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Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
88
Determination of Surface Water Quality Status and Identifying
Potential Pollution Sources of Lake Tana: Particular Emphasis on
the Lake Boundary of Bahirdar City, Amhara Region, North
West Ethiopia, 2013
Dagnew A. Ewnetu
Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of
Gondar
Email: dagnewaweke@yahoo.com
Bikes D. Bitew
Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of
Gondar
Email: bikedes@yahoo.com
Daniel H. Chercos
Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of
Gondar
E-mail: daniel.haile7@gmail.com
Abstract
Background: The water quality of Lake Tana is influenced by environmental stress and anthropogenic activities.
Point and non-point sources are the major factors which affect the quality of the lake.
Objectives: To determine surface water quality status of Lake Tana and to identify the potential pollution
sources bound to Bahirdar City Administration, Ethiopia.
Methodology: Laboratory based cross – sectional study was conducted in order to assess the quality and to
identify the potential pollution sources of the lake. Geo referenced water samples were collected at eight
sampling stations. Repeated water samples were collected and analyzed.
Result: The common water quality monitoring parameter were analysed, very low dissolved oxygen (3.5 mg/l)
and high biochemical oxygen demand (23.7mg/l) were investigated in severely stressed sites. In addition to these,
enriched nutrient like phosphorus and nitrate were identified to a level that influences algal growth. According to
microbial analysis, total coli forms >180mg/100ml and Escherichia coli type one were isolated.
Conclusions: The Canadian Water Quality Index result categorizes the lake as poor state to aquatic life,
recreation and drinking.
Keywords: Water quality, Lake, surface water, Water pollution, Point source pollution, Water Quality Index
1. Introduction
Surface waters are most vulnerable to pollution due to natural processes and anthropogenic influences. Nutrient
enriched runoff from farmlands, pollutants from septic sewers and other human-related activities increase the
flux of both inorganic and organic substances into water which cause an intense negative effects upon the quality
of surface waters worldwide(1). Human - induced changes in the hydrologic system of lakes have direct and
severe consequences on nutrient cycling and contaminant retention in adjacent floodplains (2). Contamination of
surface water is a persistent threat to human health, aquatic life and economical loss (3).
Major lakes that had been recognized as an internationally important conservation sites due to their richness in
biodiversity, the tropic status had changed as a result of anthropogenic activities (4). Eutrophication is the major
problem resulted in many lakes, which degrades freshwater systems worldwide by reducing water quality and
altering ecosystem structure and function (5).
Lake Tana which is largest lake in the country, its quality is liable to impairment likewise other lakes because of
human induced activities. Agriculture inputs like pesticides, fertilizers and organic manure drain, wastewater
from different institution, industries, residents, recreation centers and street runoff loaded directly into the lake.
Monitoring the quality of the lake in sustainable way would play a key role in identifying the trend of the quality
of the lake and to provide adequate information for decision makers. This study is aimed to contribute in
determining the current status lake quality, and to identify potential source of pollution which needs serious
attention.
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
89
2. Materials and Methods (Times New Roman, 12; Single-columned & Justified)
2.1. Study Design and Period
Laboratory based cross – sectional study was conducted to assess the quality status and the potential pollution
sources of Lake Tana from March to July, 2013.
2.2. Study Area
Lake Tana is located at the North western part of Ethiopian highlands, just to the North of Bahirdar city, the
capital of Amhara National Regional State located 565 Km from Addis Ababa and has a population of 277,566
(6). Bahirdar City is known as scenic tourism destination center because of Lake Tana Islands with historical and
religious heritages. Lake Tana is geographically situated between latitude 10°58`12.47’’N and longitude,
36°45`38.14’’ E, at altitude of 1840 m.a.s.l. Lake Tana has a surface area of 3156 km², stretching
approximately 84 km north - south and 66 km east-west. Its maximum depth is 14m and has a mean depth of
8.9m with decreasing trend due to siltation. The water volume of Lake Tana is estimated to be 49.3 billion m3
.
Lake Tana water shade has a drainage area of over 16,500km² (7).
2.3. Sample Size Determination
According to United Nation Environmental Program (UNEP) Water Quality Monitoring, a practical guide to the
design and implementation of freshwater quality studies and monitoring program (8), surface water sample size
determination for larger lakes is mainly depend on surface area of the lake. The sample stations would be
proportional to the area of the lake in logarithm of 10 km2
. A lake having an area of 10 km2
, one sampling site is
adequate for regular monitoring activity. Based on this assumption, Lake Tana having an area of 3156km2
requires a minimum of four sampling sites.
No. of sample sites = log10 surface area of lake in km2
= log 10 3156 = 4 sample sites
However, this estimate will not include sampling sites selected for specific water quality assessment monitoring
program. Based on this fact the sample stations for the study were selected from twelve potential sites of the
southern gulf of Lake Tana bounded to Bahirdar City Administration. These twelve sites were identified from
the survey result of proximity, and access, anthropogenic activity, storm water loading, lakeshore recreation
practice, marine harbor, habit of littering waste into the lake, open bathing and laundering activities were
considered as critical point of attention for water quality assessment. These twelve sites were listed according to
their geographical location from west to south in order to facilitate sampling procedure and to have a sampling
frame. For this study six sites 50% from the total potential sites and two additional sites one from potential sites
and one site which is far from reach of human activity as reference sites were selected. In total eight sites were
selected for this study.
2.4. Sampling Technique
Systematic sampling technique was used to select the location sites. This technique was used in order to have
better distribution of stations across the southern gulf of the lake. The first site was randomly selected by lottery
method and the first location was row six, known as Ghihon Hotel and the rest sites were selected successively
downward from the top listed sites according to sampling interval. Based on this procedure Ghiwon Hotele, St.
George, Shum Abo Menafesha, West Gojjam Prison, Felege Hiwot Hospital and Avanti Hotel were selected. In
addition to these sites one sampling site as reference site known as Kibran area which if far from the reach of
human activity and another additional site from potential sites called Tana Hotel was included in this study for
comparison.
2.5. Data Collection Procedure
2.5.1 Collection of Water Sample
The water sample was collected from June 7 – July 19/2013. Data was collected with prepared checklist. The
data include water test result record and sanitary survey reports. Each site was assessed for the possible potential
source of pollution. In the process of sample collection and analysis essential material and equipment were ready
before transporting to the stations. The required type sample bottles, labels and marking pens, recording sheet,
sample storage, transit containers, on site analysis testing apparatus, necessary protection equipments like life
saving vest were ready.
Samples were collected on weekly base by clustering the stations into two batches. Samples for physical and
chemical analysis were collected with pre-cleaned rinsed one liter capacity polyethylene containers while for
bacteriological analysis sterilized standard 500ml glass bottles were used. Samples for DO and BOD were
collected with 300ml BOD bottles. Sample was collected at 20 - 30cm depth from the surface of the lake with
hand dip. Sample containers used to collect sample for chemical analysis were rinsed before drawing water
sample and were completely filled and sealed with no air space, whereas samples for bacteriological analysis
were taken with container having air space. In this study no preservation was used in sample collection and
samples are transported under cold box to the laboratories.
2.5.2 Water Quality Analysis
The water quality test was conducted at different centers; the chemical analysis was carried out at the Amhra
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
90
Region Bureau of Water and Energy (BoWE) water quality laboratory. The BOD test was conducted at Bahirdar
University, School of Water Resource and Civil Engineering laboratory. Bacteriological test was done in the
Amhara Regional Health and Research Laboratory Center. In this study different equipment and test procedures
were applied, the physical analysis was carried out at field level by using the “Wagtech“ products of the
“Potalab” digital conductivity meter, pH meter and turbidity meter model No. “Wag – WT3020”. The chemical
test was analyzed with digital spectrophotometer of the “HACH” product “DR. 2800” and “DR.2010”. Tests like
total alkalinity and chloride were analysed with titration method in BoWE laboratory. The bacteriological
analysis was done with multiple tube method at the regional laboratory.
The DO and BOD test was analysed with the help ELMETRON CO – 411 Oxygen electrode probe meter. DO
was measured in the field just after sample is collected. The BOD test was processed in the laboratory. In this
process initial DO was measured for every serial of dilution of sample and for the blank distilled water. The final
BOD was recorded after the completion of 5 days incubation period under a temperature of 20o
c. The BOD test
result was computed for each dilution and taking the average of serial dilution using the formula below;
BOD = [DOinitial - DOfinal] DF(dilution factor) (9).
The physical tests like pH, temperature, conductivity, TDS, and turbidity were analyzed at field level as soon as
water sample is collected from the Lake. Instruments used for the water quality analysis were calibrated
according the manufacturers instruction and the necessary accessories supplied with.
2.5.3 Personnel involved in the study
Two water technician and one Environmental health officer were involved in the sample collection and physical
quality analysis with one cartographer who undertakes GPS readings of geographical locations. In addition, five
water quality analysers involved to process the chemical as well as the bacteriological analysis.
2.6 Data quality management
A one day orientation and introduction session was organized for data collectors to share experience and to
develop commitment. In order to maintain consistency of measurement replicate water sample were collected
and analysed in each sampling sites. Double entry was applied to check for the recorded data and maintain
accuracy. The test results were recorded and documented on pre-arranged check list. Skilled professionals were
involved in sample collection as well as in laboratory test analysis. The instruments used for the analysis were
calibrated according to the manufacturer’s manual and procedure.
2.7 Data Processing and Analysis
Data was checked and entered into EPI INFO and transferred into SPSS version 20 statistical packages for
analysis. Descriptive statistics with figures and tables are presented to show the facts obtained from the
laboratory analysis on selected and most commonly reported parameters. The Canadian Water Quality Index
CWQI model was used to summarize the findings of surface water quality analysis. This approach has been
accepted by the United Nation Environmental Program Global Environment Monitoring System (UNEP GEMS)
experts and was selected from its applicability to compare observations to the water quality guideline or site
specific background concentration (10). The model equation expressed as;
WQI = 100 –
√ 2 2 2
.
F1= Represent Scope – the percentage of parameters that exceed the guideline value set by WHO or national
guideline or standard
F1 = X 100
F2 = Represent Frequency – the percentage of individual tests within each
parameter that exceed the guideline
F2 = x 100
F3 = Represent Amplitude – the extent (excursion) to which the failed test exceeds the guideline. F3 calculated
in three stages
1st
. Excursion = – 1
2nd
. the normalized sum of excursion (nse) is calculated
nse =
∑!" #$%&'()!*
F3 =
+.+ +.+
The CWQI was mathematically calculated and shown in the annex 9 and the Canadian water quality calculator
software was employed as per to specific water quality index (11). Therefore, for this study the CWQI software
was applied to summarize the water quality status of Lake Tana bound to Bahirdar City Administration.
2.8 Ethical considerations
Ethical clearance was obtained from the ethical review board of University of Gondar. Permission was also
obtained from Tana Sub Basin Enterprise, the Blue Nile Basin Authority Federal Democratic Republic of
Ethiopia and the Regional Water Resource and Energy Bureau.
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
91
3. Results
3.1. Physio-chemical parameters
The physio-chemical parameters such as Temperature, pH, Turbidity, conductivity, Nitrate, Nitrite, Phosphate,
Phosphorous, TDS, Manganese, DO and BOD parameters were analysed and the result summary is presented in
Table 1.
3.2. Bacteriological Analysis
Bacteriological analysis was conducted to identify the total coliform and to investigate the presence of lactose
fermenting bacteria. The result of total coliform in four sites was > 180/100ml. Escherichia coli (E. coli type one)
was isolated in three locations. E. coli was not identified in the reference location which is around Kibran area
(Table 2).
3.3. Potential Pollution Sources of Lake Tana
In the process of identifying the potential sources of the Lake Tana bound to Bahirdar City Administration,
sanitary survey was conducted in all sampling stations selected for the study. The sanitary survey report used to
identify pollutions sources from different organizations and service centers (Table 3).
3.4. Water Quality Index
Canadian Water Quality Index (CWQI) (11) was used to summarize and to introduce the test result to all
interested stakes. The laboratory results entered into the CWQI calculator software Excel 2000 and computed
according to criteria set based on the guideline of fresh water quality. The water quality was indexed based on
the parameters exceeding the guideline limits set in the criteria and presented in figure 1.
4. Discussion
In water quality analysis various parametric measures need to be considered in order to conclude on the status of
the water resource. Therefore, each parameter with their relative interpretation is described below in the
discussion.
PH is the most important indicator widely investigated in water quality monitoring program. In this study the
mean value of pH was 7.41 ± 0.461 which is within acceptable range of drinking water quality of WHO
guideline.
Temperature: Is also the other most important parameters in natural surface-water quality analysis, since
surface waters are subjected to great temperature variations. Inadequately treated municipal and industrial waste
discharges, leachate and runoff, cause an increase in water temperature (12). As of the United Kingdom (UK)
water supply regulation of 1989 the water temperature is defined to be below 25o
c (13). In the current study the
water temperature was found with an average of 22.8 ± 1.19o
c. Higher temperature was recorded at station St.
George Church area. The main reason for this result may be influenced with the increase of ambient temperature
in one day measurement, and waste water loading might also responsible for an increase of water temperature,
since this particular location is prone for contaminant sources as explained in the sanitary survey report.
Turbidity: Is another important parameter in determining the quality status of water which is caused due to
suspended particles. Enhanced surface-water regulations in the United States require that the maximum
contaminant level for turbidity states not exceed 0.5 NTU in 95 % of the samples taken every month and must
never exceed 1 NTU (14). In this study the minimum turbidity result was 1.54 NTU and the maximum test result
was 43.3 NTU at station 03 known as Kibran area which is selected as reference site. The higher turbidity result
in that particular location was due to the mixing zone of tributary rivers particularly the “Gilgel Abay’’. Low
turbidity result was recorded at location 04 which is around Felege Hiwot Referral Hospital. The low turbidity
result may be characterised due to the dense algal vegetation cover in this particular Lake region. The colour of
this particular location during the period of sample collection was turned green; this condition might contribute
in sedimentation process of settle able particles present in the upper surface of the Lake.
Conductivity: Is a measure of the capacity of water to pass an electrical current. In this study the mean
conductivity measure was 171.42±23.53µSCm-1
ranging between 84 – 230 µSCm-1
. The lowest measurement
recorded in areas of the reference site which is far from anthropogenic activities and highest result was recorded
at location 08 known as Avantie Hotel area. Although the test result of conductivity was found with a range that
classifies water bodies as fresh water, the variation at different location may be an indication for the crude
mixing of wastewater into Lake.
Total Dissolved Solid (TDS): The mean test result of TDS was 102.54 ± 14.07mg/l minimum 50mg/l and
maximum 138mg/l. According to TDS classification Lake Tana is categorized under fresh water. The TDS
result was varied from location to location the higher result was recorded in areas where there is a possibility of
sewage discharge and less concentration was observed at the location selected as reference site.
Total Alkalinity: The mean of Total Alkalinity of water was 106.31±21.78mg/l where the minimum was 85mg/l
and the maximum was 159mg/l. Water with Alkalinity below 80 parts per million (ppm), known with rapid
fluctuation in pH and when high alkalinity reached to 200 ppm, the water is said to be buffered (15, 16).
According to the test result Lake Tana was found with acceptable range. These results also determine the status
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
92
of pH to be stable.
Phosphorus: The phosphorous concentration was found with the range of 0.01 – 0.92mg/l, where the mean
value was 0.14 ± 0.11mg/l. In freshwater lakes levels approaching or exceeding 0.5 mg/l are associated with
cultural eutrophication with excessive growth of algae and aquatic plants (17). A study conducted at Pushkar
Lake India 2008, phosphorus was reported with the range of 0.4 – 2.03mg/l, where the result was much higher in
the event of annual celebration characterized with dumping of waste as and bones (18). In the current study
higher concentration was recorded at location 06 around St. George Church. The reason for high concentration
might be resulted due to loading of untreated wastewater through the sewer line connected with surface runoff
drainage system, directed into Lake Tana and also prone for contaminant sources as explained in the sanitary
survey report.
Phosphate: The phosphate test result at different locations ranges between 0.05 – 2.82mg/l. higher concentration
of phosphate result was identified at location 06 known as St. Gorge church area. This result might be influenced
due to wastewater discharged from the central part of the city and anthropogenic activities at the lakeshore. This
result in conformity with a study conducted in variations of water quality of urban river in Nigeria 2013, the
phosphate level was reported with the range of 0.81 – 1.14mg/l, where the main reason for high concentration
report was due to human pressure in the urban centers which affect the downstream (19).
Nitrate: Is one of the major anions in natural waters, and concentrations can be greatly elevated due to leaching
of nitrogen from fertilizer, feedlots, and septic tanks. The mean concentration of nitrate nitrogen (NO3 as N) in a
typical surface water supply is around 0.2 to 2 mg/l (20) , where the WHO drinking water guideline 2006 defines
Nitrate Nitrogen as 11mg/l and nitrate 50mg/l (21). In the current study the nitrate level ranges between 2.7 –
12.05 mg/l and the mean value was 6 ± 2.92mg/l. The nitrate – Nitrogen concentration ranges from 0.61 –
2.72mg/l as multiplied with conversion factor to nitrogen: 1 mg/l as nitrate = 0.226 mg/l as nitrate-nitrogen; 1
mg/l as nitrite = 0.304 mg/l as nitrite-nitrogen (22). Higher Nitrate concentration was recorded at location 07
known as Tana Hotel area, this result may indicate the crude loading practice of sewage into the Lake.
Manganese : Man-made sources of manganese includes industrial wastes, discarded batteries and agricultural
products (20). In this study manganese concentration was found within the range of 0.1 – 1.30 mg/l with the
mean value of 0.58 ± 0.37 mg/l. Higher concentration was recorded in the locations around Felege Hiwot
Referral Hospital, Tana Hotel, Avantie Hotel and Shum Abo recreational area. The WHO guideline Value to
manganese is 0.4 mg/l, from aesthetic and in the basis of staining laundry, UK and the United States
Environmental Protection Agency (USEPA) limit the manganese Secondary Maximum Concentration Level
(SMCL) to 0.05 mg/l (20). A study conducted in Egypt on Water Quality and Heavy Metal Monitoring in River
Nile 2010, manganese concentration was found with the range of 0.033 – 0.099 mg/l on the analysis of water
(23). The concentration in the current study is high as compared to the guideline and from the study conducted in
Egypt. This may be due to crude dumping of waste from nearby institutions and service centers. The other may
associate to anaerobic or low oxidation conditions (20, 24).
Iron: The concentration of iron level was found within the range of 0.05 – 0.8 mg/l, where the mean value was
0.37 ± 0.18mg/l. higher result was recorded at the around Felege Hiwot Referral Hospital and at Shumabo
recreational area. The USEPA SMCL and WHO guideline level is 0.3 mg/l, the goal is to limit less than 0.05
mg/l to prevent reddish-brown staining of laundry (14, 21). A study conducted in Egypt at the River Nile 2009
Iron concentration on water analysis was ranged from 0.19 to 0.49. In the current study the iron concentration in
selected location was beyond the permissible limit, this might associate to the presence of organic matter that
produce anoxic reducing conditions and an increases dissolved Iron (25).
Dissolved Oxygen: The DO was found with range of 3.5 and 8.5 mg/l, where the mean was 6.62 ± 1.75mg/l.
Low DO was recorded at the locations ‘’Maremiabiet’’ West Gojjam prison area and Felege Hiwot Referral
Hospital. This result was similar with a study conducted on assessment of physicochemical characteristics and
suggested restoration measures for Pushkar Lake Ajmer Rajasthan, India 2008 (18) where the dissolved oxygen
varied from 4.1 – 7.3 mg/l. Another study conducted on variations of water quality in urban river of Nigeria
2013, the DO concentration ranges from 0.8 to 7.4mg/l. The main reason for low DO was reported as dumping
of waste from agricultural practice such as piggery, fish farm, snailry, Wastewater discharge and organic waste
dumped from abattoir, indiscriminate dumping of waste from marketing center were the main source of pollution
and contributing factor for low DO level in the rivers (19). Changes in dissolved oxygen concentrations can be
an early indication of undesirable conditions in physical, chemical and biochemical factors in the water bodies
(8). In the current study low dissolved oxygen level, in the two locations may be associate to loading of sewage
and other waste directly in to the Lake. The survey result supports how the condition is critical in these particular
locations.
Biochemical Oxygen Demand (BOD): In this study the BOD test was investigated within the range of 3.2 mg/l
in less impacted area of the sampling stations and 23.7mg/l in highly stressed areas of sampling locations. Low
BOD result was recorded at location 3 known as Kibran area selected as reference site. Higher BOD result was
recorded in areas with highly stressed locations Marmiabiet or West Gojjam prison area and Felege Hiwot
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
93
Referral Hospital. The UK Royal commission on sewage disposal in 1915 observed that unpolluted rivers rarely
had BOD value of more than 2 mg/l and could accept added pollution up to a total BOD of 4 mg/l without
apparent determent. This gave to raise the maximum permissible BOD of 20 mg/l in a sewage effluent entering a
watercourse with an 8:1 dilution fresh water (26). In this study the BOD level particularly in selected locations
was found very high even the permissible level of effluent. The main reason may associate to crude dumping of
waste and untreated wastewater loading. The survey report supports how the condition in these particular
locations was very critical and the result was coinciding with the current physical condition.
Bacteriological analysis: In this study the total coliform count was found over 180 /100 ml in four locations.
Out of the four positive samples analyzed for confirmative test, three sample were found positive for Escherichia
coli type one (E.coli type one). E.coli was not isolated around Kibran area selected as reference site. The
presence of E. coli is a good evidence for recent contamination of Human faeces loaded into the lake through
connection of sewer lines with surface drainage system and very close siltation of pit latrines into the Lake.
Sanitary survey: Sanitary survey in water quality analysis is a best mechanism that enables to evaluate the
condition and to demonstrate the real picture of pollution status. The survey report clearly indicates the crude
dumping of waste and the way how the lake is being polluted from different institutions and service providing
centers. The survey also enables to identify the conditions that enhance siltation because of wetland tillage and
construction activities.
The sanitary survey report and the laboratory findings clearly indicated in the indexed figure, which shows the
quality of Lake Tana, bound to Bahirdar city Administration is critically impaired.
5. Conclusion
The findings of this study showed that the water quality of Lake Tana bound to Bahirdar City Administration
was found unsatisfactory because of pollutants loaded into the lake.
The sanitary survey report signifies how the condition is serious around the southern region of Lake Tana.
Indiscriminate dumping of solid waste, connection of untreated sewage into the surface runoff drainage system
and other anthropogenic activities attribute in deteriorating the quality of the lake. The under construction runoff
drainage across Bata church and the tillage of the natural wetland may result serious effect in siltation load.
6. Author’s contribution
Dagnew A. Ewnetu, was responsible for generating the concept of this research paper, literature review and
organization, preparation of draft research proposal document, organizing data collection process, and
preparation of draft data analysis and interpretation.
Bikes D. Bitew is participated in research topic preparation process, proposal research design process, data
analysis, and interpretation process.
Daniel H. Chercos participated in proposal research design process, data analysis, and presentation and
interpretation process of result, preparation of scientific paper or the manuscript, and corresponding author of the
manuscript.
All the authors read and approve the draft manuscript.
7. Competing interests
The authors declare that they have no competing interests.
8. Acknowledgments
We would like to address our special thanks to the University of Gondar for approving ethical review Amhara
Water and Energy Development Bureau, The school of Water and Civil Engineering, Bahirdar University, and
Amhara Regional Health and Research Laboratory Center for their cooperation and allowing us to use the water
quality laboratory and theirs analytical experts.
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Alaa G. M. Osman1, Werner Kloas2. Water Quality and Heavy Metal Monitoring in Water, Sediments, and
Tissues of the African
Catfish Clarias gariepinus (Burchell, 1822) from the River Nile. Journal of Environmental Protection 2010;1:389
- 400.
WHO WHO. Guideline for drinking water quality Acceptability aspects: Taste,ogour and appearance. Malta,
Gutenberg: WHO Publication Catalogue; 2011.
Jamees K. Edzwald JET. Chemical Principles Source Water Composition and Watershade Protection. In:
Edzwald JK, editor. Water Quality and Treatment. SIxth ed. New York, Chicago: McGraw Hill American Water
Works Association; 2011. p. 3-2.
Alan C. Twort DDRaMJB. Chmistry, Microbiology and Biology of water. 2000. In: Water Supply [Internet].
Butterworth Heinman, Binnie Black and Veach, IWA publishers. 5th [196].
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
95
Table 1 Water quality summary result of Lake Tana bound to Bahirdar City Administration from June 7 - July
19/2013
. Parameters Unit Min Max Range Mean SD WHO
Guideline
EU/EEC
pH 6.48 8.34 1.86 7.41 0.46 6.5 - 8.5 6.5 -8.5
Temperature o
c 20.20 25.60 5.40 22.80 1.19 25o
c**
Conductivity µScm-1
* 84.00 230.00 146.00 171.42 23.53 1492 -
TDS mg/l 50.00 138.00 88.00 102.54 14.07 1000 -
Turbidity NTU 1.54 43.30 41.76 18.70 9.00 5 4
Nitrate mg/l 1.10 12.05 10.95 6.18 3.24 50 50
Nitrite mg/l 0.01 0.32 0.31 0.07 0.07 3 0.01-0.03
Ammonia mg/l 0.08 0.62 0.54 0.24 0.17 0.2 –1.5**
Phosphate mg/l 0.02 2.82 2.80 0.43 0.70 0.5 – 0.7**
Phosphorous
mg/l 0.01 0.92 0.91 0.14 0.11
0.005 –
0.01
Total
Alkalinity mg/l 78.00 159.00 81.00 99.31 24.92
No
reference
Sulfate mg/l 0.00 10.00 10.00 3.75 3.17 250 250
Irion mg/l 0.05 0.80 0.75 0.37 0.18 0.3 0.2
Manganese mg/l 0.10 1.30 1.20 0.58 0.37 0.4 0.05
*µScm-1
(micro Siemens per centimeter)
**EEC – European Economic Commission
Source: - Environmental Protection Agency (EPA) of Ireland Parameters of water quality interpretation and
standards, 2001
EU – European Union
Source: - UNESCO, WHO, UNEP ©1992 1996 – water quality assessment, A guide to use of Biota sediments
and water in Environmental Monitoring 2nd
edition.
Table 2 Bacteriological analysis test result of Lake Tana at selected locations From June 2013.
Locations Total coliform
org/100ml
Escherichia coli
(E.coli type 1)
Method of analysis
Shum Abo Recreational
area
> 180/100ml present Multiple tube
Maremiabiet > 180/100ml present Multiple tube
Kibran Area > 180/100ml Absent Multiple tube
Felege Hiwot Referral
Hospital
> 180/100ml Present Multiple tube
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
96
Table 3 Summary of Sanitary survey report conducted at Lake Tana Bound to Bahirdar City Administration
June 2013.
S N
Potential pollutant sources and observed changes
Observed
Yes No
1 Is there direct waste discharge mixing index into the lake? 7(87.5%) 1(12.5%)
2 Is there a practice of dumping solid waste nearby the lake? 7(87.5&) 1 (12.5%)
3 Is there industrial waste discharge into the lake? 0 8(100%)
4 Is there a practice of connecting sewer line into surface runoff
drainage system?
7(87.5%) 1(12.5%)
5 Is there a chance of oil spill into the lake? 8(100%) 0
6 Is there undesirable vegetation growth in the lake? 7(87.5%) 1(12.5%)
7 Is there any filthy and unaesthetic condition in the visited site? 7(87.5%) 1(12.5%)
8 Is dead fish observed? 0 8(100%)
9 Is there fish and other animal offal or carcass observed in the visited
site?
7(87.5%) 1(12.5%)
10 Is there any risky condition to pollution that threatens aquatic life? 8(87.5%) 1(12.5%)
11 Is the visited site found impaired for recreation? 7(87.5%) 1(12.5%)
Category of risk of pollution
Category to risk of pollution
Number %
No risk
0 0
Low risk
1 12.5%
High risk
5 62.5%
Very high risk
2 25%
Total
8 100%
Figure 1
Figure 2 Canadian Water Quality Index of Lake Tana bound To Bahirdar City Administration from June 7 -
July19/2013.
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol.4, No.13, 2014
97
Figure legends
Figure 3 Canadian Water Quality Index of Lake Tana bound To Bahirdar City Administration from June 7 -
July19/2013. .
WQI (water quality index): the water quality results based on common parameters.
Excellent: WQI value, 95-100, Water quality is protected with a virtual absence of threat or impairment;
conditions very close to natural or pristine levels; these index values can only be obtained if all measurements
are within objectives virtually all of the time.
Good: WQI value, 80-94, Water quality is protected with only a minor degree of threat or impairment;
conditions rarely depart from natural or desirable levels.
Fair: WQI value 65-79, Water quality is usually protected but occasionally threatened or impaired; conditions
sometimes depart from natural or desirable levels.
Marginal: WQI value 45-64, Water quality is frequently threatened or impaired; conditions often depart from
natural or desirable levels
Poor: WQI value, 0-44, Water quality is almost always threatened or impaired; conditions usually depart from
natural or desirable levels.
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Lake Tana Water Quality and Pollution Sources

  • 1. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 88 Determination of Surface Water Quality Status and Identifying Potential Pollution Sources of Lake Tana: Particular Emphasis on the Lake Boundary of Bahirdar City, Amhara Region, North West Ethiopia, 2013 Dagnew A. Ewnetu Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of Gondar Email: dagnewaweke@yahoo.com Bikes D. Bitew Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of Gondar Email: bikedes@yahoo.com Daniel H. Chercos Department of Environmental and Occupational Health and Safety, Institute of Public Health, University of Gondar E-mail: daniel.haile7@gmail.com Abstract Background: The water quality of Lake Tana is influenced by environmental stress and anthropogenic activities. Point and non-point sources are the major factors which affect the quality of the lake. Objectives: To determine surface water quality status of Lake Tana and to identify the potential pollution sources bound to Bahirdar City Administration, Ethiopia. Methodology: Laboratory based cross – sectional study was conducted in order to assess the quality and to identify the potential pollution sources of the lake. Geo referenced water samples were collected at eight sampling stations. Repeated water samples were collected and analyzed. Result: The common water quality monitoring parameter were analysed, very low dissolved oxygen (3.5 mg/l) and high biochemical oxygen demand (23.7mg/l) were investigated in severely stressed sites. In addition to these, enriched nutrient like phosphorus and nitrate were identified to a level that influences algal growth. According to microbial analysis, total coli forms >180mg/100ml and Escherichia coli type one were isolated. Conclusions: The Canadian Water Quality Index result categorizes the lake as poor state to aquatic life, recreation and drinking. Keywords: Water quality, Lake, surface water, Water pollution, Point source pollution, Water Quality Index 1. Introduction Surface waters are most vulnerable to pollution due to natural processes and anthropogenic influences. Nutrient enriched runoff from farmlands, pollutants from septic sewers and other human-related activities increase the flux of both inorganic and organic substances into water which cause an intense negative effects upon the quality of surface waters worldwide(1). Human - induced changes in the hydrologic system of lakes have direct and severe consequences on nutrient cycling and contaminant retention in adjacent floodplains (2). Contamination of surface water is a persistent threat to human health, aquatic life and economical loss (3). Major lakes that had been recognized as an internationally important conservation sites due to their richness in biodiversity, the tropic status had changed as a result of anthropogenic activities (4). Eutrophication is the major problem resulted in many lakes, which degrades freshwater systems worldwide by reducing water quality and altering ecosystem structure and function (5). Lake Tana which is largest lake in the country, its quality is liable to impairment likewise other lakes because of human induced activities. Agriculture inputs like pesticides, fertilizers and organic manure drain, wastewater from different institution, industries, residents, recreation centers and street runoff loaded directly into the lake. Monitoring the quality of the lake in sustainable way would play a key role in identifying the trend of the quality of the lake and to provide adequate information for decision makers. This study is aimed to contribute in determining the current status lake quality, and to identify potential source of pollution which needs serious attention.
  • 2. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 89 2. Materials and Methods (Times New Roman, 12; Single-columned & Justified) 2.1. Study Design and Period Laboratory based cross – sectional study was conducted to assess the quality status and the potential pollution sources of Lake Tana from March to July, 2013. 2.2. Study Area Lake Tana is located at the North western part of Ethiopian highlands, just to the North of Bahirdar city, the capital of Amhara National Regional State located 565 Km from Addis Ababa and has a population of 277,566 (6). Bahirdar City is known as scenic tourism destination center because of Lake Tana Islands with historical and religious heritages. Lake Tana is geographically situated between latitude 10°58`12.47’’N and longitude, 36°45`38.14’’ E, at altitude of 1840 m.a.s.l. Lake Tana has a surface area of 3156 km², stretching approximately 84 km north - south and 66 km east-west. Its maximum depth is 14m and has a mean depth of 8.9m with decreasing trend due to siltation. The water volume of Lake Tana is estimated to be 49.3 billion m3 . Lake Tana water shade has a drainage area of over 16,500km² (7). 2.3. Sample Size Determination According to United Nation Environmental Program (UNEP) Water Quality Monitoring, a practical guide to the design and implementation of freshwater quality studies and monitoring program (8), surface water sample size determination for larger lakes is mainly depend on surface area of the lake. The sample stations would be proportional to the area of the lake in logarithm of 10 km2 . A lake having an area of 10 km2 , one sampling site is adequate for regular monitoring activity. Based on this assumption, Lake Tana having an area of 3156km2 requires a minimum of four sampling sites. No. of sample sites = log10 surface area of lake in km2 = log 10 3156 = 4 sample sites However, this estimate will not include sampling sites selected for specific water quality assessment monitoring program. Based on this fact the sample stations for the study were selected from twelve potential sites of the southern gulf of Lake Tana bounded to Bahirdar City Administration. These twelve sites were identified from the survey result of proximity, and access, anthropogenic activity, storm water loading, lakeshore recreation practice, marine harbor, habit of littering waste into the lake, open bathing and laundering activities were considered as critical point of attention for water quality assessment. These twelve sites were listed according to their geographical location from west to south in order to facilitate sampling procedure and to have a sampling frame. For this study six sites 50% from the total potential sites and two additional sites one from potential sites and one site which is far from reach of human activity as reference sites were selected. In total eight sites were selected for this study. 2.4. Sampling Technique Systematic sampling technique was used to select the location sites. This technique was used in order to have better distribution of stations across the southern gulf of the lake. The first site was randomly selected by lottery method and the first location was row six, known as Ghihon Hotel and the rest sites were selected successively downward from the top listed sites according to sampling interval. Based on this procedure Ghiwon Hotele, St. George, Shum Abo Menafesha, West Gojjam Prison, Felege Hiwot Hospital and Avanti Hotel were selected. In addition to these sites one sampling site as reference site known as Kibran area which if far from the reach of human activity and another additional site from potential sites called Tana Hotel was included in this study for comparison. 2.5. Data Collection Procedure 2.5.1 Collection of Water Sample The water sample was collected from June 7 – July 19/2013. Data was collected with prepared checklist. The data include water test result record and sanitary survey reports. Each site was assessed for the possible potential source of pollution. In the process of sample collection and analysis essential material and equipment were ready before transporting to the stations. The required type sample bottles, labels and marking pens, recording sheet, sample storage, transit containers, on site analysis testing apparatus, necessary protection equipments like life saving vest were ready. Samples were collected on weekly base by clustering the stations into two batches. Samples for physical and chemical analysis were collected with pre-cleaned rinsed one liter capacity polyethylene containers while for bacteriological analysis sterilized standard 500ml glass bottles were used. Samples for DO and BOD were collected with 300ml BOD bottles. Sample was collected at 20 - 30cm depth from the surface of the lake with hand dip. Sample containers used to collect sample for chemical analysis were rinsed before drawing water sample and were completely filled and sealed with no air space, whereas samples for bacteriological analysis were taken with container having air space. In this study no preservation was used in sample collection and samples are transported under cold box to the laboratories. 2.5.2 Water Quality Analysis The water quality test was conducted at different centers; the chemical analysis was carried out at the Amhra
  • 3. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 90 Region Bureau of Water and Energy (BoWE) water quality laboratory. The BOD test was conducted at Bahirdar University, School of Water Resource and Civil Engineering laboratory. Bacteriological test was done in the Amhara Regional Health and Research Laboratory Center. In this study different equipment and test procedures were applied, the physical analysis was carried out at field level by using the “Wagtech“ products of the “Potalab” digital conductivity meter, pH meter and turbidity meter model No. “Wag – WT3020”. The chemical test was analyzed with digital spectrophotometer of the “HACH” product “DR. 2800” and “DR.2010”. Tests like total alkalinity and chloride were analysed with titration method in BoWE laboratory. The bacteriological analysis was done with multiple tube method at the regional laboratory. The DO and BOD test was analysed with the help ELMETRON CO – 411 Oxygen electrode probe meter. DO was measured in the field just after sample is collected. The BOD test was processed in the laboratory. In this process initial DO was measured for every serial of dilution of sample and for the blank distilled water. The final BOD was recorded after the completion of 5 days incubation period under a temperature of 20o c. The BOD test result was computed for each dilution and taking the average of serial dilution using the formula below; BOD = [DOinitial - DOfinal] DF(dilution factor) (9). The physical tests like pH, temperature, conductivity, TDS, and turbidity were analyzed at field level as soon as water sample is collected from the Lake. Instruments used for the water quality analysis were calibrated according the manufacturers instruction and the necessary accessories supplied with. 2.5.3 Personnel involved in the study Two water technician and one Environmental health officer were involved in the sample collection and physical quality analysis with one cartographer who undertakes GPS readings of geographical locations. In addition, five water quality analysers involved to process the chemical as well as the bacteriological analysis. 2.6 Data quality management A one day orientation and introduction session was organized for data collectors to share experience and to develop commitment. In order to maintain consistency of measurement replicate water sample were collected and analysed in each sampling sites. Double entry was applied to check for the recorded data and maintain accuracy. The test results were recorded and documented on pre-arranged check list. Skilled professionals were involved in sample collection as well as in laboratory test analysis. The instruments used for the analysis were calibrated according to the manufacturer’s manual and procedure. 2.7 Data Processing and Analysis Data was checked and entered into EPI INFO and transferred into SPSS version 20 statistical packages for analysis. Descriptive statistics with figures and tables are presented to show the facts obtained from the laboratory analysis on selected and most commonly reported parameters. The Canadian Water Quality Index CWQI model was used to summarize the findings of surface water quality analysis. This approach has been accepted by the United Nation Environmental Program Global Environment Monitoring System (UNEP GEMS) experts and was selected from its applicability to compare observations to the water quality guideline or site specific background concentration (10). The model equation expressed as; WQI = 100 – √ 2 2 2 . F1= Represent Scope – the percentage of parameters that exceed the guideline value set by WHO or national guideline or standard F1 = X 100 F2 = Represent Frequency – the percentage of individual tests within each parameter that exceed the guideline F2 = x 100 F3 = Represent Amplitude – the extent (excursion) to which the failed test exceeds the guideline. F3 calculated in three stages 1st . Excursion = – 1 2nd . the normalized sum of excursion (nse) is calculated nse = ∑!" #$%&'()!* F3 = +.+ +.+ The CWQI was mathematically calculated and shown in the annex 9 and the Canadian water quality calculator software was employed as per to specific water quality index (11). Therefore, for this study the CWQI software was applied to summarize the water quality status of Lake Tana bound to Bahirdar City Administration. 2.8 Ethical considerations Ethical clearance was obtained from the ethical review board of University of Gondar. Permission was also obtained from Tana Sub Basin Enterprise, the Blue Nile Basin Authority Federal Democratic Republic of Ethiopia and the Regional Water Resource and Energy Bureau.
  • 4. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 91 3. Results 3.1. Physio-chemical parameters The physio-chemical parameters such as Temperature, pH, Turbidity, conductivity, Nitrate, Nitrite, Phosphate, Phosphorous, TDS, Manganese, DO and BOD parameters were analysed and the result summary is presented in Table 1. 3.2. Bacteriological Analysis Bacteriological analysis was conducted to identify the total coliform and to investigate the presence of lactose fermenting bacteria. The result of total coliform in four sites was > 180/100ml. Escherichia coli (E. coli type one) was isolated in three locations. E. coli was not identified in the reference location which is around Kibran area (Table 2). 3.3. Potential Pollution Sources of Lake Tana In the process of identifying the potential sources of the Lake Tana bound to Bahirdar City Administration, sanitary survey was conducted in all sampling stations selected for the study. The sanitary survey report used to identify pollutions sources from different organizations and service centers (Table 3). 3.4. Water Quality Index Canadian Water Quality Index (CWQI) (11) was used to summarize and to introduce the test result to all interested stakes. The laboratory results entered into the CWQI calculator software Excel 2000 and computed according to criteria set based on the guideline of fresh water quality. The water quality was indexed based on the parameters exceeding the guideline limits set in the criteria and presented in figure 1. 4. Discussion In water quality analysis various parametric measures need to be considered in order to conclude on the status of the water resource. Therefore, each parameter with their relative interpretation is described below in the discussion. PH is the most important indicator widely investigated in water quality monitoring program. In this study the mean value of pH was 7.41 ± 0.461 which is within acceptable range of drinking water quality of WHO guideline. Temperature: Is also the other most important parameters in natural surface-water quality analysis, since surface waters are subjected to great temperature variations. Inadequately treated municipal and industrial waste discharges, leachate and runoff, cause an increase in water temperature (12). As of the United Kingdom (UK) water supply regulation of 1989 the water temperature is defined to be below 25o c (13). In the current study the water temperature was found with an average of 22.8 ± 1.19o c. Higher temperature was recorded at station St. George Church area. The main reason for this result may be influenced with the increase of ambient temperature in one day measurement, and waste water loading might also responsible for an increase of water temperature, since this particular location is prone for contaminant sources as explained in the sanitary survey report. Turbidity: Is another important parameter in determining the quality status of water which is caused due to suspended particles. Enhanced surface-water regulations in the United States require that the maximum contaminant level for turbidity states not exceed 0.5 NTU in 95 % of the samples taken every month and must never exceed 1 NTU (14). In this study the minimum turbidity result was 1.54 NTU and the maximum test result was 43.3 NTU at station 03 known as Kibran area which is selected as reference site. The higher turbidity result in that particular location was due to the mixing zone of tributary rivers particularly the “Gilgel Abay’’. Low turbidity result was recorded at location 04 which is around Felege Hiwot Referral Hospital. The low turbidity result may be characterised due to the dense algal vegetation cover in this particular Lake region. The colour of this particular location during the period of sample collection was turned green; this condition might contribute in sedimentation process of settle able particles present in the upper surface of the Lake. Conductivity: Is a measure of the capacity of water to pass an electrical current. In this study the mean conductivity measure was 171.42±23.53µSCm-1 ranging between 84 – 230 µSCm-1 . The lowest measurement recorded in areas of the reference site which is far from anthropogenic activities and highest result was recorded at location 08 known as Avantie Hotel area. Although the test result of conductivity was found with a range that classifies water bodies as fresh water, the variation at different location may be an indication for the crude mixing of wastewater into Lake. Total Dissolved Solid (TDS): The mean test result of TDS was 102.54 ± 14.07mg/l minimum 50mg/l and maximum 138mg/l. According to TDS classification Lake Tana is categorized under fresh water. The TDS result was varied from location to location the higher result was recorded in areas where there is a possibility of sewage discharge and less concentration was observed at the location selected as reference site. Total Alkalinity: The mean of Total Alkalinity of water was 106.31±21.78mg/l where the minimum was 85mg/l and the maximum was 159mg/l. Water with Alkalinity below 80 parts per million (ppm), known with rapid fluctuation in pH and when high alkalinity reached to 200 ppm, the water is said to be buffered (15, 16). According to the test result Lake Tana was found with acceptable range. These results also determine the status
  • 5. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 92 of pH to be stable. Phosphorus: The phosphorous concentration was found with the range of 0.01 – 0.92mg/l, where the mean value was 0.14 ± 0.11mg/l. In freshwater lakes levels approaching or exceeding 0.5 mg/l are associated with cultural eutrophication with excessive growth of algae and aquatic plants (17). A study conducted at Pushkar Lake India 2008, phosphorus was reported with the range of 0.4 – 2.03mg/l, where the result was much higher in the event of annual celebration characterized with dumping of waste as and bones (18). In the current study higher concentration was recorded at location 06 around St. George Church. The reason for high concentration might be resulted due to loading of untreated wastewater through the sewer line connected with surface runoff drainage system, directed into Lake Tana and also prone for contaminant sources as explained in the sanitary survey report. Phosphate: The phosphate test result at different locations ranges between 0.05 – 2.82mg/l. higher concentration of phosphate result was identified at location 06 known as St. Gorge church area. This result might be influenced due to wastewater discharged from the central part of the city and anthropogenic activities at the lakeshore. This result in conformity with a study conducted in variations of water quality of urban river in Nigeria 2013, the phosphate level was reported with the range of 0.81 – 1.14mg/l, where the main reason for high concentration report was due to human pressure in the urban centers which affect the downstream (19). Nitrate: Is one of the major anions in natural waters, and concentrations can be greatly elevated due to leaching of nitrogen from fertilizer, feedlots, and septic tanks. The mean concentration of nitrate nitrogen (NO3 as N) in a typical surface water supply is around 0.2 to 2 mg/l (20) , where the WHO drinking water guideline 2006 defines Nitrate Nitrogen as 11mg/l and nitrate 50mg/l (21). In the current study the nitrate level ranges between 2.7 – 12.05 mg/l and the mean value was 6 ± 2.92mg/l. The nitrate – Nitrogen concentration ranges from 0.61 – 2.72mg/l as multiplied with conversion factor to nitrogen: 1 mg/l as nitrate = 0.226 mg/l as nitrate-nitrogen; 1 mg/l as nitrite = 0.304 mg/l as nitrite-nitrogen (22). Higher Nitrate concentration was recorded at location 07 known as Tana Hotel area, this result may indicate the crude loading practice of sewage into the Lake. Manganese : Man-made sources of manganese includes industrial wastes, discarded batteries and agricultural products (20). In this study manganese concentration was found within the range of 0.1 – 1.30 mg/l with the mean value of 0.58 ± 0.37 mg/l. Higher concentration was recorded in the locations around Felege Hiwot Referral Hospital, Tana Hotel, Avantie Hotel and Shum Abo recreational area. The WHO guideline Value to manganese is 0.4 mg/l, from aesthetic and in the basis of staining laundry, UK and the United States Environmental Protection Agency (USEPA) limit the manganese Secondary Maximum Concentration Level (SMCL) to 0.05 mg/l (20). A study conducted in Egypt on Water Quality and Heavy Metal Monitoring in River Nile 2010, manganese concentration was found with the range of 0.033 – 0.099 mg/l on the analysis of water (23). The concentration in the current study is high as compared to the guideline and from the study conducted in Egypt. This may be due to crude dumping of waste from nearby institutions and service centers. The other may associate to anaerobic or low oxidation conditions (20, 24). Iron: The concentration of iron level was found within the range of 0.05 – 0.8 mg/l, where the mean value was 0.37 ± 0.18mg/l. higher result was recorded at the around Felege Hiwot Referral Hospital and at Shumabo recreational area. The USEPA SMCL and WHO guideline level is 0.3 mg/l, the goal is to limit less than 0.05 mg/l to prevent reddish-brown staining of laundry (14, 21). A study conducted in Egypt at the River Nile 2009 Iron concentration on water analysis was ranged from 0.19 to 0.49. In the current study the iron concentration in selected location was beyond the permissible limit, this might associate to the presence of organic matter that produce anoxic reducing conditions and an increases dissolved Iron (25). Dissolved Oxygen: The DO was found with range of 3.5 and 8.5 mg/l, where the mean was 6.62 ± 1.75mg/l. Low DO was recorded at the locations ‘’Maremiabiet’’ West Gojjam prison area and Felege Hiwot Referral Hospital. This result was similar with a study conducted on assessment of physicochemical characteristics and suggested restoration measures for Pushkar Lake Ajmer Rajasthan, India 2008 (18) where the dissolved oxygen varied from 4.1 – 7.3 mg/l. Another study conducted on variations of water quality in urban river of Nigeria 2013, the DO concentration ranges from 0.8 to 7.4mg/l. The main reason for low DO was reported as dumping of waste from agricultural practice such as piggery, fish farm, snailry, Wastewater discharge and organic waste dumped from abattoir, indiscriminate dumping of waste from marketing center were the main source of pollution and contributing factor for low DO level in the rivers (19). Changes in dissolved oxygen concentrations can be an early indication of undesirable conditions in physical, chemical and biochemical factors in the water bodies (8). In the current study low dissolved oxygen level, in the two locations may be associate to loading of sewage and other waste directly in to the Lake. The survey result supports how the condition is critical in these particular locations. Biochemical Oxygen Demand (BOD): In this study the BOD test was investigated within the range of 3.2 mg/l in less impacted area of the sampling stations and 23.7mg/l in highly stressed areas of sampling locations. Low BOD result was recorded at location 3 known as Kibran area selected as reference site. Higher BOD result was recorded in areas with highly stressed locations Marmiabiet or West Gojjam prison area and Felege Hiwot
  • 6. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 93 Referral Hospital. The UK Royal commission on sewage disposal in 1915 observed that unpolluted rivers rarely had BOD value of more than 2 mg/l and could accept added pollution up to a total BOD of 4 mg/l without apparent determent. This gave to raise the maximum permissible BOD of 20 mg/l in a sewage effluent entering a watercourse with an 8:1 dilution fresh water (26). In this study the BOD level particularly in selected locations was found very high even the permissible level of effluent. The main reason may associate to crude dumping of waste and untreated wastewater loading. The survey report supports how the condition in these particular locations was very critical and the result was coinciding with the current physical condition. Bacteriological analysis: In this study the total coliform count was found over 180 /100 ml in four locations. Out of the four positive samples analyzed for confirmative test, three sample were found positive for Escherichia coli type one (E.coli type one). E.coli was not isolated around Kibran area selected as reference site. The presence of E. coli is a good evidence for recent contamination of Human faeces loaded into the lake through connection of sewer lines with surface drainage system and very close siltation of pit latrines into the Lake. Sanitary survey: Sanitary survey in water quality analysis is a best mechanism that enables to evaluate the condition and to demonstrate the real picture of pollution status. The survey report clearly indicates the crude dumping of waste and the way how the lake is being polluted from different institutions and service providing centers. The survey also enables to identify the conditions that enhance siltation because of wetland tillage and construction activities. The sanitary survey report and the laboratory findings clearly indicated in the indexed figure, which shows the quality of Lake Tana, bound to Bahirdar city Administration is critically impaired. 5. Conclusion The findings of this study showed that the water quality of Lake Tana bound to Bahirdar City Administration was found unsatisfactory because of pollutants loaded into the lake. The sanitary survey report signifies how the condition is serious around the southern region of Lake Tana. Indiscriminate dumping of solid waste, connection of untreated sewage into the surface runoff drainage system and other anthropogenic activities attribute in deteriorating the quality of the lake. The under construction runoff drainage across Bata church and the tillage of the natural wetland may result serious effect in siltation load. 6. Author’s contribution Dagnew A. Ewnetu, was responsible for generating the concept of this research paper, literature review and organization, preparation of draft research proposal document, organizing data collection process, and preparation of draft data analysis and interpretation. Bikes D. Bitew is participated in research topic preparation process, proposal research design process, data analysis, and interpretation process. Daniel H. Chercos participated in proposal research design process, data analysis, and presentation and interpretation process of result, preparation of scientific paper or the manuscript, and corresponding author of the manuscript. All the authors read and approve the draft manuscript. 7. Competing interests The authors declare that they have no competing interests. 8. Acknowledgments We would like to address our special thanks to the University of Gondar for approving ethical review Amhara Water and Energy Development Bureau, The school of Water and Civil Engineering, Bahirdar University, and Amhara Regional Health and Research Laboratory Center for their cooperation and allowing us to use the water quality laboratory and theirs analytical experts. References Smith VH. Eutrophication of freshwater and coastal marine ecosystems: a global problem. Environmental science and pollution research international. 2003;10(2):126-39. PubMed PMID: 12729046. Epub 2003/05/06. eng. Lair GJ ZF, Fiebig M, Gerzabek MH, van Gestel CA, Hein T, Hohensinner S, Hsu P, Jones KC, Jordan G, Koelmans AA, Poot A, Slijkerman DM, Totsche KU, Bondar-Kunze E, Barth JA. How do long-term development and periodical changes of river-floodplain systems affect the fate of contaminants? Results from European rivers.. Environ Pollut. 2009 2009 Jul 14.;157(12):3336-46.DE. N. Sustainable microbial water quality monitoring programme design using phage-lysis and multivariate techniques. . Sci Total Environ. 2011 409(24):5188 - 95. Epub 2011 Oct 2. Sci Total Environ. Kagalou I PE, Leonardos I.
  • 7. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 94 Long term changes in the eutrophication process in a shallow Mediterranean lake ecosystem of W. Greece: response after the reduction of external load.. J Environ Manage. 2008 2007 Mar 26.;87(3):497-506. Dodds WK BW, Eitzmann JL, Pilger TJ, Pitts KL, Riley AJ, Schloesser JT, Thornbrugh DJ. Eutrophication of U.S. freshwaters: analysis of potential economic damages.. Environ Sci Technol 2009 43(1):12-9. Bureau ANRSFaED. Population size by Sex and Age Group and Urban Rural, Bahir City Administration, 2012 ADSWE. Lake Tana and Its Environs Tourism and Transport Strategic Planning Project: . 2011.Ballance JBaR. DESIGNING A MONITORING PROGRAMME. In: Meybeck MaM, editor. Water Quality Monitoring A practical guide to the design and implementation of freshwater quality studies and monitoring programmes London: E&FN Spon, an imprint of Chapman & Hall,; 1996. p. 3.7.2. George Bowman RM. BOD Analyssis Basics and Practical. Wisconcin State Wisconsin Laboratory of Hygiene. UNEP G. Global Drinking Water Quality Index Development and Sensitivity Analysis Report. Burlington, Ontario, L7R 4A6 CANADA: UNEP, 2007. CCME CCoMfE. Canadian Water Quality Index. Newfoundeland and Labrador: CCME; 2005. Josef A. Salvato PE. D. Control of Communicable and certain noninfectious Disease In: Glen Nemerow LB, editor. Environmental Engineering Fivth ed. New Jersey: Johon Wiley and Sons, Inc Hobeken; 2003. Alan C.Twort DDRaMJB. Chemistry, Microbiology and Biology of water. In: Veatch BBA, editor. Water Supply. Fivth ed. Great Britain Arnold; 2000. p. 222. Chinn TD. Water Supply In: . In: Nelson L. Nemerow FJA, Patrick Sullivan and Joseph A. Salvato, editor. Environmental Engineering, Water, Wastewater, Soil and Ground Water Treatment and Remediation. 6th ed. Jursey and Canada: Wiley; 2009. p. 1. James K. Edzwald JET. Chemical Principles, source water composition and water shade protection. 2011. In: Water Quality and Treatment, A hand book on drinking water [Internet]. New York, Chicago: Mc Graw Hill, American Water Works association; [3 - 1]. Spellman FR. Characteristics of water. In: Spellman FR, editor. Hand Book of Water, Wastewater, Treatment Plant Operations. Boca Raton, New York: LEWIs Publishers, A CRC Press Company; 2003. p. 10 - 1. David A. Vaccari. SUSTAINABILITY AND THE PHOSPHORUS CYCLE: INPUTS, OUTPUTS, MATERIAL FLOW, AND ENGINEERING Environmental Engineer: Applied Research and Practice, American Acadamy of Environmental Engineers. 2011;12:1. ASaNM. MP. Assessment of physichochemical characteristics and suggested restoration measures for Pushkar Lake, Ajmer Rajasthan, India. 2008; the 12th World lake conference:1518 - 29. Oginni FA. Variations in the Water Quality of an Urban River in Nigeria Scientific Research. 2013;2:81 - 91. published online. Gloria B. Post TBA, Perry D. Cohon. Health and Aesthethic Aspects of Drinking Water. 2011. In: Water Quality and Treatment [Internet]. Mc Graw Hill, American Woter Works Association; [2 - 41]. WHO WHO. Guideline for Drinking Water Quality. Chemical Fact Sheet. Malta Gutenberg: WHO; 2011. p. 398. Organization WH. Nitrate and Nitrite in Drinking-water, Background document for development of WHO Guidelines for Drinking-water Quality. 2011. Alaa G. M. Osman1, Werner Kloas2. Water Quality and Heavy Metal Monitoring in Water, Sediments, and Tissues of the African Catfish Clarias gariepinus (Burchell, 1822) from the River Nile. Journal of Environmental Protection 2010;1:389 - 400. WHO WHO. Guideline for drinking water quality Acceptability aspects: Taste,ogour and appearance. Malta, Gutenberg: WHO Publication Catalogue; 2011. Jamees K. Edzwald JET. Chemical Principles Source Water Composition and Watershade Protection. In: Edzwald JK, editor. Water Quality and Treatment. SIxth ed. New York, Chicago: McGraw Hill American Water Works Association; 2011. p. 3-2. Alan C. Twort DDRaMJB. Chmistry, Microbiology and Biology of water. 2000. In: Water Supply [Internet]. Butterworth Heinman, Binnie Black and Veach, IWA publishers. 5th [196].
  • 8. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 95 Table 1 Water quality summary result of Lake Tana bound to Bahirdar City Administration from June 7 - July 19/2013 . Parameters Unit Min Max Range Mean SD WHO Guideline EU/EEC pH 6.48 8.34 1.86 7.41 0.46 6.5 - 8.5 6.5 -8.5 Temperature o c 20.20 25.60 5.40 22.80 1.19 25o c** Conductivity µScm-1 * 84.00 230.00 146.00 171.42 23.53 1492 - TDS mg/l 50.00 138.00 88.00 102.54 14.07 1000 - Turbidity NTU 1.54 43.30 41.76 18.70 9.00 5 4 Nitrate mg/l 1.10 12.05 10.95 6.18 3.24 50 50 Nitrite mg/l 0.01 0.32 0.31 0.07 0.07 3 0.01-0.03 Ammonia mg/l 0.08 0.62 0.54 0.24 0.17 0.2 –1.5** Phosphate mg/l 0.02 2.82 2.80 0.43 0.70 0.5 – 0.7** Phosphorous mg/l 0.01 0.92 0.91 0.14 0.11 0.005 – 0.01 Total Alkalinity mg/l 78.00 159.00 81.00 99.31 24.92 No reference Sulfate mg/l 0.00 10.00 10.00 3.75 3.17 250 250 Irion mg/l 0.05 0.80 0.75 0.37 0.18 0.3 0.2 Manganese mg/l 0.10 1.30 1.20 0.58 0.37 0.4 0.05 *µScm-1 (micro Siemens per centimeter) **EEC – European Economic Commission Source: - Environmental Protection Agency (EPA) of Ireland Parameters of water quality interpretation and standards, 2001 EU – European Union Source: - UNESCO, WHO, UNEP ©1992 1996 – water quality assessment, A guide to use of Biota sediments and water in Environmental Monitoring 2nd edition. Table 2 Bacteriological analysis test result of Lake Tana at selected locations From June 2013. Locations Total coliform org/100ml Escherichia coli (E.coli type 1) Method of analysis Shum Abo Recreational area > 180/100ml present Multiple tube Maremiabiet > 180/100ml present Multiple tube Kibran Area > 180/100ml Absent Multiple tube Felege Hiwot Referral Hospital > 180/100ml Present Multiple tube
  • 9. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 96 Table 3 Summary of Sanitary survey report conducted at Lake Tana Bound to Bahirdar City Administration June 2013. S N Potential pollutant sources and observed changes Observed Yes No 1 Is there direct waste discharge mixing index into the lake? 7(87.5%) 1(12.5%) 2 Is there a practice of dumping solid waste nearby the lake? 7(87.5&) 1 (12.5%) 3 Is there industrial waste discharge into the lake? 0 8(100%) 4 Is there a practice of connecting sewer line into surface runoff drainage system? 7(87.5%) 1(12.5%) 5 Is there a chance of oil spill into the lake? 8(100%) 0 6 Is there undesirable vegetation growth in the lake? 7(87.5%) 1(12.5%) 7 Is there any filthy and unaesthetic condition in the visited site? 7(87.5%) 1(12.5%) 8 Is dead fish observed? 0 8(100%) 9 Is there fish and other animal offal or carcass observed in the visited site? 7(87.5%) 1(12.5%) 10 Is there any risky condition to pollution that threatens aquatic life? 8(87.5%) 1(12.5%) 11 Is the visited site found impaired for recreation? 7(87.5%) 1(12.5%) Category of risk of pollution Category to risk of pollution Number % No risk 0 0 Low risk 1 12.5% High risk 5 62.5% Very high risk 2 25% Total 8 100% Figure 1 Figure 2 Canadian Water Quality Index of Lake Tana bound To Bahirdar City Administration from June 7 - July19/2013.
  • 10. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol.4, No.13, 2014 97 Figure legends Figure 3 Canadian Water Quality Index of Lake Tana bound To Bahirdar City Administration from June 7 - July19/2013. . WQI (water quality index): the water quality results based on common parameters. Excellent: WQI value, 95-100, Water quality is protected with a virtual absence of threat or impairment; conditions very close to natural or pristine levels; these index values can only be obtained if all measurements are within objectives virtually all of the time. Good: WQI value, 80-94, Water quality is protected with only a minor degree of threat or impairment; conditions rarely depart from natural or desirable levels. Fair: WQI value 65-79, Water quality is usually protected but occasionally threatened or impaired; conditions sometimes depart from natural or desirable levels. Marginal: WQI value 45-64, Water quality is frequently threatened or impaired; conditions often depart from natural or desirable levels Poor: WQI value, 0-44, Water quality is almost always threatened or impaired; conditions usually depart from natural or desirable levels.
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