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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1095
Substituting Natural Fiber by Plastic Waste
Prashast Dheer1, Satya Veer Singh2
1M.Tech Student, Department of Civil Engineering, Rama University, (India)
2Assistant Professor, Department of Civil Engineering, Rama University, (India)
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - This article reviews the literature reports base on
agro waste plastic composites using different fiber as fillers
and rein- for cements. Various processing methods and
conditions; compression molding process, injection molding,
and extru- Sion method are used in the composites
productions. Characterization challenges associated with the
agro waste plastic composites productions were also
examined. Thus, the findings of this research review can be
used as a data base for further inquiring into the agro waste
plastic composites in a view to enhancethe developmentof the
sector.
Plastic wastes are a major environmental concern that needs
to be dealt with to minimize the amount of municipal solid
waste and depletion of natural resources thus enhancing the
sustainability concept for future generations. The objective of
this study is to enhance the propertiesofplasticproducts using
plastic wastes reinforced with treated natural fibers such as
rice straw as well as carbonized rice straw, using a simpleand
efficient technology.
Keywords: Polymers-Matrix Composites (PMCs); Recycled
Polymer; Natural Fibers; Fiber Reinforced Plastic; Agro
Waste Plastic Composite; Characterization; Production
I. INTRODUCTION
In developing countries of the world, plastic waste has
become a current challenge for the environmental engineers
to solve. For an example developing country like India,
statistics show that the exponential growthrateofIndia with
1,210,000,000 (1.21 billion) people is the second most
populous country in the world, whileChina isonthetop with
over 1,350,044,605 (1.35 billion) people. The figures show
that India represents almost 17.31% of the world's
population, which means one out of six people on thisplanet
live in India. Although, the crown of the world's most
populous country is on China’s head for decades, India is all
set to take the numerous positions by 2030. With the
population growth rate at 1.58%, India is predicted to have
more than 1.53 billion people by the end of 2030. Being
second most populous country in the world, India
continuously keeps on adding waste material within its
geographical boundaries. India has about 16% of the world
population and 2.5% of world’s land area. In an already
densely populated country with even more densely packed
urban centers, land for properwastetreatment,disposal and
overall man-agreement is scarce. Recent and sustained
economic growth increasing living standards of the people,
in-creased manufacturing and production activities has led
to increase to rapid rise in the waste generation rated. India
produces around 42 Million tons of solid waste annually.
There is wide difference in the waste generation rates in
rural and urban areas. Even within the urban areas, the
composition includes more paperandinertmaterial andless
of organic and compostable material as the city population
and size increases Now with the above data we can calculate
the per day generation of solid waste of India & also we can
calculate the expected cost for its management whichcan be
done by the processes minimization, recycling & disposal of
the solid waste generated. These processes have been
adopted by the most developed countries as the menu for
developing solid waste management strategies. Depending
upon a number of factors such as topography climate,
population density (village to metro city), transportation
infrastructure, socioeconomic and environmental laws of
India it is important to make proper pre action plan to
manage solid waste.
The market potential regarding the usage of plastic waste
into other utilizations is huge due to the high amounts of its
disposition which constitute the largest share of the global
municipal solid waste (MSW). Plastics account for an
increasing fraction of municipal solid waste around the world.
In India, plastic in MSW makes up to 9% - 12% by weight of
the total in addition to other wastes that may contain higher
proportions of plastics. The majority of plastic waste
generated is landfilled. However the continuous growth of
worldwide plastic consumption due to its short life cycle
compared to other products; roughly 40% have duration of
lifecycle smaller than 1 month, and the legalizations of many
countries concerned with minimizing landfills content and
incinerators led to a necessity of recovering plastic waste
instead of disposing. Incinerationandlandfillingalternatives
were rejected by several countries due to their potential
danger to the environment either by polluting air or land;
which result in not closing the cradle to cradle loop and
depleting natural resources.IntheUnitedStates,plastichada
total amount of 19.2 million tons in 2001, accounting for
about 8.4% of total municipal solid wastes. Thus, used
plastics are becoming a potential worldwide source of raw
materials. As a consequence the tendency towards recycling
has increased resulting in attempts for plastic recovery.
While in 2005, the United States recycled around 5.7% of the
total plastics generated. On the otherhand,somestatesinthe
US like Michigan have a high recycling rate that
accommodates all the waste produced. In Brazil, potential in
recycling have been raised where 15% of all plastics
consumed are recycled and returned to industry. Even
though the technologies and advancements with respect to
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1096
recycling plastics soared, there remains the unanswered
question of cost. A study entitled “The Cost of Reducing
Municipal Solid Waste” showed that the cost becomes an
obstacle duetoenergycost,transportationcost,sorting,labor
cost but if done on a large scale it pays back. After recycling
the waste, it could be reinforced with natural fibers such as
rice straw to enhance the mechanical properties. Rice straw
can work well with recycled polymer as reinforcing filler.
Natural fibers have the advantages of low density, low cost,
and biodegradability. However, the main disadvantages of
natural fibers in composites are the poor compatibility
between fiber and matrix and the relative high moisture
sorption. Therefore, chemical treatments using acids or
alkalis are considered in modifying the fiber surface
properties. This improves the thermal stability of fibers,
compatibility and interfacial bond stress.Thetreatmentalso
removes any impurities of the fiber.Fibertreatmentthrough
carbonization is a treatment for rice straw fibers in which
heating without air occurs. The pore structure and
adsorption properties of carbonized fibersare stronglyused
in several applications due to improved mechanical
properties. The steps of carbonization include thermal
treatment of raw fibers in an inert atmosphere followed by
an activation step with CO2 or steam at the same
temperature used. In chemical activation, the raw fibers
were impregnated in a solution of phosphoric acid and
heated at 900˚C in an inert atmosphere. This chemical
treatment leads to a high porosity, which enables a high
adsorption capacity for micro pollutants. Moreover, it
produces numeric acidic surface groups involved in the
adsorption mechanism of dyes and metal ions.
2. Composition of Municipal Solid Waste
The biodegradable portion dominatesthe bulk ofMunicipals
Solid Waste. Generally the biodegradable portion is mainly
due to food and yard waste. With rising urbanization and
change in lifestyle and food habits, the amount of municipal
solid waste has been increasing rapidly and its composition
changing.
2.1 Objective
Plastic wastes are a major environmental concern thatneeds
to be dealt with to minimize the amount of municipal solid
waste, depletion of natural resources and enhancing the
sustainability concept forfuturegenerations.Theobjectiveof
this work is to enhance the properties of plastic waste
through reinforcement with natural fiber such as rice straw,
using a simple and effective technology. Rice straw will be
treated using acids, alkali and carbonization treatment. The
mechanical properties of plastic wastes reinforced with
treated rice straw will be investigated using flexural, tensile
stress tests. The synthesized recycled composites will be
compared with the recycled polymer without reinforcement
to observe the effect of reinforcement on the mechanical
properties of the composite.
Figure 1 Pie chart for the various category of waste
generated.
3. Materials and Methods
Plastic waste was collected from different hospitals of the
city. For sorting and shredding of waste SL PlasticIndustries
In Kanpur Industrial Estate Kanpur, India were approached.
Different categories of plastic were separated from waste.
64% of the waste was LDPE, 32% was HDPE and 4%
Polypropylene.
All three types of waste was shredded (Figure 1(a)), mixed
together and then heated (Figure 1(b)). Semi solid form of
plastic obtained was cut at regular intervals and further
pulverized first manually (Figure 1(c)) then by Jaw crusher
(a) (b) (c)
Figure 2. (a) Shredded plastic waste (b) Plastic heating
pipe (c) Aggregate pulverization.
3.1. Experimental Programme
Following tests were performed on aggregates:
 Specific Gravity & Water Absorption (AASHTO T 85
ASTM Designation: C 128-88)
 Aggregate Impact Value Test (BS 812-112:1990)
 Aggregate Crushing Value Test (BS 812-110:1990)
 Loss Angeles Abrasion Test (AASHTO designation:
T96| ASTM C 535-12)
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1097
 Soundness of Aggregate Test (AASHTO T 104 and
ASTM C 88)
4. Results
4.1. Specific Gravity and Water Absorption
Specific gravity of plastic aggregates was less than natural
aggregates. Low density of LDPE, HDPE and polypropylene
was main reason for this decrease in density. Water
absorption of plastic aggregates on the other hand was very
high. Branched molecular structure of LDPE was the reason
of this high water absorption.
4.2. Soundness Test
Any type of polythene, whether HDPE or LDPE is generally
inert to chemicals. The reason for this is lack of polarity in
polythene molecules. HDPE in comparison to LDPE is more
resistant to chemicals actions because it’s low permeability.
Low permeability comesbecauseofhighmolecularweightof
HDPE.
4.3. Density and Percent Voids of Asphalt Samples
Due to lesser density of plastic aggregates, asphalt samples
made of replaced plastic aggregates showed lower densities
with increasing plastic aggregatespercentage.Asmostofthe
bitumen was used in filling pores of plastic aggregates, less
bitumen was available to fill asphalt void. This increased
percent voids in asphalt mixes.
4.4. Stability and Flow Results
Stability of the mixes showed increasing trend up to 20%
replacement than sudden decrease in stabilitywasobserved
This decrease in stability may be because of higher porosity
of plastic aggregates. Most of the binder was used in filling
the pores of plastic aggregates leaving behind insufficient
quantity of bitumen to make stronger bond. As the
compressibility of plastic aggregates was greater than
natural aggregates, asphalt sampleshavingplastic aggregate
had higher flows Flow values increased with increasing
plastic aggregate percentage but decreased at 25%
replacement. This decrease was due to decrease in stability
of mixes at 25% replacement.
Figure 3. (a) Density of asphalt mixes; (b) Voids in asphalt
samples.
Fig 4 (a) Marshall stability of asphalt mixes; (b) Flow of
asphalt mixes.
5. Conclusions
1- The investment for an on-site waste management system
in an individual health care setting is very high. In contrast,
an integrated common treatment & disposal facility cost a
maximum of Rs. 8 to 22 /kg/day with an added benefit of no
capital investment being required. The company could have
profit about 35% making it a sustainable venture if they use
natural fibers as packaging material instead of plastic The
natural fibers are environmentally sound it will also give
good market cost to the farmers
2- There is no proper solid waste management system for
Kanpur city. Mostly people throw the waste in their streets,
where it is either picked up by scavengers or dumped there
for years. In relatively developed areas of the city,
scavengers collect the waste and dump it in an open area
usually at a distance from densely populated area. Existing
landfills of the city are not well designed. Open burning of
waste on the dumpsites is observed. Major portion of the
waste generated by the city is plastic. Plastic waste can be
converted to aggregates by proper manufacturing setup.
References
1. L. F. Diaz, A. Chiumenti, G. Savage and L. Eggerth,
“Managing the Organic Fraction of Municipal Solid
Waste,” Biocycle, Vol. 47, No. 10, 2006, pp. 50-53.
2. US Environmental Protection Agency, “Municipal
Solid Waste Generation, Recycling and Disposal in
the United States: Facts and Figures for 2003,” US
Environmental Protection Agency, Washington DC,
2005.
3. K. Palmer, H. Sigman and M. Walls, “The Cost of
reducing Municipal Solid Waste. Resources for the
Future,”
4. S. P. Chandak, “Waste Biomass Workshop,” UNEP S.
2010.http:/www.cshd.dap.edu.ph/unep_biomassA.
E. O. Elkhalifa, D. M. R. Georget, S. A. Barker
5. Vigil, S.A., Theisen, H. and Tchobanoglous,G.(1993)
Integrated Solid Waste Management: Engineering
Principles and Management Issues. McGraw-Hill
Higher Education, USA.

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IRJET- Substituting Natural Fiber by Plastic Waste

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1095 Substituting Natural Fiber by Plastic Waste Prashast Dheer1, Satya Veer Singh2 1M.Tech Student, Department of Civil Engineering, Rama University, (India) 2Assistant Professor, Department of Civil Engineering, Rama University, (India) ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - This article reviews the literature reports base on agro waste plastic composites using different fiber as fillers and rein- for cements. Various processing methods and conditions; compression molding process, injection molding, and extru- Sion method are used in the composites productions. Characterization challenges associated with the agro waste plastic composites productions were also examined. Thus, the findings of this research review can be used as a data base for further inquiring into the agro waste plastic composites in a view to enhancethe developmentof the sector. Plastic wastes are a major environmental concern that needs to be dealt with to minimize the amount of municipal solid waste and depletion of natural resources thus enhancing the sustainability concept for future generations. The objective of this study is to enhance the propertiesofplasticproducts using plastic wastes reinforced with treated natural fibers such as rice straw as well as carbonized rice straw, using a simpleand efficient technology. Keywords: Polymers-Matrix Composites (PMCs); Recycled Polymer; Natural Fibers; Fiber Reinforced Plastic; Agro Waste Plastic Composite; Characterization; Production I. INTRODUCTION In developing countries of the world, plastic waste has become a current challenge for the environmental engineers to solve. For an example developing country like India, statistics show that the exponential growthrateofIndia with 1,210,000,000 (1.21 billion) people is the second most populous country in the world, whileChina isonthetop with over 1,350,044,605 (1.35 billion) people. The figures show that India represents almost 17.31% of the world's population, which means one out of six people on thisplanet live in India. Although, the crown of the world's most populous country is on China’s head for decades, India is all set to take the numerous positions by 2030. With the population growth rate at 1.58%, India is predicted to have more than 1.53 billion people by the end of 2030. Being second most populous country in the world, India continuously keeps on adding waste material within its geographical boundaries. India has about 16% of the world population and 2.5% of world’s land area. In an already densely populated country with even more densely packed urban centers, land for properwastetreatment,disposal and overall man-agreement is scarce. Recent and sustained economic growth increasing living standards of the people, in-creased manufacturing and production activities has led to increase to rapid rise in the waste generation rated. India produces around 42 Million tons of solid waste annually. There is wide difference in the waste generation rates in rural and urban areas. Even within the urban areas, the composition includes more paperandinertmaterial andless of organic and compostable material as the city population and size increases Now with the above data we can calculate the per day generation of solid waste of India & also we can calculate the expected cost for its management whichcan be done by the processes minimization, recycling & disposal of the solid waste generated. These processes have been adopted by the most developed countries as the menu for developing solid waste management strategies. Depending upon a number of factors such as topography climate, population density (village to metro city), transportation infrastructure, socioeconomic and environmental laws of India it is important to make proper pre action plan to manage solid waste. The market potential regarding the usage of plastic waste into other utilizations is huge due to the high amounts of its disposition which constitute the largest share of the global municipal solid waste (MSW). Plastics account for an increasing fraction of municipal solid waste around the world. In India, plastic in MSW makes up to 9% - 12% by weight of the total in addition to other wastes that may contain higher proportions of plastics. The majority of plastic waste generated is landfilled. However the continuous growth of worldwide plastic consumption due to its short life cycle compared to other products; roughly 40% have duration of lifecycle smaller than 1 month, and the legalizations of many countries concerned with minimizing landfills content and incinerators led to a necessity of recovering plastic waste instead of disposing. Incinerationandlandfillingalternatives were rejected by several countries due to their potential danger to the environment either by polluting air or land; which result in not closing the cradle to cradle loop and depleting natural resources.IntheUnitedStates,plastichada total amount of 19.2 million tons in 2001, accounting for about 8.4% of total municipal solid wastes. Thus, used plastics are becoming a potential worldwide source of raw materials. As a consequence the tendency towards recycling has increased resulting in attempts for plastic recovery. While in 2005, the United States recycled around 5.7% of the total plastics generated. On the otherhand,somestatesinthe US like Michigan have a high recycling rate that accommodates all the waste produced. In Brazil, potential in recycling have been raised where 15% of all plastics consumed are recycled and returned to industry. Even though the technologies and advancements with respect to
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1096 recycling plastics soared, there remains the unanswered question of cost. A study entitled “The Cost of Reducing Municipal Solid Waste” showed that the cost becomes an obstacle duetoenergycost,transportationcost,sorting,labor cost but if done on a large scale it pays back. After recycling the waste, it could be reinforced with natural fibers such as rice straw to enhance the mechanical properties. Rice straw can work well with recycled polymer as reinforcing filler. Natural fibers have the advantages of low density, low cost, and biodegradability. However, the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative high moisture sorption. Therefore, chemical treatments using acids or alkalis are considered in modifying the fiber surface properties. This improves the thermal stability of fibers, compatibility and interfacial bond stress.Thetreatmentalso removes any impurities of the fiber.Fibertreatmentthrough carbonization is a treatment for rice straw fibers in which heating without air occurs. The pore structure and adsorption properties of carbonized fibersare stronglyused in several applications due to improved mechanical properties. The steps of carbonization include thermal treatment of raw fibers in an inert atmosphere followed by an activation step with CO2 or steam at the same temperature used. In chemical activation, the raw fibers were impregnated in a solution of phosphoric acid and heated at 900˚C in an inert atmosphere. This chemical treatment leads to a high porosity, which enables a high adsorption capacity for micro pollutants. Moreover, it produces numeric acidic surface groups involved in the adsorption mechanism of dyes and metal ions. 2. Composition of Municipal Solid Waste The biodegradable portion dominatesthe bulk ofMunicipals Solid Waste. Generally the biodegradable portion is mainly due to food and yard waste. With rising urbanization and change in lifestyle and food habits, the amount of municipal solid waste has been increasing rapidly and its composition changing. 2.1 Objective Plastic wastes are a major environmental concern thatneeds to be dealt with to minimize the amount of municipal solid waste, depletion of natural resources and enhancing the sustainability concept forfuturegenerations.Theobjectiveof this work is to enhance the properties of plastic waste through reinforcement with natural fiber such as rice straw, using a simple and effective technology. Rice straw will be treated using acids, alkali and carbonization treatment. The mechanical properties of plastic wastes reinforced with treated rice straw will be investigated using flexural, tensile stress tests. The synthesized recycled composites will be compared with the recycled polymer without reinforcement to observe the effect of reinforcement on the mechanical properties of the composite. Figure 1 Pie chart for the various category of waste generated. 3. Materials and Methods Plastic waste was collected from different hospitals of the city. For sorting and shredding of waste SL PlasticIndustries In Kanpur Industrial Estate Kanpur, India were approached. Different categories of plastic were separated from waste. 64% of the waste was LDPE, 32% was HDPE and 4% Polypropylene. All three types of waste was shredded (Figure 1(a)), mixed together and then heated (Figure 1(b)). Semi solid form of plastic obtained was cut at regular intervals and further pulverized first manually (Figure 1(c)) then by Jaw crusher (a) (b) (c) Figure 2. (a) Shredded plastic waste (b) Plastic heating pipe (c) Aggregate pulverization. 3.1. Experimental Programme Following tests were performed on aggregates:  Specific Gravity & Water Absorption (AASHTO T 85 ASTM Designation: C 128-88)  Aggregate Impact Value Test (BS 812-112:1990)  Aggregate Crushing Value Test (BS 812-110:1990)  Loss Angeles Abrasion Test (AASHTO designation: T96| ASTM C 535-12)
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1097  Soundness of Aggregate Test (AASHTO T 104 and ASTM C 88) 4. Results 4.1. Specific Gravity and Water Absorption Specific gravity of plastic aggregates was less than natural aggregates. Low density of LDPE, HDPE and polypropylene was main reason for this decrease in density. Water absorption of plastic aggregates on the other hand was very high. Branched molecular structure of LDPE was the reason of this high water absorption. 4.2. Soundness Test Any type of polythene, whether HDPE or LDPE is generally inert to chemicals. The reason for this is lack of polarity in polythene molecules. HDPE in comparison to LDPE is more resistant to chemicals actions because it’s low permeability. Low permeability comesbecauseofhighmolecularweightof HDPE. 4.3. Density and Percent Voids of Asphalt Samples Due to lesser density of plastic aggregates, asphalt samples made of replaced plastic aggregates showed lower densities with increasing plastic aggregatespercentage.Asmostofthe bitumen was used in filling pores of plastic aggregates, less bitumen was available to fill asphalt void. This increased percent voids in asphalt mixes. 4.4. Stability and Flow Results Stability of the mixes showed increasing trend up to 20% replacement than sudden decrease in stabilitywasobserved This decrease in stability may be because of higher porosity of plastic aggregates. Most of the binder was used in filling the pores of plastic aggregates leaving behind insufficient quantity of bitumen to make stronger bond. As the compressibility of plastic aggregates was greater than natural aggregates, asphalt sampleshavingplastic aggregate had higher flows Flow values increased with increasing plastic aggregate percentage but decreased at 25% replacement. This decrease was due to decrease in stability of mixes at 25% replacement. Figure 3. (a) Density of asphalt mixes; (b) Voids in asphalt samples. Fig 4 (a) Marshall stability of asphalt mixes; (b) Flow of asphalt mixes. 5. Conclusions 1- The investment for an on-site waste management system in an individual health care setting is very high. In contrast, an integrated common treatment & disposal facility cost a maximum of Rs. 8 to 22 /kg/day with an added benefit of no capital investment being required. The company could have profit about 35% making it a sustainable venture if they use natural fibers as packaging material instead of plastic The natural fibers are environmentally sound it will also give good market cost to the farmers 2- There is no proper solid waste management system for Kanpur city. Mostly people throw the waste in their streets, where it is either picked up by scavengers or dumped there for years. In relatively developed areas of the city, scavengers collect the waste and dump it in an open area usually at a distance from densely populated area. Existing landfills of the city are not well designed. Open burning of waste on the dumpsites is observed. Major portion of the waste generated by the city is plastic. Plastic waste can be converted to aggregates by proper manufacturing setup. References 1. L. F. Diaz, A. Chiumenti, G. Savage and L. Eggerth, “Managing the Organic Fraction of Municipal Solid Waste,” Biocycle, Vol. 47, No. 10, 2006, pp. 50-53. 2. US Environmental Protection Agency, “Municipal Solid Waste Generation, Recycling and Disposal in the United States: Facts and Figures for 2003,” US Environmental Protection Agency, Washington DC, 2005. 3. K. Palmer, H. Sigman and M. Walls, “The Cost of reducing Municipal Solid Waste. Resources for the Future,” 4. S. P. Chandak, “Waste Biomass Workshop,” UNEP S. 2010.http:/www.cshd.dap.edu.ph/unep_biomassA. E. O. Elkhalifa, D. M. R. Georget, S. A. Barker 5. Vigil, S.A., Theisen, H. and Tchobanoglous,G.(1993) Integrated Solid Waste Management: Engineering Principles and Management Issues. McGraw-Hill Higher Education, USA.