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IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE)
e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 9, Issue 3 (Sep. - Oct. 2013), PP 01-10
www.iosrjournals.org
www.iosrjournals.org 1 | Page
Performance of Concrete at Elevated Temperatures: Utilizing A
Blended Ordinary Portland Cement (Opc)/ Saw Dust Ash (Sda)
As Binder
Nimlyat, P. S.1
datok, E. P.2
1
Department of Architecture, University of Jos
2
Department of Building University of Jos
Abstract: This study aimed at investigating the effect of subjecting concrete, produced with cement being
partially replaced with saw dust ash (SDA) to elevated temperatures. The performance of the test concrete cubes
was done by exposing them to elevated temperatures of 200oC, 400oC, 600oC and 800oC, and allowed to cool
down to room temperature before testing for their properties. Both the physical and thermal properties of the
concrete cubes were determined. The concrete produced by blending cement with 10% SDA with an average
percentage loss of 23.04% retained more of its compressive strength when exposed to the different
temperatures, than concrete produced using only OPC, which has an average percentage loss of 29.11%. It is
also found that, at an elevated temperature of 800oC, concrete fail totally in flexure due to the effect of high
heat on binding elements. The flexural strength of both the control concrete (at 0% OPC replacement) and
OPC/SDA blended concrete (at 10% OPC replacement) decreased as the temperature is increased. The
replacement of OPC by 10% SDA increased the thermal shock resistance of the concrete by 11 cycles than the
0% OPC concrete at the same temperature. The concrete produced with OPC has better thermal conductivity
than the concrete produced by blending OPC with SDA, as a result, the dislodgement of the concrete edges is
relatively lower in the SDA blended cement concrete than in the OPC concrete. The result shows that, blending
OPC with SDA in concrete performed better at elevated temperatures than concrete produced with only OPC.
Therefore, the replacement of OPC with 10% SDA can be applied as a fire resisting bonding material in
concrete.
Keywords: Blended Concrete, Elevated Temperatures, Ordinary Portland cement (OPC), Performance,
Saw Dust Ash (SDA)
I. Introduction
Concrete is a complex composite material and consist mainly of aggregates bonded together, by a
softer matrix of hardened cement paste, surrounding the aggregates in a weak transition zone. Concrete contains
about 40% capillarity pores of diameter between 1nm to 1mm and up to 28% gel pores, less than 2.6nm in
diameter [1]. Concrete when fresh, is a liquid paste that can be moulded into any desired shape and yet develops
strength to carry different loadings, when matured. This unique characteristic advantage of concrete made it the
most preferred choice for application in the construction industry. The cement component as a constituent of
concrete is the main binder in translating the liquid paste into a rigid strong concrete. Studies have shown that
pozzolanas can produce concrete that can be relatively compared with normal concrete in its characteristics [2]
[3] [4]. Therefore, the replacement of ordinary Portland cement (OPC) by a percentage of pozzolanic material
improves the strength and durability of concrete.
Concrete when exposed to high temperature (especially fire), deteriorate in its properties. Of particular
importance are; loss in compressive strength, cracking and spalling of concrete [5], destruction of the bond
between cement and the aggregates and the gradual deterioration of the hardened cement paste. Assessment of
fire damaged on concrete usually starts with visual observation of colour change[6], cracking and spalling of the
surface [5]. The ability of concrete to resist weathering actions, chemical attacks, abrasion, fire or any other
process of deterioration makes it have good durability property. Concrete is termed durable, when it keeps to its
form and shape within the allowable limits while exposed to different environmental conditions [5]. The
hydration of cement produces calcium hydroxide (Ca(OH)2) which is associated with poor durability and poor
fire resistivity. The chemical constituents of the pozzolana when mixed with cement react with the (Ca(OH)2) as
the principal hydration product of cement to produced cementation. The process of this reaction removes
(Ca(OH)2) from the mixture. The removal of this (Ca(OH)2) from the mixture has a significant influence on the
resulting concrete resistance to high fire [7]. Concrete properties and concrete response to the influencing
factors, such as loading, temperature and moisture depend on the properties of the concrete constituents. It can
be said that the concrete microstructure derives its macro properties through the combined properties of different
aggregate types and the cement paste (Cement Concrete and Aggregate Australia [8].
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According to CCAA [8], the four main properties of concrete are workability, cohesiveness, strength
and durability. The workability of concrete enables the material components to be compacted into forms having
any reasonable shape while durability ensures a long life for the hardened mass of the concrete. During
hydration and hardening, concrete develops certain physical and chemical properties. The mechanical strength
and durability are considered to have an important role in the design process. Thermal properties of concrete are
also an important aspect while dealing with durability of concrete. The study of thermal behaviour of concrete in
different situations forms an important topic while dealing with durability of concrete. The most important
aspects of thermal properties of concrete are;
a. Thermal conductivity of the concrete,
b. Coefficient of thermal expansion.
c. Fire resistance.
Concrete structures that may be subjected to a range of temperatures that are more severe than those
imposed by the ambient environmental conditions includes; Building fires, Incinerators, Nuclear plants and
Metallurgical buildings in proximity to furnace. The effect of elevated temperatures on certain mechanical and
physical properties of concrete may determine whether the concrete will maintain its structural integrity or not.
Study carried out by Morsy and Shebl [7] shows that, the replacement of Portland cement by 20 % metakaoline
in blended cement paste leads to increase in the thermal shock resistance up to 16 cycles. This is due to the
pozzolanic activity of metakaoline during hydration. The addition of pozzolanas to OPC in concrete, therefore,
has a way of improving the strength and durability of concrete, because of the interface reinforcement.
Pozzolanas are discovered to have chemical constituents that react with those released by the chemical reaction
during hydration of cement to form cementitious materials. When the chemical constituents of cement and
pozzolanas react, calcium hydroxide (Ca(OH)2) is been removed from the mixture. The removal of this calcium
hydroxide (Ca(OH)2) from the mixture improved the resistance of the concrete in aggressive environment. This
chemical reaction increases the strength of the concrete thus formed and influence other concrete properties such
as durability and thermal resistance.
Recent researches have shown that saw dust can be burnt into ash and used as a replacement of cement
in concrete. The benefit of utilizing SDA pozzolana derived from agro-waste local resources is enormous. The
conversion of saw dust into SDA Pozzolana, can create a significant benefit for the environment, by conserving
material resources and avoiding landfill disposal of timber waste products. Therefore, the need to improve on
the performance of concrete at elevated temperature blending cement with saw dust ash (SDA) pozzolana.
This study seeks to provide answers to certain research questions in the course of the investigation. The
research questions to be addressed are;
1. What is the effect of elevated temperatures on the mechanical and thermal properties of SDA/OPC blended
cement concrete?
2. Does SDA/OPC blended cement concrete perform better than OPC concrete when subjected to elevated
temperatures?
This study is aimed at investigating the effect of subjecting concrete produced with cement partially replaced
with saw dust ash (SDA) to elevated temperatures. The objectives of the research are;
1. To determine the compressive strength and flexural strength of preheated SDA pozzolana blended cement
concrete at different thermal treatment of between 200oC to 800oC.
2. To determine thermal conductivity and coefficient of thermal expansion of SDA/OPC blended cement
concrete
3. To determine the thermal shock resistance and linear shrinkage of the blended cement concrete at a
temperature of 800oC.
II. Concrete Behaviour at Elevated Temperature
Concrete offers great fire resistance to structures [6] and is physically stable to about 550oC, and, does
not fail dramatically even at higher temperatures [9]. Concrete's thermal properties protect reinforcing steel and
pre-stressing steel from structural failures acting as fireproofing coatings [6]. All of this does not mean that
concrete is not adversely affected by fire or heat. In the event of fire, concrete structures are affected by various
processes. This leads to degradation of the material and potentially spalling of the near-surface concrete layers
[10]. When concrete is exposed to temperatures above 100oC, evaporation begins to take place. Further rise in
temperature will result into spalling of the concrete due to rising pressures that exceed the strength of the
concrete [11]. Concrete, under normal atmospheric conditions, is typically exposed to temperatures below 50oC.
However, in fire conditions, concrete can be exposed to temperatures of up to 1200oC in less than 2 hours.
When heat is conducted in concrete, many changes occur in it physical structure, chemical composition and
fluid content. Therefore, the mechanical properties of concrete such as strength and stiffness, are significantly
altered when exposed to high temperatures. Generally, it can be said that concrete has good properties with
respect to fire resistance, when exposed to a temperature of up to 1000oC [12].
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A review of methods used by various investigators for elevated-temperature testing of concrete
indicates that, the tests can be categorized according to cold or hot testing [12]. In cold testing, specimens are
gradually heated to a specified temperature, permitted to stabilize thermally at that temperature for a prescribed
period, permitted to cool slowly to ambient, and then tested to determine residual mechanical properties. In hot
testing, specimens are gradually heated to a specified temperature, and permitted to stabilize thermally at the
temperature for a prescribed time, and then tested to determine mechanical properties. During testing, specimens
are maintained in either an open environment where water vapour can escape (unsealed) or a closed
environment where the moisture is contained (sealed). Mechanical properties in which the specimens have been
permitted to return to room temperature prior to testing are referred to as residual properties.
III. Temperature Effect on Pozzolanic Concrete
Pozzolanic high strength concretes (HSC) is used extensively throughout the world. The application of
such concretes is increasing day by day due to their superior structural performance, environmental friendliness,
and energy conserving implication [13]. When fine pozzolana particles are dispersed in concrete paste, they
generate a large number of nucleation sites for the precipitation of the hydration products [5]. Therefore, this
process increase the consistency of the paste and becomes dense as for the distribution of the fine pores. Morsy,
Shebl and Rashad [5], carried out an experimental investigation on the microstructure and compressive strength
of pre-heated metakaoline – silica fume blended cement paste. The result shows that there is a considerable
increase in compressive strength of the pre-heated blended cement than that of the control concrete. This
increase in compressive strength of the blended cement concrete may be due to the pozzolanic reaction of
metakaoline and silica fume with free lime to produced CSH and CAH. The increase can also be partially due to
the strengthened hydrated cement pastes during the evaporation of free water, which result into forces that
cause the cement gel layers to move closer to each other [14].
IV. Materials and Methods
The Method employed for this research includes the review of relevant literatures and publications on
concrete, and pozzolana admixture and the possible impact of fire to concrete. Other database information from
texts and internet sources are used in establishing facts. The data collection also involved field works and
laboratory experiments. The materials used for this study are cement, aggregates and SDA pozzolana. The
production of the concrete for the test are prepared from ordinary Portland cement (OPC) that is partially
substituted by SDA pozzolana using the standard water of consistence. The cement content in the concrete is
substituted by 10% partial replacement with the SDA pozzolana. This proportion is based on an already
conducted study, [3] [15] where an optimum replacement of cement with 10% SDA pozzolana in concrete for
workability and strength was suggested. The saw dust ash (SDA) used for this research resulted from waste
products of Timber sawn in Timber sheds in Jos. The saw dust came mainly from species of timber such as
Mansonia, Mahogany, Obeche and black Afara, which are common in the Nigerian market. The SDA is
produced by burning saw dust at a temperature range of 500oC – 600oC using a furnace at the National
Metallurgical Development Centre (NMDC) Jos, Nigeria. The cooled ash is then grounded to very fine texture
and sieved to a size less than 212µm.
Laboratory tests carried out includes among others; Sieve analysis, Chemical analysis of cement and
pozzolana. Also, thermal properties, compression and flexural strength test was carried out on the blended
cement concrete subjected to certain different temperatures. The concrete cubes are cast in 150mm x 150mm x
150mm mould and cure for 28 days, and the harden concrete is exposed to temperatures of 200oC, 400oC,
500oC and 800oc for two hours to achieve thermal steady state. For flexural strength test, cylindrical beams
were cast in a mould of size 500mm x 100mm x 100mm. Thermal shock resistance on the blended cement
concretes is determined by heating the concrete (after 28 days hydration period) for about 40 minutes at 700oC.
This was followed by quenching in water for 5 minutes and the cycles repeated until the sample deteriorates.
V. Results Presentation and Analysis
5.1 Density of unheated and heated concrete cubes
The density of the test cubes is determined before and the heating. The values obtained for the
unheated and heated concrete cubes are shown in Table 3. The result of the density indicates that, there is a
relationship between the density and temperature change. The application of heat to the test cubes reduces its
density relatively. Also, increasing the temperature at which the test cube is exposed to, the less the density of
the concrete cube as shown in Table 3, Fig. 2 and Fig. 3.
Comparing the percentage loss in density of the 0% OPC replacement concrete and the 10%
replacement SDA/OPC blended cement concrete after heating at the different temperature ranges, there is a
significant difference. At a temperature of 400oC, the percentage loss in density of 0% OPC replacement
concrete cube is 4.51% while that for the 10% OPC replacement blended cement concrete is 3.36% at the same
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
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temperature. At the temperature of 800oC, percentage decreased in density are 5.28% for the 0% OPC
replacement concrete cubes and 5.04% for the 10% SDA/OPC blended cement concrete cubes. It can therefore,
be said that, the SDA/OPC blended cement concrete is denser than the concrete made of 100% OPC and also,
loss in density due to heat application is lower in the former than in the later. This is as a result of SDA having a
lower specific gravity than that of cement.
5.2 Compressive Strength
Table 4 and Fig. 4 illustrate the typical development of compressive strength for the 0% and 10% OPC
replacement in the control and blended cement concrete subjected to a temperature range of 200oC to 800oC for
two hours. The compressive strength of concrete cubes made of 0% OPC replacement increased with
temperature up to 400oC and then decreased up to 8000C. The result also shows that, the 10% SDA/OPC
blended cement concrete increased in compressive strength as the treatment temperature increased up to 600oC,
and decreased at the temperature of 800oC. For the control concrete at 0% OPC replacement, the increased in
strength up to 400oC may be the result of the hydration of unhydrated cement constituents due from the heat
generated. For the 10% OPC replacement in the blended cement concrete, the increased in compressive strength
up to 600oC may be due to the pozzolanic reaction of the primary chemical constituents of the SDA pozzolana
that are deposited within the pores of the concrete. The ability of the blended cement concrete to increase in
strength even at 600oC, is as a result of the reduction in Ca(OH)2 content, by the action of SiO2 and Al2O3
which are elements in the SDA. According to Morsy et al (2008), cement matrix with higher volumes of gel-like
hydration products and lower crystalline Ca(OH)2 contents has improved fire resistance. The decline in
compressive strength of the 0% OPC replacement concrete is noticeable when the temperature is above 400oC
while that of the 10% replacement in the blended cement concrete is noticeable at a temperature of above
600oC.
Table 5 shows the result of the rate at which compressive strength is gain or loss with an increase in
temperature. From the result, the average percentage strength gained of the control concrete (at 0% OPC
replacement) is 10.22%, which is higher, than the strength gain in the blended cement concrete (10% OPC
replacement) which is 7.59%. Strength gain in the 10% OPC replacement, in the blended cement concrete, was
slower but increased up to a temperature of 600oC due to the pozzolanic activity of the SDA. The hydration of
cement consequently results into the liberation of lime. The liberated lime reacts with the pozzolana to increase
the strength development of the SDA/OPC blended cement concrete. The average percentage loss in
compressive strength of the 0% OPC replacement concrete at a temperature of over 400oC is 29.11%. This is
more than the average percentage loss in compressive strength of the SDA/OPC blended cement concrete at a
temperature of over 600oC. Since an increase in temperature resulted into decreased in densities, it is expected
that compressive strength should decrease with an increase in temperature.
5.3 Flexural Strength
The development of indirect tensile strength of the test concrete cubes as measured by the flexural
strength test is shown in Table 6 and Fig. 5. This test is carried out after subjecting the test cubes to different
elevated temperatures of 200, 400, 600, and 800oC after 28 days of curing. From the results, the flexural
strength of the two different replacements under study reduces as the temperature increases from 200oC to
600oC. There is no remarkable difference between the flexural strength of the concrete with 0% OPC
replacement and the 10% replacement of the SDA/OPC blended cement concrete. At 800oC, both the 0% OPC
replacement concrete and the SDA/OPC blended cement concrete has no values for flexural strength. This is due
to the effect of such a high heat on the binding elements of the concrete. Increasing the temperature of the test
cubes resulted into decreased in their density as shown in Table 3. The flexural strength also decreases as the
density also decreases. It is worthy of note that, the average loss in flexural strength of the SDA/OPC blended
cement concrete at 10% replacement, is 0.05 lower than the loss in flexural strength of the 0% concrete as
shown in Table 7. It can then be said that, SDA/OPC blended cement concrete can perform better in flexure
under elevated temperature when compared to the 100% OPC concrete.
5.4 Thermal Shock Resistance
The performance of the concrete cubes is shown in Table 8 and Fig. 6 as a result of exposing the tests
cubes to an elevated temperature of 800o , the outer surface of the concrete which is in direct contact with the
heat tends to expand more than the inner layers. When the heated concrete cube is cool by immersion in water,
there is a differential deformation between the outer surface and the inner layers thereby resulting into cracks
and deterioration of the concrete. The presence of the constituents of pozzolanic SDA increase the thermal
shock resistance of the 10% OPC replacement in the blended cement concrete, which is considerably higher
than that of the control (0% OPC replacement).
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
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5.5 Thermal Conductivity
The variation of thermal conductivity of the 0% OPC concrete and 10% SAD/OPC blended cement
concrete is presented in Table 9 and Fig. 7. The thermal conductivity of the 0% OPC replacement is 1.77
W/m.K while the thermal conductivity for the 10% SDA/OPC replacement is 1.68W/m.K. The result shows that
the thermal conductivity of the blended cement concrete is a little lower than that for the control concrete. The
saw dust ash (SDA) in the concrete reduced its conductivity thereby making it a lesser conductor of heat than
the concrete made from 100% ordinary Portland cement (OPC). Saw dust ash (SDA) content, therefore, had
only a slight influence on thermal conductivity of the concrete. This improves the durability of the concrete
produced by blending OPC with SDA. Also from the result, the effect of temperature on the concrete produced
of OPC is a little more than that of concrete produced by blending OPC with SDA as a result of the OPC
conducting more heat than the SDA. The difference in their thermal conductivity also resulted into more
cracking and spalling of the surfaces of the OPC concrete than the SDA blended concrete. It is pertinent to say
that, concrete produced by replacing OPC with 10% SDA can be a better material for separating warm or hot
parts from cold ones in concrete construction or furnaces.
5.5 Linear Coefficient of Thermal Expansion
The result of the average linear coefficient of thermal expansion for the test concrete cubes is presented
in Table 10, and Fig. 8. The average coefficient of thermal expansion for the 0% OPC replacement cement
concrete is 11.07 x 10-6 /oC while that for the 10% SDA/OPC blended cement concrete is 10.42 x 10-6 /oC.
The linear coefficient of thermal expansion for the SDA/OPC blended cement concrete is significantly lower
than that for the concrete made with 100% cement.
5.6 Linear Shrinkage
The result of linear shrinkage of the test cubes is presented in Table 11 and Fig. 9 as a percentage
reduction in the size of the test specimens. The rate of shrinkage is more in the 0% OPC replacement concrete
than in the 10% SDA/OPC concrete. Linear shrinkage is lower in the 10% SDA/OPC concrete than it is in the
0% concrete. There is an increase in linear shrinkage for both cement replacement in concrete with temperature.
The shrinkage of both of the test specimens is typically categorized as plastic. The addition of 10% SDA in the
blended cement contributed to decreased shrinkage of concrete produced with it. The highest shrinkage for both
concrete occurred at the highest temperature; therefore, linear shrinkage is dependent on the temperature at
which the concrete is exposed to. The linear coefficient of thermal expansion result indicated the magnitude of
thermal mismatch between the aggregate and the cement.
5.7 Cracking and Spalling
Physical observation of the test specimens are made after exposing them to different temperatures.
From the observation, there was a colour change in both concrete when exposed to temperatures of 600oC and
800oC. The OPC concrete was whitish-grey at 600oC and light-brown at 800oC while the SDA blended cement
concrete was dark-grey at 600oC and deep-brown at 800oC. At 600oC the OPC concrete started experiencing
slight fire cracks and surface peel-off, while the blended cement concrete only started experiencing fire cracks
and surface peel-off at 800oC. There was no any detachment of particles or peel-off of the concrete surface for
the SDA blended concrete when exposed to temperatures of 200oC, 400oC and 600oC while the OPC concrete
started having surface peel-off and dislodgement at a temperature of 600oC. The dislodgement or detachment of
small pieces of the surfaces of the concrete was more in the OPC than in the SDA blended cement at 800oC.
However, the spalling was not explosive at 800oC but a dislodgement of a minor portion of the concrete edges.
The dislodgement of the concrete edges in the OPC concrete as compared with SDA blended concrete is
relative.
VI. Figures and Tables
Figure 1 Experimental programme to study the effect of SDA pozzolana blended cement concrete at elevated
temperature.
OPC + SDAOPC
W/C =
0.60
W/C =
0.60
100% 90% + 10%
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
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2200
2300
2400
2500
2600
200 400 600 800
DensityKg/m3
Temperature oC
Unheated Density
Kg/m3
Figure 2 Densities of unheated and heated cubes at different temperatures for 0% OPC replacement
2200
2300
2400
2500
2600
200 400 600 800
DensityKg/m3
Temperature oC
Unheated Density
Kg/m3
Heated Density Kg/m3
Figure 3Densities of unheated and heated cubes at different temperatures for 10% OPC replacement
0
5
10
15
20
25
30
0 500 1000
CompressiveStrength
N/mm2
Temperature oC
0% Replacement
10% Replacement
Figure 4 Compressive strength development at different temperatures
0
1
2
3
4
5
0 500 1000
FlexuralStrength(N/mm2)
Temperature oC
Flexural Strength 0%
Replacement
Flexural Strength
10% Replacement
Figure 5 Flexural strength development at different temperatures
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
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0
5
10
15
0 10
No.ofResistance
(Cycles)
Replacement (%)
Test 1
Test 2
Test 3
Average Cycles
Figure 6 Thermal shock resistance
1.6
1.65
1.7
1.75
1.8
0 10
ThermalConductivity
W/m.K
Replacement (%)
Thermal Conductivity
Figure 7 Variation of thermal conductivity with percentage replacement of cement content.
10
10.2
10.4
10.6
10.8
11
11.2
0 10
CoefficientofThermal
ExpansionX10-6/oC
Cement Replacement (%)
Coefficient of
Thermal Expansion
X 10-6 /oC
Figure 8Linear coefficient of thermal expansion
0
0.1
0.2
0.3
0.4
0.5
0.6
200 400 600 800
LinearShrinkage(%)
Temperature oC
10%
Replacement
0% Replacement
Figure 9Effect of saw dust ash (SDA) on linear shrinkage of concrete with temperature.
Table 1 Physical and Chemical Properties of Saw Dust Ash (SDA)
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
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ELEMENTS SAW DUST ASH [SDA]
Moisture Content (MC) 2.06%
Specific Gravity 2.03
Compacted Bulk Density
Loss on Ignition 4.97%
PH Value 10.05
Al2O3 13.65%
Fe2O3 13.34%
SiO2 48.95%
CaO 5.40%
MgO 4.60%
MnO 0.95%
K2O 9.01%
P2O5 3.10%
SO3 1.00%
Table 2 Mix Design per Cubic Metre of Concrete (1:2:4) Water/Cement Ratio 0.60
PROPERTIES CONTROL MIX BLENDED MIX
Cement- OPC (Kg/m3
) 25 22.5
SDA (Kg/m3
) 0 2.5
Cementitous Binder (Kg/m3
) 25 25
Coarse Aggregate (Kg/m3
) 50 50
Fine Aggregate (Kg/m3
) 100 100
Total Water (Kg) 15 15
Table 3 Density of Unheated and Heated Concrete Cubes
Temperature 200o
C 400o
C 600o
C 800o
C 200o
C 400o
C 600o
C 800o
C
Unheated Density
Kg/m3 2438.5 2526 2570.4 2497.8 2555.6 2555.6 2444.5 2503.74
Heated Density Kg/m3 2376.3 2392.6 2444.5 2385.2 2494.9 2469.7 2333.4 2314.83
Percentage Decrease
in Density Kg/m3
2.55 5.28 4.9 4.51 2.38 3.36 4.55 5.04
0% OPC Replacement 10% OPC Replacement
Table 4 Variation of Compressive Strength with different Temperature Range
Room
Temperature
200o
C 400o
C 600o
C 800o
C
0 0.6 20.15 23.31 24.42 18.44 12.22
10 0.6 15.06 15.73 16.09 18.67 14.20
Percentage
Replacement
(%)
Water/Cement
Ratio
Compressive Strength N/mm2
Table 5 Rate of Compressive Strength Gain and Loss
200o
C : Room
temperature
400o
C : 200o
C 600o
C : 400o
C 800o
C : 600o
C
0 1.16 1.05 1.32 1.51 10.22 29.11
10 1.04 1.02 1.16 1.31 7.59 23.94
Percentage
Replacement
(%)
Strength Gain/Loss
Average
Percentage
Loss (%)
Average
Percentage
Gain (%)
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Table 6 Variation of Flexural Strength with different Temperature Range
Room
Temperature
200o
C 400o
C 600o
C 800o
C
0 0.6 4.16 2.55 2.1 1.02 Nil
10 0.6 3.71 2.25 1.82 0.84 Nil
Percentage
Replacement
(%)
Water/Cement
Ratio
Flexural Strength (N/mm
2
)
Table 7 Rate of Flexural Strength Loss
Percentage
Replacement (%)
200o
C : Room
temperature
400o
C : 200o
C 600o
C : 400o
C 800o
C : 600o
C
Average
Strength Loss
0 1.61 0.45 0.98 1.01
10 1.46 0.43 0.98 0.96
Table 8 Result of Thermal Shock Resistance Test at 800o
C
Test 1 Test 2 Test 3 Average Cycle
0 3 5 4 4
10 12 14 12 13
Percentage Replacement (%)
Number of Resistance in Cycles
Table 9 Results of the Thermal Conductivity Test
Percentage Replacement (%) Thermal Conductivity W/m.K
0 1.77
10 1.68
Table 10Results of the Linear Coefficient of Thermal Expansion Test
Percentage Replacement (%) Coefficient of Thermal Expansion X 10
-6
/
o
C
0 11.07
10 10.43
Table 11Variation of Linear Shrinkage with different Temperature Range
200o
C 400o
C 600o
C 800o
C
0 0.6 0.21 0.225 0.235 0.24
10 0.6 0.24 0.244 0.246 0.25
Percentage
Replacement (%)
Water/Cement
Ratio
Linear Shrinkage (%)
VII. Summaryand Conclusion
Temperature influence on strength and durability of concrete is essential for it to have the
characteristic of fire resistance. Concrete can be considered thermally stable when it retains its form
and shape within the allowable limits, while exposed to high or elevated temperatures. This study
finds out that particular chemical constituents of cement and pozzolanas are responsible for concrete
performance under heat.
The conclusion from the above investigation can be summarized as follows:
1. The density of concrete is found to decrease with temperature increased. The average percentage
loss in density for the control concrete is 4.31% while that for the SDA/OPC blended cement
concrete is 3.83%. The SDA/OPC blended cement concrete therefore retained more of its density
after been exposed to higher temperatures, than the control concrete made of 100% cement, as a
result of the SDA having a lower specific gravity than the OPC.
Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement
www.iosrjournals.org 10 | Page
2. Concrete produced by blending cement with 10% SDA increased in compressive strength, when
heated to 600oC, while the compressive strength of concrete produced with OPC reduces at the
same temperature.
3. Concrete produced by blending OPC with 10% SDA retained more of its compressive strength at
the different temperatures exposed to, than the concrete produced using only OPC.
4. At an elevated temperature of 800oC, both concrete specimens fail totally in flexure due to the
effect of high heat on binding elements. The flexural strength of both the control concrete (at 0%
OPC replacement) and SDA/OPC blended cement concrete (at 10% OPC replacement) decreased
as the temperature is increased. Their performance in flexure is relative to each other.
5. Replacement of OPC by 10% SDA increased the thermal shock resistance of the concrete by 11
cycles more than the concrete produced with 100%.
6. The Saw dust ash (SDA) content had only a slight influence on thermal conductivity of the
concrete as a result; cracking and spalling occurred more in the OPC concrete than in the SDA
blended cement concrete.
7. Linear coefficient of thermal expansion for the SDA/OPC blended cement concrete is
significantly lower than that for the concrete made with 100% cement. This is dependent on the
temperature at which the concrete is treated.
8. The addition of in 10% SDA in the blended cement concrete contributed to the decreased in linear
shrinkage of the concrete produced with the blended concrete. the shrinkage in OPC concrete is
higher than in the 10% SDA/OPC concrete.
9. Slight fire cracks started occurring on the OPC concrete at 600oC with surface peel-off and
dislodgement occurring at 800oC. The blended cement concrete experienced slight fire cracks and
surface dislodgement at 800oC. Cracking and surface peel-off are relatively lower in the SDA
blended cement concrete than in the OPC concrete.
From the tests results, it can be deduced that the replacement of OPC with about 10% SDA in
concrete relatively improved performance of concrete at elevated temperature. Blending of OPC with
10% SDA can therefore be applied as a fire resisting bonding material in concrete. In order to have a
research that is multi-facetted in its approach, it is recommended that further studies be conducted on
the performance of concrete at elevated temperature by varying the percentage replacement of cement
with SDA and also using different concrete grades.
References
[1] A.M. Neville, Properties of concrete: Special Issues in Materials Testing (Pearson Education, Fourth Edition 2007).
[2] G.A. Khoury, Performance of Heated Concrete—Mechanical Properties, Contract NUC/56/3604A with Nuclear Installations
Inspectorate (Imperial College, London, August 1996).
[3] S.A. Sumaila, and O.F. Job, Properties of SDA-OPC Concrete: A Preliminary Assessment, Journal of Environmental Sciences, 3(2),
1999, 155-159
[4] I.I. Dashan, and E.E.I. Kamang, Some Characteristics of AHA/OPC Concretes: A Preliminary Assessment, Nigerian Journal of
Construction Technology and Management, 2(1), 1999, 22-28.
[5] M.M. Morsy, S.S. Shebl, and A.M. Rashad, Effect of Fire on Microstructure and Mechanical Properties of Blended Cement Pastes
Containing Metakaoline and Silica Fume. Asian Journal of Civil Engineering (Building and Housing), 9(2), 2008, 93-105.
[6] G. Narenda, Effect of Fire on Concrete, Concrete International Magazine, April, 2006, www.highbeam.com/doc/1P3-
1106559491.html, Retrieved 22nd June, 2013
[7] M.S. Morsy, and S.S. Shebl, Effect of Silica Fume and MetakaolinePozzolana on the Performance of Blended Cement Pastes
Against Fire. Ceramic Silikaty, 51(1), 2007, 40-44.
[8] CCAA, Concrete Basics: A Guide to Concrete Practice, A Publication of Cement Concrete and Aggregate Australia, 2004, 6th
edition. www.concrete.net.au, retrieved 15th April 2010.
[9] B. Erlin, and W. Hime, The Fire Resistance of Concrete, Concrete Construction. Dec. 2004.
[10] M. Zeiml, and R. Lackner, Experimental Investigation on Spalling Mechanisms in Heated Concrete, In Kukla, K. (2010), Concrete
at high temperatures hygrothermo-mechanical degradation of concrete, doctoral thesis, Department of Civil Engineering, University
of Glasgow, 2010. http://thesis.gla.ac.uk/1666/, retrieved 3rd July, 2011.
[11] Wanye, Heat Resistance Concrete, Everything about concrete.com, http://www.everything-about-concrete.com/heat-resistant-
concrete.html
[12] D.J. Naus, The Effect of Elevated Temperature on Concrete Materials and Structures - A Literature Review (Prepared by Oak Ridge
National Laboratory, Managed by UT-Battelle, LLC, P.O. Box 2008. Oak Ridge. U.S. Nuclear Regulatory Commission
Washington, DC 20555-0001, 2006)
[13] P.K. Mehta, Advancements in Concrete Technology, Journal of Concrete International. 96(4), 1999, 69-76.
[14] H.K.M. Anwar, High Strength Blended Cement Concrete Incorporating Volcanic Ash: Performance at High Temperatures, Journal
of Cement and Concrete Composites. 28, 2006, 535-545.
[15] D.S. Matawal, Application of Ashes as Pozzolana in Mortar and Concrete Production, 1st National Academy Conference, 31st –
2nd September, 2005.

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Performance of Concrete at Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement (Opc)/ Saw Dust Ash (Sda) As Binder

  • 1. IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE) e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 9, Issue 3 (Sep. - Oct. 2013), PP 01-10 www.iosrjournals.org www.iosrjournals.org 1 | Page Performance of Concrete at Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement (Opc)/ Saw Dust Ash (Sda) As Binder Nimlyat, P. S.1 datok, E. P.2 1 Department of Architecture, University of Jos 2 Department of Building University of Jos Abstract: This study aimed at investigating the effect of subjecting concrete, produced with cement being partially replaced with saw dust ash (SDA) to elevated temperatures. The performance of the test concrete cubes was done by exposing them to elevated temperatures of 200oC, 400oC, 600oC and 800oC, and allowed to cool down to room temperature before testing for their properties. Both the physical and thermal properties of the concrete cubes were determined. The concrete produced by blending cement with 10% SDA with an average percentage loss of 23.04% retained more of its compressive strength when exposed to the different temperatures, than concrete produced using only OPC, which has an average percentage loss of 29.11%. It is also found that, at an elevated temperature of 800oC, concrete fail totally in flexure due to the effect of high heat on binding elements. The flexural strength of both the control concrete (at 0% OPC replacement) and OPC/SDA blended concrete (at 10% OPC replacement) decreased as the temperature is increased. The replacement of OPC by 10% SDA increased the thermal shock resistance of the concrete by 11 cycles than the 0% OPC concrete at the same temperature. The concrete produced with OPC has better thermal conductivity than the concrete produced by blending OPC with SDA, as a result, the dislodgement of the concrete edges is relatively lower in the SDA blended cement concrete than in the OPC concrete. The result shows that, blending OPC with SDA in concrete performed better at elevated temperatures than concrete produced with only OPC. Therefore, the replacement of OPC with 10% SDA can be applied as a fire resisting bonding material in concrete. Keywords: Blended Concrete, Elevated Temperatures, Ordinary Portland cement (OPC), Performance, Saw Dust Ash (SDA) I. Introduction Concrete is a complex composite material and consist mainly of aggregates bonded together, by a softer matrix of hardened cement paste, surrounding the aggregates in a weak transition zone. Concrete contains about 40% capillarity pores of diameter between 1nm to 1mm and up to 28% gel pores, less than 2.6nm in diameter [1]. Concrete when fresh, is a liquid paste that can be moulded into any desired shape and yet develops strength to carry different loadings, when matured. This unique characteristic advantage of concrete made it the most preferred choice for application in the construction industry. The cement component as a constituent of concrete is the main binder in translating the liquid paste into a rigid strong concrete. Studies have shown that pozzolanas can produce concrete that can be relatively compared with normal concrete in its characteristics [2] [3] [4]. Therefore, the replacement of ordinary Portland cement (OPC) by a percentage of pozzolanic material improves the strength and durability of concrete. Concrete when exposed to high temperature (especially fire), deteriorate in its properties. Of particular importance are; loss in compressive strength, cracking and spalling of concrete [5], destruction of the bond between cement and the aggregates and the gradual deterioration of the hardened cement paste. Assessment of fire damaged on concrete usually starts with visual observation of colour change[6], cracking and spalling of the surface [5]. The ability of concrete to resist weathering actions, chemical attacks, abrasion, fire or any other process of deterioration makes it have good durability property. Concrete is termed durable, when it keeps to its form and shape within the allowable limits while exposed to different environmental conditions [5]. The hydration of cement produces calcium hydroxide (Ca(OH)2) which is associated with poor durability and poor fire resistivity. The chemical constituents of the pozzolana when mixed with cement react with the (Ca(OH)2) as the principal hydration product of cement to produced cementation. The process of this reaction removes (Ca(OH)2) from the mixture. The removal of this (Ca(OH)2) from the mixture has a significant influence on the resulting concrete resistance to high fire [7]. Concrete properties and concrete response to the influencing factors, such as loading, temperature and moisture depend on the properties of the concrete constituents. It can be said that the concrete microstructure derives its macro properties through the combined properties of different aggregate types and the cement paste (Cement Concrete and Aggregate Australia [8].
  • 2. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 2 | Page According to CCAA [8], the four main properties of concrete are workability, cohesiveness, strength and durability. The workability of concrete enables the material components to be compacted into forms having any reasonable shape while durability ensures a long life for the hardened mass of the concrete. During hydration and hardening, concrete develops certain physical and chemical properties. The mechanical strength and durability are considered to have an important role in the design process. Thermal properties of concrete are also an important aspect while dealing with durability of concrete. The study of thermal behaviour of concrete in different situations forms an important topic while dealing with durability of concrete. The most important aspects of thermal properties of concrete are; a. Thermal conductivity of the concrete, b. Coefficient of thermal expansion. c. Fire resistance. Concrete structures that may be subjected to a range of temperatures that are more severe than those imposed by the ambient environmental conditions includes; Building fires, Incinerators, Nuclear plants and Metallurgical buildings in proximity to furnace. The effect of elevated temperatures on certain mechanical and physical properties of concrete may determine whether the concrete will maintain its structural integrity or not. Study carried out by Morsy and Shebl [7] shows that, the replacement of Portland cement by 20 % metakaoline in blended cement paste leads to increase in the thermal shock resistance up to 16 cycles. This is due to the pozzolanic activity of metakaoline during hydration. The addition of pozzolanas to OPC in concrete, therefore, has a way of improving the strength and durability of concrete, because of the interface reinforcement. Pozzolanas are discovered to have chemical constituents that react with those released by the chemical reaction during hydration of cement to form cementitious materials. When the chemical constituents of cement and pozzolanas react, calcium hydroxide (Ca(OH)2) is been removed from the mixture. The removal of this calcium hydroxide (Ca(OH)2) from the mixture improved the resistance of the concrete in aggressive environment. This chemical reaction increases the strength of the concrete thus formed and influence other concrete properties such as durability and thermal resistance. Recent researches have shown that saw dust can be burnt into ash and used as a replacement of cement in concrete. The benefit of utilizing SDA pozzolana derived from agro-waste local resources is enormous. The conversion of saw dust into SDA Pozzolana, can create a significant benefit for the environment, by conserving material resources and avoiding landfill disposal of timber waste products. Therefore, the need to improve on the performance of concrete at elevated temperature blending cement with saw dust ash (SDA) pozzolana. This study seeks to provide answers to certain research questions in the course of the investigation. The research questions to be addressed are; 1. What is the effect of elevated temperatures on the mechanical and thermal properties of SDA/OPC blended cement concrete? 2. Does SDA/OPC blended cement concrete perform better than OPC concrete when subjected to elevated temperatures? This study is aimed at investigating the effect of subjecting concrete produced with cement partially replaced with saw dust ash (SDA) to elevated temperatures. The objectives of the research are; 1. To determine the compressive strength and flexural strength of preheated SDA pozzolana blended cement concrete at different thermal treatment of between 200oC to 800oC. 2. To determine thermal conductivity and coefficient of thermal expansion of SDA/OPC blended cement concrete 3. To determine the thermal shock resistance and linear shrinkage of the blended cement concrete at a temperature of 800oC. II. Concrete Behaviour at Elevated Temperature Concrete offers great fire resistance to structures [6] and is physically stable to about 550oC, and, does not fail dramatically even at higher temperatures [9]. Concrete's thermal properties protect reinforcing steel and pre-stressing steel from structural failures acting as fireproofing coatings [6]. All of this does not mean that concrete is not adversely affected by fire or heat. In the event of fire, concrete structures are affected by various processes. This leads to degradation of the material and potentially spalling of the near-surface concrete layers [10]. When concrete is exposed to temperatures above 100oC, evaporation begins to take place. Further rise in temperature will result into spalling of the concrete due to rising pressures that exceed the strength of the concrete [11]. Concrete, under normal atmospheric conditions, is typically exposed to temperatures below 50oC. However, in fire conditions, concrete can be exposed to temperatures of up to 1200oC in less than 2 hours. When heat is conducted in concrete, many changes occur in it physical structure, chemical composition and fluid content. Therefore, the mechanical properties of concrete such as strength and stiffness, are significantly altered when exposed to high temperatures. Generally, it can be said that concrete has good properties with respect to fire resistance, when exposed to a temperature of up to 1000oC [12].
  • 3. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 3 | Page A review of methods used by various investigators for elevated-temperature testing of concrete indicates that, the tests can be categorized according to cold or hot testing [12]. In cold testing, specimens are gradually heated to a specified temperature, permitted to stabilize thermally at that temperature for a prescribed period, permitted to cool slowly to ambient, and then tested to determine residual mechanical properties. In hot testing, specimens are gradually heated to a specified temperature, and permitted to stabilize thermally at the temperature for a prescribed time, and then tested to determine mechanical properties. During testing, specimens are maintained in either an open environment where water vapour can escape (unsealed) or a closed environment where the moisture is contained (sealed). Mechanical properties in which the specimens have been permitted to return to room temperature prior to testing are referred to as residual properties. III. Temperature Effect on Pozzolanic Concrete Pozzolanic high strength concretes (HSC) is used extensively throughout the world. The application of such concretes is increasing day by day due to their superior structural performance, environmental friendliness, and energy conserving implication [13]. When fine pozzolana particles are dispersed in concrete paste, they generate a large number of nucleation sites for the precipitation of the hydration products [5]. Therefore, this process increase the consistency of the paste and becomes dense as for the distribution of the fine pores. Morsy, Shebl and Rashad [5], carried out an experimental investigation on the microstructure and compressive strength of pre-heated metakaoline – silica fume blended cement paste. The result shows that there is a considerable increase in compressive strength of the pre-heated blended cement than that of the control concrete. This increase in compressive strength of the blended cement concrete may be due to the pozzolanic reaction of metakaoline and silica fume with free lime to produced CSH and CAH. The increase can also be partially due to the strengthened hydrated cement pastes during the evaporation of free water, which result into forces that cause the cement gel layers to move closer to each other [14]. IV. Materials and Methods The Method employed for this research includes the review of relevant literatures and publications on concrete, and pozzolana admixture and the possible impact of fire to concrete. Other database information from texts and internet sources are used in establishing facts. The data collection also involved field works and laboratory experiments. The materials used for this study are cement, aggregates and SDA pozzolana. The production of the concrete for the test are prepared from ordinary Portland cement (OPC) that is partially substituted by SDA pozzolana using the standard water of consistence. The cement content in the concrete is substituted by 10% partial replacement with the SDA pozzolana. This proportion is based on an already conducted study, [3] [15] where an optimum replacement of cement with 10% SDA pozzolana in concrete for workability and strength was suggested. The saw dust ash (SDA) used for this research resulted from waste products of Timber sawn in Timber sheds in Jos. The saw dust came mainly from species of timber such as Mansonia, Mahogany, Obeche and black Afara, which are common in the Nigerian market. The SDA is produced by burning saw dust at a temperature range of 500oC – 600oC using a furnace at the National Metallurgical Development Centre (NMDC) Jos, Nigeria. The cooled ash is then grounded to very fine texture and sieved to a size less than 212µm. Laboratory tests carried out includes among others; Sieve analysis, Chemical analysis of cement and pozzolana. Also, thermal properties, compression and flexural strength test was carried out on the blended cement concrete subjected to certain different temperatures. The concrete cubes are cast in 150mm x 150mm x 150mm mould and cure for 28 days, and the harden concrete is exposed to temperatures of 200oC, 400oC, 500oC and 800oc for two hours to achieve thermal steady state. For flexural strength test, cylindrical beams were cast in a mould of size 500mm x 100mm x 100mm. Thermal shock resistance on the blended cement concretes is determined by heating the concrete (after 28 days hydration period) for about 40 minutes at 700oC. This was followed by quenching in water for 5 minutes and the cycles repeated until the sample deteriorates. V. Results Presentation and Analysis 5.1 Density of unheated and heated concrete cubes The density of the test cubes is determined before and the heating. The values obtained for the unheated and heated concrete cubes are shown in Table 3. The result of the density indicates that, there is a relationship between the density and temperature change. The application of heat to the test cubes reduces its density relatively. Also, increasing the temperature at which the test cube is exposed to, the less the density of the concrete cube as shown in Table 3, Fig. 2 and Fig. 3. Comparing the percentage loss in density of the 0% OPC replacement concrete and the 10% replacement SDA/OPC blended cement concrete after heating at the different temperature ranges, there is a significant difference. At a temperature of 400oC, the percentage loss in density of 0% OPC replacement concrete cube is 4.51% while that for the 10% OPC replacement blended cement concrete is 3.36% at the same
  • 4. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 4 | Page temperature. At the temperature of 800oC, percentage decreased in density are 5.28% for the 0% OPC replacement concrete cubes and 5.04% for the 10% SDA/OPC blended cement concrete cubes. It can therefore, be said that, the SDA/OPC blended cement concrete is denser than the concrete made of 100% OPC and also, loss in density due to heat application is lower in the former than in the later. This is as a result of SDA having a lower specific gravity than that of cement. 5.2 Compressive Strength Table 4 and Fig. 4 illustrate the typical development of compressive strength for the 0% and 10% OPC replacement in the control and blended cement concrete subjected to a temperature range of 200oC to 800oC for two hours. The compressive strength of concrete cubes made of 0% OPC replacement increased with temperature up to 400oC and then decreased up to 8000C. The result also shows that, the 10% SDA/OPC blended cement concrete increased in compressive strength as the treatment temperature increased up to 600oC, and decreased at the temperature of 800oC. For the control concrete at 0% OPC replacement, the increased in strength up to 400oC may be the result of the hydration of unhydrated cement constituents due from the heat generated. For the 10% OPC replacement in the blended cement concrete, the increased in compressive strength up to 600oC may be due to the pozzolanic reaction of the primary chemical constituents of the SDA pozzolana that are deposited within the pores of the concrete. The ability of the blended cement concrete to increase in strength even at 600oC, is as a result of the reduction in Ca(OH)2 content, by the action of SiO2 and Al2O3 which are elements in the SDA. According to Morsy et al (2008), cement matrix with higher volumes of gel-like hydration products and lower crystalline Ca(OH)2 contents has improved fire resistance. The decline in compressive strength of the 0% OPC replacement concrete is noticeable when the temperature is above 400oC while that of the 10% replacement in the blended cement concrete is noticeable at a temperature of above 600oC. Table 5 shows the result of the rate at which compressive strength is gain or loss with an increase in temperature. From the result, the average percentage strength gained of the control concrete (at 0% OPC replacement) is 10.22%, which is higher, than the strength gain in the blended cement concrete (10% OPC replacement) which is 7.59%. Strength gain in the 10% OPC replacement, in the blended cement concrete, was slower but increased up to a temperature of 600oC due to the pozzolanic activity of the SDA. The hydration of cement consequently results into the liberation of lime. The liberated lime reacts with the pozzolana to increase the strength development of the SDA/OPC blended cement concrete. The average percentage loss in compressive strength of the 0% OPC replacement concrete at a temperature of over 400oC is 29.11%. This is more than the average percentage loss in compressive strength of the SDA/OPC blended cement concrete at a temperature of over 600oC. Since an increase in temperature resulted into decreased in densities, it is expected that compressive strength should decrease with an increase in temperature. 5.3 Flexural Strength The development of indirect tensile strength of the test concrete cubes as measured by the flexural strength test is shown in Table 6 and Fig. 5. This test is carried out after subjecting the test cubes to different elevated temperatures of 200, 400, 600, and 800oC after 28 days of curing. From the results, the flexural strength of the two different replacements under study reduces as the temperature increases from 200oC to 600oC. There is no remarkable difference between the flexural strength of the concrete with 0% OPC replacement and the 10% replacement of the SDA/OPC blended cement concrete. At 800oC, both the 0% OPC replacement concrete and the SDA/OPC blended cement concrete has no values for flexural strength. This is due to the effect of such a high heat on the binding elements of the concrete. Increasing the temperature of the test cubes resulted into decreased in their density as shown in Table 3. The flexural strength also decreases as the density also decreases. It is worthy of note that, the average loss in flexural strength of the SDA/OPC blended cement concrete at 10% replacement, is 0.05 lower than the loss in flexural strength of the 0% concrete as shown in Table 7. It can then be said that, SDA/OPC blended cement concrete can perform better in flexure under elevated temperature when compared to the 100% OPC concrete. 5.4 Thermal Shock Resistance The performance of the concrete cubes is shown in Table 8 and Fig. 6 as a result of exposing the tests cubes to an elevated temperature of 800o , the outer surface of the concrete which is in direct contact with the heat tends to expand more than the inner layers. When the heated concrete cube is cool by immersion in water, there is a differential deformation between the outer surface and the inner layers thereby resulting into cracks and deterioration of the concrete. The presence of the constituents of pozzolanic SDA increase the thermal shock resistance of the 10% OPC replacement in the blended cement concrete, which is considerably higher than that of the control (0% OPC replacement).
  • 5. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 5 | Page 5.5 Thermal Conductivity The variation of thermal conductivity of the 0% OPC concrete and 10% SAD/OPC blended cement concrete is presented in Table 9 and Fig. 7. The thermal conductivity of the 0% OPC replacement is 1.77 W/m.K while the thermal conductivity for the 10% SDA/OPC replacement is 1.68W/m.K. The result shows that the thermal conductivity of the blended cement concrete is a little lower than that for the control concrete. The saw dust ash (SDA) in the concrete reduced its conductivity thereby making it a lesser conductor of heat than the concrete made from 100% ordinary Portland cement (OPC). Saw dust ash (SDA) content, therefore, had only a slight influence on thermal conductivity of the concrete. This improves the durability of the concrete produced by blending OPC with SDA. Also from the result, the effect of temperature on the concrete produced of OPC is a little more than that of concrete produced by blending OPC with SDA as a result of the OPC conducting more heat than the SDA. The difference in their thermal conductivity also resulted into more cracking and spalling of the surfaces of the OPC concrete than the SDA blended concrete. It is pertinent to say that, concrete produced by replacing OPC with 10% SDA can be a better material for separating warm or hot parts from cold ones in concrete construction or furnaces. 5.5 Linear Coefficient of Thermal Expansion The result of the average linear coefficient of thermal expansion for the test concrete cubes is presented in Table 10, and Fig. 8. The average coefficient of thermal expansion for the 0% OPC replacement cement concrete is 11.07 x 10-6 /oC while that for the 10% SDA/OPC blended cement concrete is 10.42 x 10-6 /oC. The linear coefficient of thermal expansion for the SDA/OPC blended cement concrete is significantly lower than that for the concrete made with 100% cement. 5.6 Linear Shrinkage The result of linear shrinkage of the test cubes is presented in Table 11 and Fig. 9 as a percentage reduction in the size of the test specimens. The rate of shrinkage is more in the 0% OPC replacement concrete than in the 10% SDA/OPC concrete. Linear shrinkage is lower in the 10% SDA/OPC concrete than it is in the 0% concrete. There is an increase in linear shrinkage for both cement replacement in concrete with temperature. The shrinkage of both of the test specimens is typically categorized as plastic. The addition of 10% SDA in the blended cement contributed to decreased shrinkage of concrete produced with it. The highest shrinkage for both concrete occurred at the highest temperature; therefore, linear shrinkage is dependent on the temperature at which the concrete is exposed to. The linear coefficient of thermal expansion result indicated the magnitude of thermal mismatch between the aggregate and the cement. 5.7 Cracking and Spalling Physical observation of the test specimens are made after exposing them to different temperatures. From the observation, there was a colour change in both concrete when exposed to temperatures of 600oC and 800oC. The OPC concrete was whitish-grey at 600oC and light-brown at 800oC while the SDA blended cement concrete was dark-grey at 600oC and deep-brown at 800oC. At 600oC the OPC concrete started experiencing slight fire cracks and surface peel-off, while the blended cement concrete only started experiencing fire cracks and surface peel-off at 800oC. There was no any detachment of particles or peel-off of the concrete surface for the SDA blended concrete when exposed to temperatures of 200oC, 400oC and 600oC while the OPC concrete started having surface peel-off and dislodgement at a temperature of 600oC. The dislodgement or detachment of small pieces of the surfaces of the concrete was more in the OPC than in the SDA blended cement at 800oC. However, the spalling was not explosive at 800oC but a dislodgement of a minor portion of the concrete edges. The dislodgement of the concrete edges in the OPC concrete as compared with SDA blended concrete is relative. VI. Figures and Tables Figure 1 Experimental programme to study the effect of SDA pozzolana blended cement concrete at elevated temperature. OPC + SDAOPC W/C = 0.60 W/C = 0.60 100% 90% + 10%
  • 6. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 6 | Page 2200 2300 2400 2500 2600 200 400 600 800 DensityKg/m3 Temperature oC Unheated Density Kg/m3 Figure 2 Densities of unheated and heated cubes at different temperatures for 0% OPC replacement 2200 2300 2400 2500 2600 200 400 600 800 DensityKg/m3 Temperature oC Unheated Density Kg/m3 Heated Density Kg/m3 Figure 3Densities of unheated and heated cubes at different temperatures for 10% OPC replacement 0 5 10 15 20 25 30 0 500 1000 CompressiveStrength N/mm2 Temperature oC 0% Replacement 10% Replacement Figure 4 Compressive strength development at different temperatures 0 1 2 3 4 5 0 500 1000 FlexuralStrength(N/mm2) Temperature oC Flexural Strength 0% Replacement Flexural Strength 10% Replacement Figure 5 Flexural strength development at different temperatures
  • 7. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 7 | Page 0 5 10 15 0 10 No.ofResistance (Cycles) Replacement (%) Test 1 Test 2 Test 3 Average Cycles Figure 6 Thermal shock resistance 1.6 1.65 1.7 1.75 1.8 0 10 ThermalConductivity W/m.K Replacement (%) Thermal Conductivity Figure 7 Variation of thermal conductivity with percentage replacement of cement content. 10 10.2 10.4 10.6 10.8 11 11.2 0 10 CoefficientofThermal ExpansionX10-6/oC Cement Replacement (%) Coefficient of Thermal Expansion X 10-6 /oC Figure 8Linear coefficient of thermal expansion 0 0.1 0.2 0.3 0.4 0.5 0.6 200 400 600 800 LinearShrinkage(%) Temperature oC 10% Replacement 0% Replacement Figure 9Effect of saw dust ash (SDA) on linear shrinkage of concrete with temperature. Table 1 Physical and Chemical Properties of Saw Dust Ash (SDA)
  • 8. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 8 | Page ELEMENTS SAW DUST ASH [SDA] Moisture Content (MC) 2.06% Specific Gravity 2.03 Compacted Bulk Density Loss on Ignition 4.97% PH Value 10.05 Al2O3 13.65% Fe2O3 13.34% SiO2 48.95% CaO 5.40% MgO 4.60% MnO 0.95% K2O 9.01% P2O5 3.10% SO3 1.00% Table 2 Mix Design per Cubic Metre of Concrete (1:2:4) Water/Cement Ratio 0.60 PROPERTIES CONTROL MIX BLENDED MIX Cement- OPC (Kg/m3 ) 25 22.5 SDA (Kg/m3 ) 0 2.5 Cementitous Binder (Kg/m3 ) 25 25 Coarse Aggregate (Kg/m3 ) 50 50 Fine Aggregate (Kg/m3 ) 100 100 Total Water (Kg) 15 15 Table 3 Density of Unheated and Heated Concrete Cubes Temperature 200o C 400o C 600o C 800o C 200o C 400o C 600o C 800o C Unheated Density Kg/m3 2438.5 2526 2570.4 2497.8 2555.6 2555.6 2444.5 2503.74 Heated Density Kg/m3 2376.3 2392.6 2444.5 2385.2 2494.9 2469.7 2333.4 2314.83 Percentage Decrease in Density Kg/m3 2.55 5.28 4.9 4.51 2.38 3.36 4.55 5.04 0% OPC Replacement 10% OPC Replacement Table 4 Variation of Compressive Strength with different Temperature Range Room Temperature 200o C 400o C 600o C 800o C 0 0.6 20.15 23.31 24.42 18.44 12.22 10 0.6 15.06 15.73 16.09 18.67 14.20 Percentage Replacement (%) Water/Cement Ratio Compressive Strength N/mm2 Table 5 Rate of Compressive Strength Gain and Loss 200o C : Room temperature 400o C : 200o C 600o C : 400o C 800o C : 600o C 0 1.16 1.05 1.32 1.51 10.22 29.11 10 1.04 1.02 1.16 1.31 7.59 23.94 Percentage Replacement (%) Strength Gain/Loss Average Percentage Loss (%) Average Percentage Gain (%)
  • 9. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 9 | Page Table 6 Variation of Flexural Strength with different Temperature Range Room Temperature 200o C 400o C 600o C 800o C 0 0.6 4.16 2.55 2.1 1.02 Nil 10 0.6 3.71 2.25 1.82 0.84 Nil Percentage Replacement (%) Water/Cement Ratio Flexural Strength (N/mm 2 ) Table 7 Rate of Flexural Strength Loss Percentage Replacement (%) 200o C : Room temperature 400o C : 200o C 600o C : 400o C 800o C : 600o C Average Strength Loss 0 1.61 0.45 0.98 1.01 10 1.46 0.43 0.98 0.96 Table 8 Result of Thermal Shock Resistance Test at 800o C Test 1 Test 2 Test 3 Average Cycle 0 3 5 4 4 10 12 14 12 13 Percentage Replacement (%) Number of Resistance in Cycles Table 9 Results of the Thermal Conductivity Test Percentage Replacement (%) Thermal Conductivity W/m.K 0 1.77 10 1.68 Table 10Results of the Linear Coefficient of Thermal Expansion Test Percentage Replacement (%) Coefficient of Thermal Expansion X 10 -6 / o C 0 11.07 10 10.43 Table 11Variation of Linear Shrinkage with different Temperature Range 200o C 400o C 600o C 800o C 0 0.6 0.21 0.225 0.235 0.24 10 0.6 0.24 0.244 0.246 0.25 Percentage Replacement (%) Water/Cement Ratio Linear Shrinkage (%) VII. Summaryand Conclusion Temperature influence on strength and durability of concrete is essential for it to have the characteristic of fire resistance. Concrete can be considered thermally stable when it retains its form and shape within the allowable limits, while exposed to high or elevated temperatures. This study finds out that particular chemical constituents of cement and pozzolanas are responsible for concrete performance under heat. The conclusion from the above investigation can be summarized as follows: 1. The density of concrete is found to decrease with temperature increased. The average percentage loss in density for the control concrete is 4.31% while that for the SDA/OPC blended cement concrete is 3.83%. The SDA/OPC blended cement concrete therefore retained more of its density after been exposed to higher temperatures, than the control concrete made of 100% cement, as a result of the SDA having a lower specific gravity than the OPC.
  • 10. Performance Of Concrete At Elevated Temperatures: Utilizing A Blended Ordinary Portland Cement www.iosrjournals.org 10 | Page 2. Concrete produced by blending cement with 10% SDA increased in compressive strength, when heated to 600oC, while the compressive strength of concrete produced with OPC reduces at the same temperature. 3. Concrete produced by blending OPC with 10% SDA retained more of its compressive strength at the different temperatures exposed to, than the concrete produced using only OPC. 4. At an elevated temperature of 800oC, both concrete specimens fail totally in flexure due to the effect of high heat on binding elements. The flexural strength of both the control concrete (at 0% OPC replacement) and SDA/OPC blended cement concrete (at 10% OPC replacement) decreased as the temperature is increased. Their performance in flexure is relative to each other. 5. Replacement of OPC by 10% SDA increased the thermal shock resistance of the concrete by 11 cycles more than the concrete produced with 100%. 6. The Saw dust ash (SDA) content had only a slight influence on thermal conductivity of the concrete as a result; cracking and spalling occurred more in the OPC concrete than in the SDA blended cement concrete. 7. Linear coefficient of thermal expansion for the SDA/OPC blended cement concrete is significantly lower than that for the concrete made with 100% cement. This is dependent on the temperature at which the concrete is treated. 8. The addition of in 10% SDA in the blended cement concrete contributed to the decreased in linear shrinkage of the concrete produced with the blended concrete. the shrinkage in OPC concrete is higher than in the 10% SDA/OPC concrete. 9. Slight fire cracks started occurring on the OPC concrete at 600oC with surface peel-off and dislodgement occurring at 800oC. The blended cement concrete experienced slight fire cracks and surface dislodgement at 800oC. Cracking and surface peel-off are relatively lower in the SDA blended cement concrete than in the OPC concrete. From the tests results, it can be deduced that the replacement of OPC with about 10% SDA in concrete relatively improved performance of concrete at elevated temperature. Blending of OPC with 10% SDA can therefore be applied as a fire resisting bonding material in concrete. In order to have a research that is multi-facetted in its approach, it is recommended that further studies be conducted on the performance of concrete at elevated temperature by varying the percentage replacement of cement with SDA and also using different concrete grades. References [1] A.M. Neville, Properties of concrete: Special Issues in Materials Testing (Pearson Education, Fourth Edition 2007). [2] G.A. Khoury, Performance of Heated Concrete—Mechanical Properties, Contract NUC/56/3604A with Nuclear Installations Inspectorate (Imperial College, London, August 1996). [3] S.A. Sumaila, and O.F. Job, Properties of SDA-OPC Concrete: A Preliminary Assessment, Journal of Environmental Sciences, 3(2), 1999, 155-159 [4] I.I. Dashan, and E.E.I. Kamang, Some Characteristics of AHA/OPC Concretes: A Preliminary Assessment, Nigerian Journal of Construction Technology and Management, 2(1), 1999, 22-28. [5] M.M. Morsy, S.S. Shebl, and A.M. Rashad, Effect of Fire on Microstructure and Mechanical Properties of Blended Cement Pastes Containing Metakaoline and Silica Fume. Asian Journal of Civil Engineering (Building and Housing), 9(2), 2008, 93-105. [6] G. Narenda, Effect of Fire on Concrete, Concrete International Magazine, April, 2006, www.highbeam.com/doc/1P3- 1106559491.html, Retrieved 22nd June, 2013 [7] M.S. Morsy, and S.S. Shebl, Effect of Silica Fume and MetakaolinePozzolana on the Performance of Blended Cement Pastes Against Fire. Ceramic Silikaty, 51(1), 2007, 40-44. [8] CCAA, Concrete Basics: A Guide to Concrete Practice, A Publication of Cement Concrete and Aggregate Australia, 2004, 6th edition. www.concrete.net.au, retrieved 15th April 2010. [9] B. Erlin, and W. Hime, The Fire Resistance of Concrete, Concrete Construction. Dec. 2004. [10] M. Zeiml, and R. Lackner, Experimental Investigation on Spalling Mechanisms in Heated Concrete, In Kukla, K. (2010), Concrete at high temperatures hygrothermo-mechanical degradation of concrete, doctoral thesis, Department of Civil Engineering, University of Glasgow, 2010. http://thesis.gla.ac.uk/1666/, retrieved 3rd July, 2011. [11] Wanye, Heat Resistance Concrete, Everything about concrete.com, http://www.everything-about-concrete.com/heat-resistant- concrete.html [12] D.J. Naus, The Effect of Elevated Temperature on Concrete Materials and Structures - A Literature Review (Prepared by Oak Ridge National Laboratory, Managed by UT-Battelle, LLC, P.O. Box 2008. Oak Ridge. U.S. Nuclear Regulatory Commission Washington, DC 20555-0001, 2006) [13] P.K. Mehta, Advancements in Concrete Technology, Journal of Concrete International. 96(4), 1999, 69-76. [14] H.K.M. Anwar, High Strength Blended Cement Concrete Incorporating Volcanic Ash: Performance at High Temperatures, Journal of Cement and Concrete Composites. 28, 2006, 535-545. [15] D.S. Matawal, Application of Ashes as Pozzolana in Mortar and Concrete Production, 1st National Academy Conference, 31st – 2nd September, 2005.