach 2.pdf
 
48900206[1]
48900206[1]48900206[1]
48900206[1]
 
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...
Solution Manual of Design of Concrete Structure, Aurther H. Nelson(13th Editi...
 
Fair shirt orders.
Fair shirt orders.Fair shirt orders.
Fair shirt orders.
 
Lunar rhythms
Lunar rhythmsLunar rhythms
Lunar rhythms
 
sslc
sslcsslc
sslc
 
Notification msme
Notification msmeNotification msme
Notification msme
 
綠建材
綠建材綠建材
綠建材
 
1. quiz
1. quiz1. quiz
1. quiz
 
15 มาตรฐาน
15 มาตรฐาน15 มาตรฐาน
15 มาตรฐาน
 

Tw201122096 A

  • 1. ;4 j , 00 (19) 'f. (12)~~{-'Jt~~~M]* ~ ml ~a ~J!~ A..NJ (ll)~MIMHt: TW20ll22096Al ....., ~?rFc~~a' ~ II l=f (43)~MIa: 'f" ~ iJ 100 (2011) .if- 07 A 01 a (21)'f"tt~~t : 099132618 (22) 'f"tt E3 : rf -f. ~ @I 99 (2010) ~ 09 A 27 E3 (51)Int. Cl. : CllD7/36 ~OO~O~ llOlL21/306 ~OO~O~ (30)11: 7t;fJ : 200911 0/24 ~ @I 61/254,669 (71) 'f "tt A. : *ffi ~ (~ @I) LEE, WAI MUN (US) ~@J (72)~aAA. : *ffi~ LEE, WAI MUN (US) (74 )1.1(.1£ A. : ~*- ,"t )Rij~ 'f"ttJfBt:~ : $.it, 'f"ttj}:;f~$[!IlJ~tt: 20 J~ Iii(.tt: 0 # 27 Ji (54)~~~ 5t5~ f- ttB£M mfA fJl)5~AbJ~1iit- COMPOSITION AND METHOD FOR CLEANING SEMICONDUCTOR SUBSTRATES (57H~* *~aAl~m~~~~~*~~~~~~.~&~~~fAk~~&1i*o#~~~'*~aAl ~-~£~f- ttB£~t ~~~4g~ ~fA1t.~i~~tM.7t1&.5t5~~~. 4bJfA fJl~4bJ&1iit- 0 -~£5t5~f- ttB £M ~1i it- ' Jt ~ %Wf t~ !ff £M ~ HP~ ' &;fo +..::. tt£ Jt,1;*@t ' ..::. If Jt,1;*@t ' If Jt,1;*@t ' ~;Ui£ If @t, mt£,1;*@t, 2-mt£L.-,1;*@t, ~fL,1;)lUt~:1fi~Jt@t5tt.%~jt,)J'-ifAtt£..::.~@tlLpHft.&~~~-t­ )~f~~"t%Jfrl ~ A.~ 6 .f-i:~ 10 ' &~ ~5';H1.1if'1PJT ~fA)Z-/~*$J , "t~tt£..::.~@t ~%~ ~ 1-,~ L.-tt-1,1- ..::.~@t ' §.If £..::.~@t ' '~§.If £..::.~@t ' ..::.jl§.1f £..::.~@t ' ,~li c.,£§.1f £..::.~@t ' 1-,~£-3­ mt~tt-1,1-..::.~@t ' 1-'~£-4-mtTtt-1,1-..::.~@tfAtt£..::.~@t 0 Rl OH O.H. 0 I "(1 I 0 -I> I 110 I 01-1 R2
  • 2. ;4 j , 00 (19) 'f. (12)~~{-'Jt~~~M]* ~ ml ~a ~J!~ A..NJ (ll)~MIMHt: TW20ll22096Al ....., ~?rFc~~a' ~ II l=f (43)~MIa: 'f" ~ iJ 100 (2011) .if- 07 A 01 a (21)'f"tt~~t : 099132618 (22) 'f"tt E3 : rf -f. ~ @I 99 (2010) ~ 09 A 27 E3 (51)Int. Cl. : CllD7/36 ~OO~O~ llOlL21/306 ~OO~O~ (30)11: 7t;fJ : 200911 0/24 ~ @I 61/254,669 (71) 'f "tt A. : *ffi ~ (~ @I) LEE, WAI MUN (US) ~@J (72)~aAA. : *ffi~ LEE, WAI MUN (US) (74 )1.1(.1£ A. : ~*- ,"t )Rij~ 'f"ttJfBt:~ : $.it, 'f"ttj}:;f~$[!IlJ~tt: 20 J~ Iii(.tt: 0 # 27 Ji (54)~~~ 5t5~ f- ttB£M mfA fJl)5~AbJ~1iit- COMPOSITION AND METHOD FOR CLEANING SEMICONDUCTOR SUBSTRATES (57H~* *~aAl~m~~~~~*~~~~~~.~&~~~fAk~~&1i*o#~~~'*~aAl ~-~£~f- ttB£~t ~~~4g~ ~fA1t.~i~~tM.7t1&.5t5~~~. 4bJfA fJl~4bJ&1iit- 0 -~£5t5~f- ttB £M ~1i it- ' Jt ~ %Wf t~ !ff £M ~ HP~ , &;fo +..::. tt£ Jt,1;*@t ' ..::. If Jt,1;*@t ' If Jt,1;*@t ' ~;Ui£ If @t, mt£,1;*@t, 2-mt£L.-,1;*@t, ~fL,1;)lUt~:1fi~Jt@t5tt.%~jt,)J'-ifAtt£..::.~@tlLpHft.&~~~-t­ )~f~~"t%Jfrl ~ A.~ 6 .f-i:~ 10 ' &~ ~5';H1.1if'1PJT ~fA)Z-/~*$J , "t~tt£..::.~@t ~%~ ~ 1-,~ L.-tt-1,1- ..::.~@t ' §.If £..::.~@t ' '~§.If £..::.~@t ' ..::.jl§.1f £..::.~@t ' ,~li c.,£§.1f £..::.~@t ' 1-,~£-3­ mt~tt-1,1-..::.~@t ' 1-'~£-4-mtTtt-1,1-..::.~@tfAtt£..::.~@t 0 Rl OH O.H. 0 I "(1 I 0 -I> I 110 I 01-1 R2
  • 3. 201122096 if§ ~ $ g~ ~ * $ g~ ~ ± ~ 2 0 0 9 if 1 0 Jj 24 B $ g~ Z ~ ~ ~ B'lf 111 "fJ. ffj $ g~ ~ 61/2546695J}t !¥; ff )t tl 0 [~EY3pJT~Z11VltT#j!~ ] *~EY3~~m~§~~~~m~oo~~~~~~*~ o ~ ~g ~ 00 i3t ~ * it ~ 91 fll ~o/.) !¥; *Jl J!fG ~o/.) Ez.. 11 1t. ' ;tt: -§, -2; - -a- ~m£=.M~~~z*m~,~~~~~~~~*~~ 91 fll ~o/.) s"J ~ ra~ 0 [ )t; JW 11 fiILT ] ~ ~ "fJ. ffj 6, 1 4 3 , 7 0 5 5J}t , 6, 3 1 0 , 0 1 9 5J}t , 6, 4 4 0 , 8 5 6 5J}t , 6,514,3525J}t' 6,514,9215J}t , 6,534,4585JJE ' 6,541,4345m ' 6,716,8035JJE' 7,250,3915JJE ' 7,312,1865JJE Ez.. 7,541,3225m j:-m -a-~ij~~~ 0 ~ ~ "fJ. ffj 6, 3 9 5 , 6 9 3 5JJE Ez.. 6, 5 4 1 , 4 345m f-m 7G - m 1£ * ?¥ ~~~~~~~~~*~m~~*?¥~~~~ooz~~~ !¥J~J!fG~Ez..1f$'~1f$-§,-a-~m~~mfl~mEz..~ •• r~~~Z~*?¥~~~~ooW-~-a-~£1£~2m£%~ ~ :P z m ~~ , *'~ O. 1 m £ % ~ ~ :P z -a- ij~ it ~ ~o/.) JJz. *'~ 2m £ % ~~:Pz~.M!¥;~~~~~o~m~~~~~~~~~ ~ *'~ 4-6Z pH 0 t5t f~:till ~ m ~ *Jl ~ ~o/.) ~ ~ *'~ 4.5-5.5!¥; pH 0 -5-
  • 4. 201122096 ( Jj ~p lOp P m ij~ M J-j 1 % f$ ~ ~~) 0 ij~ M ' flf JjU ~ 1 - f~ Z iJ'C - 1 , 1 - = ijm M ( - jlR ffi ~ HEDPA ) '~~~.~W~~~.ft~®m~~~m~B~~o B 3iS 7t J f§~ 'M HEDPA f* .L-~ ~ ;. /J fj~ 3 0 {51 ~-j B m; {51 71< * f~ m ~ , rij fF m~ • f!t! tJ:!] FtU ~U 0 m i@ 1 50 {51 ~-j B m; {51 71< B~ ~U 3iS JE 1& ; HEDPA~ it. ¥A 1'1 ~ fF 0 [ ~ EjJ pg ~ ] *~~~~m~m~~~~~MLm~~&n$o* mgM~-OO~~.~~~~m~m~,~~g~* *'5 ffiJ PO T z iJ'C ~ = ijm ~~ OH Rl OH I o=p-.....-P_O I I I HO R2 OH ~ tp R 1 ~ R 2 {* ttl [q[ gtz ~ [q[ :Mz m I§ EB T 3lU pJT *g ~ L ~$ *g : i ( H) , i ~ ft to/] ( 0 H) , l ( C 1) , ~:fF 1 ~ r,C; 8 00 mR 1* -6-
  • 5. 201122096 TZ~~~H~R~~~~H~~o~~m~~~~~= Mtt~~~·.~.;Z-~~m~ • • TB • • tt~~ ~m tJ ~JWJ ~1J p H:* n~ 6:¥ *Cj 10 • ~ ~ till fft 0 m ; % R B ~ :¥ 5 m ; % Z ~ 00 m tl:;1!fu • R 'U ~ ;. ~ 7]< 0 m~~zm~~mR~~~=.Mtim=Mtt~ft~ Z ~ 1} tt ~ *Cj 1 : 1:¥ *Cj 10: 1 0 ~{*ziJE~=n~M{*~l-f~Z~-l,l-=n~M' 5:2Ef3~ o =n~M' f~5:2Ef3~=n~M' =lt5:2Ef3~=n~M' f<1f.1a~ 5:2 Ef3 ~ = n~ M. 1-f~ ~ -3-n~ ~ i7t -1,1-= n~ M. 1-f~ ~ -4- n~Ti7t-1,1-=n~~~· JJ<.fEt~ZrMfttm 0 ~m~~~~m=Mzm~~,.~z,~m=Mm ~+=m~~~M'=Ef3~~M'Ef3~~M'~§~Ef3M . n~~~M' 2-n~~Z~M' .iiJW~~~~~~M 0 ~*fI.~ tmmm~-2r~f~~M 0 ~m~~-2r~~.~Mzm~~'~Mm~~M·~ o M'~~M'Ef3M'~EM'~M'~Ef3M'm~OOM' M~M·~*M·~=M·~mM·EffiTM·TM·= #i, Z MJJ<. fEt ~ z rM ft tm 0 ~~mmM~~,~~m~~mm~-2r.~.tt~ft ~'~~~.~~·~.~~JJ<.~ ~~~~-2r~-~ft~~~~~~ft~o •• TB • • o~~m ~ • • TB • • tt~~~~~ft~~~~Tmm~~ .tt~~~~Z:¥~-~:~~~B •• ~~~~m~~ . ~ ~ 1t [g iJE ~ j1i: ( T M A H) • ~ ~ 1t [g iiC ~ j1i: E 7]< ft tm -7-
  • 6. 201122096 ( TM A H 1i 71< -2t 1o/J) , f, ~ 1t =f [9 EJ3 £ti: ( B T M A H) , f, ~ 1t [9 T ~ti: ( TBAH) , • ~ f, ~ 1t ~m ' ~ f, ~ 1t -= ( 2- 1~ Z ~) EJ3 ~ti: (THEMAH) , - Z ~~~~ , 2- (2-1~ Z ~~~) Z~~, 2- (2-~~Z~~) Z~~, N,N,N-- (2-f<]Z~) i , ~ P3 ~~ ~~ , 3-~~ ~ -1-P3 ~~ , 2-~~ ~ -1-P3 ~~ , 2- (N-EJ3 ij~ ~) Z~~' 2- (2-~~Zij~~) Z~''=: (f<]EJ3~) ij~~Z ~'~1Bt~Z¥~-2t~o/) 0 ~ {* Z pHi'B rm {* 1)£ *- n~ 6¥ k0 10 0 ~oomttM*~m~*~m~mzm~1o/J$o~~Z ~ Im m '1'1 ~rr 19 115 ~F • -T'lt ' ~. -T'lt ' ~. -T'lt ' Ez. I 9X, mtt'M~m.9X,~*mtt • • '~*MZM~*.M9X, ~71<~~'lt.~1Ez.~.{~~ 0 ~¥®.m$,.ooz,~~m~1o/J~~m.tta~ ¥1: 10, a~¥l 50, a~¥l: 100, a~¥l: 150, a ~ ¥ 1 : 2 50 ' Ez. a ~ ¥ 1 : 500 9X, * ~ $ Z {3: {P] tt -WU r 1--) D I 71< #Ii f~ 0 H ED PAW ~ Im m 'It ~rr *J3. -2t ~ £ ~ tJ% r§J ~~ * 0 ~ Im m '[t ~rr /f im fF m ~ 7t tfj( ~rr ' 'M HEDPA1--) m W! 150{5} t1 Ef ~ {51 71< !¥J ¥. N it m B~ * ~ :ijt ~ H ED PAZ J~ Wi ~o/] ~~ fg~ lIt ~g 0 -g~m*~m~zm~1o/J!¥J~$,~1g~~m-~ ft ' ~ ~ ;ft ~ ~ !¥J ~ Im 19 ~ ~ ill ~ e Ez. {~ -k if ~ ~o/) Jf Ez. - 9X,~g~~~~Im~zrnM,~~gWi1o/J'~Im~gWi1o/J 'Ez.~~~,~~;ft~§*AA~~*AA~~W!~$£ ~ ; M~ ~ ~ ft ~ 00 W ~ fJ!J. ;. Z ~ ~ ~ * *5 f~ PO r Z ~7t ~ = ~tlf • !¥J m ~& tft fI] : - 8-
  • 7. 201122096 Rl yH yH O=r'---"'~r=O HO OH Rz Jt 9=J R 1 EZ. R 2 1* if§ ~ ~ ~ ~ illz ~ § ill T JU pJT *Ji glG z M *Ji : ~ ( H) , ii. ¥i. 1t ~o/) ( 0 H) , l ( C 1) , ~ ~ 1 ¥ $CJ 8 @J ~ !* o 'EZ.~.~~*o~mglG~~~~~~~mm,gw~EZ. /~¥i.~~z~~W~~TW£ff~~om~~nmz~ :ti ~ ffif Fa~ 1* 1£ *9 1 0 fj; W *9 3 0 5t it Z Fa' 0 :$: 3t pJT ~ z *Ji glG ~o/) ~~*~R~~~~M~m~m~~~~~~~*z~® ~*.~®~m~~~'~EZ.m~~m~.~B~zJt~ o :$:~~~~-~~~zm~m~,~m~~mm¥= ij~ ~ Wm = ~~ '1:1 1t -EI ~o/) ~ ~ ~ tt *9 1 1¥ *9 10 : 1 T i§ 1J~ 71<. ~ ~ -EI ~o/) 0 ifG£=ij~~Z£:$:*5mtzDT -9-
  • 8. 201122096 Rl OIl OB I O=p'--+--p=O I I I10 I OIl ~ $ R I Et.. R 2 1* if§ ~ :@G ~ ~ :Mz ~ § EE ~ JU pJT *Ji m ~ M *Ji : ~ ( H) , ~ ~ 1t to/.) ( 0 H) ,jA ( C 1) , ~ fj 1 ~ *Cj 8 1iI ~ 1* -T ~ i3t ~ :@G :5 ~ Et.. ;tfG ~ g~ :@G :5 ~ g~ 0 ;tfG ~ =- g~ ~ ~ Jf -WU ~D ~ JU : - 10 -
  • 9. 201122096 ~m RI R2 tf:im l-~z.m-l,l-=JmM OH CH3 yH OH OH 52Efl~=JmM H H =r+t=° OH eH 3 0lI OH H OH o=t+t=o (MDP) HO H OH ~52Efl~=JmM (HMDP) OH H O~OH o O=! !=O 1 HO H 1 OR =l52Efl~=JmM(ChMDP) Cl Cl OIl Cl Oll o=t+t=o HO CI OH ~tiB~52EJ3~-JmM OH Oll Oll OIl (HCMDP) 0 O-P -I I HO 1 1'=0 1 on o - 11 -
  • 10. 201122096 1-~~-3-H3t~m-l,1--~M OH -CH2CH2NH2 O=!+!=O (APD) OH OH OH H! HC iH 2 I H2 H 2N I 1-~£-4-MCTm-l,1--~M OH -CH2 CH2 CH2NH2 OH OH OH =t+t=° HO H CH Z1 2 OH H 2C I I NH 2 - 12 -
  • 11. 201122096 p H:* 1i~ 6 ¥ *,q 10 ' ffiJ ~ Jf9 ~ '[1: it 1% ~o/.] ~ ii. ~ it jlfl , Ii. ¥, it ~&~T~Z.~I%~mm~z~ •• ~m •• ~I%~: ~ ¥, i t . ' ~ ~ it [9 in ~. ( T M A H) , ~ ¥, it [9 in ~ ~1i: 1i 7.K 1% ~o/.] ( T M A H 1i 7.K 1% ~o/.]) , ~ ¥, it T [9 Ej3 ~1i: ( BTMAH ) , T BAH ' ~. ~ ~ it ~o/.] , WG ~ ~ it ~ ( 2 - 1<4 Z ~) Ej3 • ( THE M A H) , 1~ ~ Hti: ~tfj /fIt. ' 1~ ~ Hti: 11J !t to/.] ~D N , N - = z~~~,~~~mffi'~~~~~z{B~~~M'Z= o Hti:, -Z~~H~' N,N-=ZH~~Z~' 2- (2-1~ZH~~) Z ~~, 2- (2-H~Z~~) Z~~, N,N,N-.= (2-1<4Z~) ~, oW rg ~~ H~ ' 3-Hti: ~ -1-rg M ' , 2-H~ ~ -1-rg M ' 2- ( N-Ej3 H~ ~) Z~~, 2- (2-H~~ZHtt~) Z~~, - (1~Ej3~) Htt~ Z~, WG1m:~Z1EBI%~o/.] 0 • '11: *i 1iI ~U Z I)( £ PI ~ l& ~ ~ *,q 25m £ % 0 ~{~ZpH{*1t£*1i~6~*q 10 0 o • 1ifi ~J ':I.' 1iffi -Wu 1 T~~~mm~~.1iffi~~~~I%~Z~E~o - 13 -
  • 12. 201122096 *Jirrx 1t~lm ~1j: ~1j: ~tf1f ~tf1f m£ m£ lm m£ ~ ~1j: i}::£ % tt~ I-f<1Z3Jt=g~M 206 6 0.69 142.1 14.21 3.79 +=m~$:ii~M 326.5 1 0.115 37.55 3.75 1 25% TMAH71<~tf~ ~JWj~1J~pH 6 71< *U~£ *~..§. r~c,.m 1000 I-f<1Zm=gmM 206 6 0.69 142.1 14.21 9.96 ~l§~Ef3~ 128 1 0.115 14.72 1.47 2 25% TMAH71<~tf~ ~JWj~1J:¥pH 6 71< *U~;. *~..§. rvc,.m 1000 I-f<1Zm=gmM 206 6 0.69 142.1 14.21 13.73 1f!!~ 90 1 0.115 10.35 1.04 65% ~ ~ 1t.=. (2- f~ Z ~ ) Ef3 ~ 3 ~~1J~pH 9 (THEMAH) 71< *U~;. *~..§. 'jc.,~ 1000 1-~ZiJt=gmM 206 6 0.69 142.1 14.21 12.74 g~~ii~~ 97 1 0.115 11.16 1.12 4 45%JJt~~~1tlo/)m~ ~JWj~1J:¥pH 9 71< *U~;. *~..§. !'/C'13!. 1000 I-f~Z3Jt=gm~ 206 6 0.69 142.1 14.21 16.26 f~£Z~~ 76 1 0.115 8.74 0.87 N,N-=Zf~~g~/- Z~¥g~ 5 ~)WJ~1J~pH 7 (1:1m;.tt) 71< *U~£ ~..§. f,/C,1I! 1000 6 I-f<1Zm=gmM 206 6 0.69 142.1 14.21 14.08 li3iJ1lJ~ 87.8 1 0.115 10.1 1.01 Z=g~ ~JWj~1J:¥pH 10 71< *U~;. - 14-
  • 13. 201122096 *~E3.. '~C,.m 1000 1-f<1Z33t=fl~~ 206 6 0.69 142.1 14.21 85.24 2-n*~Z~~~ 14.5 1 0.115 1.688 0.17 7 25% TMAH7](~~1& ~JW1i1J¥pH 7 7]( *U~£ *~E3.. IVC'.m 1000 1-f<1Z~3t=n~~ 206 3 0.3 61.8 6.18 2.92 f~2 Ef3~=n~~~ 192 3 0.3 33.6 3.36 +=i5C~~Ui~ 326.5 1 0.1 32.65 3.27 8 N,N-=Zn*Zr!¥ IDWli1J¥pH 7 7]( *U~£ o ~E3.. I>C'.m 1000 1-f~~-3-n3rpgm-1,1-=n~~ 235 6 1.2 282 28.2 18.55 f~~Z~ 76 1 0.2 15.2 1.52 9 -=-(f~ Ef3 ~)fl*~Zm ~JW1i1J¥pH 9 7]( *U~£ *~E3.. fVC"l3! 1000 2Ef3~=n~~ 176 6 0.69 121.4 12.10 8.64 2-n*~Z~~ 125 1 0.115 14.4 1.40 10 28%i~1ttt~~1& ~i1J¥pH 7 7]( *U~£ *~E3.. 1000 o /VD".m 1-f~Zm=n~~ 206 6 0.69 142.1 14.21 6.44 f$~~~ 192 1 0.115 22.08 2.21 65%i~1t - (2-f~Z~) 11 ~i1J¥pH 9 Ej3~(THEMAH) 7]( *U~£ *~E3.. "Jc",lt!. 1000 f~2Ef3~=n~~ 192 6 0.69 67.2 6.72 2.06 + =~3t~~Ui~~ 326.5 1 0.1 32.65 3.27 12 25% TMAH7](~~1& ~JW1i1J¥pH 10 7]( *U~£ *~E3.. I'JC,1I! 1000 13 1-f~Z~3t=n~~~ 206 6 0.69 142.1 14.21 16.26 f~~Z~~ 76 1 0.115 8.74 0.87 - 15 -
  • 14. 201122096 1O%i~1t~7j(7§~j( ~WJ~fj~pH 7 7j( 'U~.m *IZI-E!. f'JC'£ 1000 1-1~Z:3n=H~~ 206 10 1.15 236.9 23.69 21.24 H3(~iii~~ 97 1 0.115 11.16 1.12 14 10%i~1t~7j(7§~ ~WJ~fj~pH 7 7j( 'U~.m *IZI-E!. "c.,.m 1000 I-f~Z~=H~~ 206 3 0.345 71.07 7.11 8.13 f~~Z~ 76 1 0.115 8.74 0.87 15 10%i~1t~7j(m~ ~~fj~pH 7 7j( 'U~.m ~-E!. f'JC'..m.. 1000 I-f~Zm=ij~~ 206 3 0.345 71.07 7.11 7.04 lUiJJH~ 87.8 1 0.115 10.1 1.01 16 10%i~1t~7j(7§~j( ~}jiJ~fj:¥pH 10 7j( 'U~.m. *IZI-E!. rvc.,.m 1000 I-f<1Zin=ij~~ 206 1 0.115 23.69 2.37 14.21 2-ij3(~ZiiiM 14.5 1 0.115 1.67 0.17 17 25% TMAH7j(7§~ ~~fj:¥pH 7 7j( 'U~.m. ~-E!. I'JC'.JI!. 1000 I-f<1Z;tn=ij~~ 206 4 0.4 82.4 8.24 3.9 f~~Ej3~=ij~~ 112 4 0.4 44.8 4.48 +=~~~iii~ 326.5 1 0.1 32.65 3.27 18 65%i~1t - (2-f~Z~) ~}jiJ~fj~pH 9 Ej3 j1(THEMAH) 7j( 'U~~ *IZI-E!. f'JC,lI! 1000 1-1~Z~=H~M 206 8 0.92 189.5 18.95 12.88 ~.~Ej3~~ 128 1 0.115 14.72 1.47 19 25% TMAH7j(7§~ ~WJ~fj~pH 7 7j( 'U~.m ~.§.. f'JC'.JI! 1000 - 16 -
  • 15. 201122096 I-f<1ZJlt=ij~~~ 206 8 0.92 189.5 18.95 18.31 ~~~ 90 1 0.115 10.35 1.04 65%i~it =: (24~Z~) 20 ~JWJ~1f¥pH 9 Ef3~(THEMAH) 71< 'U~; *~.§. rvc,13! 1000 f~:s:2 Ef3 ~=ij~~ 192 1 0.1 11.2 1.12 0.34 +=~lt~~Ui~ 326.5 1 0.1 32.65 3.27 65%i~it.=.(2-f<1Z~) 21 ~JWJ~p~pH 10 Ef3~(THEMAH) 71< 'U~£ o *~.§. f'J(j"l3:!. 1000 ~.~~~~~*B~zm~m~~$~~=.M~ m=MttmffiZ~~~'~.~~~~OO~Z.M.~g Wlto/.]R~ •• -TJ~Wlto/.)8"1m~t1 0 o • ~ ~U 2 ,DJ 5 {51 *Jl ~ to/.] 9 m ~ 1 00 {51 D I 71< ( 1 : 2071< m f¥ ) flft m fX = ij~ MR O. 1 2 2 % f~ ~ Z ~~ 0 ~ ill 1t- *1£ :t~ 6 : 1 ~ ~ tt 8"1 ~lt ~ - 17 -
  • 16. 201122096 =.~~m=~tt~~~oM~~m~~~~~.mffi~ 8~ *~ * 0 • :fjf!! -WU 3 .L-~ 1 {51 *J3. ~ to/.] 5 ~~ ~ 1 0 0 {51 D I 7.K ( 1 : 100 7.K m f¥ ) TIft m fl~:lV,~ 0 ~~~~~~jili~~0.141% 1-f~Z~5G=ij~~Ez. o. 0 0 9 % f~ ~ Z ~~ 0 ;It ill ~ *t t:;f 6: 1 ~ 1} tt ~ ~ ~ = ij~ ~ f1 m=~tt~~~oM~~m~~~~~.mffi~®~*o • :M!! {§U 4 .L-~ 1 {51 *J3. ~ to/.] 1 5 ~~ fj~ 1 0 0 {51 D I 7.K ( 1 : 1 0 0 7.K mt¥ ) TIft m fl ~:lV,~ 0 lIt m~ ~~:)( jili ~ ~ 0.0711% 1-f<] Z ~5G = ij~ ~ Ez. o. 0 0 9 % f~ ~ Z ~~ 0 ;It ill ~ *t t:;f 3 : 1 ~ 1} tt B~ ~ ~ = ij~ ~~ f1 m=~tt~~~oM~~m~~~~~.mffi~~~*o • :fjf!! {§U 5 tJ 5 {51 *J3. ~ to/.] 14m ~ 1 00 {51 D I 7.K ( 1 : 20 7.K mt¥ ) TIft m fl ~ :lV,~ 0 lIt ~~ ~ ~ fJlj. jili ~ ~ 1.185% 1-f~ Z ~ = ij~ ~ Ez. o. 0 5 6 % ij~ ~ E~ ~~ 0 ;It ill ~ *t t:;f 1 0 : 1 ~ 1} tt B~ ~5G ~ = ij~ ~ ~m=~tt~~~o.~~m~~~~~.mffi~®~* - 18 -
  • 17. 201122096 J7JGfB jiJjQ~~/j££~ fjtff!jiJj Wt(051) % I-f~ZJJt=g~~~ DEQUEST 2010 Thennphos 580 13.0% CAS#2809-21-4 r~~z:.~ (70%) Glycolic Acid Dupont 60 1.3% r~~g3(~m~fM (50%) SanFu 600 13.4% - z:.~~H3( (85%) TEA85 Dow 470 10.5% 7j( 2760 61.7% 4470 100.0% o J7JGfB jiJj£~/j££~ fjtff!f,Jj Wt(051) % 1-~z:.~=~~ DEQUEST 2010 Thennphos 530 11.2% CAS#2809-21-4 ~~n~7j(Zg3(~ =: (~Ef3~g~ DEQUEST 2000 Thennphos 90 1.9% ~~) CAS#6419-19-8 N,N-=z:.r~~g3( 85% Arkema 310 6.6% CAS#3710-84-7 o -z:.~~g3( MEA Dow 310 6.6% 7j( 3480 73.7% 4720 100% ::$: -x. r:p Jt II • 1ifli -wU B"J *J3. J7JG ~o/] /F ffl ~ ~ ( r e que s t) J3. ii ~f=EfE1Jm~B"JJE~~/F¥A1:r~ 0 - 19 -
  • 18. 201122096 ~m~=~~ft~&~*~~~(~~ffifiB~ffi* ~f;.f:1) PJfFffl~m~~tl 0 ft~-~ •• ~oo~,~m~~~~PJm~~m~m ~ 40/1 Z m~ tl: ~~ 8~ ~ ITll ~5 t1 ~tl ffij if 1J~ JJ! 1;) ~ m~ = g~ ~ Z *fi gIG to/.J 0 .~~'~~~ITllmttmw.~~m~u.~~.~ ~~~~m.~m~m~~Zm~~ho~~m~~z~ ITllmttm~~mo~~~~ffl~ffifi~~Z~ITllmttm~ tl5 ~ iii T 111: ' ~ iii T 1[1: ' ;}F iii T 1[1: ' m 1[1: ' !YZ ~ ~ m~ , ~~m.z*~tt •• ,*mZ~~*~M,!YZ~~m~ Z 7.1<. ~~ 1[1: • • 0 B~m®A •• ~OOB.~~mM~~.'~.&. ~OO~~~~'~.~.~~*B~~~~m~m®~~ ~§~ffi~~Z~.W*.~~~m~o~~~~.~ffi ~.~,m®~E.fl~~~ •• m~~~ft~o*W~ ~~.&.~oo~~~~m~OOtt'~*B~Z~~~~ &ffl~~~T~Z$mW~~~ffi~~oW~$m~ffig Z pJT ~ • ~ ~!IX ' W ffj , W ffj $ ~~ ~ ~ ~ gB ~ ?G #~ iff A * ~~1;tt.~ 0 - 20 -
  • 19. 201122096 862638 ~t BA l- *1 ~! BA .- (;zfs:$~*:Ji~rt ' 11Im ' ~o/J{£~~ , *§~B7:1'~*~) * tJl 1t$~ : 099132618 C- [/ /) "1-1b (2006.01) *tJl1t8 : 099~09)127EJ *IPC~. : rt:>fL L ~b (2006.01) - , it B,ij ~.: (4':>c./ ~ :>c. ) m~*~~~tt m8~*J3.frlG~O/]W 151* Composition and method for cleaning semiconductor substrates o *~~~~m~§~~~ft~~OO~~~~~&~~ ~~mfrlG~&h$o~k~Z'*~~~~-m~*~~ ~ttzm~~~OO~~~~~~*~m~~~~~mm~ &l5$o-mm~*~~~ttzl5$,~~~~~~~tt W~*'&W+=~~~~M'=~~~M'~~~M' ~e~~M' H3Z~~~~' 2-H3Z~Z~wM' ~i1iJWM~~~ o - 1-
  • 20. 201122096 The compositions and methods herein relate to the method for the removal of residues and contaminants from metal or dielectric surfaces. Particularly, a composition and method of cleaning residues after chemical mechanical polishing of a copper or aluminum surface of the semiconductor substrates. A method of cleaning semiconductor substrates comprising contacting the substrates with a solution of water, and sufficient amount of alkyl diphosphonic acid comprising alkyl diphosphonic acid selected from the group of 1 hydroxyethane 1,1 diphosphonic acid, methylene diphosphonic acid, hydroxymethylene diphosphonic acid, dichloromethylene diphosphonic acid, hydroxycyclohexylmethylene diphosphonic acid, 1- hydroxy-3-aminopropane 1,1 diphosphonic acid, l-hydroxy-4-aminobutane 1,1 diphosphonic acid mixed with dodecylbenzenesulfonic acid, xylenesulfonic acid, toluenesulfonic acid, phosphonoformic acid, sulfamic acid, 2-amino ethane sulfonic acid, or fluoroboric acid or an organic carboxylic acid and pH is adjusted to from greater than 6 to about 10 with a metal ion free base, and a surfactant. -2-
  • 21. 201122096 OH Rl OH I O=p-+--p=O I I 110 I OIl ~ rp R Ez.. R 2 1* t§ [Q] :@G /f [Q] 1ft ~ EJ ill T 7U ptf *43. nJG Z tt~ o *43. : W. ( 1 H) , W. $i, 1t lo/.j ( 0 H) 'j ( C 1) 'Jt ~ 1~ *c; 8@ ~ Jw: T Z ;tJt ~ :@G 7!i ~ Ez.. 1ft ~ Htz :@G 7!i ~ Htz e. 71< 0 o 2 . ~D $ ~N J!J. fU i'B ~ rg 1 Jj Z *43. nJG ~o/.j , ~ rp 1ft ~ = Hl ~ tl rg = ~~ I[j: 1t it ~o/.j Z ~ If tt 1* 1:£ *c; 1 : 1 ¥ ~ 1 0: 1 0 3 . ~D $ ~N J!J. fU i'B ~ ~ 1 Jj Z *43. nJG lo/.j , ~ rp ~ 1ft !k = ij~ ~~1*~I-f~Z1ft-l,I-=ij~~~, ~Et'~=g~~~, f~~Et'~= ij~~~' =j~Et'~=ij~~~' f~$a~~Et'~=gl~~' 1-1<1 ~ -3-Htz ~ 1ft -1,1-= Hl ~~ , 1-1<1 ~ -4-Htz T 1ft -1,1-= ij~ ~:@G ,Et'~~~~, ~e~Et'~~, Htz~£i~~' 2-Htz~Z~~~' ~ - 21 -
  • 22. 201122096 tiJ1IJ~~&~~1~~~ 0 5. tm $ ~~ W frj ii'B ~ ~ 4 Jj Z ffi PIG ~~ ' Jt tp ~ ~ f~ ~ ~~ ~~~~~~ffim~z~m:~M·~M·~.M·~M '~EM'~M'~~M'm~ooM'oo~M'~*M' ~=M·~mM·liffl~M·TM·-.ZM&~~zm -@I ~~ 0 6. PO $ ~~ W frj ii'B ~ ~ 1 Jj Z ffi PIG ~~ ' Jt tp ~ ~ fir ~ 1* ~~~~~ffimPIGz~m:._~~·._~~·~ •• ~~m.~&1Bl~ZYR-@lt~ 0 7 . PO $ ~~ W flJ ii'B ~ ~ 6 Jj z *J3. fflG t~ ' ;1t tp ~ ~ 1Ir ~ ~ .~~.~~~~~T~ffimPIGz.tt~-@I~tpz~~­ ~:~~~~.~·~~~m~~· •• ~~~~~( T M A H) • •• it ~ ~ ~ ~ li 7.K -@I ~~ ( TMAH li 7.K -@I t~ ) . • ~ it =T? ~ ~ ~'fr. ( B T M A H) • • ~ it ~ T j'fr. ( T BAH ) . Jlt ~ • • it t~ . :@(; • ¥i, it -=. ( 2- 1<] Z ~ ) ~ ~ ( THEMAH) . -Z~'H~' 2- (2-1<]ZH~~) Z~' 2- (2- H~Z¥i,~) Z~" N,N,N--=. (2-1<]Z~) ~. :W~~'H~' 3-H~~-I-~~" 2-H~~-I-rg~,· 2- (N-~H~~) Z~' 2- (2-H~ZH~~) Z~' - (1<]~~) H~~Z~' &1Bl~Z YR -@I t~ 0 8 . PO $ ~~ W frj ii'B ~ ~ 1 Jj Z ffi PIG t~ ' Jt ~ ~ pH:*: 15~ 6 ~ *110 0 9. PO $ ~~ W frj ii8 ~ ~ 1 Jj Z ffi PIG t~ ' Jt tp ~ ~ ITfi 15 '1:1 m~M~.~tt·~.~tt·#.~tt·mtl:@(;~~mM - 22-
  • 23. 201122096 1 0 . ~D $ gN :w frj i'B III m1 Jj Z *J3. fJt to/] , ~ rp ~ *J3. fJt to/] 1* 1£ mt¥ tt m1 : 5 0 0 j;J ~ • -=r 71< mt¥ 0 1 1. - mm ~ * ~ II ~ ift Z 15 1:t ' ~ ~ f15 T :>7U &,~ : a. m 1~ - ~ ift ' ~ ~ ift ~ ~ 8~ 1f< 00 ~ -a -a ~ ~ m JJz. 1~ - k fi' m ift *4 JJz. - ~ :g, fl ill. n~ 1£ ~ 1f< 00 J: Z ~£l ~u ' o OH Rl 0 I IH O=P"-......-p=o HO I I OH o jt: rp R 1 JJz. R 2 1* if§! f§j ~ /f f§j ~ ~ § ill T :>7U pff *J3. ffX: Z lW *J3. : ~ ( H) , ~ ~ it ~m ( 0 H) , ~ ( C 1) , ~ ~ 1 ~ *t:J 8 00 mR 1* -=r Z ~Jt ~ ~ 15 £ JJz. ;tJt ~ ij3( ~ 15 ~ ij3( iii. *f Ir ~ .,;. z - J$G :g, fl ~ ~ • -=r 11H • ~ tt it fI ~o/] .L-J g}iiJ ~p p H:* n~ 6 ~ *t:J 1 0 ; v. 71< 0 - 23-
  • 24. 201122096 1 2 . ~D $ ~% W- flj '8 ~ ~ 1 1 Jj Z 15 1* ' jt rp ~Jt ~ = ij~ ~3t t1 ~ = ~ '1:1 it if 4m z ~ 1:} tt 1* 1tf. $c.J 1 : 1:¥ ¥3 1 0: 1 0 1 3 . ~D $ g% W- flj '8 ~ ~ 1 1 Jj Z 15 1* ' jt rp ~ ;tjG ~ = ij~ ~1*m1-f~Z~Jt-1,1-=ij~M' 52EfI~=ij~M' ~]52EfI~= ij~M' =l52EfI~=ij~M' f~f.ia~52EfI~=ij~~3t' 1-f~ ~ -3-ij~ rg tt -1,1-= ij~ M' 1-~1 ~ -4-ij~ T tt -1,1-= ij~ M~ 1El~zi~if4m 0 1 4 . ~D $ ~% W- flj '8 ~ ~ 1 1 Jj Z 15 1* ' jt rp ~ ~ =M '1:1 ~if~~~~~~~mm~z~m +=tt~~~M'= EfI~uIM' EfI~ul~' ~a~EfI~3t, H~~~~3t, 2-ij~~Z filM' I'i.UJWM&~~~M 0 1 5 . ~D $ ~% W- flj '8 ~ ~ 1 4 Jj Z 15 1* ' jt rp ~ ~ tl ». ~3t ~~~~~~mm~z~m:~M'~~·~.M·EfIM '~EM'rgM'~EfIM'm~ooM'oo~M'~*M' rg=M,~mM'liffl~M·TM'=I'i.ZM&~~Z~ tr 4m 0 1 6 . ~D $ ~% W- flj f8 ~ ~ 1 1 Jj Z 15 1* ' jt rp ~ ~ 1mr ~ 1* ~~~~~mm~z~m: •• ~~, •• ~~,~ •• ~1nf.~&1El~zi~tr4m 0 1 7 . ~D $ ~% W- flj '8 ~ ~ 1 6 Jj Z 15 1* ' jt rp ~ ~ 1fr ~ • • ~~.~~~~~~~mm~z.tt~if~rpz:¥&­ ~:~~~~.~'~~~lli~~·fi~~~;tjG~~( T M A H) • •• it ~ ~Jt ~ ~i( Ii 7}( if 4m ( TMAH Ii 7}( if 4m ) , • • it T ~ EfI ~i( ( B T M A H) , •• it ~ T ji( ( T BAH ) - 24-
  • 25. 201122096 , Ht ~ i ~ it ~o/.) , ~ i ~ it - ( 2 - f~ Z £ ) EfJ ~ ( THEMAH) , - Z ~¥H3( , 2- (2-f~ Z ij3(~) z ~¥ ' 2- (2- H~Z~~) Z~¥, N,N,N-- (2-f~Z~) i' ~~MH3(' 3-H~ ~ -1-~ ~¥ ' 2-ij3( ~ -1-~ ~¥ ' 2- ( N-EfJ H~ £ ) Z ~¥ ' 2- (2-Hg(ZHg(£) Z~¥''=' (f<lEfJ£) Hg(£Z;tJt, Ez.1J5l~Z i~iJ~o/.) 0 18. tzo $ ~N $. fU iB ~ mIl Jj Z }j its. ' ~ ~ 1'f pH * ~ 6 .¥ o *s 10 0 19 . tzo $ ~~ $. fU iB ~ m I l Jj Z 15 its. ' ~ r:p ~ ~ 1m $ t1 m~M~.~tt,~.~tt,#.~tt,mtt~~~~M '~~~Mz*~tt.m'*Mz~m*MM'~~~~ ~~ z 7.1< 1~ t1 • m 0 20. tzo $ ~N $. fU iB ~ m I l Jj z 15 its. ' ~ r:p 1£ * ~ II ~ ~~~~OO~m~~~~m~~~~~~~1m~~~o o - 25-
  • 26. 201122096 1Z9 .. .t~ ~~* III : (-) *~.t~~~*1Il4: 1ft. (~)*~*IIl~~*~~~~~~:1ft. o o -3-
  • 27. 201122096 :E.. .. *- $ i(.: ~ :t ~t • i(. * ' "* 4~ ;F Jl ~ • ;F it ~ ~ It ftJ ~t • OH Rl OH I O=P----ll---P-=O I I lIO I OIl Rz - 4-