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INNOVATIONS IN DYEING OF COTTON WITH INDIGO R.B.CHAVAN, S.JAHAN,  J.N.CHAKRABORTY Department of Textile Technology Indian Institute of Technology Hauz-Khas, New Delhi 110016
FUNDAMENTALS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
pH EFFECT ,[object Object]
TWO   INDIGO FORMS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MATERIALS   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
EXPERIMENTAL ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
DYE BATH ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
DYEING ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
INDIGO ON FABRIC ,[object Object],[object Object],[object Object],[object Object]
NaOH EQUIVALENCE OF ORGANIC ALKALI ,[object Object],[object Object],[object Object]
ALKALI CONCENTRATION IN DYE BATH ,[object Object],[object Object]
NA 2 S 2 O 4  CONCENTRATION IN DYEBATH ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
NaOH Equivalence of Organic Alkalis 2.43 3.81 2.24 2.94 Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV NaOH Equivalence (1gm) Organic Alkali
DYEBATH STABILITY AND COLOUR BUILD UP ,[object Object],[object Object],[object Object]
Effect of Different Alkalis on Indigo Dye bath Stability and Colour Build up 100/15 110.0 63.5 104.6 124.4 100/14 121.1 - 137.5 155.8 100/14 118.6 148.5 140.1 146.1 100/13 133 155 133.6 143.1 100/13 128   142 131 139 NaOH Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV 8hrs 6hrs 4hrs 2hrs 0hrs Alkali
OBSERVATIONS ,[object Object],[object Object],[object Object],[object Object]
CHANGE OF pH WITH TIME BEFORE  PADDING   11.4 10.3 9.6 10.1 10.2 11.4 10.5 10.0 10.4 10.5 11.5 10.6 10.3 10.5 10.5 11.6 10.7 10.5 10.7 10.6 12.3 10.8 10.6 10.8 10.8 NaOH Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV 8hr 6hr 4hr 2hr 0hr Alkali
OBSERVATIONS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Effect of Number of dips on Alkali Consumption 17.5 15.8 14.8 29.9 16.2 14.3 12.2 28.1 15.0 13.1 9.5 20.5 12.5 11.8 8.7 21.8 11.2 9.2 7.8 18.7 10 7.9 6.9 12.5 NaOH Organic Alkali I Organic Alkali III Organic Alkali IV 6 5 4 3 2 1 % Consumption of  alkali after each dip Alkali
ALKALI CONSUMPTION ,[object Object],[object Object],[object Object],[object Object]
Effect of Number of dips on Na 2 S 2 O 4  Consumption 89.2 89.0 81.7 83.0 78.5 80.8 79.8 76.7 67.8 80.0 73.1 67.8 60.7 74.5 67.3 58.9 53.5 67.2 61.5 53.6 48.2 52.0 40.3 37.5 NaOH Organic Alkali I Organic Alkali III Organic Alkali IV 6 5 4 3 2 1 % Consumption of Na 2 S 2 O 4 Alkali
Na 2 S 2 O 4  CONSUMPTION ,[object Object],[object Object],[object Object],[object Object],[object Object]
SIMULATION OF COMMERCIAL DYEING PRACTICE ,[object Object],[object Object]
SIMULATION OF COMMERCIAL DYEING PRACTICE 11.9 10.7 16.3 19.7 12.3 10.9 16.7 20.7 NaOH Organic Alkali I pH K/S pH K/S Sample of the  7 th  day Sample of the 1 st  day Alkali
CONCLUSION ,[object Object],[object Object],[object Object],[object Object]
IRON (II) SALT COMPLEXES ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
ALTERNATIVE  ECO-FRIENDLY REDUCING AGENTS ,[object Object],[object Object],[object Object],[object Object]
IRON (II) SALT COMPLEXES ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Fe(OH) 2  AS REDUCING AGENT

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Innovations in dyeing of cotton with indigo

  • 1. INNOVATIONS IN DYEING OF COTTON WITH INDIGO R.B.CHAVAN, S.JAHAN, J.N.CHAKRABORTY Department of Textile Technology Indian Institute of Technology Hauz-Khas, New Delhi 110016
  • 2.
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  • 4.
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13. NaOH Equivalence of Organic Alkalis 2.43 3.81 2.24 2.94 Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV NaOH Equivalence (1gm) Organic Alkali
  • 14.
  • 15. Effect of Different Alkalis on Indigo Dye bath Stability and Colour Build up 100/15 110.0 63.5 104.6 124.4 100/14 121.1 - 137.5 155.8 100/14 118.6 148.5 140.1 146.1 100/13 133 155 133.6 143.1 100/13 128 142 131 139 NaOH Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV 8hrs 6hrs 4hrs 2hrs 0hrs Alkali
  • 16.
  • 17. CHANGE OF pH WITH TIME BEFORE PADDING 11.4 10.3 9.6 10.1 10.2 11.4 10.5 10.0 10.4 10.5 11.5 10.6 10.3 10.5 10.5 11.6 10.7 10.5 10.7 10.6 12.3 10.8 10.6 10.8 10.8 NaOH Organic Alkali I Organic Alkali II Organic Alkali III Organic Alkali IV 8hr 6hr 4hr 2hr 0hr Alkali
  • 18.
  • 19. Effect of Number of dips on Alkali Consumption 17.5 15.8 14.8 29.9 16.2 14.3 12.2 28.1 15.0 13.1 9.5 20.5 12.5 11.8 8.7 21.8 11.2 9.2 7.8 18.7 10 7.9 6.9 12.5 NaOH Organic Alkali I Organic Alkali III Organic Alkali IV 6 5 4 3 2 1 % Consumption of alkali after each dip Alkali
  • 20.
  • 21. Effect of Number of dips on Na 2 S 2 O 4 Consumption 89.2 89.0 81.7 83.0 78.5 80.8 79.8 76.7 67.8 80.0 73.1 67.8 60.7 74.5 67.3 58.9 53.5 67.2 61.5 53.6 48.2 52.0 40.3 37.5 NaOH Organic Alkali I Organic Alkali III Organic Alkali IV 6 5 4 3 2 1 % Consumption of Na 2 S 2 O 4 Alkali
  • 22.
  • 23.
  • 24. SIMULATION OF COMMERCIAL DYEING PRACTICE 11.9 10.7 16.3 19.7 12.3 10.9 16.7 20.7 NaOH Organic Alkali I pH K/S pH K/S Sample of the 7 th day Sample of the 1 st day Alkali
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  • 28.
  • 29. Fe(OH) 2 AS REDUCING AGENT