TOPICS COVERED: ASOLUTE AND RELATIVE HUMIDITY MOISTURE REGAIN AND CONTENT Regain-Humidity Relations of Textiles Regain VS Relative Humidity Curve Factors Affecting the Regain of Textile Materials Effect of moisture on properties
2. TOPIC
ASOLUTE AND RELATIVE HUMIDITY
MOISTURE REGAIN AND CONTENT
Regain-Humidity Relations of Textiles
Regain VS Relative Humidity Curve
Factors Affecting the Regain of Textile
Materials
3. Humidity
"Humidity" refers to the presence of water vapor
in the atmosphere.
Types of humidity
Absolute humidity
Relative humidity
4. Absolute humidity
Absolute humidity is the total amount of water
vapour present in a given volume of air. It does
not take temperature into consideration. Absolute
humidity in the atmosphere ranges from near
zero to roughly 30 grams per cubic meter when
the air is saturated at 30 °C
OR
Absolute humidity is the weight of water present
in a unit volume of moist air i.e. grams per cubic
meter or, grains per cubic meter.
5. Relative humidity
The relative humidity of an air-water mixture is
defined as the ratio of the partial pressure of
water vapour (H2O) in the mixture to the
saturated vapour pressure of water at a given
temperature.
6. REGAIN & MOISTURE CONTENT
The amount of the moisture present in a material may be
expressed in terms of regain or moisture content.
Moisture Regain
Moisture regain is defined as the percentage of
water present in a textile material of oven dry
weight .
Oven dry weight = D
Weight of water = W (= Original weight- oven dry weight)
Moisture Regain = MR or R
Then, MR (%) = 100 W/ D
7. Moisture content:
Moisture content is defined as the weight of
water in the material expressed as a
percentage of the total weight.
Oven dry weight = D
Weight of water = W (= Original weight- oven dry
weight)
Moisture Content = MC or C
Then, MC (%) = 100 W/( W + D)
8. Regain is more commonly used than moisture
content.
The regain of any given fiber type gives a very
good indication of how sensitive that fibers
towards moisture.
Its actual value will clearly depends on the
humidity of the surroundings.
9. Regain-Humidity Relations of Textiles
If a piece of fabric or other textiles materials is placed
in a room in which the humidity is constant, then it
will eventually come to equilibrium by absorbing or
desorbing moisture as necessary until it reaches a
state of constant regain.
If the air humidity is in the normal range (around
65%rh) then wet fabric would become drier, whereas
a dry fabric would gradually become wetter.
10. Regain-Humidity Relations of Textiles
Hysteresis:
If we plot regain VS time for wet and dry samples of
the same material, both tend to be mirror image of
one another as indicated in the following diagram.
11. Regain-Humidity Relations of Textiles
Hysteresis:
However the two curves do not come together at
equilibrium, the equilibrium regain value of the two curve
is different.
specifically, the initially wet sample will end up somewhat
wetter than the initially dry sample, no matter how
long the two samples remain in the conditioned
atmosphere.
This is an example of Hysteresis, and is very important
where samples have to be conditioned for testing or other
purposes.
It implies that the approach to equilibrium should always
be from the same direction (i.e. either from wet to dry, or
else from dry to wet).
12. Regain VS Relative Humidity Curve
Mostly the plots of Regain VS Relative Humidity (RH) are
S-shaped (often described as ‘sigmoidal’). Because of
Hysteresis, any given material will produce two different
curves; the absorption curve and the desorption curve
(desorption curve is always higher).
Curve A is the absorption curve, that is, the regain-r.h.
percentage relation as a material takes up moisture.
Curve D is the desorption curve.
For instance, point a is the equilibrium condition at 65 %
relative humidity when approached from the wet side, and
point a is the equilibrium regain when approached from
the dry side. this is the hysteresis effect.
14. Factors Affecting the Regain of Textile
Materials
There are different factors that effect the
regain of the textile materials, such as;
Relative Humidity
Time
Temperature
The Previous History of The Sample
15. Relative Humidity:
Relative humidity is the most important factor that affects the
regain of textile materials. If the relative humidity in the air
is more then there will be more moisture regain or more rate
of conditioning of textile materials and vice versa.
Time:
A material placed in a given atmosphere takes a certain time
to reach equilibrium. The rate of conditioning depends on
several factors, such as;
The size and form of sample
The type of material
External conditions
16. Temperature:
The effect of temperature on regain is not
important. A change of 10 0C will give a change in
regain of cotton of about 0.3 percent. This effect
can be ignored.
The previous history of the sample:
The previous history of the sample can affect the
equilibrium regain of the sample. The hysteresis is
a good example. Processing can also change the
regain. When oils, waxes and other impurities are
removed then regain may change.
17. Effect of moisture on physical
properties
The physical properties of fibres can be affected
by their moisture content.
In general the fibres that absorb the greatest
amount of moisture are the ones whose properties
change the most. Three main types of properties
are affected:
Dimensional
Physical
Electrical
18. Effect of moisture on
dimensional properties
The absorption of moisture by fibres causes them
to swell, because of the insertion of water
molecules between the previously tightly packed
fibre molecules.
Because the fibre molecules are long and narrow
most of the available intermolecular spaces are
along the length of the molecules rather than at
the ends, so that the swelling takes place mainly
in the fibre width.
Nylon is a notable exception to this.
19. Effect of moisture on mechanical
properties
Some fibres, such as wool and viscose, lose strength when they absorb
water.
some, such as cotton, flax, hemp and jute, increase in strength.
Furthermore the extensibility, that is the extension at a given load, can
increase for some fibres when they are wet. Some properties such as
fabric tearing strength are ones
that are obviously likely to be affected by fibre strength, but for other
ones
such as crease resistance or abrasion resistance the connection between
them and changes in fibre tensile properties is less apparent. It is
because
of these changes in properties that textile tests should be carried out in a
controlled atmosphere.
20. Effect of moisture on electrical
properties
The resistance decreases with increasing moisture content. For
fibres that absorb water the following approximate relation
between the electrical resistance and the moisture content holds
for relative humidities between 30%
and 90%
RMn = k
where R = resistance,
M = moisture content (%),
and n and k are constants.
There is approximately a tenfold decrease in resistance for every
13% increase in the relative humidity
21. (1) The Wet-and-Dry Bulb Hygrometer
In this type of hygrometer there are two
thermometers one of which is surrounded by a
wet sleeve of muslin. The temperature difference
between wet and dry thermometer bulbs is
determined by the evaporation rate, which in turn
can be related to RH through look-up tables.
24. (1) The Wet-and-Dry Bulb Hygrometer
Its advantages include the simplicity and the fact
that it needs no calibration.
Its disadvantages are that it requires a constant
supply of distilled water and the fact that it is an
indirect method, since tables are needed.
Its various types are;
a) Wet-and-dry bulb hygrometer, wall mounted
b) Wet-and-dry bulb hygrometer, sling type
c) Assmann type hygrometer
d) Recording type hygrometer
25. (2) Hair Hygrometer
Human hair has the property of lengthening or
shortening as the humidity of the air increases or
decreases. By connecting a band of hairs to a suitable
lever system, the relative humidity can be indicated
directly and, if needed, recorded on a chart. It is a fact
that, it does not give great accuracy.
The main advantages of this type of hygrometer are
the direct reading and elimination of distilled water.
Drawbacks (or disadvantages) are also present such
as it requires frequent calibration and it have slow
response to change in atmospheric conditions.
26. (3) Electrolytic Hygrometer
Electrolytic hygrometer operates by measuring the
electrical current flowing in a skein of very fine fibers
impregnated with salt solution (e.g. Lithium Chloride)
which have the property of very rapidly attaining
equilibrium with the surrounding atmosphere.
The heart of this type of instrument is an element
consisting of a plastic frame carrying platinum-clad
electrodes. Skein of very fine fibers impregnated with
a chemical is wound across these electrodes.
27. (3) Electrolytic Hygrometer
Three advantages of electrolytic hygrometer are:
They can have very fast response
They take direct reading
They require only low air currents
They have no particular disadvantage.
Some other types of hygrometer are;
1) Electrical Hygrometer
2) DuPont Hygrometer