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Chemistry
  • A physical science
    that involves the study
    of the properties,
    composition,&
    structure of matter and
    the changes it
    undergoes.
What is a chemical?
          • Any substance
            that has a definite
            composition or is
            used or produced
            in a chemical
            process.
          •   Sugar is an example of a
              chemical
• Everything that has
                                  mass and volume is
                                  called matter
                                • Can be simple as in
                                  elements on the
                                  Periodic Table
                                • or complex molecules
                                  as atoms combine
Elements in the same vertical
row will behave similar in
chemical reactions
Three Major Classes of Elements
• Metals- located on the left of the Periodic Table- most
  of the elements

• Non-Metals- located on the right of the Periodic Table

• Metalloids- on the zigzag line between Metals and
  Nonmetals- have properties that are skewed- ie…
  Silicon is conductive

• You will have to memorize the symbol and element
  name for approximately 40 common elements
Properties of Metals
 Metals are good
conductors of heat and
electricity
 Metals are malleable
               (can be
shaped)
 Metals are ductile (can
be drawn into wires)
 Metals have high tensile
strength
 Metals have luster
Properties of Nonmetals

Carbon, the graphite in “pencil lead” is a great
example of a nonmetallic element.

 Nonmetals are poor conductors of heat and

Electricity

 Nonmetals tend to be brittle

 Many nonmetals are gases at room
temperature
Atoms Unite To Form
            Compounds
• Chemical Formula
                            C16H10 N2O2.
  indicates number
  and type of atoms
  within the molecule
  The formula to the
  left is the molecule What type of atoms and how
  for indigo:          many are there in one molecule?
What is not matter?

          • Light

          • Electricity

          • Sound
• Fixed composition
• Cannot be separated into simpler substances by
  physical methods (physical changes)
• Can only be changed in identity and properties by
  chemical methods
• Properties do not vary- Unique Density, Constant
  Boiling and Melting Points
Elements              Compounds
• Cannot be          • Chemically joined
  decomposed into      elements- Can be
  simpler              decomposed into
                       simpler substances by
  substances by        chemical changes,
  chemical changes     always in a definite
                       ratio
• Variable composition
• Components retain their characteristic properties
• May be separated into pure substances by physical
  methods sifting, evaporation, magnetism, etc…
• Mixtures of different compositions may have
  widely different properties
• Do NOT have definite boiling/melting points
Homogenous mixtures look the same
throughout but can be separated by
physical means
Examples:   salt water, soda
• Have the same composition throughout
• Components are indistinguishable
• Can exist between all phases of matter:
  air (gases) brass (alloy- blend of
  multiple metals -solids)
   soda (gas, solid, liquid)
Adding Liquids Together
            • Miscible- will mix-
              water and alcohol

            • Immiscible- wont mix
               water and oil
Solutions are homogenous mixtures that
do not scatter light. These mixtures are
created when something is completely
dissolved in pure water. Therefore, they
are easily separated by distillation or
evaporation. Appear in one phase of
matter
Examples: sugar water, salt water
Parts of a solution
          • Solvent- part that does
            the dissolving- water
            is our universal
            solvent

          • Solute- part that was
            dissolved (salt)
How do we increase solubility of
     a solid into a liquid
• Heat it- more
  collisions between
  solute and solvent

• Mix- Fresh solvent to
  solute

• Crush- more surface
  area- more contact
Increase solubility of a gas in a liquid
                 • Henrys Law- solubility of
                   the gasis directly
                   proportional to the
                   pressure above the liquid-

                 • Effervescence- rapid
                   escape of gas from liquid

                 • Decrease temperature-
                   slows down diffusion
Heterogeneous mixtures are composed of
large pieces that are easily separated by
physical means (ie. density, polarity,
metallic properties, size).
Pond Water, Vegetable Soup- Suspensions
Visible particles
Starch Water: invisible to the eye :colloid
Colloids are Tricky
        • Some heterogeneous
          mixtures appear as
          solutions to the eye:
        • Blood, Milk, starch
          water
        • Need a test: Tyndall
          Effect a light will scatter
          the suspended particles
MATTER
                  yes                      Can it be physically
                                                                                                   no
                                              separated?

           MIXTURE                                                                  PURE SUBSTANCE

yes      Is the composition                   no               yes                         Can it be chemically        no
              uniform?                                                                       decomposed?

 Homogeneous         Heterogeneous
    Mixture             Mixture                                         Compound                             Element
   (solution)

          Colloids                                  Suspensions


                         Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem
Physical Properties – Observable traits
  of a material that may be measured
     without altering the substance

Examples: Mass, Color, Melting Point,
       Boiling Point, Density
We can use physical properties to
        separate mixtures:
  Please determine a method to separate the following and
                determine the type of matter:
Oil and Water

Iron and Sand

Sand and Salt

Sulfur and Sugar
What are the
physical properties
of the substance to
     the right?
What do you think the material is that made this
bracelet?

How could you be sure?

             Density- the amount of material in a given

                       volume- unique to the material
Chemical Change-
an irreversible change
   that changes the
identity and make up
    of the material
      Examples:
        Rusting
        Burning
• There is no observable
  change in the quantity of
  matter during a chemical
  reaction or a physical
  change.

In other words, matter cannot be
   created nor destroyed. It is just
   converted from one form to another
Energy comes in two forms :
Kinetic Energy: Movement
Potential Energy: Stored
All matter, regardless of state, undergoes
 physical and chemical changes. These
     changes can be microscopic or
              macroscopic.
A physical change occurs when the
substance changes state but does not change
its chemical composition. It is not
permanent and is reversible! Example
Phase Changes!
Physical Change
      For example: Ice melting to
        water. The form or
        appearance has changed,
        but the properties of that
        substance are the same
        (i.e. it has the same melting
        point, boiling point,
        chemical composition, etc.)
•   Melting point     • Density
•   Boiling point     • Electrical conductivity
•   Vapor pressure    • Solubility
•   Color             • Adsorption to a
•   State of matter     surface
•   Specific Heat     • Hardness
Names of Water Phase Changes
Endothermic Requires      Exothermic Gives
   Energy to go forward     energy off
 • Melting: Solid Liq        • Condensation
    • Boiling (forced)             Gas Liq
        Liquid Gas             • Freezing:
  • Evaporation ( spon)            Liq Solid
        Liquid Gas            • Deposition:
      • Sublimation               Gas Solid
        Solid Gas
A substance
changes into
something new.
It is irreversible.
Indications of A Chemical Reaction
             • Bubbles- gas given off
             • Change in energy- becomes
               warm- exothermic
                becomes cool- endothermic
                 light is given off
             • A precipitate (solid) forms
             • Sometimes a change in
               color-
All Chemical Changes can be
     written as a reaction
              • A + B  AB

              • A, B are the starting
                materials- reactants

              • AB is the result-
                product
• Reaction with acids    • Ability to act as
• Reaction with bases      reducing agent
  (alkalis)              • Reaction with other
• Reaction with oxygen     elements
  (combustion)           • Decomposition into
• Ability to act as        simpler substances
  oxidizing agent        • Corrosion
• Physical and chemical properties may be
  intensive or extensive.
• Intensive properties such as density, color, and
  boiling point do not depend on the size of the
  sample of matter and can be used to identify
  substances.
•
• Extensive properties such as mass and
  volume do depend on the quantity of the
  sample.
• Physical properties are those that we can
  determine without changing the identity of
  the substance we are studying.
• The physical properties of sodium metal can
  be observed or measured. It is a soft,
  lustrous, silver-colored metal with a
  relatively low melting point and low
  density.
• Hardness, color, melting point and density
  are all physical properties.
Specific Heat
• Physical Property that is unique
  to the material

• Amount of energy required to
  heat 1 gram of a substance by 1
  degree Celsius

• -Why do you choose to sit on the
  wooden bleachers on a cold fall day
  for a football game instead of the
  metal bleachers?
• Chemical properties describe the way a
  substance can change or react to form other
  substances.

• These properties, then, must be determined
  using a process that changes the identity of
  the substance of interest.
• One of the chemical properties of alkali metals
  such as sodium and potassium is that they react
  with water. To determine this, we would have to
  combine an alkali metal with water and observe
  what happens.

• In other words, we have to define chemical
  properties of a substance by the chemical changes
  it undergoes.
& The Kinetic Molecular Theory
•All matter is made of atom and molecules that
             act as tiny particles
•These particles are always in motion (yes even in solids)
•The higher the temperature the faster the
       particles move-
•Kinetic energy is directly proportional to Kelvin
Temperature ( bigger particles move slower)
Three Phases
•Have a definite shape
   •Have a definite volume
 Kinetic Molecular Theory
Molecules are held close together
and there is very little movement
between them. Vibrational
•Have an indefinite shape
   •Have a definite volume
Kinetic Molecular Theory:
Atoms and molecules have more
space between them than a solid
does, but less than a gas (ie. It is
more “fluid”.) Has 2 dimensional
motion- can slide past each other
•Have an indefinite shape
  •Have an indefinite volume
Kinetic Molecular Theory:
Molecules are moving in random
patterns with varying amounts of
distance between the particles.
At 100°C, water
                                    becomes water
           Between 0°C and 100      vapor, a gas.
           °C, water is a liquid.   Molecules can
           In the liquid state,     move randomly
           water molecules are      over large
           close together, but      distances.
           can move about
           freely.



Below 0°C, water
solidifies to become
ice. In the solid state,
water molecules are
held together in a
rigid structure.
Changing states requires energy in either
  the form of heat. Changing states may also
  be due to the change in pressure in a
  system.




Heat of formation, Hf.   Heat of vaporization, Hv
Plasma is by far the most common form
of matter in the universe (not here on
Earth). Plasma in the stars and in the
tenuous space between them makes up
over 99% of the visible universe and
perhaps most of that which is not
visible. Fluorescent Light Bulbs…
Star formation in the
     Eagle Nebula
Space Telescope Science Institute
         , NASA
(below)                       (Above)
                              X-ray view of
                              Sun
                              from Yohkoh,
                              ISAS and NASA
Plasma radiation within the Princeton
Tokamak during operation.
Laser plasma interaction during inertial
confinement fusion test at the
University of Rochester.
Plasma consists of a collection of free-
moving electrons and ions - atoms that
have lost electrons. Energy is needed to
strip electrons from atoms to make plasma.
The energy can be of various origins:
thermal, electrical, or light (ultraviolet
light or intense visible light from a laser).
With insufficient sustaining power,
plasmas recombine into neutral gas.
Products
manufactured
using plasmas
impact our daily
lives:
EXAMPLES:
                           •Printing on plastic food
•Computer chips and        containers
integrated circuits
                           •Energy-efficient window
•Computer hard drives      coatings
•Electronics               •High-efficiency window
•Machine tools             coatings

•Medical implants and      •Safe drinking water
prosthetics                •Voice and data
•Audio and video tapes     communications components

•Aircraft and automobile   •Anti-scratch and anti-glare
engine parts               coatings on eyeglasses and
                           other optics

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Matter

  • 1.
  • 2. Chemistry • A physical science that involves the study of the properties, composition,& structure of matter and the changes it undergoes.
  • 3. What is a chemical? • Any substance that has a definite composition or is used or produced in a chemical process. • Sugar is an example of a chemical
  • 4. • Everything that has mass and volume is called matter • Can be simple as in elements on the Periodic Table • or complex molecules as atoms combine Elements in the same vertical row will behave similar in chemical reactions
  • 5. Three Major Classes of Elements • Metals- located on the left of the Periodic Table- most of the elements • Non-Metals- located on the right of the Periodic Table • Metalloids- on the zigzag line between Metals and Nonmetals- have properties that are skewed- ie… Silicon is conductive • You will have to memorize the symbol and element name for approximately 40 common elements
  • 6. Properties of Metals  Metals are good conductors of heat and electricity  Metals are malleable (can be shaped)  Metals are ductile (can be drawn into wires)  Metals have high tensile strength  Metals have luster
  • 7. Properties of Nonmetals Carbon, the graphite in “pencil lead” is a great example of a nonmetallic element.  Nonmetals are poor conductors of heat and Electricity  Nonmetals tend to be brittle  Many nonmetals are gases at room temperature
  • 8. Atoms Unite To Form Compounds • Chemical Formula C16H10 N2O2. indicates number and type of atoms within the molecule The formula to the left is the molecule What type of atoms and how for indigo: many are there in one molecule?
  • 9. What is not matter? • Light • Electricity • Sound
  • 10. • Fixed composition • Cannot be separated into simpler substances by physical methods (physical changes) • Can only be changed in identity and properties by chemical methods • Properties do not vary- Unique Density, Constant Boiling and Melting Points
  • 11. Elements Compounds • Cannot be • Chemically joined decomposed into elements- Can be simpler decomposed into simpler substances by substances by chemical changes, chemical changes always in a definite ratio
  • 12. • Variable composition • Components retain their characteristic properties • May be separated into pure substances by physical methods sifting, evaporation, magnetism, etc… • Mixtures of different compositions may have widely different properties • Do NOT have definite boiling/melting points
  • 13. Homogenous mixtures look the same throughout but can be separated by physical means Examples: salt water, soda
  • 14. • Have the same composition throughout • Components are indistinguishable • Can exist between all phases of matter: air (gases) brass (alloy- blend of multiple metals -solids) soda (gas, solid, liquid)
  • 15. Adding Liquids Together • Miscible- will mix- water and alcohol • Immiscible- wont mix water and oil
  • 16. Solutions are homogenous mixtures that do not scatter light. These mixtures are created when something is completely dissolved in pure water. Therefore, they are easily separated by distillation or evaporation. Appear in one phase of matter Examples: sugar water, salt water
  • 17. Parts of a solution • Solvent- part that does the dissolving- water is our universal solvent • Solute- part that was dissolved (salt)
  • 18. How do we increase solubility of a solid into a liquid • Heat it- more collisions between solute and solvent • Mix- Fresh solvent to solute • Crush- more surface area- more contact
  • 19. Increase solubility of a gas in a liquid • Henrys Law- solubility of the gasis directly proportional to the pressure above the liquid- • Effervescence- rapid escape of gas from liquid • Decrease temperature- slows down diffusion
  • 20. Heterogeneous mixtures are composed of large pieces that are easily separated by physical means (ie. density, polarity, metallic properties, size). Pond Water, Vegetable Soup- Suspensions Visible particles Starch Water: invisible to the eye :colloid
  • 21. Colloids are Tricky • Some heterogeneous mixtures appear as solutions to the eye: • Blood, Milk, starch water • Need a test: Tyndall Effect a light will scatter the suspended particles
  • 22. MATTER yes Can it be physically no separated? MIXTURE PURE SUBSTANCE yes Is the composition no yes Can it be chemically no uniform? decomposed? Homogeneous Heterogeneous Mixture Mixture Compound Element (solution) Colloids Suspensions Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem
  • 23.
  • 24. Physical Properties – Observable traits of a material that may be measured without altering the substance Examples: Mass, Color, Melting Point, Boiling Point, Density
  • 25. We can use physical properties to separate mixtures: Please determine a method to separate the following and determine the type of matter: Oil and Water Iron and Sand Sand and Salt Sulfur and Sugar
  • 26. What are the physical properties of the substance to the right? What do you think the material is that made this bracelet? How could you be sure? Density- the amount of material in a given volume- unique to the material
  • 27. Chemical Change- an irreversible change that changes the identity and make up of the material Examples: Rusting Burning
  • 28. • There is no observable change in the quantity of matter during a chemical reaction or a physical change. In other words, matter cannot be created nor destroyed. It is just converted from one form to another
  • 29. Energy comes in two forms : Kinetic Energy: Movement Potential Energy: Stored
  • 30. All matter, regardless of state, undergoes physical and chemical changes. These changes can be microscopic or macroscopic.
  • 31. A physical change occurs when the substance changes state but does not change its chemical composition. It is not permanent and is reversible! Example Phase Changes!
  • 32. Physical Change For example: Ice melting to water. The form or appearance has changed, but the properties of that substance are the same (i.e. it has the same melting point, boiling point, chemical composition, etc.)
  • 33. Melting point • Density • Boiling point • Electrical conductivity • Vapor pressure • Solubility • Color • Adsorption to a • State of matter surface • Specific Heat • Hardness
  • 34.
  • 35. Names of Water Phase Changes Endothermic Requires Exothermic Gives Energy to go forward energy off • Melting: Solid Liq • Condensation • Boiling (forced) Gas Liq Liquid Gas • Freezing: • Evaporation ( spon) Liq Solid Liquid Gas • Deposition: • Sublimation Gas Solid Solid Gas
  • 36. A substance changes into something new. It is irreversible.
  • 37. Indications of A Chemical Reaction • Bubbles- gas given off • Change in energy- becomes warm- exothermic becomes cool- endothermic light is given off • A precipitate (solid) forms • Sometimes a change in color-
  • 38. All Chemical Changes can be written as a reaction • A + B  AB • A, B are the starting materials- reactants • AB is the result- product
  • 39. • Reaction with acids • Ability to act as • Reaction with bases reducing agent (alkalis) • Reaction with other • Reaction with oxygen elements (combustion) • Decomposition into • Ability to act as simpler substances oxidizing agent • Corrosion
  • 40. • Physical and chemical properties may be intensive or extensive.
  • 41. • Intensive properties such as density, color, and boiling point do not depend on the size of the sample of matter and can be used to identify substances. •
  • 42. • Extensive properties such as mass and volume do depend on the quantity of the sample.
  • 43. • Physical properties are those that we can determine without changing the identity of the substance we are studying.
  • 44. • The physical properties of sodium metal can be observed or measured. It is a soft, lustrous, silver-colored metal with a relatively low melting point and low density. • Hardness, color, melting point and density are all physical properties.
  • 45. Specific Heat • Physical Property that is unique to the material • Amount of energy required to heat 1 gram of a substance by 1 degree Celsius • -Why do you choose to sit on the wooden bleachers on a cold fall day for a football game instead of the metal bleachers?
  • 46. • Chemical properties describe the way a substance can change or react to form other substances. • These properties, then, must be determined using a process that changes the identity of the substance of interest.
  • 47. • One of the chemical properties of alkali metals such as sodium and potassium is that they react with water. To determine this, we would have to combine an alkali metal with water and observe what happens. • In other words, we have to define chemical properties of a substance by the chemical changes it undergoes.
  • 48.
  • 49. & The Kinetic Molecular Theory •All matter is made of atom and molecules that act as tiny particles •These particles are always in motion (yes even in solids) •The higher the temperature the faster the particles move- •Kinetic energy is directly proportional to Kelvin Temperature ( bigger particles move slower)
  • 51.
  • 52. •Have a definite shape •Have a definite volume Kinetic Molecular Theory Molecules are held close together and there is very little movement between them. Vibrational
  • 53. •Have an indefinite shape •Have a definite volume Kinetic Molecular Theory: Atoms and molecules have more space between them than a solid does, but less than a gas (ie. It is more “fluid”.) Has 2 dimensional motion- can slide past each other
  • 54. •Have an indefinite shape •Have an indefinite volume Kinetic Molecular Theory: Molecules are moving in random patterns with varying amounts of distance between the particles.
  • 55. At 100°C, water becomes water Between 0°C and 100 vapor, a gas. °C, water is a liquid. Molecules can In the liquid state, move randomly water molecules are over large close together, but distances. can move about freely. Below 0°C, water solidifies to become ice. In the solid state, water molecules are held together in a rigid structure.
  • 56. Changing states requires energy in either the form of heat. Changing states may also be due to the change in pressure in a system. Heat of formation, Hf. Heat of vaporization, Hv
  • 57. Plasma is by far the most common form of matter in the universe (not here on Earth). Plasma in the stars and in the tenuous space between them makes up over 99% of the visible universe and perhaps most of that which is not visible. Fluorescent Light Bulbs…
  • 58. Star formation in the Eagle Nebula Space Telescope Science Institute , NASA (below) (Above) X-ray view of Sun from Yohkoh, ISAS and NASA
  • 59. Plasma radiation within the Princeton Tokamak during operation.
  • 60. Laser plasma interaction during inertial confinement fusion test at the University of Rochester.
  • 61. Plasma consists of a collection of free- moving electrons and ions - atoms that have lost electrons. Energy is needed to strip electrons from atoms to make plasma. The energy can be of various origins: thermal, electrical, or light (ultraviolet light or intense visible light from a laser). With insufficient sustaining power, plasmas recombine into neutral gas.
  • 63. EXAMPLES: •Printing on plastic food •Computer chips and containers integrated circuits •Energy-efficient window •Computer hard drives coatings •Electronics •High-efficiency window •Machine tools coatings •Medical implants and •Safe drinking water prosthetics •Voice and data •Audio and video tapes communications components •Aircraft and automobile •Anti-scratch and anti-glare engine parts coatings on eyeglasses and other optics

Notes de l'éditeur

  1. Basic definition of matter.
  2. Basic characteristics of pure substance:
  3. The two categories of pure chemical substances.
  4. Basic identification of a mixture.
  5. Brainstorm more examples of homogenous mixtures.
  6. Definition of Conservation of matter.
  7. Definition of physical changes.
  8. Physical changes are characterized by the following:
  9. Definition of chemical change.
  10. Chemical Changes are characterized by the following: