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IUPAC Nomenclature
Naming Molecules by Following
the Rules
Getting Started…
• You first have to identify the “family”
that your molecule belongs to…
• So, check for functional groups…
• If there are none, then your molecule is
simply an alkane…
The Three Basic Parts
• The name for any organic molecule
consists of three basic parts:
Prefixes-Parent-Suffix
• Each part of the name has a purpose.
Basic Part - Suffixes
• Suffixes on the end of the name of an
organic molecule tell you what major
family the molecule belongs to
• The suffix for an alkane is “-ane”
Basic Part – the Parent
• The “parent” part of the name tells you
how many carbons are in the main chain
of the molecule
• The main chain of the molecule is
defined for alkanes as being the longest
chain in the molecule
Parent and suffix…
• The parent is named based on the
number of carbons
• 1 carbon = “meth”
• So a one-carbon alkane is called
methane
CH4
Parent and suffix…
• 2 carbons = “eth”
• So a two carbon alkane is called ethane.
CH3CH3
Parent and suffix…
• 3 carbons = “prop”
• So a three carbon alkane is called
propane.
CH3CH2CH3
Parent and suffix…
• 4 carbons = “but”
• So a four carbon alkane is called butane.
CH3CH2CH2CH3
And now the rest…
• 5 carbons = “pent”
• 6 carbons = “hex”
• 7 carbons = “hept”
• 8 carbons = “oct”
• 9 carbons = “non”
• 10 carbons = “dec”
• So be brilliant and name the following
alkane (shown as both condensed
formula and a skeletal structure)
CH3CH2CH2CH2CH2CH2CH2CH2CH3
or
Answer?
• That’s right!
• nine carbons + alkane family = NONANE
• One more thing - Should you have two
or more chains that are the same
length, the parent is the one with the
most prefixes…
• But - We need to talk Prefixes first…
we’ll come back to this…
Here we go – the Prefixes
• Prefixes are the bits and pieces that
are attached to the main chain (parent)
of the molecule.
• An example of a prefix might be a
halide attached to the main chain as in:
Br
Prefixes – the Halides
• The family called alkyl halides does not
have a suffix.
• Halides are always named as prefixes.
• Fluorine is called “fluoro”
• Chlorine is called “chloro”
• Bromine is called “bromo”
• Iodine is called “iodo”
Putting together a name…
• The rules for IUPAC nomenclature
include:
• Step 1: Find the main chain
• Step 2: Number the main chain
• Step 3: Identify all prefixes and their
position numbers
• Step 4: Write the full name: Prefixes-
Parent-Suffix
Now let’s take a look:
• Follow the rules… Name this molecule…
Br
Find the main chain…
• The longest chain in this molecule has
seven carbons… and only a halide (which
is always named as a prefix).
• This will be a heptane.
Br
Number the chain…
• This molecule is symmetrical. It doesn’t
matter if we go left to right or right to
left… that bromine is attached to
carbon #4
Br
4
Final Answer?
• If you put the prefix first, then parent
and suffix, what do you get?
• “Bromo hept ane” includes all of the
pieces, except for indicating where the
bromine is attached...
• 4-bromoheptane is the complete name.
Br
4
What would you do different..?
• How would you name this one?
• Number this asymmetric molecule by
beginning your numbering from
whichever end is closest to the first
substituent (aka: branch, prefix).
Br
So in this case…
• You would number from left to right, so
the bromine winds up on position #3.
• If you numbered from the other end,
the bromine would be on #5.
• Always aim for the lowest possible
number on the first substituent!
Br
Final Answer (again)?
• 3-bromoheptane
Br
More Prefixes
• The most common prefixes we have in
organic molecules are those little
fragments of carbon pieces attached to
the main chains.
• The carbon fragments are called “alkyl
groups”. They all end in “-yl” to indicate
they are fragments of a bigger
molecule.
Alkyl Groups
• Alkyl groups are named similarly to
alkanes, based on the number of
carbons in the fragment.
• A fragment of methane, CH4, would be
CH3-
• This fragment is called “methyl” where
“meth” stands for one carbon and “yl”
stands for fragment (alkyl group).
Methyl Group
• The molecule shown here has a 7-carbon
main chain.
• Notice that it has a branch attached to
carbon #4. This branch has a single
carbon – a methyl group.
• 4-methylheptane is the name of this
compound.
Ethyl Groups
• A two-carbon alkane is called ethane,
CH3CH3. The corresponding two-carbon
fragment is always CH3CH2-, which is
called “ethyl”.
• 4-ethylheptane is the name for this one.
Propyl Groups
• There are two possible three-carbon
alkyl groups to form from propane,
CH3CH2CH3.
• The straight chain version: CH3CH2CH2-
which is called “propyl” or “n-propyl”
(where n stands for “normal” or
straight-chained)
Isopropyl Groups
• There are two possible three-carbon
alkyl groups to form from propane,
CH3CH2CH3.
• The other possibility is to form the
fragment on the central carbon:
CH3CHCH3, which is called “isopropyl”
Butyl Groups
• There are two possible four-carbon
alkyl groups to form from butane,
CH3CH2CH2CH3.
• One possibility is to form the fragment
on one of the end carbons:
CH3CH2CH2CH2-, which is called “butyl”
or “n-butyl”
Sec-Butyl Groups
• The other possibility is to form the
fragment one of the central carbons:
CH3CHCH2CH3, which is called “sec-
butyl”. [Note that the carbon second
from the left only has three bonds – so
that’s where its bonding to the main
chain]
Isobutyl Groups
• There are two other possible four-
carbon alkyl groups to form from
isobutane, (CH3)3CH.
• One is formed as a fragment on one of
the three symmetrical end carbons:
(CH3)2CH(CH2)-, which is called
“isobutyl”
Tert-butyl Groups
• The other is formed as a fragment on
the one central carbon, (CH3)3C-, which
is called “tert-butyl”
What alkyl groups do you see?
• There’s two groups attached to the ring
below. What are they?
What alkyl groups do you see?
• The group in red has two carbons and is
an ethyl group.
• The group in blue has four carbons.
Three in a row and the extra attached
at the middle carbon. Its an isobutyl
group.
What alkyl groups do you see?
• There’s two groups attached to the ring
below. What are they?
What alkyl groups do you see?
• The group in red has three carbons
attached at the middle carbon and is an
isopropyl group.
• The group in blue has four carbons, in a
row, attached at one of the middle
carbons. It’s a sec-butyl group.
More about Prefixes…
• Every prefix needs a position number…
• And prefixes are always alphabetized by
their first letter:
– Methyl is an “m”
– Ethyl is an “e”
– Propyl is a “p”
– Isopropyl is an “i”
– Sec-butyl is a “b”… (Say what??)
Alphabetizing Prefixes…
• Sec-butyl and tert-butyl both have a
descriptive prefix that tells you the
structure of those alkyl groups... (the
prefix has a prefix!)
• When alphabetizing, we do NOT use
these descriptive prefixes (like sec- or
tert-) to alphabetize…
Continuing with Prefixes…
• If you have multiples of the same
prefixes, like two bromines in the same
molecule, you COULD name them
separately or you could combine them
into a single prefix name and include “di-
” in front to indicate TWO of them.
• 3,4-dibromohexane!
Br
Br
Continuing with Prefixes…
• Di-, tri- and tetra- are more prefixes
for the prefixes.
• Remember - when alphabetizing for
names, prefixes are never alphabetized
using a “prefix” like di- or sec-.
– Sec-butyl is a “b”
– Dimethyl is a “m”
Name the following molecule:
• Keeping all of the rules in mind, what
would you name this molecule:
And the answer is…?
• Longest chain: nine carbons
• Number: left to right (hit that first
branch on #4)
• Group on #4 is methyl.
• Group on #5 is isopropyl.
• Alphabetize!
• 5-isopropyl-4-methylnonane.
4
5
About that main chain again…
• Recall that we said if you had two chains
the same length, the parent is the one
with the most branches. Which is the
parent in this example?
Where’s the Parent?
• There are two options: Option 1 is
highlighted in red:
• Option 2 is highlighted in blue:
And the winner is…
• The red one has two branches:
• The blue one has three branches:
• The blue one is the parent.
• Write that name…
Finally… the name…
• Eight carbons in main chain. Octane.
• Number left to right (first branch on #2!)
• Three alkyl groups attached:
• 2-methyl
• 5-propyl
• 6-methyl
• Simplify prefixes by using 2,6-dimethyl
• Full name: 2,6-dimethyl-5-propyloctane.
2
5
6
The last kind of alkyl groups –
Complex Branches
• Complex branches are those that have
no simple name, yet they still need to be
named.
• Identify the complex branch and its
point of attachment.
Naming Complex Branches
• Find the point of attachment inside the
complex branch itself, first.
Naming Complex Branches
• Number the longest branch of that
complex branch, starting from the point
of attachment, #1. In this case, propyl
is the miniature parent.
1
2
3
Naming Complex Branches
• Identify the prefixes on that little
miniature parent (in this case, the
propyl chain) of the complex branch, and
their position numbers.
• In this example, there are two methyls
attached to #1.
1
2
3
Naming Complex Branches
• Write the full name, placing the
complex branch inside brackets. This
complex branch is attached to #5 of
the original main chain so:
• 5-[1,1-dimethylpropyl]nonane is the
name.
1
2
3
Now: Cyclic Compounds
• When naming cyclic compounds, first
determine if the ring is the parent, or
not.
• If the ring has more carbons than any
of the alkyl groups attached, the ring is
the parent.
• If not, the ring becomes a cycloalkyl
group and is a prefix for the main chain.
Cyclic Compounds – Parent?
• In this example, the ring has four
carbons and the chain has eight.
• The chain is the parent and the ring is a
prefix.
• The ring is a cyclobutyl group on #1.
• 1-cyclobutyloctane.
Cyclic Compounds
• In this example, the ring has five carbons
and the alkyl group has three.
• The five-carbon ring is the parent and is
called cyclopentane.
• The one alkyl group will be on #1 (of
course – that #1 isn’t even needed!)
• Propylcyclopentane is the name.
Cyclic Compounds
• Word of caution: don’t double dip… its
really easy to double count the carbon
(*) that the alkyl group is attached to.
• Alkyl groups are only those BEYOND
the ring carbons. Thus, this is a propyl
group not a butyl group.
*
1
2
3
Cyclic Compounds – Multiple
Groups
• When a ring has multiple groups, the
rule for numbering is: “Number around
the ring so as to arrive at the lowest
possible sum of the position numbers”.
• The sum in this molecule is 1 + 3 = 4.
1
3
Cyclic Compounds – Multiple
Groups
• How about this one?
Cyclic Compounds – Multiple
Groups
• Lowest possible sum?
• 1 + 2 + 4 = 7
1
2
4
Cyclic Compounds – Multiple
Groups
• If you have two possibilities for lowest
possible sum, THEN (and only then) you
should alphabetize to prioritize your
groups.
• What about this one?
Cyclic Compounds – Multiple
Groups
• Two possible “lowest sums” of 4, where
the groups must be on carbons #1 and
#3.
• Prioritize by alphabetizing – the ethyl
will be #1 and the isopropyl will be #3.
• Name? 1-ethyl-3-isopropylcyclopentane
Cyclic Compounds – Two groups
• Last comment – when you have two
groups attached to a molecule, they can
potentially either both face up (or
down) in the same direction (CIS) or one
faces up and the other faces down
(TRANS)
• We use wedges to indicate “up” or
towards you and dashes for “down” or
away.
Cyclic Compounds – Two groups
• The molecule on the left has two methyl
groups facing down (CIS) and the one on
the right has one down and one up
(TRANS).
CIS TRANS
Cyclic Compounds – Two groups
• Incorporating that into the name: Place
the term “cis” or “trans” in the
beginning of the name, before the first
prefix
• Name? CIS-1,2-dimethylcyclohexane
Finale
• I think this covers everything that you
should know and be able to do for
naming basic alkanes and cycloalkanes.
• As we add more families (alkenes,
alkynes, etc) we will build on this
“foundation” of nomenclature rules…
• Good luck…

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  • 1. IUPAC Nomenclature Naming Molecules by Following the Rules
  • 2. Getting Started… • You first have to identify the “family” that your molecule belongs to… • So, check for functional groups… • If there are none, then your molecule is simply an alkane…
  • 3. The Three Basic Parts • The name for any organic molecule consists of three basic parts: Prefixes-Parent-Suffix • Each part of the name has a purpose.
  • 4. Basic Part - Suffixes • Suffixes on the end of the name of an organic molecule tell you what major family the molecule belongs to • The suffix for an alkane is “-ane”
  • 5. Basic Part – the Parent • The “parent” part of the name tells you how many carbons are in the main chain of the molecule • The main chain of the molecule is defined for alkanes as being the longest chain in the molecule
  • 6. Parent and suffix… • The parent is named based on the number of carbons • 1 carbon = “meth” • So a one-carbon alkane is called methane CH4
  • 7. Parent and suffix… • 2 carbons = “eth” • So a two carbon alkane is called ethane. CH3CH3
  • 8. Parent and suffix… • 3 carbons = “prop” • So a three carbon alkane is called propane. CH3CH2CH3
  • 9. Parent and suffix… • 4 carbons = “but” • So a four carbon alkane is called butane. CH3CH2CH2CH3
  • 10. And now the rest… • 5 carbons = “pent” • 6 carbons = “hex” • 7 carbons = “hept” • 8 carbons = “oct” • 9 carbons = “non” • 10 carbons = “dec”
  • 11. • So be brilliant and name the following alkane (shown as both condensed formula and a skeletal structure) CH3CH2CH2CH2CH2CH2CH2CH2CH3 or
  • 12. Answer? • That’s right! • nine carbons + alkane family = NONANE • One more thing - Should you have two or more chains that are the same length, the parent is the one with the most prefixes… • But - We need to talk Prefixes first… we’ll come back to this…
  • 13. Here we go – the Prefixes • Prefixes are the bits and pieces that are attached to the main chain (parent) of the molecule. • An example of a prefix might be a halide attached to the main chain as in: Br
  • 14. Prefixes – the Halides • The family called alkyl halides does not have a suffix. • Halides are always named as prefixes. • Fluorine is called “fluoro” • Chlorine is called “chloro” • Bromine is called “bromo” • Iodine is called “iodo”
  • 15. Putting together a name… • The rules for IUPAC nomenclature include: • Step 1: Find the main chain • Step 2: Number the main chain • Step 3: Identify all prefixes and their position numbers • Step 4: Write the full name: Prefixes- Parent-Suffix
  • 16. Now let’s take a look: • Follow the rules… Name this molecule… Br
  • 17. Find the main chain… • The longest chain in this molecule has seven carbons… and only a halide (which is always named as a prefix). • This will be a heptane. Br
  • 18. Number the chain… • This molecule is symmetrical. It doesn’t matter if we go left to right or right to left… that bromine is attached to carbon #4 Br 4
  • 19. Final Answer? • If you put the prefix first, then parent and suffix, what do you get? • “Bromo hept ane” includes all of the pieces, except for indicating where the bromine is attached... • 4-bromoheptane is the complete name. Br 4
  • 20. What would you do different..? • How would you name this one? • Number this asymmetric molecule by beginning your numbering from whichever end is closest to the first substituent (aka: branch, prefix). Br
  • 21. So in this case… • You would number from left to right, so the bromine winds up on position #3. • If you numbered from the other end, the bromine would be on #5. • Always aim for the lowest possible number on the first substituent! Br
  • 22. Final Answer (again)? • 3-bromoheptane Br
  • 23. More Prefixes • The most common prefixes we have in organic molecules are those little fragments of carbon pieces attached to the main chains. • The carbon fragments are called “alkyl groups”. They all end in “-yl” to indicate they are fragments of a bigger molecule.
  • 24. Alkyl Groups • Alkyl groups are named similarly to alkanes, based on the number of carbons in the fragment. • A fragment of methane, CH4, would be CH3- • This fragment is called “methyl” where “meth” stands for one carbon and “yl” stands for fragment (alkyl group).
  • 25. Methyl Group • The molecule shown here has a 7-carbon main chain. • Notice that it has a branch attached to carbon #4. This branch has a single carbon – a methyl group. • 4-methylheptane is the name of this compound.
  • 26. Ethyl Groups • A two-carbon alkane is called ethane, CH3CH3. The corresponding two-carbon fragment is always CH3CH2-, which is called “ethyl”. • 4-ethylheptane is the name for this one.
  • 27. Propyl Groups • There are two possible three-carbon alkyl groups to form from propane, CH3CH2CH3. • The straight chain version: CH3CH2CH2- which is called “propyl” or “n-propyl” (where n stands for “normal” or straight-chained)
  • 28. Isopropyl Groups • There are two possible three-carbon alkyl groups to form from propane, CH3CH2CH3. • The other possibility is to form the fragment on the central carbon: CH3CHCH3, which is called “isopropyl”
  • 29. Butyl Groups • There are two possible four-carbon alkyl groups to form from butane, CH3CH2CH2CH3. • One possibility is to form the fragment on one of the end carbons: CH3CH2CH2CH2-, which is called “butyl” or “n-butyl”
  • 30. Sec-Butyl Groups • The other possibility is to form the fragment one of the central carbons: CH3CHCH2CH3, which is called “sec- butyl”. [Note that the carbon second from the left only has three bonds – so that’s where its bonding to the main chain]
  • 31. Isobutyl Groups • There are two other possible four- carbon alkyl groups to form from isobutane, (CH3)3CH. • One is formed as a fragment on one of the three symmetrical end carbons: (CH3)2CH(CH2)-, which is called “isobutyl”
  • 32. Tert-butyl Groups • The other is formed as a fragment on the one central carbon, (CH3)3C-, which is called “tert-butyl”
  • 33. What alkyl groups do you see? • There’s two groups attached to the ring below. What are they?
  • 34. What alkyl groups do you see? • The group in red has two carbons and is an ethyl group. • The group in blue has four carbons. Three in a row and the extra attached at the middle carbon. Its an isobutyl group.
  • 35. What alkyl groups do you see? • There’s two groups attached to the ring below. What are they?
  • 36. What alkyl groups do you see? • The group in red has three carbons attached at the middle carbon and is an isopropyl group. • The group in blue has four carbons, in a row, attached at one of the middle carbons. It’s a sec-butyl group.
  • 37. More about Prefixes… • Every prefix needs a position number… • And prefixes are always alphabetized by their first letter: – Methyl is an “m” – Ethyl is an “e” – Propyl is a “p” – Isopropyl is an “i” – Sec-butyl is a “b”… (Say what??)
  • 38. Alphabetizing Prefixes… • Sec-butyl and tert-butyl both have a descriptive prefix that tells you the structure of those alkyl groups... (the prefix has a prefix!) • When alphabetizing, we do NOT use these descriptive prefixes (like sec- or tert-) to alphabetize…
  • 39. Continuing with Prefixes… • If you have multiples of the same prefixes, like two bromines in the same molecule, you COULD name them separately or you could combine them into a single prefix name and include “di- ” in front to indicate TWO of them. • 3,4-dibromohexane! Br Br
  • 40. Continuing with Prefixes… • Di-, tri- and tetra- are more prefixes for the prefixes. • Remember - when alphabetizing for names, prefixes are never alphabetized using a “prefix” like di- or sec-. – Sec-butyl is a “b” – Dimethyl is a “m”
  • 41. Name the following molecule: • Keeping all of the rules in mind, what would you name this molecule:
  • 42. And the answer is…? • Longest chain: nine carbons • Number: left to right (hit that first branch on #4) • Group on #4 is methyl. • Group on #5 is isopropyl. • Alphabetize! • 5-isopropyl-4-methylnonane. 4 5
  • 43. About that main chain again… • Recall that we said if you had two chains the same length, the parent is the one with the most branches. Which is the parent in this example?
  • 44. Where’s the Parent? • There are two options: Option 1 is highlighted in red: • Option 2 is highlighted in blue:
  • 45. And the winner is… • The red one has two branches: • The blue one has three branches: • The blue one is the parent. • Write that name…
  • 46. Finally… the name… • Eight carbons in main chain. Octane. • Number left to right (first branch on #2!) • Three alkyl groups attached: • 2-methyl • 5-propyl • 6-methyl • Simplify prefixes by using 2,6-dimethyl • Full name: 2,6-dimethyl-5-propyloctane. 2 5 6
  • 47. The last kind of alkyl groups – Complex Branches • Complex branches are those that have no simple name, yet they still need to be named. • Identify the complex branch and its point of attachment.
  • 48. Naming Complex Branches • Find the point of attachment inside the complex branch itself, first.
  • 49. Naming Complex Branches • Number the longest branch of that complex branch, starting from the point of attachment, #1. In this case, propyl is the miniature parent. 1 2 3
  • 50. Naming Complex Branches • Identify the prefixes on that little miniature parent (in this case, the propyl chain) of the complex branch, and their position numbers. • In this example, there are two methyls attached to #1. 1 2 3
  • 51. Naming Complex Branches • Write the full name, placing the complex branch inside brackets. This complex branch is attached to #5 of the original main chain so: • 5-[1,1-dimethylpropyl]nonane is the name. 1 2 3
  • 52. Now: Cyclic Compounds • When naming cyclic compounds, first determine if the ring is the parent, or not. • If the ring has more carbons than any of the alkyl groups attached, the ring is the parent. • If not, the ring becomes a cycloalkyl group and is a prefix for the main chain.
  • 53. Cyclic Compounds – Parent? • In this example, the ring has four carbons and the chain has eight. • The chain is the parent and the ring is a prefix. • The ring is a cyclobutyl group on #1. • 1-cyclobutyloctane.
  • 54. Cyclic Compounds • In this example, the ring has five carbons and the alkyl group has three. • The five-carbon ring is the parent and is called cyclopentane. • The one alkyl group will be on #1 (of course – that #1 isn’t even needed!) • Propylcyclopentane is the name.
  • 55. Cyclic Compounds • Word of caution: don’t double dip… its really easy to double count the carbon (*) that the alkyl group is attached to. • Alkyl groups are only those BEYOND the ring carbons. Thus, this is a propyl group not a butyl group. * 1 2 3
  • 56. Cyclic Compounds – Multiple Groups • When a ring has multiple groups, the rule for numbering is: “Number around the ring so as to arrive at the lowest possible sum of the position numbers”. • The sum in this molecule is 1 + 3 = 4. 1 3
  • 57. Cyclic Compounds – Multiple Groups • How about this one?
  • 58. Cyclic Compounds – Multiple Groups • Lowest possible sum? • 1 + 2 + 4 = 7 1 2 4
  • 59. Cyclic Compounds – Multiple Groups • If you have two possibilities for lowest possible sum, THEN (and only then) you should alphabetize to prioritize your groups. • What about this one?
  • 60. Cyclic Compounds – Multiple Groups • Two possible “lowest sums” of 4, where the groups must be on carbons #1 and #3. • Prioritize by alphabetizing – the ethyl will be #1 and the isopropyl will be #3. • Name? 1-ethyl-3-isopropylcyclopentane
  • 61. Cyclic Compounds – Two groups • Last comment – when you have two groups attached to a molecule, they can potentially either both face up (or down) in the same direction (CIS) or one faces up and the other faces down (TRANS) • We use wedges to indicate “up” or towards you and dashes for “down” or away.
  • 62. Cyclic Compounds – Two groups • The molecule on the left has two methyl groups facing down (CIS) and the one on the right has one down and one up (TRANS). CIS TRANS
  • 63. Cyclic Compounds – Two groups • Incorporating that into the name: Place the term “cis” or “trans” in the beginning of the name, before the first prefix • Name? CIS-1,2-dimethylcyclohexane
  • 64. Finale • I think this covers everything that you should know and be able to do for naming basic alkanes and cycloalkanes. • As we add more families (alkenes, alkynes, etc) we will build on this “foundation” of nomenclature rules… • Good luck…