Organic Synthesis

Retrosynthetic Analysis of Organic Synthesis ,[object Object],[object Object],[object Object]

[object Object],[object Object]

Retrosynthetic analysis Disconnection of T.M. Intermediate Starting material Synthesis tree

3.2 Common terms in retrosynthetic analysis ,[object Object],[object Object],[object Object],[object Object]

Factors in Design of Synthesis ,[object Object],[object Object],[object Object],[object Object]

Reactions involved in Synthesis ,[object Object],[object Object]

Major Ionic Reactions for Carbon

Pericyclic Reactions ,[object Object],[object Object],[object Object]

Rearrangements Useful in Synthesis

Criteria for Evaluating Synthetic Methods ,[object Object],[object Object]

Key Points in Designing Synthesis ,[object Object],[object Object],[object Object],[object Object]

Grignard and related organometallic reagents ,[object Object],[object Object],[object Object],[object Object],[object Object]

Organometallic and Ylide Methods of Carbon-Carbon Bond Formation

Stereochemistry of Grignard Addition

Orthometallation Cross Coupling (Suzuki Rxn 1,4-Addition

Carbonyl Activation and Enolate Chemistry in Carbon-Carbon Bond Formation

Regiospecificity in Enol Ether Formation

Alkylation of Carbanion CH 3 -OSO 2 F methyl fluorosulfonate oxirane (epoxide) CH 3 -OSO 2 O-CH 3 dimethyl sulfate (R-OTs) toluene-p-sulfonates (or tosylates) R-OSO 2 CH 3 (R-OMs) methanesulfnates (or mesylates) R-X alkyl halide Structure Alkylating agent

Enolate Anions in Carbonyl Addition Reactions ,[object Object],[object Object],[object Object]

4. Robinson annulation - a special class of Michael additions which lead to one six-membered ring fused to another

Functional Group Interconversion ,[object Object],[object Object],[object Object],[object Object]

Reductions with Hydride Reagents

Carbocations in Synthesis ,[object Object],[object Object],[object Object]

Free Radical and Pericyclic Reactions ,[object Object],[object Object],[object Object]

Alkene Metathesis ,[object Object]

Protection Groups ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

Organic Synthesis

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Organic Synthesis