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Anaerobic Digestion of Dairy
Manure Influenced by the Wasted
Milk from Milking Operations
X. Wu, C. Dong, W. Yao, J. Zhu
Dept. of Bioproducts and Biosystems
Engineering
University of Minnesota
Introduction
• Milking parlor generates milk contaminated
water ending up in manure lagoon
• Milk has high COD (190,000 mg/L)
• Lagoon digesters are the commonly used
type on current dairy farms
• What will be the impact
of milk on digester
function in terms of
biogas production?
Objectives and procedures
• Investigate the overall response of co-
digesting dairy manure with milk using lab-
scale batch anaerobic digesters
• Milk was added to manure at 7 different
levels, i.e., 1, 3, 5, 7, 9, and 14%
• Evaluation was based
on total biogas volume
produced, methane
content, and other
chemical variables
Objectives and procedures
• Fresh dairy manure was collected from a
dairy farm equipped with a scraped manure
handling system
• Raw milk for the experiment was obtained
from another dairy farm close to
Waseca, MN
• One control digester without milk addition
was run side by side with the milk treated
digesters
• Biogas composition was determined for
each digester every two days using a GC
Results
• Increasing milk content increases
cumulative biogas production
Results
• Increasing milk content increases
cumulative biogas production
0
2000
4000
6000
8000
10000
12000
0 2 4 6 8 10 12 14 16 18 20
Totalbiogasproduced(mL)
Percent of milk added (%)
Results
• Maximum biogas production rate for each
treatment can be obtained by the slopes of the
volume curves.
10
14
18
22
26
0 3 6 9 12 15 18 21
Biogasproductionrate(mL/h)
Percent milk added (%)
Results
• Milk effect on COD reduction and TKN
The average values of COD and TKN for the batch digestion process with different milk content1
Milk content COD (mg/L)*
TKN (mg/L) C/N ratio2
Initial Final Reduction Initial Final Reduction Initial Final3
(%) (%)4
0 (Control) 14500 7300 49.7 2794 2742 1.9 5.19 2.665
1% 15561 7700 50.5 2817 2792 0.9 5.52 2.766
3% 17683 7300 58.7 2863 2840 0.8 6.18 2.577
5% 19805 8100 59.1 2909 2794 4.0 6.81 2.898
7% 21927 8300 62.1 2955 2908 1.6 7.42 2.859
9% 24049 7600 68.4 3002 2970 1.0 8.01 2.5610
14% 29354 7800 73.4 3117 3080 1.1 9.42 2.5311
19% 34659 7700 77.8 3232 3206 0.8 10.7 2.4012
13
*COD – chemical oxygen demand; TKN – total Kjeldahl nitrogen14
15
Conclusion
The following conclusions can be reached based on
the data from this study.
• Added milk will increase biogas volumetric
production and the maximum biogas production
rate as compared to the control (7 and 18% vs. 1
and 3%).
• Added milk will reduce the methane content in the
biogas produced, thus increasing CO2 production.
To avoid excessive CO2 production, the milk
content in the digester liquid should be ≤ 3%.
• Added milk will increase COD removal efficiency
from 49.7% (no milk) to 77.8% (19% milk)

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Dairy Manure Digestion Influenced by Wasted Milk from Milking Operations

  • 1. Anaerobic Digestion of Dairy Manure Influenced by the Wasted Milk from Milking Operations X. Wu, C. Dong, W. Yao, J. Zhu Dept. of Bioproducts and Biosystems Engineering University of Minnesota
  • 2. Introduction • Milking parlor generates milk contaminated water ending up in manure lagoon • Milk has high COD (190,000 mg/L) • Lagoon digesters are the commonly used type on current dairy farms • What will be the impact of milk on digester function in terms of biogas production?
  • 3. Objectives and procedures • Investigate the overall response of co- digesting dairy manure with milk using lab- scale batch anaerobic digesters • Milk was added to manure at 7 different levels, i.e., 1, 3, 5, 7, 9, and 14% • Evaluation was based on total biogas volume produced, methane content, and other chemical variables
  • 4. Objectives and procedures • Fresh dairy manure was collected from a dairy farm equipped with a scraped manure handling system • Raw milk for the experiment was obtained from another dairy farm close to Waseca, MN • One control digester without milk addition was run side by side with the milk treated digesters • Biogas composition was determined for each digester every two days using a GC
  • 5. Results • Increasing milk content increases cumulative biogas production
  • 6. Results • Increasing milk content increases cumulative biogas production 0 2000 4000 6000 8000 10000 12000 0 2 4 6 8 10 12 14 16 18 20 Totalbiogasproduced(mL) Percent of milk added (%)
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  • 9. Results • Maximum biogas production rate for each treatment can be obtained by the slopes of the volume curves. 10 14 18 22 26 0 3 6 9 12 15 18 21 Biogasproductionrate(mL/h) Percent milk added (%)
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  • 12. Results • Milk effect on COD reduction and TKN The average values of COD and TKN for the batch digestion process with different milk content1 Milk content COD (mg/L)* TKN (mg/L) C/N ratio2 Initial Final Reduction Initial Final Reduction Initial Final3 (%) (%)4 0 (Control) 14500 7300 49.7 2794 2742 1.9 5.19 2.665 1% 15561 7700 50.5 2817 2792 0.9 5.52 2.766 3% 17683 7300 58.7 2863 2840 0.8 6.18 2.577 5% 19805 8100 59.1 2909 2794 4.0 6.81 2.898 7% 21927 8300 62.1 2955 2908 1.6 7.42 2.859 9% 24049 7600 68.4 3002 2970 1.0 8.01 2.5610 14% 29354 7800 73.4 3117 3080 1.1 9.42 2.5311 19% 34659 7700 77.8 3232 3206 0.8 10.7 2.4012 13 *COD – chemical oxygen demand; TKN – total Kjeldahl nitrogen14 15
  • 13. Conclusion The following conclusions can be reached based on the data from this study. • Added milk will increase biogas volumetric production and the maximum biogas production rate as compared to the control (7 and 18% vs. 1 and 3%). • Added milk will reduce the methane content in the biogas produced, thus increasing CO2 production. To avoid excessive CO2 production, the milk content in the digester liquid should be ≤ 3%. • Added milk will increase COD removal efficiency from 49.7% (no milk) to 77.8% (19% milk)