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Y E A R 1 0 – C O M P O U N D S A N D R E A C T I O N
G . A J E T R A O
PRECIPITATION
AIM
To investigate
precipitation reaction
Write a hypothesis for the
experiment.
BACKGROUND INFORMATION
Precipitation reaction occurs when two solutions are mixed
together to form an insoluble compound called precipitate that
settles out of solution.
AB + CD  AD + BC
double displacement reaction
SOLUBILITY RULE
Soluble Ionic Compounds
• 1. All common compounds of the Group 1A ions (Li+, Na+,
K+, etc.) and the ammonium ion (NH4
+) are soluble.
• 2. All common nitrates (NO3
-), acetates (C2H3O2
-), and most
perchlorates (ClO4
-) are soluble.
• 3. All common chlorides (Cl-), bromides (Br-), and iodides
(I-) are soluble, except those of Ag+, Pb2+, and Hg2
2+.
• 4. All common sulfates (SO4
2-) are soluble, except those of
Ca2+, Sr2+, Ba2+, Pb2+, and Ag+.
SOLUBILITY RULE CONTINUED
Insoluble Ionic Compounds
• 5. All metal hydroxides (OH-) are insoluble, except those of
Group 1A, NH4
+, which are soluble, and Ca2+, Sr2+, and Ba2+,
which are slightly soluble.
• 6. All sulfides (S2-) are insoluble, except those of Group 1A,
NH4
+, Ca2+, Sr2+, and Ba2+.
• 7. All carbonates (CO3
2-) and phosphates (PO4
3-) are
insoluble, except those of Group 1A and NH4
+.
EQUIPMENT
Metal ions – barium
nitrate, calcium nitrate,
lead nitrate, copper nitrate
in dropper bottle
Non-metal ions- sodium
carbonate, sodium
chloride, sodium
hydroxide, sodium
sulfate, sodium iodide in
dropper bottle.
• Spotting plate
RISK ASSESSMENT
Risk Injury Prevention
Stain Silver nitrate and lead
nitrate are poisonous
Avoid contact with skin.
Use small amounts of
solutions in dropper bottle
METHOD
1. Take a spotting plate.
2. Add one drop of solution to
each well of the spotting
plate.
3. Add a drop of other solution
as shown in the table on the
next slide.
4. Record the presence or
absence of precipitate.
5. If there is a precipitate
observe and record the
colour of the precipitate
and the colour of the
solution.
TABLE
CO3
2-
Sodium
carbonate
Cl-
Sodium chloride
OH-
Sodium
Hydroxide
I-
Sodium Iodide
SO4
2-
Sodium sulfate
Ba2+
Barium nitrate
Ca2+
Calcium nitrate
Pb2+
Lead nitrate
Cu2+
Copper nitrate
RESULT TABLE
• Construct a result table for data you are going to gather from
the investigation.
DISCUSSION
1. Which metals ions are soluble?
2. Which non- metals ions are insoluble?
CONCLUSION
• Write a appropriate conclusion (make sure it is related to your
results).

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Precipitation reaction

  • 1. Y E A R 1 0 – C O M P O U N D S A N D R E A C T I O N G . A J E T R A O PRECIPITATION
  • 2. AIM To investigate precipitation reaction Write a hypothesis for the experiment.
  • 3. BACKGROUND INFORMATION Precipitation reaction occurs when two solutions are mixed together to form an insoluble compound called precipitate that settles out of solution. AB + CD  AD + BC double displacement reaction
  • 4. SOLUBILITY RULE Soluble Ionic Compounds • 1. All common compounds of the Group 1A ions (Li+, Na+, K+, etc.) and the ammonium ion (NH4 +) are soluble. • 2. All common nitrates (NO3 -), acetates (C2H3O2 -), and most perchlorates (ClO4 -) are soluble. • 3. All common chlorides (Cl-), bromides (Br-), and iodides (I-) are soluble, except those of Ag+, Pb2+, and Hg2 2+. • 4. All common sulfates (SO4 2-) are soluble, except those of Ca2+, Sr2+, Ba2+, Pb2+, and Ag+.
  • 5. SOLUBILITY RULE CONTINUED Insoluble Ionic Compounds • 5. All metal hydroxides (OH-) are insoluble, except those of Group 1A, NH4 +, which are soluble, and Ca2+, Sr2+, and Ba2+, which are slightly soluble. • 6. All sulfides (S2-) are insoluble, except those of Group 1A, NH4 +, Ca2+, Sr2+, and Ba2+. • 7. All carbonates (CO3 2-) and phosphates (PO4 3-) are insoluble, except those of Group 1A and NH4 +.
  • 6. EQUIPMENT Metal ions – barium nitrate, calcium nitrate, lead nitrate, copper nitrate in dropper bottle Non-metal ions- sodium carbonate, sodium chloride, sodium hydroxide, sodium sulfate, sodium iodide in dropper bottle. • Spotting plate
  • 7. RISK ASSESSMENT Risk Injury Prevention Stain Silver nitrate and lead nitrate are poisonous Avoid contact with skin. Use small amounts of solutions in dropper bottle
  • 8. METHOD 1. Take a spotting plate. 2. Add one drop of solution to each well of the spotting plate. 3. Add a drop of other solution as shown in the table on the next slide. 4. Record the presence or absence of precipitate. 5. If there is a precipitate observe and record the colour of the precipitate and the colour of the solution.
  • 9. TABLE CO3 2- Sodium carbonate Cl- Sodium chloride OH- Sodium Hydroxide I- Sodium Iodide SO4 2- Sodium sulfate Ba2+ Barium nitrate Ca2+ Calcium nitrate Pb2+ Lead nitrate Cu2+ Copper nitrate
  • 10. RESULT TABLE • Construct a result table for data you are going to gather from the investigation.
  • 11. DISCUSSION 1. Which metals ions are soluble? 2. Which non- metals ions are insoluble?
  • 12. CONCLUSION • Write a appropriate conclusion (make sure it is related to your results).