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Waste Management
The overall objective of this module is
that participants will show awareness of
waste management and transportation
requirements
Overview
โ€ข General principles for safe
acceptance of household hazardous
and/or CESQG waste from the public,
which includes: receiving, sorting,
storing, marking/labeling, packing,
transporting, and final disposal of
waste
โ€ข Understand the DOT, CFR, and UN
transportation requirements
Expectations
โ€ข List the seven steps in the waste
management process
โ€ข List the main classes of hazardous
materials and how they should be
sorted and stored
โ€ข Identify the proper selection,
marking/labeling, and handling of
containers of hazardous waste
7 Steps in Waste
Management Process
โ€ข Collecting Wastes
โ€ข Sorting
โ€ข Storing
โ€ข Marking/Labeling
โ€ข Packing
โ€ข Transporting
โ€ข Final Disposal
Collecting Wastes
โ€ข Minimum standards
โ€“ Customer restrictions
โ€“ Waste restrictions
โ€“ Container restrictions
โ€“ Contents identified
โ€“ Compatibilities of waste
โ€“ Restricted areas
Collecting Wastes
โ€ข Guidelines
โ€“ Load Inspection
โ€“ Unloading
Collecting Wastes
โ€ข Inspection
โ€“ Visually inspect the containers before
removing to ensure integrity
โ€“ Note unusual circumstances such as large
volumes or items not likely to be household
waste
Collecting Wastes
โ€ข Identifying and Dealing with
Exceptions
โ€“ Commercial wastes
โ€“ Universal waste
โ€“ Waste oil drums and oil filters
โ€“ Open and leaking containers
โ€“ Unlabeled / unknown items
โ€“ Waste left outside of facility
โ€“ Waste from farms
Collecting Wastes
โ€ข Identifying and Dealing with
Exceptions
โ€“ Infectious waste
โ€“ Ammunition and explosives
โ€“ Bombs / Unknown Packages
โ€“ Critically unstable chemicals
โ€“ Asbestos
โ€“ Nonhazardous waste
Suspected Commercial
Wastes
โ€ข Brought in a commercial vehicle
โ€ข Large amounts of the same item
โ€ข Items not normally for residential use
โ€ข Product of a business; home
business
Collecting Wastes
โ€ข Universal Wastes
โ€“ Considerations for managing UW under
UWR standards
โ€ข Whether state has adopted UWR and
additional waste added to UW list
โ€ข Whether want to receive commercial UW
โ€ข What quantity of UW you will receive and
manage
Collecting Wastes
โ€ข Universal Wastes
โ€“ Batteries
โ€“ Mercury thermostats
โ€“ Pesticides
Collecting Wastes
โ€ข Waste Reuse/ Exchange
โ€“ Inspect containers for
integrity and contents
โ€“ No reuse
โ€ข Recalled, canceled or
suspended material
โ€ข Material in containers which
are damaged, rusted or
labels are unreadable
Sorting
โ€ข Preliminary sorting
โ€ข Waste oil
โ€ข Testing waste oil for contamination
โ€ข Flames test
โ€ข Commercial test kits
โ€ข Bulking waste oil
โ€ข Pumping waste oil from barrels
Sorting
โ€ข Preliminary Sorting
โ€“ Aerosols
โ€“ Antifreeze
โ€“ Car batteries
โ€“ Unknown waste
โ€“ Waste oil
โ€“ Testing waste oil for
contamination
โ€“ Flame test
โ€“ Commercial test kits
Classification Process
โ€ข Read the labels
โ€ข Clues
โ€“ Plastic or plastic-lined containers -used for acids or
bases
โ€“ Exotic metals - extremely dangerous
โ€“ Single-walled containers - inert gas surrounding
reactive, flammable or explosive material
โ€“ Seal - reactive chemical or one which can not be
exposed to air, water, or other chemicals
โ€“ Cohesive solid in a liquid - material reactive with air or
water
โ€“ โ€œForbiddenโ€ - No transportation unless has been
diluted, stabilized or incorporated into a device
Classification Process
โ€ข Color-coded labels and caps
โ€“ green - ammonium hydroxide
โ€“ brown - acetic acid
โ€“ red - nitric acid
โ€“ yellow - sulfuric acid
โ€“ blue - hydrochloric acid
โ€“ black - perchloric acid
Sorting
โ€ข Nine DOT hazard classes
โ€“ Explosives
โ€“ Gases
โ€“ Flammable liquids
โ€“ Flammable solids
โ€“ Oxidizers
โ€“ Poisons
โ€“ Radioactive
โ€“ Corrosives
โ€“ Class 9
Sorting
โ€ข Precedence of Hazard
โ€“ Radioactive
โ€“ Poisonous gases
โ€“ Flammable gases
โ€“ Nonflammable gases
โ€“ Poisonous liquids
โ€“ Pyrophoric material
โ€“ Self-reactive material
Sorting
โ€“ Class 3- Flammable liquids
โ€“ Class 8- Corrosive materials
โ€“ Division 4.1- Flammable solids
โ€“ Division 4.2- Spontaneously combustible
materials
โ€“ Division 4.3- Dangerous when wet materials
โ€“ Division 5.1- Oxidizers
โ€“ Division 6.1- Poisonous materials
โ€“ Combustible liquids
โ€“ Miscellaneous hazardous materials
Storing
โ€ข Proper labeling on storage
cabinet, containers
โ€ข Compatibilities
โ€ข Check reactivity within Hazard
Classes
Marking/Labeling
โ€ข Proper Shipping Name (PSN)
โ€ข Selecting a Package
โ€ข Drum Preparation
โ€ข Marking
โ€ข Labels
โ€ข State Hazardous Waste Stickers
โ€ข Drum ID Number
Proper Shipping Name (PSN)
โ€ข Priority for selection:
โ€“ Chemical Name, e.g., โ€œMethyl Alcoholโ€
โ€“ Generic Name (Chemical Family), e.g.,
โ€œAlcoholโ€™s, n.o.s.โ€
โ€“ End Use of Material, e.g., โ€œPaint Related
Materialsโ€
โ€“ The n.o.s. End Use, e.g., โ€œDyes, Liquid, n.o.s.โ€
โ€“ DOT Class of Hazard, e.g., โ€œFlammable
Liquids, n.o.s.โ€
Selecting a Package
โ€ข Package must meet design and
performance standards-
โ€œperformance-based packagingโ€
โ€ข Limited quantity (LMTD QTY)
Drum Preparation
โ€ข New or reconditioned and acceptable to DOT
โ€ข Empty
โ€ข Cover, securing ring and / or bung and gaskets
โ€ข Drums used for lab packs must be lined with a
6 ml polyethylene liner
โ€ข Drums with liquids inside containers must be
marked on two opposite vertical sides of the
package with the arrows pointing in the correct
upright direction
โ€ข Marked on 2 sides - This side up
Marking
โ€ข Proper shipping name
โ€ข ID number
โ€ข Address of the shipper or
recipient
โ€ข English
โ€ข Durable
โ€ข Of contrasting color with
background
โ€ข Away from other markings
โ€ข Easy to see
Labels
โ€ข Diamond shaped
โ€ข Indicate the hazard class and
division of a material
โ€ข Placed near proper shipping name
and ID#s
State Hazardous Waste
Stickers
โ€ข โ€œAccumulation Start Dateโ€
โ€ข โ€œHazard Classโ€
โ€ข โ€œHazardous Wasteโ€ - upper one-third
of the drum
โ€ข Labels on two sides (upper third) and
the top of the drum
Drum ID Number
โ€ข Assign a serial number
Packing
โ€ข Lab Pack
โ€ข Incompatible material
โ€ข Drum inventory
โ€ข Loose Pack
โ€ข Consolidation
Packing
โ€ข Lab pack
โ€“ Extensive training
โ€“ Nonleaking containers
โ€“ Compatible with waste it is holding
โ€“ Appropriately placed in the lab pack
protecting them from breakage, rupture or
leaks
Packing
โ€ข Incompatible Material
โ€“ Nitric acid should not be placed in a drum with acetic
acid
โ€“ Cyanides and sulfides should never be placed with
acids
โ€“ Acids and bases should not be packed in the same
drum
โ€“ Ammonia solutions should never be packed with
bleach
โ€“ Oxidizers should not be placed with flammables or
corrosives
Packing
โ€ข Drum Inventory
โ€“Inventory sheets
โ€ข Trade name or major chemical
ingredient
โ€ข List liquids by volume
โ€ข List solids by weight
Packing
โ€ข Loose Pack
โ€“ Packed for short-term transport
โ€“ Aerosols packed without absorbents
โ€“ Nonleaking and tightly sealed containers
โ€“ Leaking and damaged containers - Placed
in a nonleaking container
Packing
โ€ข Consolidation
โ€“ Oil-Based Paint for Energy Recovery
โ€ข Flammable liquid label
โ€ข Hazardous waste sticker
โ€ข Grounding
โ€ข Secure to structure
Packing
โ€ข Consolidation
โ€“ Pesticides
โ€ข Same generic name and chemical constituents
โ€ข Appropriate personal protective equipment
โ€ข Containers emptied and disposed of properly
Transporting
โ€ข Shipping papers
โ€ข Emergency response
information
โ€ข Emergency response
guidebook (1996)
โ€ข Placards
โ€ข Loading, moving, and
Shipping Papers
โ€ข Shipper and receiver identification
โ€“ Package type and count
โ€“ Hazard material description (proper shipping
name, hazard class, ID number, other
information)
โ€“ Total quantity
โ€“ Emergency response information
โ€“ Shipperโ€™s certification
โ€“ Signature
Emergency Response
Information
โ€ข 24-hr contact number operated by
knowledgeable person
โ€ข Description and technical name of
the hazardous material
โ€ข Immediate hazards to health
โ€ข Risks of fire or explosion
Emergency Response
Information
โ€ข Immediate precautions to be taken in
the event of an accident or incident
โ€ข Immediate methods for handling fires
โ€ข Initial methods for handling spill or
leaks in the absence of fire
โ€ข Preliminary first aid measures
Emergency Response
Information
โ€ข Review Emergency Response
Guidebook
โ€ข Familiarize yourself with your
facilities emergency procedures
โ€ข Emergency Management process
Placards
โ€ข Large 12โ€ diamond shape
โ€ข Contain
โ€“ Hazard class or division
number
โ€“ Placard name
โ€“ Placard design section
references
โ€ข Placed on all four sides of
transport vehicle
Loading, Moving and
Unloading
โ€ข Responsibility of the carrier
โ€ข Segregation and separation
Training
โ€ข Refresher every two years
โ€ข Increases awareness of safety
considerations
Final Disposal
โ€ข Registered Transporter
โ€ข Know where your waste is going
โ€ข Recycling/TSD Facility
โ€ข Evaluate disposal facility
Monitoring
โ€ข Maintenance
โ€ข Inspections
Maintenance
โ€ข Drums
โ€“ Kept closed during storage except when items
are added
โ€“ Maintain empty space to ensure unobstructed
movement
โ€“ Label waste-containing drums
โ€“ Empty drums must be label free
โ€“ Good housekeeping
โ€“ Routine inspection checklists
Inspections
โ€ข Daily inspection of containers in the
facility
โ€“ Leakage or damage
โ€“ Liquid around base of drum
โ€“ Signs of rust or corrosion around base, top seal or
bung of drum
โ€“ Bulges or depressions
โ€“ Leaks or spills of hazardous materials
โ€ข Weekly inspection of facility by
supervisor
Safety
โ€ข Proper hygiene
โ€ข Safety meetings
โ€ข Security
โ€ข Visitors
Proper Hygiene
โ€ข Protective should be removed:
โ€“ Prior to taking breaks
โ€“ Entering the office area
โ€“ Leaving the sites
โ€ข Remove gloves last
Proper Hygiene
โ€ข Wash hands before:
โ€“ Eating
โ€“ Drinking
โ€“ Smoking
โ€“ Using the restroom
Safety Meetings
โ€ข Monthly
โ€ข Provide:
โ€“ Results of the inspections
โ€“ Review hazards identified
โ€“ Answer safety-related questions from
workers
Security
โ€ข Inform visitors of hazards and egress
routes
โ€ข Preapprove tours
โ€ข No tours during bulking, packing,
testing
โ€ข Use needed PPE

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waste_management.ppt

  • 1. Waste Management The overall objective of this module is that participants will show awareness of waste management and transportation requirements
  • 2. Overview โ€ข General principles for safe acceptance of household hazardous and/or CESQG waste from the public, which includes: receiving, sorting, storing, marking/labeling, packing, transporting, and final disposal of waste โ€ข Understand the DOT, CFR, and UN transportation requirements
  • 3. Expectations โ€ข List the seven steps in the waste management process โ€ข List the main classes of hazardous materials and how they should be sorted and stored โ€ข Identify the proper selection, marking/labeling, and handling of containers of hazardous waste
  • 4. 7 Steps in Waste Management Process โ€ข Collecting Wastes โ€ข Sorting โ€ข Storing โ€ข Marking/Labeling โ€ข Packing โ€ข Transporting โ€ข Final Disposal
  • 5. Collecting Wastes โ€ข Minimum standards โ€“ Customer restrictions โ€“ Waste restrictions โ€“ Container restrictions โ€“ Contents identified โ€“ Compatibilities of waste โ€“ Restricted areas
  • 6. Collecting Wastes โ€ข Guidelines โ€“ Load Inspection โ€“ Unloading
  • 7. Collecting Wastes โ€ข Inspection โ€“ Visually inspect the containers before removing to ensure integrity โ€“ Note unusual circumstances such as large volumes or items not likely to be household waste
  • 8. Collecting Wastes โ€ข Identifying and Dealing with Exceptions โ€“ Commercial wastes โ€“ Universal waste โ€“ Waste oil drums and oil filters โ€“ Open and leaking containers โ€“ Unlabeled / unknown items โ€“ Waste left outside of facility โ€“ Waste from farms
  • 9. Collecting Wastes โ€ข Identifying and Dealing with Exceptions โ€“ Infectious waste โ€“ Ammunition and explosives โ€“ Bombs / Unknown Packages โ€“ Critically unstable chemicals โ€“ Asbestos โ€“ Nonhazardous waste
  • 10. Suspected Commercial Wastes โ€ข Brought in a commercial vehicle โ€ข Large amounts of the same item โ€ข Items not normally for residential use โ€ข Product of a business; home business
  • 11. Collecting Wastes โ€ข Universal Wastes โ€“ Considerations for managing UW under UWR standards โ€ข Whether state has adopted UWR and additional waste added to UW list โ€ข Whether want to receive commercial UW โ€ข What quantity of UW you will receive and manage
  • 12. Collecting Wastes โ€ข Universal Wastes โ€“ Batteries โ€“ Mercury thermostats โ€“ Pesticides
  • 13. Collecting Wastes โ€ข Waste Reuse/ Exchange โ€“ Inspect containers for integrity and contents โ€“ No reuse โ€ข Recalled, canceled or suspended material โ€ข Material in containers which are damaged, rusted or labels are unreadable
  • 14. Sorting โ€ข Preliminary sorting โ€ข Waste oil โ€ข Testing waste oil for contamination โ€ข Flames test โ€ข Commercial test kits โ€ข Bulking waste oil โ€ข Pumping waste oil from barrels
  • 15. Sorting โ€ข Preliminary Sorting โ€“ Aerosols โ€“ Antifreeze โ€“ Car batteries โ€“ Unknown waste โ€“ Waste oil โ€“ Testing waste oil for contamination โ€“ Flame test โ€“ Commercial test kits
  • 16. Classification Process โ€ข Read the labels โ€ข Clues โ€“ Plastic or plastic-lined containers -used for acids or bases โ€“ Exotic metals - extremely dangerous โ€“ Single-walled containers - inert gas surrounding reactive, flammable or explosive material โ€“ Seal - reactive chemical or one which can not be exposed to air, water, or other chemicals โ€“ Cohesive solid in a liquid - material reactive with air or water โ€“ โ€œForbiddenโ€ - No transportation unless has been diluted, stabilized or incorporated into a device
  • 17. Classification Process โ€ข Color-coded labels and caps โ€“ green - ammonium hydroxide โ€“ brown - acetic acid โ€“ red - nitric acid โ€“ yellow - sulfuric acid โ€“ blue - hydrochloric acid โ€“ black - perchloric acid
  • 18. Sorting โ€ข Nine DOT hazard classes โ€“ Explosives โ€“ Gases โ€“ Flammable liquids โ€“ Flammable solids โ€“ Oxidizers โ€“ Poisons โ€“ Radioactive โ€“ Corrosives โ€“ Class 9
  • 19. Sorting โ€ข Precedence of Hazard โ€“ Radioactive โ€“ Poisonous gases โ€“ Flammable gases โ€“ Nonflammable gases โ€“ Poisonous liquids โ€“ Pyrophoric material โ€“ Self-reactive material
  • 20. Sorting โ€“ Class 3- Flammable liquids โ€“ Class 8- Corrosive materials โ€“ Division 4.1- Flammable solids โ€“ Division 4.2- Spontaneously combustible materials โ€“ Division 4.3- Dangerous when wet materials โ€“ Division 5.1- Oxidizers โ€“ Division 6.1- Poisonous materials โ€“ Combustible liquids โ€“ Miscellaneous hazardous materials
  • 21. Storing โ€ข Proper labeling on storage cabinet, containers โ€ข Compatibilities โ€ข Check reactivity within Hazard Classes
  • 22. Marking/Labeling โ€ข Proper Shipping Name (PSN) โ€ข Selecting a Package โ€ข Drum Preparation โ€ข Marking โ€ข Labels โ€ข State Hazardous Waste Stickers โ€ข Drum ID Number
  • 23. Proper Shipping Name (PSN) โ€ข Priority for selection: โ€“ Chemical Name, e.g., โ€œMethyl Alcoholโ€ โ€“ Generic Name (Chemical Family), e.g., โ€œAlcoholโ€™s, n.o.s.โ€ โ€“ End Use of Material, e.g., โ€œPaint Related Materialsโ€ โ€“ The n.o.s. End Use, e.g., โ€œDyes, Liquid, n.o.s.โ€ โ€“ DOT Class of Hazard, e.g., โ€œFlammable Liquids, n.o.s.โ€
  • 24. Selecting a Package โ€ข Package must meet design and performance standards- โ€œperformance-based packagingโ€ โ€ข Limited quantity (LMTD QTY)
  • 25. Drum Preparation โ€ข New or reconditioned and acceptable to DOT โ€ข Empty โ€ข Cover, securing ring and / or bung and gaskets โ€ข Drums used for lab packs must be lined with a 6 ml polyethylene liner โ€ข Drums with liquids inside containers must be marked on two opposite vertical sides of the package with the arrows pointing in the correct upright direction โ€ข Marked on 2 sides - This side up
  • 26. Marking โ€ข Proper shipping name โ€ข ID number โ€ข Address of the shipper or recipient โ€ข English โ€ข Durable โ€ข Of contrasting color with background โ€ข Away from other markings โ€ข Easy to see
  • 27. Labels โ€ข Diamond shaped โ€ข Indicate the hazard class and division of a material โ€ข Placed near proper shipping name and ID#s
  • 28. State Hazardous Waste Stickers โ€ข โ€œAccumulation Start Dateโ€ โ€ข โ€œHazard Classโ€ โ€ข โ€œHazardous Wasteโ€ - upper one-third of the drum โ€ข Labels on two sides (upper third) and the top of the drum
  • 29. Drum ID Number โ€ข Assign a serial number
  • 30. Packing โ€ข Lab Pack โ€ข Incompatible material โ€ข Drum inventory โ€ข Loose Pack โ€ข Consolidation
  • 31. Packing โ€ข Lab pack โ€“ Extensive training โ€“ Nonleaking containers โ€“ Compatible with waste it is holding โ€“ Appropriately placed in the lab pack protecting them from breakage, rupture or leaks
  • 32. Packing โ€ข Incompatible Material โ€“ Nitric acid should not be placed in a drum with acetic acid โ€“ Cyanides and sulfides should never be placed with acids โ€“ Acids and bases should not be packed in the same drum โ€“ Ammonia solutions should never be packed with bleach โ€“ Oxidizers should not be placed with flammables or corrosives
  • 33. Packing โ€ข Drum Inventory โ€“Inventory sheets โ€ข Trade name or major chemical ingredient โ€ข List liquids by volume โ€ข List solids by weight
  • 34. Packing โ€ข Loose Pack โ€“ Packed for short-term transport โ€“ Aerosols packed without absorbents โ€“ Nonleaking and tightly sealed containers โ€“ Leaking and damaged containers - Placed in a nonleaking container
  • 35. Packing โ€ข Consolidation โ€“ Oil-Based Paint for Energy Recovery โ€ข Flammable liquid label โ€ข Hazardous waste sticker โ€ข Grounding โ€ข Secure to structure
  • 36. Packing โ€ข Consolidation โ€“ Pesticides โ€ข Same generic name and chemical constituents โ€ข Appropriate personal protective equipment โ€ข Containers emptied and disposed of properly
  • 37. Transporting โ€ข Shipping papers โ€ข Emergency response information โ€ข Emergency response guidebook (1996) โ€ข Placards โ€ข Loading, moving, and
  • 38. Shipping Papers โ€ข Shipper and receiver identification โ€“ Package type and count โ€“ Hazard material description (proper shipping name, hazard class, ID number, other information) โ€“ Total quantity โ€“ Emergency response information โ€“ Shipperโ€™s certification โ€“ Signature
  • 39. Emergency Response Information โ€ข 24-hr contact number operated by knowledgeable person โ€ข Description and technical name of the hazardous material โ€ข Immediate hazards to health โ€ข Risks of fire or explosion
  • 40. Emergency Response Information โ€ข Immediate precautions to be taken in the event of an accident or incident โ€ข Immediate methods for handling fires โ€ข Initial methods for handling spill or leaks in the absence of fire โ€ข Preliminary first aid measures
  • 41. Emergency Response Information โ€ข Review Emergency Response Guidebook โ€ข Familiarize yourself with your facilities emergency procedures โ€ข Emergency Management process
  • 42. Placards โ€ข Large 12โ€ diamond shape โ€ข Contain โ€“ Hazard class or division number โ€“ Placard name โ€“ Placard design section references โ€ข Placed on all four sides of transport vehicle
  • 43. Loading, Moving and Unloading โ€ข Responsibility of the carrier โ€ข Segregation and separation
  • 44. Training โ€ข Refresher every two years โ€ข Increases awareness of safety considerations
  • 45. Final Disposal โ€ข Registered Transporter โ€ข Know where your waste is going โ€ข Recycling/TSD Facility โ€ข Evaluate disposal facility
  • 47. Maintenance โ€ข Drums โ€“ Kept closed during storage except when items are added โ€“ Maintain empty space to ensure unobstructed movement โ€“ Label waste-containing drums โ€“ Empty drums must be label free โ€“ Good housekeeping โ€“ Routine inspection checklists
  • 48. Inspections โ€ข Daily inspection of containers in the facility โ€“ Leakage or damage โ€“ Liquid around base of drum โ€“ Signs of rust or corrosion around base, top seal or bung of drum โ€“ Bulges or depressions โ€“ Leaks or spills of hazardous materials โ€ข Weekly inspection of facility by supervisor
  • 49. Safety โ€ข Proper hygiene โ€ข Safety meetings โ€ข Security โ€ข Visitors
  • 50. Proper Hygiene โ€ข Protective should be removed: โ€“ Prior to taking breaks โ€“ Entering the office area โ€“ Leaving the sites โ€ข Remove gloves last
  • 51. Proper Hygiene โ€ข Wash hands before: โ€“ Eating โ€“ Drinking โ€“ Smoking โ€“ Using the restroom
  • 52. Safety Meetings โ€ข Monthly โ€ข Provide: โ€“ Results of the inspections โ€“ Review hazards identified โ€“ Answer safety-related questions from workers
  • 53. Security โ€ข Inform visitors of hazards and egress routes โ€ข Preapprove tours โ€ข No tours during bulking, packing, testing โ€ข Use needed PPE