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LMS
Laser Diamond Marking System

   Diamond Marking Principles




            Emre Teoman
           Dana Lee Church
             Version 2.0
            February 2003
TeoSys Engineering LLC, Diamond Marking Principles


                                                  Table of Contents

1.0     Marking Diamonds with Lasers ................................................................................ 3
  1.1    Laser Interaction With Diamonds.......................................................................... 3
  1.2    Cracking, Thermal Ablation, and Other Destructive Issues .................................. 4
2.0     The Laser Beam and Laser Interaction with the Diamond ....................................... 4
3.0     Diamond Marking System Design............................................................................ 5
4.0     Diamond Motion....................................................................................................... 6
5.0     Mark Quality and Control......................................................................................... 8
6.0     Summation.............................................................................................................. 12




                                                       Page 2 of 12                                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles




1.0    Marking Diamonds with Lasers

The LMS is a laser based marking system. The system holds diamonds below a focused
beam of ultraviolet light. The light has been focused so tightly that it burns a small
microscopic pit onto the surface of the gem. The depth of this pit is extremely shallow
(~1 or 2 microns). The color of the pit can vary from nearly transparent to totally black.
The LMS creates characters by moving the diamond in X and Y axis while the laser is
firing. This is much like holding a pencil still, while moving the paper below it to form
characters. Marking on the girdle of a gem is the most popular use for the LMS. The
diamond can be marked over the entire diameter of the gem through a series of rotations.
The laser is kept in focus, like a camera, by moving the fixed lens, or objective, up and
down. This motion is called Z       -axis motion. In addition to moving the diamond, and the
objective, the user has many other controls at his disposal. Laser energy can be varied,
much like an artist varies the firmness by which he holds his brush. Laser spot size can
be adjusted to achieve the effect of selecting different brush widths. In addition, the laser
can be spaced to produce separate dots, or one continuous line. In a very real sense, the
LMS is much lke an artists pallet. The end result depends as much upon the skill of the
                  i
user, as well as the sophistication of the technology.

        1.1     Laser Interaction With Diamonds
Diamonds are transparent to wavelengths well beyond those visible by the human eye.
The chart below details the typical wavelength of light that can be obtained from
commercially available lasers. Diamonds are transparent to laser light from .200µm in
the UV to well past 10µm in the Infra Red. This transparency makes it difficult for light
to be absorbed onto the surface to form a legible mark. The LMS solves this problem by
emitting light in the deep UV (193nm or .193µm). At this wavelength one can mark a
diamond, with little transmission of light into the body of the gem.


                                    Laser Spectrum
             .1µm .2µm .3µm .4µm .5µm .6µm .7µm         1 µm         10 µm   100 µm




                  Ultra Violet     Visible                     Infra Red
                 (.1µm - .4µm)   (.4µm - .7µm)             (.7µm - 100µm)




This lack of transmission is critical since it means that the laser can mark without the
need for any other process or preparation. Other laser marking systems need to ‘ink’ or
prepare the diamond before they begin marking. This is done to allow the light to be
absorbed by the ink, and a mark formed by the heat generated by the process. The LMS
doesn’t need to generate this type of thermal stress to mark, and therefore presents less
risk to the gem during the marking process.



                                         Page 3 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles


        1.2    Cracking, Thermal Ablation, and Other Destructive Issues
The 193nm Excimer laser ablates a mark on the diamond in a ‘cold’ process. This
process does not appreciably affect the area around the mark. In the picture below one
can see that the surrounding material shows little sign of thermal stress after exposure to
laser energy.


           Heat
        Affected                                                             Mark Area
           Area



      Unaffected
           Area




With most other lasers the area of thermal stress is nearly as large as the mark itself.
Having said this, the 193nm Excimer is not completely free from thermal effects. One
must be careful in overlapping marks at the same point, near or on a fractured area. It is
possible to initiate a crack, or enlarge a crack with excessive energy, and extended laser
duration with some stones. In general, however, it takes quite a large amount of energy
and a long dwell time for the 193nm Excimer to risk opening a crack in a diamond.

2.0      The Laser Beam and Laser Interaction with the Diamond

The laser beam is not a straight shaft of light as some science fiction movies would have
us believe. The beam emanating from the objective of the LMS is actually a complex
array of converging and diverging rays.


                                                        Objective




                                                  Anterior (In front)

                                                  Smallest Spot

                                                  In Focus Area


                                                 Posterior (Behind)



                                       Page 4 of 12                                 Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles


The LMS is usually configured to mark in the area just past the smallest spot, or greatest
laser intensity. This is done to produce the best overall spot quality. The area that is
considered to be in focus is very small, about as small as the diameter of human hair. To
ensure that the laser is always in focus the objective is moved up and down on what we
call the Z -stage. The marks are made by moving the diamond with the laser firing, while
under the diamond.

3.0    Diamond Marking System Design

The typical diamond marking system comprises a laser, optics, a visualization system, a
motion system, a part holding jig, and a structure. The numbers of possible design
combinations are varied and myriad. All laser-marking systems, however, have these
basic elements.




                                VIDEO


          LASER                           Optics                      COMPUTER


                                         Work Surface

                             MOTION
                             MOTIO
                             N



The lasers used to mark diamonds are often pulsed lasers. Pulsed lasers generate short
bursts of energy, high enough to establish a mark and form carbon deposits. These pulses
are emitted at regular intervals. The rate of light generation is called pulse repetition rate
(PRR), or pulse repetition frequency (PRF). The higher the PRF, the higher the average
energy transferred to the work surface. The strength of each individual pulse can also be
adjusted. With Excimer lasers the pulse energy can be increased to provide greater
marking strength. Thus, there are generally two ways to increase marking strength,
greater pulse energy, or greater pulse rate.




                                        Page 5 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles




               Laser Source

                                            Laser Pulses




                              Typical Pulsed Laser Source



                                                       Pulse
   L                                                   duration
   A
   S
   E
   R
   P                                                                        Peak
   O                                                                        power
   W
   E
   R                            TIME

                           Laser Pulses and Energy Over Time


4.0    Diamond Motion

As stated earlier, the laser beam only moves up and down. A mark is made by moving
the Diamond back and forth, as well as l ft and right while the laser beam is moving up
                                               e
and down. In addition to left, right, back, front, and up and down, the Diamond can be
rotated to expose various sections of the girdle during marking.




                                     Page 6 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles



                                                  Objective

       Z - Axis                                Laser                                Z - Axis
                                               Beam
                             U Rotation



                                              U Rotation




                  X - Axis                                         Y - Axis

                    (a)                                              (b)



The left and right motion is called X-axis motion. The back and forth motion is called Y-
axis motion. Up and down is called Z-axis motion. Rotation is called U-axis motion.




                                               Diamond

      Rotation



                                                                           X-axis




                                                         Y-axis


The X and Y-axis stages are the largest and most critical to the motion system. The
typical characters made are less than the width of a single human hair. The motion
system must be able to move in steps over one hundred times smaller than the width of a
single human hair in order to make smooth and legible marks.




                                      Page 7 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles


5.0    Mark Quality and Control

As stated earlier, marking diamonds is still more art than science. Like an artists pallet,
once can control many different parameters of the LMS to achieve the desired result.

                    Methods of Controlling Mark Quality & Result

        Type of Control     Result on Mark Quality
        Laser Energy        Dots get darker with increased energy
        Shot Spacing        Lines get darker with decreased spacing
        Beam Size           Smaller and lighter marks with smaller size settings.
        Repeating Mark      Mark gets darker, and a little wider
        Slow Motion         Cleaner characters, better definition
        Scaling             Make marks bigger and smaller
        Font                Different fonts have different styles & darkness

Laser energy is the primary way to increase mark darkness. With low energy the mark is
nearly transparent. At higher energies the bottom of the mark begins to form carbon
deposits. These deposits absorb light and make the mark look dark. Under certain
circumstances the carbon can be removed. This can be accomplished by using very
strong chemical treatments. Carbon can also often be removed from marks made with
low energy setting.




             Low                         Medium                           High
            Energy                       Energy                          Energy




      No Carbonization                    Some                             High
                                       Carbonization                   Carbonization




Shot spacing will also change the look of a mark. Small spots with gaps between each
spot will produce an effect similar to that of a light, fine pencil.




                                        Page 8 of 12                                   Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles




                                                           Marks
                                                     without shot
                                                          overlap


One can overlap dots to produce a dark, continuous line.




                                                                       Marks with
                                                                       shot overlap




Beam Size will also increase spot darkness, much like power increases, however with a
more dramatic increase in spot size.




                            Increasing Laser Power



                             Increasing Beam Size

                                        Page 9 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles




Below is another example of changes in beam size affecting character quality.


                 Example of how beam size changes mark quality


         Power = 4
         Beam Size = 18.5



         Power = 4
         Beam Size = 17.5




Because the LMS utilizes a wavelength in the deep UV one can mark over the same place
repeatedly without great concern. The software for the LMS allows the user to repeat the
same marks, over the same location, with great precision. By marking the diamond
twice, the user can increase the darkness, and size of the mark in a fashion similar to the
beam size example shown above. Repeating a mark more than twice does not
appreciably increase mark darkness, or width.

Machine rate (marking speed) can be manipulated to change marking quality.




Marking Speed
Control


                                                                        LMS Setup
                                                                        Control Screen




                                        Page 10 of 12                                  Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles


Machine rate divided     by shot spacing yields maximum pulse repetition rate (PRR). In
general, by increasing   machine rate one reduces the precision that the motion system can
produce clean, sharp     characters. Lower machine rates increase production throughput
times. It is therefore   the operator’s judgment as to the best tradeoff between speed and
quality.

One unique feature of the LMS is its ability to precisely size and position text over the
live video. Once text is entered, the user can proportionally increase the size of the text
string, or relocate its position relative to the gem. This is particularly helpful when thin
or irregularly shaped girdles are encountered. Users typically don’t create characters
smaller than 30 microns, or larger than 150 microns. The system theoretically can
operate over a much wider range. The text height refers to the maximum vertical features
of the font. Most fonts have lower case elements which are much smaller.




       Scaling
          and
      Position
      Controls




Much like a typewriter, the LMS allows the user to select from a number of fonts.

Font Style Name              Description

Cyrillic                     Cyrillic-alphabetical
Gothice                      Gothic English
Gothicg                      Gothic German
Gothici                      Gothic Italian
Greekc                       Greek font double stroked with serifs
Greeks                       Greek font single stroked with sans serifs
Italicc                      Italic font double stroked with serifs
Italict                      Italic triple stroked with serifs
Monotxt                      Monospaced text font
Romanc                       Double stroked Roman font with serifs


                                         Page 11 of 12                                 Rev. 1.0
TeoSys Engineering LLC, Diamond Marking Principles


Romand                      Double stroked Roman font with serifs for high resolution
Romans                      Single stroked Roman san serif font
Romant                      Triple stroked Roman font with serifs
Scriptc                     Double stroked script font
Scripts                     Single stroked script font
Simplex                     Single stroked font
Syastro                     Astronomical symbols
Symap                       Mapping symbols
Symath                      Math symbols
Symeteo                     Meteorological symbols
Symusic                     Music symbols
Txt                         Default text


Fonts are selected through the text information block on the main screen.               One can
choose to select the text height (in microns) on this same screen.




6.0    Summation

As stated before, marking diamonds is more art than science. Before marking on high
quality stones, it is recommended that the user practice on the glass slide fixture, or with
Cubic Zirconium test gems.        Glass slides carbonize much like diamonds.           Glass,
however, tends to crack with high energy. Cubic Zirconium gems (CZ’s) are good
practice stones for speed, font, shape and position, however CZ tends not t carbonize
                                                                                o
like diamonds.

The typical beginning user takes five or ten minutes to mark a 20-character inscription.
Experienced users should be able to mark the same 20 characters, on a typical diamond,
within one or two minutes. As one becomes comfortable with the various controls and
features of the LMS speed, quality and consistency will undoubtedly improve.




                                       Page 12 of 12                                    Rev. 1.0

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TeoSys - Diamond Marking Principles

  • 1. LMS Laser Diamond Marking System Diamond Marking Principles Emre Teoman Dana Lee Church Version 2.0 February 2003
  • 2. TeoSys Engineering LLC, Diamond Marking Principles Table of Contents 1.0 Marking Diamonds with Lasers ................................................................................ 3 1.1 Laser Interaction With Diamonds.......................................................................... 3 1.2 Cracking, Thermal Ablation, and Other Destructive Issues .................................. 4 2.0 The Laser Beam and Laser Interaction with the Diamond ....................................... 4 3.0 Diamond Marking System Design............................................................................ 5 4.0 Diamond Motion....................................................................................................... 6 5.0 Mark Quality and Control......................................................................................... 8 6.0 Summation.............................................................................................................. 12 Page 2 of 12 Rev. 1.0
  • 3. TeoSys Engineering LLC, Diamond Marking Principles 1.0 Marking Diamonds with Lasers The LMS is a laser based marking system. The system holds diamonds below a focused beam of ultraviolet light. The light has been focused so tightly that it burns a small microscopic pit onto the surface of the gem. The depth of this pit is extremely shallow (~1 or 2 microns). The color of the pit can vary from nearly transparent to totally black. The LMS creates characters by moving the diamond in X and Y axis while the laser is firing. This is much like holding a pencil still, while moving the paper below it to form characters. Marking on the girdle of a gem is the most popular use for the LMS. The diamond can be marked over the entire diameter of the gem through a series of rotations. The laser is kept in focus, like a camera, by moving the fixed lens, or objective, up and down. This motion is called Z -axis motion. In addition to moving the diamond, and the objective, the user has many other controls at his disposal. Laser energy can be varied, much like an artist varies the firmness by which he holds his brush. Laser spot size can be adjusted to achieve the effect of selecting different brush widths. In addition, the laser can be spaced to produce separate dots, or one continuous line. In a very real sense, the LMS is much lke an artists pallet. The end result depends as much upon the skill of the i user, as well as the sophistication of the technology. 1.1 Laser Interaction With Diamonds Diamonds are transparent to wavelengths well beyond those visible by the human eye. The chart below details the typical wavelength of light that can be obtained from commercially available lasers. Diamonds are transparent to laser light from .200µm in the UV to well past 10µm in the Infra Red. This transparency makes it difficult for light to be absorbed onto the surface to form a legible mark. The LMS solves this problem by emitting light in the deep UV (193nm or .193µm). At this wavelength one can mark a diamond, with little transmission of light into the body of the gem. Laser Spectrum .1µm .2µm .3µm .4µm .5µm .6µm .7µm 1 µm 10 µm 100 µm Ultra Violet Visible Infra Red (.1µm - .4µm) (.4µm - .7µm) (.7µm - 100µm) This lack of transmission is critical since it means that the laser can mark without the need for any other process or preparation. Other laser marking systems need to ‘ink’ or prepare the diamond before they begin marking. This is done to allow the light to be absorbed by the ink, and a mark formed by the heat generated by the process. The LMS doesn’t need to generate this type of thermal stress to mark, and therefore presents less risk to the gem during the marking process. Page 3 of 12 Rev. 1.0
  • 4. TeoSys Engineering LLC, Diamond Marking Principles 1.2 Cracking, Thermal Ablation, and Other Destructive Issues The 193nm Excimer laser ablates a mark on the diamond in a ‘cold’ process. This process does not appreciably affect the area around the mark. In the picture below one can see that the surrounding material shows little sign of thermal stress after exposure to laser energy. Heat Affected Mark Area Area Unaffected Area With most other lasers the area of thermal stress is nearly as large as the mark itself. Having said this, the 193nm Excimer is not completely free from thermal effects. One must be careful in overlapping marks at the same point, near or on a fractured area. It is possible to initiate a crack, or enlarge a crack with excessive energy, and extended laser duration with some stones. In general, however, it takes quite a large amount of energy and a long dwell time for the 193nm Excimer to risk opening a crack in a diamond. 2.0 The Laser Beam and Laser Interaction with the Diamond The laser beam is not a straight shaft of light as some science fiction movies would have us believe. The beam emanating from the objective of the LMS is actually a complex array of converging and diverging rays. Objective Anterior (In front) Smallest Spot In Focus Area Posterior (Behind) Page 4 of 12 Rev. 1.0
  • 5. TeoSys Engineering LLC, Diamond Marking Principles The LMS is usually configured to mark in the area just past the smallest spot, or greatest laser intensity. This is done to produce the best overall spot quality. The area that is considered to be in focus is very small, about as small as the diameter of human hair. To ensure that the laser is always in focus the objective is moved up and down on what we call the Z -stage. The marks are made by moving the diamond with the laser firing, while under the diamond. 3.0 Diamond Marking System Design The typical diamond marking system comprises a laser, optics, a visualization system, a motion system, a part holding jig, and a structure. The numbers of possible design combinations are varied and myriad. All laser-marking systems, however, have these basic elements. VIDEO LASER Optics COMPUTER Work Surface MOTION MOTIO N The lasers used to mark diamonds are often pulsed lasers. Pulsed lasers generate short bursts of energy, high enough to establish a mark and form carbon deposits. These pulses are emitted at regular intervals. The rate of light generation is called pulse repetition rate (PRR), or pulse repetition frequency (PRF). The higher the PRF, the higher the average energy transferred to the work surface. The strength of each individual pulse can also be adjusted. With Excimer lasers the pulse energy can be increased to provide greater marking strength. Thus, there are generally two ways to increase marking strength, greater pulse energy, or greater pulse rate. Page 5 of 12 Rev. 1.0
  • 6. TeoSys Engineering LLC, Diamond Marking Principles Laser Source Laser Pulses Typical Pulsed Laser Source Pulse L duration A S E R P Peak O power W E R TIME Laser Pulses and Energy Over Time 4.0 Diamond Motion As stated earlier, the laser beam only moves up and down. A mark is made by moving the Diamond back and forth, as well as l ft and right while the laser beam is moving up e and down. In addition to left, right, back, front, and up and down, the Diamond can be rotated to expose various sections of the girdle during marking. Page 6 of 12 Rev. 1.0
  • 7. TeoSys Engineering LLC, Diamond Marking Principles Objective Z - Axis Laser Z - Axis Beam U Rotation U Rotation X - Axis Y - Axis (a) (b) The left and right motion is called X-axis motion. The back and forth motion is called Y- axis motion. Up and down is called Z-axis motion. Rotation is called U-axis motion. Diamond Rotation X-axis Y-axis The X and Y-axis stages are the largest and most critical to the motion system. The typical characters made are less than the width of a single human hair. The motion system must be able to move in steps over one hundred times smaller than the width of a single human hair in order to make smooth and legible marks. Page 7 of 12 Rev. 1.0
  • 8. TeoSys Engineering LLC, Diamond Marking Principles 5.0 Mark Quality and Control As stated earlier, marking diamonds is still more art than science. Like an artists pallet, once can control many different parameters of the LMS to achieve the desired result. Methods of Controlling Mark Quality & Result Type of Control Result on Mark Quality Laser Energy Dots get darker with increased energy Shot Spacing Lines get darker with decreased spacing Beam Size Smaller and lighter marks with smaller size settings. Repeating Mark Mark gets darker, and a little wider Slow Motion Cleaner characters, better definition Scaling Make marks bigger and smaller Font Different fonts have different styles & darkness Laser energy is the primary way to increase mark darkness. With low energy the mark is nearly transparent. At higher energies the bottom of the mark begins to form carbon deposits. These deposits absorb light and make the mark look dark. Under certain circumstances the carbon can be removed. This can be accomplished by using very strong chemical treatments. Carbon can also often be removed from marks made with low energy setting. Low Medium High Energy Energy Energy No Carbonization Some High Carbonization Carbonization Shot spacing will also change the look of a mark. Small spots with gaps between each spot will produce an effect similar to that of a light, fine pencil. Page 8 of 12 Rev. 1.0
  • 9. TeoSys Engineering LLC, Diamond Marking Principles Marks without shot overlap One can overlap dots to produce a dark, continuous line. Marks with shot overlap Beam Size will also increase spot darkness, much like power increases, however with a more dramatic increase in spot size. Increasing Laser Power Increasing Beam Size Page 9 of 12 Rev. 1.0
  • 10. TeoSys Engineering LLC, Diamond Marking Principles Below is another example of changes in beam size affecting character quality. Example of how beam size changes mark quality Power = 4 Beam Size = 18.5 Power = 4 Beam Size = 17.5 Because the LMS utilizes a wavelength in the deep UV one can mark over the same place repeatedly without great concern. The software for the LMS allows the user to repeat the same marks, over the same location, with great precision. By marking the diamond twice, the user can increase the darkness, and size of the mark in a fashion similar to the beam size example shown above. Repeating a mark more than twice does not appreciably increase mark darkness, or width. Machine rate (marking speed) can be manipulated to change marking quality. Marking Speed Control LMS Setup Control Screen Page 10 of 12 Rev. 1.0
  • 11. TeoSys Engineering LLC, Diamond Marking Principles Machine rate divided by shot spacing yields maximum pulse repetition rate (PRR). In general, by increasing machine rate one reduces the precision that the motion system can produce clean, sharp characters. Lower machine rates increase production throughput times. It is therefore the operator’s judgment as to the best tradeoff between speed and quality. One unique feature of the LMS is its ability to precisely size and position text over the live video. Once text is entered, the user can proportionally increase the size of the text string, or relocate its position relative to the gem. This is particularly helpful when thin or irregularly shaped girdles are encountered. Users typically don’t create characters smaller than 30 microns, or larger than 150 microns. The system theoretically can operate over a much wider range. The text height refers to the maximum vertical features of the font. Most fonts have lower case elements which are much smaller. Scaling and Position Controls Much like a typewriter, the LMS allows the user to select from a number of fonts. Font Style Name Description Cyrillic Cyrillic-alphabetical Gothice Gothic English Gothicg Gothic German Gothici Gothic Italian Greekc Greek font double stroked with serifs Greeks Greek font single stroked with sans serifs Italicc Italic font double stroked with serifs Italict Italic triple stroked with serifs Monotxt Monospaced text font Romanc Double stroked Roman font with serifs Page 11 of 12 Rev. 1.0
  • 12. TeoSys Engineering LLC, Diamond Marking Principles Romand Double stroked Roman font with serifs for high resolution Romans Single stroked Roman san serif font Romant Triple stroked Roman font with serifs Scriptc Double stroked script font Scripts Single stroked script font Simplex Single stroked font Syastro Astronomical symbols Symap Mapping symbols Symath Math symbols Symeteo Meteorological symbols Symusic Music symbols Txt Default text Fonts are selected through the text information block on the main screen. One can choose to select the text height (in microns) on this same screen. 6.0 Summation As stated before, marking diamonds is more art than science. Before marking on high quality stones, it is recommended that the user practice on the glass slide fixture, or with Cubic Zirconium test gems. Glass slides carbonize much like diamonds. Glass, however, tends to crack with high energy. Cubic Zirconium gems (CZ’s) are good practice stones for speed, font, shape and position, however CZ tends not t carbonize o like diamonds. The typical beginning user takes five or ten minutes to mark a 20-character inscription. Experienced users should be able to mark the same 20 characters, on a typical diamond, within one or two minutes. As one becomes comfortable with the various controls and features of the LMS speed, quality and consistency will undoubtedly improve. Page 12 of 12 Rev. 1.0