2. Seminar Outline
- Introduction
- What is a Biodiesel
- Sources of Biodiesel
- Transesterification
- Simple approach to make a Biodiesel
- Properties of Biodiesel
- Material compatibility of Biodiesel
- Applications of Biodiesel
- Benefits & Disadvantages of Biodiesel
- Biodiesel Emissions
5. Transesterification
CH2OH-R1 catalyst CH2OH
| |
CHOH-R2 + 3CH3OH 3CH3OHRx+ CHOH
| |
CH2OH-R3 CH2OH
Triglyceride 3 Methanol Biodiesel Glycerin
R1, R2, and R3 are fatty acid alkyl groups
(could be different, or the same), and depend
on the type of oil. The fatty acids involved
determine the final properties of the biodiesel
(cetane number, cold flow properties, etc.)
8. Properties of Biodiesel
- Calorific value- 37.27 MJ/kg
- Color- Varies from Golden to Dark Brown
- Flash point- >130 °C, >266 °F
- density ~ 0.88 g/cm³
- High boiling point
- Low vapor pressure
- Immiscible with water
- No sulphur content
- High Cetane number
9. Material compatibility
- Plastics- HDPE is compatible, PVC is not
compatible, Polysrtyne get dissolves
- Metals: Biodiesel has an effect on copper-
based materials (e.g. brass), and it also affects
zinc, tin, lead, and cast iron. Stainless steels
(316 and 304) and aluminum are unaffected
- Rubber: Biodiesel also affects some types of
natural rubbers
10. Applications
- Vehicular use and Manufacturer acceptance
- Railway uses
- Aircraft uses
- As a heating oil
- For cleaning oil spill
- In generators
11. Benefits of Biodiesel
- Clean fuel that is an excellent alternative to
petroleum.
- Hundred percent renewable
- A positive impact on the environment
- No or little vehicle modifications or special
fuelling equipment
- With a high flash point, biodiesel is safer to
handle and store
- provides excellent lubricity to the fuel
injection system
12. - Provides significantly reduced emissions of carbon
monoxide, particulate matter, unburned
hydrocarbons, and sulphates
- Helps reduce the risk of global warming by
reducing net carbon emissions to the atmosphere
- Being derived from vegetable oils, biodiesel is
naturally non-toxic
- In both soil and water, biodiesel degraded at a rate
4 times faster than regular diesel fuel
- can be made from different oils and fats, waste
products. Waste cooking oil, animal feed mixtures
can be converted to high quality biodiesel
13. Disadvantages
• Lower Energy Content
• Less energy produces , but have also higher cetane ,
lubricity, etc.
• Poor cold weather performance
• This can be mitigated by blending with diesel fuel or with
additives, or using low gel point feedstocks such as
rapeseed/canola.
• Stability Concerns
• Biodiesel is less oxidatively stable than petroleum diesel
fuel. Old fuel can become acidic and form sediments and
varnish. Additives can prevent this.
• Scalability
• Current feedstock technology limits large scalability
15. Conclusion
- By knowing about the biodiesel as a fuel we came to
know that, biodiesel is the today's best alternatives
for the fossils fuels like diesel and gasoline.
- It can be used in vehicles with some modification in
the vehicle
- Production of biodiesel is easy as compared to the
fossil fuels, also it is easy to handle and less pollutant
than that of fossil fuels.
- Biodiesel is environment friendly and human friendly
Not the same as straight vegetable oils, oils are converted to methyl esters BXX = volume XX% biodiesel
Diesel flashpoint is?
Biodiesel is the first and only alternative fuel to have a complete evaluation of emissions results and potential health effects submitted to the US EPA under the Clean Air Act 211 (b) Both Tier I and Tier II have been completed. Dept of Air Quality states that even w/ slight increase in nox, other benefits still makes it worthwhile - NOx reducing additive is being developed PAH (polycyclic Aromatic Hydrocarbons): Incomplete combustion from motor vehicles, domestic heating and forest fires are major sources of PAH in the atmosphere.
Carbon Neutral: CO2 is taken up from plants growing and then released again when combusted, no net increase in CO2 The soybean plants take up more CO2 than is released in the biodiesel Conclusion of a full lifecycle analysis conducted by the National Renewable Energy Laboratory (NREL) for the U.S. Dept of Energy and the US Dept of Agriculture (NREL/SR-580-24089 UC Category 1503) entitled "Life Cycle Inventory of Biodiesel and Petroleum Diesel for Use in an Urban Bus”