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OPTIMIZATION AND TREATMENT OF WASTEWATER USING NATURAL COAGULANTS
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OPTIMIZATION AND TREATMENT OF WASTEWATER USING NATURAL COAGULANTS
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IRJET Journal
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OPTIMIZATION AND TREATMENT OF WASTEWATER USING NATURAL COAGULANTS
1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 09 | Sep 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 1166 OPTIMIZATION AND TREATMENT OF WASTEWATER USING NATURAL COAGULANTS Ane. Mounika1, Dr. H B Aravinda2 1 P.G Student, Department of Environmental Engineering, Bapuji Institute of Engineering and Technology, Davanagere, Karnataka, India 2Principal, Bapuji Institute of Engineering and Technology, Davanagere, Karnataka, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Sewage wastewater is generating in larger quantity from various activities of living beings in day-to-day life. Which has led to be major concern in treating and discharging it to environment. Now a days huge number of research works are conducted to encounter theseproblems. In present study sewage waste-water is taken to analysis and generally to remove turbidity in any sort of polluted water chemical-based coagulants are used in reducing turbidity and other process like coagulation/flocculation process. Natural coagulants Okra and jackfruit seed has been used in replacing these chemical-based coagulants/flocculants. Firstly, initial parameters of sewage waste-water has been examined through standard procedures and later this sewage waste- water has been treated with okra powder and jackfruit seed powder in the form of natural-coagulants, mainly optimum dosages of both coagulants as performed using standard jar apparatus, which gave optimum dosage of okra powder and jackfruit seed powder as 120mg/l and 80mg/l respectively. Jackfruit seed powder has been more efficient in turbidity reduction with 84% efficiency, wherehasokrapowder treated about 60% and Okra has been found moreefficient inreducing COD about 80% but where has jackfruit seed powder was resulted to be 72% COD reduction. In BOD analysis Okra powder showed more efficiency about 48% when comparing to jackfruit seed powder which reduces to 21%. Okrahasbeen found to be more effective and can be increases its efficiency by increasing its dosages. Key Words: Coagulation-flocculation Process, Jar Test, Natural coagulants, jackfruit seed, okra. 1.INTRODUCTION Sewage/domestic Wastewater which is generated from various communities, which cannot be used directly for various purposes. It can be categorized by how it has been generated, in broad prospectivewastewatercanbeexplicate as mixture of more than one wastage, which includes waste from domestic, industries, institutional waste.Thedischarge of untreated domestic sewage and toxic industrial effluents of water courses has impacted the quality of natural water. Examining the quantification and process of treating wastewater from sewage is controlled and ruled by CPCB in central level and SPCBs/Pollution control Committees and local bodies of States. Generally, SBR and ASP techniques have been used in almost STPs. Unprocessed sewage may contain waste, unwanted nutrients, solids, pathogens, oil and greases and heavy metals. sewage treatment plantsundergosomeconventional methods like filtration, activated charcoal method and flocculation/coagulation method which is very important primary treatment, (P.Rajasulochana et al., 2016). In this present study we mainly aimed to derive natural coagulants/flocculants in replacement with conventional, chemical coagulants which leads to sustainable development. Coagulation/Flocculation treatment method,whichisvastly used in wastewater treatment. The major role of this treatment method has to get rid of suspended colloidal particles (Amir Hariz Amran et al.,2018) and to get rid of turbidity in wastewater and the water which contains more pollutants. Natural coagulants/flocculants are emerging as one of the most used coagulants/flocculants because of their easy availability and sustainable nature. Natural coagulants/flocculants are extracted from so many sources for example: Plant based, animal based and organism based. After coagulation/flocculationtreatmentof wastewaterwith synthetic or chemical coagulants/flocculants, (Vicky Kumar et al., 2017). It has resulted in huge generation of toxic sludge that makes complication in disposing of sludge. The sludge produced from this coagulation/flocculation process is very toxic in nature, it is caused due to improper reaction of synthetic coagulant/flocculant (Setyo Budi Mohd Said et al.,2020). In this study we have been used okra and jackfruit seed as natural coagulant/flocculant to know their efficiency. 1.1 Scope of present study In this study it is mainly focused on usage of naturally and locally available fruits, vegetable wastes and agricultural waste, which can be abundantly available in nature which can used as natural coagulants instead of using chemical coagulants, which produces harmful sludge after treatment and using these naturally derived coagulants which leads to
2.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 09 | Sep 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 1167 sustainable environment. In this study jackfruit seed and okra has been used to know the efficiency, there coagulation/flocculation nature and behavior of thisnatural coagulants/flocculants with sewage wastewater treatment. 1.2 Objectives 1. To collect and examine the characteristics of sewage waste water. 2. To determine the performance of Okra and Jackfruit seed as natural coagulant. 3. To extract natural coagulant from okra and jackfruit seed. 4. To identify the efficiency of jackfruit seed and okra as natural coagulants in treatment of sewage wastewater. 5. To Know the feasibility of using natural coagulants/flocculants as alternate to chemical coagulants/flocculants. 6. To remark the Sustainability and cost effectiveness of natural coagulants/flocculants over synthetic coagulants. 2. MATERIALS AND METHODOLOGY 2.1 Preparation of Natural coagulants 2.1.1 Jack fruit seed Jack fruit seed was collected about 1kg of seeds were collected, peeled of above layer of jackfruit seed andcleaned with water to remove impurities. Then these seeds were sundried for about 4-5 days, later these seeds were chopped to pieces and grind into fine powder then sieved in 4.75 mm sieve (Aneesu Rahman et al., 2018). This powder was stored in air-tight container to prevent impurities and moisture to enter the powder. Further this jackfruit seed powder isused for experiment, laterdilutionswerepreparedabout0.1gram of powder was diluted in 100 ml distilled water and further dilutions were as per requirement for studies. Fig-1: Jackfruit seed powder Preparation. 2.1.2 Okra seed okra has been cleanly washed with water 2 to 3 times, then okra was wiped with cleanclothtoremovemoisturecontent, then okra has been chopped into very small pieces and kept in hot air oven at 105ºC for 24 hours. This hot air-dried okra was grinded in normal blender to a fine texture, further this powder was sieved in 4.75mm sievelaterthissievedpowder is stored in a tight container to prevent entering of air and impurities which may cause change in characteristic of the powder (Muhammad Ridwan Fahmi et al., 2014). This powder was used carefully as per requirement for the present study, later about 0.1 gram of powder is diluted in 100 ml of distilled water and further differentdilutionswere prepared as per requirement of the ongoing project. Fig 2- Okra powder Preparation 2.2 Sample collection and analysis Raw sewage wastewater was collected using grab sampling technique from 20 MLD sewage treatment plant was usedin this study. The sample was collected atreceivingchamberor raw sewage sump, the color of the sample collected was green-brownish in color and very turbid which is situated before fine screen channels and grit chamber without disturbing the sample about 20 litersofrawsamplehasbeen collected in wastewater storing containers and carried to laboratory and preserved in very cool room temperature. Main purpose of this study is to identify initial raw wastewater characteristics like, PH, turbidity, total solids, Cod and Bod before and after treatment. Table -1: Initial characteristics of Sewage waste water. Characteristics Values PH 7.18 Turbidity 678 NTU Total solids 1200 mg/l Total dissolved solids 700 mg/l COD 800 mg/l BOD 380 mg/l
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 09 | Sep 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 1168 3. RESULTS AND DISCUSSION Performing out the jar test with different proportions of dosages of jackfruit seed powder and okra seed powder according to standard jar test procedure and then followed by turbidity test for supernatants from each jar of jar test. Optimum dosage of both okra and jackfruit seed was found accordingly to the least turbidity value.Furtherexperiments were optimized usingoptimumdosageasdosagefortreating other parameters of sewage wastewater. From the jar and turbidity tests the optimum dosage of jackfruit seed powder was found to be 80 mg/l and for okra it was found to be 120 mg/l. Chart 1- PH Variation Chart 2- Turbidity Variation Table -2: Characteristics of sewage waste water after treatment. From this present study okra and jackfruit seed has been used as natural coagulants in coagulation/flocculation process in treating of sewage wastewater. From the results obtained we can conclude that optimum dosage of both coagulants okra and jackfruit seed powder are obtained to be 120 mg/l and 80 mg/l respectively by performingjartest. In this work it has been shown the efficiencies of both jackfruit seed powder and okra powder in treating different sewage wastewater characteristics. When we compared the efficiency of both natural coagulants/flocculants. Okra powder was turned out to be more effective in removing COD, Total dissolved solids, BOD. Parameters of sewage water using jackfruit seed powder was turned out to be more effective in removing turbidity of sewage wastewater. 4 CONCLUSION The outcomes were resulted as showing turbidity reduction efficiency was found to be 60% when raw sample is treated by okra powder and 84% turbidity reduction efficiency when it is treated with jackfruit seed powder, when COD experiment was conducted using these coagulants the results were obtained as 80% COD reducing efficiencywhen okra powder used as coagulant and when jackfruit seed powder was used as coagulant it was turned to be 72% reduction in COD. When BOD test was conducted using okra powder as coagulant material it was turned out be reduced to 48% and by using jackfruit seed powder BOD was reduced to 21%, which can be improved by increasing the dosages. It can be concluded that using both natural coagulants we came to know that jackfruit seed powder has been more effective in removing turbidity effectively and okra powder has been showed more effective in removing COD and BOD effectively. REFERENCES [1] Amir Hariz Amran, Nur Syamimi Zaidi, Khalida Muda, Liew Wai Loan. “Effectiveness of natural coagulant in coagulation process: A Review”. International journal of engineering and technology, 7 (3.9) (2018) 34-37. Sl. No Characteristics Okra Jackfruit seed 1 PH 7.34 7.27 2 Turbidity 271NTU 108NTU 3 Total Solids 750mg/l 845 mg/l 4 Total dissolved solids 580mg/l 600 mg/l 5 COD 200mg/l 300mg/l 6 BOD 160mg/l 180mg/l
4.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 09 | Sep 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 1169 [2] Aneesu Rahman, Aswathy Ramesh, Rajitha O R, Suranya T, Jency Nadayil. “Efficiency of jackfruit seed powder as a natural coagulant”. International Research journal of EngineeringandTechnology,volume:05,Issue:03|Mar-2018 e- 2395-0056, pp-2395-0072. [3] B.A.P. Serasinghe, N.S. Abeysingha, D.M.S.H. Dissanyake and N.V.H.S.K. Vithanage. “Effectiveness of Locally Available Plant Materials in the Dry Zone of Sri Lanka as Natural Coagulants in Treating Turbid Water”. The journal of Agriculturl Sciences-Sri Lanka, Vol-17, No 1, January 2022. Pp-161-170. [4] Belbahloul Mounir,ZouhriAbdeljalil andAnourAbdellah. “Comparison of the Efficiency of Two Bio-flocculants in Water Treatment”. International Journal of Scientific Engineering and Technology, Vol-3, Issue-No 6, 1 June2014, e-2277-1581, pp-734-737. [5] Bouthaina Othmani, Maria Graca Rasterio.Moncef Khadhraoui. “Toward green technology: a review on some efficient model plant-based coagulants/flocculants for freshwater and wastewater remediation”. Clean Technologies and Environmental Policy, 2 May 2020. [6] Chai Siah Lee, Mei Fong Chong,John Robinson and Eleanor Binner. “Preliminary Study on Extraction of Bio- flocculants from Okra and Chinese Yam”. Vol-15, No.1, (2015), pp- 41-5. [7] CWJ Cheng, N Ismail and KS Oh. “TreatmentofGreywater by Using Artocarpus Heterophyllus Seeds as A Natural Coagulant”. Journal of Physis: ConferencesSeriese-2222,01, (2014). [8] Edilson de Jesus, Paulo Victor Cruz, Jose Adair Pacifico, Antonio Santhos Silva. “Removal of Turbidity, Suspended Solids and Ions of Fe from Aqueous Solution using Okra powder by coagulation-flocculation Process”. American Journal of Water Resources, (2013), Vol. 1, No.3, pp- 20-24. [9] K. A. Sheik Syed Ishak, A. Panneerselvam, V. Ambikapathy, R. Sathya, A. Vinothkanna.“Aninvestigation of sewage water treatment plant and its physico-chemical analysis”. Biocatalysis and Agricultural Biotechnology. 35 (2021) 102061. [10] Livia Carneiro-Marra; Larissa Sad; Marcelo Da Silva- Bastista. “Evaluation of mucilage and powder of Okra asbio- flocculant in water treatment”. Revista Ion. e-2145-8480 (2019). [11] Lukman Aliyu, Mukhtar L.W, S.I Abba. “Evaluation of Coagulation Efficiency of Natural Coagulants (Moringa Oliefera, Okra) and Alum, For Yamuna water Treatment”. International Journal of Advance Research in Science and Engineering. Vol. No 4, Special Issue (01), September 2015. [12] Mahmood N.A.C and Zaki Z.Z.M. “The Effectiveness of Raw and Dried Artocarpus Heterophyllus (jackfruit) seedas Natural Coagulant in water Treatment”. Materials science and Engineering 601 (2019) 012010. [13] Mohammed Kadhem Abid,HusniBinIbrahim, Syaizwan Zahmir Zulkifli. “Synthesis and Characterization of Biochar from peel and seed of jackfruit plant waste for the adsorption of copper Metal Ion from water”. Research j. pharm. And Tech. 12(9): September 2019, e-0974-3618. [14] Mohd Suffian Yusoff, Noor Aina Mohamad Zukil and Mohd Fai Muaz Ahmad Zamri. “Effectiveness of Jackfruit seed starch as coagulant aid in landfill leachate Treatment Process”. International Journal of GEOMATE, oct., 2016, Vol. 11, Issue 26, pp. 2684-2687. [15] Muhammad Ridwan Fahmi, Nasrul Hamidin, Che Zulzikrami Azner Abidin, M.A. Umi Fazara and M.D. Irfan Hatim. “Performance Evaluation of okra as coagulant for turbidity removal in water treatment”. Key Engineering Material (2014). [16] Nilanjana Das, Nupur Ojha and Sanjeeb Kumar Mandal. “Wastewater treatment using plant-derived bioflocculants: green chemistry approach for safe environment”. Water Science and technology | 83.8| 2021. [17] Nur Shahzaiwa Wafa Shahimi, Nur Syamimi Zaidi, Muhammad Burhanuddin Bahrodin and Amir Hariz Amran. “Utilization of fruit wastes (jackfruit and mango seeds and Banana Trunk) as natural coagulants in treating Muncipal Wastewater”. Materials Science and Engineering 1144 (2021) 012049. [18] Nor Suhaili Binti Mohamad Zin, Wan Nurhazirah Binti Kamaruzaman, Chia Soi Lee. “Study the effectiveness of Biocoagulant Between Alovera (L.). Burm. F And Okra Mucilage in Coagulation and Flocculation Treatment”. ResearchGate (2016). [19] P. Rajasulochana, V. Preethy.“Comparisionon efficiency of various techniques in treatment of waste and sewage water- A comprehensive review “. ScienceDirect (2016). [20] Rajesh K. Kaushal, Hemant Goyal. “Treatment of Waste Water Using Natural Coagulants”. International conference on “Recent advances in Interdisciplinary Trends in Engineering and Applications”. (2018-2019). [21] Rijimol.P.M, Lubna.C.H. “Evaluation of Aluminum Removal Efficiency of Jackfruit seed Powder and Guava Leaf Powder”. International Research journal of Engineeringand Technology. Vol-07 Issue-3 Mar 2020, e-2395-0056 p-2395- 0072. [22] Sarva Mangala Praveena,MuhammadImranShamsudin. “Preliminary analysis of selected tropical fruit seed extracts
5.
International Research Journal
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