This document summarizes the characterization and corrosion behavior of a Poly(ɛ-caprolactone)/Hydroxyapatite (PCL/HA) composite coating on Ti6Al4V fabricated using a dip-coating technique. The study aims to develop a polymer-ceramic composite coating to improve the adhesion of HA coatings and provide better corrosion protection compared to HA alone. Various concentrations of PCL were tested, and coatings with 30% PCL showed a densely packed structure and the best corrosion resistance based on electrochemical tests. The addition of PCL improved the adhesion of HA and could be a potential coating for biomedical applications.