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4S6
Welcome To the Chemistry   World~
Cl-
          Zn2+

                     Cl-




1 ZnCl2    =   1 Zn2+ ion    2 Cl- ions
3.4 THE MOLE AND THE VOLUME

 - the molar volume of a gas is the volume
  occupied by one mole of the gas or particles of
  gas
 - one mole of any gas always has the same volume
  under the same temperature and pressure.
 - the molar volume of any gas at STP is
     22.4 dm3mol-1
  ________________.
 -Standard Temperature and Pressure (STP) is
                                               0°C
  the conditions where temperature is ______ and
                   1 atm
  pressure is ________.
 Example:
                              22.4 dm3mol-1
 a. 1 mole of oxygen gas = _____________
                                     22.4 dm3mol-1
 b. 1 mol of carbon dioxide gas= _____________
                                 22.4 dm3mol-1
 c. 1 mol of ammonia gas = _______________
 - the molar volume of any gas at room temperature
                     24 dm3mol-1
  is ________________.
 -At room temperature is the conditions where
                   25°C                        1 atm
  temperature is ______ and pressure is ________.
 Example:
                                 24 dm3mol-1
 a. 1 mole of oxygen gas = _____________
                                        24 dm3mol-1
 b. 1 mol of carbon dioxide gas= _____________
                                  24 dm3mol-1
 c. 1 mol of ammonia gas = _______________
STP=22.4 dm3mol-1
                            Volume
                                          RTP =24 dm3mol-1



                Number of        Molar
                Moles            volume




(More Van More Vibrate)
EXAMPLE 1:


   What is the volume of 2.5mol helium gas at
    s.t.p?     22.4 dm3mol-1


Volume of gas
= No. of moles x molar volume
= 2.5 mol x 22.4dm3mol-1
= 56 dm3
EXAMPLE 2:


   What is the number of moles in 240 cm3 oxygen
    gas at r.t.p?       24 dm3mol-1


number of moles
= volume of the gas
  Molar Volume
= 0.24 dm3
  24 dm3 mol-1
= 0.01 mol              240 cm3   =   240
                                      1000
                                  =   0.24dm3
EXAMPLE 3:


 Calculate the volume of the gases at room
  temperature and pressure that contains:
a. 12 x 1022 C3H8 molecules
b. 2.4 x 1023 N2 molecules
(1 mole of gas occupies 24 dm3at room temperature;
  NA= 6 x 1023 )
CALCULATE THE VOLUME OF THE GASES AT ROOM
TEMPERATURE AND PRESSURE THAT CONTAINS:
                             24 dm3mol-1

A. 12 X 1022 C3H8 MOLECULES



Number of mole
= 12 x 1022
  6 x 1023
= 0.2 mol

Volume
= 0.2 x 24dm3
= 4.8dm3
CALCULATE THE VOLUME OF THE GASES AT ROOM
TEMPERATURE AND PRESSURE THAT CONTAINS:
B. 2.4 X 1023 N2 MOLECULES



Number of mole
= 2.4 x 1023
  6 x 1023
= 0.4 mol

 Volume
= 0.4 x 24dm3
= 9.6 dm3
ANSWER

a) Number of mole = 12 x 1022
                     6 x 1023
                      = 0.2 mol
1 mole of gas occupies 24dm3 at room temperature
0.2 mole gas occupies 0.2 x 24dm3 = 4.8dm3


b)   Number of mole = 2.4 x 1023
                        6 x 1023
                      = 0.4 mol
1 mole of gas occupies 24dm3 at room temperature
0.4 mole gas occupies 0.4 x 24dm3 = 9.6 dm3
EXAMPLE 4:

 a. What is the volume of 4g of oxygen gas in cm3 at
  STP?
 b. A sample of hydrogen gas contains molecules.
  Find the mass of the hydrogen gas.
 c. How many molecules are there in 7840 cm3 of
  ammonia gas in STP?
WHAT IS THE VOLUME OF 4G OF OXYGEN GAS IN
CM3 AT STP?



Number of mole
= 4g
  32gmol-1
= 0.125 mol
 Volume

= 0.125mol x 22.4 dm3 mol-1

= 2.8dm3
= 2800cm3
A SAMPLE OF HYDROGEN GAS CONTAINS 1.806 X
1023 MOLECULES. FIND THE MASS OF THE
HYDROGEN GAS.



Number of mole = 1.806 x 1023
                   6.02 x 1023
                = 0.3 mol

mass of the hygrogen gas
= 0.3 mol x 2gmol-1
= 0.6g
C.HOW MANY MOLECULES ARE THERE IN 7840
CM3 OF AMMONIA GAS IN STP?




7840cm3 = 7840÷ 1000= 7.84dm3
Number of mole
= 7.84dm3
   22.4dm3mol-1
= 0.35 mol

 Number of molecules
= 0.35 mol x 6.02 x 1023
= 2.107 x 1023 molecules
a. Number of mole = 4g
                                 32gmol-1
                              = 0.125 mol
 0.125 mol of oxygen gas = o.125mol x 22.4 dm3mol-1   = 2.8dm3 = 2800cm3

b) Number of mole = 1.806 x 1023
                       6.02 x 1023
                              = 0.3 mol
 0.3 mol of hydrogen gas = 0.3 mol x 2gmol-1 = 0.6g
c) 7840cm3 = 7840÷ 1000= 7.84dm3
    Number of mole = 7.84dm3
                        22.4dm3mol-1
                              = 0.35 mol
0.35   mol of ammonia gas = 0.35 mol x 6.02 x 1023 = 2.107 x 1023
                                                      molecules
CHEMISTRY FORMULAE

   A CHEMICAL FORMULA is a representation of a
        Chemical substance
    _______________________ using symbols of the
    elements and subscript numbers to show the
    numbers of each type of atoms that are present in
    the substance.
The overall charge
CHEMICAL FORMULA
                       must be   0
sodium chloride
        +          -
   Na         Cl

        NaCl
The overall charge
CALSIUM FLOURIDE
                       must be   0


        2+         -
   Ca         F

       CaF2
The overall charge
MAGNESIUM CHLORIDE
                         must be   0


        2+           -
   Mg         Cl

        MgCl2
The overall charge
MAGNESIUM SULPHATE
                     must be   0

                               Put in
        2+              2-     simplest ratio

   Mg         SO4

      MgSO4
The overall charge
ALUMINIUM OXIDE
                       must be   0


         3+           2-
   Al             O

        Al2O3
The overall charge
AMMONIUM SULFATE
                   must be   0


        +           2-
 NH4           SO4

 (NH4 )2 SO4
The overall charge
LEAD (II) HYDROXIDE
                      must be   0


         2+           -
   Pb OH
   Pb ( OH )2
NAMING
 Naming of cations of fixed oxidation state
 Naming of cations of variable oxidation state



 Naming of anions – ide
 ate- (Fat) – more oxygen

 Ite – (Fit )– less oxygen
CATIONS OF FIXED OXIDATION STATE
   Sodium ion (Na+)
    Eg: Sodium chloride (NaCl)

   Magnesium ion (Mg2+)
    Eg: Magnesium oxide (MgO)

   Calcium ion(Ca2+)
    Eg: Calcium carbonate (CaCO3)

   Aluminium ion (Al3+)
    Eg: Aluminium oxide (Al2O3)
CATIONS OF VARIABLE OXIDATION STATE
 Iron(ll) ion (Fe2+)
Eg: Iron(II) chloride (FeCl2)

 Iron(lll) ion (Fe3+)
Eg: Iron(III) chloride (FeCl3)

 Copper (l) ion (Cu+)
Eg: Copper(I) oxide (Cu2O)

 Copper (ll) ion(Cu2+)
Eg: Copper(II) oxide (CuO)

 Lead(ll) ion(Pb2+)
Eg: Lead(II) oxide (PbO)

 Lead(lV) ion (Pb4+)
Eg: Lead(IV) oxide (PbO2)
PREFIXES
 Mono     1
 Di       2
 Tri      3
 Tetra    4
 Penta    5
NAMING OF CHEMICAL COMPOUND

Fe2O3


                    O 2-
    Fe3+


         Iron(III) oxide
NAMING OF CHEMICAL COMPOUND

 PbO2

                    O 2-
    Pb4+


       Lead (IV) oxide
NAMING OF CHEMICAL COMPOUND
 ZnO       Zinc oxide
 NaNO3
          Sodium nitrate
 SO3    Sulphur trioxide
 Fe2O3 Iron(III) oxide
 CCl4  Carbon tetrachloride
 N2O4 Dinitro tetraoxide
 CaCl2  Calcium chloride
 PbI2  Lead(ll) Iodide
 PbO2   Lead (IV) oxide
 K2CO3   Potassium carbonate
 PCl5   Phosphorus pentachloride
PASS UP ON MONDAY(4/3/2013)
          Past year paper

                  Spotlight access 3.4

                    Spotlight access 3.5,
                    question8 and 9

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Chemistry Formulae and Naming

  • 1. 4S6 Welcome To the Chemistry World~
  • 2. Cl- Zn2+ Cl- 1 ZnCl2 = 1 Zn2+ ion 2 Cl- ions
  • 3. 3.4 THE MOLE AND THE VOLUME  - the molar volume of a gas is the volume occupied by one mole of the gas or particles of gas  - one mole of any gas always has the same volume under the same temperature and pressure.
  • 4.  - the molar volume of any gas at STP is 22.4 dm3mol-1 ________________.  -Standard Temperature and Pressure (STP) is 0°C the conditions where temperature is ______ and 1 atm pressure is ________.  Example: 22.4 dm3mol-1  a. 1 mole of oxygen gas = _____________ 22.4 dm3mol-1  b. 1 mol of carbon dioxide gas= _____________ 22.4 dm3mol-1  c. 1 mol of ammonia gas = _______________
  • 5.  - the molar volume of any gas at room temperature 24 dm3mol-1 is ________________.  -At room temperature is the conditions where 25°C 1 atm temperature is ______ and pressure is ________.  Example: 24 dm3mol-1  a. 1 mole of oxygen gas = _____________ 24 dm3mol-1  b. 1 mol of carbon dioxide gas= _____________ 24 dm3mol-1  c. 1 mol of ammonia gas = _______________
  • 6. STP=22.4 dm3mol-1 Volume RTP =24 dm3mol-1 Number of Molar Moles volume (More Van More Vibrate)
  • 7. EXAMPLE 1:  What is the volume of 2.5mol helium gas at s.t.p? 22.4 dm3mol-1 Volume of gas = No. of moles x molar volume = 2.5 mol x 22.4dm3mol-1 = 56 dm3
  • 8. EXAMPLE 2:  What is the number of moles in 240 cm3 oxygen gas at r.t.p? 24 dm3mol-1 number of moles = volume of the gas Molar Volume = 0.24 dm3 24 dm3 mol-1 = 0.01 mol 240 cm3 = 240 1000 = 0.24dm3
  • 9. EXAMPLE 3:  Calculate the volume of the gases at room temperature and pressure that contains: a. 12 x 1022 C3H8 molecules b. 2.4 x 1023 N2 molecules (1 mole of gas occupies 24 dm3at room temperature; NA= 6 x 1023 )
  • 10. CALCULATE THE VOLUME OF THE GASES AT ROOM TEMPERATURE AND PRESSURE THAT CONTAINS: 24 dm3mol-1 A. 12 X 1022 C3H8 MOLECULES Number of mole = 12 x 1022 6 x 1023 = 0.2 mol Volume = 0.2 x 24dm3 = 4.8dm3
  • 11. CALCULATE THE VOLUME OF THE GASES AT ROOM TEMPERATURE AND PRESSURE THAT CONTAINS: B. 2.4 X 1023 N2 MOLECULES Number of mole = 2.4 x 1023 6 x 1023 = 0.4 mol Volume = 0.4 x 24dm3 = 9.6 dm3
  • 12. ANSWER a) Number of mole = 12 x 1022 6 x 1023 = 0.2 mol 1 mole of gas occupies 24dm3 at room temperature 0.2 mole gas occupies 0.2 x 24dm3 = 4.8dm3 b) Number of mole = 2.4 x 1023 6 x 1023 = 0.4 mol 1 mole of gas occupies 24dm3 at room temperature 0.4 mole gas occupies 0.4 x 24dm3 = 9.6 dm3
  • 13. EXAMPLE 4:  a. What is the volume of 4g of oxygen gas in cm3 at STP?  b. A sample of hydrogen gas contains molecules. Find the mass of the hydrogen gas.  c. How many molecules are there in 7840 cm3 of ammonia gas in STP?
  • 14. WHAT IS THE VOLUME OF 4G OF OXYGEN GAS IN CM3 AT STP? Number of mole = 4g 32gmol-1 = 0.125 mol Volume = 0.125mol x 22.4 dm3 mol-1 = 2.8dm3 = 2800cm3
  • 15. A SAMPLE OF HYDROGEN GAS CONTAINS 1.806 X 1023 MOLECULES. FIND THE MASS OF THE HYDROGEN GAS. Number of mole = 1.806 x 1023 6.02 x 1023 = 0.3 mol mass of the hygrogen gas = 0.3 mol x 2gmol-1 = 0.6g
  • 16. C.HOW MANY MOLECULES ARE THERE IN 7840 CM3 OF AMMONIA GAS IN STP? 7840cm3 = 7840÷ 1000= 7.84dm3 Number of mole = 7.84dm3 22.4dm3mol-1 = 0.35 mol Number of molecules = 0.35 mol x 6.02 x 1023 = 2.107 x 1023 molecules
  • 17. a. Number of mole = 4g 32gmol-1 = 0.125 mol 0.125 mol of oxygen gas = o.125mol x 22.4 dm3mol-1 = 2.8dm3 = 2800cm3 b) Number of mole = 1.806 x 1023 6.02 x 1023 = 0.3 mol 0.3 mol of hydrogen gas = 0.3 mol x 2gmol-1 = 0.6g c) 7840cm3 = 7840÷ 1000= 7.84dm3 Number of mole = 7.84dm3 22.4dm3mol-1 = 0.35 mol 0.35 mol of ammonia gas = 0.35 mol x 6.02 x 1023 = 2.107 x 1023 molecules
  • 18. CHEMISTRY FORMULAE  A CHEMICAL FORMULA is a representation of a Chemical substance _______________________ using symbols of the elements and subscript numbers to show the numbers of each type of atoms that are present in the substance.
  • 19. The overall charge CHEMICAL FORMULA must be 0 sodium chloride + - Na Cl NaCl
  • 20. The overall charge CALSIUM FLOURIDE must be 0 2+ - Ca F CaF2
  • 21. The overall charge MAGNESIUM CHLORIDE must be 0 2+ - Mg Cl MgCl2
  • 22. The overall charge MAGNESIUM SULPHATE must be 0 Put in 2+ 2- simplest ratio Mg SO4 MgSO4
  • 23. The overall charge ALUMINIUM OXIDE must be 0 3+ 2- Al O Al2O3
  • 24. The overall charge AMMONIUM SULFATE must be 0 + 2- NH4 SO4 (NH4 )2 SO4
  • 25. The overall charge LEAD (II) HYDROXIDE must be 0 2+ - Pb OH Pb ( OH )2
  • 26. NAMING  Naming of cations of fixed oxidation state  Naming of cations of variable oxidation state  Naming of anions – ide  ate- (Fat) – more oxygen  Ite – (Fit )– less oxygen
  • 27. CATIONS OF FIXED OXIDATION STATE  Sodium ion (Na+) Eg: Sodium chloride (NaCl)  Magnesium ion (Mg2+) Eg: Magnesium oxide (MgO)  Calcium ion(Ca2+) Eg: Calcium carbonate (CaCO3)  Aluminium ion (Al3+) Eg: Aluminium oxide (Al2O3)
  • 28. CATIONS OF VARIABLE OXIDATION STATE  Iron(ll) ion (Fe2+) Eg: Iron(II) chloride (FeCl2)  Iron(lll) ion (Fe3+) Eg: Iron(III) chloride (FeCl3)  Copper (l) ion (Cu+) Eg: Copper(I) oxide (Cu2O)  Copper (ll) ion(Cu2+) Eg: Copper(II) oxide (CuO)  Lead(ll) ion(Pb2+) Eg: Lead(II) oxide (PbO)  Lead(lV) ion (Pb4+) Eg: Lead(IV) oxide (PbO2)
  • 29. PREFIXES  Mono 1  Di 2  Tri 3  Tetra 4  Penta 5
  • 30. NAMING OF CHEMICAL COMPOUND Fe2O3 O 2- Fe3+ Iron(III) oxide
  • 31. NAMING OF CHEMICAL COMPOUND PbO2 O 2- Pb4+ Lead (IV) oxide
  • 32. NAMING OF CHEMICAL COMPOUND  ZnO Zinc oxide  NaNO3 Sodium nitrate  SO3 Sulphur trioxide  Fe2O3 Iron(III) oxide  CCl4 Carbon tetrachloride  N2O4 Dinitro tetraoxide  CaCl2 Calcium chloride  PbI2 Lead(ll) Iodide  PbO2 Lead (IV) oxide  K2CO3 Potassium carbonate  PCl5 Phosphorus pentachloride
  • 33. PASS UP ON MONDAY(4/3/2013) Past year paper Spotlight access 3.4 Spotlight access 3.5, question8 and 9