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DENIMIST	
  2011	
                              DNMSTDENIMDESINGFASHIONARTLIFE	
  




                                   DB
                                   DENIM BOOK


                 D     E   N   I           M      I        S           T
DB
                                                                                             DENIM B O O K




                                          DENIMIST
                                                          T U R K E Y	
  




Since	
   decades	
   Denimist	
   has	
   developed	
   know-­‐how	
   in	
   denim	
   finishing	
   prior	
   to	
  
garment	
   manufacturing	
   and	
   also	
   in	
   jeans	
   washing.	
   Our	
   customers	
   derive	
  
benefit	
   from	
   this	
   experience.For	
   the	
   fabric	
   production	
   we	
   offer	
   finishing	
  
chemicals	
   which	
   provide	
   the	
   demanded	
   fabric	
   properties	
   such	
   as	
   good	
  
sewability,	
   stiffness,elasticity	
   and	
   handle.	
   The	
   other	
   field	
   of	
   our	
   activity	
   is	
   the	
  
recommendation	
   of	
   laundring	
   Procedures	
   for	
   ready-­‐made	
   clothing	
   such	
   as	
  
trousers,	
  jackets	
  or	
  skirts,	
  shirts.	
  

In	
   doing	
   so	
   we	
   have	
   learned	
   that	
   many	
   errors	
   may	
   occur	
   in	
   this	
   complicated	
  
production	
   process.	
  The	
   laundry,	
   the	
   last	
   step	
   in	
   the	
   sequence	
   of	
  	
   producers,	
   is	
  
faced	
   to	
   difficulties	
   which	
   are	
   caused	
   by	
   previous	
   inaccuracies.	
   Therefore,	
   a	
  
good	
   cooperation	
   among	
   the	
   steps	
   of	
   jeans	
   manufacturing	
   is	
   required	
   to	
   avoid	
  
problems.	
  Fabric	
  producer,	
  garment	
  manufacturer	
  and	
  laundries	
  have	
  to	
  work	
  
together	
   to	
   obtain	
   the	
   desired	
   end	
   result.	
   By	
   means	
   of	
   our	
   contacts	
   on	
   both	
  
sides	
  of	
  the	
  production	
  process	
  we	
  are	
  able	
  to	
  make	
  our	
  contribution.	
  

The	
   technical	
   stuff	
   of	
   Denimist	
   	
   is	
   always	
   ready	
   to	
   help	
   our	
   customers	
   with	
  
eventual	
   problems	
   and	
   to	
   modify	
   production	
   procedures	
   according	
   to	
   the	
  
respective	
   requirements.	
  Through	
   our	
   numerous	
   contacts	
   which	
   we	
   have	
   got	
  
with	
  denim	
  producers,	
  garment	
  manufacturers	
  and	
  laundries	
  during	
  the	
  years	
  
we	
  support	
  the	
  team	
  work	
  among	
  all	
  sections	
  of	
  the	
  jeans	
  chain	
  and	
  make	
  our	
  
know-­‐how	
  	
  available	
  to	
  all	
  of	
  the	
  parties	
  concerned	
  	
  
DBDENIM B O O K


History	
  of	
  Natural	
  Indigo	
  

A	
   variety	
   of	
   plants	
   have	
   provided	
   indigo	
   throughout	
   history,	
   but	
   most	
   natural	
  
indigo	
  is	
  obtained	
  from	
  those	
  in	
  the	
  genus	
  Indigofera,	
  which	
  are	
  native	
  to	
  the	
  
tropics.	
   In	
   temperate	
   climates	
   indigo	
   can	
   also	
   be	
   obtained	
   from	
   woad	
   (Isatis	
  
tinctoria)	
  and	
  dyer's	
  knotweed	
  (Polygonumtinctorum).	
  	
  

The	
   primary	
   commercial	
   indigo	
   species	
   in	
   Asia	
   was	
   true	
   indigo	
   (Indigofera	
  
tinctoria,	
   also	
   known	
   as	
   Indigofera	
   sumatrana).	
   In	
  Central	
   and	
   South	
  America	
  
the	
   two	
   species	
   Indigofera	
   suffruticosa	
   (Anil)	
   and	
   Indigofera	
   arrecta	
   (Natal	
  
indigo)	
  were	
  the	
  most	
  important.	
  	
  

The	
  plants	
  of	
  the	
  genus	
  Indigofera	
  produce	
  a	
  much	
  stronger	
  dye	
  that	
  those	
  of	
  
the	
   Isatis	
   (woad)	
   family;	
   however,	
   dyer’s	
   woad	
   is	
   much	
   more	
   easily	
   cultivated	
  
and	
  therefore	
  more	
  widely	
  used	
  than	
  Indigofera,	
  which	
  needs	
  a	
  tropical	
  climate.	
  
Isatis	
  tinctoria	
  grows	
  up	
  to	
  approximately	
  1.50	
  m	
  in	
  height	
  and	
  can	
  be	
  harvested	
  
three	
  times	
  a	
  year.	
  

Preparation	
  of	
  indigo	
  dye	
  with	
  Indigofera	
  tinctoria.	
  

A	
   variety	
   of	
   plants	
   have	
   provided	
   indigo	
   throughout	
   history,	
   but	
   most	
   natural	
  
indigo	
  is	
  obtained	
  from	
  those	
  in	
  the	
  genus	
  Indigofera,	
  which	
  are	
  native	
  to	
  the	
  
tropics.	
   In	
   temperate	
   climates	
   indigo	
   can	
   also	
   be	
   obtained	
   from	
   woad	
   (Isatis	
  
tinctoria)	
  and	
  dyer's	
  knotweed	
  (Polygonumtinctorum).	
  	
  

The	
   primary	
   commercial	
   indigo	
   species	
   in	
   Asia	
   was	
   true	
   indigo	
   (Indigofera	
  
tinctoria,	
   also	
   known	
   as	
   Indigofera	
   sumatrana).	
   In	
  Central	
   and	
   South	
  America	
  
the	
   two	
   species	
   Indigofera	
   suffruticosa	
   (Anil)	
   and	
   Indigofera	
   arrecta	
   (Natal	
  
indigo)	
  were	
  the	
  most	
  important.	
  	
  

The	
  plants	
  of	
  the	
  genus	
  Indigofera	
  produce	
  a	
  much	
  stronger	
  dye	
  that	
  those	
  of	
  
the	
   Isatis	
   (woad)	
   family;	
   however,	
   dyer’s	
   woad	
   is	
   much	
   more	
   easily	
   cultivated	
  
and	
  therefore	
  more	
  widely	
  used	
  than	
  Indigofera,	
  which	
  needs	
  a	
  tropical	
  climate.	
  
Isatis	
  tinctoria	
  grows	
  up	
  to	
  approximately	
  1.50	
  m	
  in	
  height	
  and	
  can	
  be	
  harvested	
  
three	
  times	
  a	
  year.	
  
DB
                                                                                            DENIM B O O K


Four	
  months	
  after	
  planting	
  the	
  seeds	
  the	
  leaves	
  of	
  the	
  indigo	
  plant	
  start	
  turning	
  
dark	
   green	
   which	
   indicates	
   good	
   quality	
   dye.	
   The	
   plants	
   are	
   cut	
   off	
   and	
   made	
  
into	
  small	
  bundles.The	
  leaves	
  are	
  then	
  soaked	
  in	
  a	
  large	
  earthenware	
  jar	
  filled	
  
with	
   water	
   and	
   left	
   to	
   be	
   fermented	
   in	
   order	
   to	
   convert	
   the	
   glycoside	
   indican	
  
which	
  is	
  naturally	
  present	
  in	
  the	
  plant	
  to	
  the	
  blue	
  dye	
  indigotin.	
  	
  


The	
   precipitate	
   from	
   the	
   fermented	
   leaf	
   solution	
   is	
   mixed	
   with	
   a	
   strong	
   base	
  
such	
   as	
   lye,	
   pressed	
   into	
   cakes,	
   dried,	
   and	
   powdered.	
  The	
   powder	
   is	
   then	
   mixed	
  
with	
   various	
   other	
   substances	
   to	
   produce	
   different	
   shades	
   of	
   blue	
   and	
  
purple.Four	
   months	
   after	
   planting	
   the	
   seeds	
   the	
   leaves	
   of	
   the	
   indigo	
   plant	
   start	
  
turning	
  dark	
  green	
  which	
  indicates	
  good	
  quality	
  dye.	
  The	
  plants	
  are	
  cut	
  off	
  and	
  
made	
  into	
  small	
  bundles.The	
  leaves	
  are	
  then	
  soaked	
  in	
  a	
  large	
  earthenware	
  jar	
  
filled	
   with	
   water	
   and	
   left	
   to	
   be	
   fermented	
   in	
   order	
   to	
   convert	
   the	
   glycoside	
  
indican	
  which	
  is	
  naturally	
  present	
  in	
  the	
  plant	
  to	
  the	
  blue	
  dye	
  indigotin.	
  	
  




                                                                                                  DENIMIST
DBDENIM B O O K


The	
   precipitate	
   from	
   the	
   fermented	
   leaf	
   solution	
   is	
   mixed	
   with	
   a	
   strong	
   base	
  
such	
   as	
   lye,	
   pressed	
   into	
   cakes,	
   dried,	
   and	
   powdered.	
  The	
   powder	
   is	
   then	
   mixed	
  
with	
  various	
  other	
  substances	
  to	
  produce	
  different	
  shades	
  of	
  blue	
  and	
  purple.	
  

Indigofera	
  Tinctoria	
  in	
  History	
  

The	
  name	
  indigo	
  comes	
  from	
   	
  the	
   	
  Roman	
   	
   	
   	
  term	
   	
  indicum,	
   	
  which	
   	
  means	
   	
  a	
  
product	
  	
  	
  of	
  	
  India.This	
  	
  is	
  	
  somewhat	
  	
  of	
  	
  a	
  	
  misnomer	
  	
  since	
  	
  the	
  	
  plant	
  	
  is	
  	
  grown	
  
in	
   	
  many	
   	
  areas	
   	
   	
  of	
   	
  the	
   	
  world,	
   	
  including	
   	
   Asia,	
   	
  Java,	
   	
  Japan,	
   	
  and	
   	
   Central	
  
America.	
  	
  Another	
  	
   ancient	
  	
  	
   term	
  	
   for	
  	
   the	
  	
   dye	
  	
   is	
  	
   nil	
  	
   from	
  	
   which	
  	
   the	
  	
  Arabic	
  
term	
   	
  For	
   	
  blue,	
   	
  al-­‐nil,	
   	
  is	
   	
  derived.	
   	
  The	
   	
   	
  English	
   	
  word	
   	
  aniline	
   	
  comes	
   	
  from	
   	
  the	
  
same	
  	
  source.	
  	
  

The	
  	
   color	
  	
   indigo,	
  	
   often	
  	
   associated	
  	
   with	
  	
   political	
  	
   power	
  	
   or	
  	
   religious	
  	
   ritual,	
  
has	
   	
   	
   held	
   	
   a	
   	
   Significant	
   	
   Place	
   	
   in	
   	
   many	
   	
   world	
   	
   civilizations	
   	
   such	
   	
   as	
  
Mesopotamia,	
   	
  Egypt,	
   	
   	
   	
   	
  Greece,	
   	
  Rome,	
   	
  Mesoamerica,	
   	
  Iran,	
   	
  and	
   	
  Africa	
   	
  for	
  
thousands	
  	
  of	
  	
  years.	
  	
  In	
  	
  the	
  	
  	
  excavation	
  	
  of	
  	
  Thebes	
  	
  an	
  	
  indigo	
  	
  Garment	
  	
  dating	
  
from	
   	
  c.	
   	
  2500	
   	
  B.C.	
   	
  was	
   	
  found,	
   	
  for	
   	
   	
  example	
   	
   	
  example	
   	
   	
   	
  furthermore,	
   	
  the	
  	
  
Hindu	
  	
  god	
  Krishna	
  	
  is	
  	
  most	
  	
  often	
  	
  depicted	
  	
  in	
  	
  blue,	
  	
  	
  human	
  	
  Sacrifices	
  	
  were	
  	
  	
  




                                                                                                                                     DENIMIST
DBDENIM B O O K


often	
   painted	
   blue	
   	
   in	
   	
   ancient	
   	
   	
   mayan	
   	
   culture,	
   	
   and	
   	
   the	
   	
   	
   Virgin	
   	
   Mary	
   	
   is	
  	
  
regularly	
   imagined	
   draped	
  	
   in	
  	
   blue	
   clothes	
  	
   in	
  Christian	
  	
   art.	
  	
   In	
  	
  	
   Mesopotamia,	
  	
  
a	
  	
   Neo	
   -­‐Babylonian	
   cuneiform	
  	
   tablet	
   of	
  	
   the	
  	
   7th	
  	
   century	
   BC	
  	
  	
  	
  	
   gives	
  	
   a	
  	
   recipe	
  	
  
for	
  	
  the	
  dyeing	
  	
  of	
  wool,	
  	
  where	
  	
  lapis-­‐colored	
  wool	
  	
  (uqnatu)	
  	
  is	
  	
  	
  	
  	
  Produced	
  	
  by	
  	
  
repeated	
  	
  immersion	
  	
  and	
  	
  airing	
  	
  of	
  the	
  	
  cloth.	
  	
  	
  

The	
   	
  dye	
   	
  is	
   	
  first	
   	
  mentioned	
   	
  in	
   	
  a	
   	
  written	
   	
  source	
   	
  for	
   	
  Western	
   	
  Europe	
   	
  in	
   	
  The	
  	
  	
  
histories	
  	
   of	
   Herodotus	
  	
   writing	
  	
   around	
  	
   450	
  	
   B.C.),	
  	
   who	
  	
   described	
  	
   its	
  	
   use	
  	
   in	
  
the	
  mediterranean	
  	
  area.	
  The	
  	
  Romans	
  	
  used	
  	
  	
  	
  merchants.	
  
Indigo	
  	
   plant	
  	
   used	
  	
   to	
  	
   be	
  	
  	
   planted	
  	
   in	
  	
   Khuzestan	
  	
   and	
  	
   other	
  	
  Southernregions	
  	
  
of	
  Iran	
   	
  too.	
   	
  It	
   	
  was	
   	
  at	
   	
  the	
  time	
  of	
  the	
  Crusades,	
  however,	
   	
  that	
  indigo	
   	
  became	
  	
  
one	
   of	
   	
   the	
   	
   valued	
   	
   “spices”	
   	
   That	
   	
   Italian	
   	
   merchants	
   	
   acquired	
   	
   in	
   	
  Cyprus,	
  
Alexandria	
   and	
   	
   Baghdad.	
  These	
   	
   cities	
   	
   were	
   	
   themselves	
   	
   end	
   points	
   	
   for	
  	
  
caravans	
   	
  from	
   	
  the	
  Far	
   	
  East.	
   	
  But	
   	
  the	
   	
  trade	
   	
  in	
   	
  indigo	
   	
  dye	
   	
  only	
   	
  became	
   	
  a	
  	
  
Commercial	
  	
   force	
  	
   after	
   1498	
  	
   with	
  	
   the	
  	
   opening	
  	
  	
   of	
  	
   the	
  	
   sea	
  	
   route	
  	
   to	
  	
   India	
  
this	
   is	
   not	
   to	
   say	
   that	
   Europeans	
   had	
   no	
  Other	
  Way	
   of	
   obtaining	
   deep	
   blue	
   dye.	
  
The	
  woad	
  plant,	
  native	
  to	
  northern	
  Italy,	
  southern	
  France,	
  And	
  parts	
  of	
  England	
  	
  
and	
   Germany,	
  yielded	
  indigo-­‐colored	
  dye	
  from	
  its	
  leaves,	
  but	
  it	
  was	
  inferior	
  to	
  
that	
  Obtained	
  from	
  the	
  indigo	
  plant.	
  

This	
   is	
   not	
   to	
   say	
   that	
   Europeans	
   had	
   no	
   other	
  Way	
   of	
   obtaining	
   deep	
   blue	
   dye.	
  
The	
  woad	
  plant,	
  native	
  to	
  northern	
  Italy,	
  southern	
  France,	
  And	
  parts	
  of	
  England	
  
and	
   Germany,	
  yielded	
  indigo-­‐colored	
  dye	
  from	
  its	
  leaves,	
  but	
  it	
  was	
  inferior	
  to	
  
that	
   obtained	
   from	
   the	
   indigo	
   plant	
   quite	
   naturally,	
   the	
   woad	
   -­‐growers	
   of	
  
Europe	
   (both	
   peasants	
   and	
   princes)	
   sought	
   to	
   protect	
   their	
   industry	
   against	
   the	
  
influx	
  of	
  affordable	
  indigo	
  in	
  the	
  16th	
  century.	
  In	
  1598	
  indigo	
  was	
  prohibited	
  in	
  
France	
   and	
   parts	
   of	
   Germany,	
   and	
   dyers	
   had	
   to	
   swear,	
   often	
   on	
   the	
   pain	
   of	
  
death,	
  that	
  they	
  would	
  not	
  use	
  that	
  dye.	
  	
  

Nevertheless,	
  in	
  the	
  17th	
  century	
  indigo	
  became	
  one	
  of	
  the	
  chief	
  articles	
  of	
  trade	
  
of	
   both	
   the	
   Dutch	
   and	
   the	
   British	
   East	
   India	
  Companies.	
   	
   Dauril	
  Alden	
   argues	
  
that,	
   in	
   fact,	
   the	
   indigo	
   supplies	
   in	
   India	
   were	
   not	
   sufficient	
   to	
   meet	
   the	
  
European	
   demand	
   in	
   the	
   17th	
   century	
   and	
   that	
   is	
   why	
   indigo	
   cultivation	
   was	
  
taken	
  up	
  in	
  the	
  New	
  World	
  as	
  well.	
  	
  
DBDENIM B O O K


In	
   Japan,	
   indigo	
   became	
   especially	
   important	
   in	
   the	
   Edo	
   period	
   ,,	
   also	
   called	
  
Tokugawa	
  period,	
  is	
  a	
  division	
  of	
  Japanese	
  history	
  running	
  from	
  1603	
  to	
  1868)	
  
when	
   it	
   was	
   forbidden	
   to	
   use	
   silk,	
   so	
   the	
  Japanese	
   began	
   to	
   import	
   and	
   plant	
  
cotton.	
   It	
   was	
   difficult	
   to	
   dye	
   the	
   cotton	
   fiber	
   except	
   with	
   indigo.	
   Many	
   years	
  
later	
   the	
   use	
   of	
   indigo	
   is	
   very	
   much	
   appreciated	
   as	
   a	
   color	
   for	
   the	
   summer	
  
Kimono	
  Yukata,	
   as	
   the	
   blue	
   sea	
   and	
   the	
   nature	
   are	
   recalled	
   on	
   this	
   traditional	
  
clothing.	
  

An	
   indigenous	
   variety	
   of	
   indigo	
   began	
   to	
   be	
   cultivated	
   by	
  Spanish	
   overseers	
   on	
  
the	
   plantations	
   of	
   Honduras	
   and	
   the	
   Pacific	
   slopes	
   of	
   Central	
   America	
   in	
   the	
  
1560s.	
   The	
   indigo	
   plant	
   was	
   known	
   to	
   early	
   Guatemalan	
   colonialists	
   by	
   the	
  
Nahuatl	
   word	
   xiquilite,	
   and	
   the	
   dye	
   was	
   known	
   to	
   contemporaries	
   as	
  
“Guatemalan	
  Indigo.”	
  M.	
  De	
  Beauvais	
  Raseau,	
  writing	
  about	
  indigo	
  cultivation	
  
in	
   the	
   Eighteenth	
  Century,	
   stated	
   that	
   the	
   Native	
  Americans	
   also	
   knew	
   about	
  
extracting	
  from	
  the	
  plant.	
  	
  




                                                                                                   DENIMIST
DBDENIM B O O K


They	
  called	
  it	
  “Tlauhoylimihuitl”	
  and	
  used	
  it	
  to	
  darken	
  their	
  hair.	
  It	
  seems	
  that	
  
indigo	
  production	
  continued	
  to	
  increase	
  throughout	
  the	
  17th	
  century	
  in	
  the	
  New	
  
World.	
   The	
   French	
   colony	
   of	
   Saint	
   Domingo	
   eventually	
   became	
   the	
   major	
  
producer	
  of	
  indigo,	
  and	
  this	
  dye	
  was	
  also	
  of	
  the	
  best	
  quality.	
  The	
  English	
  gained	
  
their	
   first	
   indigo-­‐producing	
   colony	
   in	
   this	
   part	
   of	
   the	
   world	
   in	
   1655	
   when	
   they	
  
captured	
  Jamaica	
  




                                                                                                                                             DENIMIST




   Engraving	
  of	
  an	
  indigo	
  plantation	
  in	
  the	
  French	
  West	
  Indies,	
  1760s	
  
   This	
   engraving	
   shows	
   slaves	
   engaged	
   in	
   various	
   jobs	
   associated	
   with	
   indigo	
   production.	
  The	
   steps	
   are	
   identified	
   by	
  
   number	
   in	
   the	
   engraving;	
   an	
   accompanying	
   explanation	
   in	
   the	
   text	
   in	
   French	
   describes	
   each	
   number.	
   For	
   example,	
   no.	
  
   8,	
  slave	
  who	
  carries	
  the	
  indigo	
  plants	
  into	
  the	
  storage	
  tank	
  or	
  steeping	
  trough;	
  no.	
  9,	
  slave	
  who	
  agitate/stir	
  the	
  indigo	
  
   plants	
  in	
  the	
  steeping	
  trough	
  with	
  baskets	
  attached	
  to	
  the	
  end	
  of	
  poles);	
  no.	
  10,	
  indigo	
  plants.	
  

   M.	
  Chambon,	
  Le	
  commerce	
  de	
  l’Amerique	
  par	
  Marseille	
  (Avignon,	
  1764),	
  I:365.	
  
DB
                                                                                                DENIM B O O K


However,	
   it	
   is	
   unclear	
   how	
   important	
   New	
  World	
   indigo	
   was	
   in	
   the	
   worldwide	
  
indigo	
   market,	
   as	
   prices	
   fluctuated	
   and	
   so	
   did	
   production	
   numbers.	
   By	
   1740	
  
sugar	
  had	
  replaced	
  indigo	
  as	
  the	
  main	
  crop	
  of	
   Jamaica,	
  but,	
  on	
  the	
  other	
  hand,	
  
this	
  was	
  also	
  the	
  beginning	
  of	
  the	
  indigo	
  boom	
  in	
   South	
  Carolina	
  it	
  seems	
  that	
  
“Guatemalan	
   indigo”	
   did	
   not	
   enjoy	
   as	
   high	
   a	
   reputation	
   in	
   Europe	
   as	
   indigo	
  
from	
   Asian	
   countries.	
   In	
   1746,	
   when	
   “A	
   Friend	
   to	
   Carolina”	
   wrote	
   his	
   tract	
  
encouraging	
   the	
   cultivation	
   of	
   indigo	
   in	
   South	
   Carolina	
   he	
   emphasized	
   the	
  
necessity	
   of	
   establishing	
   a	
   superior	
   product:	
   “All	
   Kinds	
   [of	
   indigo	
   dyes]	
   are	
  
better	
   or	
   worse,	
   as	
   they	
   are	
   neat	
   or	
   pure;	
   for	
   those	
   who	
   make	
   it	
   in	
  America,	
  
often	
  maliciously	
  mix	
  it	
  with	
  Sand	
  and	
  Dirt,	
  but	
  the	
   Cheat	
  is	
  easily	
  discovered;	
  
as	
  Indigo	
  that	
  is	
  fine	
  and	
  pure	
  will	
  burn	
  like	
  Wax,	
  and,	
  when	
  burnt,	
  the	
  Earth	
  or	
  
Sand	
  will	
  remain.”	
  He	
  pointed	
  out	
  that	
  in	
  the	
  	
  

Americas	
  indigo	
  dye	
  was	
  o6en	
  made	
  with	
  the	
  stems	
  and	
  branches	
  of	
  the	
  plant	
  
instead	
  of	
  just	
  with	
  the	
  leaves.	
  He	
  felt	
  that	
  this	
  too	
  might	
  be	
  detrimental	
  to	
  its	
  
quality	
   -­‐	
   “But	
   one	
   ought	
   to	
   have	
   the	
   Leisure	
   and	
   PaHence	
   of	
   the	
   Indians,	
   to	
  
undertake	
   such	
   a	
   Work	
   [stripping	
   the	
   leaves],	
   and	
   have	
   Workmen	
   as	
   cheap	
   as	
  
they	
   are	
   in	
   that	
   Country.”	
   He	
   pointed	
   out	
   that	
   in	
   the	
   Americas	
   indigo	
   dye	
   was	
  
o6en	
   made	
   with	
   the	
   stems	
   and	
   branches	
   of	
   the	
   plant	
   instead	
   of	
   just	
   with	
   the	
  
leaves.	
  	
  

He	
  felt	
  that	
  this	
  too	
  might	
  be	
  detrimental	
  to	
  its	
  quality	
  —	
  “But	
  one	
  ought	
  to	
  have	
  
the	
   Leisure	
   and	
   PaHence	
   of	
   the	
   Indians,	
   to	
   undertake	
   such	
   a	
   Work	
   [stripping	
   the	
  
leaves],	
  and	
  have	
  Workmen	
  as	
  cheap	
  as	
  they	
  are	
  in	
  that	
  Country.”	
  	
  
Raseau,	
  who	
  was	
  captain	
  of	
  the	
  miliHa	
  on	
  Saint	
  Domingo	
  prior	
  to	
  1770,	
  discusses	
  
the	
  history	
  of	
  indigo	
  in	
  all	
  the	
  regions	
  of	
  the	
  world	
  where	
  it	
  could	
  be	
  grown.	
  	
  
He	
   gives	
   various	
   methods	
   that	
   were	
   employed	
   for	
   extracHng	
   the	
   dye	
   and	
   then	
  
goes	
  into	
  greater	
  detail	
  on	
  indigo	
  producHon	
  in	
  South	
  and	
  Central	
  America.	
  His	
  
wonderful	
   liXle	
   book	
   contains	
   diagrams	
   of	
   the	
   plants,	
   the	
   process	
   of	
   making	
  
indigo	
   dye,	
   as	
   well	
   as	
   the	
   ideal	
   plantaHon.	
   Indigo	
   plantaHons	
   did	
   not	
   require	
  
much	
  labor	
  except	
  during	
  July,	
  August	
  and	
  September	
  when	
  the	
  plants	
  were	
  cut,	
  
fermented	
  and	
  the	
  dye	
  was	
  extracted.	
  

Because	
   it	
   was	
   thought	
   that	
   the	
   Indians	
   were	
   parHcularly	
   suscepHble	
   to	
   the	
  
diseases	
  that	
  bred	
  around	
  the	
  fermentaHon	
  vats,	
  plantaHon	
  owners	
  claimed	
  that	
  
DB
                                                                                                   DENIM B O O K


they	
  did	
  most	
  of	
  the	
  field	
  work,	
  while	
  Black	
  slaves	
  extracted	
  the	
  dye.	
  In	
  reality,	
  
the	
   division	
   of	
   labor	
   was	
   probably	
   not	
   so	
   strict	
   	
   parHcularly	
   since	
   Black	
   slaves	
  
were	
  in	
  relaHvely	
  short	
  supply	
  and	
  were	
  o6en	
  more	
  expensive	
  to	
  hire	
  than	
  the	
  
Indians.John	
   Stedman	
   in	
   his	
   "NarraHve	
   of	
   five	
   years"	
   expediHon	
   described	
   the	
  
extracHon	
   of	
   the	
   dye	
   throughly.	
   Stedman	
   was	
   invited	
   to	
   view	
   the	
   process	
   of	
  
making	
  indigo	
  dye	
  at	
  the	
  plantaHon	
  of	
  the	
  governor	
  of	
  Surinam	
  and	
  he	
  gives	
  the	
  
following	
  account	
  of	
  it	
  :	
  When	
  all	
  of	
  the	
  verdure	
  is	
  cut	
  off,	
  the	
  whole	
  crop	
  is	
  Hed	
  
in	
   bunches,	
   and	
   put	
   into	
   a	
   very	
   large	
   tub	
   with	
   water,	
   covered	
   over	
   with	
   very	
  
heavy	
   logs	
   of	
   wood	
   by	
   way	
   of	
   pressers:	
   thus	
   kept,	
   it	
   begins	
   to	
   ferment;	
   in	
   less	
  
than	
  18	
  hours	
  the	
  water	
  seems	
  to	
  boil,	
  and	
  becomes	
  of	
  a	
  violet	
  or	
  garter	
  blue	
  
colour,	
   extracHng	
   all	
   the	
   grain	
   or	
   colouring	
   maXer	
   from	
   the	
   plant;	
   in	
   this	
  
situaHon.	
  

The	
   liquor	
   is	
   drawn	
   off	
   into	
   another	
   tub,	
   which	
   is	
   something	
   less,	
   when	
   the	
  
remaining	
   trash	
   is	
   carefully	
   picked	
   up	
   and	
   thrown	
   away;	
   and	
   the	
   very	
   noxious	
  
smell	
  of	
  this	
  refuse	
  it	
  is	
  that	
  occasions	
  the	
  peculiar	
  unhealthiness	
  which	
  is	
  always	
  
incident	
  to	
  this	
  business	
  

Being	
   now	
   in	
   the	
   second	
   tub,	
   the	
   mash	
   is	
   agitated	
   by	
   paddles	
   adapted	
   for	
   the	
  
purpose,	
  Hll	
  by	
  a	
  skillful	
  maceraHon	
  all	
  the	
  grain	
  separates	
  from	
  the	
  water,	
  the	
  
first	
   sinking	
   like	
   mud	
   to	
   the	
   boXom,	
   while	
   the	
   laXer	
   appears	
   clear	
   and	
  
transparent	
   on	
   the	
   surface:	
   this	
   water,	
   being	
   carefully	
   removed	
   Hll	
   near	
   the	
  
coloured	
   mass,	
   the	
   remaining	
   liquor	
   is	
   drawn	
   off	
   into	
   a	
   third	
   tub,	
   to	
   let	
   what	
  
indigo	
   it	
   may	
   contain	
   also	
   seXle	
   in	
   the	
   boXom;	
   a6er	
   which,	
   the	
   last	
   drops	
   of	
  
water	
  here	
  being	
  also	
  removed,	
  the	
  sediment	
  or	
  indigo	
  is	
  put	
  into	
  proper	
  vessels	
  
to	
   dry,	
   where	
   being	
   divested	
   of	
   its	
   last	
   remaining	
   moisture,	
   and	
   formed	
   into	
  
small,	
  round,	
  and	
  oblong	
  square	
  pieces,	
  it	
  is	
  become	
  a	
  beauHful	
  dark	
  blue,	
  and	
  
fit	
  for	
  exportaHon.	
  	
  

The	
   best	
   indigo	
   ought	
   to	
   be	
   light,	
   hard,	
   and	
   sparkling."	
   These	
   blocks	
   of	
   indigo	
  
were	
  what	
  was	
  so	
  highly	
  prized	
  on	
  the	
  European	
  market.	
  	
  
Demand	
   for	
   indigo	
   dramaHcally	
   increased	
   during	
   	
   the	
   industrial	
   revoluHon,	
   in	
  
part	
   due	
   to	
   the	
   popularity	
   of	
   Levi	
   Strauss's	
   blue	
   denim	
   jeans.	
   The	
   natural	
  
extracHon	
   process	
   was	
   expensive	
   and	
   could	
   not	
   produce	
   the	
   mass	
   quanHHes	
  
required	
  for	
  the	
  burgeoning	
  garment	
  industry.	
  In	
  1865	
  the	
  German	
  chemist	
  	
  	
  
DB
                                                                                                      DENIM B O O K


Johann	
  Friedrich	
  Wilhelm	
  Adolf	
  von	
  Baeyer	
  began	
  working	
  with	
  indigo.	
  	
  
His	
   work	
   culminated	
   in	
   the	
   first	
   synthesis	
   of	
   indigo	
   in	
   1880	
   from	
   o-­‐
nitrobenzaldehyde	
   and	
   acetone	
   upon	
   addiHon	
   of	
   dilute	
   sodium	
   hydroxide,	
  
barium	
  hydroxide,	
  or	
  ammonia	
  and	
  the	
  announcement	
  of	
  its	
  chemical	
  structure	
  
three	
  years	
  later.	
  BASF	
  developed	
  a	
  commercially	
  feasible	
  manufacturing	
  process	
  
that	
   was	
   in	
   use	
   by	
   1897.	
   In	
   1905	
   Baeyer	
   was	
   awarded	
   the	
   Nobel	
   Prize	
   for	
   his	
  
discovery.	
  




                                                                                                       DENIMIST




 Workers	
  in	
  the	
  	
  indigo	
  factory	
  wearing	
  denim	
  work	
  clothes,	
  1930s	
  
  Jenny	
  Balfour-­‐Paul,	
  Indigo	
  (London:	
  Bri-sh	
  Museum	
  Press,	
  1998),	
  85.	
  
DBDENIM B O O K




                                                                     DENIMIST




“Indigo	
  Manufacture	
  in	
  India,”	
  from	
  The	
  Graphic,	
  1887	
  

“Views	
   from	
   the	
   Illustrated	
   London	
   News	
   and	
   The	
   Graphic,”	
   South	
   Asia	
  
study	
   resources	
   compiled	
   by	
   Frances	
   PritcheK,	
   hKp://www.	
  
columbia.edu/itc/mealac/pritcheK/00routesdata/1800_1899/
dailylife_drawings/ilnviews/ilnviews.html	
  
DB
                                                                           DENIM BOOK




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History of indıgo.

  • 1. d   n  m   o   k   1 e   i   b   o   DENIMIST  2011   DNMSTDENIMDESINGFASHIONARTLIFE   DB DENIM BOOK D E N I M I S T
  • 2. DB DENIM B O O K DENIMIST T U R K E Y   Since   decades   Denimist   has   developed   know-­‐how   in   denim   finishing   prior   to   garment   manufacturing   and   also   in   jeans   washing.   Our   customers   derive   benefit   from   this   experience.For   the   fabric   production   we   offer   finishing   chemicals   which   provide   the   demanded   fabric   properties   such   as   good   sewability,   stiffness,elasticity   and   handle.   The   other   field   of   our   activity   is   the   recommendation   of   laundring   Procedures   for   ready-­‐made   clothing   such   as   trousers,  jackets  or  skirts,  shirts.   In   doing   so   we   have   learned   that   many   errors   may   occur   in   this   complicated   production   process.  The   laundry,   the   last   step   in   the   sequence   of     producers,   is   faced   to   difficulties   which   are   caused   by   previous   inaccuracies.   Therefore,   a   good   cooperation   among   the   steps   of   jeans   manufacturing   is   required   to   avoid   problems.  Fabric  producer,  garment  manufacturer  and  laundries  have  to  work   together   to   obtain   the   desired   end   result.   By   means   of   our   contacts   on   both   sides  of  the  production  process  we  are  able  to  make  our  contribution.   The   technical   stuff   of   Denimist     is   always   ready   to   help   our   customers   with   eventual   problems   and   to   modify   production   procedures   according   to   the   respective   requirements.  Through   our   numerous   contacts   which   we   have   got   with  denim  producers,  garment  manufacturers  and  laundries  during  the  years   we  support  the  team  work  among  all  sections  of  the  jeans  chain  and  make  our   know-­‐how    available  to  all  of  the  parties  concerned    
  • 3. DBDENIM B O O K History  of  Natural  Indigo   A   variety   of   plants   have   provided   indigo   throughout   history,   but   most   natural   indigo  is  obtained  from  those  in  the  genus  Indigofera,  which  are  native  to  the   tropics.   In   temperate   climates   indigo   can   also   be   obtained   from   woad   (Isatis   tinctoria)  and  dyer's  knotweed  (Polygonumtinctorum).     The   primary   commercial   indigo   species   in   Asia   was   true   indigo   (Indigofera   tinctoria,   also   known   as   Indigofera   sumatrana).   In  Central   and   South  America   the   two   species   Indigofera   suffruticosa   (Anil)   and   Indigofera   arrecta   (Natal   indigo)  were  the  most  important.     The  plants  of  the  genus  Indigofera  produce  a  much  stronger  dye  that  those  of   the   Isatis   (woad)   family;   however,   dyer’s   woad   is   much   more   easily   cultivated   and  therefore  more  widely  used  than  Indigofera,  which  needs  a  tropical  climate.   Isatis  tinctoria  grows  up  to  approximately  1.50  m  in  height  and  can  be  harvested   three  times  a  year.   Preparation  of  indigo  dye  with  Indigofera  tinctoria.   A   variety   of   plants   have   provided   indigo   throughout   history,   but   most   natural   indigo  is  obtained  from  those  in  the  genus  Indigofera,  which  are  native  to  the   tropics.   In   temperate   climates   indigo   can   also   be   obtained   from   woad   (Isatis   tinctoria)  and  dyer's  knotweed  (Polygonumtinctorum).     The   primary   commercial   indigo   species   in   Asia   was   true   indigo   (Indigofera   tinctoria,   also   known   as   Indigofera   sumatrana).   In  Central   and   South  America   the   two   species   Indigofera   suffruticosa   (Anil)   and   Indigofera   arrecta   (Natal   indigo)  were  the  most  important.     The  plants  of  the  genus  Indigofera  produce  a  much  stronger  dye  that  those  of   the   Isatis   (woad)   family;   however,   dyer’s   woad   is   much   more   easily   cultivated   and  therefore  more  widely  used  than  Indigofera,  which  needs  a  tropical  climate.   Isatis  tinctoria  grows  up  to  approximately  1.50  m  in  height  and  can  be  harvested   three  times  a  year.  
  • 4. DB DENIM B O O K Four  months  after  planting  the  seeds  the  leaves  of  the  indigo  plant  start  turning   dark   green   which   indicates   good   quality   dye.   The   plants   are   cut   off   and   made   into  small  bundles.The  leaves  are  then  soaked  in  a  large  earthenware  jar  filled   with   water   and   left   to   be   fermented   in   order   to   convert   the   glycoside   indican   which  is  naturally  present  in  the  plant  to  the  blue  dye  indigotin.     The   precipitate   from   the   fermented   leaf   solution   is   mixed   with   a   strong   base   such   as   lye,   pressed   into   cakes,   dried,   and   powdered.  The   powder   is   then   mixed   with   various   other   substances   to   produce   different   shades   of   blue   and   purple.Four   months   after   planting   the   seeds   the   leaves   of   the   indigo   plant   start   turning  dark  green  which  indicates  good  quality  dye.  The  plants  are  cut  off  and   made  into  small  bundles.The  leaves  are  then  soaked  in  a  large  earthenware  jar   filled   with   water   and   left   to   be   fermented   in   order   to   convert   the   glycoside   indican  which  is  naturally  present  in  the  plant  to  the  blue  dye  indigotin.     DENIMIST
  • 5. DBDENIM B O O K The   precipitate   from   the   fermented   leaf   solution   is   mixed   with   a   strong   base   such   as   lye,   pressed   into   cakes,   dried,   and   powdered.  The   powder   is   then   mixed   with  various  other  substances  to  produce  different  shades  of  blue  and  purple.   Indigofera  Tinctoria  in  History   The  name  indigo  comes  from    the    Roman        term    indicum,    which    means    a   product      of    India.This    is    somewhat    of    a    misnomer    since    the    plant    is    grown   in    many    areas      of    the    world,    including     Asia,    Java,    Japan,    and     Central   America.    Another     ancient       term     for     the     dye     is     nil     from     which     the    Arabic   term    For    blue,    al-­‐nil,    is    derived.    The      English    word    aniline    comes    from    the   same    source.     The     color     indigo,     often     associated     with     political     power     or     religious     ritual,   has       held     a     Significant     Place     in     many     world     civilizations     such     as   Mesopotamia,    Egypt,          Greece,    Rome,    Mesoamerica,    Iran,    and    Africa    for   thousands    of    years.    In    the      excavation    of    Thebes    an    indigo    Garment    dating   from    c.    2500    B.C.    was    found,    for      example      example        furthermore,    the     Hindu    god  Krishna    is    most    often    depicted    in    blue,      human    Sacrifices    were       DENIMIST
  • 6. DBDENIM B O O K often   painted   blue     in     ancient       mayan     culture,     and     the       Virgin     Mary     is     regularly   imagined   draped     in     blue   clothes     in  Christian     art.     In       Mesopotamia,     a     Neo   -­‐Babylonian   cuneiform     tablet   of     the     7th     century   BC           gives     a     recipe     for    the  dyeing    of  wool,    where    lapis-­‐colored  wool    (uqnatu)    is          Produced    by     repeated    immersion    and    airing    of  the    cloth.       The    dye    is    first    mentioned    in    a    written    source    for    Western    Europe    in    The       histories     of   Herodotus     writing     around     450     B.C.),     who     described     its     use     in   the  mediterranean    area.  The    Romans    used        merchants.   Indigo     plant     used     to     be       planted     in     Khuzestan     and     other    Southernregions     of  Iran    too.    It    was    at    the  time  of  the  Crusades,  however,    that  indigo    became     one   of     the     valued     “spices”     That     Italian     merchants     acquired     in    Cyprus,   Alexandria   and     Baghdad.  These     cities     were     themselves     end   points     for     caravans    from    the  Far    East.    But    the    trade    in    indigo    dye    only    became    a     Commercial     force     after   1498     with     the     opening       of     the     sea     route     to     India   this   is   not   to   say   that   Europeans   had   no  Other  Way   of   obtaining   deep   blue   dye.   The  woad  plant,  native  to  northern  Italy,  southern  France,  And  parts  of  England     and   Germany,  yielded  indigo-­‐colored  dye  from  its  leaves,  but  it  was  inferior  to   that  Obtained  from  the  indigo  plant.   This   is   not   to   say   that   Europeans   had   no   other  Way   of   obtaining   deep   blue   dye.   The  woad  plant,  native  to  northern  Italy,  southern  France,  And  parts  of  England   and   Germany,  yielded  indigo-­‐colored  dye  from  its  leaves,  but  it  was  inferior  to   that   obtained   from   the   indigo   plant   quite   naturally,   the   woad   -­‐growers   of   Europe   (both   peasants   and   princes)   sought   to   protect   their   industry   against   the   influx  of  affordable  indigo  in  the  16th  century.  In  1598  indigo  was  prohibited  in   France   and   parts   of   Germany,   and   dyers   had   to   swear,   often   on   the   pain   of   death,  that  they  would  not  use  that  dye.     Nevertheless,  in  the  17th  century  indigo  became  one  of  the  chief  articles  of  trade   of   both   the   Dutch   and   the   British   East   India  Companies.     Dauril  Alden   argues   that,   in   fact,   the   indigo   supplies   in   India   were   not   sufficient   to   meet   the   European   demand   in   the   17th   century   and   that   is   why   indigo   cultivation   was   taken  up  in  the  New  World  as  well.    
  • 7. DBDENIM B O O K In   Japan,   indigo   became   especially   important   in   the   Edo   period   ,,   also   called   Tokugawa  period,  is  a  division  of  Japanese  history  running  from  1603  to  1868)   when   it   was   forbidden   to   use   silk,   so   the  Japanese   began   to   import   and   plant   cotton.   It   was   difficult   to   dye   the   cotton   fiber   except   with   indigo.   Many   years   later   the   use   of   indigo   is   very   much   appreciated   as   a   color   for   the   summer   Kimono  Yukata,   as   the   blue   sea   and   the   nature   are   recalled   on   this   traditional   clothing.   An   indigenous   variety   of   indigo   began   to   be   cultivated   by  Spanish   overseers   on   the   plantations   of   Honduras   and   the   Pacific   slopes   of   Central   America   in   the   1560s.   The   indigo   plant   was   known   to   early   Guatemalan   colonialists   by   the   Nahuatl   word   xiquilite,   and   the   dye   was   known   to   contemporaries   as   “Guatemalan  Indigo.”  M.  De  Beauvais  Raseau,  writing  about  indigo  cultivation   in   the   Eighteenth  Century,   stated   that   the   Native  Americans   also   knew   about   extracting  from  the  plant.     DENIMIST
  • 8. DBDENIM B O O K They  called  it  “Tlauhoylimihuitl”  and  used  it  to  darken  their  hair.  It  seems  that   indigo  production  continued  to  increase  throughout  the  17th  century  in  the  New   World.   The   French   colony   of   Saint   Domingo   eventually   became   the   major   producer  of  indigo,  and  this  dye  was  also  of  the  best  quality.  The  English  gained   their   first   indigo-­‐producing   colony   in   this   part   of   the   world   in   1655   when   they   captured  Jamaica   DENIMIST Engraving  of  an  indigo  plantation  in  the  French  West  Indies,  1760s   This   engraving   shows   slaves   engaged   in   various   jobs   associated   with   indigo   production.  The   steps   are   identified   by   number   in   the   engraving;   an   accompanying   explanation   in   the   text   in   French   describes   each   number.   For   example,   no.   8,  slave  who  carries  the  indigo  plants  into  the  storage  tank  or  steeping  trough;  no.  9,  slave  who  agitate/stir  the  indigo   plants  in  the  steeping  trough  with  baskets  attached  to  the  end  of  poles);  no.  10,  indigo  plants.   M.  Chambon,  Le  commerce  de  l’Amerique  par  Marseille  (Avignon,  1764),  I:365.  
  • 9. DB DENIM B O O K However,   it   is   unclear   how   important   New  World   indigo   was   in   the   worldwide   indigo   market,   as   prices   fluctuated   and   so   did   production   numbers.   By   1740   sugar  had  replaced  indigo  as  the  main  crop  of   Jamaica,  but,  on  the  other  hand,   this  was  also  the  beginning  of  the  indigo  boom  in   South  Carolina  it  seems  that   “Guatemalan   indigo”   did   not   enjoy   as   high   a   reputation   in   Europe   as   indigo   from   Asian   countries.   In   1746,   when   “A   Friend   to   Carolina”   wrote   his   tract   encouraging   the   cultivation   of   indigo   in   South   Carolina   he   emphasized   the   necessity   of   establishing   a   superior   product:   “All   Kinds   [of   indigo   dyes]   are   better   or   worse,   as   they   are   neat   or   pure;   for   those   who   make   it   in  America,   often  maliciously  mix  it  with  Sand  and  Dirt,  but  the   Cheat  is  easily  discovered;   as  Indigo  that  is  fine  and  pure  will  burn  like  Wax,  and,  when  burnt,  the  Earth  or   Sand  will  remain.”  He  pointed  out  that  in  the     Americas  indigo  dye  was  o6en  made  with  the  stems  and  branches  of  the  plant   instead  of  just  with  the  leaves.  He  felt  that  this  too  might  be  detrimental  to  its   quality   -­‐   “But   one   ought   to   have   the   Leisure   and   PaHence   of   the   Indians,   to   undertake   such   a   Work   [stripping   the   leaves],   and   have   Workmen   as   cheap   as   they   are   in   that   Country.”   He   pointed   out   that   in   the   Americas   indigo   dye   was   o6en   made   with   the   stems   and   branches   of   the   plant   instead   of   just   with   the   leaves.     He  felt  that  this  too  might  be  detrimental  to  its  quality  —  “But  one  ought  to  have   the   Leisure   and   PaHence   of   the   Indians,   to   undertake   such   a   Work   [stripping   the   leaves],  and  have  Workmen  as  cheap  as  they  are  in  that  Country.”     Raseau,  who  was  captain  of  the  miliHa  on  Saint  Domingo  prior  to  1770,  discusses   the  history  of  indigo  in  all  the  regions  of  the  world  where  it  could  be  grown.     He   gives   various   methods   that   were   employed   for   extracHng   the   dye   and   then   goes  into  greater  detail  on  indigo  producHon  in  South  and  Central  America.  His   wonderful   liXle   book   contains   diagrams   of   the   plants,   the   process   of   making   indigo   dye,   as   well   as   the   ideal   plantaHon.   Indigo   plantaHons   did   not   require   much  labor  except  during  July,  August  and  September  when  the  plants  were  cut,   fermented  and  the  dye  was  extracted.   Because   it   was   thought   that   the   Indians   were   parHcularly   suscepHble   to   the   diseases  that  bred  around  the  fermentaHon  vats,  plantaHon  owners  claimed  that  
  • 10. DB DENIM B O O K they  did  most  of  the  field  work,  while  Black  slaves  extracted  the  dye.  In  reality,   the   division   of   labor   was   probably   not   so   strict     parHcularly   since   Black   slaves   were  in  relaHvely  short  supply  and  were  o6en  more  expensive  to  hire  than  the   Indians.John   Stedman   in   his   "NarraHve   of   five   years"   expediHon   described   the   extracHon   of   the   dye   throughly.   Stedman   was   invited   to   view   the   process   of   making  indigo  dye  at  the  plantaHon  of  the  governor  of  Surinam  and  he  gives  the   following  account  of  it  :  When  all  of  the  verdure  is  cut  off,  the  whole  crop  is  Hed   in   bunches,   and   put   into   a   very   large   tub   with   water,   covered   over   with   very   heavy   logs   of   wood   by   way   of   pressers:   thus   kept,   it   begins   to   ferment;   in   less   than  18  hours  the  water  seems  to  boil,  and  becomes  of  a  violet  or  garter  blue   colour,   extracHng   all   the   grain   or   colouring   maXer   from   the   plant;   in   this   situaHon.   The   liquor   is   drawn   off   into   another   tub,   which   is   something   less,   when   the   remaining   trash   is   carefully   picked   up   and   thrown   away;   and   the   very   noxious   smell  of  this  refuse  it  is  that  occasions  the  peculiar  unhealthiness  which  is  always   incident  to  this  business   Being   now   in   the   second   tub,   the   mash   is   agitated   by   paddles   adapted   for   the   purpose,  Hll  by  a  skillful  maceraHon  all  the  grain  separates  from  the  water,  the   first   sinking   like   mud   to   the   boXom,   while   the   laXer   appears   clear   and   transparent   on   the   surface:   this   water,   being   carefully   removed   Hll   near   the   coloured   mass,   the   remaining   liquor   is   drawn   off   into   a   third   tub,   to   let   what   indigo   it   may   contain   also   seXle   in   the   boXom;   a6er   which,   the   last   drops   of   water  here  being  also  removed,  the  sediment  or  indigo  is  put  into  proper  vessels   to   dry,   where   being   divested   of   its   last   remaining   moisture,   and   formed   into   small,  round,  and  oblong  square  pieces,  it  is  become  a  beauHful  dark  blue,  and   fit  for  exportaHon.     The   best   indigo   ought   to   be   light,   hard,   and   sparkling."   These   blocks   of   indigo   were  what  was  so  highly  prized  on  the  European  market.     Demand   for   indigo   dramaHcally   increased   during     the   industrial   revoluHon,   in   part   due   to   the   popularity   of   Levi   Strauss's   blue   denim   jeans.   The   natural   extracHon   process   was   expensive   and   could   not   produce   the   mass   quanHHes   required  for  the  burgeoning  garment  industry.  In  1865  the  German  chemist      
  • 11. DB DENIM B O O K Johann  Friedrich  Wilhelm  Adolf  von  Baeyer  began  working  with  indigo.     His   work   culminated   in   the   first   synthesis   of   indigo   in   1880   from   o-­‐ nitrobenzaldehyde   and   acetone   upon   addiHon   of   dilute   sodium   hydroxide,   barium  hydroxide,  or  ammonia  and  the  announcement  of  its  chemical  structure   three  years  later.  BASF  developed  a  commercially  feasible  manufacturing  process   that   was   in   use   by   1897.   In   1905   Baeyer   was   awarded   the   Nobel   Prize   for   his   discovery.   DENIMIST Workers  in  the    indigo  factory  wearing  denim  work  clothes,  1930s   Jenny  Balfour-­‐Paul,  Indigo  (London:  Bri-sh  Museum  Press,  1998),  85.  
  • 12. DBDENIM B O O K DENIMIST “Indigo  Manufacture  in  India,”  from  The  Graphic,  1887   “Views   from   the   Illustrated   London   News   and   The   Graphic,”   South   Asia   study   resources   compiled   by   Frances   PritcheK,   hKp://www.   columbia.edu/itc/mealac/pritcheK/00routesdata/1800_1899/ dailylife_drawings/ilnviews/ilnviews.html  
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