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Roup A., Kalmanovitch E., Baykov Y., Toledo V.
Shefa Yamim (A.T.M.) Ltd., 90 Herzel St., P.O.B. 720, Netanya – 42106
Web site: www.shefayamim.com E-mail: gold101@netvision.net.il
B”H
March,2009
In 1893, Nobel-Prize winning
scientist Henri Moissan began
studying fragments of this
meteorite from nearby Diablo
Canyon. In these fragments Dr.
Moissan discovered minute
quantities of a shimmering new
mineral, with fire and brilliance
never before seen on earth. After
extensive research, Dr. Moissan
concluded that this mineral was
made of silicon carbide. In 1905,
this mineral was named
moissanite, in his honor.
During Shefa Yamim exploration and prospecting activities, SY found this rare mineral in drill cores, and in samples taken from the up-surface of various magmatic
bodies on Mount Carmel. The crystals found ranged in sizes from 0.1mm to 2.2mm. More than one thousand pieces of moissanite were recovered in the area of the SY
licenses. This finding was made while drilling for diamonds in which 77 micro and macro diamonds have been found to date. 76 diamonds were found within drill cores in
the Kishon graben sedimentation and 1 diamond in the Rakefet Magmatic Complex (RMC) (De Beers, May 2004).
The colors of the moissanite grains varies between black, yellow, dark blue, blue green, green-blue, grey and colourless. Moissanite grains were found associated together
with large amounts of "Kimberlite Indicator Minerals" such as pyrope garnet, chrome-spinel, ilmenite, clinopyroxene (chrome-diopside), rutile etc'.
The result of 8 X-Ray tests (Chemical Department, Technion, Haifa, analyst Dr. M. Botoshansky) show that unit cell parameters of all examined samples ranges a=3.0794-
3.0810 (average 3.0806) and c=15.111-15.161 (average 15.125), c:a= 4.909 with primitive hexagonal symmetry. These crystallographic parameters are typical for
moissanite and characteristic of the 6H polytype. This typical moissanite modification is dark-coloured, hexagonal (6H-polytype), and usually occurs in association with
diamond, corundum, pyrope, Mg-rich olivine (forsterite) , and Cr-spinel in kimberlite pipes and alluvial placers.
The presence of moissanite indicates extreme reducing and ultra-high pressure conditions also favorable for diamond formation. Thermodynamic and thermochemical
data indicate the existence of moissanite in the P-T range of 1100-14000 K and 2.0-16.0 GPa in a Fe-free peridotite composition.
Despite the fact that results of SEM analyses of grains of moissanite may not always be 100% accurate concerning the variable Si/C ratio, according to Dr. Y. Levin and
Dr. P. Mukhin (November 2001) the chemical composition of more than 100 moissanite grains, which were analyzed by SEM (IGS, Jerusalem), shows a variable Si/C ratio of
the analyzed samples. This indicates that the moissanite grains contain excessive carbon and silica free phases from 5-6% average, compared with a theoretical moissanite
composition (Si-70.04 %, C-29.96 %).
Moissanite(-
2mm)
Moissanite(+2mm
)
Diamond and Moissanite Distribution in some of the Shefa Yamim drills
Diamond
3.5mm
Sample 602
Physical properties: moissanite belongs to the hexagonal crystal system, space group is P 63mc; cleavage is indistinct; refractive index of 2.65–2.69; density of 3.22 g/cm³; hardness of 9.25 and varies in
colour including clear, greyish green, greyish yellow, grey, greenish yellow, brownish yellow and yellow green (Read P.(2005. Moissanite is stable to temperatures up to 1127 °C (1400 K) and can withstand
pressures up to 52.1 GPa (Xu J. and Mao H., 2000). These properties make moissanite unique. Silicon carbide has a wide, adjustable bandgap, giving the mineral variable conductance properties, which
are useful in nanotechnology (Melinon P. et al 2007). Moissanite belongs to the carbon group and because of its similarity to diamonds it is used as a replacement for diamonds in fashion and in scientific
applications.
Name: moissanite
Synonyms: Carborundum, Silicon Carbide
Chemical Formula: SiC
Special gravity (g/cm3): 3.1 – 3.2
Hardness: 9.25 – 9.5
Luster: Adamantine, metallic
Color: Black, blue, green, green-yellow, colorless
Diaphaneity: Opaque to transparent
Refractive Index (brilliance): 2.65-2.69
Crystallography: Hexagonal and Trigonal polytypes
SY Moissanite in host rock (15% Moissanite content)
Sample 321Sample 216
“… One of the most indicative peculiarities of the Shefa Yamim
moissanite grains is systematical enrichment with free carbon,
which seems to be a solid phase and/or minor diamond
inclusions.The large quantity of moissanite in the host rock of the
Kishon river placer indicates undoubtedly about deposition of
diamonds at the same stratigraphic level... It promises, in addition
to high concentration of small grains of moissanite, that there is a
good chance to discover unique commercial deposit of moissanite
(in the sizes and commercial amounts) in the Shefa Yamim license
area. The potential’s of the Shefa Yamim license area will
incredibly increase, if large crystals of moissanite are found",
quote from "Moissanite – New Mineral Findings in the Shefa
Yamim Licence Area by Dr. Pavel Mukhin and Dr. Yaakov Levin
(November 25, 2001).
©MendyDesign
Geological occurrence: Moissanite, as a native silicon carbide is a very rare mineral, predominantly found (in small amounts) only in kimberlites (Yakutia, Central Asia, Ural Mts., Archangelsk district, Finland) and
in meteorites (Diablo Canyon). A new find hosted in serpentinite has recently been reported from the Dabie Mountains in China (Shutong Xu. et al., 2008). One unique specimen was found at a beach along the
Turkish coast of the Mediterranean Sea around 150 km NW from Izmir and is most likely derived from Tertiary volcanic rocks outcropping in the area (Rock-Forming moissanite (natural -silicon carbide) S. D.
Pierro, et al 2003). In addition, 14 blue-green grains of moissanite and 2 diamonds were found in the lamprophyric breccia by Cabo Mining in Canada. Discoveries have shown that moissanite occurs naturally as
inclusions in diamonds and xenoliths and in ultramafic rocks such as kimberlite and lamproite (Di Pierro et al., 2003).
Inclusions in moissanite (sample 59)
Green crystal (olivine?) Long incl.(rutile? olivine?)
Blue crystal. Anisotropy and isotrop.Gauze-liquid inclus
Olivine?
Dodecahedrons (garnet?)
Moissanite is found within the sedimentation along Emek
Yisrael and into the Zevulun Valley and almost to the
Mediterranean Sea (both sides of the Kishon River) – as well
as along Nahal Zippory. In addition, large amounts of
moissanite crystals were found within the Rakefet magmatic
complex (RMC). Nahal Rakefet flows into and joins Nahal
Yokneam; our largest moissanite discovery (3.5mm) was
made in the drainage area within the sediments of Nahal
Yokneam. There seems to be a "pattern" of findings in a
South to North direction.
There is no doubt about moissanite occurrence in the upper
cretaceous magmatic bodies, such as: Rakefet, Kerem
Maharal, Shefeya.

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Shefa Yamem Poster 2009

  • 1. Roup A., Kalmanovitch E., Baykov Y., Toledo V. Shefa Yamim (A.T.M.) Ltd., 90 Herzel St., P.O.B. 720, Netanya – 42106 Web site: www.shefayamim.com E-mail: gold101@netvision.net.il B”H March,2009 In 1893, Nobel-Prize winning scientist Henri Moissan began studying fragments of this meteorite from nearby Diablo Canyon. In these fragments Dr. Moissan discovered minute quantities of a shimmering new mineral, with fire and brilliance never before seen on earth. After extensive research, Dr. Moissan concluded that this mineral was made of silicon carbide. In 1905, this mineral was named moissanite, in his honor. During Shefa Yamim exploration and prospecting activities, SY found this rare mineral in drill cores, and in samples taken from the up-surface of various magmatic bodies on Mount Carmel. The crystals found ranged in sizes from 0.1mm to 2.2mm. More than one thousand pieces of moissanite were recovered in the area of the SY licenses. This finding was made while drilling for diamonds in which 77 micro and macro diamonds have been found to date. 76 diamonds were found within drill cores in the Kishon graben sedimentation and 1 diamond in the Rakefet Magmatic Complex (RMC) (De Beers, May 2004). The colors of the moissanite grains varies between black, yellow, dark blue, blue green, green-blue, grey and colourless. Moissanite grains were found associated together with large amounts of "Kimberlite Indicator Minerals" such as pyrope garnet, chrome-spinel, ilmenite, clinopyroxene (chrome-diopside), rutile etc'. The result of 8 X-Ray tests (Chemical Department, Technion, Haifa, analyst Dr. M. Botoshansky) show that unit cell parameters of all examined samples ranges a=3.0794- 3.0810 (average 3.0806) and c=15.111-15.161 (average 15.125), c:a= 4.909 with primitive hexagonal symmetry. These crystallographic parameters are typical for moissanite and characteristic of the 6H polytype. This typical moissanite modification is dark-coloured, hexagonal (6H-polytype), and usually occurs in association with diamond, corundum, pyrope, Mg-rich olivine (forsterite) , and Cr-spinel in kimberlite pipes and alluvial placers. The presence of moissanite indicates extreme reducing and ultra-high pressure conditions also favorable for diamond formation. Thermodynamic and thermochemical data indicate the existence of moissanite in the P-T range of 1100-14000 K and 2.0-16.0 GPa in a Fe-free peridotite composition. Despite the fact that results of SEM analyses of grains of moissanite may not always be 100% accurate concerning the variable Si/C ratio, according to Dr. Y. Levin and Dr. P. Mukhin (November 2001) the chemical composition of more than 100 moissanite grains, which were analyzed by SEM (IGS, Jerusalem), shows a variable Si/C ratio of the analyzed samples. This indicates that the moissanite grains contain excessive carbon and silica free phases from 5-6% average, compared with a theoretical moissanite composition (Si-70.04 %, C-29.96 %). Moissanite(- 2mm) Moissanite(+2mm ) Diamond and Moissanite Distribution in some of the Shefa Yamim drills Diamond 3.5mm Sample 602 Physical properties: moissanite belongs to the hexagonal crystal system, space group is P 63mc; cleavage is indistinct; refractive index of 2.65–2.69; density of 3.22 g/cm³; hardness of 9.25 and varies in colour including clear, greyish green, greyish yellow, grey, greenish yellow, brownish yellow and yellow green (Read P.(2005. Moissanite is stable to temperatures up to 1127 °C (1400 K) and can withstand pressures up to 52.1 GPa (Xu J. and Mao H., 2000). These properties make moissanite unique. Silicon carbide has a wide, adjustable bandgap, giving the mineral variable conductance properties, which are useful in nanotechnology (Melinon P. et al 2007). Moissanite belongs to the carbon group and because of its similarity to diamonds it is used as a replacement for diamonds in fashion and in scientific applications. Name: moissanite Synonyms: Carborundum, Silicon Carbide Chemical Formula: SiC Special gravity (g/cm3): 3.1 – 3.2 Hardness: 9.25 – 9.5 Luster: Adamantine, metallic Color: Black, blue, green, green-yellow, colorless Diaphaneity: Opaque to transparent Refractive Index (brilliance): 2.65-2.69 Crystallography: Hexagonal and Trigonal polytypes SY Moissanite in host rock (15% Moissanite content) Sample 321Sample 216 “… One of the most indicative peculiarities of the Shefa Yamim moissanite grains is systematical enrichment with free carbon, which seems to be a solid phase and/or minor diamond inclusions.The large quantity of moissanite in the host rock of the Kishon river placer indicates undoubtedly about deposition of diamonds at the same stratigraphic level... It promises, in addition to high concentration of small grains of moissanite, that there is a good chance to discover unique commercial deposit of moissanite (in the sizes and commercial amounts) in the Shefa Yamim license area. The potential’s of the Shefa Yamim license area will incredibly increase, if large crystals of moissanite are found", quote from "Moissanite – New Mineral Findings in the Shefa Yamim Licence Area by Dr. Pavel Mukhin and Dr. Yaakov Levin (November 25, 2001). ©MendyDesign Geological occurrence: Moissanite, as a native silicon carbide is a very rare mineral, predominantly found (in small amounts) only in kimberlites (Yakutia, Central Asia, Ural Mts., Archangelsk district, Finland) and in meteorites (Diablo Canyon). A new find hosted in serpentinite has recently been reported from the Dabie Mountains in China (Shutong Xu. et al., 2008). One unique specimen was found at a beach along the Turkish coast of the Mediterranean Sea around 150 km NW from Izmir and is most likely derived from Tertiary volcanic rocks outcropping in the area (Rock-Forming moissanite (natural -silicon carbide) S. D. Pierro, et al 2003). In addition, 14 blue-green grains of moissanite and 2 diamonds were found in the lamprophyric breccia by Cabo Mining in Canada. Discoveries have shown that moissanite occurs naturally as inclusions in diamonds and xenoliths and in ultramafic rocks such as kimberlite and lamproite (Di Pierro et al., 2003). Inclusions in moissanite (sample 59) Green crystal (olivine?) Long incl.(rutile? olivine?) Blue crystal. Anisotropy and isotrop.Gauze-liquid inclus Olivine? Dodecahedrons (garnet?) Moissanite is found within the sedimentation along Emek Yisrael and into the Zevulun Valley and almost to the Mediterranean Sea (both sides of the Kishon River) – as well as along Nahal Zippory. In addition, large amounts of moissanite crystals were found within the Rakefet magmatic complex (RMC). Nahal Rakefet flows into and joins Nahal Yokneam; our largest moissanite discovery (3.5mm) was made in the drainage area within the sediments of Nahal Yokneam. There seems to be a "pattern" of findings in a South to North direction. There is no doubt about moissanite occurrence in the upper cretaceous magmatic bodies, such as: Rakefet, Kerem Maharal, Shefeya.